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An ultraviolet-visible distinguishable broadband photodetector based on the positive and negative photoconductance effects of a graphene/ZnO quantum dot heterostructure 基于石墨烯/ZnO量子点异质结构正负光导效应的紫外-可见光可分辨宽带光电探测器
IF 3.1 3区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2022-01-01 DOI: 10.20517/microstructures.2022.24
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引用次数: 2
Retraction notice to “Structural, electronic, optical, elastic and thermal properties of CdSnP2 with the application in solar cell devices” [Superlattice. Microst. 85 (2015) 859–871] “CdSnP2的结构、电子、光学、弹性和热性质及其在太阳能电池器件中的应用”[超晶格]的撤回通知。Microst. 85 (2015) 859-871]
IF 3.1 3区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2022-01-01 DOI: 10.1016/j.spmi.2021.107093
Ruchita Gautam , Pravesh Singh , Sheetal Sharma , Sarita Kumari , A.S. Verma
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引用次数: 0
Metal-organic framework-tailored perovskite solar cells 金属有机框架定制钙钛矿太阳能电池
IF 3.1 3区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2022-01-01 DOI: 10.20517/microstructures.2022.05
Peng Chen, Jingwei Hou, Lianzhou Wang
Metal-organic frameworks (MOFs) with tailorable structures and building blocks have demonstrated their advantages in improving the long-term stability of perovskite solar cells (PSCs). However, the inferior conductivity of MOFs and their lack of strong chemical interaction with perovskites cause undesirable interfacial charge carrier recombination and then deteriorate the photovoltaic (PV) performance of PSCs. This perspective offers an insightful overview of the versatile functionalities and key merits of MOFs for stabilizing PSCs under various external stimuli in terms of MOF interlayers and MOF-perovskite heterostructures. To tackle the charge transport problem of MOFs, promising strategies are outlined to improve the intrinsic conductivity and chemical coordination of MOFs, with the aim of achieving long-term stable PSCs without compromising their PV performance. The current challenging issues and potential solutions are also discussed to provide a roadmap for MOF-tailored PSCs towards practical applications.
具有可定制结构和构建块的金属有机框架(MOFs)在提高钙钛矿太阳能电池(PSCs)的长期稳定性方面具有优势。然而,由于mof的电导率较差,且与钙钛矿缺乏强的化学相互作用,导致PSCs的界面载流子重组,从而降低了其光伏(PV)性能。从MOF中间层和MOF-钙钛矿异质结构的角度,对MOF在各种外部刺激下稳定psc的多功能和关键优点进行了深刻的概述。为了解决mof的电荷输运问题,概述了改善mof的内在电导率和化学配位的有希望的策略,目的是在不影响其PV性能的情况下实现长期稳定的PSCs。本文还讨论了当前具有挑战性的问题和潜在的解决方案,为mof定制PSCs走向实际应用提供了路线图。
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引用次数: 4
Effects of processing parameters on a β-solidifying TiAl alloy fabricated by laser-based additive manufacturing 工艺参数对激光增材制造β-凝固TiAl合金的影响
IF 3.1 3区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2022-01-01 DOI: 10.20517/microstructures.2022.17
Danni Huang, Yangping Dong, Han-De Chen, Yinghao Zhou, M. Zhang, Ming Yan
β-solidifying TiAl alloys are considered as promising candidate materials for high-temperature structural applications. Laser-based additive manufacturing (LAM) enables the fabrication of components with geometrical complexity in near-net shape, leading to time and feedstock savings. In this study, a gas-atomized Ti-44Al-4Nb-1Mo-1Cr powder is used as a feedstock material for LAM. However, the LAM of TiAl alloys remains a challenge due to serious cracking during the printing process. To minimize the cracking, the optimization of the LAM processing parameters is essential. Hence, the effects of the LAM processing parameters on the cracking susceptibility and microstructure are studied here. Our experimental results show that the cracking susceptibility can be mitigated by increasing the laser power. Accordingly, the microstructure transforms from the dominating α2 grains to a near-lamellar microstructure with an increment in laser power, leading to a reduction in microhardness, even though it is still higher than that of its as-cast counterparts. It is concluded that changes in the laser power can directly tailor the microstructure, phase composition and microhardness of LAM-fabricated TiAl alloys.
β-凝固TiAl合金是一种很有前途的高温结构材料。基于激光的增材制造(LAM)能够以近净形状制造几何复杂的部件,从而节省时间和原料。本研究采用气雾化Ti-44Al-4Nb-1Mo-1Cr粉末作为LAM的原料。然而,由于在打印过程中存在严重的裂纹,TiAl合金的LAM仍然是一个挑战。为了最大限度地减少开裂,优化LAM的加工参数是必不可少的。因此,本文研究了LAM工艺参数对裂纹敏感性和微观组织的影响。实验结果表明,增加激光功率可以减轻材料的裂纹敏感性。随着激光功率的增加,合金组织由α2晶粒为主转变为近片层组织,显微硬度降低,但仍高于铸态合金。结果表明,激光功率的变化可以直接改变TiAl合金的显微组织、相组成和显微硬度。
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引用次数: 2
Design and manufacture of high-performance microbatteries: lithium and beyond 高性能微电池的设计和制造:锂及其他
IF 3.1 3区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2022-01-01 DOI: 10.20517/microstructures.2022.10
Feiyang Chen, Zheng-Long Xu
The accelerated development of miniaturized and customized electronics has stimulated the demand for high-energy microbatteries (MBs) as on-chip power sources for autonomous state operations. However, commercial MBs with thin-film configurations exhibit insufficient energy and power density due to their limited active materials and sluggish ion diffusion kinetics. In order to simultaneously enhance electrochemical performance and maintain low-cost production, efforts have been devoted to constructing three-dimensional battery architectures. This review summarizes the state-of-the-art progress in designing and fabricating microelectrodes for microbattery assembly, including the top-down etching and bottom-up printing techniques, with a particular focus on elucidating the correlations between electrode structures, battery performance, and cost-effectiveness. More importantly, advancements in post-lithium batteries based on sodium, zinc and aluminum are also surveyed to offer alternative options with potentially higher energy densities and/or lower battery manufacturing costs. The applications of advanced MBs in on-chip microsystems and wearable electronics are also highlighted. Finally, conclusions and perspectives for the future development of MBs are proposed.
小型化和定制化电子产品的加速发展刺激了对高能微电池(mb)作为自主状态操作的片上电源的需求。然而,具有薄膜结构的商用MBs由于其有限的活性材料和缓慢的离子扩散动力学而表现出不足的能量和功率密度。为了同时提高电化学性能和保持低成本生产,人们一直致力于构建三维电池结构。本文综述了用于微电池组装的微电极的设计和制造的最新进展,包括自顶向下的蚀刻和自底向上的印刷技术,重点阐述了电极结构、电池性能和成本效益之间的关系。更重要的是,基于钠、锌和铝的后锂电池的进展也被调查,以提供潜在的更高能量密度和/或更低电池制造成本的替代方案。介绍了先进的mb在片上微系统和可穿戴电子产品中的应用。最后,对未来的发展提出了结论和展望。
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引用次数: 3
Applications of in situ electron microscopy in oxygen electrocatalysis 原位电子显微镜在氧电催化中的应用
IF 3.1 3区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2022-01-01 DOI: 10.20517/microstructures.2021.12
Zhi‐Peng Wu, Hui Zhang, Cailing Chen, Guanxing Li, Yu Han
Oxygen electrocatalysis involving the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) plays a vital role in cutting-edge energy conversion and storage technologies. In situ studies of the evolution of catalysts during oxygen electrocatalysis can provide important insights into their structure - activity relationships and stabilities under working conditions. Among the various in situ characterization tools available, in situ electron microscopy has the unique ability to perform structural and compositional analyzes with high spatial resolution. In this review, we present the latest developments in in situ and quasi-in situ electron microscopic techniques, including identical location electron microscopy, in situ liquid cell (scanning) transmission electron microscopy and in situ environmental transmission electron microscopy, and elaborate their applications in the ORR and OER. Our discussion centers on the degradation mechanism, structural evolution and structure - performance correlations of electrocatalysts. Finally, we summarize the earlier discussions and share our perspectives on the current challenges and future research directions of using in situ electron microscopy to explore oxygen electrocatalysis and related processes.
氧电催化涉及氧还原反应(ORR)和析氧反应(OER),在能量转换和存储的前沿技术中起着至关重要的作用。对氧电催化过程中催化剂的原位研究可以为了解其结构-活性关系和工作条件下的稳定性提供重要的见解。在各种可用的原位表征工具中,原位电子显微镜具有高空间分辨率进行结构和成分分析的独特能力。本文综述了原位和准原位电镜技术的最新进展,包括同位电镜、原位液体细胞(扫描)透射电镜和原位环境透射电镜,并阐述了它们在ORR和OER中的应用。主要讨论了电催化剂的降解机理、结构演变和结构性能关系。最后,我们总结了前面的讨论,并对原位电子显微镜研究氧电催化及其相关过程面临的挑战和未来的研究方向进行了展望。
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引用次数: 3
Polarization boosted catalysis: progress and outlook 极化助推催化:进展与展望
IF 3.1 3区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2022-01-01 DOI: 10.20517/microstructures.2021.14
Lin Ju, Xiao Tang, Liangzhi Kou
Polarization has a significant impact on chemical reactions, as demonstrated by recent research of photo-/electrocatalytic water splitting, electrocatalytic CO2 reduction, water treatment, dye degradation and so on. This review summarizes the fundamental influence of polarization on the physical/chemical properties of catalysts and discusses polarization-dependent catalytic processes. Based on the research progress of polarization-modulated chemical reactions, we draw the conclusion that the control of polarization can be used to adjust the reactivity and selectivity of various catalytic reactions by tuning the miscellaneous fundamental properties of polarized catalysts. At the end of the review, the future research challenges are also discussed, including the ultrafast reversal of polarization, the magnetic-field control of chemical reactions through the magnetoelectric effect and in-plane polarization.
极化对化学反应有着重要的影响,近年来在光/电催化水分解、电催化CO2还原、水处理、染料降解等方面的研究都证明了这一点。本文综述了极化对催化剂物理/化学性质的基本影响,并讨论了依赖极化的催化过程。根据极化调制化学反应的研究进展,我们得出极化控制可以通过调节极化催化剂的各种基本性质来调节各种催化反应的反应活性和选择性。最后,对未来的研究挑战进行了展望,包括超快极化反转、利用磁电效应和光面内极化控制化学反应等。
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引用次数: 7
Low neutron cross-section FeCrVTiNi based high-entropy alloys: design, additive manufacturing and characterization 低中子截面FeCrVTiNi基高熵合金:设计、增材制造和表征
IF 3.1 3区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2022-01-01 DOI: 10.20517/microstructures.2021.09
B. Dong, Zhiyang Wang, Hanliang Zhu, O. Muránsky, Zhijun Qiu, Chen Shen, Z. Pan, Huijun Li
The development of high-entropy alloys (HEAs) based on the novel alloying concept of multi-principal components presents opportunities for achieving new materials with desired properties for increasingly demanding applications. In this study, a low neutron cross-section FeCrVTiNi-based HEA was developed for potential nuclear applications. A face-centred cubic (FCC) HEA with the nominal composition of FeCr0.4V0.3Ti0.2Ni1.3 is proposed based on the empirical thermodynamic models and the CALculation of PHAse diagrams (CALPHAD) calculation. Verifications of the predictions were performed, including the additive manufacturing of the proposal material and a range of microstructural characterizations and mechanical property tests. Consistent with the prediction, the as-fabricated HEA consists of a dominant FCC phase and minor Ni3Ti precipitates. Moreover, significant chemical segregation in the alloy, as predicted by the CALPHAD modelling, was observed experimentally in the produced dendritic microstructure showing the enrichment of Ni and Ti elements in the interdendritic regions and the segregation of Cr and V elements in the dendritic cores. Heterogenous mechanical properties, including microhardness and tensile strengths, were observed along the building direction of the additively manufactured HEA. The various solid solution strengthening effects, due to the chemical segregation (in particular Cr and V elements) during solidification, are identified as significant contributing factors to the observed mechanical heterogeneity. Our study provides useful knowledge for the design and additive manufacturing of compositionally complex HEAs and their composition-microstructure-mechanical property correlation.
基于多主成分合金新概念的高熵合金(HEAs)的发展为获得具有期望性能的新材料提供了机会,以满足日益苛刻的应用要求。在这项研究中,基于低中子截面fecrvti的HEA被开发用于潜在的核应用。基于经验热力学模型和相图计算(CALPHAD)计算,提出了一种名义成分为FeCr0.4V0.3Ti0.2Ni1.3的面心立方HEA (FCC)。对预测进行了验证,包括提议材料的增材制造和一系列微观结构表征和机械性能测试。与预测一致,制备的HEA主要由FCC相和少量Ni3Ti相组成。此外,正如CALPHAD模型预测的那样,在实验中观察到合金中存在明显的化学偏析,在生成的枝晶组织中,Ni和Ti元素在枝晶间区域富集,Cr和V元素在枝晶核心中偏析。沿增材制造的HEA的构建方向观察到非均质力学性能,包括显微硬度和拉伸强度。由于凝固过程中的化学偏析(特别是Cr和V元素),各种固溶体强化效应被认为是造成观察到的机械非均质性的重要因素。本研究为结构复杂的HEAs的设计和增材制造及其组成-显微组织-力学性能的相关性提供了有益的知识。
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引用次数: 5
Modeling of Schottky diode characteristic by machine learning techniques based on experimental data with wide temperature range 基于宽温度范围实验数据的肖特基二极管特性机器学习建模
IF 3.1 3区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2021-12-01 DOI: 10.1016/j.spmi.2021.107062
Yunis Torun , Hülya Doğan

In this study, 4 common machine learning methods have been used to model the I–V characteristic of the Au/Ni/n-GaN/undoped GaN Schottky diode. The current values of previously produced Au/Ni/n-GaN/undoped GaN Schottky diode against the voltages applied to the diode terminal starting from the temperature of 40K up to 400K with 20K steps were measured. Models were created using Adaptive Neuro Fuzzy System, Artificial Neural Network, Support Vector Regression, and Gaussian Process Regression techniques using experimental data containing 5192 samples in total. After determining the combinations and specifications for each one that provide the lowest model error of each model, the performances of the obtained models were compared with each other concerning the various performance indices. The performance of the ANFIS model was found to be much better than the others in both the learning and test phases with RMSE model errors as 6.231e-06 and 6.806e-06, respectively. Therefore, it was proposed as a powerful tool for modeling I–V characteristics at all temperature values between 40K and 400K.

在本研究中,使用了4种常见的机器学习方法来模拟Au/Ni/n-GaN/未掺杂GaN肖特基二极管的I-V特性。测量了先前生产的Au/Ni/n-GaN/未掺杂GaN肖特基二极管在从温度40K到400K的电压下,以20K步长施加在二极管端子上的电流值。采用自适应神经模糊系统、人工神经网络、支持向量回归和高斯过程回归技术建立模型,实验数据共包含5192个样本。在确定每个模型的最小模型误差的组合和规格后,对得到的模型的各项性能指标进行比较。在学习阶段和测试阶段,ANFIS模型的性能都明显优于其他模型,RMSE模型误差分别为6.231e-06和6.806e-06。因此,它被认为是在40K和400K之间的所有温度值下建模I-V特性的强大工具。
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引用次数: 7
Properties of optical bipolaron in symmetric quantum dot 对称量子点中光学双极化子的性质
IF 3.1 3区 物理与天体物理 Q2 PHYSICS, CONDENSED MATTER Pub Date : 2021-12-01 DOI: 10.1016/j.spmi.2021.107082
J.-R.D. Djomou, A.J. Fotue, S.C. Kenfack, L.C. Fai

Optical bipolaron properties in the symmetric quantum dot were investigated using the Lee-Low-Pines-Huybrechts method and the Tokuda linear combination operator method. Algebraic expressions are derived for the energies of the fundamental and first excited states, the effective mass, mobility, binding energy and oscillation period of the optical bipolaron. Results prove that the energies of fundamental and first excited states increase with the coupling constant. Another point is that the strong coupling method dominates the weak coupling and the intermediate one when the electron-phonon coupling enhances. We also observe that the binding energy becomes always positive when confinement strength is above 5. In other points, the binding energy of optical bipolaron is well studied in all coupling, especially in weak coupling. It is also noticed that energies are increasing the function of the dielectric ratio and the oscillation period is reducing with the dielectric ratio. This proves that the electron-electron interaction is strengthened in a quantum dot. The stronger the coupling, the higher mobility in the case of low temperature.

利用Lee-Low-Pines-Huybrechts方法和Tokuda线性组合算子方法研究了对称量子点的光学双极化子性质。导出了光学双极化子的基本激发态和第一激发态能量、有效质量、迁移率、结合能和振荡周期的代数表达式。结果表明,基本态和第一激发态的能量随耦合常数的增大而增大。另一点是,当电子-声子耦合增强时,强耦合方法优于弱耦合方法和中间耦合方法。我们还观察到,当约束强度大于5时,结合能总是正的。在其他方面,光学双极化子的结合能在所有耦合,特别是弱耦合中得到了很好的研究。能量随介电比的增大而增大,振荡周期随介电比的增大而减小。这证明了电子-电子相互作用在量子点中得到加强。在低温条件下,耦合越强,迁移率越高。
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引用次数: 0
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Superlattices and Microstructures
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