首页 > 最新文献

Science and Engineering of Composite Materials最新文献

英文 中文
Metakaolin-based geopolymers filled with volcanic fly ashes: FT-IR, thermal characterization, and antibacterial property 粉煤灰填充偏高岭土聚合物:红外光谱、热特性和抗菌性能
IF 1.9 4区 材料科学 Q3 Materials Science Pub Date : 2023-01-01 DOI: 10.1515/secm-2022-0192
I. Blanco, A. D'angelo, Veronica Viola, L. Vertuccio, M. Catauro
Abstract In countries where volcanic activity is widespread, fly ash (FA) formation can represent both a waste to be disposed of and a resource of inorganic substances that can be utilized. Among the technologies able to incorporate FA, geopolymers (GP) or inorganic aluminosilicate amorphous materials are very suitable for this purpose. In this study, GP are realized using metakaolin (MK), sodium hydroxide solution (NaOH 8 M), sodium silicate solution (Na2SiO3), and FA as filler (20 wt% with respect to MK content). The samples were cured at 25 or 40°C for 24 h and the physicochemical, thermal, and antibacterial properties of this material through the integrity test, weight loss test, Fourier-transform infra-red spectroscopy (FT-IR), thermogravimetric analysis (TGA), and Kirby-Bauer assay were assessed. Integrity and weight loss tests indirectly revealed the stability of the macroscopic 3D networks and that the curing at 40°C led to more stable GP. The shift of the Si–O–T absorption band (from 1,090 cm−1 of the MK to 1,017–1,012 cm−1 of the specimens with and without FA) in FT-IR spectra suggested the occurrence of the geopolymerizazion reactions, while TGA study confirmed the higher stability of samples cured at 40°C (with a mass loss equal to 7–13% at 800°C under nitrogen atmosphere). Finally, the antimicrobial activity shed light on the ability of the synthesized GP with the filler and treated at 40°C to have a great effect against Escherichia coli and Pseudomonas aeruginosa.
在火山活动广泛的国家,粉煤灰(FA)的形成既可以作为废物处理,也可以作为无机物资源加以利用。在能够加入FA的技术中,地聚合物(GP)或无机铝硅酸盐非晶材料非常适合用于此目的。本研究采用偏高岭土(MK)、氢氧化钠溶液(NaOH 8 M)、硅酸钠溶液(Na2SiO3)和FA作为填料(占MK含量的20%)实现GP。样品在25或40°C下固化24 h,通过完整性测试、失重测试、傅里叶变换红外光谱(FT-IR)、热重分析(TGA)和Kirby-Bauer法评估该材料的物理化学、热性能和抗菌性能。完整性和减重测试间接揭示了宏观三维网络的稳定性,并且在40°C下固化导致GP更稳定。FT-IR光谱中Si-O-T吸收带的变化(从MK的1,090 cm−1到添加和不添加FA的样品的1,017-1,012 cm−1)表明发生了地聚合反应,而TGA研究证实了在40°C下固化的样品具有更高的稳定性(在氮气气氛下800°C时质量损失为7-13%)。最后,通过抗菌活性分析,揭示了用填料合成的GP经40℃处理后对大肠杆菌和铜绿假单胞菌具有较好的抑菌效果。
{"title":"Metakaolin-based geopolymers filled with volcanic fly ashes: FT-IR, thermal characterization, and antibacterial property","authors":"I. Blanco, A. D'angelo, Veronica Viola, L. Vertuccio, M. Catauro","doi":"10.1515/secm-2022-0192","DOIUrl":"https://doi.org/10.1515/secm-2022-0192","url":null,"abstract":"Abstract In countries where volcanic activity is widespread, fly ash (FA) formation can represent both a waste to be disposed of and a resource of inorganic substances that can be utilized. Among the technologies able to incorporate FA, geopolymers (GP) or inorganic aluminosilicate amorphous materials are very suitable for this purpose. In this study, GP are realized using metakaolin (MK), sodium hydroxide solution (NaOH 8 M), sodium silicate solution (Na2SiO3), and FA as filler (20 wt% with respect to MK content). The samples were cured at 25 or 40°C for 24 h and the physicochemical, thermal, and antibacterial properties of this material through the integrity test, weight loss test, Fourier-transform infra-red spectroscopy (FT-IR), thermogravimetric analysis (TGA), and Kirby-Bauer assay were assessed. Integrity and weight loss tests indirectly revealed the stability of the macroscopic 3D networks and that the curing at 40°C led to more stable GP. The shift of the Si–O–T absorption band (from 1,090 cm−1 of the MK to 1,017–1,012 cm−1 of the specimens with and without FA) in FT-IR spectra suggested the occurrence of the geopolymerizazion reactions, while TGA study confirmed the higher stability of samples cured at 40°C (with a mass loss equal to 7–13% at 800°C under nitrogen atmosphere). Finally, the antimicrobial activity shed light on the ability of the synthesized GP with the filler and treated at 40°C to have a great effect against Escherichia coli and Pseudomonas aeruginosa.","PeriodicalId":21480,"journal":{"name":"Science and Engineering of Composite Materials","volume":" ","pages":""},"PeriodicalIF":1.9,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43801104","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Prediction of the rubberized concrete behavior: A comparison of gene expression programming and response surface method 橡胶混凝土性能预测:基因表达编程与响应面法的比较
4区 材料科学 Q3 Materials Science Pub Date : 2023-01-01 DOI: 10.1515/secm-2022-0222
Rana Faisal Tufail, Danish Farooq, Muhammad Faisal Javed, Tahir Mehmood, Ahsen Maqsoom, Hassan Ashraf, Ahmed Farouk Deifalla, Jawad Ahmad
Abstract The use of rubber in concrete to partially substitute mineral aggregates is an effort to decrease the global amount of scrap tires. This study investigates the behavior of rubberized concrete (RC) with various replacement ratios (0–50%) by volume and replacement type (fine, coarse, and fine-coarse) using soft computing techniques. The uniaxial compressive strength (CS), elastic modulus (EM), and ductility (D) are measured, and the effect of rubber content and the rubber aggregate type on the properties of RC is investigated. Scanning electron microscopy and X-ray diffraction analyses are made to determine its microstructural and chemical composition. This article compares the efficiency of two RC models using a recently developed artificial intelligence technique, i.e., gene expression programming (GEP) and conventional technique, i.e., response surface method (RSM). Statistical models are developed to predict the CS, TS, EM, and D. The mathematical models are validated using determination coefficient ( R 2 ) and adjusted coefficient ( R 2 adj), and they are found to be significant. Furthermore, both methods (i.e., RSM and GEP) are very well correlated with the experimental data. The GEP is found to be more effective at predicting the experimental test results for RC. The projected methods can be executed for any practical value of RC.
在混凝土中使用橡胶来部分替代矿物骨料是减少全球废轮胎量的一种努力。本研究使用软计算技术研究了按体积和替代类型(细、粗和细粗)不同替代比(0-50%)的橡胶混凝土(RC)的行为。测定了混凝土的单轴抗压强度(CS)、弹性模量(EM)和延性(D),并研究了橡胶含量和橡胶骨料类型对混凝土性能的影响。用扫描电子显微镜和x射线衍射分析确定了其显微结构和化学成分。本文比较了最近发展的人工智能技术,即基因表达编程(GEP)和传统技术,即响应面法(RSM)的两种RC模型的效率。建立了预测CS、TS、EM和d的统计模型,使用决定系数(r2)和调整系数(r2 adj)对数学模型进行了验证,发现它们具有显著性。此外,两种方法(即RSM和GEP)都与实验数据具有很好的相关性。结果表明,GEP对钢筋混凝土试验结果的预测更为有效。投影方法可适用于任何实际RC值。
{"title":"Prediction of the rubberized concrete behavior: A comparison of gene expression programming and response surface method","authors":"Rana Faisal Tufail, Danish Farooq, Muhammad Faisal Javed, Tahir Mehmood, Ahsen Maqsoom, Hassan Ashraf, Ahmed Farouk Deifalla, Jawad Ahmad","doi":"10.1515/secm-2022-0222","DOIUrl":"https://doi.org/10.1515/secm-2022-0222","url":null,"abstract":"Abstract The use of rubber in concrete to partially substitute mineral aggregates is an effort to decrease the global amount of scrap tires. This study investigates the behavior of rubberized concrete (RC) with various replacement ratios (0–50%) by volume and replacement type (fine, coarse, and fine-coarse) using soft computing techniques. The uniaxial compressive strength (CS), elastic modulus (EM), and ductility (D) are measured, and the effect of rubber content and the rubber aggregate type on the properties of RC is investigated. Scanning electron microscopy and X-ray diffraction analyses are made to determine its microstructural and chemical composition. This article compares the efficiency of two RC models using a recently developed artificial intelligence technique, i.e., gene expression programming (GEP) and conventional technique, i.e., response surface method (RSM). Statistical models are developed to predict the CS, TS, EM, and D. The mathematical models are validated using determination coefficient ( R 2 ) and adjusted coefficient ( R 2 adj), and they are found to be significant. Furthermore, both methods (i.e., RSM and GEP) are very well correlated with the experimental data. The GEP is found to be more effective at predicting the experimental test results for RC. The projected methods can be executed for any practical value of RC.","PeriodicalId":21480,"journal":{"name":"Science and Engineering of Composite Materials","volume":"34 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135151612","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Analysis of multiple impact tests’ damage to three-dimensional four-directional braided composites 三维四向编织复合材料的多次冲击损伤分析
IF 1.9 4区 材料科学 Q3 Materials Science Pub Date : 2022-01-01 DOI: 10.1515/secm-2022-0023
S. Yan, Xixi Chen, Yun Zhao
Abstract This article was designed with a plurality of impact tests of three-dimensional four-directional braided composites, and the impact response of specimen impacted by a circular punch was studied. Ultrasonic C-scanning was used to detect the internal damage area to study the damage propagation process under multiple impact loads. The finite-element software ABAQUS was used to model the meso-structure of three-dimensional four-directional braided composites. Based on material characteristics, the three-dimensional Hashin damage criterion was used for the fiber bundle, and the maximum stress criterion was used for the matrix to judge the material damage. Combined with test and simulation results, the failure mode and damage evolution process of the specimen under multiple impact loads were studied. The results showed that the impact resistance of the three-dimensional woven composite material is affected by the braided angle. The larger the braided angle of the specimen, the better the impact resistance. The damaged area of the large braided angle material expanded to the periphery, and the damaged area of the small braided angle material was primarily developed in the longitudinal direction. The failure modes of the specimen during the impact process were primarily a longitudinal tensile failure of fiber bundles, transverse tensile failure and transverse compression failure of fiber bundles and matrix.
摘要本文设计了三维四向编织复合材料的多次冲击试验,研究了圆形冲头冲击试样的冲击响应。采用超声C扫描法检测内部损伤区域,研究了多冲击载荷下的损伤扩展过程。利用有限元软件ABAQUS对三维四向编织复合材料的细观结构进行了建模。根据材料特性,纤维束采用三维Hashin损伤准则,基体采用最大应力准则判断材料损伤。结合试验和仿真结果,研究了试件在多重冲击载荷作用下的失效模式和损伤演化过程。结果表明,编织角度对三维机织复合材料的抗冲击性能有影响。试样的编织角越大,抗冲击性越好。大编织角材料的损伤区域向周边扩展,小编织角材料损伤区域主要沿纵向发展。试样在冲击过程中的失效模式主要是纤维束的纵向拉伸失效、纤维束和基体的横向拉伸失效和横向压缩失效。
{"title":"Analysis of multiple impact tests’ damage to three-dimensional four-directional braided composites","authors":"S. Yan, Xixi Chen, Yun Zhao","doi":"10.1515/secm-2022-0023","DOIUrl":"https://doi.org/10.1515/secm-2022-0023","url":null,"abstract":"Abstract This article was designed with a plurality of impact tests of three-dimensional four-directional braided composites, and the impact response of specimen impacted by a circular punch was studied. Ultrasonic C-scanning was used to detect the internal damage area to study the damage propagation process under multiple impact loads. The finite-element software ABAQUS was used to model the meso-structure of three-dimensional four-directional braided composites. Based on material characteristics, the three-dimensional Hashin damage criterion was used for the fiber bundle, and the maximum stress criterion was used for the matrix to judge the material damage. Combined with test and simulation results, the failure mode and damage evolution process of the specimen under multiple impact loads were studied. The results showed that the impact resistance of the three-dimensional woven composite material is affected by the braided angle. The larger the braided angle of the specimen, the better the impact resistance. The damaged area of the large braided angle material expanded to the periphery, and the damaged area of the small braided angle material was primarily developed in the longitudinal direction. The failure modes of the specimen during the impact process were primarily a longitudinal tensile failure of fiber bundles, transverse tensile failure and transverse compression failure of fiber bundles and matrix.","PeriodicalId":21480,"journal":{"name":"Science and Engineering of Composite Materials","volume":"29 1","pages":"242 - 264"},"PeriodicalIF":1.9,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49391162","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multiscale heat conduction and fractal oxidation behaviors of needle-punched carbon/carbon composites 针刺碳/碳复合材料的多尺度导热和分形氧化行为
IF 1.9 4区 材料科学 Q3 Materials Science Pub Date : 2022-01-01 DOI: 10.1515/secm-2022-0174
Meng Han, Chuwei Zhou, V. Silberschmidt, Qinsheng Bi
Abstract Needle-punched (NP) carbon/carbon composites (CCCs) are widely used in structures re-entering the atmosphere of aerospace, thanks to their excellent mechanical properties. They are easily oxidized at high temperatures with atmospheric oxygen. The oxidation behavior is influenced by the process of heat conduction. In this study, longitudinal and transverse heat conduction in micro- and mesoscale models of CCCs was investigated. It was established that the heat transfer interface of a fiber bundle demonstrated peak-like morphology, while the punching structures of composites slowed down the process of heat conduction. Oxidation behavior of NP CCCs was predicted with a fractional Brownian motion strategy. It was found that the oxidized fiber bundles formed “bamboo shoots” morphology due to different oxidation rates of the matrix and fibers. Stochastic oxidation behavior was successfully described with this fractal strategy.
摘要针刺碳/碳复合材料以其优异的力学性能被广泛应用于重返航空航天大气的结构中。它们在高温下很容易被大气中的氧气氧化。氧化行为受到热传导过程的影响。在本研究中,研究了CCCs的微尺度和中尺度模式中的纵向和横向热传导。研究表明,纤维束的传热界面呈现出峰状形态,而复合材料的冲压结构减缓了热传导过程。用分数布朗运动策略预测NP类CCCs的氧化行为。研究发现,由于基体和纤维的氧化速率不同,氧化后的纤维束形成“竹笋”形态。用这种分形策略成功地描述了随机氧化行为。
{"title":"Multiscale heat conduction and fractal oxidation behaviors of needle-punched carbon/carbon composites","authors":"Meng Han, Chuwei Zhou, V. Silberschmidt, Qinsheng Bi","doi":"10.1515/secm-2022-0174","DOIUrl":"https://doi.org/10.1515/secm-2022-0174","url":null,"abstract":"Abstract Needle-punched (NP) carbon/carbon composites (CCCs) are widely used in structures re-entering the atmosphere of aerospace, thanks to their excellent mechanical properties. They are easily oxidized at high temperatures with atmospheric oxygen. The oxidation behavior is influenced by the process of heat conduction. In this study, longitudinal and transverse heat conduction in micro- and mesoscale models of CCCs was investigated. It was established that the heat transfer interface of a fiber bundle demonstrated peak-like morphology, while the punching structures of composites slowed down the process of heat conduction. Oxidation behavior of NP CCCs was predicted with a fractional Brownian motion strategy. It was found that the oxidized fiber bundles formed “bamboo shoots” morphology due to different oxidation rates of the matrix and fibers. Stochastic oxidation behavior was successfully described with this fractal strategy.","PeriodicalId":21480,"journal":{"name":"Science and Engineering of Composite Materials","volume":"29 1","pages":"508 - 515"},"PeriodicalIF":1.9,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42239403","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effects of local fiber discontinuity on the fatigue strength parameter at the fiber inclusion corner in fiber-reinforced composites 纤维增强复合材料纤维夹杂角处局部纤维不连续对疲劳强度参数的影响
IF 1.9 4区 材料科学 Q3 Materials Science Pub Date : 2022-01-01 DOI: 10.1515/secm-2022-0021
Cong Wang, X. Ping, Xing Wang
Abstract To comprehend the fatigue failure mechanism at the fiber discontinuity in fiber-reinforced composites, it is necessary to evaluate the local mechanical behaviors. The fatigue strength depends on the stress distribution at the fiber inclusion corner. An improved advanced finite element method (IAFEM) is proposed for the stress intensity factor (SIF) analysis at the fiber inclusion corner. In the IAFEM, the element stiffness matrix of singular inclusion corner element (SICE) is obtained, and the singular elastic field at the tip of the fiber inclusion is determined. The effects of load direction, fiber distribution, fiber geometry, and material properties on SIFs are analyzed numerically using the IAFEM. The difference in stress field distribution between two-dimensional and three-dimensional fiber inclusions is discussed. The IAFEIM and calculation results can provide reference for fatigue strength analysis and preparation of composite materials.
摘要为了理解纤维增强复合材料在纤维不连续处的疲劳破坏机理,有必要对其局部力学行为进行评估。疲劳强度取决于纤维夹杂角处的应力分布。提出了一种改进的先进有限元法(IAFEM),用于分析光纤包合角处的应力强度因子(SIF)。在IAFEM中,获得了奇异夹杂角元(SICE)的单元刚度矩阵,确定了纤维夹杂尖端的奇异弹性场。利用IAFEM数值分析了载荷方向、纤维分布、纤维几何形状和材料性能对SIFs的影响。讨论了二维和三维纤维夹杂物应力场分布的差异。该方法及其计算结果可为复合材料的疲劳强度分析和制备提供参考。
{"title":"Effects of local fiber discontinuity on the fatigue strength parameter at the fiber inclusion corner in fiber-reinforced composites","authors":"Cong Wang, X. Ping, Xing Wang","doi":"10.1515/secm-2022-0021","DOIUrl":"https://doi.org/10.1515/secm-2022-0021","url":null,"abstract":"Abstract To comprehend the fatigue failure mechanism at the fiber discontinuity in fiber-reinforced composites, it is necessary to evaluate the local mechanical behaviors. The fatigue strength depends on the stress distribution at the fiber inclusion corner. An improved advanced finite element method (IAFEM) is proposed for the stress intensity factor (SIF) analysis at the fiber inclusion corner. In the IAFEM, the element stiffness matrix of singular inclusion corner element (SICE) is obtained, and the singular elastic field at the tip of the fiber inclusion is determined. The effects of load direction, fiber distribution, fiber geometry, and material properties on SIFs are analyzed numerically using the IAFEM. The difference in stress field distribution between two-dimensional and three-dimensional fiber inclusions is discussed. The IAFEIM and calculation results can provide reference for fatigue strength analysis and preparation of composite materials.","PeriodicalId":21480,"journal":{"name":"Science and Engineering of Composite Materials","volume":"29 1","pages":"274 - 286"},"PeriodicalIF":1.9,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43784872","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Discussion of ceramic bar reinforced TWIP steel composite structure 陶瓷棒增强TWIP钢组合结构的探讨
IF 1.9 4区 材料科学 Q3 Materials Science Pub Date : 2022-01-01 DOI: 10.1515/secm-2022-0173
Guorui Sun, Wang Qi, Hou Miaoyu
Abstract A ceramic–steel composite structure which consists of Si3N4 ceramic bars and twinning-induced plasticity (TWIP) steel matrix was prepared using lost foam casting method. Microstructural analysis indicated that the ceramic bars and TWIP steel matrix can form favorable and tight interface. A comparison of mechanical properties between the composite structure and TWIP steel matrix was made. Results show that the bending strength increased from 388 to 805 MPa compared with TWIP steel matrix. The influence of annealing heat treatment on the bending strength of this new type of composite structure was also discussed.
摘要:采用消失模铸造法制备了由Si3N4陶瓷棒和孪生诱导塑性(TWIP)钢基体组成的陶瓷-钢复合组织。显微组织分析表明,陶瓷棒与TWIP钢基体能形成良好而紧密的界面。对复合材料组织与TWIP钢基体的力学性能进行了比较。结果表明:与TWIP钢基体相比,其抗弯强度由388 MPa提高到805 MPa;讨论了退火热处理对这种新型复合材料抗弯强度的影响。
{"title":"Discussion of ceramic bar reinforced TWIP steel composite structure","authors":"Guorui Sun, Wang Qi, Hou Miaoyu","doi":"10.1515/secm-2022-0173","DOIUrl":"https://doi.org/10.1515/secm-2022-0173","url":null,"abstract":"Abstract A ceramic–steel composite structure which consists of Si3N4 ceramic bars and twinning-induced plasticity (TWIP) steel matrix was prepared using lost foam casting method. Microstructural analysis indicated that the ceramic bars and TWIP steel matrix can form favorable and tight interface. A comparison of mechanical properties between the composite structure and TWIP steel matrix was made. Results show that the bending strength increased from 388 to 805 MPa compared with TWIP steel matrix. The influence of annealing heat treatment on the bending strength of this new type of composite structure was also discussed.","PeriodicalId":21480,"journal":{"name":"Science and Engineering of Composite Materials","volume":"29 1","pages":"481 - 487"},"PeriodicalIF":1.9,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43874888","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Wear and corrosion mechanisms of Ni–WC coatings modified with different Y2O3 by laser cladding on AISI 4145H steel AISI 4145H钢激光熔覆不同Y2O3改性Ni–WC涂层的磨损和腐蚀机制
IF 1.9 4区 材料科学 Q3 Materials Science Pub Date : 2022-01-01 DOI: 10.1515/secm-2022-0163
Qizheng Cao, L. Fan, Haiyan Chen, Yue Hou, L. Dong, Zhiwei Ni
Abstract In order to evaluate the effect of rare earth Y2O3 on the wear and corrosion properties of WC–Ni composite coatings, X-ray diffraction, scanning electron microscopy(SEM), electrochemical polarization curve, electrochemical impedance spectroscopy (EIS), and friction and wear tests were used to analyze the metallographic structure, corrosion characteristics in simulated seawater and friction and wear principle of the composite coatings. Results of SEM revealed that the microstructure of the Y2O3 added coatings was refined with the grains changing smaller and the impurity disappearing. The EIS results proved that the addition of Y2O3 brought a positive influence on the corrosion resistance by reducing the capacitance and increasing the R f and R c. The hardness of the coatings with Y2O3 addition tends to be smooth without wild fluctuation, and the coating with 0.5 wt% Y2O3 owned the hardness values reaching 850 HV. With the addition of rare earth elements, the coefficient of fiction values decreased, reaching the lowest (0.3418) at the content of Y2O3 of 0.5 wt%. The surface of the coating without Y2O3 appears grooved due to the abrasive wear; the coatings with Y2O3 did not suffer serious wear and tear. The coating with 0.5 wt% Y2O3 exhibited the best corrosion resistance and wear resistance properties in all the specimens.
摘要为了评价稀土Y2O3对WC-Ni复合涂层磨损和腐蚀性能的影响,采用x射线衍射、扫描电镜(SEM)、电化学极化曲线、电化学阻抗谱(EIS)和摩擦磨损试验等方法,分析了复合涂层的金相组织、模拟海水中的腐蚀特征和摩擦磨损原理。SEM结果表明,添加了Y2O3的涂层组织细化,晶粒变小,杂质消失。EIS结果表明,Y2O3的加入降低了镀层的电容,提高了R f和R c,对镀层的耐蚀性产生了积极的影响。Y2O3的加入使镀层的硬度趋于光滑,没有剧烈的波动,当Y2O3含量为0.5 wt%时,镀层的硬度值达到850 HV。随着稀土元素的加入,虚构系数减小,在Y2O3含量为0.5 wt%时达到最低(0.3418)。不含Y2O3的涂层表面由于磨料磨损而出现沟槽;含Y2O3的涂层磨损不严重。在所有试样中,Y2O3含量为0.5 wt%的涂层具有最佳的耐蚀性和耐磨性。
{"title":"Wear and corrosion mechanisms of Ni–WC coatings modified with different Y2O3 by laser cladding on AISI 4145H steel","authors":"Qizheng Cao, L. Fan, Haiyan Chen, Yue Hou, L. Dong, Zhiwei Ni","doi":"10.1515/secm-2022-0163","DOIUrl":"https://doi.org/10.1515/secm-2022-0163","url":null,"abstract":"Abstract In order to evaluate the effect of rare earth Y2O3 on the wear and corrosion properties of WC–Ni composite coatings, X-ray diffraction, scanning electron microscopy(SEM), electrochemical polarization curve, electrochemical impedance spectroscopy (EIS), and friction and wear tests were used to analyze the metallographic structure, corrosion characteristics in simulated seawater and friction and wear principle of the composite coatings. Results of SEM revealed that the microstructure of the Y2O3 added coatings was refined with the grains changing smaller and the impurity disappearing. The EIS results proved that the addition of Y2O3 brought a positive influence on the corrosion resistance by reducing the capacitance and increasing the R f and R c. The hardness of the coatings with Y2O3 addition tends to be smooth without wild fluctuation, and the coating with 0.5 wt% Y2O3 owned the hardness values reaching 850 HV. With the addition of rare earth elements, the coefficient of fiction values decreased, reaching the lowest (0.3418) at the content of Y2O3 of 0.5 wt%. The surface of the coating without Y2O3 appears grooved due to the abrasive wear; the coatings with Y2O3 did not suffer serious wear and tear. The coating with 0.5 wt% Y2O3 exhibited the best corrosion resistance and wear resistance properties in all the specimens.","PeriodicalId":21480,"journal":{"name":"Science and Engineering of Composite Materials","volume":"29 1","pages":"364 - 377"},"PeriodicalIF":1.9,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46998308","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Influence of hydrothermal aging on the mechanical performance of foam core sandwich panels subjected to low-velocity impact 水热老化对泡沫芯芯夹芯板低速冲击力学性能的影响
IF 1.9 4区 材料科学 Q3 Materials Science Pub Date : 2022-01-01 DOI: 10.1515/secm-2022-0003
Youping Liu, Ye Wu
Abstract The effect of hydrothermal aging on the impact resistance of foam core sandwich panels is studied in this study. The sandwich panels with glass fiber-reinforced skins and polyurethane foam core were fabricated and then were treated with different hydrothermal aging conditions. The moisture absorption characteristic of the composite skins was evaluated. A modified Fickian formulation was proposed to predict the moisture absorption behavior of composite skins. The low-velocity impact resistance of the aged sandwich panels was determined at three different impact energies. The impact responses including contact force, deflection, and dissipated energy of the sandwich panels with and without hydrothermal aging were analyzed. The macroscopic and microscopic damage morphologies were observed by visual inspection and scanning electron microscope methods, respectively. The damage mechanism of the aged panels was revealed. Results indicate that the impact resistance of aged sandwich panels is degraded, and the performance degradation is larger with increasing aging temperature. Compared to the panel without hydrothermal aging, the reduction of the contact force is 35.69%, and the increase of the deflection is 71.43% for the aged panel at 70°C aging temperature. The fiber/matrix interfacial cohesive performance is degraded resulting from the hydrothermal aging.
摘要本文研究了水热老化对泡沫芯芯夹芯板抗冲击性能的影响。制备了玻璃纤维增强外皮和聚氨酯泡沫芯夹芯板,并对夹芯板进行了不同的水热老化处理。对复合材料表皮的吸湿性能进行了评价。提出了一种改进的Fickian公式来预测复合材料皮肤的吸湿性能。在三种不同的冲击能量下,测定了老化夹层板的低速抗冲击性能。分析了热液老化前后夹层板的接触力、挠度和耗散能等冲击响应。通过目测和扫描电镜分别观察损伤的宏观和微观形态。揭示了老化板的损伤机理。结果表明,老化夹层板的抗冲击性能下降,且随着老化温度的升高,性能下降幅度更大。在70℃时效温度下,与未经热液时效的面板相比,时效面板的接触力降低了35.69%,挠度增加了71.43%。水热老化导致纤维/基体界面粘结性能下降。
{"title":"Influence of hydrothermal aging on the mechanical performance of foam core sandwich panels subjected to low-velocity impact","authors":"Youping Liu, Ye Wu","doi":"10.1515/secm-2022-0003","DOIUrl":"https://doi.org/10.1515/secm-2022-0003","url":null,"abstract":"Abstract The effect of hydrothermal aging on the impact resistance of foam core sandwich panels is studied in this study. The sandwich panels with glass fiber-reinforced skins and polyurethane foam core were fabricated and then were treated with different hydrothermal aging conditions. The moisture absorption characteristic of the composite skins was evaluated. A modified Fickian formulation was proposed to predict the moisture absorption behavior of composite skins. The low-velocity impact resistance of the aged sandwich panels was determined at three different impact energies. The impact responses including contact force, deflection, and dissipated energy of the sandwich panels with and without hydrothermal aging were analyzed. The macroscopic and microscopic damage morphologies were observed by visual inspection and scanning electron microscope methods, respectively. The damage mechanism of the aged panels was revealed. Results indicate that the impact resistance of aged sandwich panels is degraded, and the performance degradation is larger with increasing aging temperature. Compared to the panel without hydrothermal aging, the reduction of the contact force is 35.69%, and the increase of the deflection is 71.43% for the aged panel at 70°C aging temperature. The fiber/matrix interfacial cohesive performance is degraded resulting from the hydrothermal aging.","PeriodicalId":21480,"journal":{"name":"Science and Engineering of Composite Materials","volume":"29 1","pages":"9 - 22"},"PeriodicalIF":1.9,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41854051","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Vibration and noise reduction of pipelines using shape memory alloy 形状记忆合金管道减振降噪
IF 1.9 4区 材料科学 Q3 Materials Science Pub Date : 2022-01-01 DOI: 10.1515/secm-2022-0015
Ju Qiu, I. Stiharu
Abstract In this article, the pipeline design is introduced. The new pipe structure is made of new fiber metal laminates with the unidirectional composite and sheet metal (Ti–Ni alloy). Many pipe structures are in the heating environment such as in or around the engine, which will also cause the heating-up structure. If the shape memory alloy (SMA) fiber is added to the composite lamination, it can be seen that with the increase of temperature, the stiffness of the structure is increased and so is its frequency. The changed frequency of the structure can avoid the excitation frequency in this way, which effectively inhibits the resonance. In dynamic analysis, it can also show that the pipeline with the SMA fiber has good performance for vibration reduction and noise attenuation. Additionally, the convergence of the meshing model and the effect of the thickness of the SMA material on vibration and noise reduction are also discussed.
摘要本文介绍了管道的设计。新型管道结构由新型纤维金属层压板、单向复合材料和片状金属(Ti–Ni合金)制成。许多管道结构处于加热环境中,如发动机内部或周围,这也会导致加热结构。如果将形状记忆合金(SMA)纤维添加到复合材料叠层中,可以看出,随着温度的升高,结构的刚度增加,其频率也增加。通过改变结构的频率可以避免激励频率,从而有效地抑制了共振。在动力学分析中,还可以表明SMA纤维管道具有良好的减振降噪性能。此外,还讨论了网格模型的收敛性以及SMA材料厚度对减振降噪的影响。
{"title":"Vibration and noise reduction of pipelines using shape memory alloy","authors":"Ju Qiu, I. Stiharu","doi":"10.1515/secm-2022-0015","DOIUrl":"https://doi.org/10.1515/secm-2022-0015","url":null,"abstract":"Abstract In this article, the pipeline design is introduced. The new pipe structure is made of new fiber metal laminates with the unidirectional composite and sheet metal (Ti–Ni alloy). Many pipe structures are in the heating environment such as in or around the engine, which will also cause the heating-up structure. If the shape memory alloy (SMA) fiber is added to the composite lamination, it can be seen that with the increase of temperature, the stiffness of the structure is increased and so is its frequency. The changed frequency of the structure can avoid the excitation frequency in this way, which effectively inhibits the resonance. In dynamic analysis, it can also show that the pipeline with the SMA fiber has good performance for vibration reduction and noise attenuation. Additionally, the convergence of the meshing model and the effect of the thickness of the SMA material on vibration and noise reduction are also discussed.","PeriodicalId":21480,"journal":{"name":"Science and Engineering of Composite Materials","volume":"29 1","pages":"165 - 175"},"PeriodicalIF":1.9,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48796103","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Fabrications and microstructure analysis of cobalt-based coatings by an easy-coating and sintering process 钴基涂层的简易涂覆和烧结制备及微观结构分析
IF 1.9 4区 材料科学 Q3 Materials Science Pub Date : 2022-01-01 DOI: 10.1515/secm-2022-0178
Lingyu Meng, M. Hu, Keming Jia
Abstract In order to enhance the service life of special complex shaped workpieces under severe working conditions, a new coating preparation process, namely, easy-coating and sintering technology, has been proposed. In this study, the feasibility of preparing Co-based coatings on 38CrMoAl substrates using the easy-coating and sintering process was investigated, and the microstructure and properties of the Co-based coatings were studied. By optimizing the parameters of the sintering process, the prepared coating is dense, and the coating forms a good metallurgical bond with the substrate with few pores, but no other defects. As the process has good applicability to the surface of complex-shaped parts, the inner wall of small serpentine tubes and large thicknesses, and is low-cost and easy to operate, the easy-coating-sintering process has great application prospects.
摘要为了提高特殊复杂形状工件在恶劣工作条件下的使用寿命,提出了一种新的涂层制备工艺,即易涂层和烧结技术。本研究探讨了采用简易涂层和烧结工艺在38CrMoAl基体上制备钴基涂层的可行性,并对钴基涂层组织和性能进行了研究。通过优化烧结工艺参数,制备的涂层致密,涂层与基体形成良好的冶金结合,气孔少,但没有其他缺陷。由于该工艺对复杂形状零件的表面、小蛇形管内壁和大厚度具有良好的适用性,且成本低、操作方便,因此易涂层烧结工艺具有很大的应用前景。
{"title":"Fabrications and microstructure analysis of cobalt-based coatings by an easy-coating and sintering process","authors":"Lingyu Meng, M. Hu, Keming Jia","doi":"10.1515/secm-2022-0178","DOIUrl":"https://doi.org/10.1515/secm-2022-0178","url":null,"abstract":"Abstract In order to enhance the service life of special complex shaped workpieces under severe working conditions, a new coating preparation process, namely, easy-coating and sintering technology, has been proposed. In this study, the feasibility of preparing Co-based coatings on 38CrMoAl substrates using the easy-coating and sintering process was investigated, and the microstructure and properties of the Co-based coatings were studied. By optimizing the parameters of the sintering process, the prepared coating is dense, and the coating forms a good metallurgical bond with the substrate with few pores, but no other defects. As the process has good applicability to the surface of complex-shaped parts, the inner wall of small serpentine tubes and large thicknesses, and is low-cost and easy to operate, the easy-coating-sintering process has great application prospects.","PeriodicalId":21480,"journal":{"name":"Science and Engineering of Composite Materials","volume":"29 1","pages":"529 - 534"},"PeriodicalIF":1.9,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46107405","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Science and Engineering of Composite Materials
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1