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Preparation and performance analysis of gas-quenched steel slag beads 气淬钢渣微珠的制备及性能分析
Pub Date : 2020-12-01 DOI: 10.1051/metal/2019073
Hui Wang, Zhang Wei, Chao Liu, Hongwei Xing, Guo Chen, Yuzhu Zhang
The low utilization rate of steel slag in China has exposed serious environmental and social problems. In the present work, the basic oxygen furnace (BOF) slag was modified by blast furnace (BF) slag and then beaded by the means of gas quenching. The gas-quenching rate, bead formation rate, physical properties, microscopic characteristics and free lime (f-CaO) of gas-quenched slag beads were analyzed to broaden the utilization of BOF slag. The results show that the more BF slag is added, the higher the gas-quenching rate is, and the lower the bead formation rate becomes. When no BF slag is added, the beads are mainly composed of magnetite, limonite and melilite. After BF slag is added, a large amount of glass phase and a little amount of Ca2 SiO4 and MgO are found in beads. The content of f-CaO beads decreases after the modified slag is gas quenched at high temperature. Moreover, the more BF slag is added, the higher the elimination rate of f-CaO becomes. Considering the industry standard of steel slag sand in China as well as the gas-quenching rate, physical and chemical properties, the gas-quenched steel slag beads with 5 and 15% BF slag better meet the medium sand standard, which can be used as fine aggregate.
中国钢渣利用率低,暴露出严重的环境和社会问题。本文采用高炉炉渣对碱性氧炉炉渣进行改性,然后采用气淬的方法对其进行钢化处理。分析了气淬渣球的气淬速率、球团形成速率、物理性能、微观特征和游离石灰(f-CaO),拓宽了转炉渣的利用范围。结果表明:炉渣添加量越大,气淬速率越高,球团形成速率越低;当不添加高炉渣时,球团主要由磁铁矿、褐铁矿和镁铝石组成。添加高炉渣后,珠粒中含有大量的玻璃相和少量的Ca2 SiO4和MgO。改性渣经高温气淬后,f-CaO珠含量降低。而且,炉渣添加量越大,f-CaO的去除率越高。综合考虑国内钢渣砂行业标准及气淬率、理化性能,掺5%和15%高炉渣的气淬钢渣微珠较好地满足中砂标准,可作为细骨料使用。
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引用次数: 4
Abnormal toughness characteristics and fracture model in simulated welding HAZ of 5%Ni Steel 5%Ni钢模拟焊接热影响区异常韧性特征及断裂模式
Pub Date : 2020-06-01 DOI: 10.1051/metal/2020037
D. Min
The toughness property of the coarse grained heat affected zone had become much worse since the large heat input welding was applied in HSLA for improving welding efficiency and reducing welding costs. Unlike previous investigations of the decreasing fracture toughness with heating time, the toughness of coarse grained heat affected zone increases in long heating time. Based on microstructure and mechanical properties, very remarkable impact toughness was obtained when the t8/5 was 80 s: toughness of 171 J. The toughness improvement initiates not from inclusions but directly from the microstructure of substrate. The microstructure type and inclusion level will compete to dominate the toughness of the 5% Ni steel.
为提高焊接效率,降低焊接成本,采用大热输入焊接技术,使粗晶热影响区的韧性大大降低。与以往研究的断裂韧性随加热时间降低不同,粗晶热影响区的韧性随加热时间延长而增加。从显微组织和力学性能来看,当t8/5为80 s时,获得了非常显著的冲击韧性,韧性为171 J。韧性的提高不是由夹杂物引起的,而是直接由基体的显微组织引起的。显微组织类型和夹杂物水平对5% Ni钢的韧性起主导作用。
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引用次数: 0
Measurement of the steady state tearing in thin sheets using the contactless system 用非接触式系统测量薄板的稳态撕裂
Pub Date : 2020-05-01 DOI: 10.1051/metal/2020032
Ľ. Ambriško, L. Pešek
The purpose of the present paper is the diagnostic method of the steady state tearing tests in thin steel sheets. The camera-based contactless system was used in the experimental research. The MATLAB software was used for the processing of real-time images. The data collected in the experiments were used to establish the R-curves in terms of the CTOD (crack tip opening displacement) based resistance curves. The innovative techniques allow extracting a large amount of geometrical information about the entire tearing process and the crack tip development. The steady state tearing was evaluated using automotive steel sheets and the tearing resistance was determined for three grades of thin sheets. The paper describes a comprehensive method of obtaining the material properties necessary for modelling and simulation. The proposed methodology for the testing and evaluation of the steady state tearing is applicable to thin sheets. The measurement method within the test for the determination of the tearing resistance was based on the image analysis.
本文的目的是研究薄钢板稳态撕裂试验的诊断方法。实验研究采用了基于摄像机的非接触式系统。利用MATLAB软件对实时图像进行处理。利用实验数据建立基于裂纹尖端张开位移的阻力曲线r曲线。创新的技术允许提取有关整个撕裂过程和裂纹尖端发展的大量几何信息。以汽车钢板为研究对象,对其稳态撕裂性能进行了评价,并对3种等级的薄板进行了抗撕裂性能测定。本文描述了一种获得建模和仿真所需的材料性能的综合方法。所提出的测试和评价稳态撕裂的方法适用于薄板。试验中测定抗撕裂性的测量方法是基于图像分析。
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引用次数: 2
Evaluation of carbothermic processing for mixed discarded lithium-ion batteries 混合废弃锂离子电池碳热处理评价
Pub Date : 2020-04-01 DOI: 10.1051/metal/2020025
Sanjay Pindar, N. Dhawan
The limited life span and huge demand for lithium-ion batteries, environment concerns, and the consumption of rare metals such as lithium and cobalt are the key facts for the worldwide recycling efforts. In this study, the cathode material of discarded lithium-ion batteries was carbothermally reduced using recovered graphite. A comparative evaluation of reduction behavior of single-phase (LiCoO2 ) and mixed-phase (LiCoO2 .LiNi0.5 Mn1.5 O4 .LiMn2 O4 ) cathode materials was investigated under an ambient and inert atmosphere. Processing of single-phase cathode material in inert atmosphere yielded pure metallic cobalt, whereas, higher metallic recoveries and metal purity were obtained by processing of mixed cathode material in ambient conditions. The excellent product obtained under ambient conditions comprises 68% Co, 21% Mn, 2.5% Ni with saturation magnetization: 106 emu/g, and a precursor for the synthesis of cathode material. The process yield is 46.2% and lithium extraction 83%. In terms of metal purity and recovery, graphite was found to be better for reduction than activated charcoal. The process followed is simple, adaptable, and cost-effective for metals recovery from discarded lithium-ion batteries.
锂离子电池有限的寿命和巨大的需求、环境问题以及锂和钴等稀有金属的消耗是全球回收努力的关键因素。本研究采用回收石墨对废旧锂离子电池正极材料进行碳热还原。对比评价了单相(LiCoO2)和混合相(LiCoO2 . lini0.5 Mn1.5 O4 . limn2 O4)正极材料在环境气氛和惰性气氛下的还原行为。在惰性气氛中处理单相正极材料可获得纯金属钴,而在环境条件下处理混合正极材料可获得更高的金属回收率和金属纯度。在常温条件下获得的优异产品含有68% Co, 21% Mn, 2.5% Ni,饱和磁化强度为106 emu/g,是合成正极材料的前驱体。该工艺收率为46.2%,锂提取率为83%。在金属纯度和回收率方面,石墨被发现比活性炭更好的还原。接下来的过程简单,适应性强,从废弃的锂离子电池中回收金属具有成本效益。
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引用次数: 3
Influence of Nb2O5 and basicity on the viscosity and structure of CaO-SiO2-Nb2O5-CeO2-CaF2 slag system Nb2O5和碱度对CaO-SiO2-Nb2O5-CeO2-CaF2渣体系粘度和结构的影响
Pub Date : 2020-04-01 DOI: 10.1051/metal/2020023
Zhuang Ma, Zengwu Zhao, Wentao Guo, Z. Wang
In order to utilize niobium concentrate of Bayan Obo effectively, the effect of Nb2 O5 and basicity on the viscosity of CaO-SiO2 -Nb2 O5 -5.0 wt.% CeO2 -5.0 wt.% CaF2 slag system was studied from 1653 to 1813 K in reducing atmosphere by rotating cylinder method. For the same condition, the as-quenched samples were investigated through X-ray diffraction and Raman spectroscopy. The results show that the viscosity, break temperature and activation energy of viscous flow decrease with the increase of Nb2 O5 and basicity. Raman spectra show that the Nb4+ ions exist in the form of [NbO6 ] octahedron with different distortion and little [NbO4 ] tetrahedron in the slags. The Nb2 O5 addition and basicity lower the degree of polymerization, where the complex Si-O network is depolymerized into simple structural units.
为了有效利用巴彦鄂博铌精矿,研究了Nb2 - O5和碱度对CaO-SiO2 -Nb2 - O5 -5.0 wt粘度的影响。% CeO2 -5.0 wt。用旋转圆筒法研究了还原气氛中1653 ~ 1813 K的% CaF2渣体系。在相同的条件下,通过x射线衍射和拉曼光谱对淬火后的样品进行了研究。结果表明:黏性流动的粘度、断裂温度和活化能随着Nb2 O5浓度和碱度的增加而降低;拉曼光谱表明,Nb4+离子以不同畸变的[NbO6]八面体形式存在,而[NbO4]四面体在渣中存在较少。Nb2 O5的加入和碱度降低了聚合度,其中复杂的Si-O网络被解聚成简单的结构单元。
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引用次数: 4
Application of integral method for investigating the boriding kinetics of AISI 316 steel 应用积分法研究AISI 316钢渗硼动力学
Pub Date : 2020-02-01 DOI: 10.1051/metal/2020011
Chaima Zouzou, M. Keddam
The present work is dealing with the modelling of boriding kinetics of AISI 316 steel in the temperature range 1123–1273 K. A diffusion model based on the integral method was used in order to investigate the kinetics of formation of FeB and Fe2 B layers and that of diffusion zone formed on AISI 316 steel by considering the presence of boride incubation times. By using a particular solution of the resulting differential algebraic system, the diffusion coefficients in FeB, Fe2 B and diffusion zone (DZ) were estimated as well as the corresponding values of activation energies. Finally, this present diffusion model has been experimentally validated for two additional boriding conditions (1243 K for 3 and 5 h of treatment). A good concordance was observed between the experimental and the simulated results in terms of layers’ thicknesses.
本文研究了AISI 316钢在1123 ~ 1273 K温度范围内的渗硼动力学模型。采用基于积分法的扩散模型,研究了考虑硼化物孕育时间的AISI 316钢表面FeB和fe2b层形成动力学和扩散区形成动力学。利用所得到的微分代数系统的特解,估计了FeB、fe2b和扩散区(DZ)的扩散系数以及相应的活化能值。最后,该扩散模型在另外两种渗硼条件下(1243 K渗硼3 h和5 h)进行了实验验证。实验结果与模拟结果在层厚方面有很好的一致性。
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引用次数: 5
Enhancement of microstructure uniformity and grain refining efficiency of Al-5Ti-1B alloy via powder extrusion 粉末挤压提高Al-5Ti-1B合金组织均匀性和晶粒细化效率
Pub Date : 2020-01-01 DOI: 10.1051/metal/2020069
Shun-cheng Wang, Huilan Huang, Zhibo Zhang, K. Zheng
Microstructure uniformity and grain refining efficiency of Al-5Ti-1B alloy rod prepared by powder extruded process and continuous casting and rolling process are investigated in detail by X ray diffractometer, scanning electron microscope and electron probe. It is found that TiB2 and TiAl3 particles are uniformly distributed in the powder extruded Al-5Ti-1B alloy via gas atomization and hot extrusion process. The samples with 0.2% powder extruded Al-5Ti-1B alloy rod holding for 2 min consist of equiaxed grains with an average diameter of 183 µm. Even the holding time extended to 180 min, the average diameter is still stable (229 µm). Al-5Ti-1B alloy rod prepared by the powder extruded process presents better grain refinement and stronger resistance to grain coarsening.
采用X射线衍射仪、扫描电镜和电子探针对粉末挤压法和连铸连轧法制备的Al-5Ti-1B合金棒材的组织均匀性和晶粒细化效率进行了详细研究。通过气体雾化和热挤压法制备的Al-5Ti-1B粉末合金中,TiB2和TiAl3颗粒均匀分布。经0.2%粉末挤压的Al-5Ti-1B合金棒材保温2 min后,样品为平均直径为183µm的等轴晶粒。即使保温时间延长到180 min,平均直径仍然稳定(229µm)。粉末挤压法制备的Al-5Ti-1B合金棒具有较好的晶粒细化和较强的抗晶粒粗化能力。
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引用次数: 0
Physical and numerical modeling of liquid slag entrainment in mould during slabs casting 板坯连铸过程中结晶器液渣夹带的物理和数值模拟
Pub Date : 2020-01-01 DOI: 10.1051/metal/2020055
M. Bielnicki, J. Jowsa
The paper presents results of physical and numerical modeling of liquid slag entrainment during continuous casting of steel slabs process. The main aim of this work was to determine the critical casting speed and also to specify, which entrainment mechanism is most responsible for transport of slag droplets into steel volume. Physical modeling was based on water-oil model of mould, made on reduced linear scale of Sl  = 0.4. In mathematical modeling, Realizable k-e and LES WALE models were used to describe turbulent motion of water and oil, whereas Volume of Fluid model was used to take into account interactions between phases. It was found, that the main cause of slag entrainment is the formation of von Karman vortex in the vicinity of submerged entry nozzle. The results of laboratory experiments and numerical simulations were compared each other. Both method are a useful tools for modeling of slag entrainment. Great agreement was found between laboratory experiments and numerical simulation carried out using LES WALE model, regarding the shape of the oil and oil entrainment as a result of vortex structures formation. However, in the simulation case using Realizable k-e model, the oil entrainment hasn’t been modeled for the conditions under consideration.
本文介绍了钢坯连铸过程液渣夹带的物理和数值模拟结果。这项工作的主要目的是确定临界铸造速度,并确定哪种夹带机制是导致渣滴进入钢体的主要原因。物理建模以模具的水-油模型为基础,按Sl = 0.4的线性缩减比例制作。在数学建模中,采用Realizable k-e和LES WALE模型来描述水和油的湍流运动,而采用Volume of Fluid模型来考虑相之间的相互作用。研究发现,在水下入口喷口附近形成的冯·卡门涡是导致夹渣的主要原因。对室内实验结果和数值模拟结果进行了比较。这两种方法都是模拟夹渣过程的有效工具。利用LES WALE模型进行的数值模拟结果与室内实验结果非常吻合,关于油的形状和油的夹带是涡结构形成的结果。然而,在使用Realizable k-e模型的模拟案例中,并没有根据考虑的条件对携油量进行建模。
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引用次数: 2
Hot forming limit curves for numerical press hardening simulation of AISI 420C AISI 420C数值压硬化模拟的热成形极限曲线
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3667
B. Behrens, J. Uhe, H. Wester, E. Stockburger
A possible alternative to the established press hardening steel 22MnB5 are hot formed martensitic chromium steels. Both strength and ductility of the martensitic chromium steels can reach very high values with appropriate heat treatments. Therefore, car body parts with high crash safety can be produced by hot forming martensitic chromium steels. To identify the formability of a sheet metal, forming limit curves are state of the art. Conventional forming limit curves are recorded at room temperature and do not adequately describe the forming capacity for hot sheet metal forming as it strongly depends on temperature. Therefore, in this paper, an experimental-numerical method for determining quasi-isothermal FLC at high forming temperatures is applied to the martensitic chromium steel AISI 420C (X46Cr13) for forming temperatures between 7501,050 °C according to its process route. The results show an increase of the formability with rising forming temperature with the highest at 1,050 °C.
热成形马氏体铬钢是现有压硬化钢22MnB5的可能替代品。通过适当的热处理,马氏体铬钢的强度和延展性都可以达到很高的值。因此,采用热成形马氏体铬钢可以生产出具有高碰撞安全性的汽车车身零部件。为了确定板材的可成形性,成形极限曲线是目前最先进的。传统的成形极限曲线是在室温下记录的,并不能充分描述热板料成形的成形能力,因为它强烈地依赖于温度。因此,本文根据马氏体铬钢AISI 420C (X46Cr13)的工艺路线,采用实验-数值方法确定高成形温度下的准等温FLC。结果表明:随着成形温度的升高,成形性能有所提高,在1050℃时成形性能最高;
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引用次数: 7
THE INFLUENCE OF LASER PROCESSING ON MICROSTRUCTURE AND SELECTED PROPERTIES OF THE DIFFUSION BORONIZED LAYERS PRODUCED ON TOOL STEEL FOR METAL FORMING 激光加工对金属成形用工具钢扩散渗硼层组织和性能的影响
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3481
A. Bartkowska, P. Jurči, M. Hudáková, D. Bartkowski, D. Przestacki, M. Kusý, M. Kuřík
The paper presents the study results of microstructure, phase composition, microhardness and wear resistance of Vanadis-6 tool steel after diffusion boriding and laser processing. In this study the diode laser device was used. As a result of diffusion boriding the obtained surface layers were characterized by needlelike microstructure with good cohesion with the substrate but in the subsurface area delamination and porosity could be observed. Therefore the diffusion boronized layer was processed using laser heat treatment. As a result of influence of the laser beam, three zones were obtained. The remelted zone near the surface, next the heat affected zone and finally steel substrate were observed. The newly created microstructure in the remelted zone consisted of boron-martensite eutectic. Microhardness of boronized layer after laser processing in comparison to the one without laser processing was slightly lower and was approx. from 1300 HV0.1 to 1100 HV0.1. It was found that additional advantage of laser processing of boronized layers was the presence of heat affected zone. This led to obtaining a mild microhardness gradient between the surface and the substrate. The boronized layer after laser processing was characterized by higher wear resistance in comparison to one not subjected to this kind of processing.
本文介绍了钒6工具钢经扩散渗硼和激光加工后的显微组织、相组成、显微硬度和耐磨性的研究结果。本研究采用了二极管激光器件。扩散渗硼后得到的表层具有针状组织,与基体结合良好,但在次表层存在分层和孔隙现象。因此,采用激光热处理对扩散渗硼层进行了加工。由于激光束的影响,得到了三个区域。观察到靠近表面的重熔区,其次是热影响区,最后是钢基体。在重熔区新形成的组织由硼-马氏体共晶组成。激光处理后的渗硼层显微硬度略低于未经激光处理的渗硼层显微硬度。从1300 HV0.1到1100 HV0.1。发现激光加工渗硼层的另一个优点是热影响区的存在。这导致在表面和衬底之间获得温和的显微硬度梯度。激光处理后的渗硼层与未经激光处理的渗硼层相比,具有更高的耐磨性。
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引用次数: 0
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Revue De Metallurgie-cahiers D Informations Techniques
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