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MODELING of static recrystallization IN alloyed austenite with account of recovery 考虑恢复的IN合金奥氏体静态再结晶建模
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3511
A. Vasilyev, S. Sokolov, D. Sokolov, A. Zisman
To predict kinetics of static recrystallization with account of recovery and resulting grain size in alloyed austenite, a quantitative model is developed. Physically motivated, the model relates activation energy of the process with that of bulk self-diffusion. The known dependence of the latter on chemical composition of austenite solid solution, established previously, essentially simplifies the modeling. Employed empirical parameters have been fitted to relevant data covering a wide range of chemical compositions (12 steels) and sizes of recrystallized austenite grains. The model satisfactorily complies with experiments on steels whose apparent activation energy of recrystallization varies from 146.1 to 308.1 kJ/mol. It is notable as well that this performance has been achieved with no direct allowance for the pinning of grain boundaries by solute atoms (solute drag effect).
考虑到合金奥氏体的恢复和晶粒尺寸,为了预测静态再结晶动力学,建立了一个定量模型。基于物理动机,该模型将该过程的活化能与体自扩散活化能联系起来。已知的后者依赖于奥氏体固溶体的化学成分,先前建立的,本质上简化了建模。所采用的经验参数已拟合到涵盖广泛的化学成分(12种钢)和再结晶奥氏体晶粒尺寸的相关数据中。该模型与再结晶表观活化能在146.1 ~ 308.1 kJ/mol范围内的钢的实验结果吻合较好。值得注意的是,这种性能是在没有直接考虑溶质原子(溶质阻力效应)钉住晶界的情况下实现的。
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引用次数: 0
The importance of ore raw materials basicity in terms of their comprehensive quality evaluation 矿石原料碱度在其综合质量评价中的重要性
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3644
P. Besta, L. Luzar
Basicity is one of the key chemical criteria in evaluating the properties of ore raw materials. The alkaline character of the blast furnace charge affects the efficiency of the iron production process in the blast furnace. The basicity of the raw ore material also affects the cost of the process, which may require additional basic additives. However, raw ore materials can be evaluated according to a range of criteria, which may be physical, chemical, economic or technological in character. In each category, many other criteria can be identified. Metallurgical companies have long endured problems in selecting suitable raw ore types and other input sources. Complications generally arise because of the wide spectrum of criteria, but also their varying character, which is difficult to uniformly assess. The range of criteria can be evaluated in categorically different units, which is then difficult to compare at an overall level. The significance and influence of basicity in relation to other key criteria in assessing ores was experimentally assessed in this research. The overall quality of the selected ores was also assessed under this task. Ore quality was analysed according to key criteria, which vary in character. Research was conducted at the company TŘINECKÉ ŽELEZÁRNY, a.s. The article discusses the results of research on the significance of basicity in the assessment criteria structure for ores and demonstrates the possibility of assessing ores using mathematical tools.
碱度是评价矿石原料性质的重要化学指标之一。高炉炉料的碱性影响着高炉铁生产过程的效率。原料的碱度也影响工艺的成本,这可能需要额外的碱性添加剂。然而,原材料可以根据一系列标准进行评估,这些标准可能是物理的、化学的、经济的或技术的。在每个类别中,可以确定许多其他标准。长期以来,冶金公司在选择合适的原矿类型和其他投入来源方面一直存在问题。并发症的出现通常是因为标准范围广,但也有不同的特点,这是很难统一评估。标准的范围可以用不同的分类单位来评估,这样就很难在整体水平上进行比较。本文通过实验研究,探讨了碱度与其他关键指标在矿石评价中的重要性和影响。在此任务下,还对选定矿石的整体质量进行了评估。根据不同性质的关键标准对矿石质量进行了分析。研究是在TŘINECKÉ ŽELEZÁRNY, a.s.公司进行的。文章讨论了碱度在矿石评价标准结构中的重要性的研究结果,并论证了使用数学工具评价矿石的可能性。
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引用次数: 0
INFLUENCE OF MODIFICATION ON MICROSTRUCTURE DEGRADATION OF AlSi12 ALLOY EXPOSED TO THE CORROSION ENVIRONMENT 改性对腐蚀环境下AlSi12合金组织退化的影响
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3596
Franjo Kozina, Zdenka Zovko Brodarac
The corrosion resistance of aluminum-silicon (Al-Si) foundry alloys is a result of microstructure development influenced by melt treatment and solidification. As a part of the main eutectic (αAl + βSi), βSi particles are cathodic with respect to the αAl matrix enabling micro-galvanic couple formation and localized corrosion. Despite its high polarization and low current density, increase in the eutectic (αAl + βSi) will contribute to the microstructure degradation of an alloy in corrosive environment. The research was performed in order to estimate the influence of eutectic βSi particles size on the microstructure degradation of AlSi12 alloy with mixed morphology of eutectic (αAl + βSi). The results of light microscopy indicated preferred initiation and progress of cavities involving modified eutectic (αAl + βSi) with eutectic βSi particles of smaller average particle size. The unmodified eutectic (αAl + βSi) with lamellar morphology and dendrites of primary αAl phase were not visually affected by degradation. The average cavity size and pH value of the solution increase with the increasing exposure time, while microstructure degradation rate decreases.
铝硅铸造合金的耐蚀性是受熔体处理和凝固影响的组织发展的结果。作为主共晶(αAl + βSi)的一部分,βSi颗粒相对于αAl基体呈阴极,有利于微电偶的形成和局部腐蚀。尽管合金具有高极化和低电流密度,但共晶(αAl + βSi)的增加会导致合金在腐蚀环境中的组织退化。研究共晶βSi颗粒尺寸对混合共晶(αAl + βSi) AlSi12合金显微组织退化的影响。光镜观察结果表明,共晶βSi颗粒平均粒径较小,改性共晶αAl + βSi有利于空腔的萌生和发展。未改性共晶(αAl + βSi)的片层形貌和初生αAl相枝晶不受降解的明显影响。随着暴露时间的延长,溶液的平均空腔尺寸和pH值增加,微观结构降解速率降低。
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引用次数: 0
Influence of quasi-continuous ECAP with various channel intersection angles on the structure formation, mechanical and functional properties of Ti-Ni shape memory alloys 不同通道交会角准连续ECAP对Ti-Ni形状记忆合金结构形成、力学和功能性能的影响
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3624
R. Karelin, I. Khmelevskaya, V. Komarov, V. Andreev, M. Perkas, V. Yusupov, S. Prokoshkin
Influence of quasi-continuous ECAP with channel intersection angles of 110 and 120° on the structure formation and properties of Ti-50.1 at% Ni shape memory alloy was studied and compared. The structure was studied using X-ray diffraction analyses and transmission electron microscopy. The mechanical properties were determined by the uniaxial tensile and hardness tests. The maximum completely recoverable strain and temperatures of reverse martensitic transformation were estimated by a thermomechanical method using a bending mode for strain inducing. After ECAP with channel intersection angle of 120° for 3 passes at 400 °C a mixed ultrafine-grained structure with high density of free dislocations and incompletely equiaxed structural elements size of about 130-150 nm is formed. In comparison, after ECAP with channel intersection angle of 110° an ultrafine-grained structure with deformation bands elongated in the direction perpendicular to the sample axis, consisting of the less uniform equiaxed and ellipsoid structural elements with the size of about 50-150 nm is obtained. After both studied ECAP regimes samples have relatively high values of hardness (220 HV) and strength characteristics (σy = 850/1000 MPa, σB = 1040/1020 MPa, 120/110°). Maximum completely recoverable strain of 7.1 % is obtained after ECAP with channel intersection angle of 110°, and post-deformation annealing at 400 °C, 1 h.
研究并比较了通道交角为110°和120°的准连续ECAP对Ti-50.1 at% Ni形状记忆合金结构形成和性能的影响。用x射线衍射分析和透射电镜对其结构进行了研究。通过单轴拉伸和硬度试验确定了材料的力学性能。采用弯曲应变诱导的热力学方法,估计了反马氏体相变的最大完全可恢复应变和温度。在400℃条件下,通道交角为120°的ECAP经过3道后,形成了具有高密度自由位错和尺寸约为130 ~ 150 nm的不完全等轴结构元的混合超细晶结构。相比而言,通道交角为110°的ECAP后,得到的变形带在垂直于试样轴线方向上伸长的超细晶结构,由尺寸约为50 ~ 150 nm的不均匀等轴和椭球结构单元组成。经过两种ECAP处理后,样品具有较高的硬度值(220 HV)和强度特征(σy = 850/1000 MPa, σB = 1040/1020 MPa, 120/110°)。通道交角为110°的ECAP,变形后在400℃,1 h下退火,可获得最大的完全恢复应变,为7.1%。
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引用次数: 0
In-situ synthesis Ni-Ti alloy by laser cladding 激光熔覆原位合成ni -钛合金
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3519
S. Igoshin, D. Masaylo, A. Kim, A. Popovich
The NiTi alloy shape memory effect can have a much larger field of application in industry and everyday life than it is now. The high cost of obtaining this material and the laboriousness of the process limit its scope of application. The use of modern 3D technology may help solve this problem This paper explores the possibility of growing samples of simple geometric shapes in the form of tubes from Ni and Ti elemental powders. Samples from 3 types of powder mixtures have been produced. The first mixture with an excess of Ni relative to the equatorial ratio, the second with a deficit of Ni, the third with 5 % addition of Cu. The microstructure of samples before and after thermal treatment in argon at 900 ̊C was studied. The heat treatment contributed the process of homogenization of the solid solution, but had no significant effect on the sample hardness or reduction of secondary phases. Heat treatment changed hardness by an average of 10%. Phase analysis before and after the heat treatment showed a significant proportion of NiTi phase as well as secondary phases of NiTi2, Ni3Ti, TiO2.
NiTi合金的形状记忆效应在工业和日常生活中的应用领域将比现在大得多。这种材料的高成本和加工过程的费力限制了它的应用范围。使用现代3D技术可能有助于解决这一问题。本文探讨了从Ni和Ti元素粉末中生长出简单几何形状的管状样品的可能性。已经生产了3种粉末混合物的样品。第一种混合物中相对于赤道比有过量的镍,第二种混合物中有不足的镍,第三种混合物中有5%的Cu。研究了900℃氩气热处理前后试样的显微组织。热处理促进了固溶体的均匀化过程,但对样品硬度和二次相的减少没有显著影响。热处理使硬度平均变化10%。热处理前后的物相分析表明,NiTi相和NiTi2、Ni3Ti、TiO2的二次相比例显著。
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引用次数: 1
IMPROVEMENT OF STEEL SHEETS’ CORROSION RESISTANCE BY APPLICATION OF NEW GENERATION COATINGS 应用新一代涂料提高钢板的耐蚀性
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3546
E. Evin, M. Tomáš, J. Kepič
Besides customers and environmental requirements such as safety increase, the weight and emission reduction, and the life-time improvement, huge role plays corrosion resistance of the car-body components. This is improved by applying Zn-based coatings on the steel sheets. In the article are presented results of corrosion tests performed on the steel sheets with Zn-Al-Mg coatings applied. These are compared to the standard Zn coating. Samples were deformed by Erichsen stretching test and by 3-point bending tests to the angle of 90° and 180°. After that, these were exposed to salt spray in the corrosion chamber. The limit criteria were time to red corrosion appearance and percentage of corroded surface evaluated on time. The results showed the small amount of Al and Mg improved the corrosion resistance of Zn-Al-Mg coatings when compared to the conventional Zn coating.
除了提高安全性、减轻重量和减少排放、提高使用寿命等客户和环境要求外,车身零部件的耐腐蚀性也起着巨大的作用。这可以通过在钢板上涂上锌基涂层来改善。本文介绍了用锌铝镁涂层对钢板进行腐蚀试验的结果。这些都是比较标准锌涂层。试样进行Erichsen拉伸试验和三点弯曲试验,弯曲角度分别为90°和180°。之后,这些被暴露在腐蚀室的盐雾中。极限标准为红色腐蚀出现的时间和腐蚀表面的百分比。结果表明,与常规Zn镀层相比,少量Al和Mg的加入提高了Zn-Al-Mg镀层的耐蚀性。
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引用次数: 1
Resistance spot weldability of TBF steel sheets with dissimilar thickness 不同厚度TBF钢板的电阻点焊性
Pub Date : 2020-01-01 DOI: 10.1051/metal/2020071
Imren Ozturk Yilmaz, Abdullah Yasin Bilici, H. Aydın
This paper presents an experimental study on weldability of TBF steel sheets with dissimilar thickness. Nominal thickness of TBF sheets were 0.95 and 1.55 mm. Optical microscope was used to observe the cracks formed in the weld zone. The indentation depths were determined by ultrasonic technique. Tensile shear tests were applied to the welded specimens in order to determine the mechanical properties. Higher weld current and time resulted in higher nugget size and indentation depth. This increase in nugget size and indentation depth with increasing of weld current and weld time was almost linearly. The liquid metal embrittlement crack sensitivity in the HAZ was very high on TBF spot welds. The liquid metal embrittlement cracks were much deeper and wider along the weld periphery regions compared to the nugget regions. These cracks were occurred easily with a higher heat input and the crack depth increased almost linearly with increasing of heat input. Weld strength of the specimens was governed by crack formation in the HAZ. Lower weld currents and weld times resulted in higher tensile shear properties. The highest tensile shear load (18.50 kN) and energy absorption (37.5 J) were achieved at 6 kA for 20 cycles. This weld exhibited interfacial failure mode.
本文对不同厚度TBF钢板的可焊性进行了试验研究。TBF板的公称厚度分别为0.95和1.55毫米。用光学显微镜观察焊接区形成的裂纹。采用超声技术测定压痕深度。为了确定焊接试样的力学性能,对焊接试样进行了拉伸剪切试验。焊接电流和时间越长,熔核尺寸越大,压痕深度越大。熔核尺寸和压痕深度随焊接电流和焊接时间的增加几乎呈线性增长。热影响区液态金属脆化裂纹对TBF点焊具有很高的敏感性。与熔核区相比,焊缝外围区液态金属脆化裂纹更深、更宽。热输入越大,裂纹越容易产生,裂纹深度随热输入的增加几乎呈线性增加。试样的焊接强度受热影响区裂纹形成的影响。较低的焊接电流和焊接时间导致较高的拉伸剪切性能。在6 kA、20次循环下,获得了最高的拉伸剪切载荷(18.50 kN)和能量吸收(37.5 J)。焊缝呈现界面破坏模式。
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引用次数: 3
Effect of holding time at stabilization annealing on properties of 08CH18N10T austenitic stainless steel 稳定化退火保温时间对08CH18N10T奥氏体不锈钢性能的影响
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3498
H. Jirková, T. Janda, J. Růžička, J. Mach, J. Volkmannová
Titanium-stabilized austenitic stainless steel 08Ch18N10T is often used in nuclear power facilities due to its favourable properties. Many parts of the primary circuit of VVER 440 and VVER 1000-type nuclear power plants are manufactured of this steel. This means that the material must possess very good corrosion resistance and thermal stability of structure. Yield strength of at least 177 MPa at 350 °C is required. Heat treatment of this steel comprises several important stages which affect the resulting mechanical properties. In particular, the solution and stabilization annealing after forging or rolling are time and energy consuming. Therefore, various ways to optimize these processes are being sought. A combination of solution annealing at 1020 °C for 15 and 30 minutes and stabilization annealing at 720 °C with dwell of 2.5 hours to 15 hours was tested on 08Ch18N10 steel samples. The aim was to establish the effects of stabilization annealing and solution annealing times on mechanical properties. Longer solution annealing has a pronounced effect on the reduction of scatter in mechanical properties. All annealing routes led to yield strengths at 350 °C higher than 200 MPa and tensile strengths of more than 380 MPa.
钛稳定奥氏体不锈钢08Ch18N10T由于其良好的性能,常用于核电设施。VVER 440型和VVER 1000型核电站一次回路的许多部件都是用这种钢制造的。这意味着材料必须具有非常好的耐腐蚀性和结构的热稳定性。350°C时的屈服强度至少为177 MPa。这种钢的热处理包括几个影响最终机械性能的重要阶段。特别是锻造或轧制后的固溶和稳定化退火是费时耗力的。因此,人们正在寻求各种方法来优化这些过程。对08Ch18N10钢样品进行了1020℃溶液退火15 ~ 30分钟和720℃稳定化退火2.5 ~ 15小时的试验。目的是确定稳定化退火和固溶退火时间对力学性能的影响。长时间固溶退火对降低材料力学性能的散射有显著的效果。所有退火路线均使材料在350℃时的屈服强度大于200 MPa,抗拉强度大于380 MPa。
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引用次数: 2
DEVELOPMENT OF TECHNICAL SOLUTIONS FOR PREVENTING DISCHARGE OF LIQUID TECHNOGENIC WASTE AT ENTERPRISES USING SURVIVAL PROCESSING PROCESSES 开发企业生存处理工艺防止工艺废水排放的技术解决方案
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3589
A. Kolesnikov, T. V. Davydkova
In the course of the work, a resource-saving version of the work of all basic elements was developed. The developed technological scheme will allow wastewater to be treated to modern maximum permissible concentrations (MPC) standards due to the highly efficient removal of heavy and non-ferrous metals and organic impurities, which can significantly reduce the cost of water supply to the enterprise.
在工作过程中,形成了资源节约型的各项基本要素工作。开发的技术方案将允许将废水处理到现代最大允许浓度(MPC)标准,因为它可以高效地去除重金属和有色金属以及有机杂质,这可以显着降低企业的供水成本。
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引用次数: 0
Research on flow rate engineering calculation model of U-pipes for fabricating transverse variable profiled (TVP) strips by simulation and experiment 通过仿真和实验研究了制造横向变型带用u型管的流量工程计算模型
Pub Date : 2020-01-01 DOI: 10.1051/metal/2020057
Ce Ji, Hua-gui Huang, Yifeng Sun, C. Zhang, G. Lin, Zhang Shangbin
Transverse variable profiled (TVP) strips have significant lightweight and functional characteristics due to the nonuniform section, but need to be cooled nonuniformly in order to obtain the uniform microstructure and performance. Hence, it has become the consensus of the industry to develop new on-line cooling equipment that can adjust and control the cooling capacity along the width direction (WD). Therefore, a multi-functional test platform was designed based on the U-pipes used in the industrial runout table cooling process. A steady-state Computational Fluid Dynamics (CFD) model was built based on the Fluent software, and the influence of the main pipe inlet pressure, U-pipe inner diameter, restrictor ring thickness, and restrictor ring inner diameter was analyzed. The results indicate that the flow rate increases as the U-pipe inner diameter increase when there is no restrictor ring, and the result is contrary when there is a restrictor ring. The influence of main pipe inlet pressure, restrictor ring thickness, and restrictor ring inner diameter on the flow rate is monotonic. Besides, the restrictor ring inner diameter has a wide flow rate adjusting range and has little impact on the equipment structure, which helps to reduce the reconstruction cost. Finally, considering the influence of geometric parameters, the flow rate engineering calculation models of the U-pipe were derived and verified, which lays the theoretical foundation to customize the flow rate distribution along the WD at the design stage.
横向变型带材由于截面不均匀,具有显著的轻量化和功能性,但为了获得均匀的组织和性能,需要进行不均匀冷却。因此,开发能够沿宽度方向调节和控制制冷量的新型在线冷却设备已成为业界的共识。为此,针对工业跳动台冷却过程中使用的u型管,设计了多功能测试平台。基于Fluent软件建立了稳态计算流体动力学(CFD)模型,分析了主管道进口压力、u型管内径、节流环厚度、节流环内径等因素的影响。结果表明:无节流环时,流量随节流环内径的增大而增大,有节流环时,流量随节流环内径的增大而增大;总管进口压力、节流环厚度和节流环内径对流量的影响是单调的。此外,节流环内径调节流量范围宽,对设备结构影响小,有助于降低改造成本。最后,考虑几何参数的影响,推导并验证了u型管的流量工程计算模型,为在设计阶段定制随钻方向的流量分布奠定了理论基础。
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引用次数: 0
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Revue De Metallurgie-cahiers D Informations Techniques
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