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A Novel Dual-Clustering Approach for Identifying Hydrological Response Patterns From Catchment Characteristics and Environmental Changes 从流域特征和环境变化中识别水文响应模式的新型双聚类方法
IF 5.4 1区 地球科学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-03-10 DOI: 10.1029/2025wr041613
Yuhao Wang, Ke Zhang, Edward Park, Jie Liu, Yuning Luo, Shunzhang Li, Sheng Wang
Understanding how catchments respond to environmental changes is critical for water resource management. However, few studies have systematically linked catchment characteristics, environmental changes, and hydrological responses. Therefore, this study proposes a novel dual-clustering approach for identifying hydrological response patterns. It constructs the catchment characteristic indicator system for the baseline period and introduces dynamic similarity indicators that reflect climate change and anthropogenic impacts to achieve dual clustering, thereby identifying hydrological response differences. Furthermore, it employs the eXtreme Gradient Boosting (XGBoost) and SHapley Additive exPlanations (SHAP) methods to identify key influencing factors of runoff change significance, providing interpretable insights into differences in hydrological responses. The approach is applied to the Haihe River Basin, indicating that 160 catchments are classified into nine static groups (A1–A9) based on catchment characteristics and five dynamic groups (B1–B5) based on environmental changes. The XGBoost model demonstrates good performance in identifying hydrological response patterns, SHAP analysis identifies the top four important factors as percentage of areas with substantial declines in the water table (positive), proportion of natural land use (positive), degree of humidity (negative), and mean elevation (positive). Catchments located in the northwestern mountainous areas are more susceptible to environmental changes, while those located in the southwestern mountainous areas and the southern plains show relatively stable response patterns. Additionally, environmental change patterns characterized by substantial water table decline are more likely to trigger significant runoff change. This approach provides new insights into the effects of interactions between static catchment characteristics and dynamic environmental changes on hydrological functioning.
了解集水区如何应对环境变化对水资源管理至关重要。然而,很少有研究系统地将流域特征、环境变化和水文响应联系起来。因此,本研究提出了一种新的双聚类方法来识别水文响应模式。构建基准期流域特征指标体系,引入反映气候变化和人为影响的动态相似性指标,实现双聚类,识别水文响应差异。此外,采用极端梯度增强(XGBoost)和SHapley加性解释(SHAP)方法识别径流变化显著性的关键影响因素,为水文响应差异提供可解释的见解。将该方法应用于海河流域,160个流域根据流域特征划分为9个静态类群(a1 ~ a9)和5个基于环境变化的动态类群(b1 ~ b5)。XGBoost模型在识别水文响应模式方面表现良好,SHAP分析确定了水位大幅下降的地区百分比(正)、自然土地利用比例(正)、湿度(负)和平均海拔(正)这四个重要因素。西北山区的流域对环境变化的响应更敏感,而西南山区和南部平原的流域则表现出相对稳定的响应模式。此外,以地下水位大幅下降为特征的环境变化模式更有可能引发显著的径流变化。这种方法为静态流域特征和动态环境变化之间的相互作用对水文功能的影响提供了新的见解。
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引用次数: 0
Impact of Density Gradients and Momentum Ratios on Streamwise Circulation at River Confluences 密度梯度和动量比对河流汇合处流向环流的影响
IF 5.4 1区 地球科学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-03-09 DOI: 10.1029/2025wr041585
Abdelrahman Hosny Abdou, Jason Duguay, Pascale Biron, Jay Lacey
Mixing processes in confluences influence concentrations of water quality parameters such as suspended sediment loads and water chemistry in the post-confluent reach. Thus, improving our understanding of confluence flow structures and mixing is key to predicting the impact of the downstream propagation of pollutants and nutrients. Parameters such as density difference <span data-altimg="/cms/asset/01665dc1-ef2c-4cda-9454-08a6f4fa4f7d/wrcr70778-math-0001.png"></span><math altimg="urn:x-wiley:00431397:media:wrcr70778:wrcr70778-math-0001" display="inline" location="graphic/wrcr70778-math-0001.png"><semantics><mrow><mo stretchy="false">(</mo><mrow><mi mathvariant="normal">Δ</mi><mi>ρ</mi></mrow><mo stretchy="false">)</mo></mrow>$({Delta }rho )$</annotation></semantics></math> and momentum ratio <span data-altimg="/cms/asset/ec244274-2ca2-4633-ae2a-c380a7b0b4be/wrcr70778-math-0002.png"></span><math altimg="urn:x-wiley:00431397:media:wrcr70778:wrcr70778-math-0002" display="inline" location="graphic/wrcr70778-math-0002.png"><semantics><mrow><mo stretchy="false">(</mo><mrow><mi>M</mi><mi>r</mi></mrow><mo stretchy="false">)</mo></mrow>$(Mr)$</annotation></semantics></math> significantly influence the flow field and mixing processes. This study uses eddy-resolved numerical simulations to investigate the impact of these parameters on the formation of density-driven streamwise-oriented vortices (density-driven SOVs) and mixing in a symmetric experimental confluence. Three values of <span data-altimg="/cms/asset/807f4c30-c683-4642-bf08-6b8618fb8175/wrcr70778-math-0003.png"></span><math altimg="urn:x-wiley:00431397:media:wrcr70778:wrcr70778-math-0003" display="inline" location="graphic/wrcr70778-math-0003.png"><semantics><mrow><mi>M</mi><mi>r</mi></mrow>$Mr$</annotation></semantics></math> with varying magnitudes of the densimetric Froude number <span data-altimg="/cms/asset/f412edb6-6913-40fd-9bd6-92c5dd52de02/wrcr70778-math-0004.png"></span><math altimg="urn:x-wiley:00431397:media:wrcr70778:wrcr70778-math-0004" display="inline" location="graphic/wrcr70778-math-0004.png"><semantics><mrow><mfenced close=")" open="(" separators=""><msub><mi>F</mi><mi>D</mi></msub></mfenced></mrow>$left({F}_{D}right)$</annotation></semantics></math>, representing <span data-altimg="/cms/asset/b4e47aa0-1234-4367-b75e-699364eb983d/wrcr70778-math-0005.png"></span><math altimg="urn:x-wiley:00431397:media:wrcr70778:wrcr70778-math-0005" display="inline" location="graphic/wrcr70778-math-0005.png"><semantics><mrow><mi mathvariant="normal">Δ</mi><mi>ρ</mi></mrow>${Delta }rho $</annotation></semantics></math> were considered in the numerical simulations. A clear pattern for the dominant streamwise circulation (circulation caused by the <span data-altimg="/cms/asset/ef31400c-0c92-4f80-b04f-2b30da84eb4f/wrcr70778-math-0006.png"></span><math altimg="urn:x-wiley:00431397:media:wrcr70778:wrcr70778-math-0006" display="inline" location="graphic/wrcr
汇合处的混合过程会影响汇合处后河段悬沙负荷和水化学等水质参数的浓度。因此,提高我们对汇流流结构和混合的理解是预测污染物和营养物下游传播影响的关键。密度差(Δρ) $({Delta }rho )$和动量比(Mr) $(Mr)$等参数对流场和混合过程有显著影响。本研究使用涡分辨数值模拟来研究这些参数对对称实验合流中密度驱动流向涡旋(密度驱动sov)形成和混合的影响。在数值模拟中考虑了Mr $Mr$的三个不同大小的密度弗鲁德数FD $left({F}_{D}right)$,表示Δρ ${Delta }rho $。在FD ${F}_{D}$和Mr $Mr$的变化中,可以观察到明显的主流环流模式(由Δρ ${Delta }rho $标志引起的环流)。因此,提出了一个方程来预测主导的流向环流作为Mr $Mr$, FD ${F}_{D}$和到顶点距离的函数。此外,结果表明,流向环流和混合速率与Δρ ${Delta }rho $(即FD减小${F}_{D}$)呈正相关。结果表明,增加Mr $Mr$和降低FD ${F}_{D}$(从而增加Δρ ${Delta }rho $)促进了混合。结果表明,密度驱动汇流中的混合不仅仅是由密度驱动的sov驱动的,还受到其他共存结构的驱动,如垂直取向的Kelvin-Helmholtz不稳定性。
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引用次数: 0
Satellite Solutions: Facing Chlorophyll-a Retrieval in Small Mountain Lakes in the Sierra Nevada, Spain 面向西班牙内华达山脉小山地湖泊叶绿素a反演的卫星解决方案
IF 5.4 1区 地球科学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-03-09 DOI: 10.1029/2026wr043523
J. Llodrà-Llabrés, J. C. Pérez-Girón, T. Postma, C. Pérez-Martínez, D. Alcaraz-Segura, J. Martínez-López
National and international regulations enforce monitoring programmes of water quality to guide management actions of inland water ecosystems. Our study evaluates the effect of spectral and spatial resolutions on the estimation of chlorophyll-a concentrations in mountain lakes, and derives implications for addressing the adjacency effect, which is critical and understudied in small water bodies. Five lakes in Sierra Nevada (Spain) were repeatedly sampled during 2020, 2021, and 2023, and a total of 100 chlorophyll-a samples with suitable coincident satellite imagery were analyzed. Laboratory-obtained chlorophyll-a concentrations were modeled comparing up to 86 spectral indices and bands as predictors from three satellites: Sentinel-2 (12 bands, 20 m/pixel), Planet (8 bands, 3 m/pixel) and WorldView-3 (11 bands, 1.24 m/pixel). Our results showed that multivariate models for estimating chlorophyll-a using spectral indices did not perform significantly better than using bands alone. The best models always had multiple predictors and included green and near-infrared bands. Models based on Sentinel-2 and Planet (Radj2 > 0.45) outperformed those of WorldView-3 (Radj2 ∼ 0.37), confirming that the latter performed worst despite higher spatial resolution. Regarding distance to shoreline, the Planet model showed the most consistent performance, with stable Radj2 values and low RMSE even at 3 m from shore with a high level of accuracy (Radj2 ∼ 0.3; RMSE ∼ 1.15 μg L−1). Data and models are released to facilitate near-real-time monitoring of these vulnerable ecosystems, where field sampling is extremely challenging.
国家和国际法规强制执行水质监测方案,以指导内陆水生态系统的管理行动。我们的研究评估了光谱和空间分辨率对山地湖泊叶绿素a浓度估算的影响,并得出了解决邻接效应的建议,这在小水体中是至关重要的,但研究不足。对西班牙内华达山脉5个湖泊在2020年、2021年和2023年进行了重复采样,分析了100份符合卫星影像的叶绿素-a样本。利用来自Sentinel-2(12个波段,20 m/像元)、Planet(8个波段,3 m/像元)和WorldView-3(11个波段,1.24 m/像元)的86个光谱指数和波段作为预测因子,对实验室获得的叶绿素a浓度进行了建模。结果表明,利用光谱指数估算叶绿素-a的多变量模型并不比单独使用波段估算的模型效果好。最好的模型总是有多个预测因子,包括绿色和近红外波段。基于Sentinel-2和Planet (Radj2 > 0.45)的模型优于WorldView-3 (Radj2 ~ 0.37),证实后者在更高的空间分辨率下表现最差。在与海岸线的距离方面,Planet模型表现出最一致的性能,即使在距离海岸3 m处,Radj2值稳定,RMSE低,精度高(Radj2 ~ 0.3; RMSE ~ 1.15 μg L−1)。发布数据和模型是为了促进对这些脆弱生态系统的近实时监测,在这些生态系统中,现场采样极具挑战性。
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引用次数: 0
Integrating Deep Learning and Distance-Based Clustering to Optimize the Field Scale In Situ Uranium Leaching System in Heterogeneous Reservoirs 结合深度学习和距离聚类优化非均质储层现场铀浸出系统
IF 5.4 1区 地球科学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-03-09 DOI: 10.1029/2025wr041741
Wenjie Qiu, Dianguang Liu, Yun Yang, Jian Song, Weimin Que, Zhengbang Liu, Haicheng Weng, Jianfeng Wu, Jichun Wu
Utilization of the integrated simulation-optimization models for supporting decisions of the in situ leaching (ISL) design of uranium (U) mining is often hampered by the physicochemical heterogeneity within the sandstone reservoirs. Nevertheless, the conventional way suffers from a high conceptual uncertainty due to almost ubiquitous simplifying assumptions used in model parameterizations. Additionally, the increasing complexity of process-based reactive transport simulators results in substantial computational demands, limiting the feasibility of conducting numerous model evaluations. Addressing the optimization challenges posed by geological uncertainty typically involves Monte Carlo-based population search methods with evolutionary algorithms which are often computationally intensive and suffer from excessive model redundancy. This study presents a novel optimization framework for identifying the optimal well control strategies for a field-scale neutral ISL of U mining system in the Songliao Basin, China. The proposed approach integrates a deep learning-based proxy model with distance-based clustering components. Specifically, a ResNet-LSTM network is employed to predict dynamic U recovery concentration. A small subset of representative reservoir realizations is selected through clustering analysis, effectively capturing the uncertainty space without relying on the full ensemble. The subset is then embedded into a heuristic evolutionary algorithm with the objective of maximizing economic benefits. The results demonstrate that this integrated framework significantly enhances the decision-making process in a computationally efficient way. By integrating the proxy model with cluster-based realization selection, the proposed procedure achieves a 15.2% improvement in net present value compared to unoptimized scenarios. Overall, the framework provides a versatile and powerful tool for robust optimization in heterogeneous reservoirs.
砂岩储层内部的物理化学非均质性往往阻碍了综合模拟优化模型在铀矿就地浸出设计支持决策中的应用。然而,由于模型参数化中几乎无处不在的简化假设,传统的方法具有很高的概念不确定性。此外,基于过程的反应传输模拟器的复杂性日益增加,导致大量的计算需求,限制了进行大量模型评估的可行性。解决地质不确定性带来的优化挑战通常涉及基于蒙特卡罗的种群搜索方法和进化算法,这些算法通常计算量大且模型冗余过多。本文提出了一种新的优化框架,用于确定松辽盆地U开采系统现场中性ISL的最优井控策略。该方法将基于深度学习的代理模型与基于距离的聚类组件集成在一起。具体而言,采用ResNet-LSTM网络预测U的动态回收浓度。通过聚类分析选择具有代表性的油藏实现的一小部分,有效地捕获不确定性空间,而不依赖于完整的集合。然后将该子集嵌入到以经济效益最大化为目标的启发式进化算法中。结果表明,该集成框架以计算效率的方式显著提高了决策过程。通过将代理模型与基于集群的实现选择相结合,与未优化的场景相比,所提出的过程实现了15.2%的净现值改进。总的来说,该框架为非均质油藏的稳健优化提供了一个通用而强大的工具。
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引用次数: 0
Latent Data Assimilation for Efficient and Accurate Groundwater Modeling 有效和准确模拟地下水的潜在数据同化
IF 5.4 1区 地球科学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-03-09 DOI: 10.1029/2025wr042424
Yongda Liu, Xi Chen, Zitao Wang, Jianzhi Dong
Groundwater model predictions are often inaccurate due to uncertainties in model structure, heterogeneous parameters, and initial conditions, leading to error accumulation during simulations. Traditional data assimilation (DA) faces severe computational challenges in high-dimensional systems due to the costly inversion of large covariance matrices. In addition, the inaccurate estimation of background and observation error statistics introduces further biases. To address these challenges, we develop and evaluate an integrated framework that couples a computationally efficient deep learning surrogate model for rapid prediction with Latent Data Assimilation (LDA) to accurately correct simulations. The framework employs dimensionality reduction, specifically Proper Orthogonal Decomposition (POD), to project the high-dimensional physical state into a low-dimensional latent space. Data assimilation is then performed in this reduced space using the Ensemble Kalman Filter (EnKF). Results demonstrate that POD provides a robust representation of simulated concentration fields and interpolated observations for dimensionality reduction. The EnKF operating in the latent space effectively reduces prediction errors. Key advantages of the LDA framework include: enabling sparse observations to effectively inform global state updates through the low-dimensional latent variables, achieving higher accuracy comparable to traditional physical-space DA while requiring significantly fewer observations, and inherently filtering high-frequency noise from the initial condition during the dimensionality reduction process. Collectively, these features establish LDA as a powerful and computationally efficient methodology for enhancing predictive accuracy and managing uncertainty in complex and high-dimensional groundwater systems.
由于模型结构的不确定性、参数的非均质性和初始条件的不确定性,地下水模型预测往往不准确,导致模拟过程中的误差积累。传统的数据同化(DA)在高维系统中由于需要大量的协方差矩阵进行反演而面临着严峻的计算挑战。此外,对背景和观测误差统计量的不准确估计会导致进一步的偏差。为了应对这些挑战,我们开发并评估了一个集成框架,该框架将计算效率高的深度学习替代模型与潜在数据同化(LDA)相结合,用于快速预测,以准确纠正模拟。该框架采用降维,特别是适当正交分解(POD),将高维物理状态投影到低维潜在空间中。然后使用集成卡尔曼滤波器(EnKF)在该简化空间中执行数据同化。结果表明,POD提供了模拟浓度场的鲁棒表示和插值观测的降维。EnKF在潜在空间中有效地降低了预测误差。LDA框架的主要优势包括:使稀疏观测能够通过低维潜在变量有效地通知全局状态更新;与传统的物理空间数据分析相比,在需要更少观测量的情况下实现更高的精度;在降维过程中固有地过滤初始条件中的高频噪声。总的来说,这些特征使LDA成为一种强大且计算效率高的方法,用于提高复杂和高维地下水系统的预测准确性和管理不确定性。
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引用次数: 0
Evaluating Evapotranspiration Simulation Performance in 30 Conceptual Hydrological Models: Insights Into ET Representation Across Diverse Climates 评估30个概念水文模型的蒸散发模拟性能:对不同气候条件下蒸散发表征的见解
IF 5.4 1区 地球科学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-03-09 DOI: 10.1029/2025wr040017
Shuyue Wu, Yuting Yang, Changming Li, Wenjing Yang, Jianshi Zhao
Existing comparative studies on conceptual hydrological model structures have generally focused on streamflow, with less attention to evapotranspiration (ET). Yet, appropriate ET representation in conceptual models is crucial for obtaining reliable hydrological simulations, especially under climate change and in ungauged basins. To address this gap, we investigated 30 conceptual models for their ET representations and ability to reproduce two state-of-the-art ET products (PML-V2 and FLUXCOM-X-BASE) across 507 CAMELS-US catchments with diverse climates and landscapes. FLUXNET ET from nearby sites was used for additional validation. The conceptual model ensemble outperformed a benchmark model that relies on PET and long-term water balance in most catchments. Models with different ET representations showed distinct ET simulation performance, highlighting the importance of selecting appropriate ET representations. The appropriate ET representations vary across climates. Linear and nonlinear ET–soil–moisture equations with a parameter governing the long-term ET-to-PET ratio are sufficient for accurately reproducing ET products in humid, summer-rainfall regions, where model equifinality in ET simulation is high. In arid catchments, considering the contribution of lower soil storage to ET generation was necessary to reproduce ET products, especially during rainless periods. In humid winter-rainfall-dominated catchments, explicit representation of interception evaporation constrained by interception capacity or storage was critical. Models that performed well in reproducing product-based ET also performed well when evaluated against FLUXNET ET, supporting the robustness of our findings. This study provides guidance on appropriately representing the conversion of PET and precipitation into ET across diverse climates, thereby helping to constrain model structural uncertainty.
现有的概念水文模型结构的比较研究一般集中在流量上,对蒸散发(ET)的关注较少。然而,概念模型中适当的蒸散发表示对于获得可靠的水文模拟至关重要,特别是在气候变化和未测量的流域中。为了解决这一差距,我们研究了30个概念模型的ET表示,并在507个不同气候和景观的CAMELS-US流域重现两种最先进的ET产品(PML-V2和FLUXCOM-X-BASE)的能力。使用附近站点的FLUXNET进行额外验证。概念模型集合优于大多数集水区依赖PET和长期水平衡的基准模型。不同ET表示的模型表现出不同的ET模拟性能,突出了选择合适的ET表示的重要性。适当的ET表示因气候而异。线性和非线性ET-土壤水分方程具有控制长期ET- pet比的参数,足以准确再现湿润的夏季降雨地区的ET产品,在这些地区,ET模拟的模式均衡性很高。在干旱流域,考虑下层土壤储存量对蒸散发产生的贡献是重现蒸散发产品的必要条件,特别是在无雨期。在潮湿的冬季降雨为主的集水区,明确表示受拦截能力或储存限制的拦截蒸发是至关重要的。在模拟基于产品的ET方面表现良好的模型在针对FLUXNET ET进行评估时也表现良好,这支持了我们研究结果的稳健性。该研究为如何在不同气候条件下恰当地表示PET和降水转化为ET提供了指导,从而有助于约束模型结构的不确定性。
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引用次数: 0
Deriving Long-Term Operating Rules for Cascade Hydropower Plants Compensating for Short-Term Uncertainties in Wind and Solar Power Generation 补偿风能和太阳能发电短期不确定性的梯级水电站长期运行规则的推导
IF 5.4 1区 地球科学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-03-09 DOI: 10.1029/2025wr042181
Mengke Lin, Jianjian Shen, Xianren Ai, Yuqian Wang
Hydropower offers both regulation and scale advantages that can respond to the substantial grid flexibility requirements arising from the integration of variable renewable energy (VRE). However, its short-term regulatory capability heavily depends on long-term operating rules, which largely overlook short-term grid flexibility needs. This study proposes a novel method for deriving operating rules of hydro-wind-solar complementary systems (HWPCS) that accounts for short-term flexible power allocation in different months. Typical historical hydropower output curves, along with peak capacity and peak duration, are initially used to quantify grid flexibility demands. Under grid demand constraints, a short-term simulation model is developed to generate feasible hydropower output intervals and peak-shaving electricity curves, which capture the responsiveness of long-term generation to short-term power fluctuations. Finally, a multi-objective optimization model is formulated to simultaneously maximize energy production and regulation capability, subject to hydropower output interval constraints, thereby deriving optimal long-term operating rules. A practical engineering cases demonstrate that: (a) The system's regulation capability is most effective when hydropower generation is maintained at around 50% of installed capacity, with a wind-dominant mix calling for even higher optimal output; (b) The overall regulation capability of the system improves by 30.2%, while the grid demand deficit drops by 12%. Wet-year conditions further amplify this advantage; and (c) Extending peak-shaving durations will reduce overall benefits, though the marginal impact decreases with peak duration. These findings highlight the potential of HWPCS to improve system flexibility and support large-scale VRE integration.
水电具有调节和规模优势,可以应对可变可再生能源(VRE)整合带来的大量电网灵活性要求。然而,其短期监管能力在很大程度上依赖于长期运行规则,这在很大程度上忽视了短期电网灵活性需求。本文提出了一种新的方法来推导考虑不同月份短期灵活电力分配的水电-风能-太阳能互补系统(HWPCS)运行规则。典型的历史水电输出曲线,连同峰值容量和峰值持续时间,最初用于量化电网灵活性需求。在电网需求约束下,建立短期仿真模型,生成可行的水电出力区间和调峰电力曲线,以捕捉长期发电对短期电力波动的响应性。最后,在水电出力区间约束下,建立了以发电量和调节能力同时最大化为目标的多目标优化模型,从而得出最优的长期运行规律。实际工程实例表明:(A)当水力发电保持在装机容量的50%左右时,系统的调节能力最有效,风力发电占主导地位,需要更高的最优输出;(2)系统整体调节能力提高30.2%,电网需求赤字下降12%。潮湿的年份进一步放大了这一优势;(c)延长调峰时间将减少总体效益,尽管边际影响随着调峰时间的延长而减少。这些发现突出了HWPCS在提高系统灵活性和支持大规模VRE集成方面的潜力。
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引用次数: 0
Model-Based Interpretation of Solute Exports and Carbon Partitioning During Shale Weathering in a Mountainous Hillslope 基于模型的山地山坡页岩风化过程中溶质输出和碳分配的解释
IF 5.4 1区 地球科学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-03-09 DOI: 10.1029/2025wr041597
Lucien Stolze, Dipankar Dwivedi, Carl Steefel, Sergi Molins, Wenming Dong, Curtis Beutler, Alexander Newman, Kenneth Williams
The weathering of sedimentary rocks in high-elevation catchments influences freshwater quality and the global carbon cycle. While individual biogeochemical mechanisms involved in this process are relatively well understood, quantifying their contributions to solute export and carbon fluxes under natural, transient conditions remains challenging. Here, we implement a numerical multidimensional and multiphase model to simulate coupled hydrological and biogeochemical processes in a shale-underlain, snow-dominated hillslope in the Rocky Mountains, Colorado. The model captures the dynamic interplay between soil respiration, mineral weathering, and climate-driven hydrological forcing, reproducing observed soil CO2 dynamics, groundwater chemistry, and subsurface flow. Our results reveal that seasonal snowmelt enhances carbonate weathering by promoting the infiltration of CO2-rich water to depth, while pyrite oxidation is primarily sensitive to low water saturation that facilitates O2 diffusion through the regolith. Topography modulates the spatial distribution of shale weathering, as steeper slopes enhance lateral drainage, favoring the delivery of reactants to greater depths. While shale weathering at our site acts as a transient carbon sink, with silicates and carbonates buffering acidity and promoting atmospheric CO2 consumption (1% of soil-derived CO2), the exported dissolved inorganic carbon is predominantly geogenic (∼73%). Consequently, when accounting for long-term marine carbonate precipitation. The current weathering regime represents a net source of carbon to the atmosphere. The oxidation of pyrite and petrogenic organic carbon together release approximately 0.9 mol·m−2·yr−1 of CO2. Our findings highlight the role of topography, hydroclimate, and the coupling between acid-base reactions in shaping the carbon balance and the solute exports in mountainous critical zones.
高海拔集水区沉积岩的风化作用影响淡水质量和全球碳循环。虽然对这一过程中涉及的各个生物地球化学机制了解得相对较好,但量化它们在自然瞬态条件下对溶质输出和碳通量的贡献仍然具有挑战性。在这里,我们实施了一个多维和多相的数值模型来模拟在科罗拉多州落基山脉的页岩下,积雪为主的山坡上的水文和生物地球化学耦合过程。该模型捕捉了土壤呼吸、矿物风化和气候驱动的水文强迫之间的动态相互作用,再现了观测到的土壤二氧化碳动态、地下水化学和地下流量。研究结果表明,季节性融雪通过促进富含co2的水向深部渗透来增强碳酸盐风化,而黄铁矿氧化主要对低水饱和度敏感,从而促进O2在风化层中的扩散。地形调节了页岩风化的空间分布,因为陡坡增强了侧向排水,有利于向更深的深度输送反应物。虽然我们基地的页岩风化作用是一个短暂的碳汇,硅酸盐和碳酸盐缓冲了酸度,促进了大气二氧化碳的消耗(占土壤来源二氧化碳的1%),但出口的溶解无机碳主要是地成因的(约73%)。因此,在考虑长期海相碳酸盐降水时。当前的风化机制是大气中碳的一个净来源。黄铁矿和岩质有机碳的氧化共同释放约0.9 mol·m−2·yr−1的CO2。我们的研究结果强调了地形、水文气候和酸碱反应之间的耦合在塑造山区关键地带的碳平衡和溶质出口中的作用。
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引用次数: 0
A Hybrid Data Assimilation Approach Integrating Kalman With Deep Learning-Based Updates for Nonlinear and Non-Gaussian Groundwater Systems 基于卡尔曼和深度学习的非线性非高斯地下水系统混合同化方法
IF 5.4 1区 地球科学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-03-08 DOI: 10.1029/2024wr039665
Lei Yao, Jiangjiang Zhang, Yuxin Ye, Chenglong Cao, Jianyun Zhang, Junliang Jin
In hydrological research, data assimilation (DA) is a powerful tool for integrating observational data with numerical models, significantly enhancing predictive accuracy. However, nonlinear groundwater systems often exhibit high-dimensional and non-Gaussian characteristics in observations, parameters, and state variables, posing substantial challenges for traditional DA methods such as Markov chain Monte Carlo and ensemble smoother based on the Kalman update (<span data-altimg="/cms/asset/5aa53644-a4ae-48c2-b0be-53d90ede5f84/wrcr70703-math-0001.png"></span><mjx-container ctxtmenu_counter="867" ctxtmenu_oldtabindex="1" jax="CHTML" role="application" sre-explorer- style="font-size: 103%; position: relative;" tabindex="0"><mjx-math aria-hidden="true" location="graphic/wrcr70703-math-0001.png"><mjx-semantics><mjx-mrow><mjx-msub data-semantic-children="0,4" data-semantic- data-semantic-role="unknown" data-semantic-speech="ES Subscript left parenthesis normal upper K right parenthesis" data-semantic-type="subscript"><mjx-mtext data-semantic-annotation="clearspeak:unit" data-semantic-font="normal" data-semantic- data-semantic-parent="5" data-semantic-role="unknown" data-semantic-type="text"><mjx-c></mjx-c><mjx-c></mjx-c></mjx-mtext><mjx-script style="vertical-align: -0.177em;"><mjx-mrow data-semantic-children="2" data-semantic-content="1,3" data-semantic- data-semantic-parent="5" data-semantic-role="leftright" data-semantic-type="fenced" size="s"><mjx-mo data-semantic- data-semantic-operator="fenced" data-semantic-parent="4" data-semantic-role="open" data-semantic-type="fence"><mjx-c></mjx-c></mjx-mo><mjx-mi data-semantic-annotation="clearspeak:simple" data-semantic-font="normal" data-semantic- data-semantic-parent="4" data-semantic-role="latinletter" data-semantic-type="identifier"><mjx-c></mjx-c></mjx-mi><mjx-mo data-semantic- data-semantic-operator="fenced" data-semantic-parent="4" data-semantic-role="close" data-semantic-type="fence"><mjx-c></mjx-c></mjx-mo></mjx-mrow></mjx-script></mjx-msub></mjx-mrow></mjx-semantics></mjx-math><mjx-assistive-mml display="inline" unselectable="on"><math altimg="urn:x-wiley:00431397:media:wrcr70703:wrcr70703-math-0001" display="inline" location="graphic/wrcr70703-math-0001.png" xmlns="http://www.w3.org/1998/Math/MathML"><semantics><mrow><msub data-semantic-="" data-semantic-children="0,4" data-semantic-role="unknown" data-semantic-speech="ES Subscript left parenthesis normal upper K right parenthesis" data-semantic-type="subscript"><mtext data-semantic-="" data-semantic-annotation="clearspeak:unit" data-semantic-font="normal" data-semantic-parent="5" data-semantic-role="unknown" data-semantic-type="text">ES</mtext><mrow data-semantic-="" data-semantic-children="2" data-semantic-content="1,3" data-semantic-parent="5" data-semantic-role="leftright" data-semantic-type="fenced"><mo data-semantic-="" data-semantic-operator="fenced" data-semantic-parent="4" data-semantic-role="open" data-semantic-type="fence">(</mo><mi da
在水文研究中,数据同化(data assimilation, DA)是将观测数据与数值模型相结合的有力工具,可以显著提高预测精度。然而,非线性地下水系统在观测值、参数和状态变量上往往表现出高维和非高斯特征,这对传统的数据分析方法(如马尔可夫链蒙特卡罗和基于卡尔曼更新(ES(K)${text{ES}}_{( maththrm {K})}$)的集成平滑)提出了实质性的挑战。为了解决这些挑战,我们之前引入了ES(DL)${text{ES}}_{(text{DL})}$,它用基于非线性深度学习(DL)的更新取代了线性卡尔曼更新,从而改进了对非高斯性问题的处理。尽管ES(DL)${text{ES}}_{(text{DL})}$有其优点,但受到DL模型训练的计算成本和集成统计的有限利用的限制。在本研究中,我们提出ES(K-DL)${text{ES}}_{( maththrm {K}mbox{-}text{DL})}$,这是一种混合数据处理方法,将卡尔曼与基于DL的更新相结合,以克服这些局限性。ES(K-DL)${text{ES}}_{( mathm {K}mbox{-}text{DL})}$将ES(K)${text{ES}}_{( mathm {K})}$的效率和统计优雅性与ES(DL)${text{ES}}_{(text{DL})}$的适应性相结合。为了评估ES(K-DL)${text{ES}}_{( maththrm {K}mbox{-}text{DL})}$,我们将其应用于一个具有挑战性的案例研究,该案例涉及八个污染源参数和3,321维非高斯分布的水力传导率场的联合反演。通过综合数值实验研究了影响性能的因素,包括基于dl的更新次数、Kalman和基于dl的更新顺序以及误差膨胀因子的配置。结果表明,混合更新策略在保持数据分析结果稳定性和可靠性的同时,降低了计算成本。最优的ES(K-DL)${text{ES}}_{( mathm {K}mbox{-}text{DL})}$变体与ES(K)${text{ES}}_{( mathm {K})}$和ES(DL)${text{ES}}_{(text{DL})}$相比,获得了更好的性能,突出了这种互补方法的好处。
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引用次数: 0
Longitudinal Mean Velocity and Turbulent Kinetic Energy Within an Emergent Canopy in Nonuniform Flows 非均匀流动中突发性冠层的纵向平均速度和湍流动能
IF 5.4 1区 地球科学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-03-07 DOI: 10.1029/2025wr040864
Yonggang Zhang, Ping Wang, Ke Xiang, Zheng Gong, Zi Wu
Vegetation-induced drag generates nonuniform water surface profiles through flow disruption, creating complex hydrodynamic conditions characterized by enhanced turbulence and energy dissipation. This study investigates the longitudinal velocity and turbulent kinetic energy (TKE) dynamics in emergent canopies under streamwise varying flow conditions. Laboratory flume experiments systematically examined four vegetation densities and two flow discharge scenarios. The results indicate that the time-mean longitudinal velocity and the TKE both enhance significantly downstream along the emergent canopy. Based on TKE budget, an analytical model to predict the longitudinal TKE evolution within the emergent canopy was developed. Compared to uniform flows in a vegetated channel, the flow nonuniformity gives rise to distinct terms including the streamwise-position dependent mean velocity <span data-altimg="/cms/asset/7ea5b557-8d66-4e3c-8f15-b0f778ddc564/wrcr70719-math-0001.png"></span><mjx-container ctxtmenu_counter="473" ctxtmenu_oldtabindex="1" jax="CHTML" role="application" sre-explorer- style="font-size: 103%; position: relative;" tabindex="0"><mjx-math aria-hidden="true" location="graphic/wrcr70719-math-0001.png"><mjx-semantics><mjx-mrow data-semantic-annotation="clearspeak:simple" data-semantic-children="0,4" data-semantic-content="5,0" data-semantic- data-semantic-role="simple function" data-semantic-speech="upper U left parenthesis x right parenthesis" data-semantic-type="appl"><mjx-mi data-semantic-annotation="clearspeak:simple" data-semantic-font="italic" data-semantic- data-semantic-operator="appl" data-semantic-parent="6" data-semantic-role="simple function" data-semantic-type="identifier"><mjx-c></mjx-c></mjx-mi><mjx-mo data-semantic-added="true" data-semantic- data-semantic-operator="appl" data-semantic-parent="6" data-semantic-role="application" data-semantic-type="punctuation" style="margin-left: 0.056em; margin-right: 0.056em;"><mjx-c></mjx-c></mjx-mo><mjx-mrow data-semantic-children="2" data-semantic-content="1,3" data-semantic- data-semantic-parent="6" data-semantic-role="leftright" data-semantic-type="fenced"><mjx-mo data-semantic- data-semantic-operator="fenced" data-semantic-parent="4" data-semantic-role="open" data-semantic-type="fence" style="margin-left: 0.056em; margin-right: 0.056em;"><mjx-c></mjx-c></mjx-mo><mjx-mi data-semantic-annotation="clearspeak:simple" data-semantic-font="italic" data-semantic- data-semantic-parent="4" data-semantic-role="latinletter" data-semantic-type="identifier"><mjx-c></mjx-c></mjx-mi><mjx-mo data-semantic- data-semantic-operator="fenced" data-semantic-parent="4" data-semantic-role="close" data-semantic-type="fence" style="margin-left: 0.056em; margin-right: 0.056em;"><mjx-c></mjx-c></mjx-mo></mjx-mrow></mjx-mrow></mjx-semantics></mjx-math><mjx-assistive-mml display="inline" unselectable="on"><math altimg="urn:x-wiley:00431397:media:wrcr70719:wrcr70719-math-0001" display="inline" location="graphic/wrcr
植被诱导的阻力通过水流破坏产生不均匀的水面轮廓,形成以湍流增强和能量耗散为特征的复杂水动力条件。本文研究了在顺流变流条件下突发性冠层的纵向速度和湍流动能(TKE)动力学。实验室水槽实验系统地考察了四种植被密度和两种流量排放情景。结果表明:沿顺流冠层下游,时间平均纵向速度和TKE均显著增强;基于TKE收支,建立了一个预测突发性冠层内TKE纵向演化的分析模型。与植物通道中的均匀流动相比,流动不均匀性产生了不同的项,包括与流向位置相关的平均速度U(x)$ U(x)$,水面梯度∂H/∂x$mathit{偏}H/mathit{偏}x$和弗罗德数Fr(x)。该模型显示纵向TKE与平均流速之间的有效幂律指数为2/3,而不是典型值2,这归因于水面梯度的剩余能量贡献。这些结果为预测植被泛滥平原水流的顺流湍流演化提供了一个机制框架,解决了生态水力模拟的一个关键空白。
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引用次数: 0
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Water Resources Research
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