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A review of water valuation metrics: Supporting sustainable water use in manufacturing 水资源评估指标综述:支持制造业可持续用水
IF 5.1 3区 工程技术 Q1 WATER RESOURCES Pub Date : 2023-06-01 DOI: 10.1016/j.wri.2022.100199
Sujit Das , Heidi Fuchs , Ritu Philip , Prakash Rao

In the manufacturing sector, water has been often considered too cheap to conserve. Such thinking relies on water valuations that limit the value of water to the price paid. Using such simple methods, the share of water cost to total manufacturing cost is significantly small, <3%. As a result, conserving water and enabling technology uptake is difficult to justify economically and slow to advance, hindering progress toward sustainable water use.

However, the value of water to a manufacturer is far greater than the price paid. Valuations such as the true cost of water consider the additional in-plant treatment and energy costs and have been gaining greater traction in the manufacturing sector. However, true cost alone still undervalues water by not accounting for economic and social costs related to scarcity and environmental externalities.

This paper makes the case and presents a framework for valuing manufacturing water beyond the price paid and the true cost. The proposed fuller valuation of manufacturing water takes into account the internal and opportunity costs associated with the realization of water risks. The paper follows with a review of a wide range of water valuation metrics, both at the specific industry level and regional/economy-wide level. The use of various valuation metrics incorporating the relationship between the change in value with change in water use, such as marginal value of water, shadow price, and elasticity at the specific industry level, has been limited in the U.S. manufacturing sector. Further, a limited number of studies exist on data-intensive subjective evaluation techniques such as computable general equilibrium modeling and input-output modeling for regional water valuation.

After reviewing water value metrics, several recent case studies from manufacturers from the literature are presented to illustrate both the promise and challenges of a fuller valuation of water as proposed here. Some large multinational corporations have moved toward assessing the value of water via supply chain sustainability initiatives, environmental profit and loss accounting, estimating risk-adjusted values of water, hydro-economic modeling, natural capital asset valuation, and developing value chain indices. This paper provides policymakers and technology developers a framework for monetizing water value beyond its true cost and current metrics. If adopted, such fuller water valuations can help make the business case for the development and deployment of cost-effective water-conserving technologies, thereby improving the sustainability of the manufacturing sector with respect to water.

在制造业,人们常常认为水太便宜而无法节约。这种想法依赖于水的估值,将水的价值限制在支付的价格上。使用这种简单的方法,水成本占总制造成本的份额非常小,为3%。因此,节约用水和促进技术吸收在经济上很难证明是合理的,而且进展缓慢,阻碍了可持续用水方面的进展。然而,水对制造商的价值远远大于所支付的价格。水的真实成本等估值考虑了额外的厂内处理和能源成本,并在制造业获得了更大的吸引力。然而,单纯的真实成本仍然低估了水的价值,因为它没有考虑到与稀缺和环境外部性有关的经济和社会成本。本文提出了一个超越支付的价格和真实成本来评估生产用水的框架。建议对生产用水进行更全面的评估,考虑到与实现水风险相关的内部成本和机会成本。本文随后对具体行业层面和区域/经济层面的各种水价值评估指标进行了回顾。在美国制造业中,各种评估指标的使用受到了限制,这些评估指标结合了价值变化与用水变化之间的关系,如水的边际价值、影子价格和特定行业层面的弹性。此外,关于数据密集的主观评价技术的研究数量有限,如可计算的一般平衡模型和区域水评价的投入产出模型。在回顾了水价值指标之后,本文从文献中介绍了几个最近来自制造商的案例研究,以说明本文提出的更全面的水价值评估的前景和挑战。一些大型跨国公司已经转向通过供应链可持续性倡议、环境损益核算、估计水的风险调整价值、水文经济模型、自然资本资产评估和开发价值链指数来评估水的价值。本文为政策制定者和技术开发人员提供了一个框架,使水的价值超越其真实成本和当前指标。如果采用这种更充分的水资源估价,可以帮助为发展和部署成本效益高的节约用水技术提供商业理由,从而改善制造业在水资源方面的可持续性。
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引用次数: 2
Natural deep eutectic solvent based ultrasound assisted liquid-liquid micro-extraction method for methyl violet dye determination in contaminated river water 天然深共晶溶剂超声辅助液-液微萃取法测定污染河水中甲基紫染料
IF 5.1 3区 工程技术 Q1 WATER RESOURCES Pub Date : 2023-06-01 DOI: 10.1016/j.wri.2023.100210
Hameed Ul Haq , Azmat Wali , Faisal Safi , Muhammad Balal Arain , Lingshuai Kong , Grzegorz Boczkaj

Simple and green natural deep eutectic solvent (NADES) based ultrasound assisted liquid-liquid micro-extraction (UA-LLME) method was developed for extraction and determination of methyl violet dye in contaminated river water samples using UV/Vis spectrophotometry. Choline chloride - decanoic acid based natural deep eutectic solvent was used for extraction. Important analytical parameters like pH, deep eutectic solvent volume/phase ratio, tetrahydrofuran volume, sonication time, and temperature were optimized. Limit of detection (LOD) and limit of quantification (LOQ) were 2.20 μg/L and 7.34 μg/L respectively. Relative standard deviation was 2.35–3.21%. Linearity of method was investigated in a concentration range 10–400 μg/L. Enrichment factor was calculated as 20. For 20 mL sample, the optimized parameters were as deep eutectic solvent volume 1.5 mL, tetrahydrofuran volume was 0.6 mL, pH = 6, sonication time 2 min. The optimized method was tested for extraction of methyl violet in real water samples confirming its applicability in routine environmental analysis.

建立了一种简单、绿色的天然深共熔溶剂(NADES)超声辅助液液微萃取(UA-LLME)方法,紫外/可见分光光度法提取并测定污染河样中甲基紫染料。采用氯化胆碱-癸酸天然深共熔溶剂进行萃取。优化了pH、深度共晶溶剂体积/相比、四氢呋喃体积、超声时间和温度等重要分析参数。检测限和定量限分别为2.20 μg/L和7.34 μg/L。相对标准偏差为2.35 ~ 3.21%。在10 ~ 400 μg/L浓度范围内考察了方法的线性关系。富集系数计算为20。对20 mL样品,优化参数为:深度共晶溶剂体积1.5 mL,四氢呋喃体积0.6 mL, pH = 6,超声时间2 min。对实际水样中甲基紫的提取进行了实验,验证了优化方法在常规环境分析中的适用性。
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引用次数: 7
Condensate as a water source in terrestrial and extra-terrestrial conditions 在地球和地外环境中作为水源的凝结水
IF 5.1 3区 工程技术 Q1 WATER RESOURCES Pub Date : 2023-06-01 DOI: 10.1016/j.wri.2022.100196
Anna Jurga , Anna Pacak , Demis Pandelidis , Bartosz Kaźmierczak

A condensate generated from air in air conditioning (AC) units is a reliable, and a stable source of water possible to be reused in different forms. This study focuses on condensate recovery from heating ventilation air conditioning (HVAC) systems maintaining ambient or indoor air. The database of experiments conducted in outdoor air is much larger than those conducted in indoor air. The experiments conducted in greenhouses, plant factories, vertical farms, and space systems and applications come with assistance The latter include facilities such as the International Space Station and closed analog ecosystems simulating future space bases. In these locations, condensate is mainly recovered for crew needs (consumption, hygiene, etc.). From these studies it is possible to derive knowledge of what treatment processes are required to obtain water of high quality. In general, the most important parameters affecting the quantity and quality of recovered condensate are climate zone and associated climate parameters, building type, building use, and supply air volume. Additionally in case of indoor air recovery, the most important parameters are the climatic conditions, people activity, plant types grown, and whether the system has to operate in a closed loop. Other important parameters influencing condensate composition is construction and material of the HVAC system and the condensate capture system. The growing interest in the market for vertical farms and closed-loop grow chambers is observed globally. Thus, this study will favor future research on condensate recovery from these facilities. This paper deepens the look at the problem of HVAC condensate recovery by including previously not considered places such as closed ecological systems, where condensate is used for drinking water purposes.

空调(AC)机组中空气产生的冷凝水是一种可靠的、稳定的水源,可以以不同的形式重复使用。本研究的重点是采暖通风空调(HVAC)系统维持环境或室内空气的冷凝水回收。在室外空气中进行的实验数据库比在室内空气中进行的实验数据库大得多。在温室、植物工厂、垂直农场和空间系统和应用中进行的实验得到了协助,后者包括国际空间站和模拟未来空间基地的封闭模拟生态系统等设施。在这些地方,冷凝水主要用于船员需求(消费、卫生等)。从这些研究中,我们可以了解需要什么样的处理过程才能获得高质量的水。一般来说,影响回收冷凝水数量和质量的最重要参数是气候带及相关气候参数、建筑类型、建筑用途和送风量。此外,在室内空气回收的情况下,最重要的参数是气候条件,人的活动,种植的植物类型,以及系统是否必须在闭环中运行。影响凝结水组成的其他重要参数是暖通空调系统和凝结水捕获系统的结构和材料。全球对垂直农场和闭环生长室市场的兴趣日益浓厚。因此,这项研究将有利于未来对这些设施的凝析油回收的研究。本文通过包括以前未考虑的地方,如封闭生态系统,其中冷凝水用于饮用水目的,加深了对暖通空调冷凝水回收问题的关注。
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引用次数: 3
The effects of fermented olive mill wastewater mixtures on the growth and development of bean (phaseolus vulgaris) 发酵橄榄厂废水对豆科植物生长发育的影响
IF 5.1 3区 工程技术 Q1 WATER RESOURCES Pub Date : 2023-06-01 DOI: 10.1016/j.wri.2023.100201
Zaydoun Abu Salem , Kamel Alzboon , Jalal Al-Tabbal , Moawiya A. Haddad , Nabeel M. Bani-Hani

The extraction of olive oil generates considerable volumes of an agricultural by-product, olive mill wastewater (OMWW), which is damaging to the environment and biological life. To investigate the effect of fermented OMWW on number of pods, pod length, pod weight, dry weight of plant, chlorophyll a, chlorophyll b, and total chlorophyll of common bean, plants were grown and irrigated with various percentages of fermented OMWW (0%, 4%, 6%, 8%, 10%, and 100%) in a greenhouse. The study found that irrigating agricultural land with a water mix containing a specified quantity of OMWW enhanced physicochemical parameters and influenced plant characteristics. The plant characteristics were substantially affected when wastewater irrigated agricultural areas with water polluted with OMWW at concentrations no more than 4%. According to the findings of this study, utilizing 4% OMWW resulted in the best bean plant growth response, with an increase in growth indices and photosynthetic pigments.

橄榄油的提取会产生大量的农业副产品,即橄榄油厂废水(OMWW),这对环境和生物生命都是有害的。为了研究发酵OMWW对普通豆的荚果数、荚果长、荚果重、植株干重、叶绿素a、叶绿素b和总叶绿素的影响,在温室中以不同比例(0%、4%、6%、8%、10%和100%)的发酵OMWW进行种植和灌溉。研究发现,用含有一定量OMWW的混合水灌溉农田,可以提高农田的理化参数,影响植物特性。当废水灌溉的农业区被浓度不超过4%的OMWW污染时,植物的特性受到了很大的影响。本研究结果表明,施用4% OMWW的大豆植株生长响应最佳,其生长指标和光合色素均有所增加。
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引用次数: 1
Fuzzy analytical hierarchy process methods in changing the damming level of a small hydropower plant: Case study of Rosko SHP in Poland 模糊层次分析法在小水电厂坝位变化中的应用——以波兰罗斯科水电站为例
IF 5.1 3区 工程技术 Q1 WATER RESOURCES Pub Date : 2023-06-01 DOI: 10.1016/j.wri.2023.100204
Ireneusz Laks , Zbigniew Walczak , Natalia Walczak

Small hydropower plants are one of the most important renewable energy sources that do not degrade and consume natural resource. The paper presents a case study of an already operating small hydropower plant (SHP) and a potential increase in its energy production by raising the damming level. Three variants were defined and subjected to detailed analysing. The analyses used the Fuzzy AHP methodology (FAHP), which allowed for identifying the variant that has the best chance of being implemented in the context of administrative, legal and social realities of the country where an SHP is located. The adopted solution will increase electricity production by 108.78 MWh annually, while reducing carbon dioxide emissions by 86000 kg CO2. The described methodology is of general use and can be applied in any country in the world.

小型水电站是最重要的可再生能源之一,不会降解和消耗自然资源。本文介绍了一个已经运行的小型水电站(SHP)的案例研究,以及通过提高筑坝水平来增加其能源生产的潜力。定义了三种变体,并对其进行了详细分析。分析使用了模糊层次分析法(FAHP),该方法允许在SHP所在国的行政、法律和社会现实背景下确定最有可能实施的变体。采用的解决方案将每年增加108.78兆瓦时的电力产量,同时减少86000公斤二氧化碳的排放。所描述的方法具有通用性,可以应用于世界上任何国家。
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引用次数: 0
Reclamation of treated municipal wastewater in cooling towers of thermal power plants: Determination of the wastewater quality index 热电厂冷却塔处理后城市污水的回用:废水水质指标的测定
IF 5.1 3区 工程技术 Q1 WATER RESOURCES Pub Date : 2023-06-01 DOI: 10.1016/j.wri.2023.100207
Ghorban Asgari , Mohammad Khazaei , Abdolmotaleb Seidmohammad , Muharram Mansoorizadeh , Somayeh Talebi

Water quality in cooling towers of thermal power plants (CTTPP) has a critical role in the operation and maintenance of CTTPP and the need for an index which represents well the quality of water used in CTTPP. In this study, municipal wastewater effluent (MWE) as a source of water for use in the CTTPP was evaluated by determining the water quality index. 22 MWE quality parameters were considered in terms of their potential effects on cooling towers. The relative weight of the parameters is calculated by the analytical hierarchical process (AHP). The analysis of water classification was done by using the fuzzy inference system (FIS). In the fuzzy logic approach, the trapezoidal and triangular membership functions and the Mamdani inference system were used, and the final rules consist of 240 rules. The center-of-gravity method is used for the Defuzzification of the results. The values obtained from the cooling tower effluent quality index (CTEQI) based on the FIS were generally more stable than the values from CTEQI based on the traditional system. The outcomes of this study established that the quality of effluent entering the cooling towers in a Shahid Moftteh power plant in the Hamadan (effluent sampling site) is moderate to good condition (annual fuzzy index 50–90, average annual traditional index 79.52–95.99). This research result reveals that CTEQI can be counted as a general tool for evaluating the quality of effluent that use in the CTTPP and can be used with confidence for this purpose.

火电厂冷却塔水质对冷却塔的运行和维护起着至关重要的作用,需要一个能很好地反映冷却塔用水质量的指标。在本研究中,通过确定水质指标,对城市污水(MWE)作为CTTPP使用的水源进行了评价。考虑了22个MWE质量参数对冷却塔的潜在影响。采用层次分析法(AHP)计算各参数的相对权重。采用模糊推理系统(FIS)对水体分类进行分析。在模糊逻辑方法中,使用了梯形和三角形隶属函数以及Mamdani推理系统,最终规则由240条规则组成。采用重心法对结果进行去模糊化处理。基于FIS的冷却塔出水水质指数(CTEQI)值一般比基于传统系统的CTEQI值更稳定。研究结果表明,哈马丹沙希德莫夫特电厂冷却塔出水水质处于中等至良好状态(年模糊指数50 ~ 90,年均传统指数79.52 ~ 95.99)。研究结果表明,CTEQI可作为CTTPP出水水质评价的通用工具,并可可靠地用于该目的。
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引用次数: 0
Degradation of bisphenol S – a contaminant of emerging concern - by synergistic ozone and percarbonate based AOP 降解双酚S -一个新兴的关注污染物-通过协同臭氧和过碳酸酯基AOP
IF 5.1 3区 工程技术 Q1 WATER RESOURCES Pub Date : 2023-06-01 DOI: 10.1016/j.wri.2023.100208
Zahra Askarniya , Manoj P. Rayaroth , Xun Sun , Zhaohui Wang , Grzegorz Boczkaj

Degradation of bisphenol S was studied using ozone activated by sodium percarbonate and the effectiveness of optimized process was compared with the peroxone process. The influence of several factors including sodium percarbonate concentration, ozone dose, pH, and water matrix were investigated. A synergetic coefficient of 3.84 was achieved for the combination of sodium percarbonate and ozone, confirming the effectiveness of this hybrid process. Scavenging tests revealed, that carbonate radicals, hydroxyl radicals, superoxide radicals, and singlet oxygen contributed to the degradation of bisphenol S. At the same operating condition, degradation effectiveness values of 99% and 81% were obtained by ozone combined with sodium percarbonate and hydrogen peroxide, respectively, demonstrating the superiority of sodium percarbonate over hydrogen peroxide in combination with ozone for the degradation of bisphenol S. Low concentration of inorganic anions had a negligible effect on the degradation, while carbonate ions increased the first-order degradation rate constant by 56%.

研究了过碳酸钠活化臭氧对双酚S的降解效果,并将优化后的工艺与过氧酮工艺进行了比较。考察了过碳酸钠浓度、臭氧剂量、pH值和水基质等因素的影响。过碳酸钠与臭氧复合的协同系数为3.84,证实了该混合工艺的有效性。清除实验表明,臭氧对双酚s的降解作用主要有碳酸盐自由基、羟基自由基、超氧自由基和单线态氧。在相同的操作条件下,臭氧与过碳酸钠和过氧化氢复合的降解效率分别为99%和81%。证明过碳酸钠比过氧化氢与臭氧结合降解双酚s的优势。低浓度的无机阴离子对降解的影响可以忽略不计,而碳酸盐离子使一级降解速率常数提高了56%。
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引用次数: 5
Treatment of real tannery wastewater using facile synthesized magnesium oxide nanoparticles: Experimental results and geochemical modeling 使用易合成氧化镁纳米颗粒处理实际制革厂废水:实验结果和地球化学模型
IF 5.1 3区 工程技术 Q1 WATER RESOURCES Pub Date : 2023-06-01 DOI: 10.1016/j.wri.2023.100205
V. Masindi , M. Tekere , S. Foteinis

Tannery wastewater (TWW) is a toxic and hazardous effluent that causes great harm to receiving ecosystems if released untreated. Here, magnesium oxide nanoparticles (MgO-NPs), synthesized from low-cost and readily available magnesite, were used for the treatment of real TWW under batch laboratory conditions. The optimum treatment conditions were 90 min contact time and 10 g MgO-NPs dosage per L of real TWW, under ambient pH and temperature. Results were underpinned by state-of-the-art analytical techniques, including ICP-OES, XRD, XRF, and FIB/EDS-SEM, along with geochemical modelling (PHREEQC). The removal efficiency for the main contaminants that are typically found in TWW was, from higher to lower score, Fe ≥ U ≥ Cr ≥ Mn ≥ Al ≥ Sb ≥ Cu ≥ Ni ≥ TOC ≥ COD≥ SO42. The removal percentages for these contaminants were ≥99%, aside from Ni (97%), TOC (71%), COD (69%) and particularly SO42 (21%). The underlying mechanism for contaminants removal is linked to the scavenging of metals by the MgO-NPs, forming complexes, in combination with alkalinity addition (through MgO dissolution) that lead to contaminants precipitation. The PHREEQC geochemical model confirmed the existence of divalent, trivalent, oxyanions, and multivalent chemical species in MgO-NPs/TWW solution, including complexes. Contaminants attenuation was achieved through precipitation, co-precipitation, adsorption, and co-adsorption, while these were removed as hydroxides, sulfides, carbonates, oxide, and oxyhydrosulfates. Overall, results highlight the great potential of MgO-NPs for the sustainable management of real TWW.

制革厂废水(TWW)是一种有毒有害的废水,如果未经处理,会对接收生态系统造成巨大危害。在这里,氧化镁纳米颗粒(MgO-NPs)是由低成本和容易获得的菱镁矿合成的,用于在批量实验室条件下处理真实的TWW。最佳处理条件为接触时间90 min,实际TWW的MgO-NPs用量为10 g / L,在环境pH和温度下。结果得到了最先进的分析技术的支持,包括ICP-OES, XRD, XRF, FIB/EDS-SEM,以及地球化学建模(PHREEQC)。TWW中常见的主要污染物去除率由高到低依次为Fe≥U≥Cr≥Mn≥Al≥Sb≥Cu≥Ni≥TOC≥COD≥SO42−。除Ni(97%)、TOC(71%)、COD(69%),特别是SO42−(21%)外,这些污染物的去除率均≥99%。污染物去除的潜在机制与MgO- nps对金属的清除有关,形成配合物,与碱度添加(通过MgO溶解)相结合,导致污染物沉淀。PHREEQC地球化学模型证实了MgO-NPs/TWW溶液中存在二价、三价、氧阴离子和多价化学物质,包括配合物。污染物的衰减是通过沉淀、共沉淀、吸附和共吸附来实现的,而这些污染物以氢氧化物、硫化物、碳酸盐、氧化物和硫酸氢氧化物的形式被去除。总体而言,结果突出了MgO-NPs在实际TWW可持续管理方面的巨大潜力。
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引用次数: 2
A state-level analysis of the water system management efficiency in Mexico: Two-stage DEA approach 墨西哥水系统管理效率的州级分析:两阶段DEA方法
IF 5.1 3区 工程技术 Q1 WATER RESOURCES Pub Date : 2023-06-01 DOI: 10.1016/j.wri.2022.100200
Marien Morán-Valencia , Martin Flegl , David Güemes-Castorena

The public water system management in Mexico has recently been criticized due to severe problems with the availability of drinkable water. Significant differences exist between Mexican regions regarding the availability of renewable water and water system distribution. Moreover, water governance in the country is inefficient due to the lack of transparency in the water policies. Therefore, the article aims to investigate whether there is a direct relationship between water system management efficiency and water system improvement efficiency and how the efficiency reflects the size of the population and the availability of renewable water in each state. For this, a two-stage DEA model is constructed to evaluate the water system management efficiency in Mexico. The results indicate high average water management efficiency but very low efficiency in the water system improvements. Furthermore, immense differences in the water system efficiency can be observed with respect to the characteristics and adopted policies.

墨西哥的公共供水系统管理最近受到批评,原因是饮用水供应存在严重问题。墨西哥各地区在可再生水的可用性和水系统分布方面存在显著差异。此外,由于水政策缺乏透明度,该国的水治理效率低下。因此,本文旨在研究水系统管理效率与水系统改善效率之间是否存在直接关系,以及效率如何反映各州的人口规模和可再生水的可用性。为此,本文构建了一个两阶段DEA模型来评价墨西哥水系管理效率。结果表明,平均水管理效率较高,但水系统改善效率很低。此外,可以观察到水系统效率在特点和采取的政策方面的巨大差异。
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引用次数: 7
FAHP methods in changing the damming level of a small hydropower plant: Case study of Rosko SHP in Poland FAHP方法在改变小水电站坝位中的应用:波兰Rosko SHP的案例研究
IF 5.1 3区 工程技术 Q1 WATER RESOURCES Pub Date : 2023-02-01 DOI: 10.1016/j.wri.2023.100204
Ireneusz Laks, Z. Walczak, N. Walczak
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引用次数: 0
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