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Effect of efficient structural tuning on the microstructure, corrosion resistance, and wear performance of AlCoCrFeNi/AT13 composite coatings 高效结构调整对 AlCoCrFeNi/AT13 复合涂层微观结构、耐腐蚀性和磨损性能的影响
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-11-07 DOI: 10.1016/j.triboint.2024.110377
Kaicheng Zhang , Zenan Su , Shiyao Xu , Lintao Wu , Xin Zhang , Zehua Zhou , Guangyu Wang
This study developed a rapid structure control technique for AlCoCrFeNi/AT13 (Al₂O₃–13 % TiO₂) composite coatings using plasma spraying and dual powder feeding. Four coatings were fabricated: pure HEA, HEA-D (dispersed), HEA-S1 (multilayer with outer HEA), and HEA-S2 (multilayer with outer AT13). The introduction of AT13 altered the internal stress distribution and enhanced corrosion resistance by lowering the electrochemical reaction rate. In layered coatings (HEA-S1, HEA-S2), the AT13 interlayer barrier reduced corrosion tendency. Additionally, pure HEA coatings exhibited adhesive wear. While HEA-D coatings experienced abrasive wear as AT13 particles improved plastic deformation and interface shearing. HEA-S1 reduced strain and wear via an internal AT13 layer. HEA-S2 achieved superior abrasion resistance through an outer AT13 layer, exhibiting typical abrasive wear mechanisms.
本研究采用等离子喷涂和双粉喂料技术,开发了一种铝钴铬铁镍/AT13(Al₂O₃-13 % TiO₂)复合涂层的快速结构控制技术。共制作了四种涂层:纯 HEA、HEA-D(分散)、HEA-S1(外层为 HEA 的多层)和 HEA-S2(外层为 AT13 的多层)。AT13 的引入改变了内应力分布,并通过降低电化学反应速率增强了耐腐蚀性。在分层涂层(HEA-S1、HEA-S2)中,AT13 层间阻挡层降低了腐蚀倾向。此外,纯 HEA 涂层表现出粘着磨损。由于 AT13 颗粒改善了塑性变形和界面剪切,HEA-D 涂层出现了磨料磨损。HEA-S1 通过内部 AT13 层减少了应变和磨损。HEA-S2 通过外层 AT13 实现了优异的耐磨性,表现出典型的磨损机制。
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引用次数: 0
Enhanced braking performance of copper metal matrix composites incorporating fine mosaic pitch coke when mated with 30CrMnVA and C/C-SiC 与 30CrMnVA 和 C/C-SiC 配合使用时,掺入细镶嵌沥青焦的铜金属基复合材料的制动性能得到增强
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-11-06 DOI: 10.1016/j.triboint.2024.110378
Yuxuan Xu , Donglin Liu , Qi Chen , Peiyu Zhou , Ziyi Liu , Xing Wang , Minwen Deng , Haibin Zhou , Yong Han , Pingping Yao
By substituting 10 wt% of conventional graphite particles, pitch coke particles with fine mosaics demonstrate superior performance in enhancing the braking properties of copper metal matrix composites (CMMCs) operating at various conditions. When mated with C/C-SiC, the coefficient of friction increases by 18.6 % at low speeds and 38.8 % at high braking speeds, along with a significant enhancement in wear resistance across various counterparts. This improvement is attributed to the incorporation of pitch coke with fine mosaics and superior mechanical properties, which not only imparts high thermal capacity and mechanical strength to the CMMCs but also fosters a synergistic interaction between pitch coke and the iron oxide layer, stabilizing the friction layer.
通过替代 10 wt%的传统石墨颗粒,具有细小马赛克的沥青焦颗粒在提高铜金属基复合材料(CMMC)在各种条件下的制动性能方面表现出了卓越的性能。当与 C/C-SiC 配合使用时,低速摩擦系数增加了 18.6%,高速制动时增加了 38.8%,同时在各种对应条件下的耐磨性也显著增强。这种改善归功于沥青焦的加入,沥青焦具有精细的镶嵌和卓越的机械性能,不仅为 CMMC 带来了高热容量和机械强度,还促进了沥青焦和氧化铁层之间的协同作用,稳定了摩擦层。
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引用次数: 0
Effects of various laser cladding materials on the tribological properties of damaged wheel treads under various temperatures and humidities 各种激光熔覆材料在不同温度和湿度条件下对受损车轮胎面摩擦学特性的影响
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-11-06 DOI: 10.1016/j.triboint.2024.110374
Chenggang He , Gang Zou , Xinji Wang , Haiqiao Liu , Peng Li , Jihua Liu , Siuming Lo
Laser cladding technology is used to repair damaged wheels and plays an important role in prolonging their service life. Additionally, the temperature and humidity of the environment have important effects on the operation of the repaired wheels. In this study, widely used 316 L and 420 stainless steel alloy powders were selected as cladding materials, and three environmental conditions (25℃-RH60 %, 50℃-RH60 %, and 50℃-RH90 %) were set according to changes in temperature and humidity in different areas of China. Friction and wear tests were performed under different temperature and humidity conditions on a damaged wheel after local repair by laser cladding. The results clearly show that there are demarcated equiaxed and directional columnar grain regions in the 316 L cladding, whereas there are uniform plate and strip martensite structures in the 420 cladding, which are well formed by the metallurgical bonding of the wheel substrate. From 25℃-RH60 % to 50℃-RH90 %, the friction coefficient, plastic deformation thickness, and wear rate of the wheel–rail tended to decrease. However, the wear rates of the 420-coated wheels increased as the environmental conditions increased from 25 °C-RH60 % and 50 °C-RH60 %, and the wear rates of the corresponding rail samples remained high. The main forms of surface damage are fatigue cracks and material spalling. With increasing temperature and humidity, the damage to the bonding zone between the cladding and substrate surface decreases. The damage to the cladding profile is caused mainly by cracks at different angles and spalling pits. In the 25 °C-RH60 % environment, cracks initiate in the profile of the bonding zone and propagate along the plastic rheological line to the interior of the material. In comparison, the locally repaired wheel with 316 L stainless steel alloy powder as the laser cladding material has better tribological properties and is more suitable for repairing damaged wheels.
激光熔覆技术用于修复损坏的车轮,在延长其使用寿命方面发挥着重要作用。此外,环境的温度和湿度对修复后车轮的运行也有重要影响。本研究选择了广泛使用的 316 L 和 420 不锈钢合金粉末作为覆层材料,并根据中国不同地区的温度和湿度变化设定了三种环境条件(25℃-RH60 %、50℃-RH60 % 和 50℃-RH90 %)。在不同温湿度条件下,对激光熔覆局部修复后的受损轮毂进行了摩擦磨损试验。结果表明,316 L堆焊层中存在分界的等轴晶粒区和定向柱状晶粒区,而420堆焊层中存在均匀的板状和条状马氏体结构,轮毂基体冶金结合良好。从 25℃-RH60%到 50℃-RH90%,轮轨的摩擦系数、塑性变形厚度和磨损率都呈下降趋势。然而,随着环境条件从 25 ℃-RH60 % 和 50 ℃-RH60 % 的升高,420 涂层车轮的磨损率也随之升高,而相应钢轨样品的磨损率仍然很高。表面损伤的主要形式是疲劳裂纹和材料剥落。随着温度和湿度的升高,覆层与基体表面之间的粘合区的损坏程度降低。覆层轮廓的损坏主要由不同角度的裂纹和剥落坑造成。在 25 °C-RH60 % 的环境中,裂纹从粘合区的剖面开始,沿着塑性流变线向材料内部扩展。相比之下,使用 316 L 不锈钢合金粉末作为激光熔覆材料的局部修复车轮具有更好的摩擦学特性,更适合修复受损车轮。
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引用次数: 0
Tribological properties of polyimide coating filled with solvent-free covalent carbon quantum dots nanofluids 无溶剂共价碳量子点纳米流体填充聚酰亚胺涂层的摩擦学特性
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-11-06 DOI: 10.1016/j.triboint.2024.110376
Baokai Zhang , Xianqiang Pei , Yanming Wang , Shanhong Wan , Gai Zhao , Qihua Wang , Tingmei Wang
Novel organic coatings were developed by incorporating solvent-free covalent carbon quantum dots nanofluids (CQDs NFs) into a polyimide (PI) matrix. The tribological properties of CQDs NFs/PI composite coatings were tested using a ball-on-disk tribometer, revealing that even a low loading of CQDs NFs significantly improved tribological performance of PI. Molecular dynamics (MD) simulations and nanoindentation tests showed that CQDs NFs restricted PI molecular chain movement, enhancing mechanical properties. Additionally, CQDs NFs promoted the formation of stable transfer films on steel surfaces, improving wear resistance. This study confirms CQDs NFs' effectiveness in modifying PI composite coatings' friction and wear properties.
通过在聚酰亚胺(PI)基体中加入无溶剂共价碳量子点纳米流体(CQDs NFs),开发出了新型有机涂层。使用球盘摩擦磨损仪测试了 CQDs NFs/PI 复合涂层的摩擦学性能,结果表明即使 CQDs NFs 的负载量很低,也能显著改善 PI 的摩擦学性能。分子动力学(MD)模拟和纳米压痕测试表明,CQDs NFs 限制了 PI 分子链的运动,从而提高了机械性能。此外,CQDs NFs 还能促进钢表面形成稳定的转移膜,从而提高耐磨性。这项研究证实了 CQDs NFs 在改变 PI 复合涂层的摩擦和磨损性能方面的有效性。
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引用次数: 0
Achieving considerable wear resistance in new Ti-based high-entropy alloys through microstructural hardening by adding Nb 通过添加 Nb 进行微结构硬化,在新型钛基高熵合金中实现可观的耐磨性
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-11-06 DOI: 10.1016/j.triboint.2024.110379
Zhiwei Wang , Yongcun Li , Hang Dong , Yong Wang
In this study, (CoCrNiMn)78Ti22−xNbx eutectic high-entropy alloys were successfully synthesised via an arc melting process under vacuum, and the phase structure, microstructure, mechanical properties and dry sliding tribological behaviour of the alloys were systematically investigated. The XRD results for the (CoCrNiMn)78Ti22−xNbx eutectic high-entropy alloys are almost in agreement with the JMatPro phase diagram simulations, and the volume fraction of the Laves phase increased with increasing Nb content. OM and SEM images revealed that the microstructure was composed of dendrites (BCC A2) and interdendrites (BCC B2 +Laves) and changed from a hypoeutectic to a eutectic to a BCC B2 +Laves dual-phase structure, with the average grain size decreasing from 6.715 µm to 6.391 µm. Ti promoted the growth of the layered Laves phase and provided the alloy with base hardness and wear resistance. The hardness of the alloy combination of 21 % Ti and 1 % Nb reached the maximum value of 707.04 HV, whereas the average coefficient of friction (COF) and wear rate reached the lowest values of 0.49 and 1.668 × 10−4 mm3/N·m, respectively. With increasing load, the wear mechanism was mixed fatigue, delamination wear, and abrasive wear accompanied by oxidation, and the possibility of three-body wear paths between compacted tribolayers cannot be excluded. The debris was mostly in the form of microclusters, and the particle size range was concentrated between 1 −2 µm; meanwhile, the shape of the debris tended to develop from lamellar to spherical with increasing hardness.
本研究通过真空电弧熔炼工艺成功合成了(CoCrNiMn)78Ti22-xNbx 共晶高熵合金,并系统研究了合金的相结构、显微组织、力学性能和干滑动摩擦行为。(CoCrNiMn)78Ti22-xNbx 共晶高熵合金的 XRD 结果与 JMatPro 相图模拟结果基本一致,并且随着 Nb 含量的增加,Laves 相的体积分数也在增加。OM 和 SEM 图像显示,微观结构由树枝状晶(BCC A2)和树枝间晶(BCC B2 +Laves)组成,从低共晶到共晶再到 BCC B2 +Laves 双相结构,平均晶粒尺寸从 6.715 µm 减小到 6.391 µm。钛促进了层状 Laves 相的生长,并为合金提供了基本硬度和耐磨性。含 21% Ti 和 1% Nb 的合金组合的硬度达到最大值 707.04 HV,而平均摩擦系数(COF)和磨损率则分别达到最低值 0.49 和 1.668 × 10-4 mm3/N-m。随着载荷的增加,磨损机理为混合疲劳、分层磨损和伴有氧化的磨料磨损,不排除压实摩擦层之间存在三体磨损路径的可能性。碎屑大多以微簇的形式存在,粒度范围集中在 1 -2 µm 之间;同时,随着硬度的增加,碎屑的形状趋向于从片状发展为球状。
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引用次数: 0
Prediction of grease performance and optimal additive ratio based on the SSA-GDA-LSSVM model 基于 SSA-GDA-LSSVM 模型的润滑脂性能和最佳添加剂比例预测
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-11-05 DOI: 10.1016/j.triboint.2024.110366
Yanqiu Xia, Hanbin Zhao, Xin Feng
In this paper, to address the issue of compounding three additives in PTFE grease, we propose a machine learning model based on SSA-GDA-LSSVM to predict both the tribological performance and the optimal ratio of additives in PTFE grease. Gaussian data augmentation expanded the experimental data, and the Sparrow Algorithm optimized hyperparameters of the Least Squares Support Vector Machine. SHAP analysis clarified model predictions, and a Non-Dominated Sorting Genetic Algorithm identified optimal additive ratios, which were experimentally validated. The results showed that the model predicted friction coefficients and wear scar widths with R² values exceeding 0.97, and the experimental error for optimal ratios was less than 1 %.
本文针对聚四氟乙烯润滑脂中三种添加剂的复配问题,提出了一种基于 SSA-GDA-LSSVM 的机器学习模型,用于预测聚四氟乙烯润滑脂的摩擦学性能和添加剂的最佳配比。高斯数据增强扩展了实验数据,麻雀算法优化了最小二乘支持向量机的超参数。SHAP 分析澄清了模型预测,非支配排序遗传算法确定了最佳添加剂比率,并通过实验进行了验证。结果表明,模型预测的摩擦系数和磨损疤痕宽度的 R² 值超过了 0.97,最佳比率的实验误差小于 1%。
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引用次数: 0
Fabrication and tribological properties of bionic surface texture self-lubricating 60NiTi alloy via selective laser melting and infiltration 通过选择性激光熔融和浸润技术制造仿生表面纹理自润滑 60NiTi 合金及其摩擦学特性
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-11-05 DOI: 10.1016/j.triboint.2024.110364
Xiaofei Yan , Hua Yan , Peilei Zhang , Qinghua Lu , Haichuan Shi
Due to its low elastic modulus, low density, non-magnetic and good lubricity, 60NiTi alloy is considered a novel fourth-generation aerospace bearing material. In this paper, 60NiTi biomimetic surface textured self-lubricating composites were fabricated by selective laser melting (SLM) and high-temperature fusion infiltration (HTFI). The effects of different slit widths (NTD), edge lengths (NTA), and soft metal Sn-Pb-Ag (SPA) infiltration on its tribological properties were studied. The results show that the NTA-SPA structural samples with medium texture density (ρ = 16 %) promoted the diffusion of the lubricant phase to the friction surface, resulting in a complete lubricant film. The COF stabilized at 0.2, and the wear rate decreased to 0.56 × 10−3 mm3/Nm, providing a more stable self-lubrication effect compared to the NTD-SPA sample.
60NiTi 合金具有弹性模量低、密度小、无磁性、润滑性好等特点,被认为是第四代新型航空轴承材料。本文采用选择性激光熔融(SLM)和高温熔渗(HTFI)技术制备了 60NiTi 仿生物表面纹理自润滑复合材料。研究了不同缝隙宽度(NTD)、边缘长度(NTA)和软金属锡铅汞(SPA)浸润对其摩擦学性能的影响。结果表明,具有中等纹理密度(ρ = 16 %)的 NTA-SPA 结构样品促进了润滑剂相向摩擦表面的扩散,形成了完整的润滑膜。COF 稳定在 0.2,磨损率降至 0.56 × 10-3 mm3/Nm,与 NTD-SPA 样品相比,自润滑效果更加稳定。
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引用次数: 0
A study on the particle emission from cobalt-free studded tires against road materials 无钴有铆钉轮胎与路面材料的颗粒排放研究
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-11-05 DOI: 10.1016/j.triboint.2024.110365
Ulf Olofsson , Erik Holmström , Yezhe Lyu
The use of studded tires can cause significant wear of road surfaces then also affect the air quality in urban areas. The studs of today’s studded tires are manufactured from hard metal containing cobalt. In this study, we investigated using alternative cobalt-free hard metal studs to reduce particulate emissions in the future. The tire-to-road interface is subjected to both impact wear and sliding abrasive wear. The alternative hard metal studs were evaluated in parallel with standard studs using two different laboratory test rigs specially designed for wear and particulate emission testing. Stone materials commonly used in the road tarmacadam were utilized as counter material. The results showed that the cobalt-free studs generated lower particle concentrations and less road wear.
使用带钉轮胎会对路面造成严重磨损,还会影响城市地区的空气质量。现在的有铆钉轮胎的铆钉是用含钴的硬金属制造的。在这项研究中,我们调查了使用替代性无钴硬金属钉来减少未来微粒排放的情况。轮胎与路面的接触面会受到冲击磨损和滑动磨料磨损。我们使用专门为磨损和颗粒排放测试设计的两种不同的实验室测试设备,对替代硬质金属螺柱和标准螺柱进行了平行评估。路面柏油路面常用的石料被用作反向材料。结果表明,无钴螺柱产生的颗粒浓度较低,路面磨损也较小。
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引用次数: 0
Calculation and analysis of wet clutch sliding torque based on fluid-solid coupling dynamic behavior 基于流固耦合动态行为的湿式离合器滑动扭矩计算与分析
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-11-05 DOI: 10.1016/j.triboint.2024.110363
Jiaxi Jin , Xueliang Li , Shujun Yang , Haidi Yi , Haodong Sun , Wenqi Hao
The fluid dynamics equations of groove cavity and non-grooved gap are established and combined to obtain fluid load bearing model. Considering the chain effect among local deformation, the deformation equation of friction surface under fluid-solid coupling load is developed to characterize reconstructed friction gap. The internal pressure and external load are used to iteratively solve the distribution of film thickness and contact area. An improved sliding torque calculation model is established by the microscopic state of fluid motion and solid deformation instead of fitting friction coefficient by multiple conditions. The accuracy of torque model is proved by sliding test. The influence of applied pressure, relative speed and lubricant flow on torque is weakened in turn according to fluid-solid state analysis.
建立了沟槽腔和无沟槽间隙的流体动力学方程,并将其结合起来,得到了流体承载模型。考虑到局部变形之间的连锁效应,建立了流固耦合载荷作用下摩擦面的变形方程,以表征重建的摩擦间隙。利用内部压力和外部载荷迭代求解摩擦膜厚度和接触面积的分布。通过流体运动和固体变形的微观状态建立了改进的滑动扭矩计算模型,而不是通过多重条件拟合摩擦系数。通过滑动试验证明了扭矩模型的准确性。根据流固状态分析,依次削弱了外加压力、相对速度和润滑剂流动对扭矩的影响。
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引用次数: 0
Tribological behaviour of DIN 1.2740 hot working tool steel during mandrel mill stretching process DIN 1.2740 热加工工具钢在芯轴轧机拉伸过程中的摩擦学特性
IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-11-04 DOI: 10.1016/j.triboint.2024.110361
Hamed Aghajani Derazkola , Dieter Fauconnier , Ádám Kalácska , Eduardo Garcia , Alberto Murillo-Marrodán , Patrick De Baets
This study evaluates the tribological properties of DIN 1.2740 hot tool steel against Super Cr13 martensitic stainless steel at 700 °C. The results show that the coefficient of friction (COF) ranged from 0.15 to 0.63, indicating moderate frictional interaction. The wear rate of DIN 1.2740 was observed to be low, suggesting good resistance to wear at high temperatures. The complex surface oxide layer that formed on the pin’s top surface, significantly reducing the COF and acting as a solid lubricant at elevated temperatures. The oxide layer was also fragile and unable to withstand the high sliding velocities and high loads. The steel exhibited a high surface roughness when subjected to increasing normal loads and increasing sliding velocities.
本研究评估了 DIN 1.2740 热工具钢与超级 Cr13 马氏体不锈钢在 700 °C 下的摩擦学特性。结果表明,摩擦系数(COF)在 0.15 至 0.63 之间,表明摩擦作用适中。DIN 1.2740 的磨损率较低,表明在高温下具有良好的耐磨性。销顶表面形成了复杂的表面氧化层,大大降低了 COF 值,并在高温下起到了固体润滑剂的作用。氧化层也很脆弱,无法承受高滑动速度和高负载。在承受越来越大的法向载荷和越来越高的滑动速度时,钢的表面粗糙度很高。
{"title":"Tribological behaviour of DIN 1.2740 hot working tool steel during mandrel mill stretching process","authors":"Hamed Aghajani Derazkola ,&nbsp;Dieter Fauconnier ,&nbsp;Ádám Kalácska ,&nbsp;Eduardo Garcia ,&nbsp;Alberto Murillo-Marrodán ,&nbsp;Patrick De Baets","doi":"10.1016/j.triboint.2024.110361","DOIUrl":"10.1016/j.triboint.2024.110361","url":null,"abstract":"<div><div>This study evaluates the tribological properties of DIN 1.2740 hot tool steel against Super Cr13 martensitic stainless steel at 700 °C. The results show that the coefficient of friction (COF) ranged from 0.15 to 0.63, indicating moderate frictional interaction. The wear rate of DIN 1.2740 was observed to be low, suggesting good resistance to wear at high temperatures. The complex surface oxide layer that formed on the pin’s top surface, significantly reducing the COF and acting as a solid lubricant at elevated temperatures. The oxide layer was also fragile and unable to withstand the high sliding velocities and high loads. The steel exhibited a high surface roughness when subjected to increasing normal loads and increasing sliding velocities.</div></div>","PeriodicalId":23238,"journal":{"name":"Tribology International","volume":"202 ","pages":"Article 110361"},"PeriodicalIF":6.1,"publicationDate":"2024-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142660424","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Tribology International
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