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Oil film mixed lubrication of heavy-load friction pairs: Theoretical modeling, solution methods, and applications 重载摩擦副油膜混合润滑:理论建模、求解方法及应用
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-12-16 DOI: 10.1016/j.triboint.2025.111589
Kaiming Zheng , Xiaolong Zhang , Kou Du , Shuai Li , Junhui Zhang , Wei Wu , Bing Xu , Huayong Yang , Chao Zhang
The importance of heavy-load friction pairs is highlighted by the extensive use of heavy machinery in large engineering projects. Their performance under mixed lubrication conditions directly impacts efficiency, reliability, and service life. Accurately and effectively establishing a lubrication characteristic model for the oil film in friction pairs and solving it is of paramount importance. Currently, there is a lack of systematic analysis and summaries of models in this field. This work comprehensively reviews the modeling and solution methods, as well as the core challenges, associated with the oil film characteristics of heavy-load friction pairs under mixed lubrication. It also provides detailed descriptions of typical applications for each method. Finally, based on previous research, this paper outlines future development directions. The review aims to provide model guidance for improving the lubrication performance and extending the service life of heavy-load friction pairs, promoting the application of mixed lubrication theory in engineering practice.
重型机械在大型工程项目中的广泛应用凸显了重载摩擦副的重要性。它们在混合润滑条件下的性能直接影响效率、可靠性和使用寿命。准确有效地建立摩擦副油膜润滑特性模型并进行求解是至关重要的。目前,对该领域的模型缺乏系统的分析和总结。本文全面综述了混合润滑下重载摩擦副油膜特性的建模、求解方法及其面临的核心挑战。它还提供了每种方法的典型应用的详细描述。最后,在前人研究的基础上,提出了未来的发展方向。旨在为提高重载摩擦副的润滑性能和延长其使用寿命提供模型指导,促进混合润滑理论在工程实践中的应用。
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引用次数: 0
Investigation into the synergistic effects of tesla valve micro-textures and CrN/DLC coatings on the friction and cutting performance of YG8N cemented carbide tools 特斯拉阀微织构与CrN/DLC涂层对YG8N硬质合金刀具摩擦与切削性能的协同效应研究
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-12-14 DOI: 10.1016/j.triboint.2025.111584
Li Jing , Yang Fazhan , Jiang Fulin , Chen Anqi , Wang Xue , Li Guangdi , Yan Shibin
To tackle the severe wear experienced by YG8N cemented carbide cutting tools when machining difficult-to-cut materials such as titanium alloys, the present study proposes and experimentally validates a synergistic surface-engineering strategy based on tesla valve micro-texturing in combination with CrN/DLC composite coatings. This method innovatively integrates a diode-like tesla valve micro-texture with a high-hardness, low-friction CrN/DLC composite coating in a unified design, enabling the coupled optimisation of interfacial lubrication conditions and surface mechanical performance. A tesla valve micro-texture was fabricated on the cemented carbide surface using femtosecond laser ablation, after which a CrN transition layer and a top DLC coating were sequentially deposited by magnetron sputtering, thereby producing a composite surface with directional fluid-control capability. The microstructure and mechanical properties of the coatings were characterised by means of X-ray diffraction (XRD), Raman spectroscopy, and nanoindentation. Tribological performance was subsequently evaluated through ball-on-disc tests conducted under both dry and lubricated conditions. The results demonstrate that the engineered composite surface exhibits outstanding friction-reducing performance under lubricated conditions: At low speed and low load (10 N, 1 m/s), the reverse-textured specimen (D-RT) achieved the lowest coefficient of friction (0.069), owing to lubricant entrapment and the pressure-build-up effect induced by the tesla valve structure. At high speed and high load (20 N, 6 m/s), the forward-textured specimen (D-FT) recorded the lowest coefficient of friction (0.049), benefiting from the enhanced hydrodynamic lubricant-guiding capability of the texture orientation. The cutting tests further confirm that, compared with conventional tools, those incorporating the CrN/DLC tesla valve hybrid structure can significantly suppress tool wear, delay tool-tip failure, and substantially extend tool life at high cutting speeds. This study elucidates the synergistic mechanism between the anisotropic fluid-control characteristics of the tesla valve micro-texture and the low-shear behaviour of the DLC coating. It thereby proposes a texture–coating coupling strategy that can be effectively applied to high-performance cemented carbide tools, offering both a new theoretical foundation and a practical engineering approach for achieving efficient, long-life machining of difficult-to-cut materials.
为了解决YG8N硬质合金刀具在加工钛合金等难切削材料时的严重磨损问题,本研究提出了一种基于特斯拉阀微织构与CrN/DLC复合涂层相结合的协同表面工程策略,并进行了实验验证。该方法创新性地将二极管状特斯拉阀微纹理与高硬度、低摩擦CrN/DLC复合涂层统一设计,实现了界面润滑条件和表面机械性能的耦合优化。利用飞秒激光烧蚀技术在硬质合金表面制备了特斯拉阀微织体,然后通过磁控溅射沉积CrN过渡层和顶部DLC涂层,从而制备了具有定向流体控制能力的复合表面。利用x射线衍射(XRD)、拉曼光谱和纳米压痕技术对涂层的微观结构和力学性能进行了表征。随后,通过在干燥和润滑条件下进行的球盘测试来评估摩擦性能。结果表明,在润滑条件下,工程复合材料表面表现出出色的减摩性能:在低速和低载荷(10 N, 1 m/s)下,由于润滑油夹带和特斯拉阀结构引起的压力积聚效应,反织构试样(D-RT)的摩擦系数最低(0.069)。在高速和高载荷(20 N, 6 m/s)下,正向织构试样(D-FT)的摩擦系数最低(0.049),这得益于织构取向的流体动力导向能力增强。切削试验进一步证实,与传统刀具相比,采用CrN/DLC特斯拉阀混合结构的刀具可以显著抑制刀具磨损,延缓刀具尖端失效,并在高切削速度下大幅延长刀具寿命。本研究阐明了特斯拉阀微织构的各向异性流控特性与DLC涂层的低剪切特性之间的协同作用机制。由此提出了一种可有效应用于高性能硬质合金刀具的织构-涂层耦合策略,为实现难切削材料的高效、长寿命加工提供了新的理论基础和工程实践途径。
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引用次数: 0
Study on the layer number effect and synergistic lubrication mechanism in ionic liquid/graphene oxide composite aqueous lubrication system 离子液体/氧化石墨烯复合水润滑体系的层数效应及协同润滑机理研究
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-12-14 DOI: 10.1016/j.triboint.2025.111583
Guoqing Chen , Pengyang Li , Feizhou Li , Guojun Dong , Zhaozhao Yang , Yaohe Li , Shanni Liu , Jian Sun , Peng Yang
To address the challenges of high friction coefficient and severe adhesive wear of titanium alloys under aqueous lubrication conditions, this study systematically investigated the layer-number effect of graphene oxide (GO) and its synergistic lubrication mechanism with ionic liquid using macroscopic tribological experiments, SEM, XPS, FIB-HRTEM, and molecular dynamics simulations. Experimental results show that the multi-layer GO/ionic liquid composite system reduces the friction coefficient to 0.0813 and the wear volume by 96.85 % compared to pure water, with a smooth worn surface exhibiting almost no adhesive features. FIB-HRTEM cross-sectional analysis further confirms the formation of a dense tribofilm approximately 15–24 nm thick on the titanium alloy surface. The study reveals that the number of GO layers can significantly affect lubrication performance: even in the absence of ionic liquid, multi-layer GO still significantly outperforms single-layer and few-layer GO; after the introduction of the ionic liquid, its enhanced interfacial adsorption and the improved dispersion of GO synergistically further enhance the lubrication performance. Molecular dynamics simulations reveal that multi-layer GO, through its easier interlayer sliding, denser hydrogen-bonding network, and more stable hydration layer, cooperates with preferentially adsorbed ionic liquid to jointly reduce the interfacial shear strength.
为了解决水润滑条件下钛合金高摩擦系数和严重粘着磨损的问题,本研究采用宏观摩擦学实验、SEM、XPS、FIB-HRTEM和分子动力学模拟等方法,系统地研究了氧化石墨烯(GO)的层数效应及其与离子液体的协同润滑机理。实验结果表明,与纯水相比,多层氧化石墨烯/离子液体复合体系的摩擦系数降低了0.0813,磨损体积降低了96.85 %,磨损表面光滑,几乎没有粘附特征。FIB-HRTEM横截面分析进一步证实钛合金表面形成了厚度约为15-24 nm的致密摩擦膜。研究表明,氧化石墨烯的层数对润滑性能有显著影响:即使在没有离子液体的情况下,多层氧化石墨烯的润滑性能仍显著优于单层和少层氧化石墨烯;离子液体引入后,其界面吸附的增强与氧化石墨烯分散性的改善协同作用,进一步提高了润滑性能。分子动力学模拟表明,多层氧化石墨烯通过其更易于层间滑动、更致密的氢键网络和更稳定的水化层,与优先吸附的离子液体协同作用,共同降低界面剪切强度。
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引用次数: 0
Tailoring microstructure and tribological performance of directed energy deposited Ti-6Al-4V alloy through in-situ oxygen doping 原位氧掺杂定向能沉积Ti-6Al-4V合金的微观结构和摩擦学性能
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-12-14 DOI: 10.1016/j.triboint.2025.111585
Zhen Wang , Sihan Yu , Daichen Ji , Nengbin Hua , Cuiyong Tang , Wen Zhou
This study re-evaluates the role of oxygen in Ti-6Al-4V production via directed energy deposition (DED), challenging the conventional perception of oxygen as a detrimental impurity. The coupled effects of processing parameters and controlled in-situ oxygen doping (0.1 %-10 %) on microstructural evolution and tribological behavior were systematically investigated. The results revealed that increasing laser power and scanning speed caused a transition in primary β grain morphology from equiaxed to columnar and increased the aspect ratio of α' martensite from 6.57 to 8.98. Within the tested processing window, an intermediate heat input (800 W, 400 mm/min) produced refined equiaxed β grains with fine acicular α′ martensite, resulting in the lowest wear rate of 3.60 × 10−7 mm3·N−1·mm−1. The addition of oxygen further refined the β grains and promoted the transformation of acicular α' into coarse lamellar α, accompanied by TiO2 precipitates. These microstructural changes increased in hardness from 355.8 HV0.3 to 527 HV0.3, and resulted in a non-monotonic relationship between oxygen content and tribological performance. Optimal results were observed at intermediate oxygen levels (3–5 %), where the friction coefficient decreased from 0.78 to 0.67, and the wear rate was reduced by 7.48 % compared to the low-oxygen baseline, with abrasive wear remaining the dominant mechanism. In contrast, high oxygen concentrations (8–10 %) caused severe embrittlement and brittle fracture, increasing the friction coefficient to 1.14 and the wear rate to 6.26 × 10–7 mm3·N−1·mm−1. At these elevated oxygen levels, the dominant wear mechanism shifted to adhesive and oxidative wear, resulting in significantly reduced tribological performance.
本研究通过定向能沉积(DED)重新评估了氧在Ti-6Al-4V生产中的作用,挑战了氧是有害杂质的传统观念。系统研究了工艺参数和可控原位氧掺杂(0.1 %-10 %)对合金微观组织演变和摩擦学行为的耦合影响。结果表明,增大激光功率和扫描速度可使初生β晶粒形貌由等轴向柱状转变,α′马氏体长径比由6.57提高到8.98;在测试的加工窗口内,中等热量输入(800 W, 400 mm/min)产生具有细针状α′马氏体的精致等轴β晶粒,导致最低磨损率为3.60 × 10−7 mm3·N−1·mm−1。氧的加入进一步细化了β晶粒,促进了针状α′向粗片层状α的转变,并伴有TiO2析出。显微组织的变化使合金硬度从355.8 HV0.3提高到527 HV0.3,氧含量与摩擦学性能呈非单调关系。在中氧水平(3-5 %)下,摩擦系数从0.78下降到0.67,磨损率比低氧基线降低了7.48 %,磨料磨损仍然是主要机制。高氧浓度(8-10 %)引起了严重的脆化和脆性断裂,摩擦系数达到1.14,磨损率达到6.26 × 10-7 mm3·N−1·mm−1。在高氧水平下,主要磨损机制转变为粘结磨损和氧化磨损,导致摩擦性能显著降低。
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引用次数: 0
Study on laser cladding micro/nanocrystals coating based on amorphous induction and wear-corrosion coupling damage mechanism 基于非晶感应和磨损-腐蚀耦合损伤机理的激光熔覆微纳米晶涂层研究
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-12-14 DOI: 10.1016/j.triboint.2025.111580
Shuaibing Li , Xiuyang Zhong , Lei Jia , Yaohong Jiang , Jian Liu , Jun Fan , Xuming Pang , Jibin Pu
Corrosion-wear coupling represents the primary failure mechanism for moving components in marine environments. Inspired by the fact that rapid solidification amorphous induction can avoid the formation of coarse-crystalline microstructure and plastic-tough FCC structures, the design of laser-melted micro/nanocrystals tribocorrosion resistance coating is proposed. The results indicate that incorporating FCC phase-dominated Ni-based alloys into the Fe-based amorphous matrix during the melting and cladding process promoted the formation of a micro/nanocrystal structure and suppressed defect formation, such as porosity and cracking. The microhardness of the coating reached approximately 1000 HV0.2. Among the coatings investigated, the one with a 45 % Ni-based alloy content exhibited optimal tribocorrosion performance, achieving a wear rate of 8.81 × 10−7 mm3/(N·m) and a corrosion current density as low as 5.82 × 10−8 A/cm2. Analysis of the tribocorrosion mechanism indicates that the addition of an appropriate amount of Ni-based alloy promotes the refinement and dispersion of the μ phase, thereby reducing the formation of pitting corrosion. This microstructural evolution achieves dispersion strengthening while simultaneously reducing stress concentration at the μ-phase/matrix interface and fatigue crack initiation tendency. It mitigates the accelerating effect of corrosion on wear, enabling the coating to exhibit a low synergistic factor under friction-corrosion conditions and demonstrate outstanding comprehensive tribocorrosion resistance. This study provides a novel design concept and a theoretical foundation for the application of Fe-based amorphous coatings in marine environments.
腐蚀磨损耦合是海洋环境中运动部件的主要失效机制。基于快速凝固非晶感应可以避免形成粗晶组织和塑性韧性FCC结构的特点,提出了激光熔化微/纳米晶耐摩擦腐蚀涂层的设计方法。结果表明,在熔炼和熔覆过程中,将FCC相主导的ni基合金加入到fe基非晶基体中,促进了微/纳米晶结构的形成,抑制了气孔和裂纹等缺陷的形成。涂层显微硬度达到1000 HV0.2左右。在所研究的涂层中,镍基合金含量为45% %的涂层表现出最佳的摩擦腐蚀性能,磨损率为8.81 × 10−7 mm3/(N·m),腐蚀电流密度低至5.82 × 10−8 a /cm2。摩擦腐蚀机理分析表明,适量的ni基合金的加入促进了μ相的细化和分散,从而减少了点蚀的形成。这种微观组织的演变实现了弥散强化,同时降低了μ相/基体界面处的应力集中和疲劳裂纹萌生倾向。它减轻了腐蚀对磨损的加速作用,使涂层在摩擦腐蚀条件下表现出较低的协同系数,并表现出出色的综合抗摩擦腐蚀能力。本研究为铁基非晶涂层在海洋环境中的应用提供了新的设计理念和理论基础。
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引用次数: 0
Skid resistance assessment of wet asphalt runways by coupling finite element simulation with real texture evolution data 湿沥青跑道抗滑性能有限元模拟与真实纹理演化数据耦合评价
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-12-14 DOI: 10.1016/j.triboint.2025.111579
Yunhong Yu , Houzhi Wang , You Wu , Haopeng Wang , Yixin Zhou , Jun Yang , Wei Huang
Adequate runway friction capacity during aircraft landing is crucial for flight safety. Accurately evaluating skid resistance under realistic service conditions remains a key challenge for maintaining flight safety. This study proposes a comprehensive skid resistance evaluation method that integrates laboratory testing with finite element simulation. A refined tire-pavement-fluid coupled model was developed, incorporating measured and series-generated worn texture data as key geometric boundary conditions in numerical analysis. The coupled effects of runway texture state, tire kinematics, and water film thickness on skid resistance were systematically investigated. Results suggest that runway macrotexture plays a vital role in maintaining skid resistance, with Stone Mastic Asphalt (SMA) mixtures providing superior skid resistance compared to Asphalt Concrete (AC) mixtures. As runway wear progresses, the combined influence of high speed and thick water films significantly increases the risk of hydroplaning and extends braking distance. This study highlights the significant effects of speed, water film thickness, and texture evolution on runway friction, offering theoretical guidance for material selection and safety evaluation of airport pavements.
飞机着陆过程中,足够的跑道摩擦能力对飞行安全至关重要。准确评估实际服务条件下的防滑性能仍然是维护飞行安全的关键挑战。本研究提出一种将实验室测试与有限元模拟相结合的综合防滑性评估方法。建立了一个精细的轮胎-路面-流体耦合模型,将实测和系列生成的磨损纹理数据作为数值分析的关键几何边界条件。系统研究了跑道织构状态、轮胎运动学和水膜厚度对防滑性能的耦合影响。结果表明,跑道宏观结构在保持防滑性方面起着至关重要的作用,与沥青混凝土(AC)混合物相比,石胶泥沥青(SMA)混合物具有更好的防滑性。随着跑道磨损的加剧,高速和厚水膜的共同影响显著增加了打滑的风险,延长了制动距离。研究结果表明,速度、水膜厚度和织构演变对跑道摩擦的影响显著,为机场路面材料的选择和安全性评价提供理论指导。
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引用次数: 0
Investigation on fretting fatigue crack initiation of scale press-fitted railway axle containing axial defects 含轴向缺陷的大型压装铁路轴微动疲劳裂纹萌生研究
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-12-13 DOI: 10.1016/j.triboint.2025.111581
Dongfang Zeng , Yihui Dong , Hai Zhao , Minwei Guan , Mingming Ren , Xiang Li , Jiwang Zhang , Liantao Lu
Axial defects induced during axle disassembly/assembly represent the typical failure mode in the press-fitted region of railway axle. However, their specific influence on fretting fatigue behavior remains inadequately characterized. This study experimentally and numerically investigates fretting fatigue crack initiation in scale press-fitted axles containing artificial axial defects. It encompassed fretting fatigue testing, crack observation, fretting wear assessment, microstructure analysis of fretted zones, stress states analysis around the defect, and fatigue crack initiation prediction. Results demonstrate that the fretting fatigue strength decreases with increasing defect depth. The peak stress concentration induced by axial defects occurs at defect edges on the wheel seat surface, leading to fatigue crack initiation at these sites. In addition, axial defects produce lower stress concentration and a smaller high-stressed volume than circumferential defects, thus exerting a markedly reduced detrimental effect on the fretting fatigue strength of press-fitted axles. Given the significant effect of frictional shear stress on crack initiation, the MWCM multiaxial fatigue criterion, integrated with the critical plane method, was employed for prediction. The model, incorporating fretting wear profiles, successfully predicts the occurrence of fretting damage, as well as crack initiation location and angle. This research can provide a theoretical basis for rational assessment and management of railway axles containing axial defects.
铁路车轴拆装过程中产生的轴向缺陷是铁路车轴压合区的典型失效形式。然而,它们对微动疲劳行为的具体影响尚未充分表征。本文对含人工轴向缺陷的大型压合轴的微动疲劳裂纹萌生进行了实验和数值研究。包括微动疲劳试验、裂纹观察、微动磨损评估、微动区显微组织分析、缺陷周围应力状态分析和疲劳裂纹起裂预测。结果表明,微动疲劳强度随缺陷深度的增加而降低。轴向缺陷引起的应力峰值集中出现在车轮座表面缺陷边缘,导致这些部位产生疲劳裂纹。此外,轴向缺陷比环向缺陷产生更低的应力集中和更小的高应力体积,从而对压合轴微动疲劳强度的有害影响明显减小。考虑到摩擦剪切应力对裂纹萌生的显著影响,采用MWCM多轴疲劳准则,结合临界平面法进行预测。该模型结合微动磨损轮廓,成功地预测了微动损伤的发生,以及裂纹起裂的位置和角度。该研究可为铁路轴向缺陷的合理评估和管理提供理论依据。
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引用次数: 0
Synthesis, thermophysical properties and tribological behavior of (La0.2Nd0.2Sm0.2Eu0.2Gd0.2)2Zr2O7 high-entropy ceramics (La0.2Nd0.2Sm0.2Eu0.2Gd0.2)2Zr2O7高熵陶瓷的合成、热物理性能及摩擦学行为
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-12-13 DOI: 10.1016/j.triboint.2025.111582
Hanzhi Zhang , Jun Cheng , Juanjuan Chen , Wenyuan Chen , Jiao Chen , Hui Tan , Shengyu Zhu , Jun Yang
To promote the practical application of next-generation thermal barrier coating materials, a dense high-entropy ceramic (La0.2Nd0.2Sm0.2Eu0.2Gd0.2)2Zr2O7 was successfully synthesized via a two-step solid-state reaction method. Benefiting from the high-entropy effect, the (La0.2Nd0.2Sm0.2Eu0.2Gd0.2)2Zr2O7 ceramic exhibits a pyrochlore structure and demonstrates superior thermophysical properties. Its thermal expansion coefficient is about 11.0 × 10−6 K−1, and the thermal conductivity is 1.2 W·m−1·K−1 at 1200 ℃. Both of these properties are significantly superior to those of the widely used YSZ material. Owing to its high hardness (12.7 ± 0.8 GPa), the tribological behavior of the ceramic was systematically investigated. The results indicate that the (La0.2Nd0.2Sm0.2Eu0.2Gd0.2)2Zr2O7 ceramic shows low wear rates and good stability at both at room temperature and 1000 ℃. These comprehensive properties suggest that (La0.2Nd0.2Sm0.2Eu0.2Gd0.2)2Zr2O7 ceramic possesses considerable potential as a candidate material for the next-generation of thermal barrier coatings.
为了促进下一代热障涂层材料的实际应用,采用两步固相反应法制备了致密高熵陶瓷(La0.2Nd0.2Sm0.2Eu0.2Gd0.2)2Zr2O7。利用高熵效应,(La0.2Nd0.2Sm0.2Eu0.2Gd0.2)2Zr2O7陶瓷具有焦绿盐结构,具有优异的热物理性能。在1200℃时,其热膨胀系数约为11.0 × 10−6 K−1,导热系数为1.2 W·m−1·K−1。这两种性能都明显优于广泛使用的YSZ材料。由于其高硬度(12.7 ± 0.8 GPa),系统地研究了陶瓷的摩擦学行为。结果表明,(La0.2Nd0.2Sm0.2Eu0.2Gd0.2)2Zr2O7陶瓷在室温和1000℃下均表现出较低的磨损率和良好的稳定性。这些综合性能表明(La0.2Nd0.2Sm0.2Eu0.2Gd0.2)2Zr2O7陶瓷作为下一代热障涂层的候选材料具有相当大的潜力。
{"title":"Synthesis, thermophysical properties and tribological behavior of (La0.2Nd0.2Sm0.2Eu0.2Gd0.2)2Zr2O7 high-entropy ceramics","authors":"Hanzhi Zhang ,&nbsp;Jun Cheng ,&nbsp;Juanjuan Chen ,&nbsp;Wenyuan Chen ,&nbsp;Jiao Chen ,&nbsp;Hui Tan ,&nbsp;Shengyu Zhu ,&nbsp;Jun Yang","doi":"10.1016/j.triboint.2025.111582","DOIUrl":"10.1016/j.triboint.2025.111582","url":null,"abstract":"<div><div>To promote the practical application of next-generation thermal barrier coating materials, a dense high-entropy ceramic (La<sub>0.2</sub>Nd<sub>0.2</sub>Sm<sub>0.2</sub>Eu<sub>0.2</sub>Gd<sub>0.2</sub>)<sub>2</sub>Zr<sub>2</sub>O<sub>7</sub> was successfully synthesized via a two-step solid-state reaction method. Benefiting from the high-entropy effect, the (La<sub>0.2</sub>Nd<sub>0.2</sub>Sm<sub>0.2</sub>Eu<sub>0.2</sub>Gd<sub>0.2</sub>)<sub>2</sub>Zr<sub>2</sub>O<sub>7</sub> ceramic exhibits a pyrochlore structure and demonstrates superior thermophysical properties. Its thermal expansion coefficient is about 11.0 × 10<sup>−6</sup> K<sup>−1</sup>, and the thermal conductivity is 1.2 W·m<sup>−1</sup>·K<sup>−1</sup> at 1200 ℃. Both of these properties are significantly superior to those of the widely used YSZ material. Owing to its high hardness (12.7 ± 0.8 GPa), the tribological behavior of the ceramic was systematically investigated. The results indicate that the (La<sub>0.2</sub>Nd<sub>0.2</sub>Sm<sub>0.2</sub>Eu<sub>0.2</sub>Gd<sub>0.2</sub>)<sub>2</sub>Zr<sub>2</sub>O<sub>7</sub> ceramic shows low wear rates and good stability at both at room temperature and 1000 ℃. These comprehensive properties suggest that (La<sub>0.2</sub>Nd<sub>0.2</sub>Sm<sub>0.2</sub>Eu<sub>0.2</sub>Gd<sub>0.2</sub>)<sub>2</sub>Zr<sub>2</sub>O<sub>7</sub> ceramic possesses considerable potential as a candidate material for the next-generation of thermal barrier coatings.</div></div>","PeriodicalId":23238,"journal":{"name":"Tribology International","volume":"216 ","pages":"Article 111582"},"PeriodicalIF":6.1,"publicationDate":"2025-12-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145798599","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Superior friction and wear performance of alloy Ti4Al6V lubricated by a novel green material yam: A comparative tribological study 新型绿色材料yam润滑Ti4Al6V合金的优异摩擦磨损性能:比较摩擦学研究
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-12-12 DOI: 10.1016/j.triboint.2025.111575
Yatong Zhang , Zhiguang Guo , Weimin Liu
As a type of green lubricant, yam mucilage possesses a layered molecular structure with excellent composite lubrication properties. Considering the superior lubrication and friction-reducing effects of layered double hydroxides, this study explored the lubrication mechanisms and tribological properties of yam mucilage when applied as a lubricant. Given the poor wear resistance of Ti6Al4V (TC4) alloy, systematic tests were conducted to evaluate the lubrication, friction reduction, and wear resistance performance of yam mucilage under different loads, with dry friction and graphite-coated friction serving as controls. Notably, although both yam mucilage and graphite exhibit layered molecular structures at the microscopic level, yam mucilage demonstrated significantly better performance: under identical conditions, it reduced the average coefficient of friction by about 60.70 % compared with graphite-coated friction and by about 59.30 % compared with dry friction. In addition, yam mucilage markedly enhanced the wear resistance of the TC4 substrate, reducing the average wear volume by 69.77 % relative to dry friction and by 76.52 % relative to graphite-coated friction. These improvements are primarily attributed to the adsorption of yam mucilage molecules on the TC4 surface and the elastohydrodynamic lubrication generated during sliding, which facilitated the formation of a friction-induced in-situ protective film with self-healing capability. Overall, the use of yam mucilage lubricant, combined with the elastohydrodynamic lubrication formed against the TC4 alloy surface, promoted a friction-induced in-situ film formation mechanism that effectively protected the TC4 alloy substrate from severe wear.
山药黏液具有层状的分子结构,具有优异的复合润滑性能,是一种绿色润滑剂。考虑到层状双氢氧化物优异的润滑和减摩效果,本研究探讨了山药黏液作为润滑剂时的润滑机理和摩擦学性能。针对Ti6Al4V (TC4)合金耐磨性较差的特点,以干摩擦和涂石墨摩擦为对照,对山药黏液在不同载荷下的润滑、减摩和耐磨性能进行了系统的试验研究。值得注意的是,虽然山药黏液和石墨在微观水平上都表现出分层的分子结构,但山药黏液表现出明显更好的性能:在相同的条件下,山药黏液与涂有石墨的摩擦相比,平均摩擦系数降低了约60.70 %,与干摩擦相比,平均摩擦系数降低了约59.30 %。此外,山药黏液显著提高了TC4基体的耐磨性,相对于干摩擦,TC4基体的平均磨损量减少了69.77 %,相对于涂石墨摩擦,TC4基体的平均磨损量减少了76.52 %。这些改进主要归功于山药黏液分子在TC4表面的吸附和滑动过程中产生的弹流动力润滑,这有助于形成具有自修复能力的摩擦原位保护膜。总体而言,山药黏液润滑剂的使用与TC4合金表面形成的弹流动力润滑相结合,促进了摩擦诱导的原位膜形成机制,有效地保护了TC4合金衬底免受严重磨损。
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引用次数: 0
Effect of graphene on microstructure and tribological properties of FLG/SiC/TC4 composites prepared by vacuum arc melting 石墨烯对真空电弧熔炼FLG/SiC/TC4复合材料微观结构和摩擦学性能的影响
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2025-12-12 DOI: 10.1016/j.triboint.2025.111574
Rongyang Zhao , Baoxian Su , Yinling Jin , Zhenjie Cui , Binbin Wang , Xiangyu Sun , Bao Ding , Chao Xu , Eshov Bakhtiyor , Chen Liu , Liang Wang , Yanqing Su
Ti-6Al-4V (TC4) alloy, characterized by low density, high tensile and fatigue strengths, and excellent corrosion resistance, is a vital material widely used in aerospace, chemical engineering, energy, and biomedicine. However, its poor strain-hardening effect and weak protective mechanically mixed layer (MML, a surface layer formed by mechanical actions with material mixing) limit its tribological applications. In this study, few-layer graphene (FLG)/SiC/TC4 composites were fabricated via vacuum arc melting, with SiC added to suppress the reaction between FLG and the matrix. The effects of FLG content on mechanical properties and wear resistance were investigated. Results show that moderate FLG addition promotes the formation of a continuous, dense MML during dry friction, protecting the matrix and lowering the wear rate. The composite with 0.4 wt% FLG shows excellent tensile strength and wear resistance, with its tensile strength increasing from 839.57 MPa of pure TC4–939.25 MPa, the depth of plastic deformation zone after wear becoming shallower, and the wear rate significantly decreasing by 52.15 %.
Ti-6Al-4V (TC4)合金具有密度低、抗拉强度和疲劳强度高、耐腐蚀性能优异等特点,是广泛应用于航空航天、化工、能源、生物医药等领域的重要材料。然而,其应变硬化效果差,保护性机械混合层(MML,材料混合形成的机械作用表面层)薄弱,限制了其摩擦学应用。本研究采用真空弧熔法制备了少层石墨烯(FLG)/SiC/TC4复合材料,加入SiC抑制FLG与基体的反应。研究了FLG含量对材料力学性能和耐磨性的影响。结果表明:适量添加FLG可促进干摩擦过程中连续致密的MML的形成,保护基体,降低磨损率;含有0.4 wt% FLG的复合材料具有优异的抗拉强度和耐磨性,其抗拉强度从纯tc4的839.57 MPa提高到939.25 MPa,磨损后塑性变形区深度变浅,磨损率显著降低52.15 %。
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Tribology International
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