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Preparation of corrosion-resistant hydrophobic composite films on magnesium alloy 镁合金表面耐腐蚀疏水复合膜的制备
IF 2.8 4区 材料科学 Q3 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2022-09-02 DOI: 10.1080/02670844.2022.2161762
Jiyuan Zhu, Chenxi Jia
ABSTRACT Magnesium alloy has attracted wide attention for excellent properties but poor corrosion resistance hinders its application. The method of preparing high-performance corrosion-resistant films with low cost and easy operation is significantly crucial to the corrosion protection of magnesium alloy. By synthesizing zeolite film directly on AZ91D magnesium alloy, the work presented a simple, efficient and environmentally-friendly preparation method. In this study, a one-step synthesis method of multi-structure composite film on AZ91D magnesium alloy was explored. The prepared film surface had dense Mg(OH)2 bottom layer and K2Al2Si4O12·xH2O upper layer with porous support microstructure. Compared with the substrate, the corrosion current on the sample surface modified by stearic acid was reduced by about three orders of magnitude, and the corrosion inhibition rate reached 99.96% with a stable contact angle of about 125°. The results showed the excellent corrosion resistance and stable hydrophobicity of the prepared sample.
镁合金因其优异的性能而受到广泛关注,但其耐腐蚀性差阻碍了镁合金的应用。制备低成本、易于操作的高性能耐腐蚀膜的方法对镁合金的腐蚀防护至关重要。通过在AZ91D镁合金上直接合成沸石膜,提出了一种简单、高效、环保的制备方法。本研究探索了在AZ91D镁合金上一步合成多结构复合膜的方法。制备的薄膜表面具有致密的Mg(OH)2底层和K2Al2Si4O12·xH2O上层,具有多孔的支撑微观结构。与基体相比,硬脂酸改性样品表面的腐蚀电流降低了约三个数量级,缓蚀率达到99.96%,稳定的接触角约为125°。结果表明,制备的样品具有良好的耐腐蚀性和稳定的疏水性。
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引用次数: 3
Comparison between heat treatment and SPS treatment on CoCrFeMnNi/WC coatings CoCrFeMnNi/WC涂层热处理与SPS处理的比较
IF 2.8 4区 材料科学 Q3 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2022-09-02 DOI: 10.1080/02670844.2022.2154033
Yicheng Zhou, Bing-Jiang Yang, Guo Zhang
ABSTRACT In this study, spark plasma sintering (SPS) was used for the thermoelectric composite treatment of CrMnFeCoNi/WC plasma transfer arc welding (PTA) coating to explore the difference compared with common heat treatment (HT). X-ray diffraction (XRD) was used to detect the phase composition, and a combination of scanning electron microscopy (SEM) and transmission electron microscopy (TEM) was used to characterize the microstructure. The performance of nano-indentation was tested. The results show that the coating after PTA has a large dislocation density due to internal stress, while HT and SPS treatment significantly reduce the internal stress and dislocation density of the coating. Nano-indentation test shows that the hardness of the coating after PTA is 4.24 GPa, and after HT, the hardness decreases to 4.05 GPa. However, the coating after SPS treatment has significant precipitation-strengthening effect due to the wide existence of the precipitated phase, and the hardness rises to 4.78 GPa.
摘要本研究采用火花等离子体烧结(SPS)对CrMnFeCoNi/WC等离子转移焊(PTA)涂层进行热电复合处理,以探讨其与普通热处理(HT)的差异。使用X射线衍射(XRD)检测相组成,并使用扫描电子显微镜(SEM)和透射电子显微镜(TEM)的组合来表征微观结构。测试了纳米压痕的性能。结果表明,PTA处理后的涂层由于内应力而具有较大的位错密度,而HT和SPS处理显著降低了涂层的内应力和位错密度。纳米压痕试验表明,PTA后涂层的硬度为4.24 GPa,HT后硬度降至4.05 GPa。然而,SPS处理后的涂层由于沉淀相的广泛存在,具有显著的沉淀强化效果,硬度提高到4.78 GPa。
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引用次数: 1
Structural investigation of ZrN+Si3N4 thin films co-deposited by magnetron sputtering 磁控溅射共沉积ZrN+Si3N4薄膜的结构研究
IF 2.8 4区 材料科学 Q3 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2022-09-02 DOI: 10.1080/02670844.2022.2154965
I.L. Dias, A. R. Terto, P. C. Silva Neto, D. A. Ramirez, E. Tentardini
ABSTRACT Zirconium silicon nitride thin films with 1.6% Si addition were deposited via reactive magnetron sputtering and characterized by RBS, SEM-FEG, GAXRD, XPS and high temperature oxidation tests, aiming to investigate how silicon is structurally inserted in Zirconium nitride (ZrN) matrix. GAXRD results show a reduction in lattice parameter and grain size due to Si incorporation and XPS analyses demonstrate Si is present only in nitride form. Such observations proved the non-formation of substitutional or interstitial solid solution in ZrN, but the presence of Si3N4, even in low Si concentrations.
摘要采用反应磁控溅射法沉积了硅添加量为1.6%的氮化锆硅薄膜,并通过RBS、SEM-FEG、GAXRD、XPS和高温氧化测试对其进行了表征,旨在研究硅在氮化锆(ZrN)基体中的结构嵌入。GAXRD结果显示,由于Si的掺入,晶格参数和晶粒尺寸减小,XPS分析表明Si仅以氮化物形式存在。这些观察结果证明,即使在低Si浓度下,ZrN中也没有形成取代或间隙固溶体,而是存在Si3N4。
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引用次数: 1
Transparency and icephobicity of moth eye-inspired tailored omniphobic surface 蛾眼设计的透明和疏冰表面
IF 2.8 4区 材料科学 Q3 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2022-09-02 DOI: 10.1080/02670844.2022.2153512
Thanh-Binh Nguyen
ABSTRACT In this work, we presented a facile method to introduce a transparent and anti-icing omniphobic surface fabricated on the glass substrate. The uniform moth eye-inspired structure was generated by the Deep Reactive Ion Etching method and followed by an additional wet etching step to enhance the sharpness of the nanostructure. A hydrophobe compound was assembled on the rough substrate by chemical vapor coating to achieve remarkable liquid-repellent properties. The tensile strength test was conducted using a designed apparatus to evaluate the anti-icing performance of functional surfaces compared to the as-received one. In addition, the optical performance in terms of transmittance and reflectance also was tested and revealed significant optical enhancement owing to the unique design of nanoarrays. The results demonstrated the great potential and proposed design for multifunctional surfaces.
在这项工作中,我们提出了一种简单的方法,在玻璃基板上制备透明和防冰的全憎表面。采用深度反应离子刻蚀法生成均匀的蛾眼结构,然后进行额外的湿法刻蚀步骤以增强纳米结构的清晰度。通过化学气相涂层在粗糙的基材上组装疏水化合物,获得了优异的拒水性能。利用设计的抗拉强度试验装置对功能表面的抗冰性能进行了比较。此外,在透射率和反射率方面的光学性能测试也显示出由于纳米阵列的独特设计而显着的光学增强。结果显示了多功能表面的巨大潜力和建议的设计。
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引用次数: 1
Modified polymer nanopillars array for enhanced light trapping on large area 用于增强大面积光捕获的改性聚合物纳米柱阵列
IF 2.8 4区 材料科学 Q3 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2022-09-02 DOI: 10.1080/02670844.2022.2153478
Anagdha Sharma, S. Aravindan, P. Rao
ABSTRACT Electroless plating is used to enhance the strength of anodised aluminium oxide (AAO) which can be further utilised as a mould to fabricate the structures on large area of polymer for anti-reflection properties. Nanopillars of high aspect ratio are fabricated on polymer (polystyrene) sheet by hot embossing process which has ensured repeatability with precision and high throughput. The height of nanopillars matches the depth of the mould cavity. The enhanced light trapping performance is attributed to the high aspect ratio nanopillars with cup-shaped top surface. GRAPHICAL ABSTRACT
摘要:化学镀用于提高阳极氧化铝(AAO)的强度,AAO可进一步用作模具,在大面积聚合物上制造结构,具有抗反射性能。通过热压工艺在聚合物(聚苯乙烯)片上制备了高纵横比的纳米颗粒,确保了高精度和高通量的可重复性。纳米柱的高度与模具腔体的深度相匹配。光捕获性能的增强归因于具有杯形顶表面的高纵横比纳米柱。图形摘要
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引用次数: 0
Core shell particles 核壳颗粒
IF 2.8 4区 材料科学 Q3 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2022-09-02 DOI: 10.1080/02670844.2022.2170550
L. Gopal, T. Sudarshan
The formal study of core-shell particles may be traced back to the late sixties in the development of a novel sorbent of HPLC comprising porous spherical soft shells supported by fluid-impermeable glass microspheres [1]. Such ‘pellicular’ structures were found to be more stable at increasing pressures, changing column temperatures, and eluent compositions than conventional monolithic soft sorbents. Since then, many core-shell-type particles have been designed for various purposes because such composite particles exhibit the combined properties of the core and shell materials. The study of core-shell particles has expanded exponentially in the past few decades, given the variety of structures possible and the vast gamut of applications they can support (Figure 1). The composites that have been studied have been of various constituents, gross sizes, relative sizes, and morphologies (Figure 2). While the shell is almost always solid, the cores contain solids, liquids (capsules), or gases (hollow particles). These composite nanoparticle cores and shells have been in various combinations of inorganic, organic, polymeric, and crystalline materials. The entire ensembles have been nanometric or micrometric in size. The core has comprised single particles or multiple ones, and shells that have been studied have been continuous, multi-layered, or discontinuous domains. These particles themselves have been of various shapes as well.
核壳颗粒的正式研究可以追溯到60年代末,当时开发了一种新型高效液相色谱吸附剂,该吸附剂由不渗透的玻璃微球b[1]支撑的多孔球形软壳组成。这种“膜状”结构被发现在增加压力、改变柱温和洗脱液成分时比传统的整体软吸附剂更稳定。从那时起,许多核-壳型颗粒被设计用于各种用途,因为这种复合颗粒表现出核和壳材料的综合性能。在过去的几十年里,核-壳颗粒的研究呈指数级增长,因为它们可以支持各种各样的结构和广泛的应用范围(图1)。所研究的复合材料具有各种成分、总尺寸、相对尺寸和形态(图2)。虽然壳几乎总是固体,但核含有固体、液体(胶囊)或气体(空心颗粒)。这些复合纳米颗粒芯和壳以无机、有机、聚合物和晶体材料的各种组合形式存在。整个系统的尺寸都是纳米级或微米级。核由单个粒子或多个粒子组成,而已研究的壳层有连续的、多层的或不连续的区域。这些粒子本身也有不同的形状。
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引用次数: 0
Surface modification during hydroxyapatite powder mixed electric discharge machining of metallic biomaterials: a review 羟基磷灰石粉末混合电火花加工金属生物材料表面改性研究进展
IF 2.8 4区 材料科学 Q3 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2022-09-02 DOI: 10.1080/02670844.2022.2155406
H. Bisaria, Bharat Bhusan Patra, S. Mohanty
ABSTRACT Surface modifications play a vital role in the performance of bio-implants. Powder mixed electric discharge machining (PM-EDM), a recently developed advanced machining method, can machine and coat the surface of conductive materials at the same time. Hydroxyapatite is a bio-ceramic with a bone-like composition and excellent biocompatibility. Several coating techniques are used to deposit a bio-ceramic layer on the implant surface; however, hydroxyapatite powder mixed–EDM (HAp-EDM) is an electro-thermal process that can be used for surface coating as well as machining of metallic biomaterials. In this review article, surface characteristics such as surface morphology/topography, micro-hardness, phase analysis, recast layer, elemental composition, corrosion/wear resistance, and biocompatibility of the coated surface of an implant after HAp-EDM have been meticulously reviewed. This review also looks at future research opportunities for the HAp-EDM process to meet the high standards required for biomedical materials and their applications in bio-implant manufacturing.
摘要表面修饰对生物植入物的性能起着至关重要的作用。粉末混合放电加工(PM-EDM)是最近发展起来的一种先进的加工方法,可以同时加工和涂覆导电材料的表面。羟基磷灰石是一种具有类骨组成和良好生物相容性的生物陶瓷。几种涂层技术用于在植入物表面上沉积生物陶瓷层;然而,羟基磷灰石粉末混合电火花加工(HAp-EDM)是一种可用于表面涂层和金属生物材料加工的电热工艺。在这篇综述文章中,对HAp EDM后植入物涂层表面的表面特征,如表面形态/形貌、显微硬度、相分析、重铸层、元素组成、耐腐蚀性/耐磨性和生物相容性进行了仔细的综述。这篇综述还展望了HAp EDM工艺未来的研究机会,以满足生物医学材料及其在生物植入物制造中的应用所需的高标准。
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引用次数: 8
Comparative study of perhydropolysilazane protective films 全氢聚硅氮烷保护膜的比较研究
IF 2.8 4区 材料科学 Q3 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2022-09-02 DOI: 10.1080/02670844.2022.2155445
E.G. Shmagina, M. Danilson, V. Mikli, S. Bereznev
ABSTRACT Silicon dioxide thin films are a promising alternative to protective glass in solar cells. In this work, one-layer and four-layer thin films of a perhydropolysilazane (PHPS) were spin-coated from solution in dibutyl ether and cured by exposure to moderate temperatures or ultraviolet (UV) light to obtain glassy SiOx layers. Optical and morphological properties as well as their long-term stability were studied using XPS, FTIR, UV-Vis spectroscopy, and SEM microscopy with EDX analysis. The results showed that the process of converting PHPS layers to SiOx continues after the completion of the curing procedure for both methods. However, the composition of the thermally cured films is similar to silicon oxide, while the UV-cured samples demonstrate a composition similar to silicon dioxide due to differences in the reactions occurring during the curing process. The prolonged transformation process opens up possibilities for creating self-improving protective coatings based on PHPS. GRAPHICAL ABSTRACT
摘要:二氧化硅薄膜是太阳能电池中保护玻璃的一种很有前途的替代品。在本工作中,从二丁基醚溶液中旋涂一层和四层全氢聚硅氮烷(PHPS)薄膜,并通过暴露于中等温度或紫外线(UV)光进行固化,以获得玻璃状SiOx层。使用XPS、FTIR、UV-Vis光谱和SEM显微镜结合EDX分析研究了它们的光学和形态性质及其长期稳定性。结果表明,在两种方法的固化程序完成后,将PHPS层转化为SiOx的过程仍在继续。然而,热固化膜的组成类似于氧化硅,而UV固化样品由于固化过程中发生的反应的差异而表现出类似于二氧化硅的组成。延长的转化过程为创造基于PHPS的自我改进保护涂层开辟了可能性。图形摘要
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引用次数: 0
High-temperature wear behaviour of ZrC/NbC-reinforced CrMnFeCoNi coatings ZrC/ nbc增强crmneconi涂层的高温磨损性能
IF 2.8 4区 材料科学 Q3 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2022-09-02 DOI: 10.1080/02670844.2022.2153497
Dacheng Sun, Yangchuan Cai, Lisong Zhu, Jianv Han
ABSTRACT Nowadays, studies of high entropy alloys (HEAs) have shown excellent properties. To improve the high-temperature wear resistance of CrMnFeCoNi alloy, refractory carbides (NbC and ZrC, respectively) reinforced CrMnFeCoNi composite coating were prepared by laser cladding (LC), and its wear performance was investigated. The composite coating showed no cracks or other defects that had metallurgical bonding with the substrate. Those coatings exhibited oxidative and adhesive wear mechanisms in reciprocating wear tests at 600°C. In contrast to the strengthening of NbC, the ZrC in the coating rapidly oxidized during high-temperature wear, forming a large amount of ZrO2. These oxides formed in wear promote the formation of a protective film, further improving the oxidation resistance and wear resistance of the coating.
摘要近年来,对高熵合金的研究显示出优异的性能。为了提高CrMnFeCoNi合金的高温耐磨性,采用激光熔覆法制备了难熔碳化物(NbC和ZrC)增强CrMnFeCoNi复合涂层,并对其耐磨性能进行了研究。该复合涂层没有显示出与基体冶金结合的裂纹或其他缺陷。在600°C的往复磨损试验中,这些涂层表现出氧化和粘附磨损机制。与NbC的强化相反,涂层中的ZrC在高温磨损过程中迅速氧化,形成大量的ZrO2。这些在磨损中形成的氧化物促进了保护膜的形成,进一步提高了涂层的抗氧化性和耐磨性。
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引用次数: 1
Novel synthesis of SiC coating by liquid phase deposition 液相沉积法合成新型碳化硅涂层
IF 2.8 4区 材料科学 Q3 MATERIALS SCIENCE, COATINGS & FILMS Pub Date : 2022-09-02 DOI: 10.1080/02670844.2022.2161760
Yongfu Zhang, Xiaolin Wei, Weiwei Chen
ABSTRACT In this study, SiC coating was prepared on carbon fibres from solution at ambient temperatures for the first time. The thickness of the coating was ∼85 nm. Analysis of the coatings revealed the presence of only SiC in the coating. The initial oxidation temperature of the SiC-coated carbon fibres increased by ∼50°C and the complete oxidation temperature was increased by ∼167°C, indicating excellent oxidation resistance owing to the presence of the SiC coating. We believe that the excellent properties and easy preparation process of SiC coating reported in this paper would provide us with a new way to produce SiC coating on carbon substrates.
摘要本研究首次在常温下用溶液在碳纤维上制备了SiC涂层。涂层厚度为~85 nm。对涂层的分析显示涂层中仅存在SiC。SiC涂层碳纤维的初始氧化温度增加了~50°C,完全氧化温度增加~167°C,表明由于SiC涂层的存在,具有优异的抗氧化性。我们相信,本文报道的SiC涂层的优异性能和易于制备的工艺将为我们在碳衬底上制备SiC涂层提供一种新的途径。
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引用次数: 0
期刊
Surface Engineering
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