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Influence of mixing conditions on coagulant recovery efficiency and quality 混合条件对混凝剂回收效率和质量的影响
Q3 WATER RESOURCES Pub Date : 2023-11-07 DOI: 10.2166/wpt.2023.190
Bruno Moreno Ramos da Silva, Rafael Kopschitz Xavier Bastos, Thiago José Dias Godinho
Abstract In this work, the influence of mixing conditions on aluminium recovery from alum sludge and on the recovered coagulant (RC) quality was investigated using acidic treatment. The response surface methodology with a face centred design was used to evaluate the effects of velocity gradient and mixing time on aluminium recovery efficiency, and on the chemical oxygen demand (COD), total suspended solids (TSS) and total phosphorus contents of the RC. No significant effects of both mixing intensity and mixing time on aluminium recovery efficiency were observed; however, these factors significantly affected the quality of the RC in terms of COD, TSS and total phosphorus. The higher velocity gradient increased COD and TSS and the longer mixing time increased phosphorus and TSS in the RC. The defined operational conditions (velocity gradient = 100 s−1 and mixing time = 5 min) for aluminium recovery were suggested on economic basis. At these optimal conditions, the RC presented the lowest values of TSS and total phosphorus (100 mg L−1 and 7.0 mg P L−1, respectively), and the following other characteristics: 1,001 mg Al L−1; 384 mg Fe L−1 and 1,100 mg COD L−1.
摘要采用酸性处理方法,研究了混合条件对明矾污泥回收铝的影响以及对回收混凝剂质量的影响。采用面中心设计的响应面法,考察了速度梯度和搅拌时间对RC中铝回收率、化学需氧量(COD)、总悬浮固体(TSS)和总磷含量的影响。混合强度和混合时间对铝回收率无显著影响;然而,这些因素在COD、TSS和总磷方面对RC质量有显著影响。速度梯度越大,RC中COD和TSS增加,混合时间越长,RC中磷和TSS增加。从经济的角度提出了铝回收的操作条件(速度梯度为100 s−1,混合时间为5 min)。在这些最佳条件下,RC的TSS和总磷含量最低(分别为100 mg L−1和7.0 mg P L−1),并且具有以下特征:Al L−1为1001 mg;384 mg Fe L−1和1100 mg COD L−1。
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引用次数: 0
Hydrogeochemical–geophysical investigations of groundwater quality and susceptibility potential in Ikot Ekpene–Obot Akara Local Government Areas, Southern Nigeria 尼日利亚南部Ikot Ekpene-Obot Akara地方政府地区地下水水质和易感性潜力的水文地球化学-地球物理调查
Q3 WATER RESOURCES Pub Date : 2023-11-06 DOI: 10.2166/wpt.2023.187
Aniekan Martin Ekanem, Ndifreke I. Udosen
Abstract Groundwater contamination is of global concern. The study area (Ikot Ekpene–Obot Akara Local Government Areas) continues to experience a swift increase in human population and associated economic activities, leading to the generation of more waste. The fundamental goal of this work is therefore to weigh up the groundwater standard through hydrogeochemical investigation of groundwater samples and the susceptibility potential of the economically exploited aquifer units in the area. The results of the electrical geo-sounding data acquired at 28 locations in the area reveal three to four lithological successions comprising fine/coarse sands and gravels amid patches of thin clay interbeddings at several places. The primary aquifer is the third layer, which is between 10.5 and 101.5 m deep with resistivity values between 359.4 and 2,472.8 Ωm. The hydrogeochemical evaluation of groundwater samples in the area shows that the measured physicochemical parameters are well within the World Health Organization's acceptable limits except for lead and nickel ions. The groundwater quality and susceptibility potential maps generated seem to correlate well and clearly demarcate the poor groundwater quality/high susceptibility potential zones. These maps are useful tools that could aid policymakers in successful groundwater management in the area to meet the needs of the populace.
地下水污染是全球关注的问题。研究区域(Ikot Ekpene-Obot Akara地方政府区域)继续经历人口和相关经济活动的快速增长,导致产生更多的废物。因此,这项工作的根本目的是通过对地下水样品的水文地球化学调查和该地区经济开发含水层单元的敏感性潜力来衡量地下水标准。在该地区的28个地点获得的电测深数据的结果显示,在几个地方的薄粘土互层中,有三到四个岩性序列,包括细/粗砂和砾石。主含水层为第三层,深度为10.5 ~ 101.5 m,电阻率值为359.4 ~ 2472.8 Ωm。对该地区地下水样本进行的水文地球化学评价表明,除铅和镍离子外,所测量的物理化学参数完全在世界卫生组织的可接受限度之内。生成的地下水水质图与易感电位图相关性较好,清晰地划分出地下水水质差/易感电位高的区域。这些地图是有用的工具,可以帮助决策者成功地管理该地区的地下水,以满足民众的需求。
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引用次数: 0
Importance of process design on carbon footprint from drinking water treatment by enhanced coagulation-filtration 工艺设计对强化混凝过滤处理饮用水碳足迹的重要性
Q3 WATER RESOURCES Pub Date : 2023-11-06 DOI: 10.2166/wpt.2023.189
Paula Pellikainen, Bjørnar Eikebrokk, Riku Vahala
Abstract There are several process design options for enhanced coagulation-filtration in drinking water treatment plants (DWTPs). This study compares the carbon footprint and economic impact of two common process designs based on enhanced coagulation-filtration with pH, Ca, and alkalinity adjustment for corrosion control. The process designs are direct filtration (DF) using Al coagulant with limewater (DF-Al) and contact filtration (CF) using Fe coagulant with alkaline filter layers (CF-Fe). The comparison focuses on the operational phase, which has the largest carbon footprint in the plant's life cycle. The operational data are retrieved from full-scale DWTPs. The results show that the carbon footprint from operations is five times larger for the DF-Al compared to the CF-Fe. Operational costs covering chemicals and energy are almost 30% higher for the DF-Al. Simplified material intensity estimations for the construction phase show that the carbon footprint and investment cost increase with increasing process area, which are larger for the DF-Al. Therefore, to reduce environmental impacts and costs, the design of drinking water treatment processes should be carefully considered even for very similar processes. The results should motivate both water professionals and decision-makers to include a carbon footprint evaluation as a routine step in the DWTP selection and design phases.
在饮用水处理厂(DWTPs)中有几种强化混凝过滤的工艺设计方案。本研究比较了两种常见的基于pH、Ca和碱度调节的强化混凝过滤工艺设计的碳足迹和经济影响。工艺设计为使用Al混凝剂与石灰水(DF-Al)直接过滤(DF)和使用Fe混凝剂与碱性过滤层(CF-Fe)接触过滤(CF)。比较的重点是运营阶段,这是工厂生命周期中碳足迹最大的阶段。操作数据是从全尺寸dwtp中检索的。结果表明,与CF-Fe相比,DF-Al的操作碳足迹是CF-Fe的五倍。DF-Al的化学品和能源运营成本几乎高出30%。施工阶段的简化材料强度估算表明,碳足迹和投资成本随着工艺面积的增加而增加,其中DF-Al的工艺面积更大。因此,为了减少对环境的影响和成本,即使对于非常相似的工艺,也应仔细考虑饮用水处理工艺的设计。研究结果将激励水务专业人员和决策者将碳足迹评估作为DWTP选择和设计阶段的常规步骤。
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引用次数: 0
Application and comparison of four assessment methods for water quality of Sancha Lake in Central Sichuan Province, China 川中三岔湖4种水质评价方法的应用与比较
Q3 WATER RESOURCES Pub Date : 2023-11-04 DOI: 10.2166/wpt.2023.186
Kai Su, Zhongshan Peng, Qin Wang, Rong Cao, Yingwei Xi
Abstract In order to analyze and compare the characteristics and applicability of different water quality evaluation methods applied to lake water quality evaluation, four monitoring sections were set up in Sancha Lake in 2019, 2020, and 2021, and 20 water quality parameters were selected. The single factor index method, the comprehensive pollution index method, the Nemerow pollution index method, and the improved Nemerow pollution index method were used to comprehensively evaluate water quality. The research results showed that the single factor index evaluation method is simple to operate and can quickly determine the water quality category by identifying the worst single water quality indicator. The comprehensive pollution index method and the Nemerow pollution index method determine the degree of water pollution based on the numerical values representing the overall pollution level of the representative water body. The evaluation results showed that except for the evaluation results of the single factor evaluation method with categories II and III, the results of other evaluation methods were all category I, indicating that the water quality was good.
为分析比较不同水质评价方法应用于湖泊水质评价的特点和适用性,在三岔湖设置了2019年、2020年和2021年4个监测断面,选取了20个水质参数。采用单因素指数法、综合污染指数法、Nemerow污染指数法和改进的Nemerow污染指数法对水质进行综合评价。研究结果表明,单因素指标评价方法操作简单,可通过识别最差单项水质指标快速确定水质类别。综合污染指数法和内梅罗污染指数法根据代表代表性水体整体污染水平的数值来确定水体的污染程度。评价结果表明,除单因素评价法的评价结果为二类和三类外,其他评价方法的评价结果均为一类,说明水质较好。
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引用次数: 0
Removal of 17α-ethinylestradiol (EE2) from aqueous solutions by peanut shells (Arachis hypogaea): adsorption kinetic, isothermal, and thermodynamic studies 花生壳从水溶液中去除17α-炔雌醇(EE2):吸附动力学、等温和热力学研究
Q3 WATER RESOURCES Pub Date : 2023-11-04 DOI: 10.2166/wpt.2023.183
Alley Michael da Silva Procópio, Fabricio Vieira de Andrade, Flávio Soares da Silva, Sandro Andrade
Abstract This study evaluated the potential of using raw peanut shells as an adsorbent to remove the hormone 17α-ethylestradiol (EE2) from water. High-performance liquid chromatography with fluorescence detection was used in the determination of EE2. Kinetics data were tested with the pseudo-first-order, pseudo-second-order, and Elovich models, whereas isothermal data were tested with the Langmuir, Freundlich, and Sips models, and the parameters (ΔG°, ΔH° and ΔS°) were evaluated. A maximum removal rate of approximately 90% was observed in a solution with an initial EE2 concentration of 263.2 μg L−1, under the best experimental conditions (stirring speed = 500 rpm, pH = 6, and adsorbent mass = 2 g in 24 h), and showed an adsorption capacity of 17.3 μg g−1 at 306 K. The pseudo-first-order model adjusted better to the data in the studied temperature range, presenting a potential barrier of 16.69 kJ mol−1 (Ea) for adsorption kinetics. The Freundlich model and Sips model adjusted better to the data in the studied temperature range. The negative value of ΔG° (−15.87 kJ mol−1 at 306 K) confirmed the viability and spontaneity of the adsorption process. The positive value of ΔH° (168.9 kJ mol−1) characterized the chemical nature of the adsorption process.
摘要本研究评价了生花生壳作为吸附剂去除水中激素17α-乙基雌醇(EE2)的潜力。采用高效液相色谱-荧光检测法测定EE2。动力学数据采用拟一阶、拟二阶和Elovich模型进行测试,而等温数据采用Langmuir、Freundlich和Sips模型进行测试,并对参数(ΔG°、ΔH°和ΔS°)进行评估。在最佳实验条件下(搅拌转速为500 rpm, pH = 6,吸附剂质量为2 g,搅拌24 h), EE2初始浓度为263.2 μg L−1时,最大去除率约为90%,306 K时吸附量为17.3 μg−1。拟一阶模型较好地适应了所研究温度范围内的数据,其吸附动力学势垒为16.69 kJ mol−1 (Ea)。Freundlich模型和Sips模型较好地适应了所研究温度范围内的数据。ΔG°的负值(306 K时为- 15.87 kJ mol - 1)证实了吸附过程的活力和自发性。ΔH°(168.9 kJ mol−1)的正值表征了吸附过程的化学性质。
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引用次数: 0
Wetland water quality assessment of eco-engineered landscaping practices: a case study of constructed wetland parks in Hangzhou 生态工程景观实践中的湿地水质评价——以杭州市人工湿地公园为例
Q3 WATER RESOURCES Pub Date : 2023-11-03 DOI: 10.2166/wpt.2023.184
Yan Huang, Tianjie Li, Yang Jin
Abstract Urban constructed water quality treatment (WQT) wetlands are often applied to be integrated with ecological engineered landscaping (EEL) measures for wastewater treatments. This study aims to identify the interrelationships between the hydrological factors and pollutant removal contributions of typical WQT wetlands at each WQT stage, i.e., subsurface flow wetlands (SSF), vertical flow wetlands (VF), free surface flow wetland (FSF), floating wetland island (FWI), aeration ponds (APs), and ornamental ponds (OPs) in four typical wetland parks in Hangzhou, China. Water quality indices (WQIs) of wetland parks have been monitored. Interactive comparisons and correlations between hydrological indicators and WQIs (i.e., pH, DO, NH3-N, CODCr, and TP) are developed, while the removal contribution of each WQI was explained. It is found that each stage had heterogeneous effects on wastewater treatment due to various geo-ecological factors, including hydraulic conditions, plant type, and microbial microenvironment, whereas the temperature of waterbodies affected WQT performances at full sites in all seasons. Three corresponding EEL guiding principles were derived, i.e., optimising the EEL measures, adapting planting methods, and incorporating multifunctional design and adaptive management. The findings will be helpful for improving the efficacy of WQT stages as one of the potential ecosystem services provided by wetland parks.
城市人工水质处理湿地(WQT)常与生态工程美化(EEL)措施相结合,用于污水处理。以杭州4个典型湿地公园为研究对象,研究了典型湿地各阶段(潜流湿地(subsurface flow wetlands, SSF)、垂直流湿地(vertical flow wetlands, VF)、自由地表流湿地(free surface flow wetlands, FSF)、漂浮湿地岛(floating wetland island, FWI)、通气池(ventilation pond, APs)和观赏池(观赏池))的水文因子与污染物去除贡献之间的相互关系。对湿地公园的水质指标进行了监测。建立了水文指标与WQI(即pH、DO、NH3-N、CODCr和TP)之间的交互比较和相关性,并解释了每种WQI的去除贡献。研究发现,由于水力条件、植物类型和微生物微环境等不同的地质生态因素,每个阶段对废水处理的影响都是不均匀的,而水体温度在所有季节都影响着全站点的WQT性能。提出了优化生态环境效益措施、适应种植方式、结合多功能设计和适应性管理的生态环境效益指导原则。研究结果将有助于提高WQT阶段作为湿地公园潜在生态系统服务之一的效能。
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引用次数: 0
Study of outdoor rainwater drainage pollution in a hospital 某医院室外雨水排水污染研究
Q3 WATER RESOURCES Pub Date : 2023-11-03 DOI: 10.2166/wpt.2023.185
Ming Fang, Chunhu Chen, Xinren Ding, Zhen Qian
Abstract The outdoor rainwater drainage pollution in a large general hospital poses considerable threats to the environment and our health. A systematic analysis method was summarized in the investigation practice. Results showed that the pipe network damage caused by uneven geological settlement was the main reason for the pollution of the rainwater pipe network in the hospital. Countermeasures such as settlement repair and geological foundation reinforcement, rainwater and sewage pipeline transformation, the repair of mixed connection of rainwater and sewage pipes and polluted water sources, drainage health safety in isolated areas, and emergency storage tanks were discussed. After implementing the measures, the NH3-N measured value was within 0.82 mg/L, and the average removal rate was 97.4%. The COD concentration also decreased significantly with an average of 12 mg/L and the average removal rate was 91.8%. The results show that the reconstruction can effectively deal with the problem of outdoor rainwater drainage pollution in the hospital. The study has specific engineering reference significance for medical building drainage system's health and safety research.
某大型综合医院室外雨水排水污染对环境和人体健康构成相当大的威胁。在调查实践中总结出系统的分析方法。结果表明,不均匀地质沉降造成的管网破坏是造成医院雨水管网污染的主要原因。探讨了沉降修复和地质基础加固、雨污水管道改造、雨污水管道与污染水源混接修复、边远地区排水卫生安全、应急储罐等对策。实施该措施后,NH3-N测定值在0.82 mg/L以内,平均去除率为97.4%。COD浓度也显著下降,平均为12 mg/L,平均去除率为91.8%。结果表明,改造能有效解决医院室外雨水排水污染问题。该研究对医疗建筑排水系统的健康安全研究具有特定的工程参考意义。
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引用次数: 0
Mapping and analyzing temporal variability of spectral indices in lowland regions of Far western Nepal 绘制和分析尼泊尔远西部低地地区光谱指数的时间变异性
Q3 WATER RESOURCES Pub Date : 2023-10-31 DOI: 10.2166/wpt.2023.180
Mahesh Prasad Awasthi
Abstract Satellite imagery-based spectral indices are essential for monitoring natural resource changes and urban environments. Assessing these indices is vital for natural resource management and environmental sustainability. This study adopted geospatial techniques and satellite imagery (Landsat 5 TM and Landsat 8 OLI/TIRS) to analyze changes in key spectral indices, i.e. Normalized Difference Vegetation Index (NDVI), Normalized Difference Built-Up Index (NDBI), and Normalized Difference Water Index (NDWI) over the past three decades (1991–2022) in the low land region of Far Western Nepal. The study examined the temporal trends and intricate relationships between these indices during this time frame. The substantial changes in NDVI, NDBI, and NDWI within the study area have been quantified from 1991 to 2022. The findings revealed significantly elevated NDBI values in 1991, 2001, and 2013 compared to 2022, while NDWI and NDVI values were consistently lower in 1991,2001, and 2013 compared to 2022. Notably, a negative correlation was observed between NDVI and both NDBI and NDWI, contrasting with the positive correlation found between NDBI and NDWI. The study underscores the potential of combining these spectral indices to evaluate vegetated areas, built-up areas, and water bodies, providing valuable insights for effective land management, urban planning, environmental monitoring, and sustainable water resource management.
基于卫星影像的光谱指数是监测自然资源变化和城市环境的重要手段。评估这些指数对自然资源管理和环境可持续性至关重要。本研究采用地理空间技术和卫星影像(Landsat 5 TM和Landsat 8 OLI/TIRS),分析了尼泊尔远西部低地地区近30年(1991-2022)归一化植被指数(NDVI)、归一化建筑指数(NDBI)和归一化水指数(NDWI)的变化。该研究考察了这些指数在这段时间内的时间趋势和复杂关系。研究区NDVI、NDBI和NDWI在1991 - 2022年间的实质性变化已被量化。研究结果显示,与2022年相比,1991年、2001年和2013年的NDBI值显著升高,而1991年、2001年和2013年的NDWI和NDVI值持续降低。值得注意的是,NDVI与NDBI和NDWI均呈负相关,而NDBI与NDWI呈正相关。该研究强调了将这些光谱指数结合起来评估植被区、建成区和水体的潜力,为有效的土地管理、城市规划、环境监测和可持续水资源管理提供了有价值的见解。
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引用次数: 0
Chromium (VI) and lead (II) adsorption using Mangifera kemanga leaves 芒树叶对铬(ⅵ)和铅(ⅱ)的吸附研究
Q3 WATER RESOURCES Pub Date : 2023-10-28 DOI: 10.2166/wpt.2023.182
Dian Arrisujaya, Niti Sae Utami, Tia Mulyawati, Dea Rahmalisa, Siska Wati, Hidayat Hidayat
Abstract This work reports the use of Mangifera kemanga leaves (MKL) treated with ethanol and nitric acid as an adsorbent to remove Cr(VI) and Pb(II) ions at different pHs, adsorbent dosages, times, initial metal ion concentrations, and temperatures. The MKL's maximum adsorption capacity was 213 mg/g for Cr(VI) at pH 2 and 89 mg/g for Pb(II) at pH 6. Batch experiments showed that MKL follows the Langmuir isotherm model in absorbing Cr(VI) and Pb(II). The Cr(VI) and Pb(II) adsorption kinetics are best suited by the pseudo-second-order kinetics model. Thermodynamic data studies indicated that surface complexation coexisted with ion exchange as the preliminary removal means. The results implied that MKL could potentially remove Cr(VI) and Pb(II).
摘要以芒果叶为材料,在不同ph值、吸附剂用量、吸附剂时间、初始金属离子浓度和吸附剂温度条件下,用乙醇和硝酸对芒果叶进行吸附,去除Cr(VI)和Pb(II)离子。MKL在pH 2时对Cr(VI)的最大吸附量为213 mg/g, pH 6时对Pb(II)的最大吸附量为89 mg/g。批量实验表明,MKL吸附Cr(VI)和Pb(II)符合Langmuir等温线模型。Cr(VI)和Pb(II)的吸附动力学最适合拟二级动力学模型。热力学数据研究表明,表面络合与离子交换作为初步去除手段并存。结果表明,MKL对Cr(VI)和Pb(II)具有一定的去除作用。
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引用次数: 0
Ionic solvent-mediated electrolytic decontamination of pesticide-containing wastewater 离子溶剂介导的含农药废水电解净化
Q3 WATER RESOURCES Pub Date : 2023-10-27 DOI: 10.2166/wpt.2023.181
John A. O. Oyekunle, Solomon S. Durodola, Oluwakemi O. Tovide, Allen A. Olorunkosebi, Ebunoluwa O. Olufisayo, Abolanle S. Adekunle, Aderemi O. Ogunfowokan
Abstract This study investigated the performance of different ionic solvents (NaCl, KNO3, and Na2SO4) in mediating electrolytic decontamination of pesticide-containing wastewaters and established the most suitable ionic solvent that can satisfactorily achieve decontamination of such wastewaters. These were done to find a water-purification technique suitable for the removal of recalcitrant and hazardous trace organic substances from wastewater. Organochlorine pesticide (OCP)-containing wastewaters were constituted according to prescribed modalities. It was observed that complete decontamination of the wastewater was achieved within 2 h of using Na2SO4. The study concluded that the 1.0 M of Na2SO4 solution-mediated electrolytic process was most efficient in decontaminating OCP-containing wastewater.
摘要本研究考察了不同离子溶剂(NaCl、KNO3和Na2SO4)在含农药废水电解除污中的中介作用,确定了最适合的离子溶剂,能较好地实现含农药废水的除污。这些都是为了找到一种适合去除废水中顽固和有害的微量有机物质的水净化技术。按规定的方式配制含有机氯农药废水。结果表明,在使用Na2SO4后的2 h内,废水得到了完全的净化。研究结果表明,1.0 M Na2SO4溶液介导的电解工艺对含ocp废水的净化效果最好。
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引用次数: 0
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Water Practice and Technology
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