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Breaks in Hall-Petch Relationship in Magnesium 镁中霍尔-萃取关系的断裂
Pub Date : 2023-12-05 DOI: 10.4028/p-8qxhof
Amanda P. Carvalho, R. Figueiredo
Magnesium and its alloys display a non-usual relationship between flow stress and grain size at room temperature. Breaks in the Hall-Petch relationship have been reported in the literature. Inverse Hall-Petch behavior in which flow stress reduces with grain size decreasing has also been reported in pure magnesium and magnesium alloys with ultrafine and nanocrystalline structures. The present overview discusses these effects in terms of controlling deformation mechanisms. The distinct strength observed in pure magnesium and magnesium alloys with ultrafine grained structure is also discussed. It is shown that experimental data for fine and ultrafine grained magnesium alloys agree with a model suggested recently based on the mechanism of grain boundary sliding. It is also exhibited that the stability of the grain structure might control the strength of ultrafine grained samples.
在室温下,镁及其合金的流变应力与晶粒尺寸之间表现出不同寻常的关系。文献中已经报道了Hall-Petch关系的破裂。在具有超细和纳米晶结构的纯镁和镁合金中也发现了流动应力随晶粒尺寸减小而减小的逆Hall-Petch行为。本综述从控制变形机制的角度讨论了这些影响。还讨论了纯镁和超细晶镁合金的明显强度。结果表明,细晶和超细晶镁合金的实验数据与最近提出的基于晶界滑动机制的模型一致。晶粒结构的稳定性可能是控制超细晶试样强度的重要因素。
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引用次数: 0
Defects-Driven Plasticity: Rationalization Based on Notch Strengthening and Continuous Damage Mechanics 缺陷驱动塑性:基于切口强化和连续损伤力学的合理化建议
Pub Date : 2023-12-05 DOI: 10.4028/p-de4q1j
G. Angella, F. Zanardi
A novel procedure for material quality assessment developed for castings like ductile irons and Al alloys, is based on the analysis of tensile strain hardening through dislocation-density-related constitutive equation, and consists of plotting the Voce equation parameters found through modeling the tensile flow curves with the Voce constitutive equation. In sound materials the Voce parameters have a regular trend, consistent with the physical meaning of the dislocation-density-related Voce constitutive equation. The Voce parameters identify a regular trend also in defective materials, even if defects and metallurgical discontinuities might be expected to add a random and unpredictable component to the plastic behavior. This unexpected regular behavior in defective materials has been called as Defects-Driven Plasticity (DDP), and its rationalization seems to be possible by coupling the concepts of Notch Strengthening (NS) of defects, and stable ductile fracture propagation of the Continuous Damage Mechanics (CDM). The rationalization of DDP and the experimental findings to support, are here reported in high Silicon strengthened ductile irons.
基于位错-密度相关本构方程对拉伸应变硬化的分析,利用Voce本构方程对拉伸流动曲线进行建模,绘制出Voce方程参数,为球墨铸铁和铝合金等铸件的材料质量评估提供了一种新的方法。在声材料中,声速参数有一个规律的趋势,与位错-密度相关的声速本构方程的物理意义一致。即使缺陷和冶金不连续可能会给塑性行为增加随机和不可预测的成分,voice参数也能识别缺陷材料的规律趋势。缺陷材料的这种意想不到的规则行为被称为缺陷驱动塑性(DDP),并且通过将缺陷的缺口强化(NS)和连续损伤力学(CDM)的稳定韧性断裂扩展的概念相结合,似乎可以使其合理化。本文报道了高硅强化球墨铸铁中DDP的合理化和实验结果的支持。
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引用次数: 0
Ultrafast Laser Fabrication of Microchannels on Aluminium Alloy Substrate 超快激光在铝合金基底上制造微通道
Pub Date : 2023-12-05 DOI: 10.4028/p-rjfpy3
Abhijit Cholkar, Suman Chatterjee, David Kinahan, D. Brabazon
Aluminium alloy 6061 has a versatile application within industrial heat exchangers, heat sinks, chemical equipment, and frames of aircraft and ships. Its physical and mechanical properties such as lightweight, high strength, corrosion resistance, and thermal and electrical conductivity make it a suitable material choice for these applications. Within thermal and micro-electromechanical applications, such as heat exchanges, radiators, and heat sinks used in microelectronics, the dissipation of heat plays an important role. For optimum heat dissipation, a higher surface area is required. This can be achieved by modifying the surface by fabricating microchannels. A number of processing techniques are used for fabricating microchannels on different materials. A laser is a flexible non-contact machining tool that may be used to create any profile or contour on practically any material. In recent times due to the advancement in laser technology, the use of ultrafast laser material processing is one potential route toward further extending the fabrication of high-quality microchannels without defects caused due to heat-affected zones and in a sustainable manner. In this paper, we present an experimental work of fabrication of microchannels on an aluminium alloy 6061 surfaces by using a low power (<4 W) 400 fs laser system. The dimensional accuracy of the fabricated microchannels is assessed using scanning electron microscopy and 3D profilometry. Furthermore, as processing speed and scale is of importance in industrial laser processes, the use of scanning optics is examined as a means of developing a rapid and scalable ultrafast laser process.
6061铝合金在工业热交换器,散热器,化学设备以及飞机和船舶的框架中具有广泛的应用。其物理和机械性能,如轻质,高强度,耐腐蚀性,导热性和导电性,使其成为这些应用的合适材料选择。在热和微机电应用中,例如用于微电子的热交换器、散热器和散热器,热量的消散起着重要的作用。为了达到最佳的散热效果,需要更大的表面积。这可以通过制造微通道来修饰表面来实现。许多加工技术被用于在不同的材料上制造微通道。激光是一种灵活的非接触加工工具,可用于在几乎任何材料上创建任何轮廓或轮廓。近年来,由于激光技术的进步,使用超快激光材料加工是进一步扩展高质量微通道制造的潜在途径,没有热影响区引起的缺陷,并且以可持续的方式。本文介绍了利用低功率(<4 W) 400 fs激光系统在6061铝合金表面制备微通道的实验工作。利用扫描电子显微镜和三维轮廓术对制备的微通道的尺寸精度进行了评估。此外,由于加工速度和规模在工业激光加工中很重要,因此研究了使用扫描光学作为开发快速和可扩展的超快激光工艺的手段。
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引用次数: 0
Unusual Precipitation at Grain Boundaries in Non-Equiatomic CoCrFeMnNi High Entropy Alloys 非等原子钴铬铁镍高熵合金晶界处的异常沉淀
Pub Date : 2023-12-05 DOI: 10.4028/p-4knuld
Hiroyuki Y. Yasuda, Masaki Horiguchi, Ken Cho, Takahiro Masuda, Takeshi Nagase
In Cr-rich CoCrFeMnNi alloys, the precipitation of the σ phase at grain boundaries during recrystallization is so fast that ultrafine-grained structure is formed due to the pinning effect of the precipitates. The average grain size of the fcc parent phase is found to be consistent with modified Zener-Smith model. If conventional alloys come to equilibrium, volume fraction of precipitates should approach a saturation value. However, it is interesting to note that the volume fraction of the σ phase in Cr-rich CoCrFeMnNi alloys is inversely proportional to the average grain size of the fcc parent phase. For instance, in Co20Cr25Fe20Ni15Mn20 alloys, the volume fraction changes from 6.5% to 1.2% with increasing average gran size from 14 μm to 210 μm even after annealing at 1273 K for 100 h. It is well known that heterogeneous nucleation of precipitates at grain boundary is energetically favorable and fast diffusion through grain boundary can assist the precipitation. However, they cannot account for the grain size dependence of the volume fraction after reaching equilibrium. Based on stereology, the reciprocal of grain size is proportional to grain boundary area. Thus, chemical fluctuation at grain boundaries (e.g. segregation) is considered to be related to the unusual precipitation at the grain boundaries.
在富cr的CoCrFeMnNi合金中,再结晶过程中晶界处σ相的析出速度非常快,由于析出相的钉住作用形成了超细晶组织。发现fcc母相的平均晶粒尺寸与修正的Zener-Smith模型一致。如果常规合金达到平衡,析出物的体积分数应该接近饱和值。然而,有趣的是,富cr CoCrFeMnNi合金中σ相的体积分数与fcc母相的平均晶粒尺寸成反比。以Co20Cr25Fe20Ni15Mn20合金为例,在1273 K下退火100 h后,Co20Cr25Fe20Ni15Mn20合金的体积分数从6.5%增加到1.2%,平均晶粒尺寸从14 μm增加到210 μm。众所周知,晶界析出相在能量上有利于非均相形核,晶界快速扩散有助于析出。然而,它们不能解释达到平衡后体积分数对晶粒尺寸的依赖关系。基于立体学,晶粒尺寸的倒数与晶界面积成正比。因此,晶界上的化学波动(如偏析)被认为与晶界上的异常降水有关。
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引用次数: 0
Factor for Improvement of Plastic Workability in Magnesium Alloy Pipes through Processing by Torsion and Back-Torsion 通过扭转和反扭转加工改善镁合金管材塑性加工性的因素
Pub Date : 2023-12-05 DOI: 10.4028/p-dtd09z
Hayata Okazaki, T. Kato, M. Furui
Magnesium alloys have the advantages being lightweight and high recyclability. On the other hands, it is thought that magnesium has the disadvantage of poor plastic workability at room temperature due to its crystal structure. Especially, in pipe materials, winkles occur on the compressed side during bending. We aim to improve the bending workability in magnesium alloy pipe by torsion and back-torsion. In this study, tensile and compressive tests using specimens of pipes processed by torsion and back-torsion showed reduction the difference of yield stress. Microstructural observation of processed pipes revealed reducing crystal grain size and forming deformation twinning. Vickers hardness tests shows increasing hardness by torsion and back-torsion. Moreover, bending tests showed decreasing flatting ratio by torsion and back-torsion. These results demonstrated that torsion and back-torsion have effect of improvement in bending workability for magnesium alloy pipes.
镁合金具有重量轻、可回收性高等优点。另一方面,人们认为镁由于其晶体结构,在室温下具有塑性加工性差的缺点。特别是在管道材料中,弯曲时压缩侧会产生褶皱。通过扭转和反扭转,提高镁合金管材的弯曲加工性。在本研究中,使用经过扭转和反扭转处理的管道试件进行拉伸和压缩试验,表明屈服应力差异减小。加工后的管材组织观察显示,晶粒尺寸减小,形成变形孪晶。维氏硬度试验表明,通过扭转和反扭转,硬度增加。弯曲试验表明,经扭转和反扭转后,压扁率降低。结果表明,扭转和反扭转对镁合金管材的弯曲加工性有改善作用。
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引用次数: 0
Developments of Cost Affordable Titanium Alloys in Japan 日本成本低廉的钛合金的发展情况
Pub Date : 2023-12-05 DOI: 10.4028/p-n1iiyw
Masahiko Ikeda, Masato Ueda, Yusuke Yamanishi
Titanium and its alloys are the 5th most common metallic materials used world wide but the markets volume of titanium materials, is difficult to expand due to associated production costs, and the decrease of those costs are critical in order to expand their markets. A possible option is the alloy design, i.e. using low price alloying element, such as iron, chromium, manganese and oxygen, and the selection of other raw materials, i.e. grade of sponge titanium. In beta titanium alloy, Ti-Mo system alloy using ferro-molybdeum was developed by USA company or Ti-Cr-Fe-Al beta alloy were also developed by Japan company. In this paper, those developed alloys were explained. Furthermore, substitution of Ti-10V-2Fe-3Al near beta alloy, presenters are studying about Ti-Mn-Fe-Al alloy.
钛及其合金是世界上第五大最常用的金属材料,但由于相关的生产成本,钛材料的市场规模难以扩大,而这些成本的降低对于扩大其市场至关重要。一种可能的选择是合金设计,即使用低价格的合金元素,如铁、铬、锰和氧,并选择其他原材料,即海绵钛的等级。在β钛合金中,美国公司开发了以钼铁为原料的Ti-Mo系合金,日本公司也开发了Ti-Cr-Fe-Al系合金。本文对已开发的合金进行了说明。在此基础上,对Ti-10V-2Fe-3Al近β合金的替代进行了研究。
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引用次数: 0
Manufacturing Method and Thermal Properties of Open-Cell Type Aluminum Foam by Replication Casting Process 用复制铸造工艺制造开孔型铝泡沫的方法和热性能
Pub Date : 2023-12-05 DOI: 10.4028/p-g8exke
Jong Min Kim, Tae Kyu Ha, Beom Suck Han, Young Jig Kim
Open-cell type aluminum foam possesses unique structural characteristics comprising numerous interconnected pores within. This intriguing structure facilitates the passage of fluids (gas or liquid) through the interior of the open-cell type aluminum foams, enabling easy transfer to the exterior. The objective of this study is to manufacture open-cell type aluminum foams with varying pore sizes using the replication casting process and to evaluate their thermal properties. The equipment designed for the production of open-cell type aluminum foams consists of a chamber and an inner container. The chamber is connected to a vacuum line and an Ar gas line, with the container positioned inside. The aluminum alloys utilized for the foams were A356 and ADC12, and Na2CO3 served as the space holder. As a result of manufacturing the foams, there was no significant difference of porosity with space holder size and alloy types, the porosity averaged around 62%. To investigate the thermal properties of open-cell type aluminum foams in relation to pore size and alloy types, temperature variations were measured during sample heating via the hot plate method. Consequently, it was confirmed that the thermal properties of the foams were influenced by the structural conditions and alloy types.
开孔型泡沫铝具有独特的结构特点,其中包括许多相互连接的孔。这种有趣的结构有利于流体(气体或液体)通过开孔型泡沫铝的内部,使其易于转移到外部。本研究的目的是利用复制铸造工艺制造具有不同孔径的开孔型泡沫铝,并评估其热性能。设计用于生产开孔型泡沫铝的设备由一个腔室和一个内容器组成。该腔室与真空管路和氩气管路相连,容器位于腔室内部。泡沫材料采用A356铝合金和ADC12铝合金,Na2CO3作为空间保持剂。由于泡沫的制造,孔隙率与空间支架尺寸和合金类型没有显著差异,平均孔隙率在62%左右。为了研究开孔型泡沫铝的热性能与孔径和合金类型的关系,通过热板法测量了样品加热过程中的温度变化。结果表明,泡沫材料的热性能受结构条件和合金类型的影响。
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引用次数: 0
Effect of Heating Rate on the Annealing Behavior of Aluminium Alloys 加热速率对铝合金退火行为的影响
Pub Date : 2023-12-05 DOI: 10.4028/p-31wxmv
P. Chakravarty, J. J. Sidor
This contribution presents a study on the effect of heating rate maintained during annealing treatment on the final microstructure and mechanical properties of cold rolled Al1050 sheet. This study is focused on microstructure and texture evolution of Al1050 annealed at various heating rates, annealing temperatures, and holding times. It was observed that the longer exposure time for deformed microstructure affects the Vickers hardness values, grain size, and texture intensity. It seems that the crystallographic texture evolution is not affected by heating rate on quantitative level since the same set of orientations tended to evolve in all studied cases. The sample annealed at slow heating rate in a box-type furnace produced recrystallized microstructure with fine grain size, and comparatively lower texture intensity & hardness.
本文研究了退火过程中加热速率对冷轧Al1050薄板最终组织和力学性能的影响。研究了Al1050在不同加热速率、退火温度和保温时间下的微观组织和织构演变。观察到,变形组织暴露时间的延长会影响合金的维氏硬度值、晶粒尺寸和织构强度。在定量水平上,晶体织构的演变似乎不受升温速率的影响,因为在所有研究情况下都倾向于演化出同一组取向。在箱式炉中慢速退火后,试样产生晶粒细小的再结晶组织,织构强度和硬度相对较低。
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引用次数: 0
The Role of Grain Size in the Mechanical Properties of Metals 晶粒尺寸在金属机械特性中的作用
Pub Date : 2023-12-05 DOI: 10.4028/p-d7em1c
M. Kawasaki, R. Figueiredo, Terence G. Langdon
It is now well established that the grain size is the fundamental microstructural feature of all polycrystalline materials. In practice, a very wide range of grain sizes will be needed in order to fully evaluate the effect of grain size on the mechanical properties of metals. For many years this was a significant limitation because it was not possible to use conventional thermomechanical processing to produce materials with submicrometer or nanometer grain sizes. Recently, this problem has been addressed by developing alternative processing techniques based on the application of severe plastic deformation. This overview demonstrates that, although the flow stress increases with decreasing grain size at low temperatures and decreases with decreasing grain size at high temperatures, this clear dichotomy in behavior may be adequately explained by using a single theoretical flow mechanism based on the occurrence of grain boundary sliding.
现在已经确定晶粒尺寸是所有多晶材料的基本微观结构特征。在实践中,为了充分评价晶粒尺寸对金属力学性能的影响,需要一个非常广泛的晶粒尺寸范围。多年来,这是一个重大的限制,因为不可能使用传统的热机械加工来生产亚微米或纳米粒度的材料。最近,这个问题已经通过开发基于严重塑性变形应用的替代加工技术来解决。这一综述表明,尽管流动应力在低温下随晶粒尺寸的减小而增大,在高温下随晶粒尺寸的减小而减小,但用基于晶界滑动发生的单一理论流动机制可以充分解释这种明显的二元行为。
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引用次数: 0
Microstructure Based Flow Stress Modelling of Superalloy 718 基于微观结构的超耐热合金 718 流动应力建模
Pub Date : 2023-12-05 DOI: 10.4028/p-alg9hs
Nilesh Kumar, S. D. Yadav
In order to get the insights about microstructural changes that occurs under the thermo-mechanical processing conditions, the physics based modelling approach is very useful. Therefore, the flow curves of alloy 718 are theoretical simulated using a dislocation density dependent constitutive model for different conditions. Presented model considers the microstructural ingredients that are immobile dislocation density, effective grain size and dislocation cell size as the variables to address the creep. The simulated flow curves show a good agreement with the experimental flow curves. The magnitude of immobile dislocation density and dislocation cell size in between 3.87× 1014 - 3.87× 1014­ m-2 and 8.29-8.45 μm, respectively, at the completion of the simulation. Furthermore, this approach also provides the possibility to quantify and depict the variation in each strengthening contributions.
为了深入了解在热机械加工条件下发生的微观结构变化,基于物理的建模方法非常有用。因此,采用位错密度相关的本构模型对718合金在不同条件下的流动曲线进行了理论模拟。该模型考虑了不动位错密度、有效晶粒尺寸和位错单元尺寸等微观结构因素作为变量来处理蠕变问题。模拟流动曲线与实验流动曲线吻合较好。模拟结束时,固定位错密度和位错胞尺寸分别在3.87× 1014 - 3.87× 1014 - m-2和8.29-8.45 μm之间。此外,这种方法还提供了量化和描述每种强化贡献的变化的可能性。
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引用次数: 0
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Solid State Phenomena
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