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XRD analysis determined crystal cage occupying number n of carbon anion substituted mayenite-type cage compound C12A7: nC XRD分析确定了碳阴离子取代的钙铝石型笼状化合物C12A7:nC的晶体笼占据数n
IF 1.9 4区 材料科学 Q3 Materials Science Pub Date : 2023-01-01 DOI: 10.1515/secm-2022-0197
Cong Ji, Fan Gu
Abstract In this study, a series of samples of C12A7 derivative was prepared by high temperature sintering in a sealed graphite crucible. The theoretical model of C12A7 derivatives with different carbon occupation numbers was established. The X-ray diffraction (XRD) theoretical calculation was carried out. The conjecture was verified to a certain extent through the comparison of the theoretical calculation of XRD with the experimental results. According to the calculation results, it was found that the XRD patterns of C12A7 and its derivatives changed regularly with the change in the occupation number in the crystal cage. Under the condition that the types of vacancy atoms remained unchanged, the more vacancy atoms occupied in C12A7 crystal, the higher the peak at 2θ = 33.35° in the diffraction pattern. It was also found that the higher the atomic number of vacancy atoms in C12A7 crystal, the higher the peak at 2θ = 33.35° in the diffraction pattern. The carbon occupation number of samples at different experimental temperatures was deduced. The results showed that the carbon occupancy of the samples prepared at 990, 1,353 and 1,680°C were 11, 4 and 8, respectively.
摘要本研究在密封石墨坩埚中高温烧结制备了一系列C12A7衍生物样品。建立了不同碳占有数C12A7衍生物的理论模型。进行了x射线衍射(XRD)理论计算。通过XRD的理论计算与实验结果的对比,在一定程度上验证了这一猜想。计算结果表明,C12A7及其衍生物的XRD谱图随着在晶笼中占据数的变化而有规律地变化。在空位原子类型不变的情况下,C12A7晶体中占据的空位原子越多,衍射图中2θ = 33.35°处的峰越高。C12A7晶体中空位原子的原子序数越高,衍射图中2θ = 33.35°处的峰越高。推导了不同实验温度下样品的碳占据数。结果表明,在990℃、1353℃和1680℃下制备的样品的碳占用率分别为11、4和8。
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引用次数: 0
Chloride ion transport and service life prediction of aeolian sand concrete under dry–wet cycles 干湿循环下风沙混凝土氯离子输运及寿命预测
IF 1.9 4区 材料科学 Q3 Materials Science Pub Date : 2023-01-01 DOI: 10.1515/secm-2022-0188
Wei Dong, Yajing Ji
Abstract In this study, the dry–wet cycle test of chloride salt was carried out on aeolian sand concrete with different contents, and the chloride ion content in aeolian sand concrete was determined by taking powder from different depths on one side of the test block. And then combined with Monte Carlo stochastic statistical simulation and Weibull probability distribution function, the service life prediction model of aeolian sand concrete against chloride ion erosion is established. The results show that the free chloride ion content in aeolian sand concrete decreases with the increase in the depth from the surface of the specimen. At the same depth from the surface of the specimen, the free chloride ion content gradually increases with the increase in the number of dry–wet cycles. Through the analysis of life prediction, it is concluded that with the increase in aeolian sand content, the service life of aeolian sand concrete increases first and then decreases. The service life value of concrete with 75% aeolian sand content is the largest, and the greater the thickness of the protective layer, the more favorable the service life value.
摘要本研究对不同掺量的风成砂混凝土进行氯盐干湿循环试验,通过在试验块一侧取不同深度的粉料,测定风成砂混凝土中氯离子含量。然后结合蒙特卡罗随机统计模拟和威布尔概率分布函数,建立了风沙混凝土抗氯离子侵蚀寿命预测模型。结果表明:风成砂混凝土中游离氯离子含量随离试件表面深度的增加而降低;在离试件表面相同深度处,随着干湿循环次数的增加,游离氯离子含量逐渐增加。通过寿命预测分析,得出随着风积砂掺量的增加,风积砂混凝土的使用寿命先增大后减小的结论。75%风积砂含量的混凝土使用寿命值最大,且保护层厚度越大,使用寿命值越有利。
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引用次数: 2
Method for deriving twisting process parameters of large package E-glass yarn by measuring physical properties of bobbin yarn 通过测量筒子纱的物理性能推导大包e -玻璃纱加捻工艺参数的方法
IF 1.9 4区 材料科学 Q3 Materials Science Pub Date : 2023-01-01 DOI: 10.1515/secm-2022-0212
Xi Wang, Juanfen Chen, Shuai Li, Pei Xiao, Kai Cheng, Yanhe Wang, Tianyong Zheng
Abstract Twisting is an important part in the production process of large package E-glass yarn. To derive the twisting process parameters of large package E-glass yarn, a method from the physical properties of bobbin yarn is proposed based on the study of the twisting principle of E-glass yarn. After unwinding the bobbin yarn and measuring its twist, loop pitch, and corresponding diameter, the calculation is completed according to the steps of first determining the descending speed of the traveler, then fitting the spindle speed data, and finally calculating the elevating speed of the traveler. The result is that the twisting spindle speed of D450 E-glass yarn with 31.8 T/m decreases from 5,015 to 4,550 rpm, the elevating speed of the traveler is 0.91 m/min, and the descending speed of the traveler is 1.50 m/min. The accuracy of the calculation is verified by monitoring the rotating speed of the roving cake and measuring the loop pitch of bobbin yarn in the twisting experiment. The result shows that the prediction error of this method is less than 1.1%, which can effectively derive the twisting process parameters of large package E-glass yarn, and provide a reference for the twisting process design scheme of glass fiber strand manufacturers.
摘要加捻是大包E玻璃纱生产过程中的一个重要环节。为了推导出大包装E玻璃纱的加捻工艺参数,在研究E玻璃纱加捻原理的基础上,提出了一种从筒管纱物理性能出发的方法。将筒子纱线展开并测量其捻度、线圈节距和相应直径后,按照先确定走线器下降速度,然后拟合主轴速度数据,最后计算走线器上升速度的步骤完成计算。结果表明,D450 E-玻璃纱的捻轴速度为31.8 T/m从5015降至4550 rpm,行走器的提升速度为0.91 米/分钟,旅行者的下降速度为1.50 米/分钟。在加捻实验中,通过对粗纱饼转速的监测和筒子纱环距的测量,验证了计算的准确性。结果表明,该方法的预测误差小于1.1%,可以有效地推导出大包装E-玻璃丝的加捻工艺参数,为玻璃纤维股线生产企业的加捻过程设计方案提供参考。
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引用次数: 0
Development of Mg-based metal matrix biomedical composites for acicular cruciate ligament fixation by reinforcing with rare earth oxide and hydroxyapatite – A mechanical, corrosion, and microstructural perspective 用稀土氧化物和羟基磷灰石增强固定十字韧带的镁基金属基生物医学复合材料的开发——从力学、腐蚀和微观结构的角度
IF 1.9 4区 材料科学 Q3 Materials Science Pub Date : 2023-01-01 DOI: 10.1515/secm-2022-0179
D. Aggarwal, V. Kumar, Siddharth R. Sharma
Abstract This study provides an insight into the synthesis of high-strength and corrosion-inhibiting Mg-based biodegradable implant material by the addition of rare earth oxide material for acicular cruciate ligament reconstruction applications. The matrix has been reinforced with a naturally occurring mineral, hydroxyapatite (Ca5(PO4)3OH) and rare earth oxide, neodymium oxide (Nd2O3), in different concentrations. The mechanical response has been assessed by analyzing the samples’ microhardness, ultimate compressive, and tensile strength. In contrast, the corrosion rates were calculated using phosphate buffer saline solution by using different techniques under suitable physiological conditions. The microstructure characterization has been carried out by field emission scanning electron microscope, electron dispersive spectroscopy, optical microscopy, and X-ray diffraction techniques. Moreover, the surface properties of the composites were assessed using surface roughness and contact angle measurements. The sample showed maximum hardness at a concentration of 1.5% rare earth oxide. Moreover, the highest ultimate compressive and tensile strength followed the same order, i.e., 1.5% > 2% > 1%. In addition, the microstructure analysis revealed a refined microstructure and the formation of secondary intermetallic phases. Resistance to dislocation and grain growth barricading were the prominent features highlighted in the study for enhanced mechanical and corrosion properties. Moreover, the hydrogen evolution was lower for Mg–HA–1.5Nd2O3 samples, which was a clear indication of a reduced corrosion rate.
摘要本研究通过添加稀土氧化物材料合成高强度、耐腐蚀的镁基生物可降解植入材料,用于针状交叉韧带重建应用。基质已经用不同浓度的天然矿物羟基磷灰石(Ca5(PO4)3OH)和稀土氧化物钕氧化物(Nd2O3)增强。通过分析样品的显微硬度、极限抗压强度和抗拉强度来评估机械响应。相反,在合适的生理条件下,通过使用不同的技术,使用磷酸盐缓冲盐水溶液计算腐蚀速率。通过场发射扫描电子显微镜、电子色散光谱、光学显微镜和X射线衍射技术对其微观结构进行了表征。此外,使用表面粗糙度和接触角测量来评估复合材料的表面性能。样品在1.5%的稀土氧化物浓度下显示出最大硬度。此外,最高极限抗压强度和抗拉强度遵循相同的顺序,即1.5%>2%>1%。此外,微观结构分析揭示了细化的微观结构和次生金属间相的形成。抗位错和晶粒生长阻挡是研究中强调的增强机械和腐蚀性能的突出特征。此外,Mg–HA–1.5Nd2O3样品的析氢量较低,这清楚地表明腐蚀速率降低。
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引用次数: 0
Study on properties of recycled mixed polyester/nylon/spandex modified by hydrogenated petroleum resin 加氢石油树脂改性再生混合聚酯/尼龙/氨纶的性能研究
4区 材料科学 Q3 Materials Science Pub Date : 2023-01-01 DOI: 10.1515/secm-2022-0225
Xinmou Kuang, Minru Su, Liang Wang, Hao Li, Xiaolan Shen, Mengyun Yu, Yiran Wu
Abstract In order to improve the utilization value of recycled materials, the study considers recycled materials such as polyester/nylon/spandex as raw materials. Using polyester/polyamide/spandex as raw materials, the recycled polyester/polyamide/spandex mixed materials were first pretreated to obtain the pretreated mixed materials. Then, the pretreated mixed materials were evenly mixed with hydrogenated petroleum resin. The composite materials were prepared through extrusion and injection molding. By comparing the mechanical properties, the effects of different hydrogenated petroleum resins and their additives on the tensile strength, bending strength, impact strength, elongation at break, and bending modulus of the composites were investigated. And the microstructure of the fracture surface was characterized by scanning electron microscopy. The results showed that: (a) when the addition amount of hydrogenated C5 petroleum resin was 4.5%, the maximum impact strength and fracture elongation were 18.03 kJ/m 2 and 15.92%, respectively. (b) The maximum tensile strength, bending strength, and bending modulus could reach 22.9, 38.72, and 2217.9 MPa, when the addition amount of hydrogenated C9 petroleum resin was 4.5, 29.5, and 39.5%, respectively.
摘要为了提高回收材料的利用价值,本研究以聚酯/尼龙/氨纶等回收材料为原料。以聚酯/聚酰胺/氨纶为原料,先对回收的聚酯/聚酰胺/氨纶混料进行预处理,得到预处理后的混料。然后,将预处理后的混合材料与加氢石油树脂均匀混合。通过挤压和注射成型制备了复合材料。通过力学性能的比较,研究了不同氢化石油树脂及其添加剂对复合材料的拉伸强度、弯曲强度、冲击强度、断裂伸长率和弯曲模量的影响。并用扫描电镜对断口形貌进行了表征。结果表明:(a)氢化C5石油树脂添加量为4.5%时,最大冲击强度为18.03 kJ/ m2,断裂伸长率为15.92%;(b)当氢化C9石油树脂添加量为4.5%、29.5%和39.5%时,其最大抗拉强度、抗弯强度和抗弯模量分别达到22.9、38.72和2217.9 MPa。
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引用次数: 0
Effect of particle size distribution on microstructure and chloride permeability of blended cement with supplementary cementitious materials 粒径分布对掺补胶凝材料水泥微观结构和氯离子渗透性的影响
4区 材料科学 Q3 Materials Science Pub Date : 2023-01-01 DOI: 10.1515/secm-2022-0226
Ge Gao, Qiang Li, Hongjie Luo, Xiao Huang
Abstract In order to improve the chloride ion penetration resistance of supplementary cementitious materials (SCMs) in blended cement, this study optimizes the particle size distribution of cementitious components based on the Fuller model. Portland cement (PC), fly ash (FA), and ground granulated blast furnace slag (GGBFS) are successfully divided into four particle size ranges by precision air classifier, which are 0–8, 8–30, 30–50, and 50–80 μm, respectively. The optimum cementitious materials in four ranges based on 28-day compressive strength are determined by nine groups of orthogonal tests. The blended cement with optimal performance is obtained by GGBFS in 0–8 μm, PC in 8–30 μm, GGBFS in 30–50 μm, and FA in 50–80 μm. The results show that the blended cement with SCMs based on Fuller model have superior microstructure and chloride ion penetration resistance, which is due to their smaller pore size, a strong volcanic ash effect, and chloride ion binding ability. In addition, this research presents a novel approach for realizing the application of a large amount of SCMs in blended cement.
摘要为了提高混合水泥中补充胶凝材料(SCMs)的抗氯离子渗透能力,本研究基于Fuller模型对胶凝组分的粒径分布进行了优化。采用精密空气分级机将硅酸盐水泥(PC)、粉煤灰(FA)和矿渣粉(GGBFS)分别划分为0 ~ 8 μm、8 ~ 30 μm、30 ~ 50 μm和50 ~ 80 μm四个粒径范围。通过9组正交试验,确定了以28天抗压强度为基准的4个范围内的最佳胶凝材料。GGBFS粒径为0 ~ 8 μm, PC粒径为8 ~ 30 μm, GGBFS粒径为30 ~ 50 μm, FA粒径为50 ~ 80 μm,得到了性能最佳的混合水泥。结果表明,基于Fuller模型的SCMs混合水泥具有更小的孔径、更强的火山灰效应和更强的氯离子结合能力,因此具有更好的微观结构和抗氯离子渗透能力。此外,本研究还为实现SCMs在混合水泥中的大量应用提供了一种新的途径。
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引用次数: 0
In situ ligand synthesis affording a new Co(ii) MOF for photocatalytic application 原位配体合成为光催化应用提供了一种新的Co(ii) MOF
4区 材料科学 Q3 Materials Science Pub Date : 2023-01-01 DOI: 10.1515/secm-2022-0229
Jing Li, Hongjiang Ren, Jiangtao Li, Liuchang Wang
Abstract In situ disulfide bond formation affords a new flexible dicarboxylic acid ligand of 3,3′-dithiobisbenzoic acid (3,3′-H 2 DTBA), which assembled with Co( ii ) ions under hydrothermal conditions, generating a novel metal–organic framework (MOF), namely, [Co(3,3′-DTBA) 2 (H 2 O) 2 ] n ( 1 ). This compound is assembled from layered structures, featuring weak interlayer interactions that can reduce pore blockage through relative sliding. The results of photocatalytic experiment indicate that MOF 1 is a good semiconducting material and it can function as photocatalyst for degrading methylene blue under the ultraviolet light irradiation. Cyclic experiments demonstrated its good stability and long-lasting photocatalytic performance, indicating its potential application value.
原位二硫键形成提供了一种新的柔性二羧酸配体3,3 ' -二硫代双苯甲酸(3,3 ' - h2dtba),该配体与Co(ii)离子在水热条件下组装,生成了一种新的金属有机骨架(MOF),即[Co(3,3 ' -DTBA) 2 (h2o) 2] n(1)。该化合物由层状结构组装而成,具有层间弱相互作用,可以通过相对滑动减少孔隙堵塞。光催化实验结果表明,MOF 1是一种良好的半导体材料,在紫外光照射下可作为降解亚甲基蓝的光催化剂。循环实验证明其具有良好的稳定性和持久的光催化性能,具有潜在的应用价值。
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引用次数: 0
The influence of preparation of nano-ZrO2/α-Al2O3 gradient coating on the corrosion resistance of 316L stainless steel substrate 制备纳米zro2 /α-Al2O3梯度涂层对316L不锈钢基体耐腐蚀性能的影响
IF 1.9 4区 材料科学 Q3 Materials Science Pub Date : 2023-01-01 DOI: 10.1515/secm-2022-0185
Lianzhi Zhang, Zhangyong Wu, Ting Wang, Z. Mo
Abstract Generally, 316L stainless steel instrumentation tubes working in a humid environment with a large amount of Cl− all the year round have serious corrosion problems, so the stainless steel substrate should be gradiently coated with nano-ZrO2/α-Al2O3 slurry. In this article, the slender 316L stainless steel tube was first ground by magnetorheological fluid and then coated with the slurry, which can not only increase the contact area between the coating and the substrate but also prevent the generation of new substances that have adversely affected the adhesion of the coating. The properties of the samples were characterized and analyzed; the results showed that the substrate ground by magnetorheological fluid is more favorable for bonding with coating under the grinding conditions that the speed of the tube is 210 rpm, magnetic induction intensity is 40.83 mT, and mass ratio of micron and submicron magnetic particles is 2.3. The coating prepared under the above conditions has uniform thickness, flat surface, and can better inhibit the diffusion of Cr of the substrate to its surface. It can be obtained from corrosion resistance analysis that the coating has the highest self-corrosion potential of −0.016 V and the lowest corrosion current density of 0.491 μA/cm2, which indicate that the coating has the strongest corrosion resistance. According to the composition analysis of the coating, the composition of the corroded coating is similar to that of the coating itself, but accompanied by a small amount of Fe, which indirectly indicates that the coating is relatively compact, the coating is well bonded with the substrate, and the coating can protect the substrate; thus, the service life of 316L stainless steel instrumentation tubes is extended.
摘要:316L不锈钢仪表管常年工作在Cl−含量较大的潮湿环境中,腐蚀问题严重,因此应在不锈钢基体上梯度涂覆纳米zro2 /α-Al2O3浆液。本文将细长的316L不锈钢管先用磁流变液研磨,再涂上浆液,既可以增加涂层与基材的接触面积,又可以防止产生对涂层附着力有不利影响的新物质。对样品的性能进行了表征和分析;结果表明:在管材转速为210 rpm、磁感应强度为40.83 mT、微米级和亚微米级磁性颗粒质量比为2.3的磨削条件下,磁流变液研磨的基体更有利于与涂层结合。在上述条件下制备的涂层厚度均匀,表面平整,能较好地抑制基体中Cr向其表面的扩散。耐蚀性分析表明,该涂层的自腐蚀电位最高为- 0.016 V,腐蚀电流密度最低为0.491 μA/cm2,具有较强的耐蚀性。根据对涂层的成分分析,被腐蚀涂层的成分与涂层本身的成分相似,但伴随有少量的铁,这间接表明涂层相对致密,涂层与基体结合良好,涂层能够保护基体;从而延长了316L不锈钢仪表管的使用寿命。
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引用次数: 0
A simulative study on the effect of friction coefficient and angle on failure behaviors of GLARE subjected to low-velocity impact 低速碰撞下摩擦系数和角度对眩光失效行为影响的仿真研究
IF 1.9 4区 材料科学 Q3 Materials Science Pub Date : 2023-01-01 DOI: 10.1515/secm-2022-0194
Peiyu You, H. Chen, Mingjie Li, Ye Wu
Abstract The aim of this paper is to study the effect of friction coefficient and impact angle on the failure behaviors of glass fiber reinforced aluminum laminates (GLARE) under the low-velocity impact (LVI) loading. A methodology is developed in commercial software ABAQUS/Explicit, and its accuracy is verified based on the results of comparison between simulation and experiment. In the simulation, Johnson–Cook flow stress model and surface-based cohesive behavior are carried out to simulate the damage evolution of aluminum alloy layers and delamination at the interface. Further, both the dynamic response history and damage mechanism characterization of these hybrid laminates are presented and compared carefully. Additionally, due to the advantage of simulation, it is accurate and easy to discuss on the evolution of the damage contour consisting of the damage degree of composite and metal layers as well as the interface between them. Finally, the influence rules of friction coefficient and angle on the failure behaviors of GLARE under LVI are drawn clearly.
摘要本文旨在研究摩擦系数和冲击角对玻璃纤维增强铝层压板(GLARE)在低速冲击(LVI)载荷下破坏行为的影响。在商业软件ABAQUS/Explicit中开发了一种方法,并通过仿真与实验对比验证了该方法的准确性。在模拟中,采用Johnson-Cook流动应力模型和基于表面的内聚行为来模拟铝合金层的损伤演化和界面处的分层。此外,对混合层合板的动态响应历史和损伤机理特征进行了详细的比较。此外,由于仿真的优势,可以准确、方便地讨论由复合材料层与金属层的损伤程度及其界面组成的损伤轮廓的演变过程。最后,明确了LVI下摩擦系数和角度对眩光失效行为的影响规律。
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引用次数: 0
Experimental study on the influence of high-frequency vibratory mixing on concrete performance 高频振动搅拌对混凝土性能影响的试验研究
IF 1.9 4区 材料科学 Q3 Materials Science Pub Date : 2023-01-01 DOI: 10.1515/secm-2022-0199
Zhao Wu, Wang Rongfang
Abstract The method and parameter of mixing are crucial to the quality of concrete, and ordinary vibratory mixing is beneficial to the performance of concrete, which has been explored in numerous studies. In order to study the influence of high-frequency vibratory mixing on the performance of concrete more accurately, ordinary concrete C40, C50 steel fiber concrete, and C60 high-strength concrete are selected to make reach experiments in the article. After determining the optimum mixing ratio, the contrast experiment on forced mixing and high-frequency vibratory mixing (which at a given frequency) was operated first, which is for studying the improvement of workability and mechanical properties of concrete by vibratory mixing and then exploring the change of concrete performance under different vibration frequency in slump test, compressive strength test, and freeze–thaw test. The results indicate that compared with forced mixing, the compressive strength and splitting tensile strength of concrete all have been proposed in different ages (3 days, 7 days, and 28 days) with vibratory concrete mixing, and C50 steel fiber concrete has the highest compressive strength improvement rate. There is a deviation in the mechanism of concrete in different ages, which is affected by high-frequency vibration. But in the context of the whole test, high-frequency vibratory mixing is helpful for the working properties, mechanical properties, and durability of the concrete. Within the scope of the frequency values in the test, the best vibration frequency for C40 ordinary concrete is 190 Hz, and in 212 Hz, C50 steel fiber concrete and C60 high-frequency concrete present the best performance.
搅拌的方法和参数对混凝土的质量至关重要,普通的振动搅拌有利于混凝土的性能,这一点已被大量的研究所探讨。为了更准确地研究高频振动搅拌对混凝土性能的影响,本文选取普通混凝土C40、C50钢纤维混凝土和C60高强混凝土进行了深度试验。在确定最佳配比后,首先进行强制搅拌与高频振动搅拌(在给定频率下)的对比试验,研究振动搅拌对混凝土和易性和力学性能的改善,然后在坍落度试验、抗压强度试验和冻融试验中探索不同振动频率下混凝土性能的变化。结果表明:与强制搅拌相比,振动搅拌不同龄期(3天、7天、28天)混凝土的抗压强度和劈裂抗拉强度均得到了提高,C50钢纤维混凝土抗压强度提高率最高;受高频振动的影响,不同龄期混凝土的机理存在偏差。但在整体试验的背景下,高频振动搅拌对混凝土的工作性能、力学性能和耐久性都是有利的。在试验频率值范围内,C40普通混凝土的最佳振动频率为190 Hz,在212 Hz范围内,C50钢纤维混凝土和C60高频混凝土表现最佳。
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引用次数: 1
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Science and Engineering of Composite Materials
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