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Electrospun nanofibers for the adsorption and separation of pollutants from wastewater: New opportunities and recent advances 静电纺纳米纤维对废水中污染物的吸附和分离:新机遇和最新进展。
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2025-12-10 DOI: 10.1016/j.cis.2025.103749
Maryam Majlesi , Elham Assadpour , Milad Tavassoli , Seid Mahdi Jafari
Due to the high concentration of various toxic and hazardous pollutants, industrial wastewaters have posed increasing threats. Water reclamation has recently received attention by using one-dimensional nanostructured materials such as electrospun nanofibrous membranes (ENMs). ENMs exhibit numerous advantageous properties, including a high surface area, substantial porosity, robust mechanical strength, and the ability to control surface morpHology. ENMs are promising candidates for efficient and environmentally sustainable water purification solutions. This review examines the recent advances in the use of ENMs for the treatment of contaminated water, in which the types of nanofibers that can be used to remove pollutants present in industrial wastewater (WW) are separately described. We aim to provide a comprehensive understanding of the topic and encourage stakeholders and researchers to use ENMs in industrial WW treatment, which will help create a reliable water source for future generations.
由于工业废水中各种有毒有害污染物的高浓度,对环境的威胁越来越大。利用电纺纳米纤维膜等一维纳米结构材料进行水回收是近年来研究的热点。enm具有许多优点,包括高表面积、高孔隙率、强大的机械强度和控制表面形貌的能力。enm是高效和环境可持续的水净化解决方案的有希望的候选者。本文综述了纳米纤维用于污水处理的最新进展,其中分别描述了可用于去除工业废水中污染物的纳米纤维的类型。我们的目标是提供对该主题的全面理解,并鼓励利益相关者和研究人员在工业废水处理中使用enm,这将有助于为子孙后代创造可靠的水源。
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引用次数: 0
Phenolic acid-functionalized and loaded electrospun nanofibers: Innovations in active and multifunctional food packaging 酚酸功能化和负载电纺纳米纤维:活性和多功能食品包装的创新。
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2025-12-10 DOI: 10.1016/j.cis.2025.103747
Guoyuan Xiong , Wanli Zhang , Ajahar Khan , Zohreh Riahi , P. Ananthi , Guanghua Xia , Seid Mahdi Jafari
The growing demand for sustainable food packaging has driven innovation in electrospun nanofibers integrated with bioactive phenolic acids. This review highlights the pivotal role of phenolic acids—such as tannic acid, gallic acid, and tea polyphenols—in enhancing the functionality of biodegradable polymer matrices (e.g., PLA, PVA, chitosan) made from electrospun nanofibers. These compounds improve mechanical strength, thermal stability, and barrier properties through hydrogen bonding and covalent interactions, while their antioxidant and antimicrobial activities effectively combat oxidative spoilage and microbial contamination. Case studies demonstrate their efficacy in extending the shelf life of perishable foods, including fruits, meats, and seafood. Controlled release mechanisms, achieved via advanced electrospinning techniques like coaxial or multilayer architectures, ensure sustained bioactivity. Challenges in optimizing release kinetics and scaling production are discussed. By bridging material innovation with practical food preservation needs, phenolic acid-functionalized nanofibers emerge as a versatile, eco-friendly solution for next-generation active packaging systems.
对可持续食品包装日益增长的需求推动了与生物活性酚酸集成的电纺纳米纤维的创新。本文综述了酚酸(如单宁酸、没食子酸和茶多酚)在提高静电纺纳米纤维制备的可生物降解聚合物基体(如聚乳酸、聚乙烯醇、壳聚糖)的功能方面的关键作用。这些化合物通过氢键和共价相互作用提高机械强度、热稳定性和屏障性能,同时它们的抗氧化和抗菌活性有效地对抗氧化变质和微生物污染。案例研究证明了它们在延长易腐食品(包括水果、肉类和海鲜)的保质期方面的功效。控制释放机制,通过先进的静电纺丝技术,如同轴或多层结构实现,确保持续的生物活性。讨论了优化释放动力学和结垢生产的挑战。通过将材料创新与实际食品保存需求相结合,酚醛酸功能化纳米纤维成为下一代活性包装系统的多功能、环保解决方案。
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引用次数: 0
Flotation separation in lithium-ion battery recycling: Challenges and recent advances 锂离子电池回收中的浮选分离:挑战和最新进展。
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2025-12-10 DOI: 10.1016/j.cis.2025.103753
Qing Sun , Kai Zeng , Jingsi Chen , Hongjian Zhang , Hongbo Zeng
The rapid growth of electric vehicles, portable electronic devices, and stationary energy storage systems, coupled with the limited lifespan of lithium-ion batteries (LIBs), has led to a substantial increase in spent LIBs. In response to the urgent demand for resource recovery and environmental protection, the recycling of spent LIBs, particularly the separation of anode and cathode materials, which are the two most significant components, has become a critical area of research. Froth flotation offers a promising method by selectively separating particles based on differences in surface hydrophobicity, without altering the structure or chemical composition of the materials involved. The intrinsic hydrophobicity differences between anode and cathode materials (e.g., graphite and lithium metal oxides) make flotation an attractive technique for the recycling of spent LIBs. Hence, this review first outlines the fundamental principles of froth flotation, with particular emphasis on the roles of flotation agents—collectors, frothers, and dispersants—in modifying the surface hydrophobicity of various electrode materials. The interplay between flotation agents and the separation efficiency of anode and cathode components is examined in depth. However, several factors, such as the presence of organic binders and additives, residual lithium in the discharged anode, and surface degradation of electrode materials, may impede effective separation. Accordingly, this review further explores a range of pretreatment strategies designed to restore electrode surface properties and enhance flotation performance. This paper provides a comprehensive perspective of flotation-based separation in spent LIBs recycling, offering valuable insights and practical implications for advancing large-scale, efficient, and sustainable recovery technologies.
电动汽车、便携式电子设备和固定式储能系统的快速增长,加上锂离子电池(LIBs)的有限寿命,导致了废锂电池的大幅增加。为了响应资源回收和环境保护的迫切需求,废旧锂电池的回收利用,特别是作为锂电池最重要的两个组成部分——阳极和阴极材料的分离已成为一个重要的研究领域。泡沫浮选提供了一种很有前途的方法,它可以根据表面疏水性的差异选择性地分离颗粒,而不会改变所涉及材料的结构或化学成分。阳极和阴极材料(如石墨和锂金属氧化物)之间固有的疏水性差异使浮选成为回收废锂的一种有吸引力的技术。因此,本文首先概述了泡沫浮选的基本原理,特别强调了浮选剂——捕收剂、起泡剂和分散剂——在改变各种电极材料表面疏水性方面的作用。深入研究了浮选剂对阳极、阴极组分分离效率的影响。然而,一些因素,如有机粘合剂和添加剂的存在,放电阳极中残留的锂,以及电极材料的表面降解,可能会阻碍有效分离。因此,本文进一步探讨了一系列旨在恢复电极表面性能和提高浮选性能的预处理策略。本文提供了废lib回收中基于浮选分离的全面视角,为推进大规模,高效和可持续的回收技术提供了有价值的见解和实际意义。
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引用次数: 0
Obituary for Stanislav Samuilovich Dukhin Stanislav Samuilovich Dukhin的讣告。
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2025-12-10 DOI: 10.1016/j.cis.2025.103750
N.O. Mishchuk , V.I. Kovalchuk , E.K. Zholkovskiy , R. Miller
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引用次数: 0
A comprehensive review on droplet impact dynamics on liquid surfaces: Experimental and numerical investigations of momentum, mass, and heat transfer 液滴在液体表面上的碰撞动力学综述:动量、质量和传热的实验和数值研究。
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2025-12-09 DOI: 10.1016/j.cis.2025.103751
Shahin Faghiri, Parham Poureslami, Mikaeel Minaei, Shahin Akbari, Mohammadreza Asadi, Javad Ranjbar Kermani, Mohamad Ali Bijarchi, Mohammad Behshad Shafii
Studies on the impact of liquid drops, particularly over the last twenty years, have attracted the researchers’ attention due to the demand for improved predictive accuracy across various industries. This paper provides a review of existing research on mass and momentum interactions, as well as phase changes, that occur when drops impact a liquid surface. Initially, the classification of impact liquids and the non-dimensional numbers utilized in drop impact are introduced. Subsequently, the experimental, numerical, and theoretical methods employed in past research are discussed. These findings are obtained by careful analysis of drop collision phenomena. This analysis includes the formation of the crown sheet, jet, and various splash types that occur during high-velocity impacts. Each of these phenomena is examined regarding the fundamental physical mechanisms involved, as well as the relevant predictive correlations and models. Based on the liquid depth in which the droplet impacts, the studies are categorized into thin film, liquid film, shallow pool, and deep pool, and this study covers all four types. Although considerable efforts have been made in the past to comprehend and characterize these phenomena, there remains a substantial gap in past research, particularly concerning multiple drop impacts and phase changes during impingement on liquid surfaces. Therefore, this article provides an in-depth review of experimental, numerical, and theoretical models of drop impact on liquid surfaces, which includes a comprehensive understanding of their underlying physics in all these phenomena.
由于各行业对提高预测准确性的需求,对液滴影响的研究,特别是在过去的二十年中,引起了研究人员的注意。本文对液滴撞击液体表面时发生的质量和动量相互作用以及相变的现有研究进行了综述。首先,介绍了冲击液体的分类和液滴冲击中使用的无量纲数。随后,讨论了以往研究中采用的实验、数值和理论方法。这些发现是通过对跌落碰撞现象的仔细分析得出的。这一分析包括了冠层的形成,射流,以及高速撞击过程中产生的各种飞溅类型。这些现象中的每一种都是根据所涉及的基本物理机制以及相关的预测相关性和模型进行检查的。根据液滴撞击的液体深度,将研究分为薄膜型、液膜型、浅池型和深池型,本研究涵盖了这四种类型。尽管过去已经做出了相当大的努力来理解和表征这些现象,但过去的研究仍然存在很大的差距,特别是关于多次液滴撞击和撞击液体表面时的相位变化。因此,本文对液滴撞击液体表面的实验、数值和理论模型进行了深入的综述,其中包括对所有这些现象的潜在物理学的全面理解。
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引用次数: 0
Non-homogeneous complex fluids for conformance control and displacement: A transformative enhanced oil recovery technology 用于稠度控制和驱替的非均质复杂流体:一种变革性的提高采收率技术。
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2025-12-08 DOI: 10.1016/j.cis.2025.103748
Weiyao Zhu , Yubao Gao , Qipeng Ma , Wengang Bu , Fuyong Wang , Ming Yue
The efficient exploitation of low-permeability tight reservoirs is essential to mitigating the global energy crisis. However, the development of such resources remains technically challenging owing to low fluid mobility, pronounced heterogeneity, and the limited effectiveness of conventional chemical flooding techniques. This review introduces the concept of nano−/micro-engineered non-homogeneous complex fluids (NHCFs)—tailored fluid systems designed to modulate interfacial behavior in porous media—as a transformative approach for Quaternary reservoir recovery. By integrating insights from colloid science, interfacial thermodynamics, and multiscale transport phenomena, we elucidate the underlying mechanisms of NHCFs, including wettability alteration, targeted interfacial regulation, and capillary–permeability coupling. This work synthesizes recent advances in experimental, mechanistic, and theoretical studies of NHCFs for enhanced oil recovery (EOR), establishing critical links between pore-scale interfacial processes and reservoir-scale flow dynamics. Furthermore, we propose redefining Quaternary recovery as a form of precision interfacial engineering aimed at mobilizing trapped oil in low-flow regions. Finally, the review addresses emerging directions in advanced interfacial control, intelligent multiscale regulation of NHCFs, superfluid-like flow enhancement, and unified seepage simulation frameworks, outlining a pathway for the development of next-generation EOR technologies.
低渗透致密储层的高效开发是缓解全球能源危机的关键。然而,由于流体流动性低、非均质性明显以及常规化学驱技术的有效性有限,此类资源的开发在技术上仍然具有挑战性。本文介绍了纳米/微工程非均质复杂流体(NHCFs)的概念,这是一种定制的流体系统,旨在调节多孔介质中的界面行为,是第四系油藏开采的一种变革性方法。通过整合胶体科学、界面热力学和多尺度输运现象的见解,我们阐明了nhcf的潜在机制,包括润湿性改变、靶向界面调节和毛细血管-渗透率耦合。本研究综合了NHCFs用于提高采收率(EOR)的实验、机理和理论研究的最新进展,建立了孔隙尺度界面过程和油藏尺度流动动力学之间的关键联系。此外,我们建议将第四系采油重新定义为一种旨在动员低流区困油的精密界面工程。最后,综述了先进界面控制、nhcf智能多尺度调节、类超流体增强和统一渗流模拟框架等新兴方向,概述了下一代EOR技术的发展路径。
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引用次数: 0
Mineral precipitation in porous media systems: Controlling factors and impacts on porous media evolution 多孔介质系统中的矿物沉淀:控制因素及对多孔介质演化的影响
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2025-12-08 DOI: 10.1016/j.cis.2025.103745
Hang Deng , Jenna Poonoosamy
Mineral precipitation in porous media is an important process that controls the evolution of physical-chemical properties of many natural and engineered systems. This review aims to provide an overview of the status quo understandings of this process and a perspective on future research needs. We reviewed the fundamentals of the thermodynamic and kinetic theories of nucleation and crystal growth, and the key factors (e.g., substrate properties and pore sizes) that control mineral precipitation in porous media. In particular, we focused on how local reactive transport conditions dictate the extent and spatial distribution of mineral precipitates in flowing supersaturated solutions, mixing dominated systems, and coupled mineral dissolution and precipitation systems. Moreover, the review summarizes constitutive relations that have been used to model precipitation-driven alteration in bulk properties such as permeability, diffusivity and mineral reactivity, as well as their applicability and limitations. While there have been exciting developments in experimental and modeling efforts in improved understanding, some outstanding research questions require dedicated future investigations. They include more rigorous descriptions of emerging precipitation phenomena such as oscillatory zoning during the precipitation of solid solutions, considerations of the coupling between geochemical and geomechanical processes with precipitation induced cracking being a worthy example, and the upscaling of fine scale process and properties (e.g., confinement, multiphase flow dynamics) in to macroscopic predictive models. Overall, this review highlights the importance, advances and challenges of improved understanding of mineral precipitation in fractured porous media.
多孔介质中的矿物沉淀是控制许多自然和工程系统的物理化学性质演变的重要过程。本文旨在对这一过程的现状进行概述,并对未来的研究需求进行展望。我们回顾了成核和晶体生长的热力学和动力学理论的基本原理,以及控制多孔介质中矿物沉淀的关键因素(如基质性质和孔径)。我们特别关注了局部反应输运条件如何决定流动过饱和溶液中矿物沉淀的程度和空间分布,混合主导系统,以及耦合矿物溶解和沉淀系统。此外,本文还总结了用于模拟渗透率、扩散率和矿物反应性等土体性质变化的本构关系,以及它们的适用性和局限性。虽然在提高理解的实验和建模努力方面取得了令人兴奋的进展,但一些突出的研究问题需要专门的未来调查。它们包括对新出现的降水现象的更严格的描述,如固溶体降水过程中的振荡分区,考虑地球化学和地质力学过程之间的耦合,其中降水引起的裂缝是一个有价值的例子,以及将精细尺度的过程和性质(例如,约束,多相流动力学)升级为宏观预测模型。总的来说,这篇综述强调了提高对裂隙多孔介质中矿物沉淀的理解的重要性、进展和挑战。
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引用次数: 0
Capsule-based chemical delivery for enhanced oil recovery 以胶囊为基础的化学输送,提高石油采收率。
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2025-12-08 DOI: 10.1016/j.cis.2025.103743
Wenzhu Xia , Xi Lu , Chong Guo , Pinxian Li , Faxue Zhang , Weiyi Wang , Boyao Wen , Zhengyuan Luo , Bofeng Bai
Chemical flooding is an effective enhanced oil recovery (EOR) method, particularly in oil-wet, low-permeability, and high-viscosity conditions. However, its application is limited by high costs and environmental risks due to chemical losses. As an innovative technology, capsule-based chemical delivery enables targeted chemical release in residual oil-rich areas to significantly reduce the chemical losses. Currently, this technology remains in its early development stages with key challenges, including maintaining capsule stability in high-temperature, high-salinity environments, ensuring long-distance delivery with minimal loss in porous media, and controlling release rates in complex reservoirs. However, advances of capsules in fields like biomedicine and food processing can offer valuable insights. This review refines progress from these areas to address these challenges. It first summarizes strategies for capsule material selection, structural design, and preparation techniques, focusing on their applicability for oil displacement. The impacts of reservoir environments on capsule movement, rupture, adhesion, and blockage are also analyzed, along with approaches to minimize losses and enhance targeting. Triggering mechanisms of capsule release in oilfield environments, transmembrane pathways of chemicals, and description methods for regulating release dynamics are further discussed. Finally, strategies and perspectives for capsule-based chemical EOR are presented. This article provides guidance and broader insights for the applications of capsule in oilfield and other specialized environments.
化学驱是一种有效的提高采收率(EOR)的方法,特别是在油湿、低渗透和高粘度条件下。然而,它的应用受到高成本和化学损失带来的环境风险的限制。作为一项创新技术,以胶囊为基础的化学物质释放可以在富含剩余油的区域有针对性地释放化学物质,从而显著减少化学物质的损失。目前,该技术仍处于早期开发阶段,面临的主要挑战包括在高温、高盐度环境下保持胶囊的稳定性,确保在多孔介质中以最小的损失长距离输送,以及控制复杂油藏的释放速度。然而,胶囊在生物医学和食品加工等领域的进步可以提供有价值的见解。本次审查将对这些领域的进展进行细化,以应对这些挑战。首先总结了胶囊材料选择、结构设计和制备技术的策略,重点介绍了它们在驱油方面的适用性。还分析了储层环境对胶囊运动、破裂、粘连和堵塞的影响,以及减少损失和增强靶向性的方法。进一步讨论了油田环境中胶囊释放的触发机制、化学物质的跨膜途径以及调节释放动力学的描述方法。最后,提出了基于胶囊的化学提高采收率的策略和前景。本文为胶囊在油田和其他特殊环境中的应用提供了指导和更广泛的见解。
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引用次数: 0
Mechanisms and applications of reducing microbubble size via oscillatory gas supply: A comprehensive review 通过振荡供气减小微泡尺寸的机理和应用:综述。
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2025-12-07 DOI: 10.1016/j.cis.2025.103746
Zhen Chen , Jia’ao Yu , Wenhao Gao , Jiangshan Xi , Wei Fan , Himiyage Chaminda Hemaka Bandulasena , Mingxin Huo
Oscillatory gas supply (OGS) has emerged as an effective method to enhance gas-liquid mass transfer in industrial applications by minimizing bubble size at submerged orifices. Compared to traditional steady gas supply (SGS), OGS facilitates premature bubble detachment from microporous diffusers, thereby reducing coalescence and enhancing transport phenomena. This improvement leads to lower energy consumption across sectors such as environmental engineering and chemical processing. This review critically examines the feasibility and applications of OGS in multiphase flow systems, including wastewater treatment, flotation separation, algae cultivation, and gas stripping. We first elucidate the mechanisms that contribute to bubble size reduction via OGS, followed by a comparative assessment of three technologies for generating oscillating airflow: solenoid valve, loudspeaker, and fluidic oscillator. Key factors influencing OGS performance, particularly oscillation frequency and amplitude, are discussed for their momentous role in producing smaller bubbles. Our findings demonstrate that OGS-generated microbubbles not only boost reaction efficiency and lower energy consumption but also reduce chemical usage and the footprint of treatment facilities. We conclude with insights and potential directions for advancing OGS technology, emphasizing that while enhancing gas-liquid mass transfer through OGS presents a promising approach, the development of stable oscillation-generating equipment is crucial for optimizing process performance.
在工业应用中,振荡供气(OGS)是一种有效的提高气液传质的方法,它可以最小化淹没孔处的气泡大小。与传统的稳定供气(SGS)相比,OGS有助于气泡从微孔扩压器中过早脱离,从而减少聚结并增强输运现象。这一改进降低了环境工程和化学加工等部门的能耗。本文综述了OGS在多相流系统中的可行性和应用,包括废水处理、浮选分离、藻类培养和气提。我们首先阐明了通过OGS减少气泡尺寸的机制,然后对产生振荡气流的三种技术进行了比较评估:电磁阀、扬声器和流体振荡器。讨论了影响OGS性能的关键因素,特别是振荡频率和振幅对产生小气泡的重要作用。我们的研究结果表明,ogs产生的微泡不仅提高了反应效率,降低了能耗,还减少了化学品的使用和处理设施的足迹。最后,我们总结了OGS技术发展的见解和潜在方向,强调虽然通过OGS提高气液传质是一种很有前途的方法,但稳定振荡产生设备的开发对于优化工艺性能至关重要。
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引用次数: 0
Receptor-targeted metal-organic frameworks: Recent progress in synthesis, modifications, and applications in targeted drug delivery 受体靶向金属有机框架:合成、修饰和靶向给药应用的最新进展。
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2025-12-06 DOI: 10.1016/j.cis.2025.103744
Hossein Poursadegh , Siamak Javanbakht , Jeremiah J. Gassensmith , Shengqian Ma , Seyed Mohammad Davachi
Metal-organic frameworks (MOFs) have emerged as pivotal materials in contemporary scientific research, offering vast potential for the development of portable and sophisticated systems. This has opened new avenues for exploration across various fields and enabled a broad spectrum of novel applications. Over the past decade, MOFs have rapidly evolved in drug delivery systems (DDS), showcasing significant advancements in the creation of novel targeted platforms. Notably, receptor-targeted MOFs have introduced innovative architectures with adaptable features, particularly in biologically relevant scaffolds, thereby suggesting alternatives for cancer therapy. This review delves into recent developments in receptor-targeted MOFs, focusing on their synthesis, chemical modification, and applications in targeted anticancer drug delivery, highlighting their potential to drive future innovations in biomedical fields.
金属有机框架(mof)已成为当代科学研究中的关键材料,为便携式和复杂系统的发展提供了巨大的潜力。这为各个领域的探索开辟了新的途径,并实现了广泛的新应用。在过去的十年中,mof在给药系统(DDS)中迅速发展,在创建新的靶向平台方面取得了重大进展。值得注意的是,受体靶向mof引入了具有适应性特征的创新结构,特别是在生物相关支架中,从而为癌症治疗提供了替代方案。本文综述了受体靶向mof的最新进展,重点介绍了它们的合成、化学修饰和在靶向抗癌药物传递中的应用,强调了它们在生物医学领域推动未来创新的潜力。
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引用次数: 0
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Advances in Colloid and Interface Science
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