Owing to their unique layered hexagonal crystal structure and hybrid metallic-covalent bonding characteristics, Cr2AlC MAX-phase ceramics exhibit outstanding thermal conductivity, oxidation resistance, and thermal stability at elevated temperatures. These properties render them highly sought after for tribological systems operating in extreme environments. This work investigates the dry sliding tribological behaviour of Cr2AlC films in air between 700 and 900 ℃, examining the temperature-dependent evolution of their friction and wear characteristics, as well as the corresponding oxidation protection mechanisms. Results indicate that the coefficient of friction decreases progressively with increasing temperature, while the wear rate exhibits a non-monotonic trend, initially increasing followed by a reduction. At 900 ℃, the wear rate diminishes significantly to 1.2 × 10−5 mm3/(N·m), demonstrating exceptional high-temperature lubrication performance. This superior performance is primarily attributed to the in situ formation of a continuous, dense Cr2O3-Al2O3 composite oxide film on the friction contact surface. This oxide film not only enhances the material's shear resistance but also effectively isolates direct contact between the mating surfaces, thereby transforming the wear mechanism from abrasive wear-dominated to oxide film lubrication-dominated. Furthermore, in high-temperature oxidation experiments, the selective outward diffusion of Al serves as the key driver for the formation of the protective Al2O3 layer. As temperatures rise further, Cr tends to precipitate at Al₂O₃ grain boundaries or defect sites, effectively filling microscopic diffusion channels within the oxide layer and enhancing structural integrity. This research provides new insights for the design and application of MAX phase ceramics in high-temperature friction systems.
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