Abstract In this study, a series of samples of C12A7 derivative was prepared by high temperature sintering in a sealed graphite crucible. The theoretical model of C12A7 derivatives with different carbon occupation numbers was established. The X-ray diffraction (XRD) theoretical calculation was carried out. The conjecture was verified to a certain extent through the comparison of the theoretical calculation of XRD with the experimental results. According to the calculation results, it was found that the XRD patterns of C12A7 and its derivatives changed regularly with the change in the occupation number in the crystal cage. Under the condition that the types of vacancy atoms remained unchanged, the more vacancy atoms occupied in C12A7 crystal, the higher the peak at 2θ = 33.35° in the diffraction pattern. It was also found that the higher the atomic number of vacancy atoms in C12A7 crystal, the higher the peak at 2θ = 33.35° in the diffraction pattern. The carbon occupation number of samples at different experimental temperatures was deduced. The results showed that the carbon occupancy of the samples prepared at 990, 1,353 and 1,680°C were 11, 4 and 8, respectively.
{"title":"XRD analysis determined crystal cage occupying number n of carbon anion substituted mayenite-type cage compound C12A7: nC","authors":"Cong Ji, Fan Gu","doi":"10.1515/secm-2022-0197","DOIUrl":"https://doi.org/10.1515/secm-2022-0197","url":null,"abstract":"Abstract In this study, a series of samples of C12A7 derivative was prepared by high temperature sintering in a sealed graphite crucible. The theoretical model of C12A7 derivatives with different carbon occupation numbers was established. The X-ray diffraction (XRD) theoretical calculation was carried out. The conjecture was verified to a certain extent through the comparison of the theoretical calculation of XRD with the experimental results. According to the calculation results, it was found that the XRD patterns of C12A7 and its derivatives changed regularly with the change in the occupation number in the crystal cage. Under the condition that the types of vacancy atoms remained unchanged, the more vacancy atoms occupied in C12A7 crystal, the higher the peak at 2θ = 33.35° in the diffraction pattern. It was also found that the higher the atomic number of vacancy atoms in C12A7 crystal, the higher the peak at 2θ = 33.35° in the diffraction pattern. The carbon occupation number of samples at different experimental temperatures was deduced. The results showed that the carbon occupancy of the samples prepared at 990, 1,353 and 1,680°C were 11, 4 and 8, respectively.","PeriodicalId":21480,"journal":{"name":"Science and Engineering of Composite Materials","volume":null,"pages":null},"PeriodicalIF":1.9,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48988550","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract This study provides an insight into the synthesis of high-strength and corrosion-inhibiting Mg-based biodegradable implant material by the addition of rare earth oxide material for acicular cruciate ligament reconstruction applications. The matrix has been reinforced with a naturally occurring mineral, hydroxyapatite (Ca5(PO4)3OH) and rare earth oxide, neodymium oxide (Nd2O3), in different concentrations. The mechanical response has been assessed by analyzing the samples’ microhardness, ultimate compressive, and tensile strength. In contrast, the corrosion rates were calculated using phosphate buffer saline solution by using different techniques under suitable physiological conditions. The microstructure characterization has been carried out by field emission scanning electron microscope, electron dispersive spectroscopy, optical microscopy, and X-ray diffraction techniques. Moreover, the surface properties of the composites were assessed using surface roughness and contact angle measurements. The sample showed maximum hardness at a concentration of 1.5% rare earth oxide. Moreover, the highest ultimate compressive and tensile strength followed the same order, i.e., 1.5% > 2% > 1%. In addition, the microstructure analysis revealed a refined microstructure and the formation of secondary intermetallic phases. Resistance to dislocation and grain growth barricading were the prominent features highlighted in the study for enhanced mechanical and corrosion properties. Moreover, the hydrogen evolution was lower for Mg–HA–1.5Nd2O3 samples, which was a clear indication of a reduced corrosion rate.
{"title":"Development of Mg-based metal matrix biomedical composites for acicular cruciate ligament fixation by reinforcing with rare earth oxide and hydroxyapatite – A mechanical, corrosion, and microstructural perspective","authors":"D. Aggarwal, V. Kumar, Siddharth R. Sharma","doi":"10.1515/secm-2022-0179","DOIUrl":"https://doi.org/10.1515/secm-2022-0179","url":null,"abstract":"Abstract This study provides an insight into the synthesis of high-strength and corrosion-inhibiting Mg-based biodegradable implant material by the addition of rare earth oxide material for acicular cruciate ligament reconstruction applications. The matrix has been reinforced with a naturally occurring mineral, hydroxyapatite (Ca5(PO4)3OH) and rare earth oxide, neodymium oxide (Nd2O3), in different concentrations. The mechanical response has been assessed by analyzing the samples’ microhardness, ultimate compressive, and tensile strength. In contrast, the corrosion rates were calculated using phosphate buffer saline solution by using different techniques under suitable physiological conditions. The microstructure characterization has been carried out by field emission scanning electron microscope, electron dispersive spectroscopy, optical microscopy, and X-ray diffraction techniques. Moreover, the surface properties of the composites were assessed using surface roughness and contact angle measurements. The sample showed maximum hardness at a concentration of 1.5% rare earth oxide. Moreover, the highest ultimate compressive and tensile strength followed the same order, i.e., 1.5% > 2% > 1%. In addition, the microstructure analysis revealed a refined microstructure and the formation of secondary intermetallic phases. Resistance to dislocation and grain growth barricading were the prominent features highlighted in the study for enhanced mechanical and corrosion properties. Moreover, the hydrogen evolution was lower for Mg–HA–1.5Nd2O3 samples, which was a clear indication of a reduced corrosion rate.","PeriodicalId":21480,"journal":{"name":"Science and Engineering of Composite Materials","volume":null,"pages":null},"PeriodicalIF":1.9,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43540261","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xi Wang, Juanfen Chen, Shuai Li, Pei Xiao, Kai Cheng, Yanhe Wang, Tianyong Zheng
Abstract Twisting is an important part in the production process of large package E-glass yarn. To derive the twisting process parameters of large package E-glass yarn, a method from the physical properties of bobbin yarn is proposed based on the study of the twisting principle of E-glass yarn. After unwinding the bobbin yarn and measuring its twist, loop pitch, and corresponding diameter, the calculation is completed according to the steps of first determining the descending speed of the traveler, then fitting the spindle speed data, and finally calculating the elevating speed of the traveler. The result is that the twisting spindle speed of D450 E-glass yarn with 31.8 T/m decreases from 5,015 to 4,550 rpm, the elevating speed of the traveler is 0.91 m/min, and the descending speed of the traveler is 1.50 m/min. The accuracy of the calculation is verified by monitoring the rotating speed of the roving cake and measuring the loop pitch of bobbin yarn in the twisting experiment. The result shows that the prediction error of this method is less than 1.1%, which can effectively derive the twisting process parameters of large package E-glass yarn, and provide a reference for the twisting process design scheme of glass fiber strand manufacturers.
{"title":"Method for deriving twisting process parameters of large package E-glass yarn by measuring physical properties of bobbin yarn","authors":"Xi Wang, Juanfen Chen, Shuai Li, Pei Xiao, Kai Cheng, Yanhe Wang, Tianyong Zheng","doi":"10.1515/secm-2022-0212","DOIUrl":"https://doi.org/10.1515/secm-2022-0212","url":null,"abstract":"Abstract Twisting is an important part in the production process of large package E-glass yarn. To derive the twisting process parameters of large package E-glass yarn, a method from the physical properties of bobbin yarn is proposed based on the study of the twisting principle of E-glass yarn. After unwinding the bobbin yarn and measuring its twist, loop pitch, and corresponding diameter, the calculation is completed according to the steps of first determining the descending speed of the traveler, then fitting the spindle speed data, and finally calculating the elevating speed of the traveler. The result is that the twisting spindle speed of D450 E-glass yarn with 31.8 T/m decreases from 5,015 to 4,550 rpm, the elevating speed of the traveler is 0.91 m/min, and the descending speed of the traveler is 1.50 m/min. The accuracy of the calculation is verified by monitoring the rotating speed of the roving cake and measuring the loop pitch of bobbin yarn in the twisting experiment. The result shows that the prediction error of this method is less than 1.1%, which can effectively derive the twisting process parameters of large package E-glass yarn, and provide a reference for the twisting process design scheme of glass fiber strand manufacturers.","PeriodicalId":21480,"journal":{"name":"Science and Engineering of Composite Materials","volume":null,"pages":null},"PeriodicalIF":1.9,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46198731","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract In this study, the dry–wet cycle test of chloride salt was carried out on aeolian sand concrete with different contents, and the chloride ion content in aeolian sand concrete was determined by taking powder from different depths on one side of the test block. And then combined with Monte Carlo stochastic statistical simulation and Weibull probability distribution function, the service life prediction model of aeolian sand concrete against chloride ion erosion is established. The results show that the free chloride ion content in aeolian sand concrete decreases with the increase in the depth from the surface of the specimen. At the same depth from the surface of the specimen, the free chloride ion content gradually increases with the increase in the number of dry–wet cycles. Through the analysis of life prediction, it is concluded that with the increase in aeolian sand content, the service life of aeolian sand concrete increases first and then decreases. The service life value of concrete with 75% aeolian sand content is the largest, and the greater the thickness of the protective layer, the more favorable the service life value.
{"title":"Chloride ion transport and service life prediction of aeolian sand concrete under dry–wet cycles","authors":"Wei Dong, Yajing Ji","doi":"10.1515/secm-2022-0188","DOIUrl":"https://doi.org/10.1515/secm-2022-0188","url":null,"abstract":"Abstract In this study, the dry–wet cycle test of chloride salt was carried out on aeolian sand concrete with different contents, and the chloride ion content in aeolian sand concrete was determined by taking powder from different depths on one side of the test block. And then combined with Monte Carlo stochastic statistical simulation and Weibull probability distribution function, the service life prediction model of aeolian sand concrete against chloride ion erosion is established. The results show that the free chloride ion content in aeolian sand concrete decreases with the increase in the depth from the surface of the specimen. At the same depth from the surface of the specimen, the free chloride ion content gradually increases with the increase in the number of dry–wet cycles. Through the analysis of life prediction, it is concluded that with the increase in aeolian sand content, the service life of aeolian sand concrete increases first and then decreases. The service life value of concrete with 75% aeolian sand content is the largest, and the greater the thickness of the protective layer, the more favorable the service life value.","PeriodicalId":21480,"journal":{"name":"Science and Engineering of Composite Materials","volume":null,"pages":null},"PeriodicalIF":1.9,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42912534","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract In order to improve the utilization value of recycled materials, the study considers recycled materials such as polyester/nylon/spandex as raw materials. Using polyester/polyamide/spandex as raw materials, the recycled polyester/polyamide/spandex mixed materials were first pretreated to obtain the pretreated mixed materials. Then, the pretreated mixed materials were evenly mixed with hydrogenated petroleum resin. The composite materials were prepared through extrusion and injection molding. By comparing the mechanical properties, the effects of different hydrogenated petroleum resins and their additives on the tensile strength, bending strength, impact strength, elongation at break, and bending modulus of the composites were investigated. And the microstructure of the fracture surface was characterized by scanning electron microscopy. The results showed that: (a) when the addition amount of hydrogenated C5 petroleum resin was 4.5%, the maximum impact strength and fracture elongation were 18.03 kJ/m 2 and 15.92%, respectively. (b) The maximum tensile strength, bending strength, and bending modulus could reach 22.9, 38.72, and 2217.9 MPa, when the addition amount of hydrogenated C9 petroleum resin was 4.5, 29.5, and 39.5%, respectively.
{"title":"Study on properties of recycled mixed polyester/nylon/spandex modified by hydrogenated petroleum resin","authors":"Xinmou Kuang, Minru Su, Liang Wang, Hao Li, Xiaolan Shen, Mengyun Yu, Yiran Wu","doi":"10.1515/secm-2022-0225","DOIUrl":"https://doi.org/10.1515/secm-2022-0225","url":null,"abstract":"Abstract In order to improve the utilization value of recycled materials, the study considers recycled materials such as polyester/nylon/spandex as raw materials. Using polyester/polyamide/spandex as raw materials, the recycled polyester/polyamide/spandex mixed materials were first pretreated to obtain the pretreated mixed materials. Then, the pretreated mixed materials were evenly mixed with hydrogenated petroleum resin. The composite materials were prepared through extrusion and injection molding. By comparing the mechanical properties, the effects of different hydrogenated petroleum resins and their additives on the tensile strength, bending strength, impact strength, elongation at break, and bending modulus of the composites were investigated. And the microstructure of the fracture surface was characterized by scanning electron microscopy. The results showed that: (a) when the addition amount of hydrogenated C5 petroleum resin was 4.5%, the maximum impact strength and fracture elongation were 18.03 kJ/m 2 and 15.92%, respectively. (b) The maximum tensile strength, bending strength, and bending modulus could reach 22.9, 38.72, and 2217.9 MPa, when the addition amount of hydrogenated C9 petroleum resin was 4.5, 29.5, and 39.5%, respectively.","PeriodicalId":21480,"journal":{"name":"Science and Engineering of Composite Materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135212008","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract In order to improve the chloride ion penetration resistance of supplementary cementitious materials (SCMs) in blended cement, this study optimizes the particle size distribution of cementitious components based on the Fuller model. Portland cement (PC), fly ash (FA), and ground granulated blast furnace slag (GGBFS) are successfully divided into four particle size ranges by precision air classifier, which are 0–8, 8–30, 30–50, and 50–80 μm, respectively. The optimum cementitious materials in four ranges based on 28-day compressive strength are determined by nine groups of orthogonal tests. The blended cement with optimal performance is obtained by GGBFS in 0–8 μm, PC in 8–30 μm, GGBFS in 30–50 μm, and FA in 50–80 μm. The results show that the blended cement with SCMs based on Fuller model have superior microstructure and chloride ion penetration resistance, which is due to their smaller pore size, a strong volcanic ash effect, and chloride ion binding ability. In addition, this research presents a novel approach for realizing the application of a large amount of SCMs in blended cement.
{"title":"Effect of particle size distribution on microstructure and chloride permeability of blended cement with supplementary cementitious materials","authors":"Ge Gao, Qiang Li, Hongjie Luo, Xiao Huang","doi":"10.1515/secm-2022-0226","DOIUrl":"https://doi.org/10.1515/secm-2022-0226","url":null,"abstract":"Abstract In order to improve the chloride ion penetration resistance of supplementary cementitious materials (SCMs) in blended cement, this study optimizes the particle size distribution of cementitious components based on the Fuller model. Portland cement (PC), fly ash (FA), and ground granulated blast furnace slag (GGBFS) are successfully divided into four particle size ranges by precision air classifier, which are 0–8, 8–30, 30–50, and 50–80 μm, respectively. The optimum cementitious materials in four ranges based on 28-day compressive strength are determined by nine groups of orthogonal tests. The blended cement with optimal performance is obtained by GGBFS in 0–8 μm, PC in 8–30 μm, GGBFS in 30–50 μm, and FA in 50–80 μm. The results show that the blended cement with SCMs based on Fuller model have superior microstructure and chloride ion penetration resistance, which is due to their smaller pore size, a strong volcanic ash effect, and chloride ion binding ability. In addition, this research presents a novel approach for realizing the application of a large amount of SCMs in blended cement.","PeriodicalId":21480,"journal":{"name":"Science and Engineering of Composite Materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135311332","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jing Li, Hongjiang Ren, Jiangtao Li, Liuchang Wang
Abstract In situ disulfide bond formation affords a new flexible dicarboxylic acid ligand of 3,3′-dithiobisbenzoic acid (3,3′-H 2 DTBA), which assembled with Co( ii ) ions under hydrothermal conditions, generating a novel metal–organic framework (MOF), namely, [Co(3,3′-DTBA) 2 (H 2 O) 2 ] n ( 1 ). This compound is assembled from layered structures, featuring weak interlayer interactions that can reduce pore blockage through relative sliding. The results of photocatalytic experiment indicate that MOF 1 is a good semiconducting material and it can function as photocatalyst for degrading methylene blue under the ultraviolet light irradiation. Cyclic experiments demonstrated its good stability and long-lasting photocatalytic performance, indicating its potential application value.
{"title":"In situ ligand synthesis affording a new Co(ii) MOF for photocatalytic application","authors":"Jing Li, Hongjiang Ren, Jiangtao Li, Liuchang Wang","doi":"10.1515/secm-2022-0229","DOIUrl":"https://doi.org/10.1515/secm-2022-0229","url":null,"abstract":"Abstract In situ disulfide bond formation affords a new flexible dicarboxylic acid ligand of 3,3′-dithiobisbenzoic acid (3,3′-H 2 DTBA), which assembled with Co( ii ) ions under hydrothermal conditions, generating a novel metal–organic framework (MOF), namely, [Co(3,3′-DTBA) 2 (H 2 O) 2 ] n ( 1 ). This compound is assembled from layered structures, featuring weak interlayer interactions that can reduce pore blockage through relative sliding. The results of photocatalytic experiment indicate that MOF 1 is a good semiconducting material and it can function as photocatalyst for degrading methylene blue under the ultraviolet light irradiation. Cyclic experiments demonstrated its good stability and long-lasting photocatalytic performance, indicating its potential application value.","PeriodicalId":21480,"journal":{"name":"Science and Engineering of Composite Materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135610797","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract Generally, 316L stainless steel instrumentation tubes working in a humid environment with a large amount of Cl− all the year round have serious corrosion problems, so the stainless steel substrate should be gradiently coated with nano-ZrO2/α-Al2O3 slurry. In this article, the slender 316L stainless steel tube was first ground by magnetorheological fluid and then coated with the slurry, which can not only increase the contact area between the coating and the substrate but also prevent the generation of new substances that have adversely affected the adhesion of the coating. The properties of the samples were characterized and analyzed; the results showed that the substrate ground by magnetorheological fluid is more favorable for bonding with coating under the grinding conditions that the speed of the tube is 210 rpm, magnetic induction intensity is 40.83 mT, and mass ratio of micron and submicron magnetic particles is 2.3. The coating prepared under the above conditions has uniform thickness, flat surface, and can better inhibit the diffusion of Cr of the substrate to its surface. It can be obtained from corrosion resistance analysis that the coating has the highest self-corrosion potential of −0.016 V and the lowest corrosion current density of 0.491 μA/cm2, which indicate that the coating has the strongest corrosion resistance. According to the composition analysis of the coating, the composition of the corroded coating is similar to that of the coating itself, but accompanied by a small amount of Fe, which indirectly indicates that the coating is relatively compact, the coating is well bonded with the substrate, and the coating can protect the substrate; thus, the service life of 316L stainless steel instrumentation tubes is extended.
{"title":"The influence of preparation of nano-ZrO2/α-Al2O3 gradient coating on the corrosion resistance of 316L stainless steel substrate","authors":"Lianzhi Zhang, Zhangyong Wu, Ting Wang, Z. Mo","doi":"10.1515/secm-2022-0185","DOIUrl":"https://doi.org/10.1515/secm-2022-0185","url":null,"abstract":"Abstract Generally, 316L stainless steel instrumentation tubes working in a humid environment with a large amount of Cl− all the year round have serious corrosion problems, so the stainless steel substrate should be gradiently coated with nano-ZrO2/α-Al2O3 slurry. In this article, the slender 316L stainless steel tube was first ground by magnetorheological fluid and then coated with the slurry, which can not only increase the contact area between the coating and the substrate but also prevent the generation of new substances that have adversely affected the adhesion of the coating. The properties of the samples were characterized and analyzed; the results showed that the substrate ground by magnetorheological fluid is more favorable for bonding with coating under the grinding conditions that the speed of the tube is 210 rpm, magnetic induction intensity is 40.83 mT, and mass ratio of micron and submicron magnetic particles is 2.3. The coating prepared under the above conditions has uniform thickness, flat surface, and can better inhibit the diffusion of Cr of the substrate to its surface. It can be obtained from corrosion resistance analysis that the coating has the highest self-corrosion potential of −0.016 V and the lowest corrosion current density of 0.491 μA/cm2, which indicate that the coating has the strongest corrosion resistance. According to the composition analysis of the coating, the composition of the corroded coating is similar to that of the coating itself, but accompanied by a small amount of Fe, which indirectly indicates that the coating is relatively compact, the coating is well bonded with the substrate, and the coating can protect the substrate; thus, the service life of 316L stainless steel instrumentation tubes is extended.","PeriodicalId":21480,"journal":{"name":"Science and Engineering of Composite Materials","volume":null,"pages":null},"PeriodicalIF":1.9,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45164937","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract The method and parameter of mixing are crucial to the quality of concrete, and ordinary vibratory mixing is beneficial to the performance of concrete, which has been explored in numerous studies. In order to study the influence of high-frequency vibratory mixing on the performance of concrete more accurately, ordinary concrete C40, C50 steel fiber concrete, and C60 high-strength concrete are selected to make reach experiments in the article. After determining the optimum mixing ratio, the contrast experiment on forced mixing and high-frequency vibratory mixing (which at a given frequency) was operated first, which is for studying the improvement of workability and mechanical properties of concrete by vibratory mixing and then exploring the change of concrete performance under different vibration frequency in slump test, compressive strength test, and freeze–thaw test. The results indicate that compared with forced mixing, the compressive strength and splitting tensile strength of concrete all have been proposed in different ages (3 days, 7 days, and 28 days) with vibratory concrete mixing, and C50 steel fiber concrete has the highest compressive strength improvement rate. There is a deviation in the mechanism of concrete in different ages, which is affected by high-frequency vibration. But in the context of the whole test, high-frequency vibratory mixing is helpful for the working properties, mechanical properties, and durability of the concrete. Within the scope of the frequency values in the test, the best vibration frequency for C40 ordinary concrete is 190 Hz, and in 212 Hz, C50 steel fiber concrete and C60 high-frequency concrete present the best performance.
{"title":"Experimental study on the influence of high-frequency vibratory mixing on concrete performance","authors":"Zhao Wu, Wang Rongfang","doi":"10.1515/secm-2022-0199","DOIUrl":"https://doi.org/10.1515/secm-2022-0199","url":null,"abstract":"Abstract The method and parameter of mixing are crucial to the quality of concrete, and ordinary vibratory mixing is beneficial to the performance of concrete, which has been explored in numerous studies. In order to study the influence of high-frequency vibratory mixing on the performance of concrete more accurately, ordinary concrete C40, C50 steel fiber concrete, and C60 high-strength concrete are selected to make reach experiments in the article. After determining the optimum mixing ratio, the contrast experiment on forced mixing and high-frequency vibratory mixing (which at a given frequency) was operated first, which is for studying the improvement of workability and mechanical properties of concrete by vibratory mixing and then exploring the change of concrete performance under different vibration frequency in slump test, compressive strength test, and freeze–thaw test. The results indicate that compared with forced mixing, the compressive strength and splitting tensile strength of concrete all have been proposed in different ages (3 days, 7 days, and 28 days) with vibratory concrete mixing, and C50 steel fiber concrete has the highest compressive strength improvement rate. There is a deviation in the mechanism of concrete in different ages, which is affected by high-frequency vibration. But in the context of the whole test, high-frequency vibratory mixing is helpful for the working properties, mechanical properties, and durability of the concrete. Within the scope of the frequency values in the test, the best vibration frequency for C40 ordinary concrete is 190 Hz, and in 212 Hz, C50 steel fiber concrete and C60 high-frequency concrete present the best performance.","PeriodicalId":21480,"journal":{"name":"Science and Engineering of Composite Materials","volume":null,"pages":null},"PeriodicalIF":1.9,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47130741","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ran Liu, G. Shen, Peng-fei Zhang, Sa Yang, Wei Zhou, Chaolin Ye, Qing Li
Abstract Understanding the influence of delamination defects on the damage evolution behavior of carbon-fiber-reinforced polymers (CFRPs) is crucial to improve their engineering applications. This study examined the flexural damage behaviors of CFRP composites by using a combination of acoustic emission (AE) and X-ray micro-computed tomography (micro-CT). Four specimens with different delamination defects and 0.1 wt% cellulose nanofibers (CNFs) were subjected to three-point bending tests. AE was employed to monitor the loading process, and then, micro-CT was utilized to detect the internal damage. The results showed that for the specimens with preset delamination defects near the surface, CNF-reinforced specimen exhibited no obvious enhancement effect on bending strength, and its cumulative acoustic energy decreased by 28% compared with that of CFRP specimens. For the specimen with preset delamination damage in the middle position, CNFs had an obvious enhancement effect on mechanical behavior, and the cumulative acoustic energy decreased by 43%. No obvious kink band was observed in the CNF-reinforced specimens, and during crack propagation, causing cracking and delamination damage was difficult. The results of micro-CT are consistent with those of AE. The results combined the combination of AE and micro-CT reflect the superiority of the hybrid detection system.
{"title":"Effects of cellulose nanofibers on flexural behavior of carbon-fiber-reinforced polymer composites with delamination","authors":"Ran Liu, G. Shen, Peng-fei Zhang, Sa Yang, Wei Zhou, Chaolin Ye, Qing Li","doi":"10.1515/secm-2022-0180","DOIUrl":"https://doi.org/10.1515/secm-2022-0180","url":null,"abstract":"Abstract Understanding the influence of delamination defects on the damage evolution behavior of carbon-fiber-reinforced polymers (CFRPs) is crucial to improve their engineering applications. This study examined the flexural damage behaviors of CFRP composites by using a combination of acoustic emission (AE) and X-ray micro-computed tomography (micro-CT). Four specimens with different delamination defects and 0.1 wt% cellulose nanofibers (CNFs) were subjected to three-point bending tests. AE was employed to monitor the loading process, and then, micro-CT was utilized to detect the internal damage. The results showed that for the specimens with preset delamination defects near the surface, CNF-reinforced specimen exhibited no obvious enhancement effect on bending strength, and its cumulative acoustic energy decreased by 28% compared with that of CFRP specimens. For the specimen with preset delamination damage in the middle position, CNFs had an obvious enhancement effect on mechanical behavior, and the cumulative acoustic energy decreased by 43%. No obvious kink band was observed in the CNF-reinforced specimens, and during crack propagation, causing cracking and delamination damage was difficult. The results of micro-CT are consistent with those of AE. The results combined the combination of AE and micro-CT reflect the superiority of the hybrid detection system.","PeriodicalId":21480,"journal":{"name":"Science and Engineering of Composite Materials","volume":null,"pages":null},"PeriodicalIF":1.9,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42367051","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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