Advances in Colloid and Interface Science最新文献

The global corrosion cost is estimated to be around 2.5 trillion USD, which is more than 3 % of the global GDP. Against this background, large efforts have been made to find effective corrosion inhibitors. Ionic liquids (ILs) are nowadays regarded as reliable functional materials and one of the most promising classes of anticorrosion agents. Not only are they efficient in preventing corrosion of iron and other metals, but they are also relatively inexpensive, need no solvents, and are non-toxic to humans This review addresses both experimental and theoretical investigations conducted to IL-based corrosion inhibitors (CIs). It covers various ILs used, synthesis methods, and their performance in diverse corrosive environments. Electrochemical techniques like EIS and potentiodynamic polarization, along with computational approaches including quantum chemical calculations and DFT, provide valuable insights into corrosion inhibition mechanisms and the interactions between anticorrosion agents-surfaces. The synergistic combination of experimental and theoretical approaches enhances our understanding of corrosion inhibition, enabling the design and optimization of effective and sustainable corrosion protection strategies. This review consolidates the existing knowledge on ionic liquid-based corrosion inhibitors, highlights the key findings from both experimental and theoretical investigations, and points out possible directions for further studies in this area.

Phenylboronic acid (PBA) is recognized as one of the most promising cancer cell binding modules attributed to its potential to form reversible and dynamic boronic ester covalent bonds. Exploring the advanced chemical versatility of PBA is crucial for developing new anticancer therapeutics. The presence of a specific Lewis acidic boron atom-based functional group and a Π-ring-connected ring has garnered increasing interest in the field of cancer immunotherapy. PBA-derivatized functional biomaterials can form reversible bonds with diols containing cell surface markers and proteins. This review primarily focuses on the following topics: (1) the importance and versatility of PBA, (2) different PBA derivatives with pKa values, (3) specific key features of PBA-mediated biomaterials, and (4) cell surface activity for cancer immunotherapy applications. Specific key features of PBA-mediated materials, including sensing, bioadhesion, and gelation, along with important synthesis strategies, are highlighted. The utilization of PBA-mediated biomaterials for cancer immunotherapy, especially the role of PBA-based nanoparticles and PBA-mediated cell-based therapeutics, is also discussed. Finally, a perspective on future research based on PBA-biomaterials for immunotherapy applications is presented.

In recent years, multidrug-resistant pathogenic microorganisms (MDROs) have emerged as a severe threat to human health, exhibiting robust resistance to traditional antibiotics. This has created a formidable challenge in modern medicine as we grapple with limited options to combat these resilient bacteria. Despite extensive efforts by scientists to develop new antibiotics targeting these pathogens, the quest for novel antibacterial molecules has become increasingly arduous. Fortunately, nature offers a potential solution in the form of cationic antimicrobial peptides (AMPs) and their synthetic counterparts. AMPs, naturally occurring peptides, have displayed promising efficacy in fighting bacterial infections by disrupting bacterial cell membranes, hindering their survival and reproduction. These peptides, along with their synthetic mimics, present an exciting alternative in combating antibiotic resistance. They hold the potential to emerge as a formidable tool against MDROs, offering hope for improved strategies to protect communities. Extensive research has explored the diversity, history, and structure-properties relationship of AMPs, investigating their amphiphilic nature for membrane disruption and mechanisms of action. However, despite their therapeutic promise, AMPs face several documented limitations. Among these challenges, poor pharmacokinetic properties stand out, impeding the attainment of therapeutic levels in the body. Additionally, some AMPs exhibit toxicity and susceptibility to protease cleavage, leading to a short half-life and reduced efficacy in animal models. These limitations pose obstacles in developing effective treatments based on AMPs. Furthermore, the high manufacturing costs associated with AMPs could significantly hinder their widespread use. In this review, we aim to present experimental and theoretical insights into different AMPs, focusing specifically on antibacterial peptides (ABPs). Our goal is to offer a concise overview of peptide-based drug candidates, drawing from a wide array of literature and peer-reviewed studies. We also explore recent advancements in AMP development and discuss the challenges researchers face in moving these molecules towards clinical trials. Our main objective is to offer a comprehensive overview of current AMP and ABP research to guide the development of more precise and effective therapies for bacterial infections.

The present disrupted scenario of the world calls for urgent attention to the need for renewable resources as an energy source for harnessing and feeding uninterrupted power supply to mankind. Amidst this, Photocatalysis (PC) and Photoelectrocatalysis (PEC) are some of the most budding methods of exploiting solar energy. LaFeO₃-based systems are eligible for PC/PEC Hydrogen (H₂) generation, incorporating the process of water splitting, etc. It would be fair to mention that the above methods can mimic the natural process of photosynthesis. This review comprises an encyclopedia of recent advancements in LaFeO₃ and modified systems towards sustainable Photocatalytic and Photoelectrocatalytic Hydrogen Evolution Reactions (HER). Besides the challenges, the review presents a clear and brief idea for the scientific research community on paving the future in upscaling and industrializing the LaFeO₃-mediated green fuel (H2) generation to meet global energy needs.

This review paper focuses on group IVB transition metal nitrides (TMNs) such as titanium nitride (TiN), zirconium nitride (ZrN), and hafnium nitride (HfN) and as alternative plasmonic materials to noble metals like gold and silver. It delves into the fabrication methods of these TMNs, particularly emphasizing thin film fabrication techniques like magnetron sputtering and atomic layer deposition, as well as nanostructure fabrication processes applied to these thin films. Overcoming the current fabrication and application-related challenges requires a deep understanding of the material properties, deposition techniques, and application requirements. Here, we discuss the impact of fabrication parameters on the properties of resulting films, highlighting the importance of aligning fabrication methods with practical application requirements for optimal performance. Additionally, we summarize and tabulate the most recent plasmonic applications of these TMNs in fields like biosensing, photovoltaic energy, and photocatalysis, contributing significantly to the current literature by consolidating knowledge on TMNs.

The mechanisms of non-Newtonian behaviour of suspensions and emulsions in steady shear flow are reviewed. The review is divided into two parts. In the first part, the mechanisms of non-Newtonian behaviour in suspensions and emulsions composed of Newtonian matrix are reviewed. Both dilute and concentrated systems are discussed. In the second part, the mechanisms of non-Newtonian behaviour in suspensions and emulsions composed of non-Newtonian matrix are reviewed. Where appropriate, mathematical models describing the rheology are included.

Microalgae are microorganisms that are rich in bioactive compounds, including pigments, proteins, lipids, and polysaccharides. These compounds can be utilized for a number of biomedical purposes, including drug delivery, wound healing, and tissue engineering. Nevertheless, encapsulating microalgae cells and microalgae bioactive metabolites is vital to protect them and prevent premature degradation. This also enables the development of intelligent controlled release strategies for the bioactive compounds. This review outlines the most employed encapsulation techniques for microalgae, with a particular focus on their biomedical applications. These include ionic gelation, oil-in-water emulsions, and spray drying. Such techniques have been widely explored, due to their ability to protect sensitive compounds from degradation, enhance their stability, extend their shelf life, mask undesirable tastes or odours, control the release of bioactive compounds, and enable targeted delivery to specific sites within the body or environment. Moreover, a patent landscape analysis is also provided, allowing an overview of the microalgae encapsulation technology development applied to a variety of fields, including pharmaceuticals, cosmetics, food, and agriculture.

Nanoparticles improve traditional Enhanced Oil Recovery (EOR) methods but face instability issues. Surface modification resolves these, making it vital to understand its impact on EOR effectiveness. This paper examines how surface-modified nanoparticles can increase oil recovery rates. We discuss post-synthesis modifications like chemical functionalization, surfactant and polymer coatings, surface etching, and oxidation, and during-synthesis modifications like core-shell formation, in-situ ligand exchange, and surface passivation. Oil displacement studies show surface-engineered nanoparticles outperform conventional EOR methods. Coatings or functionalizations alter nanoparticle size by 1–5 nm, ensuring colloidal stability for 7 to 30 days at 25 to 65 °C and 30,000 to 150,000 ppm NaCl. This stability ensures uniform distribution and enhanced penetration through low-permeability (1–10 md) rocks, improving oil recovery by 5 to 50 %. Enhanced recovery is achieved through 1–25 μm oil-in-water emulsions, increased viscosity by ≥30 %, wettability changes from 170° to <10°, and interfacial tension reductions of up to 95 %. Surface oxidation is suitable for carbon-based nanoparticles in high-permeability (≥500 md) reservoirs, leading to 80 % oil recovery in micromodel studies. Surface etching is efficient for all nanoparticle types, and combining it with chemical functionalization enhances resistance to harsh conditions (≥40,000 ppm salinity and ≥ 50 °C). Modifying nanoparticle surfaces with a silane coupling agent before using polymers and surfactants improves EOR parameters and reduces polymer thermal degradation (e.g., only 10 % viscosity decrease after 90 days). Economically, 500 ppm of nanoparticles requires 56.25 kg in a 112,500 m³ reservoir, averaging $200/kg, and 2000 ppm of surface modifiers require 4 kg at $3.39/kg. This results in 188,694.30 barrels, or $16,039,015.50 at $85 per barrel for a 20 % increase in oil recovery. The economic benefits justify the initial costs, highlighting the importance of cost-effective nanoparticles for EOR applications.

The wettability of subsurface minerals is a critical factor influencing the pore-scale displacement of fluids in underground reservoirs. As such, it plays a key role in hydrocarbon production and greenhouse gas geo-sequestration. We present a comprehensive and critical review of the current state of knowledge on the intermolecular forces governing wettability of rock minerals most relevant to subsurface fluid storage and recovery. In this review we first provide a detailed summary of the available data, both experimental and theoretical, from the perspective of the fundamental intermolecular and surface forces, specifically considering the roles played by the surface chemistry, fluid properties, as well as other significant factors. We subsequently offer an analysis of the effects of chemical additives such as surfactants and nanoparticles that have emerged as viable means for manipulating wettability. In each example, we highlight the practical implications for hydrocarbon production and CO₂ geo-storage as two of the most important current applications. As the physico-chemical mechanisms governing the wetting phenomena are the main focus, special emphasis is placed on nano-scale experimental approaches along with atomic-scale modeling that specifically probe the underlying intermolecular and surface forces. Lastly, we discuss the gaps in the current state of knowledge and outline future research directions to further our fundamental understanding of the interactions and their impact on the wetting characteristics of Earth's minerals.