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CRACKs FORMATION IN Nickel-based single crystal alloy manufactured by SELECTIVE LASER MELTING 选择性激光熔化制备镍基单晶合金裂纹的形成
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3625
E. Borisov, K. Starikov, A. Popovich, V. Popovich
The aim of this study was to determine the influence of selective laser melting (SLM) process parameters on the formation of cracks in nickel-based single crystal alloy. Several sets of laser scanning parameters, with varied laser power, scanning speed and hatch distance, thus resulting in different volumetric and linear energy densities, were investigated. The relationship between energy density, specimen densification, cracks formation and evolution of directional microstructure was shown. It was found that higher linear energy density results in fewer cracking and defects. Cracking in lower energy samples was attributed to the formation of thermal shrinkage pores in the interdendritic spaces and precipitation of Ta, Mo and Nb carbides along the dendrites boundaries.
本研究旨在确定选择性激光熔化(SLM)工艺参数对镍基单晶合金裂纹形成的影响。研究了不同激光功率、扫描速度和舱口距离对不同体积和线性能量密度的影响。揭示了能量密度、试样致密化、裂纹形成与定向组织演化之间的关系。结果表明,线能量密度越高,裂纹和缺陷越少。低能试样的开裂主要是由于在枝晶间隙形成热收缩孔和沿枝晶边界析出Ta、Mo和Nb碳化物所致。
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引用次数: 2
Effect of the weir structure in the tundish on the cleanliness of IF steels and elimination of spot-like defects in deep drawing automobile steel sheets 中间包堰组织对中频钢洁净度及汽车钢板深拉深缺陷消除的影响
Pub Date : 2020-01-01 DOI: 10.1051/metal/2020061
Xiaoxuan Deng, Guoliang Liu, Qiangqiang Wang, Baisong Liu, C. Ji, Haibo Li, Xiao-jing Shao, Guo-sen Zhu
The flow control devices (FCDs) in the tundish play an important role in steel cleanliness and removal of macro-inclusions. To eliminate the spot-like defects during deep-drawing process, the liquid steel samples were taken from tundish in three industrial IF steel heats, and the effect of weir structure in the tundish on the steel cleanliness were evaluated and compared with the aid of ASPEX with the total detection area of over 54 000 mm2 . The results showed that non-metallic inclusions over 5 µm observed in the liquid tundish samples were categorized into two types: type 1: alumina based inclusions and type 2: calcium aluminates. Compared to the tundish without weir, the number density of macro-inclusions reduces by half when furnished with weir. In addition, several large sized calcium aluminates were occasionally found without weir whereas no calcium aluminates were detected with the weir. The mechanism of the inclusion distributions with the weir was proposed based on the experimental results, which shows that the weir act as a baffle that block the large sized inclusions from moving toward the mould. After using the weir in the actual casting practice, the occurrence ratio of spot-like defects was decreased by about 25%.
中间包内的流动控制装置(FCDs)对钢的清洁度和宏观夹杂物的去除起着重要的作用。为了消除拉深过程中出现的点状缺陷,在三次中碳钢工业加热中提取了中间包的钢液样品,并借助于ASPEX对中间包的围护结构对钢材清洁度的影响进行了评价和比较,总检测面积超过54000 mm2。结果表明,中间包液样品中大于5µm的非金属夹杂物可分为两类:一类为氧化铝基夹杂物,二类为铝酸钙夹杂物。与未加堰的中间包相比,有堰的中间包中宏观夹杂物的数量密度降低了一半。此外,偶尔发现一些大尺寸的铝酸钙没有堰,而没有堰检测到铝酸钙。根据实验结果,提出了夹杂物随堰的分布机理,表明堰起到了阻挡大尺寸夹杂物向模具移动的挡板作用。在实际铸造中使用后,点状缺陷的发生率降低了25%左右。
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引用次数: 3
THERMAL ANNEALING OF WWER – 440 NUCLEAR REACTOR PRESSURE VESSEL INTERNALS MATERIAL wwer - 440型核反应堆压力容器内部材料的热退火
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3497
Ivana Schnablová, R. Kopřiva, Ondřej Buršík, K. Rusňáková, A. Materna
Current trend of long-term operation of NPP’s for more than 60 years requires assurance of its safety and reliability. One of the solutions how to extend service life of reactor pressure vessel (RPV) is thermal annealing, which became a verified technology and its application in nuclear industry was prompted mainly due to an inability of RPV exchange. At present time, there is no comparable method for RPV internals that are not monitored by surveillance program and their material is exposed to significantly more intense neutron flux than the RPV. Paper presents the thermal annealing as one of the possible solutions to provide and re-establish sufficient mechanical properties of RPV internals during the operation. According to previously obtained results of unirradiated material, two thermal annealing regimes for irradiated experimental material were selected based on the annealing temperatures of 550 and 600 °C. The possibility of recovery of mechanical properties to the level almost corresponding to the initial state by the thermal annealing was studied by hardness testing and static fracture toughness tests before and after the thermal annealing of irradiated material.
核电站长期运行超过60年的趋势要求保证其安全性和可靠性。延长反应堆压力容器(RPV)使用寿命的解决方案之一是热退火技术,该技术已得到验证,其在核工业中的应用主要是由于RPV无法交换。目前,对于不受监测程序监测的RPV内部,没有可比较的方法,它们的材料暴露在比RPV更强的中子通量中。本文提出了热退火作为一种可能的解决方案,以提供和重新建立足够的机械性能的RPV内部在操作过程中。根据已有的未辐照材料的结果,选择了两种退火方案,退火温度分别为550℃和600℃。通过对辐照材料进行热处理前后的硬度测试和静态断裂韧性测试,研究了热处理使材料的力学性能恢复到几乎与初始状态相对应的水平的可能性。
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引用次数: 0
QUality CONTROL BASE ON surface roughness CHARACTERISTIC – OXIDE layer on PURE titanium 基于表面粗糙度特征的质量控制-纯钛表面氧化层
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3659
D. Klimecka-Tatar
Titanium, invariably for decades, is the most promising metallic material used in medicine (implantology). And its suitability is primarily determined by biotolerance, which depends on the preparation of the surface of the elements. This paper assesses the quality control of oxide layers produced on pure (medical) titanium in the process of thermal oxidation in an air atmosphere. The parameters characterizing surface roughness have been used as control parameters. It was noted that the titanium surface undergoes a slight change with short oxidation times, and the oxidation is relatively even in nature. However, with longer oxidation times (more than 45 minutes) roughness parameters change drastically, which is not always beneficial from the point of view of further use.
几十年来,钛一直是医学(种植学)中最有前途的金属材料。其适用性主要由生物耐受性决定,而生物耐受性又取决于元素表面的制备。本文对纯钛(医用钛)在空气中热氧化过程中产生的氧化层的质量控制进行了评价。采用表征表面粗糙度的参数作为控制参数。结果表明,氧化时间短,钛表面变化不大,氧化性质相对均匀。然而,随着氧化时间的延长(超过45分钟),粗糙度参数急剧变化,从进一步使用的角度来看,这并不总是有益的。
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引用次数: 2
STUDY OF AUSTEMPERED DUCTILE CAST IRON ENRICHED BY PARTICULAR RATIO OF Nickel, mOLYBDENUM AND COPPER 特定富集镍、钼、铜比例的等温球墨铸铁的研究
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3444
R. Bendikiene, A. Ciuplys, R. Česnavičius, V. Grigas, A. Jutas, A. Bahdanovich, D. N. Marmysh, A. Nasan, Liudmila Shemet, S. Sherbakov
This research paper combines investigation of mechanical properties of austempered ductile cast iron (ADI) and comparison with standard grades of steel and cast iron. Due to the special features of both materials – catsability from cast iron, and toughness from steel, ADI attracts an attention of industry and science because of economic benefits and high performance at the different application areas. Austempered ductile iron was tested on tension where unconventional behaviour was observed: with the increase of tensile strength almost to 1600 MPa the metal became less brittle. Hardness test revealed absence of linear relation between strength and hardness, different hardness values ~ 40 HRC or ~ 55 HRC can be reached with the same tensile strength 1000 – 1200 MPa. After successful tensile tests the main direction of further studies was solving relevant practical wear and fatigue problems in rail-wheel system. The complex practical studies demonstrated that ADI is consistent with heat treated steels including the rail steels: required tensile strength of rail steel ranges from 1180 MPa to 1280 MPa when rolling surface hardness is expected to be in the range of 38 HRC – 44 HRC, whereas tensile strength of ADI was higher, up to 1400 MPa, and hardness slightly higher than of steel, 50 HRC. Herewith the workability of frictional couple cast iron/steel 20MnCr5G exceeded work performance of steel/steel system by 14 %. Specific properties emerged from successful ratio of three elements Mo, Ni, and Cu, and properly chosen austenitization schedule.
本研究论文结合了对等温球墨铸铁(ADI)力学性能的研究,并与标准牌号钢和铸铁进行了比较。由于这两种材料的特点——铸铁的可溶性和钢的韧性,ADI因其在不同应用领域的经济效益和高性能而受到工业界和科学界的关注。对奥氏体球墨铸铁进行了拉伸测试,观察到不同寻常的行为:随着拉伸强度的增加,几乎达到1600兆帕,金属变得不那么脆了。硬度试验表明,强度与硬度之间不存在线性关系,相同抗拉强度1000 ~ 1200mpa时,硬度值可达~ 40hrc或~ 55hrc。在成功的拉伸试验后,进一步研究的主要方向是解决轨道-车轮系统的相关实际磨损和疲劳问题。复杂的实际研究表明,ADI与包括钢轨钢在内的热处理钢一致:钢轨钢的抗拉强度要求在1180 MPa ~ 1280 MPa之间,轧制表面硬度在38 HRC ~ 44 HRC之间,而ADI的抗拉强度更高,可达1400 MPa,硬度略高于钢的50 HRC。其中,20MnCr5G摩擦偶铸铁/钢的可加工性比钢/钢体系的工作性能高出14%。Mo、Ni、Cu三种元素配比的成功和奥氏体化工艺的合理选择产生了特定的性能。
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引用次数: 1
Study on the transformation and microstructure evolution during hot-charging rolling process of a weathering steel 某耐候钢热装轧制过程相变及组织演变研究
Pub Date : 2020-01-01 DOI: 10.1051/metal/2020027
Man Liu, Guang Xu, Guanghui Chen, Zhoutou Wang
The effect of hot-charging temperature (HCT) on the transformation and microstructure evolution of a weathering steel was investigated by metallography and dilatometry. The results show that the microstructure consisted of ferrite and pearlite in all specimens when the HCT was between 500 ∼ 850 °C. The difference was that pearlite amount increased obviously at 750 °C, which is detrimental to the plasticity of steels. The reason for more pearlite is that ferrite and austenite coexisted at 750 °C, which belongs to the dual-phase region temperature. The reversed transformation of ferrite to austenite happened and the pre-existing austenite became coarse during the secondary austenization. The carbon content in fine reversed austenite was relatively low, while the coarse austenite contained higher carbon content, which decomposed into blocky pearlite in the final cooling process. Therefore, to obtain the desirable ferrite phase, the HCT of about 750 °C should be avoided. The results provide theoretical reference for optimizing hot-charging rolling process parameters.
采用金相和膨胀法研究了热装温度对耐候钢相变和组织演化的影响。结果表明:当高温温度在500 ~ 850℃之间时,所有试样的显微组织均由铁素体和珠光体组成;不同的是,在750℃时珠光体数量明显增加,不利于钢的塑性。珠光体较多的原因是在750℃时铁素体和奥氏体共存,属于双相区温度。在二次奥氏体化过程中发生了铁素体向奥氏体的反向转变,原有的奥氏体变粗。细反转奥氏体含碳量相对较低,粗反转奥氏体含碳量较高,在最终冷却过程中分解为块状珠光体。因此,为了获得理想的铁素体相,应避免750℃左右的高温高温。研究结果为优化热装轧制工艺参数提供了理论参考。
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引用次数: 0
Enhancement of the productivity of non-recovery stamp charge coke oven plant at JSPL Raigarh 提高拉加尔JSPL非回收印花焦炉装置生产效率
Pub Date : 2020-01-01 DOI: 10.1051/metal/2020074
Rupak Ranjan, H. P. Tiwari, P. Srivastava, M. S. Raghuwanshi, A. K. Jaiswal, M. Borkar
In recent past, Jindal Steel & Power Limited, Raigarh unit, has increased the hot metal production capacity by the renovation of the existing blast furnaces. Therefore, the blast furnace coke demand has increased. This excess demand for metallurgical coke production from the existing non-recovery stamp charge coke oven plant was a very tough challenge, because the coke oven plant was already running at rated production capacity. Therefore, to fulfill the requirement of excess coke and to deliver more value to the customers, several initiatives have been taken by the Coke Oven and Technical Services Department within the existing setup. Few approaches had been adopted to increase the productivity of coke by ∼20% without deteriorating the resultant coke quality. This paper describes in details the steps taken to enhance the productivity of non-recovery stamp charge coke oven plant.
在最近的过去,金达尔钢铁和电力有限公司,Raigarh单位,通过改造现有的高炉,增加了铁水生产能力。因此,高炉焦炭的需求量有所增加。现有的非回收印花焦炉装置对冶金焦生产的过剩需求是一个非常严峻的挑战,因为焦炉装置已经在额定生产能力下运行。因此,为了满足多余焦炭的需求,并为客户提供更多的价值,焦炉和技术服务部在现有的设置下采取了一些措施。很少有方法可以在不降低焦炭质量的情况下将焦炭的生产效率提高~ 20%。本文详细介绍了提高非回收印花焦炉生产效率所采取的措施。
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引用次数: 0
Evolution of microstructure, texture and inhibitor of medium temperature grain-oriented silicon steel 中温晶粒取向硅钢组织、织构及抑制剂的演变
Pub Date : 2020-01-01 DOI: 10.1051/metal/2020050
Fan Lifeng, Xingyuan Zhao, Li-jun Xiao, Jiao Huang, Y. Zhang
The medium temperature reheating and two-stage cold rolling process were adopted to produce industrialized Grain-oriented silicon steel. Results showed there were three sections (surface layer, transition layer and central layer) along the thickness direction on hot rolled sheets. Surface layer was occupied by complete recrystallization grains with average grain size 42.81 µm, while the central layer mainly consisted of fibrous microstructure. The Goss texture appeared only on surface layer with content 3.44%∼3.65%. After the first cold rolling with 72% reduction and decarburization annealing, the primary recrystallization occurred and average grains size reached 19.0 µm, simultaneously accompanied with texture rotated to λ, γ fiber texture and Goss texture dropped to 2.89%. Adopting the second cold rolling with 58% reduction, the cold rolled sheet consisted of deformed fiber microstructure and the texture maintained γ fiber texture with a peak at {111} . The precipitates in hot rolled sheets comprised Cu2 S and few AlN, and the average particle size was ∼14 nm. The inhibitors in the decarburization annealing sheet were mainly AlN, Cu2 S, MnS and their composite precipitation, which were spherical or massive with the average particle size ∼21 nm. The single Goss oriented grains with average grain size 9.41 mm were obtained after high temperature annealing, and the intensity reached 873.30. The final magnetic properties were: B8  = 1.865 T and P1.7/50  = 1.124 W/kg, which met the requirement of 27Q120.
采用中温再加热和两段冷轧工艺生产工业化晶粒取向硅钢。结果表明:热轧薄板沿厚度方向存在表面层、过渡层和中心层三个断面;表层为完全再结晶晶粒,平均晶粒尺寸为42.81µm,中间层主要为纤维组织。高斯织构只出现在表层,含量为3.44% ~ 3.65%。经72%还原和脱碳退火后的第一次冷轧发生了一次再结晶,平均晶粒尺寸达到19.0µm,同时织构旋转为λ, γ纤维织构和高斯织构下降到2.89%。冷轧钢板采用第二次冷轧,还原率为58%,冷轧钢板由变形纤维组织组成,织构保持γ纤维织构,织构峰值在{111}处。热轧薄板析出相主要由Cu2 S和少量AlN组成,平均粒径为~ 14 nm。脱碳退火片中的抑制剂主要是AlN、Cu2 S、MnS及其复合析出物,它们呈球状或块状,平均粒径为~ 21 nm。经高温退火后,得到平均晶粒尺寸为9.41 mm的单一Goss取向晶粒,晶粒强度达到873.30。最终磁性能为:B8 = 1.865 T, P1.7/50 = 1.124 W/kg,满足27Q120的要求。
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引用次数: 0
THE APPLICATION OF ENA FOR COMPARISON OF PROTECTIVE PERFORMANCE OF ZRP MODIFIED BY COMBINATION OF Zn DUST WITH ALUMINIUM OR CARBON TYPE FILLERS 摘要应用ENA对锌粉与铝、碳型填料复合改性ZRP的防护性能进行了比较
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3543
B. Eremiáš, L. Mindos, L. Turek
The possible effects on the protective performance of ZRP modified by combination of Zn dust with aluminium or carbon type fillers were investigated using electrochemical noise analysis (ENA). The role of different oxygen diffusion characteristics (identified on tested coating systems with ENA) on delamination tendency was tested during 168 hrs immersion tests in 0.05 M NaCl. It was shown the protective performance of tested type of coating systems can be changing with immersion time rather differently in relation to different ability of polymer matrix with the Zn/Al or Zn/C particles combination for oxygen transport to the coating/steel interface.
利用电化学噪声分析(ENA)研究了锌粉与铝或碳型填料复合改性ZRP对其防护性能可能产生的影响。在0.05 M NaCl中浸泡168小时,测试了不同的氧扩散特性(在测试的ENA涂层体系中确定)对分层倾向的影响。结果表明,不同类型的聚合物基体与Zn/Al或Zn/C颗粒组合向涂层/钢界面输送氧的能力不同,其防护性能随浸泡时间的变化有较大差异。
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引用次数: 1
ON THE METAHEURISTIC OPTIMIZATION ALGORITHMS IN THE STRUGGLE FOR THE HOT FLOW CURVE APPROXIMATION ACCURACY 热流曲线近似精度斗争中的元启发式优化算法
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3466
P. Opěla, I. Schindler, S. Rusz, V. Ševčák, I. Mamuzic
A hot flow curve approximation performed via flow stress models as well as artificial neural networks requires precisely estimated constants. This estimation is in the case of highly-nonlinear issues often solved via gradient optimization algorithms. Nevertheless, by natural processes or physical laws inspired approaches (metaheuristic algorithms) are also of high interest. In the submitted manuscript, three selected metaheuristic algorithms were compared under the approximation of an experimental hot flow curve dataset via the wellknown Hensel-Spittel relationship. One often used gradient algorithm was also included into this comparison. Results have showed that the metaheuristic algorithms are useful if such complex approximation model is applied and no estimate of material constants from a previous approximation issue is used. On the other hand, if this estimation exists, the gradient algorithms should provide a better solution.
通过流动应力模型和人工神经网络进行的热流曲线近似需要精确估计常数。这种估计是在高度非线性问题的情况下,通常通过梯度优化算法来解决。然而,由自然过程或物理定律启发的方法(元启发式算法)也引起了人们的高度兴趣。在提交的手稿中,通过著名的Hensel-Spittel关系,在实验热流曲线数据集的近似下,比较了三种选定的元启发式算法。一种常用的梯度算法也被纳入到这个比较中。结果表明,如果应用这种复杂的近似模型,并且不使用先前近似问题的材料常数估计,则元启发式算法是有用的。另一方面,如果存在这种估计,梯度算法应该提供更好的解决方案。
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引用次数: 0
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