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Application of waste rigid polyurethane foam for oil removal from water 废硬质聚氨酯泡沫塑料在水中除油中的应用
IF 7.5 3区 工程技术 Q1 WATER RESOURCES Pub Date : 2025-12-04 DOI: 10.1016/j.wri.2025.100336
Roland Nagy , Rebeka Bejczi
This study investigated the use of rigid polyurethane (PUR) foam for demulsifying oil-containing emulsions, focusing on improving oil removal from water. Emulsions with 5 V/V% oil content were treated using PUR foams of different geometries to evaluate how foam structure affects separation efficiency. During demulsification, the coalescence of fine oil droplets led to the formation of larger aggregates, which increased turbidity; therefore, in this study, higher turbidity indicated a more advanced demulsification stage rather than poorer water quality. Both larger PUR surface area and higher foam volume enhanced the coalescence process and improved oil removal efficiency. The results demonstrate that waste PUR foam can be effectively repurposed for oil–water separation, supporting sustainable and resource-efficient wastewater treatment.
研究了硬质聚氨酯(PUR)泡沫塑料对含油乳剂的破乳效果,重点研究了其对水中除油效果的影响。采用不同几何形状的PUR泡沫对含油量为5 V/V%的乳剂进行处理,以评价泡沫结构对分离效率的影响。破乳过程中,细油滴聚结形成较大的团聚体,增加了浊度;因此,在本研究中,浊度越高说明破乳阶段越先进,而不是水质越差。更大的聚氨酯比表面积和更高的泡沫体积都能促进聚结过程,提高除油效率。结果表明,废弃PUR泡沫塑料可以有效地用于油水分离,支持可持续和资源高效的废水处理。
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引用次数: 0
Performance comparison of four polymeric ultrafiltration membranes for wool scouring effluent treatment 四种高分子超滤膜处理羊毛洗涤废水的性能比较
IF 7.5 3区 工程技术 Q1 WATER RESOURCES Pub Date : 2025-12-01 DOI: 10.1016/j.wri.2025.100333
Tuomas Sinisaari , Joona Nieminen , Ari Ora , Mika Mänttäri , Tiina Rissanen
The water footprint of wool scouring could be reduced with membrane filtration of scouring effluent, allowing recycling of purified washing water. This study compares the performance of four commercially available polymeric ultrafiltration membranes for scouring effluent treatment. In a cross-flow system, permeate flux decreased by 30–54 % after 120 min of filtration. Chemical oxygen demand, turbidity, and colour retentions ranged from 72 to 90 %, 98–99 %, and 80–93 %, respectively. After one week exposure to scouring effluent, degradation was observed in the regenerated cellulose membrane, in which the molecular weight cut-off increased from 3.5 to 8.2 kDa. Polysulphone and regenerated cellulose had the highest fluxes, but polysulphone was prone to fouling, whereas regenerated cellulose degraded, making composite fluoropolymer membrane a competitive alternative. The results offer guidance for membrane selection and contribute to establishing a foundation for membrane-based effluent recycling in commercial wool scouring facilities.
对洗涤出水进行膜过滤,可以减少羊毛洗涤的水足迹,使净化后的洗涤水循环使用。本研究比较了四种市售聚合物超滤膜处理冲洗废水的性能。在横流系统中,过滤120分钟后,渗透通量下降了30 - 54%。化学需氧量、浊度和颜色保留率分别为72 - 90%、98 - 99%和80 - 93%。在浸泡出水一周后,再生纤维素膜出现降解,其分子量下限从3.5 kDa增加到8.2 kDa。聚砜和再生纤维素的通量最高,但聚砜容易结垢,而再生纤维素降解,使复合含氟聚合物膜成为有竞争力的替代品。研究结果为膜的选择提供了指导,并为商业羊毛洗涤设施中膜基废水的循环利用奠定了基础。
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引用次数: 0
Implementation of circular economy of water in the automobile batteries recycling industry 在汽车电池回收行业实施水循环经济
IF 7.5 3区 工程技术 Q1 WATER RESOURCES Pub Date : 2025-12-01 DOI: 10.1016/j.wri.2025.100330
Miguel Ángel López Zavala
Circular economy arises as an alternative to facilitate sustainable development in the industrial sector by enhancing water resource efficiency, reducing wastewater generation, and establishing closed-loop systems. This study presents two approaches to implement circular economy of water in the automobile batteries recycling industry. In these proposals, the key principles driving the circular economy model (reduce, reclaim, reuse, recycle, recover, and rethink) were considered, emphasizing the essential role of reduction, direct reuse, reclaiming, recycling, recovery and rethinking in achieving sustainable water management. Survey and measuring campaign were done to determine flowrates and characteristics of freshwater, wastewater, and treated wastewater stream. Then, water and pollutants mass balances were conducted. As a result, i) important reductions on freshwater consumption (69.5 %) and total water inputs (>66.0 %) in the industrial process can be achieved by implementing direct wastewater reuse; ii) direct wastewater reuse and wastewater recycle can be increased in 12 % and 18 %, respectively, thus contributing in reducing 6.2 % the wastewater generation; iii) batteries' electrolyte is the main source of wastewater pollutants; therefore, it is recommended to rethink and redesign the industrial process to extract batteries’ electrolyte before they are processed; implementing this strategy will contribute in recovering 0.31 m3/1000 batteries/month (248 m3/month) of concentrated sulfuric acid, achieving zero disposal of wastewater, attenuating aquifer pollution by heavy metals and salts, and reducing wastewater treatment costs in 90 %, which represents savings greater than US$ 90,000.00/month or 1.15 million US dollars per year.
循环经济是通过提高水资源效率、减少废水产生和建立闭环系统来促进工业部门可持续发展的一种替代方案。本文提出了在汽车电池回收行业实施水循环经济的两种途径。在这些建议中,考虑了推动循环经济模式的关键原则(减少、回收、再利用、再循环、回收和重新思考),强调了减少、直接再利用、回收、再循环、回收和重新思考在实现可持续水管理中的重要作用。进行了调查和测量活动,以确定淡水、废水和处理后的废水流的流量和特性。然后,进行水和污染物的质量平衡。因此,i)通过实施废水直接回用,可以显著减少工业过程中的淡水消耗(69.5%)和总水投入(> 66.0%);Ii)废水直接回用和废水再循环可分别增加12%和18%,从而有助于减少6.2%的废水产生量;Iii)电池电解液是废水污染物的主要来源;因此,建议重新思考和重新设计工业流程,在电池加工前提取电解液;实施这一战略将有助于每月回收0.31立方米/1000个电池(248立方米/月)的浓硫酸,实现废水零处理,减轻重金属和盐类对含水层的污染,并将废水处理成本降低90%,相当于每月节省9万多美元或每年节省115万美元。
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引用次数: 0
Removal notice to “Development of a methodology for identifying and quantifying mining environmental liabilities in aquatic ecosystems: A case study of Segovia, Colombia” [Water Resour. Ind. 34 (2025) 100307] 对“查明和量化水生生态系统中采矿环境责任的方法的发展:哥伦比亚塞戈维亚的案例研究”的删除通知[水资源]。第34(2025)100307号公告]
IF 7.5 3区 工程技术 Q1 WATER RESOURCES Pub Date : 2025-12-01 DOI: 10.1016/j.wri.2025.100334
Wilfredo Marimon-Bolívar , John Chavarro Diaz , Armando Sarmiento , Nathalie Toussaint Jimenez
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引用次数: 0
Editorial: AOPs for industrial waters 社论:工业用水的AOPs
IF 7.5 3区 工程技术 Q1 WATER RESOURCES Pub Date : 2025-12-01 DOI: 10.1016/j.wri.2025.100299
Yongjun Zhang , Sven Uwe Geissen , Jiangyong Hu
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引用次数: 0
Techno-economic evaluation of maximizing minimum liquid discharge from seawater desalination for the fertilizer industry 化肥工业海水淡化最大最小排液量技术经济评价
IF 7.5 3区 工程技术 Q1 WATER RESOURCES Pub Date : 2025-11-26 DOI: 10.1016/j.wri.2025.100332
Nikhil Dilip Pawar , Carmelo Morgante , Thomas Pregger , Patrick Jochem
The Middle East and North Africa region faces critical water scarcity and food security challenges that threaten economic development. Fertilizer use supports food self-sufficiency, but its production is highly water intensive. Supplying desalinated water to a decarbonized fertilizer plant offers an environmentally sustainable pathway.
This study investigates co-locating a decarbonized fertilizer plant with a seawater desalination facility, optionally implementing minimum liquid discharge (MLD) to generate additional revenue through recovery of magnesium hydroxide and sodium chloride (NaCl). Three configurations were modeled: a conventional seawater reverse osmosis (SWRO)-based plant; and two MLD configurations using high-pressure RO (HPRO), osmotically-assisted RO (OARO), and crystallizers. Financial performance was assessed using a novel discounted and allocated levelized cost (DALC) method, internal rate of return (IRR), and net present value (NPV).
In a Moroccan case study, the conventional configuration achieved the lowest DALC and energy consumption (0.70 USD/m3water and 3.8 KWhel/m3), with an IRR of 23.9 %. The first MLD configuration had higher costs (0.94 USD/m3water, 12.0 KWhel/m3) and a lower IRR (14.5 %), with water recovery limited to 71.4 % due to nonuse of magnesium crystallizer effluent (60.4 % in the conventional setup). Reusing this effluent in the second MLD configuration increased water recovery to 96.7 %, yet higher impurities at the NaCl crystallizer feed reduced the IRR to 9.7 %, which could be improved through financing strategies such as lowering capital costs to endorse the MLD-maximizing option.
The findings emphasize advancing impurity removal methods and exploring innovative project financing strategies to enable financially and environmentally sustainable seawater desalination for decarbonized fertilizer production.
中东和北非地区面临严重的水资源短缺和粮食安全挑战,威胁着经济发展。化肥的使用支持粮食自给自足,但其生产是高度用水密集型的。向脱碳化肥厂供应淡化水提供了一条环境可持续发展的途径。本研究探讨了脱碳化肥厂与海水淡化设施的共存,可选择实施最小液体排放(MLD),通过回收氢氧化镁和氯化钠(NaCl)来产生额外的收入。模拟了三种配置:基于传统海水反渗透(SWRO)的工厂;以及使用高压RO (HPRO)、渗透辅助RO (OARO)和结晶器的两种MLD配置。财务绩效的评估采用了一种新的贴现和分配的平均成本(DALC)方法,内部收益率(IRR)和净现值(NPV)。在摩洛哥的一个案例研究中,传统配置实现了最低的DALC和能耗(0.70美元/立方米水和3.8千瓦时/立方米),IRR为23.9%。第一个MLD配置成本较高(0.94美元/m3水,12.0千瓦时/m3), IRR较低(14.5%),由于不使用镁结晶器出水,水回收率限制在71.4%(常规配置为60.4%)。在第二个MLD配置中重复使用该废水,水回收率提高到96.7%,但NaCl结晶器进料中较高的杂质使IRR降低到9.7%,这可以通过降低资本成本等融资策略来提高,以支持MLD最大化的选择。研究结果强调了推进杂质去除方法和探索创新的项目融资策略,以实现用于脱碳肥料生产的经济和环境可持续的海水淡化。
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引用次数: 0
Degradation of polylactide microplastics in the marine environment under low temperature and in fine-grained sediments - a laboratory scale evaluation 聚乳酸微塑料在海洋环境中低温和细颗粒沉积物中的降解——实验室规模评估
IF 7.5 3区 工程技术 Q1 WATER RESOURCES Pub Date : 2025-11-20 DOI: 10.1016/j.wri.2025.100331
Karolina Szewc , Bożena Graca , Maksymilian Plata-Gryl , Grzegorz Boczkaj
The degradation of microplastics (MPs) in marine environments, especially under low temperatures and in fine-grained sediments, remains poorly understood. In this study, laboratory experiments were conducted on MPs of polylactide (PLA), a bio-based and industrially compostable polymer, and polystyrene (PS), a conventional oil-based polymer, to investigate their degradation in marine water and sediments at low temperatures. After 3 months PLA incubation in marine water (6–8 °C), gel permeation chromatography/size exclusion chromatography (GPC/SEC) showed a 17 % reduction in molecular weight (Mn) and increased polydispersity index in samples under combined abiotic and biotic hydrolysis. Scanning electron microscopy indicated a local surface collapse of PLA. Degradation was inhibited in samples under abiotic hydrolysis alone. No molecular-level degradation occurred in samples buried in oxygen-deficient, fine-grained sediment. A limited (0.02–0.08 %) weight loss of PLA was observed across all experiments. Polystyrene microplastics showed no signs of degradation during the experiments. Our findings suggest that in bottom sediments, where temperatures are low and oxygen is scarce, PLA undergoes limited surface erosion rather than bulk degradation. This leads to long-term persistence and gradual reduction in particle size. Therefore, improperly managed PLA waste may contribute to micro- and nanoplastic pollution in deep-sea environments.
微塑料(MPs)在海洋环境中的降解,特别是在低温和细颗粒沉积物中的降解,仍然知之甚少。在本研究中,对聚乳酸(PLA)(一种生物基和工业可堆肥聚合物)和聚苯乙烯(PS)(一种传统的油基聚合物)的MPs进行了实验室实验,以研究它们在低温下在海水和沉积物中的降解情况。PLA在海水(6-8°C)中培养3个月后,凝胶渗透色谱/粒径排除色谱(GPC/SEC)显示,在非生物和生物联合水解下,样品的分子量(Mn)降低了17%,多分散性指数增加。扫描电镜显示PLA局部表面塌陷。仅在非生物水解条件下,样品的降解被抑制。埋在缺氧、细粒度沉积物中的样品没有发生分子水平的降解。所有实验均观察到PLA的有限失重(0.02 - 0.08%)。聚苯乙烯微塑料在实验中没有显示出降解的迹象。我们的研究结果表明,在温度低、氧气稀缺的底部沉积物中,聚乳酸只经历有限的表面侵蚀,而不是整体降解。这导致长期的持久性和逐渐减少的颗粒大小。因此,处理不当的聚乳酸废物可能会导致深海环境中的微塑料和纳米塑料污染。
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引用次数: 0
Robust water quality prediction across multiple indicator formulations using an explainable ensemble learning model 使用可解释的集成学习模型跨多个指标公式的鲁棒水质预测
IF 7.5 3区 工程技术 Q1 WATER RESOURCES Pub Date : 2025-11-12 DOI: 10.1016/j.wri.2025.100329
Chi Thuong Doan, Huu Du Nguyen
Reliable assessment of water quality is critical for sustainable resource management. The Water Quality Index (WQI) is a valuable tool for evaluating water quality. However, the existence of multiple WQI techniques often results in inconsistent assessments and considerable uncertainty in the correct water quality classification. This study aimed to examine the robustness of machine learning (ML) methods for water quality assessment across several widely used WQIs. A stacking ensemble learning framework was developed, integrating multiple ML base learners with a meta-learner based on the Ensemble Deep Random Vector Functional Link structure. Experimental results show that the proposed approach consistently achieves superior performance, outperforming existing state-of-the-art models with accuracy, precision, recall, and F1-score ranging from 99.17 % to 99.59 % across all evaluated WQIs. SHAP-based analysis was employed to interpret the model's output and clarify the contribution of each base learner to the final decision. It revealed that the most influential interactions affecting classification outcomes were those between BOD and DO, as well as between conductivity and pH. Meanwhile, the main contributors among the base learners were the deep learning models, particularly LSTM and MLP. These findings demonstrate that the proposed framework not only resolves inconsistencies in multiple index-based water assessments but also provides a transparent and reliable decision-support tool for water quality monitoring and management.
可靠的水质评估对可持续的资源管理至关重要。水质指数(WQI)是评价水质的重要工具。然而,多种WQI技术的存在往往导致评估结果不一致,在正确的水质分类中存在相当大的不确定性。本研究旨在检验机器学习(ML)方法在几种广泛使用的水质评价指标中的鲁棒性。开发了一个堆叠集成学习框架,将多个ML基础学习器与基于集成深度随机向量功能链接结构的元学习器集成在一起。实验结果表明,所提出的方法在所有评估的wqi中均取得了优异的性能,其准确率、精密度、召回率和f1得分范围为99.17%至99.59%,优于现有的最先进的模型。采用基于shap的分析来解释模型的输出,并阐明每个基础学习者对最终决策的贡献。结果表明,对分类结果影响最大的交互作用是BOD和DO之间的交互作用,以及电导率和ph之间的交互作用。同时,基础学习器中的主要贡献者是深度学习模型,特别是LSTM和MLP。研究结果表明,该框架不仅解决了基于多个指标的水质评价不一致的问题,而且为水质监测和管理提供了透明可靠的决策支持工具。
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引用次数: 0
Correlating plant-to-pollutant mass ratio in phytotreating batik industry effluent using Actinoscirpus grossus 放线菌处理蜡染工业废水中植物-污染物质量比的相关性研究
IF 7.5 3区 工程技术 Q1 WATER RESOURCES Pub Date : 2025-10-27 DOI: 10.1016/j.wri.2025.100328
Nurull Muna Daud , Siti Rozaimah Sheikh Abdullah , Hassimi Abu Hasan , Ahmad Razi Othman , Noorashikin Md Salleh , Nor Sakinah Mohd Said , Nur 'Izzati Ismail
Batik, a clothing fabric, is synonymous with people in Southeast Asian countries. The batik industry is one of the industries that produces poorly treated wastewater. This study was conducted to determine the capability and suitability of phytoremediation treatment using Malaysia's native plant, Actinoscirpus grossus (previously known as Scirpus grossus), with plant-to-pollutant ratio (PPR: g plant/g COD) approach. Four A. grossus plants (40.4 ± 4 g) were exposed to batik effluent with four different COD concentrations (275 mg/L for 40 % dilution, 399 mg/L for 60 % dilution, 484 mg/L for 80 % dilution and 637 mg/L for batik effluent without dilution) for 28 days. The PPR of batik industry effluent concentrations of 40 %, 60 %, 80 % and 100 % was calculated and denoted as PPR1 (49 g plant/g COD), PPR2 (33 g plant/g COD), PPR3 (27 g plant/g COD) and PPR4 (21 g plant/g COD), respectively. Physical appearance, length, COD and colour removal efficiencies were monitored throughout the 28-day exposure period. Results showed that the plant ratio of PPR2 and the exposure of 28 days with 77.2 % COD removal were sufficient to be used for phytoremediation of similar effluents. The total mass of plants required for a future system can be estimated based on the PPR approach. This approach could ease the reproducibility of the treatment for similar types of wastewaters and for scaling up for real industry applications.
蜡染,一种服装面料,是东南亚国家人民的代名词。蜡染工业是产生未经处理的废水的工业之一。本研究以马来西亚原生植物放线菌(Actinoscirpus grossus)为研究对象,采用植物-污染物比(PPR: g plant/g COD)方法确定植物修复处理的能力和适宜性。4株毛竹(40.4±4 g)暴露于4种不同COD浓度的蜡染废水中(稀释40%的275 mg/L、稀释60%的399 mg/L、稀释80%的484 mg/L和未稀释的637 mg/L) 28天。计算了蜡染工业废水浓度为40%、60%、80%和100%时的PPR,分别表示为PPR1 (49 g厂/g COD)、PPR2 (33 g厂/g COD)、PPR3 (27 g厂/g COD)和PPR4 (21 g厂/g COD)。在28天的暴露期内监测其物理外观、长度、COD和去色效率。结果表明,PPR2的植物比例和28 d的COD去除率为77.2%,足以用于类似废水的植物修复。基于PPR方法,可以估计未来系统所需的电厂总质量。这种方法可以简化处理类似类型废水的可重复性,并扩大实际工业应用的规模。
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引用次数: 0
Different impacts of landscape pattern and industrial structure on water quality in Yellow River's mainstream and tributary in Gansu, China 甘肃省黄河干支流景观格局和产业结构对水质的不同影响
IF 7.5 3区 工程技术 Q1 WATER RESOURCES Pub Date : 2025-10-24 DOI: 10.1016/j.wri.2025.100327
Zhixiang Lu , Jinbo Zhang , Haolin Li , Jiali Xie , Yan Luo , Qi Feng
The water quality of rivers is usually influenced by landscape patterns and industrial structures, but the impact of the COVID-19 pandemic has received less attention. Taking the mainstream and tributary rivers of the Yellow River in Gansu Province as the study area, the correlation between water quality indicators and landscape pattern index, as well as the social and economic factors were analyzed to explain the driving forces of the differences in water quality from 2018 to 2021, moreover, the impact of the COVID-19 pandemic on water quality were investigated. The water quality of the mainstream and tributary rivers was improving, except the Taohe River; however, the monthly nitrogen source pollution in the Weihe River (3.58–11.19 mg/L for TN and 0.25–1.88 mg/L for NH4+-N), Jinghe River (2.66–8.18 mg/L for TN and 0.25–1.69 mg/L for NH4+-N) and Zhuanglang River (1.20–6.75 mg/L for TN and 0.18–0.65 mg/L for NH4+-N) still had high levels, and the average values of TN even fall within the Class V standard. Water quality is positively correlated with the aggregation degree and connectivity of landscape, but the risk of water pollution increased with the increase of the degree of landscape fragmentation and dispersion. The NH4+-N, TP, CODMn and COD are influenced by rural domestic and agricultural activities, while TN and DO are affected by urban domestic and industrial production. The COVID-19 pandemic has affected river water quality by impacting production and daily life. These findings provide a foundation for managing the water quality of Yellow River Basin.
河流水质通常受到景观格局和产业结构的影响,但COVID-19大流行的影响受到的关注较少。以甘肃省黄河干支流为研究区,分析水质指标与景观格局指数的相关性以及社会经济因素,解释2018 - 2021年水质差异的驱动因素,并调查新冠肺炎疫情对水质的影响。除洮河外,干支流水质均呈改善趋势;但渭河(TN为3.58 ~ 11.19 mg/L, NH4+-N为0.25 ~ 1.88 mg/L)、泾河(TN为2.66 ~ 8.18 mg/L, NH4+-N为0.25 ~ 1.69 mg/L)和庄浪河(TN为1.20 ~ 6.75 mg/L, NH4+-N为0.18 ~ 0.65 mg/L)月度氮源污染水平仍然较高,TN平均值甚至落在V类标准之内。水质与景观的聚集度和连通性呈正相关,但水污染风险随着景观破碎化和分散程度的增加而增加。NH4+-N、TP、CODMn和COD受农村家庭和农业活动的影响,TN和DO受城市家庭和工业生产的影响。2019冠状病毒病大流行通过影响生产和日常生活来影响河流水质。研究结果为黄河流域水质管理提供了依据。
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Water Resources and Industry
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