Navid Ahmadi, Muhammad Muniruzzaman, Jacopo Cogorno, Massimo Rolle
The dissolution of sulfide minerals in subsurface porous media has important environmental implications. We investigate the oxidative dissolution of pyrite under evaporative conditions and advance a mechanistic understanding of the interactions between multiple physical processes and mineral/surface reactions. We performed a set of experiments in which initially water saturated and anoxic soil columns, containing a top layer of pyrite, are exposed to the atmosphere under no evaporation (single-phase) and natural evaporative (two-phase) conditions. The oxidative dissolution of pyrite was monitored by non-invasive high-resolution measurements of oxygen and pH. Additionally, we developed and applied a multiphase and multicomponent reactive transport model to quantitatively describe the experimental outcomes and elucidate the interplay between the physico-chemical mechanisms controlling the extent of pyrite dissolution. The results confirm that the extent of pyrite dissolution under single-phase conditions was constrained by the slow diffusive transport of oxygen in the liquid phase. In contrast, during evaporation, the evolution of fluid phases and interphase mass transfer processes imposed distinct physical constraints on the dynamics of pyrite oxidation. Initially, the invasion of the gaseous phase led to a fast delivery of high oxygen concentrations in the reactive zone and thus markedly increased pyrite oxidation and acidity/sulfate production. However, such enhanced release of reaction products was progressively limited over time as drying conditions prevailed in the reactive zone and inhibited pyrite oxidation. The transient phase displacement was also found to control the distribution of aqueous species and formation of secondary minerals by creating spatio-temporally variable redox conditions.
{"title":"Oxidative Dissolution of Sulfide Minerals in Porous Media Under Evaporative Conditions: Multiphase Experiments and Process-Based Modeling","authors":"Navid Ahmadi, Muhammad Muniruzzaman, Jacopo Cogorno, Massimo Rolle","doi":"10.1029/2024wr037317","DOIUrl":"https://doi.org/10.1029/2024wr037317","url":null,"abstract":"The dissolution of sulfide minerals in subsurface porous media has important environmental implications. We investigate the oxidative dissolution of pyrite under evaporative conditions and advance a mechanistic understanding of the interactions between multiple physical processes and mineral/surface reactions. We performed a set of experiments in which initially water saturated and anoxic soil columns, containing a top layer of pyrite, are exposed to the atmosphere under no evaporation (single-phase) and natural evaporative (two-phase) conditions. The oxidative dissolution of pyrite was monitored by non-invasive high-resolution measurements of oxygen and pH. Additionally, we developed and applied a multiphase and multicomponent reactive transport model to quantitatively describe the experimental outcomes and elucidate the interplay between the physico-chemical mechanisms controlling the extent of pyrite dissolution. The results confirm that the extent of pyrite dissolution under single-phase conditions was constrained by the slow diffusive transport of oxygen in the liquid phase. In contrast, during evaporation, the evolution of fluid phases and interphase mass transfer processes imposed distinct physical constraints on the dynamics of pyrite oxidation. Initially, the invasion of the gaseous phase led to a fast delivery of high oxygen concentrations in the reactive zone and thus markedly increased pyrite oxidation and acidity/sulfate production. However, such enhanced release of reaction products was progressively limited over time as drying conditions prevailed in the reactive zone and inhibited pyrite oxidation. The transient phase displacement was also found to control the distribution of aqueous species and formation of secondary minerals by creating spatio-temporally variable redox conditions.","PeriodicalId":23799,"journal":{"name":"Water Resources Research","volume":"19 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2024-12-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142888006","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ahmed Elkouk, Yadu Pokhrel, Ben Livneh, Elizabeth Payton, Lifeng Luo, Yifan Cheng, Katherine Dagon, Sean Swenson, Andrew W. Wood, David M. Lawrence, Wim Thiery
Crucial to the assessment of future water security is how the land model component of Earth System Models partition precipitation into evapotranspiration and runoff, and the sensitivity of this partitioning to climate. This sensitivity is not explicitly constrained in land models nor the model parameters important for this sensitivity identified. Here, we seek to understand parametric controls on runoff sensitivity to precipitation and temperature in a state-of-the-science land model, the Community Land Model version 5 (CLM5). Process-parameter interactions underlying these two climate sensitivities are investigated using the sophisticated variance-based sensitivity analysis. This analysis focuses on three snow-dominated basins in the Colorado River headwaters region, a prominent exemplar where land models display a wide disparity in runoff sensitivities. Runoff sensitivities are dominated by indirect or interaction effects between a few parameters of subsurface, snow, and plant processes. A focus on only one kind of parameters would therefore limit the ability to constrain the others. Surface runoff exhibits strong sensitivity to parameters of snow and subsurface processes. Constraining snow simulations would require explicit representation of the spatial variability across large elevation gradients. Subsurface runoff and soil evaporation exhibit very similar sensitivities. Model calibration against the subsurface runoff flux would therefore constrain soil evaporation. The push toward a mechanistic treatment of processes in CLM5 have dampened the sensitivity of parameters compared to earlier model versions. A focus on the sensitive parameters and processes identified here can help characterize and reduce uncertainty in water resource sensitivity to climate change.
{"title":"Toward Understanding Parametric Controls on Runoff Sensitivity to Climate in the Community Land Model: A Case Study Over the Colorado River Headwaters","authors":"Ahmed Elkouk, Yadu Pokhrel, Ben Livneh, Elizabeth Payton, Lifeng Luo, Yifan Cheng, Katherine Dagon, Sean Swenson, Andrew W. Wood, David M. Lawrence, Wim Thiery","doi":"10.1029/2024wr037718","DOIUrl":"https://doi.org/10.1029/2024wr037718","url":null,"abstract":"Crucial to the assessment of future water security is how the land model component of Earth System Models partition precipitation into evapotranspiration and runoff, and the sensitivity of this partitioning to climate. This sensitivity is not explicitly constrained in land models nor the model parameters important for this sensitivity identified. Here, we seek to understand parametric controls on runoff sensitivity to precipitation and temperature in a state-of-the-science land model, the Community Land Model version 5 (CLM5). Process-parameter interactions underlying these two climate sensitivities are investigated using the sophisticated variance-based sensitivity analysis. This analysis focuses on three snow-dominated basins in the Colorado River headwaters region, a prominent exemplar where land models display a wide disparity in runoff sensitivities. Runoff sensitivities are dominated by indirect or interaction effects between a few parameters of subsurface, snow, and plant processes. A focus on only one kind of parameters would therefore limit the ability to constrain the others. Surface runoff exhibits strong sensitivity to parameters of snow and subsurface processes. Constraining snow simulations would require explicit representation of the spatial variability across large elevation gradients. Subsurface runoff and soil evaporation exhibit very similar sensitivities. Model calibration against the subsurface runoff flux would therefore constrain soil evaporation. The push toward a mechanistic treatment of processes in CLM5 have dampened the sensitivity of parameters compared to earlier model versions. A focus on the sensitive parameters and processes identified here can help characterize and reduce uncertainty in water resource sensitivity to climate change.","PeriodicalId":23799,"journal":{"name":"Water Resources Research","volume":"92 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2024-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142874205","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Md Abu Bakar Siddik, Arman Shehabi, Prakash Rao, Landon T. Marston
Electricity generation in the United States entails significant water usage and greenhouse gas emissions. However, accurately estimating these impacts is complex due to the intricate nature of the electric grid and the dynamic electricity mix. Existing methods to estimate the environmental consequences of electricity use often generalize across large regions, neglecting spatial and temporal variations in water usage and emissions. Consequently, electric grid dynamics, such as temporal fluctuations in renewable energy resources, are often overlooked in efforts to mitigate environmental impacts. The U.S. Department of Energy (DOE) has initiated the development of resilient energyshed management systems, requiring detailed information on the local electricity mix and its environmental impacts. This study supports DOE's goal by incorporating geographic and temporal variations in the electricity mix of the local electric grid to better understand the environmental impacts of electricity end users. We offer hourly estimates of the U.S. electricity mix, detailing fuel types, water withdrawal intensity, and water consumption intensity for each grid balancing authority through our publicly accessible tool, the Water Integrated Mapping of Power and Carbon Tracker (Water IMPACT). While our primary focus is on evaluating water intensity factors, our dataset and programming scripts for historical and real-time analysis also include evaluations of carbon dioxide (equivalence) intensity within the same modeling framework. This integrated approach offers a comprehensive understanding of the environmental footprint associated with electricity generation and use, enabling informed decision-making to effectively reduce Scope 2 water usage and emissions.
{"title":"Spatially and Temporally Detailed Water and Carbon Footprints of U.S. Electricity Generation and Use","authors":"Md Abu Bakar Siddik, Arman Shehabi, Prakash Rao, Landon T. Marston","doi":"10.1029/2024wr038350","DOIUrl":"https://doi.org/10.1029/2024wr038350","url":null,"abstract":"Electricity generation in the United States entails significant water usage and greenhouse gas emissions. However, accurately estimating these impacts is complex due to the intricate nature of the electric grid and the dynamic electricity mix. Existing methods to estimate the environmental consequences of electricity use often generalize across large regions, neglecting spatial and temporal variations in water usage and emissions. Consequently, electric grid dynamics, such as temporal fluctuations in renewable energy resources, are often overlooked in efforts to mitigate environmental impacts. The U.S. Department of Energy (DOE) has initiated the development of resilient energyshed management systems, requiring detailed information on the local electricity mix and its environmental impacts. This study supports DOE's goal by incorporating geographic and temporal variations in the electricity mix of the local electric grid to better understand the environmental impacts of electricity end users. We offer hourly estimates of the U.S. electricity mix, detailing fuel types, water withdrawal intensity, and water consumption intensity for each grid balancing authority through our publicly accessible tool, the Water Integrated Mapping of Power and Carbon Tracker (Water IMPACT). While our primary focus is on evaluating water intensity factors, our dataset and programming scripts for historical and real-time analysis also include evaluations of carbon dioxide (equivalence) intensity within the same modeling framework. This integrated approach offers a comprehensive understanding of the environmental footprint associated with electricity generation and use, enabling informed decision-making to effectively reduce Scope 2 water usage and emissions.","PeriodicalId":23799,"journal":{"name":"Water Resources Research","volume":"201 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2024-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142874207","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Groundwater level variations represent signals of superimposed physical processes, with memory. Groundwater level records are used to understand how aquifer systems respond to natural and anthropogenic perturbations. Here we analyze groundwater levels across the South Coast of British Columbia (BC) in the Pacific Northwest with the objective of determining groundwater responses to atmospheric rivers (ARs) and drought. An AR catalog was derived and used to associate precipitation amounts to AR occurrence. Droughts were quantified using dry day metrics, in conjunction with the standardized precipitation index. Historically (1980–2023), from September to January, approximately 40% of total precipitation was contributed by ARs. From April to September, more than 50% of days received no precipitation, with typically 26 consecutive dry days. We used the autocorrelation structure of groundwater levels, commonly used to characterize aquifer memory, to identify two distinct clusters of observation well responses. Cluster 1 wells respond to recharge from local precipitation, primarily rainfall, and respond rapidly to both ARs during winter recharge and significant rainfall deficits during summer. Cluster 2 wells are driven by local precipitation but are influenced by the Fraser River's large summer freshet which briefly recharges the aquifers, thereby delaying drought propagation. The results suggest that groundwater memory encapsulates multiple hydrogeological factors, including boundary conditions, influencing the response outcome to extreme events.
{"title":"Groundwater Responses to Deluge and Drought in the Fraser Valley, Pacific Northwest","authors":"A. H. Nott, D. M. Allen, W. J. Hahm","doi":"10.1029/2023wr036769","DOIUrl":"https://doi.org/10.1029/2023wr036769","url":null,"abstract":"Groundwater level variations represent signals of superimposed physical processes, with memory. Groundwater level records are used to understand how aquifer systems respond to natural and anthropogenic perturbations. Here we analyze groundwater levels across the South Coast of British Columbia (BC) in the Pacific Northwest with the objective of determining groundwater responses to atmospheric rivers (ARs) and drought. An AR catalog was derived and used to associate precipitation amounts to AR occurrence. Droughts were quantified using dry day metrics, in conjunction with the standardized precipitation index. Historically (1980–2023), from September to January, approximately 40% of total precipitation was contributed by ARs. From April to September, more than 50% of days received no precipitation, with typically 26 consecutive dry days. We used the autocorrelation structure of groundwater levels, commonly used to characterize aquifer memory, to identify two distinct clusters of observation well responses. Cluster 1 wells respond to recharge from local precipitation, primarily rainfall, and respond rapidly to both ARs during winter recharge and significant rainfall deficits during summer. Cluster 2 wells are driven by local precipitation but are influenced by the Fraser River's large summer freshet which briefly recharges the aquifers, thereby delaying drought propagation. The results suggest that groundwater memory encapsulates multiple hydrogeological factors, including boundary conditions, influencing the response outcome to extreme events.","PeriodicalId":23799,"journal":{"name":"Water Resources Research","volume":"157 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2024-12-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142832913","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Artificial intelligence (AI) methods have created insurmountable performance in prediction tasks for geoscientific problems yet are unable to derive process insights and answer specific scientific questions. The geoscience community faces a dilemma of reconciling process comprehension with high predictive accuracy. Here we introduce a deep process learning (DPL) approach empowering neural networks to deduce intrinsic processes from observable data, wherein the intuitive physics of geosystems is directly coupled within the deep learning (DL) architecture as structural prior. We aim to incorporate as raw common concepts as possible as macroscopic guidance: on the one hand, to reduce interference with DL's data adaptability. On the other hand, to allow the information flow of the model to converge along specific paths toward the target output, thus enabling the potential to gain process insights with limited supervision. Illustrating its application to precipitation-runoff modeling across the USA, DPL yields an ensemble median Nash-Sutcliffe efficiency of 0.758 and Kling-Gupta efficiency of 0.778 with robust transferability, compared to 0.762 and 0.751 for the state-of-the-art DL model. The good match between internal representations of DPL and independent data sets of snow water equivalent and evapotranspiration, along with its superior capability for catchment water budget closures, demonstrates proficient process mastery. The study also highlights beneficial synergies from large-scale data collaboration, promoting the organic unity of process understanding and predictive performance. This work shows a promising avenue for learning processes from big data and will benefit geoscientific domains that remain concerned with process clarity in the era of AI.
{"title":"Synergizing Intuitive Physics and Big Data in Deep Learning: Can We Obtain Process Insights While Maintaining State-Of-The-Art Hydrological Prediction Capability?","authors":"Leilei He, Liangsheng Shi, Wenxiang Song, Jiawen Shen, Lijun Wang, Xiaolong Hu, Yuanyuan Zha","doi":"10.1029/2024wr037582","DOIUrl":"https://doi.org/10.1029/2024wr037582","url":null,"abstract":"Artificial intelligence (AI) methods have created insurmountable performance in prediction tasks for geoscientific problems yet are unable to derive process insights and answer specific scientific questions. The geoscience community faces a dilemma of reconciling process comprehension with high predictive accuracy. Here we introduce a deep process learning (DPL) approach empowering neural networks to deduce intrinsic processes from observable data, wherein the intuitive physics of geosystems is directly coupled within the deep learning (DL) architecture as structural prior. We aim to incorporate as raw common concepts as possible as macroscopic guidance: on the one hand, to reduce interference with DL's data adaptability. On the other hand, to allow the information flow of the model to converge along specific paths toward the target output, thus enabling the potential to gain process insights with limited supervision. Illustrating its application to precipitation-runoff modeling across the USA, DPL yields an ensemble median Nash-Sutcliffe efficiency of 0.758 and Kling-Gupta efficiency of 0.778 with robust transferability, compared to 0.762 and 0.751 for the state-of-the-art DL model. The good match between internal representations of DPL and independent data sets of snow water equivalent and evapotranspiration, along with its superior capability for catchment water budget closures, demonstrates proficient process mastery. The study also highlights beneficial synergies from large-scale data collaboration, promoting the organic unity of process understanding and predictive performance. This work shows a promising avenue for learning processes from big data and will benefit geoscientific domains that remain concerned with process clarity in the era of AI.","PeriodicalId":23799,"journal":{"name":"Water Resources Research","volume":"21 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2024-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142821004","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Using a constant channel velocity, <span data-altimg="/cms/asset/70a4c7db-bd6a-48ef-a7e9-acfa323f7367/wrcr27612-math-0001.png"></span><math altimg="urn:x-wiley:00431397:media:wrcr27612:wrcr27612-math-0001" display="inline" location="graphic/wrcr27612-math-0001.png">