Advances in Colloid and Interface Science最新文献_第7页

Cationic antibacterial polymers for development of bactericidal materials: Strategies, mechanisms, and applications 用于开发杀菌材料的阳离子抗菌聚合物：策略、机制和应用

IF 19.3 1区化学 Q1 CHEMISTRY, PHYSICAL

Advances in Colloid and Interface Science

Pub Date : 2025-09-04 DOI: 10.1016/j.cis.2025.103658

Zhaochuan Yu , Chao Deng , Tong Lei , Huijie Wang , Yuqian Liu , Chao Liu , Farzad Seidi , Qiang Yong , Huining Xiao

The worldwide consumption of antibiotics has significantly contributed to the escalating challenge of antibiotic resistance over the past decades. Therefore, there is a tremendous interest in the development of new non-antibiotic antibacterial agents as alternatives to traditional antimicrobial drugs, which could exhibit prolonged action, enhanced efficacy, and reduced toxicity. Among various antibacterial agents, cationic antibacterial polymers (CAPs) have been particularly appearing due to their plenty of positive-charged groups or segments, enabling them to interact effectively with the negatively charged surfaces of microorganisms, thereby inhibiting their growth. This review paper begins by summarizing the different types and features of CAPs including quaternary ammonium salt (QAS) polymers, guanidine salt (GS) polymers, and quaternary phosphonium salt (QPS) polymers, originating from both natural and synthetic polymers. Subsequently, the antimicrobial mechanisms of CAPs are further discussed, including electrostatic interactions, cell membrane damage, protein precipitation, and DNA damage, and it was pointed out that the synergistic effect of these mechanisms confers strong antimicrobial capabilities to CAPs. Additionally, the article extensively discusses the applications of CAPs in key areas such as textiles, medical care, food packaging, and water treatment, and identifies current challenges, such as the development of resistance, environmental impact, and potential biotoxicity. Moreover, this review summarizes the latest literature on the antibacterial activity of various CAPs combined with different polymers as substrates and provides future directions for exploring the novel non-antibiotic antibacterial agents for various applications.

在过去的几十年里，抗生素的全球消费极大地加剧了抗生素耐药性的挑战。因此，人们对开发新的非抗生素抗菌剂作为传统抗菌药的替代品产生了极大的兴趣，这种抗菌剂可以表现出延长作用时间、增强疗效和降低毒性。在各种抗菌剂中，阳离子抗菌聚合物（cap）因其含有大量带正电荷的基团或片段，使其能够与微生物的带负电荷的表面有效地相互作用，从而抑制微生物的生长而特别引人注目。本文首先综述了高分子聚合物的不同类型和特点，包括季铵盐（QAS）聚合物、胍盐（GS）聚合物和季磷盐（QPS）聚合物，包括天然聚合物和合成聚合物。随后，进一步讨论了CAPs的抗菌机制，包括静电相互作用、细胞膜损伤、蛋白质沉淀和DNA损伤，并指出这些机制的协同作用赋予了CAPs强大的抗菌能力。此外，本文还广泛讨论了cap在纺织、医疗、食品包装和水处理等关键领域的应用，并确定了当前面临的挑战，如耐药性的发展、对环境的影响和潜在的生物毒性。此外，本文还对不同聚合物作为底物组合的各种cap抗菌活性的最新文献进行了综述，并为探索各种应用的新型非抗生素抗菌剂提供了未来的研究方向。

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引用次数: 0

Recent advances in eutectogels: Preparation, properties and applications 共凝胶的制备、性能和应用

IF 19.3 1区化学 Q1 CHEMISTRY, PHYSICAL

Advances in Colloid and Interface Science

Pub Date : 2025-09-04 DOI: 10.1016/j.cis.2025.103659

Jihui Wang , Yueju Zhen , Jingcheng Hao , Chunxiao Chai

Multiple stretchable gels with conductivity have been thoroughly prepared in diverse solvents historically to modulate their superlative properties in a multitude of applications, such as soft robotics, wearable devices, and e-skins. Eutectogels are considered as an emerging class of gels that combine the best features of both hydrogels and organogels, including environmental friendliness, thermal stability and customizable nature. Eutectogels, composed of deep eutectic solvents (DES) immobilized within different matrices, not only inherit the merits of DES, but also show some additional properties derived from the special structure and compositions, which are conducive to development potential. This review emphasizes the developments and advances in eutectogels from the compositions, functions and applications. Correspondingly, the optimization strategies, mechanisms and advanced progress through solvent engineering and structure tailoring are summarized for multifunctional eutectogels. Then environmental adaptability and intelligent applications in flexible electronics, energy, biology and other fields are discussed in the tailor-made eutectogels. From these recent research efforts of eutectogels and our academic background, the existing challenges and opportunities for future research directions in this filed are thoroughly deliberated at last.

具有导电性的多种可拉伸凝胶已经在不同的溶剂中进行了充分的制备，以调节其在软机器人、可穿戴设备和电子皮肤等众多应用中的最高性能。共凝胶被认为是一种新兴的凝胶，它结合了水凝胶和有机凝胶的最佳特性，包括环境友好性、热稳定性和可定制性。由固定在不同基质内的深层共晶溶剂（DES）组成的共晶凝胶不仅继承了DES的优点，而且由于其特殊的结构和组成而表现出一些额外的性能，有利于发展潜力。本文从共凝胶的组成、功能和应用等方面综述了共凝胶的研究进展。总结了多功能共凝胶的溶剂工程和结构裁剪优化策略、机理和最新进展。然后讨论了定制共凝胶的环境适应性和在柔性电子、能源、生物等领域的智能应用。最后，从这些近年来共析凝胶的研究成果和我们的学术背景出发，对该领域存在的挑战和未来研究方向的机遇进行了深入探讨。

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引用次数: 0

Recent advances in g-C3N5-based S-scheme heterojunction photocatalysts: From design to application g- c3n5基s型异质结光催化剂的研究进展：从设计到应用。

IF 19.3 1区化学 Q1 CHEMISTRY, PHYSICAL

Advances in Colloid and Interface Science

Pub Date : 2025-09-04 DOI: 10.1016/j.cis.2025.103661

Aditya Tiwari , Thangapandi Chellapandi , Krzysztof Pikoń , Mahesh Ganesapillai

Graphitic carbon nitride g-C₃N₅ is a subject of significant research interest as an advanced photocatalyst, largely attributed to its distinctive electronic structure and nitrogen-rich, extended π-conjugated framework. Compared to traditional g-C₃N₄, it offers a narrower bandgap, enhanced charge carrier mobility, and stronger redox potential, making it highly suitable for solar-driven applications such as green energy production, effluent remediation and synthesis of commercially viable chemicals. However, its performance is limited by rapid e⁻/h⁺ pair recombination. To overcome this, the construction of S-scheme heterojunctions has emerged as a promising strategy, as it enables efficient charge separation while retaining strong redox capabilities and advantages that conventional Type-I and Type-II heterojunctions lack. The built-in electric field and band bending are inherent to S-scheme heterojunctions, that further enhances charge migration and utilization of absorbed solar energy. Despite these benefits, detailed studies on g-C₃N₅-based S-scheme systems remain sparse. Therefore, this review critically examines the charge transfer mechanisms in g-C₃N₅ S-scheme systems and highlights their enhanced performance relative to conventional heterostructures. Furthermore, the review provides an in-depth discussion on various synthesis strategies via dimensional assembled S-scheme for g-C₃N₅-based heterojunctions and evaluates advanced characterization techniques used to probe charge migration behavior. Finally, the study explores the photocatalytic mechanisms of these heterojunctions for green hydrogen evolution, pollutant degradation, CO₂ reduction, and H₂O₂ synthesis. Collectively, this review offers a comprehensive analysis of g-C₃N₅-based S-scheme heterojunction photocatalysts and outlines key directions for advancing their development to meet future sustainability challenges.

石墨化氮化碳g-C3N5作为一种先进的光催化剂，由于其独特的电子结构和富氮的扩展π共轭框架而备受关注。与传统的g-C3N4相比，它具有更窄的带隙，增强的电荷载流子迁移率和更强的氧化还原电位，使其非常适合太阳能驱动的应用，如绿色能源生产，废水修复和商业上可行的化学品合成。但其性能受到e-/h+对快速复合的限制。为了克服这一问题，构建S-scheme异质结已经成为一种很有前途的策略，因为它可以实现有效的电荷分离，同时保留传统的i型和ii型异质结所缺乏的强氧化还原能力和优势。内置电场和带弯曲是s型异质结所固有的，这进一步增强了电荷迁移和吸收太阳能的利用。尽管有这些好处，但对基于g- c3n5的S-scheme系统的详细研究仍然很少。因此，本文对g-C3N5 S-scheme体系中的电荷转移机制进行了批判性的研究，并强调了它们相对于传统异质结构的性能增强。此外，本文还深入讨论了基于g- c3n5异质结的尺寸组装s方案的各种合成策略，并评估了用于探测电荷迁移行为的先进表征技术。最后，研究探讨了这些异质结在绿色析氢、污染物降解、CO2还原和H2O2合成等方面的光催化机制。综上所述，本文对基于g- c3n5的s -图式异质结光催化剂进行了全面的分析，并概述了推进其发展以应对未来可持续性挑战的关键方向。

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引用次数: 0

The role of surface material properties on the behavior of ionic liquids in nanoconfinement: A critical review and perspective of theory and simulations 表面材料性质对纳米约束下离子液体行为的影响：理论与模拟的评述与展望

IF 19.3 1区化学 Q1 CHEMISTRY, PHYSICAL

Advances in Colloid and Interface Science

Pub Date : 2025-09-01 DOI: 10.1016/j.cis.2025.103623

Irina Nesterova , Nikolay Kondratyuk , Yury A. Budkov , Kirill M. Gerke , Aleksey Khlyupin

Room temperature ionic liquids show great promise as electrolytes in various technological applications, such as energy storage or electrotunable lubrication. These applications are particularly intriguing due to the specific behavior of ionic liquids in nanoconfinement. While previous research has been focused on optimizing the required characteristics through the selection of electrolyte properties, the contribution of confining material properties in these systems has been largely overlooked. In this review, we provide constructive analysis of recent developments of theoretical and numerical studies related to the description of surface material properties impact on the ionic liquid behavior in confinement and propose potential ways for further investigations in this direction. Although the presented advances reveal the importance of surface material properties in the application processes with confined ionic liquids, there are still a lot of issues that should be thoroughly investigated in the future. We believe that this review will significantly contribute to the development of new approaches with material properties consideration for confined ionic liquid research.

室温离子液体作为电解质在各种技术应用中显示出巨大的前景，如储能或电可调润滑。由于离子液体在纳米约束下的特殊行为，这些应用特别有趣。虽然以前的研究主要集中在通过选择电解质特性来优化所需的特性，但在这些系统中限制材料特性的贡献在很大程度上被忽视了。在这篇综述中，我们提供了建设性的理论和数值研究的最新进展，这些研究与描述表面材料性质对限制离子液体行为的影响有关，并提出了在这一方向上进一步研究的潜在途径。虽然目前的进展揭示了表面材料性能在受限离子液体应用过程中的重要性，但未来仍有许多问题需要深入研究。我们相信，这一综述将为限制性离子液体研究中考虑材料性质的新方法的发展做出重大贡献。

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引用次数: 0

Decahedron-derived five-fold twin noble metal nanocrystals: Solution-phase synthesis, growth mechanism, and applications 十面体衍生的五重双贵金属纳米晶体：固相合成、生长机制和应用

IF 19.3 1区化学 Q1 CHEMISTRY, PHYSICAL

Advances in Colloid and Interface Science

Pub Date : 2025-08-30 DOI: 10.1016/j.cis.2025.103650

Nan Hou , Haihong Wen , Wei Chen , Yun Yang , Bo Jiang , Wei Wang , Shaoming Huang , Shun Wang

Five-fold twinned (FFT) noble metal nanocrystals have attracted considerable interest in nanoscience due to their unique structures. This review gives a comprehensive analysis on four common types of FFT noble metal NCs (Au, Ag, Pd, and Pt) synthesized in solution, covering both monometallic structures (e.g., nanodecahedra, nanorods, nanowires, nanobipyramids, and their derivatives) and multimetallic heterostructures, with a brief discussion on FFT Cu nanowires and Rh nanodecahedra. We start with a clear overview of their structural properties, thermodynamic and kinetic stability, and twinning behavior, which is followed by a detailed discussion of key synthetic methods and growth mechanisms driving their development. Next, we provide a summary of their applications. Finally, the review also includes personal insights and identifies future challenges, suggesting potential research directions in this field.

五重孪晶（FFT）贵金属纳米晶体以其独特的结构引起了纳米科学领域的广泛关注。本文综述了在溶液中合成的四种常见的FFT贵金属NCs (Au、Ag、Pd和Pt)，包括单金属结构（如纳米十面体、纳米棒、纳米线、纳米金字塔及其衍生物）和多金属异质结构，并对FFT Cu纳米线和Rh纳米十面体进行了简要的讨论。我们首先对它们的结构性质、热力学和动力学稳定性以及孪生行为进行了清晰的概述，然后详细讨论了关键的合成方法和驱动它们发展的生长机制。接下来，我们将简要介绍它们的应用。最后，综述还包括个人的见解和未来的挑战，提出了该领域的潜在研究方向。

引用次数: 0

“Silatranization”: Surface modification with silatrane coupling agents “硅烷化”：用硅烷偶联剂进行表面改性

IF 19.3 1区化学 Q1 CHEMISTRY, PHYSICAL

Advances in Colloid and Interface Science

Pub Date : 2025-08-30 DOI: 10.1016/j.cis.2025.103649

Myong Joon Oh , Ireneusz Kownacki , Joanna Ortyl

Silatranization, a specialized variant of silanization using silatrane compounds, is emerging as a powerful strategy to functionalize material surfaces. Compared to conventional silane coupling agents, silatranes exhibit remarkable hydrolytic stability and enhanced resistance to self-condensation, enabling controllable, water-independent formation of a polysiloxane self-assembled monolayer. This review critically examines the unique structure of silatranyl cages, emphasizing how the intramolecular N->Si bond and chelate effect modulate the silicon center's reactivity toward hydroxyl-decorated surfaces. The discussion encompasses a comprehensive comparison of silatranization and conventional silanization in the aspect of preparation of starting materials, deposition kinetics and morphology of resulting organic adlayer. Key reaction parameters – solvent choice, temperature, silatrane concentration and catalyst– are systematically evaluated to guide the design of efficient protocols. Strategies to remove triethanolamine byproduct are also outlined for achieving contaminant-free coatings. Additionally, analytical techniques (FT-IR, NMR, AFM, XPS) that allow to verify correct formation of a silatrane-derived self-assembled monolayer are presented. Finally, the review showcases wide-ranging applications underscoring how silatranes can provide durable, functional interfaces for metal oxides, glass and organic polymers. The insights collected here aim to accelerate future innovations in surface science and engineering through the robust and versatile approach of silatranization.

硅烷化是硅烷化的一种特殊变体，使用硅烷化合物，正在成为一种强大的材料表面功能化策略。与传统的硅烷偶联剂相比，硅烷具有显著的水解稳定性和更强的抗自缩聚能力，能够形成可控的、不依赖水的聚硅氧烷自组装单层。本文综述了硅氰基笼的独特结构，强调了分子内N->；Si键和螯合效应如何调节硅中心对羟基修饰表面的反应性。讨论了硅烷化和传统硅烷化在原料制备、沉积动力学和所得有机层形貌等方面的全面比较。系统地评估了关键反应参数——溶剂选择、温度、硅烷浓度和催化剂——以指导高效方案的设计。本文还概述了去除三乙醇胺副产物的策略，以实现无公害涂层。此外，分析技术（FT-IR， NMR， AFM， XPS）允许验证硅烷衍生自组装单层的正确形成。最后，综述展示了硅烷的广泛应用，强调了硅烷如何为金属氧化物、玻璃和有机聚合物提供耐用的功能界面。这里收集的见解旨在通过强大和通用的硅烷化方法加速表面科学和工程的未来创新。

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引用次数: 0

Bacteriogenic metallic and semiconducting nano-system as a potential sustainable solution for one health complexities 致细菌金属和半导体纳米系统作为一种潜在的可持续解决方案的健康复杂性

IF 19.3 1区化学 Q1 CHEMISTRY, PHYSICAL

Advances in Colloid and Interface Science

Pub Date : 2025-08-29 DOI: 10.1016/j.cis.2025.103648

Vishal Chaudhary , Sonu Sonu , Pankaj Raizada , Ajeet Kaushik

Considering the complexities of electronics waste management to meet the requirements of digital-age technologies, this article underscores the pressing need for eco-friendly, economical, and sustainable engineering solutions. Here, it uniquely focuses on bacteriogenic metallic and semiconducting nano-systems as a promising yet underexplored solution for sustainable materials innovation. Unlike conventional green nanofabrication methods involving plants or eukaryotic microbes, bacteria possess numerous merits for fabrication, including ease of cultivation, a wide spectrum of genera, abundance, prompt cell division efficacy, genetic elasticity, and high bio-reduction/oxidation efficacy that make them highly adaptable platforms for engineered nanostructures. This article provides a comprehensive and first-of-its-kind framework integrating bacterial synthesis pathways (intercellular and extracellular), bacterial class (Monoderm and Diderm), reaction parameters (pH, temperature, precursor concentration), and molecular precursors (proteins, enzymes, exopolysaccharides, redox mediators). It further highlights emerging applications of bacteriogenic nanomaterials across medicine, energy, environment, and food sectors, enabled by their antipathogenic, catalytic, anticancer, antioxidant, photocatalytic, and biocompatible properties, contributing to the betterment of One Health. Besides, this article emphasizes exploring challenges like cytotoxicity, scalability, and stability, which restrict their transformative aspects. To address these obstacles, systematic studies including in-vitro/in-vivo toxicity, lifecycle, biodistribution and bioaccumulation analyses, and predictive modelling by adopting contemporary technologies like artificial intelligence (AI), complex systems, bioinformatics, and biotechnology to bridge the laboratory-to-market gap are suggested to enrich the suggested class of nano-systems. Overall, this article not only consolidates the state-of-the-art but also presents a novel interdisciplinary vision where bacterial complexity drives next-generation nanoengineering, aligning with the United Nations' sustainability goals.

考虑到电子废物管理的复杂性，以满足数字时代技术的要求，本文强调迫切需要环保，经济和可持续的工程解决方案。在这里，它独特地专注于细菌的金属和半导体纳米系统，作为一个有前途但尚未开发的可持续材料创新解决方案。与涉及植物或真核微生物的传统绿色纳米制造方法不同，细菌具有许多制造优点，包括易于培养，广谱属，丰度，快速细胞分裂效率，遗传弹性和高生物还原/氧化效率，使其成为工程纳米结构的高度适应性平台。本文提供了一个全面的、史无前例的框架，整合了细菌合成途径（细胞间和细胞外）、细菌类别（单胚层和双胚层）、反应参数（pH、温度、前体浓度）和分子前体（蛋白质、酶、外多糖、氧化还原介质）。它进一步强调了细菌纳米材料在医药、能源、环境和食品领域的新兴应用，这些材料具有抗病原、催化、抗癌、抗氧化、光催化和生物相容性等特性，有助于改善“同一个健康”。此外，本文强调探索诸如细胞毒性、可伸缩性和稳定性之类的挑战，这些挑战限制了它们的变革方面。为了解决这些障碍，建议采用人工智能（AI）、复杂系统、生物信息学和生物技术等当代技术进行系统研究，包括体外/体内毒性、生命周期、生物分布和生物积累分析，以及预测建模，以弥合实验室到市场的差距，以丰富所建议的纳米系统类别。总的来说，这篇文章不仅整合了最先进的技术，而且还提出了一个新的跨学科愿景，即细菌复杂性驱动下一代纳米工程，与联合国的可持续发展目标保持一致。

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引用次数: 0

The Microbial Factor in Subsurface Hydrogen behavior: Implications for Wettability and Interfacial Dynamics 地下氢行为中的微生物因素：对润湿性和界面动力学的影响

IF 19.3 1区化学 Q1 CHEMISTRY, PHYSICAL

Advances in Colloid and Interface Science

Pub Date : 2025-08-29 DOI: 10.1016/j.cis.2025.103647

Hamid Esfandyari , Raziallah Jafari Jozani , Aliakbar Hassanpouryouzband , Farhid Hemmatzadeh , Manouchehr Haghighi , Stefan Iglauer , Alireza Keshavarz , Abbas Zeinijahromi

Microbial activity plays a significant role in subsurface hydrogen behavior, with implications for underground storage and natural hydrogen systems. This study examines how microbial processes influence the wettability and solid–liquid interfacial characteristics of key subsurface minerals, calcite, dolomite, quartz, and gypsum, in hydrogen-brine-rock systems under realistic subsurface conditions. Wettability directly affects hydrogen distribution, flow dynamics, and trapping, making it a critical factor for both storage and natural recovery applications. Experiments were conducted under high-pressure, high-temperature conditions, with SEM/EDS analysis used to characterize interfacial modifications and mineral surface changes across three scenarios: clean, organic acid-aged, and microbial-aged. Microbial aging consistently increased mineral hydrophilicity, reducing advancing contact angles, such as from 57° (clean) to 40° (microbial-aged) on calcite at 50 °C and 8 MPa. Similar trends were observed for dolomite, with smaller changes for quartz and gypsum. Microbial biofilms were most prominent on calcite and dolomite surfaces, accompanied by decreases in brine pH (e.g., from 7.4 to 5.2 for calcite). These results reveal how microbial processes reshape mineral properties and hydrogen behavior in the subsurface. This study provides critical insights into microbial-mineral interactions, offering valuable guidance for optimizing hydrogen storage and natural hydrogen recovery systems.

微生物活动在地下氢行为中起着重要作用，对地下储存和天然氢系统具有重要意义。本研究考察了在真实的地下条件下，微生物过程如何影响氢-盐水-岩石系统中关键地下矿物方解石、白云石、石英和石膏的润湿性和固液界面特征。润湿性直接影响氢气分布、流动动力学和捕集，使其成为存储和自然采收应用的关键因素。实验在高压、高温条件下进行，利用SEM/EDS分析表征了三种情况下的界面修饰和矿物表面变化：清洁、有机酸老化和微生物老化。微生物老化持续增加矿物的亲水性，降低推进接触角，例如在50°C和8 MPa下方解石上从57°（清洁）到40°（微生物老化）。白云石也有类似的趋势，石英和石膏的变化较小。微生物生物膜在方解石和白云石表面最为突出，并伴随着盐水pH值的降低（例如，方解石从7.4降至5.2）。这些结果揭示了微生物过程如何重塑地下矿物性质和氢的行为。这项研究为微生物与矿物的相互作用提供了重要的见解，为优化氢储存和天然氢回收系统提供了有价值的指导。

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引用次数: 0

Understanding the mechanothermally superior nanotwinned copper: Fabrication procedure, mechanistic models and technological applications 了解机械热性能优越的纳米孪晶铜：制造过程、机制模型和技术应用

IF 19.3 1区化学 Q1 CHEMISTRY, PHYSICAL

Advances in Colloid and Interface Science

Pub Date : 2025-08-25 DOI: 10.1016/j.cis.2025.103630

Zhijie Zhang , Yulong Hu , Xiangyu Li , Fengjiang Wang , Yi Li , Anil Kunwar

The rapid evolution of microelectronics requires materials that combine exceptional strength, ductility, and electrical conductivity for joining applications and durable lithium-ion battery anodes. Nanotwinned Cu (nt-Cu) surpasses conventional strengthening approaches, which often compromise ductility and conductivity, by using nanoscale twin boundaries to enhance both mechanical and electrical properties. This review examines the thermomechanical characteristics, fabrication methods, multiscale mechanistic insights, and technological applications of nt-Cu, bridging fundamental science with engineering practice. Using an informatics-driven approach that incorporates advanced text mining and visualization techniques, this study elucidates key trends in the structural and mechanical properties of nt-Cu, advancing its application in cutting-edge joining technologies.

微电子技术的快速发展需要结合特殊强度、延展性和导电性的材料来连接应用和耐用的锂离子电池阳极。纳米孪晶铜（nt-Cu）通过使用纳米孪晶边界来增强机械和电学性能，超越了传统的强化方法，这些方法通常会损害延展性和导电性。本文综述了纳米铜的热力学特性、制造方法、多尺度力学见解和技术应用，将基础科学与工程实践联系起来。本研究采用信息学驱动的方法，结合先进的文本挖掘和可视化技术，阐明了nt-Cu结构和力学性能的关键趋势，推进了其在尖端连接技术中的应用。

引用次数: 0

Bio-based materials regulating interfacial behavior of multiphase systems during CO2 geological utilization and storage: A review 生物基材料在二氧化碳地质利用与封存过程中调控多相系统界面行为的研究进展

IF 19.3 1区化学 Q1 CHEMISTRY, PHYSICAL

Advances in Colloid and Interface Science

Pub Date : 2025-08-24 DOI: 10.1016/j.cis.2025.103646

Zesen Peng , Yueliang Liu , Hanchi Zheng , Xing Huang , Zhenhua Rui , Jirui Zou , Andrey Afanasyev

CO₂ geological utilization and storage involve complex multiphase interfacial behaviors that significantly influence the overall efficiency. Recently, bio-based materials have attracted increasing attention as promising candidates for interfacial regulation owing to their structural diversity, abundance, and environmental compatibility. This review summarizes recent advances in utilizing biomass-derived materials to regulate interfacial behaviors in subsurface multiphase systems. The relationship between interfacial behaviors and CO₂ utilization and sequestration is discussed under typical scenarios. Molecular structures, functional group characteristics, and environmental compatibility of bio-based materials are systematically reviewed. This article highlights the adsorption behaviors of bio-based molecules at liquid/liquid, solid/liquid, and gas/liquid interfaces, interfacial molecular arrangement and distribution, and spontaneous self-assembly behaviors. Effects of these materials on key interfacial properties including interfacial tension (IFT), wettability, and capillary forces are further analyzed. This study also examines some dynamic interfacial phenomena, such as the formation of multilamellar vesicle structures that accelerate mass transfer between phases, the synergistic interactions between nanoparticles and small biomolecules at solid-liquid interfaces under electrostatic forces, and the role of bio-based materials in promoting CO₂ transfer by providing additional adsorption sites. These insights offer new perspectives for fundamental understanding of interfacial mass transfer. Finally, the review outlines future research trends in studying the regulation of multiphase interfacial behaviors by bio-based materials, emphasizing the need for in situ microscopic characterization techniques to support their efficient application in CO₂ geological utilization and storage.

CO 2的地质利用和储存涉及复杂的多相界面行为，对整体效率有显著影响。近年来，生物基材料因其结构的多样性、丰度和环境相容性，作为界面调控的有前景的候选材料而受到越来越多的关注。本文综述了近年来利用生物质材料调控地下多相系统界面行为的研究进展。讨论了典型场景下界面行为与CO₂利用和固存的关系。系统地综述了生物基材料的分子结构、官能团特征和环境相容性。本文重点介绍了生物基分子在液/液、固/液、气/液界面上的吸附行为、界面分子的排列和分布以及自发自组装行为。进一步分析了这些材料对界面张力（IFT）、润湿性和毛细管力等关键界面性能的影响。本研究还探讨了一些动态界面现象，如多层囊泡结构的形成加速了相间的传质，纳米颗粒和小生物分子在静电力作用下的固液界面协同相互作用，以及生物基材料通过提供额外的吸附位点来促进CO₂的转移。这些见解为理解界面传质提供了新的视角。最后，综述了生物基材料多相界面行为调控研究的未来发展趋势，强调了原位微观表征技术的必要性，以支持其在CO 2地质利用和储存中的有效应用。

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引用次数: 0