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Advanced tools and methodologies for identification, characterization, and quantification of micro/nano plastics in environmental matrices 先进的工具和方法鉴定,表征,和定量的微/纳米塑料在环境基质
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2025-11-11 DOI: 10.1016/j.cis.2025.103716
Bunty Sharma , Srishti Mangla , Shikha Aery , Chahat Sharma , Ajeet Kaushik , Sandeep Kumar , Ganga Ram Chaudhary
Although plastics were a ground-breaking invention that transformed modern life, their widespread mismanagement and accumulation have led to pervasive pollution, with microplastics (MPs) and nanoplastics (NPs) now posing risks to ecosystems and human health. This reality is drawing urgent research attention toward their isolation, identification, and quantification in the environment, which is not well-established yet. Therefore, to cover this gap, this review article provides a comprehensive overview of various separation methods, including density separation, oil separation, electrostatic separation, magnetic separation, elutriation, membrane filtration, enzymatic treatments, and sieving. These methods are useful for separating MPs from their surrounding environment. Furthermore, the present work discusses the recent methodologies/techniques employed for the identification and characterization of MPs/NPs in environment, including Fourier-transform infrared spectroscopy (FTIR), Raman spectroscopy, scanning electron microscopy (SEM), laser direct infrared (LDIR), pressurized fluid extraction (PFE), thermal analysis, electrochemical sensing, optical sensing, chromatographic techniques, and visual inspection. These techniques are effective in detecting MPs and are widely used to analyse their polymer composition, size, morphology, and shape. This review further outlines recent developments in MPs/NPs identification & quantification methods, major challenges, toxicological mechanism, regulation framework and also, compare their detection limit, cost, accessibility advantages and addresses the limitations associated with various available analytical tools. Overall, this review offers an overview of the various methods for separating, identifying, and quantifying MPs, and underscores the need for continuous innovation required for the advancements and addressing the challenges in the field.
尽管塑料是一项改变现代生活的突破性发明,但它们的广泛管理不善和积累导致了无处不在的污染,微塑料(MPs)和纳米塑料(NPs)现在对生态系统和人类健康构成了威胁。这一现实迫切需要对其在环境中的分离、鉴定和量化进行研究,但这方面的研究尚未完善。因此,为了弥补这一空白,本文综述了各种分离方法,包括密度分离、油分离、静电分离、磁分离、洗脱、膜过滤、酶处理和筛分。这些方法有助于将MPs与其周围环境分离。此外,本工作还讨论了环境中MPs/NPs鉴定和表征的最新方法/技术,包括傅里叶变换红外光谱(FTIR)、拉曼光谱、扫描电子显微镜(SEM)、激光直接红外(LDIR)、加压流体萃取(PFE)、热分析、电化学传感、光学传感、色谱技术和目视检测。这些技术在检测MPs方面是有效的,并广泛用于分析它们的聚合物组成、大小、形态和形状。本文进一步概述了MPs/NPs鉴定和定量方法的最新进展,主要挑战,毒理学机制,监管框架,并比较了它们的检出限,成本,可及性优势,并解决了与各种可用分析工具相关的局限性。总体而言,本文概述了分离、识别和量化MPs的各种方法,并强调了该领域进步和应对挑战所需的持续创新的必要性。
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引用次数: 0
In-situ carbon mineralization through injection of CO2-saturated water into basalts: Effects on pore network 玄武岩注入饱和co2水原位碳矿化:对孔隙网络的影响
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2025-11-11 DOI: 10.1016/j.cis.2025.103710
Seyi Philemon Akanji , Lionel Esteban , Ausama Giwelli , Joel Sarout , Alireza Keshavarz , Stefan Iglauer
Carbon capture and storage (CCS) offers the potential to remove and safely store significant quantities of carbon dioxide from the atmosphere, thereby limiting global warming. Conventional geological storage involves injecting CO2, in gaseous or supercritical state, into porous rock reservoirs, relying on geological top seals, capillary forces and/or dissolution in groundwater as the primary “locking-in” processes. An alternative method injects CO2-saturated water into mafic rocks (basalts), chemically inducing in-situ mineralization of CO2 to form solid carbonate minerals. This mechanism offers the lowest risk of carbon returning to the atmosphere. This review synthesizes field and laboratory studies on CO2 mineralization in basaltic rocks and the resulting impact on the rock’s pore network, permeability and porosity. Evidence indicates that dissolution-precipitation reactions substantially alter basalt microstructure, with outcomes strongly influenced by (i) sufficient fluid residence time within the pore space, (ii) adequate reactive surface area, including both total rock surface and reactive mineral phases, and (iii) in-situ permeability and porosity that enable efficient CO2-saturated water injection with minimal energy input. While dissolution enhances pore connectivity and injectivity, secondary carbonate precipitation can clog flow pathways, though fracture opening under pressure-temperature gradients may counteract these effects. Field-scale projects such as CarbFix demonstrate that continuous dissolved-CO2 injection promotes near-well dissolution while shifting carbonate precipitation farther from the injection site, reducing clogging risks. Current findings highlight basaltic formations as promising, safe, and scalable reservoirs for permanent CO2 storage, though further research is needed to quantify pore-scale processes and optimize injection strategies.
碳捕获与封存(CCS)提供了从大气中移除并安全封存大量二氧化碳的潜力,从而限制了全球变暖。传统的地质封存是将气态或超临界状态的二氧化碳注入多孔岩石储层,依靠地质顶部密封、毛细管力和/或地下水溶解作为主要的“锁定”过程。另一种方法是将二氧化碳饱和的水注入基性岩石(玄武岩)中,化学诱导CO2的原位矿化,形成固体碳酸盐矿物。这种机制提供了最低的碳返回大气的风险。本文综述了玄武岩中CO2矿化及其对岩石孔隙网络、渗透率和孔隙度的影响的野外和室内研究。有证据表明,溶解-沉淀反应在很大程度上改变了玄武岩的微观结构,其结果受到以下因素的强烈影响:(i)足够的流体在孔隙空间内停留时间,(ii)足够的反应表面积,包括总岩石表面和反应矿物相,以及(iii)原位渗透率和孔隙度,从而能够以最小的能量输入有效地注入二氧化碳饱和水。虽然溶蚀作用增强了孔隙连通性和注入性,但次生碳酸盐沉淀会阻塞流动通道,尽管压力-温度梯度下的裂缝张开可能会抵消这些影响。CarbFix等油田规模的项目表明,连续注入溶解二氧化碳可以促进近井溶解,同时将碳酸盐沉淀转移到远离注入点的地方,从而降低堵塞风险。目前的研究结果表明,玄武岩地层是一种有前途的、安全的、可扩展的永久二氧化碳储存储层,但还需要进一步的研究来量化孔隙尺度过程并优化注入策略。
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引用次数: 0
A critical review of cushion gas in underground hydrogen storage: Thermophysical properties, interfacial interactions, and numerical perspectives 地下储氢中的缓冲气:热物理性质、界面相互作用和数值观点。
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2025-11-09 DOI: 10.1016/j.cis.2025.103701
Haiyang Zhang , Yihuai Zhang , Muhammad Arif
Underground hydrogen storage (UHS) represents a large-scale energy storage system, aiming to ensure a consistent supply by storing hydrogen generated from surplus energy. In the practice of UHS, cushion gas is typically injected into the formation to maintain reservoir pressure for efficient hydrogen withdrawal. This paper reviews the impact of cushion gas on the performance of UHS from both experimental and numerical simulation perspectives. The thermophysical (e.g., density, viscosity, compressibility, and solubility) and petrophysical (interfacial tension, wettability, and relative permeability) properties, as well as the mixing and diffusion behavior of different cushion gases, were compared. The corresponding impact of different cushion gases on plume migration and trapping potential is then discussed. Furthermore, this review critically analyzes and explains the impact of various factors on the performance of UHS, including the type of cushion gas, the composition of cushion gas mixtures, the volume of injected cushion gas, and the effects of bio-methanation processes. The corresponding analysis specifically focuses on key performance indicators, including H2 recovery factor, formation pressure, brine production, and H2 outflow purity. Thus, this review provides a comprehensive analysis of the role of cushion gas in UHS, offering insight into the effective management and optimization of cushion gas injection in field-scale UHS operations.
地下储氢(UHS)是一种大型储能系统,旨在通过储存剩余能量产生的氢气来确保持续供应。在UHS的实践中,通常将缓冲气注入地层中,以保持储层压力,从而有效地提取氢气。本文从实验和数值模拟两方面综述了缓冲气体对UHS性能的影响。对比了不同缓冲层气体的热物理特性(如密度、粘度、可压缩性和溶解度)和岩石物理特性(界面张力、润湿性和相对渗透率),以及混合和扩散行为。讨论了不同垫层气体对烟柱运移和圈闭潜力的影响。此外,本文还批判性地分析和解释了各种因素对UHS性能的影响,包括缓冲气体的类型、缓冲气体混合物的组成、注入缓冲气体的体积以及生物甲烷化过程的影响。相应的分析侧重于关键性能指标,包括H2采收率、地层压力、卤水产量和H2流出纯度。因此,本文全面分析了缓冲气在UHS中的作用,为油田规模UHS作业中有效管理和优化缓冲气注入提供了见解。
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引用次数: 0
Rheology-driven approaches in slurry transportation: Influence of bimodal mixtures, additives, and modelling perspectives 流变驱动的泥浆输送方法:双峰混合物、添加剂和建模观点的影响。
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2025-11-09 DOI: 10.1016/j.cis.2025.103714
Asisha Ranjan Pradhan
Slurry transportation through pipelines is an essential technology supporting mining, mineral processing, power generation, dredging, and related industries. Its performance is governed by the interactions between solid particles, carrier fluids, and operating conditions, which collectively determine rheology, stability, and energy demand. This review synthesises recent developments on the influence of particle size distribution, concentration, and morphology on slurry flow behaviour, as well as the role of chemical and bio-based additives in improving suspension stability, reducing viscosity, and enabling higher solids loading. The discussion extends to advances in rheological modelling and computational approaches, ranging from empirical correlations to computational fluid dynamics (CFD), discrete element modelling, and emerging hybrid frameworks that integrate artificial intelligence and machine learning for improved prediction and control. Case studies and experimental findings highlight the potential of optimised formulations and modelling strategies to enhance flowability, minimise pressure losses, and promote energy-efficient operation. Attention is also given to the limitations of current methods, challenges in scaling laboratory results to field conditions, and the need for standardisation in additive evaluation and model validation. By consolidating these insights, the review provides a comprehensive understanding of slurry pipeline transport and outlines opportunities for developing reliable, sustainable, and adaptable systems suited to future industrial demands.
管道输送浆体是支撑采矿、选矿、发电、疏浚及相关行业的重要技术。它的性能取决于固体颗粒、载体流体和操作条件之间的相互作用,这些因素共同决定了流变性、稳定性和能量需求。这篇综述综合了粒度分布、浓度和形态对浆液流动行为的影响的最新进展,以及化学和生物基添加剂在改善悬浮液稳定性、降低粘度和实现更高固体负载方面的作用。讨论扩展到流变建模和计算方法的进展,从经验关联到计算流体动力学(CFD),离散元素建模,以及集成人工智能和机器学习以改进预测和控制的新兴混合框架。案例研究和实验结果强调了优化配方和建模策略在提高流动性、减少压力损失和促进节能操作方面的潜力。还注意到当前方法的局限性,将实验室结果扩展到现场条件的挑战,以及在添加剂评估和模型验证方面标准化的必要性。通过整合这些见解,该综述提供了对泥浆管道输送的全面了解,并概述了开发可靠、可持续和适应性强的系统以适应未来工业需求的机会。
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引用次数: 0
ZIF-67-derived electrode materials for high-performance supercapacitors: Advances and perspectives 用于高性能超级电容器的zif -67衍生电极材料:进展和前景
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2025-11-08 DOI: 10.1016/j.cis.2025.103703
Muhammad Hassan Zaheer Khan , Muhammad Umair Tariq , Sara Riaz , Muhammad Shahbaz , Muhammad Mitee Ullah , Enza Fazio , Ammar Tariq , Shahid Atiq , Shahid M. Ramay
The development of next-generation energy storage devices necessitates electrode materials that can simultaneously offer high surface area, tunable porosity, and efficient charge transport. Zeolitic Imidazolate Framework-67 (ZIF-67), a cobalt-based metal organic framework, has emerged as a modular platform for designing high-performance supercapacitor electrodes. This review provides a comprehensive analysis of recent breakthroughs in the synthesis, modification, and application of ZIF-67 and its derivatives. Diverse synthetic routes ranging from solvothermal and hydrothermal to surfactant-assisted, microwave, and green solid-state methods are systematically compared with respect to structural control and electrochemical outcomes. Special emphasis is placed on ZIF-67-based composites incorporating carbon materials, conductive polymers, and transition metal compounds, which unlock synergistic effects to enhance conductivity and capacitance. Additionally, the role of doping, redox-active interfaces, and advanced electrolytes in tuning charge storage behavior is critically examined. We highlight the limitations that persist, particularly in cycling stability and scalability, and propose design principles to overcome these hurdles. This review positions ZIF-67 as a highly adaptable framework for next-generation supercapacitors and offers a roadmap for future innovations in MOF-derived energy storage systems.
下一代储能设备的发展需要能够同时提供高表面积、可调孔隙率和高效电荷传输的电极材料。沸石咪唑酸框架-67 (ZIF-67)是一种钴基金属有机框架,已成为设计高性能超级电容器电极的模块化平台。本文综述了ZIF-67及其衍生物的合成、改性和应用方面的最新进展。从溶剂热法和水热法到表面活性剂辅助法、微波法和绿色固态法等不同的合成路线在结构控制和电化学结果方面进行了系统的比较。特别强调的是基于zif -67的复合材料,包括碳材料、导电聚合物和过渡金属化合物,它们可以释放协同效应,增强导电性和电容。此外,掺杂、氧化还原活性界面和高级电解质在调整电荷存储行为中的作用也得到了严格的检验。我们强调了持续存在的局限性,特别是在循环稳定性和可扩展性方面,并提出了克服这些障碍的设计原则。这篇综述将ZIF-67定位为下一代超级电容器的高度适应性框架,并为mof衍生储能系统的未来创新提供了路线图。
{"title":"ZIF-67-derived electrode materials for high-performance supercapacitors: Advances and perspectives","authors":"Muhammad Hassan Zaheer Khan ,&nbsp;Muhammad Umair Tariq ,&nbsp;Sara Riaz ,&nbsp;Muhammad Shahbaz ,&nbsp;Muhammad Mitee Ullah ,&nbsp;Enza Fazio ,&nbsp;Ammar Tariq ,&nbsp;Shahid Atiq ,&nbsp;Shahid M. Ramay","doi":"10.1016/j.cis.2025.103703","DOIUrl":"10.1016/j.cis.2025.103703","url":null,"abstract":"<div><div>The development of next-generation energy storage devices necessitates electrode materials that can simultaneously offer high surface area, tunable porosity, and efficient charge transport. Zeolitic Imidazolate Framework-67 (ZIF-67), a cobalt-based metal organic framework, has emerged as a modular platform for designing high-performance supercapacitor electrodes. This review provides a comprehensive analysis of recent breakthroughs in the synthesis, modification, and application of ZIF-67 and its derivatives. Diverse synthetic routes ranging from solvothermal and hydrothermal to surfactant-assisted, microwave, and green solid-state methods are systematically compared with respect to structural control and electrochemical outcomes. Special emphasis is placed on ZIF-67-based composites incorporating carbon materials, conductive polymers, and transition metal compounds, which unlock synergistic effects to enhance conductivity and capacitance. Additionally, the role of doping, redox-active interfaces, and advanced electrolytes in tuning charge storage behavior is critically examined. We highlight the limitations that persist, particularly in cycling stability and scalability, and propose design principles to overcome these hurdles. This review positions ZIF-67 as a highly adaptable framework for next-generation supercapacitors and offers a roadmap for future innovations in MOF-derived energy storage systems.</div></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"347 ","pages":"Article 103703"},"PeriodicalIF":19.3,"publicationDate":"2025-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145517329","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent progress on the application of imine-based surfactants in emulsion systems: from delivery systems to pH-responsive platforms 亚胺基表面活性剂在乳液体系中的应用进展:从输送系统到ph响应平台
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2025-11-08 DOI: 10.1016/j.cis.2025.103711
Md Shabudden Ahamed , Cuie Tang , Shili Liu , Bin Li , Elham Assadpour , Seid Mahdi Jafari , Yan Li
Emulsions often face separation and degradation challenges under external stimuli such as pH shifts, temperature fluctuations, and ionic strength variations in complex mixtures during processing and storage. Conventional stabilization approaches often involve processing complexity, high energy cost, and risk of degrading sensitive components. Imine chemistry presents a transformative alternative by leveraging dynamic covalent bonds, where the reversible formation of a (C=N) linkage via condensation enables to create intelligent, responsive emulsions. Formation of imine-based surfactants through in situ reactions between amine and aldehyde precursors is a simple and shorter step that not only stabilizes interfaces but also confers unique functionalities, offering dynamic control over emulsion stability. These imine-based surfactants exhibit a highly tunable hydrophilic-lipophilic balance, reversible emulsification behavior, and exceptional pH responsiveness due to the acid-labile nature of the imine bond. This review critically evaluates the molecular design, synthesis, and interfacial mechanism of imine-surfactants, highlighting their application in developing responsive emulsion systems for targeted drug delivery, enhanced oil recovery, biosensing, and food production.
在加工和储存过程中,乳剂经常面临外部刺激下的分离和降解挑战,如pH值变化、温度波动和复杂混合物中的离子强度变化。传统的稳定方法通常涉及加工复杂性、高能源成本和敏感部件退化的风险。亚胺化学通过利用动态共价键提供了一种变革性的选择,其中通过缩合可逆形成(C=N)键,可以创建智能,反应灵敏的乳剂。通过胺和醛前体之间的原位反应形成亚胺基表面活性剂是一个简单而短暂的步骤,不仅稳定了界面,而且赋予了独特的功能,提供了乳液稳定性的动态控制。这些亚胺基表面活性剂表现出高度可调的亲水亲脂平衡,可逆的乳化行为,以及由于亚胺键的酸不稳定性而产生的特殊的pH响应性。本文综述了亚胺表面活性剂的分子设计、合成和界面机理,重点介绍了它们在靶向药物递送、提高石油采收率、生物传感和食品生产等方面的应用。
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引用次数: 0
Challenges and advances in nanolubricants: Stability, performance mechanisms, and industrial applications 纳米润滑剂的挑战和进展:稳定性、性能机制和工业应用。
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2025-11-07 DOI: 10.1016/j.cis.2025.103702
Yaghoub Mohammadfam , Hadi Pourpasha , Saeed Zeinali Heris , Jun Deng , Yaqing Li , Jie Yang
Nanolubricants (NLs) offer transformative potential for enhancing the energy efficiency and durability of systems in the automotive, aerospace, wind energy, and refrigeration sectors. However, their successful industrial implementation is hindered by several challenges, including inconsistent experimental protocols, inadequate short-term stability, and a scarcity of real-world operational data. This study provides a systematic review of the current state of NL research, examining challenges related to stabilization techniques (both physical and chemical), stability evaluation methods, lubrication mechanisms, nanoparticle selection, and environmental and health risks. A key finding is that long-term stability remains the paramount yet most neglected challenge; only approximately 60 % of studies address it, and a mere fraction investigate performance under real-world conditions. The analysis demonstrates that hybrid stabilization methods, which combine chemical and physical techniques, significantly outperform singular approaches. Furthermore, this work identifies major inconsistencies in stability evaluation protocols and a limited understanding of dynamic lubrication mechanisms, both of which obstruct meaningful cross-study comparisons. Based on the analysis, the transition from lab-scale innovation to industrial application requires three critical developments: standardized testing protocols incorporating accelerated aging, unified reporting metrics, and optimized hybrid stabilization strategies. This review offers a clear framework to overcome these barriers, paving the way for the reliable and scalable implementation of next-generation NLs.
纳米润滑剂(NLs)为提高汽车、航空航天、风能和制冷行业系统的能源效率和耐用性提供了变革性的潜力。然而,它们的成功工业实施受到几个挑战的阻碍,包括不一致的实验协议,短期稳定性不足,以及缺乏实际操作数据。本研究对NL研究的现状进行了系统回顾,研究了与稳定技术(物理和化学)、稳定性评估方法、润滑机制、纳米颗粒选择以及环境和健康风险相关的挑战。一个重要的发现是,长期稳定仍然是最重要但最容易被忽视的挑战;只有大约60%的研究解决了这个问题,只有一小部分研究了现实条件下的性能。分析表明,结合化学和物理技术的混合稳定方法明显优于单一方法。此外,这项工作确定了稳定性评估方案的主要不一致之处以及对动态润滑机制的有限理解,这两者都阻碍了有意义的交叉研究比较。根据分析,从实验室规模的创新到工业应用的转变需要三个关键的发展:标准化的测试协议,包括加速老化,统一的报告指标,以及优化的混合稳定策略。本综述为克服这些障碍提供了一个清晰的框架,为下一代NLs的可靠和可扩展实施铺平了道路。
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引用次数: 0
Engineered materials for sustainable development in environmental and healthcare applications 环境和医疗保健应用中可持续发展的工程材料。
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2025-11-04 DOI: 10.1016/j.cis.2025.103700
Sandeep Kumar , Reinhard Miller
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引用次数: 0
Cutting-edge synthetic strategies and interaction mechanisms in polymeric nanostructures: Bridging preformed polymers with polymerization-induced self-assembly 高分子纳米结构的前沿合成策略和相互作用机制:用聚合诱导的自组装桥接预制聚合物
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2025-10-29 DOI: 10.1016/j.cis.2025.103699
Ranjit De , Bijan Das , Matthew J. Derry , Jonghyuk Park
Recent progress in nanosized drug delivery carrier design has immensely contributed to the development of next-generation smart healthcare facilities, offering enhanced solubility, prolonged circulation time, reduced toxicity to healthy cells and real-time monitoring. Among various materials, polymeric nanocarriers (PNCs) stand out due to the customizable properties of polymer molecules, which can further be tailored to fulfill specific requirements. This review provides a comprehensive evaluation of the different intermolecular interactions, such as hydrogen bonding, π-π stacking, electrostatic interactions, hydrophobic/hydrophilic interactions, and host-guest interactions, that influence the self-assembly processes during PNC design. It also explores a range of fabrication techniques for PNCs, including emulsion-evaporation, nanoprecipitation, dialysis, gelation, salting-out, supercritical fluid technology, coacervation, and molecularly imprinted polymerization. Additionally, the impact of experimental conditions on controlling the size of PNCs is analyzed in detail. The review further evaluates the process of polymerization-induced self-assembly (PISA) in conjunction with various polymerization methods, highlighting the potential for advanced PNC fabrication. Lastly, it discusses the prospects and challenges associated with PNC design, considering both preformed polymers and PISA methodologies.
纳米级药物传递载体设计的最新进展极大地促进了下一代智能医疗设施的发展,提供增强的溶解度、延长的循环时间、降低对健康细胞的毒性和实时监测。在各种材料中,聚合物纳米载体(pnc)由于聚合物分子的可定制特性而脱颖而出,可以进一步定制以满足特定要求。本文综述了影响PNC设计过程中自组装过程的分子间相互作用,如氢键、π-π堆叠、静电相互作用、疏水/亲水性相互作用和主客体相互作用等。它还探讨了pnc的一系列制造技术,包括乳液蒸发、纳米沉淀、透析、凝胶、盐析、超临界流体技术、凝聚和分子印迹聚合。此外,还详细分析了实验条件对pnc尺寸控制的影响。本文进一步评估了聚合诱导自组装(PISA)与各种聚合方法的结合过程,强调了先进PNC制造的潜力。最后,它讨论了与PNC设计相关的前景和挑战,考虑到预制聚合物和PISA方法。
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引用次数: 0
Nano/micro-encapsulated enzymes as engineered biocatalysts for the food industry 纳米/微封装酶作为食品工业的工程生物催化剂
IF 19.3 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2025-10-29 DOI: 10.1016/j.cis.2025.103697
Mohammad Mahdi Rostamabadi , Fuat Topuz , Asli Can Karaca , Elham Assadpour , Hadis Rostamabadi , Seid Mahdi Jafari
Enzymes are indispensable tools in modern food processing, offering precise catalytic functions that improve product quality, texture, and preservation. Nevertheless, their industrial utility is often constrained by poor stability under thermal, oxidative, or acidic/alkaline conditions. Nano/microencapsulation technologies have emerged as robust strategies to overcome these limitations, enhancing enzyme resilience, prolonging activity, and enabling targeted delivery. This review presents a thorough examination of both established and novel encapsulation approaches for enzymes, i.e. coacervation, spray drying, liposomal systems, supercritical CO₂ processing, sol-gel techniques, and metal-organic frameworks. The role of various biomolecules e.g. polysaccharides, proteins, lipids, and nucleic acids in encapsulation systems is discussed in the context of improving enzyme protection and functional integration. Mechanisms for environmental shielding and stimulus-responsive release are also highlighted. Applications of encapsulated enzymes in diverse food sectors, including dairy, baking, beverages, meat processing, and functional food development, are explored, showcasing their potential in optimizing food formulation and processing efficiency. Although these technologies offer significant promise, hurdles like production scalability, material safety, economic feasibility, and regulatory compliance remain. Future research aimed at refining encapsulation systems and designing intelligent, cost-effective carriers will be pivotal in advancing the use of engineered enzymes in food technology.
酶是现代食品加工中不可缺少的工具,提供精确的催化功能,提高产品质量,质地和保存。然而,它们的工业用途往往受到热、氧化或酸/碱性条件下稳定性差的限制。纳米/微胶囊技术已经成为克服这些限制的强大策略,增强酶的弹性,延长活性,并实现靶向递送。本文综述了现有的和新的酶包封方法,即凝聚、喷雾干燥、脂质体系统、超临界二氧化碳处理、溶胶-凝胶技术和金属有机框架。在改善酶保护和功能整合的背景下,讨论了各种生物分子如多糖、蛋白质、脂质和核酸在包封系统中的作用。环境屏蔽和刺激反应释放的机制也得到了强调。探讨了胶囊化酶在乳制品、烘焙、饮料、肉类加工和功能食品开发等食品领域的应用,展示了它们在优化食品配方和加工效率方面的潜力。尽管这些技术带来了巨大的希望,但生产可扩展性、材料安全性、经济可行性和法规遵从性等障碍仍然存在。未来的研究旨在改进封装系统和设计智能,具有成本效益的载体将是推进工程酶在食品技术中的应用的关键。
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引用次数: 0
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Advances in Colloid and Interface Science
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