{"title":"Nanomaterials, Advanced Materials and Protective Coatings","authors":"Kazuo Umemura, Ramesh K. Agarwal, Ian McAndrew","doi":"10.4028/b-kto2dp","DOIUrl":"https://doi.org/10.4028/b-kto2dp","url":null,"abstract":"","PeriodicalId":21754,"journal":{"name":"Solid State Phenomena","volume":"62 12","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140234184","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Paul Kamugisha, Mohamed F.M. Fahmy, Ayman Ali Ahmed Nada, M. Gepreel
The control of the residually stressed γ’-FCC phase in the grain boundaries that affects super-elasticity in the promising Fe-Mn-Al-Ni shape memory alloy (SMA) and grain size enhancement was an epitome for research in the current study. New composition Fe-33Mn-17Al-8.5Ni (at. %) was designed with the help of thermocalc software TCFE 11 database, produced in an electric arc furnace under an argon atmosphere and systematically investigated in the as-cast and heat-treated conditions. Characterization was performed using optical microscopy, X-ray diffraction measurements (XRD), and compression tests. Controlling the cooling conditions after heat treatment (HT) with high flowrate air cooling helped to reduce on the formation of the detrimental phase, γ’ at the grain boundaries as well as observed some grain growth in the microstructure without necessarily causing cracking as reported previously with quenching in cold water. The yield strength depicting the stress-induced martensitic transformation was 925 MPa for as cast and 909 MPa upon heat treatment. From cyclic compression loading/deloading training, a recovery strain of 2.1% and 2.3% was attained at 800 MPa maximum stress in the as-cast and heat treated-conditions, respectively.
{"title":"Microstructure and Super-Elasticity of Fe-33Mn-17Al-8.5Ni (at. %) Alloy for Structural Applications","authors":"Paul Kamugisha, Mohamed F.M. Fahmy, Ayman Ali Ahmed Nada, M. Gepreel","doi":"10.4028/p-ltj0kd","DOIUrl":"https://doi.org/10.4028/p-ltj0kd","url":null,"abstract":"The control of the residually stressed γ’-FCC phase in the grain boundaries that affects super-elasticity in the promising Fe-Mn-Al-Ni shape memory alloy (SMA) and grain size enhancement was an epitome for research in the current study. New composition Fe-33Mn-17Al-8.5Ni (at. %) was designed with the help of thermocalc software TCFE 11 database, produced in an electric arc furnace under an argon atmosphere and systematically investigated in the as-cast and heat-treated conditions. Characterization was performed using optical microscopy, X-ray diffraction measurements (XRD), and compression tests. Controlling the cooling conditions after heat treatment (HT) with high flowrate air cooling helped to reduce on the formation of the detrimental phase, γ’ at the grain boundaries as well as observed some grain growth in the microstructure without necessarily causing cracking as reported previously with quenching in cold water. The yield strength depicting the stress-induced martensitic transformation was 925 MPa for as cast and 909 MPa upon heat treatment. From cyclic compression loading/deloading training, a recovery strain of 2.1% and 2.3% was attained at 800 MPa maximum stress in the as-cast and heat treated-conditions, respectively.","PeriodicalId":21754,"journal":{"name":"Solid State Phenomena","volume":"49 29","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140231013","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In this study, various NR:EPDM:EVA rubber foams were prepared. The ratios of NR:EPDM:EVA were at 50:20:30 and 50:10:40. The amounts of blowing agent, dinitrosopentamethylenetetramine (or Supercell DP) were 5, 6, and 7 part per hundred of rubber (phr). The vulcanizing agent, dicumyl peroxide (or DCP) loadings were at 0.7 and 1 phr. The influence of rubber formula on the performance of the obtained rubber foam was discussed here. The results showed that increasing EVA proportion and Supercell DP loading and decreasing DCP loading led to the decrease in density, thus giving the lower thermal conductive rubber foam which was suitable for using as an insulating ceiling board. However, the above condition gave the rubber foam with slightly inferior mechanical properties including lower hardness and higher % compression set.
{"title":"Effect of Rubber Formula on Performance of Natural Rubber Based Foam for Insulating Ceiling Board Application","authors":"Natyada Jantawong, K. Boonkerd, K. Hancharoen","doi":"10.4028/p-2hhh04","DOIUrl":"https://doi.org/10.4028/p-2hhh04","url":null,"abstract":"In this study, various NR:EPDM:EVA rubber foams were prepared. The ratios of NR:EPDM:EVA were at 50:20:30 and 50:10:40. The amounts of blowing agent, dinitrosopentamethylenetetramine (or Supercell DP) were 5, 6, and 7 part per hundred of rubber (phr). The vulcanizing agent, dicumyl peroxide (or DCP) loadings were at 0.7 and 1 phr. The influence of rubber formula on the performance of the obtained rubber foam was discussed here. The results showed that increasing EVA proportion and Supercell DP loading and decreasing DCP loading led to the decrease in density, thus giving the lower thermal conductive rubber foam which was suitable for using as an insulating ceiling board. However, the above condition gave the rubber foam with slightly inferior mechanical properties including lower hardness and higher % compression set.","PeriodicalId":21754,"journal":{"name":"Solid State Phenomena","volume":"69 9","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140234278","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In this paper, a novel lightweight and low-cost Al35Mg20Zn15Cu10Si20 at. % (Al26.17Mg13.47Zn27.18Cu17.61Si15.57 wt.%) has been successfully designed, produced, and characterized. The thermophysical parameters were used to understand the phases associated with this alloy that show a low density of 3.42 g/cm3. The designed alloy was manufactured using both the arc and the muffle furnace. The alloy was characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM) equipped with an energy dispersive spectrometer (EDS). The alloy is characterized by a multiphase microstructure with three major phases including Mg2Si intermetallic phase and eutectic. The volume fraction of the eutectic and the intermetallic phases are 37.83 and 34.99 respectively. The heat capacities of the alloy were also determined by means of differential scanning calorimetry (DSC). The alloy provides a high latent heat of up to 124 J/g, which is one of the highest among the high-temperature metallic materials. The present work provides valuable information for researchers wishing to design and manufacture industrial-grade high-entropy alloys (HEAs).
{"title":"Phase Formation of Novel Al-Mg-Zn-Cu-Si Lightweight High Entropy Alloy","authors":"Godson Nyaforkpa, Mohamed Emam, M. Gepreel","doi":"10.4028/p-uia1wc","DOIUrl":"https://doi.org/10.4028/p-uia1wc","url":null,"abstract":"In this paper, a novel lightweight and low-cost Al35Mg20Zn15Cu10Si20 at. % (Al26.17Mg13.47Zn27.18Cu17.61Si15.57 wt.%) has been successfully designed, produced, and characterized. The thermophysical parameters were used to understand the phases associated with this alloy that show a low density of 3.42 g/cm3. The designed alloy was manufactured using both the arc and the muffle furnace. The alloy was characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM) equipped with an energy dispersive spectrometer (EDS). The alloy is characterized by a multiphase microstructure with three major phases including Mg2Si intermetallic phase and eutectic. The volume fraction of the eutectic and the intermetallic phases are 37.83 and 34.99 respectively. The heat capacities of the alloy were also determined by means of differential scanning calorimetry (DSC). The alloy provides a high latent heat of up to 124 J/g, which is one of the highest among the high-temperature metallic materials. The present work provides valuable information for researchers wishing to design and manufacture industrial-grade high-entropy alloys (HEAs).","PeriodicalId":21754,"journal":{"name":"Solid State Phenomena","volume":"88 8","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140231994","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Carlos Martinez Llaccohua, William Cordero Escobar, Rebeca Salvador Reyes, Grimaldo Quispe Santivañez
The present research aimed to evaluate the effect of nickel-based electrochemical metallization (EMNi) on the quality and performance of electric motor components, compared to high-velocity oxy-fuel (HVOF) thermal spray coating, the most widely used coating in the mining industry. The experiment was conducted using motor components comprised of 4340 VCN steel, 4140 VCL steel, 1045 steel, and stainless steel, which underwent both treatments. The surface temperature of the components was monitored during the processing stage, followed by evaluations of their Rockwell hardness (HRC) and surface characteristics (taper, ovality, parallelism, finish, wear) at the onset (day 0) and after 2 years of use the results indicate that EMNi delivers electric motor components with superior finishes and extended warranty and service life in comparison to HVOF.
{"title":"Electrochemical Metallization for Enhancing the Quality and Performance of Electric Motor","authors":"Carlos Martinez Llaccohua, William Cordero Escobar, Rebeca Salvador Reyes, Grimaldo Quispe Santivañez","doi":"10.4028/p-4zyngq","DOIUrl":"https://doi.org/10.4028/p-4zyngq","url":null,"abstract":"The present research aimed to evaluate the effect of nickel-based electrochemical metallization (EMNi) on the quality and performance of electric motor components, compared to high-velocity oxy-fuel (HVOF) thermal spray coating, the most widely used coating in the mining industry. The experiment was conducted using motor components comprised of 4340 VCN steel, 4140 VCL steel, 1045 steel, and stainless steel, which underwent both treatments. The surface temperature of the components was monitored during the processing stage, followed by evaluations of their Rockwell hardness (HRC) and surface characteristics (taper, ovality, parallelism, finish, wear) at the onset (day 0) and after 2 years of use the results indicate that EMNi delivers electric motor components with superior finishes and extended warranty and service life in comparison to HVOF.","PeriodicalId":21754,"journal":{"name":"Solid State Phenomena","volume":"16 2","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140232729","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Baoleer Baoleer, Yue Xiang, Li Shi, Wen Tao Sun, Zhi Xiong Wu, Rong Jin Huang, Lai Feng Li
ITER IF coils and the German WX-7 star simulator fusion reactor both use cyanate ester/epoxy resin as the matrix material for their insulation structure. The main reason is that cyanate ester/epoxy resin insulation materials have low-temperature mechanics and radiation resistance, and have extremely low rheological properties and long applicability periods. However, high-energy polymerization will occur when the two are mixed, releasing a huge amount of heat. This study used different molds to prepare cyanate ester/epoxy resin (mass ratio 4:6), and used DSC (Differential Calorimetry Scanning) thermal analyzer and temperature monitoring to study the curing behavior and thermal stability of cyanate ester-modified epoxy resin-based materials. After multiple optimizations, the resin was completely cured within a controllable range, and there was no significant change in the glass transition temperature before and after adjustment.
{"title":"Analysis of the Curing Behavior of Cyanate/Epoxy Resins for Fusion Magnets","authors":"Baoleer Baoleer, Yue Xiang, Li Shi, Wen Tao Sun, Zhi Xiong Wu, Rong Jin Huang, Lai Feng Li","doi":"10.4028/p-d57zjm","DOIUrl":"https://doi.org/10.4028/p-d57zjm","url":null,"abstract":"ITER IF coils and the German WX-7 star simulator fusion reactor both use cyanate ester/epoxy resin as the matrix material for their insulation structure. The main reason is that cyanate ester/epoxy resin insulation materials have low-temperature mechanics and radiation resistance, and have extremely low rheological properties and long applicability periods. However, high-energy polymerization will occur when the two are mixed, releasing a huge amount of heat. This study used different molds to prepare cyanate ester/epoxy resin (mass ratio 4:6), and used DSC (Differential Calorimetry Scanning) thermal analyzer and temperature monitoring to study the curing behavior and thermal stability of cyanate ester-modified epoxy resin-based materials. After multiple optimizations, the resin was completely cured within a controllable range, and there was no significant change in the glass transition temperature before and after adjustment.","PeriodicalId":21754,"journal":{"name":"Solid State Phenomena","volume":"25 5","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140232890","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
S. Tsai, Wei Wu, Hiroyoshi Sota, T. Hirogaki, E. Aoyama
An improved melt-blowing method have developed to manufacture the organic nonwoven nanofibers through our previous study. As a parallel phase, this study explores the potential of polylactic acid (PLA) nanofibers as a plant growth substrate, emphasizing the unique properties and performance when mixed with pellets. Preliminary experiments comparing different fiber materials, cultivated crops, and fiber diameters demonstrate the favorable characteristics of PLA, such as wettability and growth promotion. Comparative experiment with rockwool, a commonly used medium, shows that PLA nanofibers exhibit superior growth performance. On the other hand, a solidified PLA medium is produced and tested. Hydroponic tests using solidified medium configurations with varying fiber diameters and soil conditioners further confirm the benefits of PLA as a medium for plant growth. The findings suggest that PLA nanofibers have the potential to revolutionize cultivation practices, providing sustainable and environmentally friendly alternatives to traditional substrates.
{"title":"Investigation of Polylactic Acid Nanofibers as Enhanced Plant Growth Medium by Improved Melt-Blowing Method","authors":"S. Tsai, Wei Wu, Hiroyoshi Sota, T. Hirogaki, E. Aoyama","doi":"10.4028/p-fap6yj","DOIUrl":"https://doi.org/10.4028/p-fap6yj","url":null,"abstract":"An improved melt-blowing method have developed to manufacture the organic nonwoven nanofibers through our previous study. As a parallel phase, this study explores the potential of polylactic acid (PLA) nanofibers as a plant growth substrate, emphasizing the unique properties and performance when mixed with pellets. Preliminary experiments comparing different fiber materials, cultivated crops, and fiber diameters demonstrate the favorable characteristics of PLA, such as wettability and growth promotion. Comparative experiment with rockwool, a commonly used medium, shows that PLA nanofibers exhibit superior growth performance. On the other hand, a solidified PLA medium is produced and tested. Hydroponic tests using solidified medium configurations with varying fiber diameters and soil conditioners further confirm the benefits of PLA as a medium for plant growth. The findings suggest that PLA nanofibers have the potential to revolutionize cultivation practices, providing sustainable and environmentally friendly alternatives to traditional substrates.","PeriodicalId":21754,"journal":{"name":"Solid State Phenomena","volume":"348 6","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140232937","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Balkar Singh, Sehijpal Singh, V. Aggarwal, Gurpreet Singh
Due to their numerous applications in the aerospace, chemical, and nuclear power industries, environmentally responsible superalloy machining is a major problem in the current production environment. Additionally, Ni-based superalloys are regarded as difficult to manufacture because of their great strength under hot and chemically reactive settings. Therefore, it is necessary to machine these materials using adequate cooling and lubricating solutions. Current study has been based on the optimisation and modelling of turning Hastelloy C-276 under dry, flood, and least lubrication system. A Taguchi L-9 arrangement was used as plan of experiment and modeling was enabled through ANOVA, regression analysis and Taguchi optimization. The results depicted optimal parameters for surface roughness and temperature at v2-f1-d1-CE3 and v1-f2-d1-CE3. Likewise, for CRC and shear angle the best combination was observed at v3-f3-d2-CE2. From ANOVA analysis, the benefaction of C.E, depth of cut and feed rate on S.R been listed as 46.70%, 40.44% and 10.66%. Likewise, for temperature cutting speed has benefaction of (53.09%), cooling environment (23.94%), depth of cut (6.10%) and feed rate 5.49% . In similar fashion, CRC and Shear angle were influenced by feed rate and cutting speed having contribution of 62.89% and 5.15% respectively. Furthermore, minimum standard error between the fitted and observed values for S.R., temperature, CRC, and shear angle were calculated as 0.0149, 7.66, 0.267, and 1.80 units. Finally, the marginal reduction of cutting temperature and surface roughness through utilization of MQL implies the sustainable machining conditions.
{"title":"Modeling and Optimization of Turning Hastelloy C-276 under Sustainable Machining Environments","authors":"Balkar Singh, Sehijpal Singh, V. Aggarwal, Gurpreet Singh","doi":"10.4028/p-bj6vjw","DOIUrl":"https://doi.org/10.4028/p-bj6vjw","url":null,"abstract":"Due to their numerous applications in the aerospace, chemical, and nuclear power industries, environmentally responsible superalloy machining is a major problem in the current production environment. Additionally, Ni-based superalloys are regarded as difficult to manufacture because of their great strength under hot and chemically reactive settings. Therefore, it is necessary to machine these materials using adequate cooling and lubricating solutions. Current study has been based on the optimisation and modelling of turning Hastelloy C-276 under dry, flood, and least lubrication system. A Taguchi L-9 arrangement was used as plan of experiment and modeling was enabled through ANOVA, regression analysis and Taguchi optimization. The results depicted optimal parameters for surface roughness and temperature at v2-f1-d1-CE3 and v1-f2-d1-CE3. Likewise, for CRC and shear angle the best combination was observed at v3-f3-d2-CE2. From ANOVA analysis, the benefaction of C.E, depth of cut and feed rate on S.R been listed as 46.70%, 40.44% and 10.66%. Likewise, for temperature cutting speed has benefaction of (53.09%), cooling environment (23.94%), depth of cut (6.10%) and feed rate 5.49% . In similar fashion, CRC and Shear angle were influenced by feed rate and cutting speed having contribution of 62.89% and 5.15% respectively. Furthermore, minimum standard error between the fitted and observed values for S.R., temperature, CRC, and shear angle were calculated as 0.0149, 7.66, 0.267, and 1.80 units. Finally, the marginal reduction of cutting temperature and surface roughness through utilization of MQL implies the sustainable machining conditions.","PeriodicalId":21754,"journal":{"name":"Solid State Phenomena","volume":"293 9","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140233287","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
We present a theoretical study of the optical absorption of the group-V transition-metal dichalcogenids TaX2 (X = S, Se) by using the Wannier tight-binding Hamiltonian method. The absorption spectra show diverse and interesting features, including dominant peaks and shoulder-like structures. We provide an in-depth discussion on the optical spectral structures based on the energy dispersion and density of states. This work can advance the understanding of optical properties of two-dimensional materials which is important in the search for proper candidates for next-generation electronic devices.
我们采用 Wannier 紧约束哈密顿方法，对 V 族过渡金属二钙钛矿 TaX2（X = S、Se）的光吸收进行了理论研究。吸收光谱显示出多种有趣的特征，包括主峰和肩状结构。我们根据能量弥散和态密度对光学光谱结构进行了深入讨论。这项工作可以促进对二维材料光学特性的理解，这对寻找下一代电子器件的合适候选材料非常重要。
{"title":"Optical Absorption of TaS2 and TaSe2 Transition-Metal Dichalcogenides","authors":"T. Do, P. Shih, G. Gumbs","doi":"10.4028/p-2afd0s","DOIUrl":"https://doi.org/10.4028/p-2afd0s","url":null,"abstract":"We present a theoretical study of the optical absorption of the group-V transition-metal dichalcogenids TaX2 (X = S, Se) by using the Wannier tight-binding Hamiltonian method. The absorption spectra show diverse and interesting features, including dominant peaks and shoulder-like structures. We provide an in-depth discussion on the optical spectral structures based on the energy dispersion and density of states. This work can advance the understanding of optical properties of two-dimensional materials which is important in the search for proper candidates for next-generation electronic devices.","PeriodicalId":21754,"journal":{"name":"Solid State Phenomena","volume":"11 4","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140232736","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
L. Rumiyanti, Shania Garcia, Muhammad Mahfudz Fauzi Syamsuri, Ronius Marjunus, N. Istiqomah, Chotimah Chotimah, E. Suharyadi
This work identifies the effect of loading benzotriazole (BTA) on mesoporous silica nanoparticles (MSN) as an initial step in preparing a self-healing corrosion-protective coating with environmentally friendly precursors, rice husk, which advantages cheaper, renewable, and contains relatively high silica. This research uses the sol-gel method to synthesize MSN. Based on the result, it is known that the loading of BTA strongly affects the porosity properties of these nanoparticles. The pore sizes increase as the surface areas and pore volumes decrease. However, the silicone composition shrinks. Based on pore size, it is known that all the samples in this work were mesoporous materials (over 2 nm) with spherical and globular morphologies (like coral reefs).
{"title":"Characteristics of Mesoporous Silica Nanoparticles-Benzotriazole (MSN-BTA) Using Rice Husk as an Environmentally Friendly Precursor","authors":"L. Rumiyanti, Shania Garcia, Muhammad Mahfudz Fauzi Syamsuri, Ronius Marjunus, N. Istiqomah, Chotimah Chotimah, E. Suharyadi","doi":"10.4028/p-81peok","DOIUrl":"https://doi.org/10.4028/p-81peok","url":null,"abstract":"This work identifies the effect of loading benzotriazole (BTA) on mesoporous silica nanoparticles (MSN) as an initial step in preparing a self-healing corrosion-protective coating with environmentally friendly precursors, rice husk, which advantages cheaper, renewable, and contains relatively high silica. This research uses the sol-gel method to synthesize MSN. Based on the result, it is known that the loading of BTA strongly affects the porosity properties of these nanoparticles. The pore sizes increase as the surface areas and pore volumes decrease. However, the silicone composition shrinks. Based on pore size, it is known that all the samples in this work were mesoporous materials (over 2 nm) with spherical and globular morphologies (like coral reefs).","PeriodicalId":21754,"journal":{"name":"Solid State Phenomena","volume":"109 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140234008","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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