Advances in Colloid and Interface Science最新文献

Growing concerns about environmental pollution have highlighted the need for efficient and sustainable methods to remove dye contamination from various ecosystems. In this context, computational methods such as molecular dynamics (MD), Monte Carlo (MC) simulations, quantum mechanics (QM) calculations, and machine learning (ML) methods are powerful tools used to study and predict the adsorption processes of dyes on various adsorbents. These methods provide detailed insights into the molecular interactions and mechanisms involved, which can be crucial for designing efficient adsorption systems. MD simulations, detailing molecular arrangements, predict dyes' adsorption behaviour and interaction energies with adsorbents. They simulate the entire adsorption process, including surface diffusion, solvent layer penetration, and physisorption. QM calculations, especially density functional theory (DFT), determine molecular structures and reactivity descriptors, aiding in understanding adsorption mechanisms. They identify stable adsorption configurations and interactions like hydrogen bonding and electrostatic forces. MC simulations predict equilibrium properties and adsorption energies by sampling molecular configurations. ML methods have proven highly effective in predicting and optimizing dye adsorption processes. These models offer significant advantages over traditional methods, including higher accuracy and the ability to handle complex datasets. These methods optimize adsorption conditions, clarify adsorbent functionalization roles, and predict dye removal efficiency under various conditions. This research explores MD, MC, QM, and ML approaches to connect molecular interactions with macroscopic adsorption phenomena. Probing these techniques provides insights into the dynamics and energetics of dye pollutants on adsorption surfaces. The findings will aid in developing and optimizing new materials for dye removal. This review has significant implications for environmental remediation, offering a comprehensive understanding of adsorption at various scales. Merging microscopic data with macroscopic observations enhances knowledge of dye pollutant adsorption, laying the groundwork for efficient, sustainable removal technologies. Addressing the growing challenges of ecosystem protection, this study contributes to a cleaner, more sustainable future.

Developing clean and renewable energy sources is key to a sustainable future. For human society to progress sustainably, environmentally friendly energy conversion and storage technologies are critical. The use of nanostructured advanced functional materials heavily influences the functionality of these systems. Porous carbons are multifunctional materials boasting considerable industrial utility. They possess many remarkable physiochemical and mechanical characteristics which have garnered interest in various fields. In this review, the application of porous carbon materials in electrocatalysis (HER, OER, ORR, NARR, and CO₂RR) and rechargeable batteries (LIBs, LiS batteries, NIBs, and KIBs) for renewable energy conversion and storage are discussed. The suitability of porous carbon materials for these applications is discussed, and some recent works are reviewed. Finally, a few viewpoints on developing porous carbons in electrocatalysis and rechargeable batteries are given. This review aims to generate interest in current and upcoming researchers in porous carbon application for a sustainable future.

There is a pressing need for sustainable sources of proteins to address the escalating food demands of the expanding global population, without damaging the environment. Lentil proteins offer a more sustainable alternative to animal-derived proteins (such as those from meat, fish, eggs, or milk). They are abundant, affordable, protein rich, nutritious, and functional, which makes them highly appealing as ingredients in the food, personal care, cosmetics, pharmaceutical and other industries. In this article, the chemical composition, nutritional value, and techno-functional properties of lentil proteins are reviewed. Then, recent advances on the extraction, purification, and modification of lentil proteins are summarized. Hurdles to the widespread utilization of lentil proteins in the food industry are highlighted, along with potential strategies to surmount these challenges. Finally, the potential applications of lentil protein in foods and beverages are discussed. The intention of this article is to offer an up-to-date overview of research on lentil proteins, addressing gaps in the knowledge related to their potential nutritional benefits and functional advantages for application within the food industry. This includes exploring the utilization of lentil proteins as nanocarriers for bioactive compounds, emulsifiers, edible inks for 3D food printing, meat analogs, and components of biodegradable packaging.

The synthesis of nanoparticles (NPs) using environmentally friendly methods has garnered significant attention in response to concerns about the environmental impact of various nanomaterial manufacturing techniques. To address this issue, natural resources like extracts from plants, fungi, and bacteria are employed as a green alternative for nanoparticle synthesis. Plant extracts, which contain active components such as terpenoids, alkaloids, phenols, tannins, and vitamins, operate as coating and reducing agents. Bacteria and fungi, on the other hand, rely on internal enzymes, sugar molecules, membrane proteins, nicotinamide adenine dinucleotide (NADH), and nicotinamide adenine dinucleotide phosphate (NADPH) dependent enzymes to play critical roles as reducing agents. This review collects recent advancements in biomimetic methods for nanoparticle synthesis, critically discussing the preparation approaches, the type of particles obtained, and their envisaged applications. A specific focus is given on using Prosopis fractal plant extracts to synthesize nanoparticles tailored for biomedical applications. The applications of this plant and its role in the biomimetic manufacturing of nanoparticles have not been reported yet, making this review a pioneering and valuable contribution to the field.

Biopolymer hydrogels have a broad range of applications as soft materials in a variety of commercial products, including foods, cosmetics, agrochemicals, personal care products, pharmaceuticals, and biomedical products. They consist of a network of entangled or crosslinked biopolymer molecules that traps relatively large quantities of water and provides semi-solid properties, like viscoelasticity or plasticity. Composite biopolymer hydrogels contain inclusions (fillers) to enhance their functional properties, including solid particles, liquid droplets, gas bubbles, nanofibers, or biological cells. These fillers vary in their composition, size, shape, rheology, and surface properties, which influences their impact on the rheological properties of the biopolymer hydrogels. In this article, the various types of biopolymers used to fabricate composite hydrogels are reviewed, with an emphasis on edible proteins and polysaccharides from sustainable sources, such as plants, algae, or microbial fermentation. The different kinds of gelling mechanism exhibited by these biopolymers are then discussed, including heat-, cold-, ion-, pH-, enzyme-, and pressure-set mechanisms. The different ways that biopolymer molecules can organize themselves in single and mixed biopolymer hydrogels are then highlighted, including polymeric, particulate, interpenetrating, phase-separated, and co-gelling systems. The impacts of incorporating fillers on the rheological properties of composite biopolymer hydrogels are then discussed, including mathematical models that have been developed to describe these effects. Finally, potential applications of composite biopolymer hydrogels are presented, including as delivery systems, packaging materials, artificial tissues, wound healing materials, meat analogs, filters, and adsorbents. The information provided in this article is intended to stimulate further research into the development and application of composite biopolymer hydrogels.

Acoustofluidic technologies that integrate acoustic waves and microfluidic chips have been widely used in bioparticle manipulation. As a representative technology, acoustic tweezers have attracted significant attention due to their simple manufacturing, contact-free operation, and low energy consumption. Recently, acoustic tweezers have enabled the efficient and smart manipulation of biotargets with sizes covering millimeters (such as zebrafish) and nanometers (such as DNA). In addition to acoustic tweezers, other related acoustofluidic chips including acoustic separating, mixing, enriching, and transporting chips, have also emerged to be powerful platforms to manipulate micro/nano bioparticles (cells in blood, extracellular vesicles, liposomes, and so on). Accordingly, some interesting applications were also developed, such as smart sensing. In this review, we firstly introduce the principles of acoustic tweezers and various related technologies. Second, we compare and summarize recent applications of acoustofluidics in bioparticle manipulation and sensing. Finally, we outlook the future development direction from the perspectives such as device design and interdisciplinary.

With the rapid development of information and communication industries, the usage of electromagnetic waves has caused the hazard of human health and misfunction of devices. The adsorption and shielding of electromagnetic waves have been achieved in various materials. The unique adjustable spatial structure makes metal-organic frameworks (MOFs) promising for electromagnetic shielding and adsorbing. As MOFs research advances, various large-scale MOF-based materials have been developed. For instance, MOFs spatial structure has been expanded from 2D to 3D to load more ligands. Progress in synthetic methods for MOFs and their derivatives is advancing, with priority on large-scale preparation and green synthesis. This review summarizes the methods for synthesizing MOFs and their derivatives, and explores the effects of MOFs spatial structure on electromagnetic interference (EMI) shielding and electromagnetic wave absorption capabilities. At the same time, detailed examples are used to focus on the applications of five different MOFs composites in electromagnetic shielding and electromagnetic wave absorption. Finally, the current challenges and prospects of MOFs in the electromagnetic field are introduced, providing a useful reference for the preparation and design of MOFs and their composites for electromagnetic wave processing applications.

Pickering emulsions and foams as well as capillary suspensions are becoming increasingly more popular as inks for 3D printing. However, a lack of understanding of the bulk rheological properties needed for their application in 3D printing is potentially stifling growth in the area, hence the timeliness of this review. Herein, we review the stability and bulk rheology of these materials as well as the applications of their 3D-printed products. By highlighting how the bulk rheology is tuned, and specifically the inks storage modulus, yield stress and critical balance between the two, we present a rheological performance map showing regions where good prints and slumps are observed thus providing clear guidance for future ink formulations. To further advance this field, we also suggest standard experimental protocols for characterizing the bulk rheology of the three types of ink: capillary suspension, Pickering emulsion and Pickering foam for 3D printing by direct ink writing.

This review explores the crystallographic versatility of niobium pentoxide (Nb₂O₅) at the nanoscale, showcasing enhanced catalytic efficiency for cutting-edge sustainable energy and environmental applications. The synthesis strategies explored encompass defect engineering, doping engineering, s-scheme formation, and heterojunction engineering to fine-tune the physicochemical attributes of diverse dimensional (0-D, 1-D, 2-D, and 3-D) Nb₂O₅ nanosystems as per targeted application. In addressing escalating environmental challenges, Nb₂O₅ emerges as a semiconductor photocatalyst with transformative potential, spanning applications from dye degradation to antibiotic and metal removal. Beyond its environmental impact, Nb₂O₅ is pivotal in sustainable energy applications, specifically in carbon dioxide and hydrogen conversion. However, challenges such as limited light absorption efficiency and scalability in production methods prompt the need for targeted research endeavors. The review details the state-of-the-art Nb₂O₅ nanosystems engineering, tuning their physicochemical properties employing material engineering, and their high catalytic performance in environment remediation and energy generation. It outlines challenges, potential mitigation strategies, and prospects, urging for developing greener synthesis routes, advanced charge transfer techniques, targeted optimization for specific pollutants, and application for micro/nano plastics photocatalytic reduction. As researchers and environmental stewards collaborate, Nb₂O₅ stands poised at the intersection of environmental remediation, energy harvesting, and nanomaterial advancements, offering a beacon of progress toward a cleaner, more sustainable future.

The Hungarian baron Roland Eötvös (Eötvös Loránd, 1848–1919) lived in the difficult period between two revolutions in Hungary, but nevertheless he achieved revolutionary results in two fields of science: capillarity (1875–1886) and gravity (after 1886). This paper describes his famous capillary equation published in 1886 in the world-language of the time (German) and in one of the most famous scientific journals of the time (Annalen der Physik und Chemie). In his paper he showed a simple equation for the temperature dependence of surface tension of one-component liquids and more importantly he showed that this quantity approaches zero as temperature tends towards the critical temperature. This result was achieved by measuring the surface tension of 160 (!) different liquids along their boiling lines as function of temperature, in a home-made high-pressure high-temperature equipment, probably the first one of this kind. In this way he extended the meaning of the critical point previously introduced by van der Waals. In this paper, also a modern model of surface tension of one-component liquids is discussed, simplified and compared to the Eötvös equation. It is also shown, how the Avogadro number and the molecular sizes can be determined from the experimental results of Eötvös (note: the Avogadro number was estimated with reasonable accuracy for the first time by Einstein in 1905 from the kinetic theory of liquids). Apparently, it was not that easy to do back in 1886: this becomes obvious from the 1911-paper by Einstein, who gave a wrong estimate for the diameter of Hg atoms (5.19 nm) using the data of Eötvös (the correct value is around 0.3 nm). The Appendix to this paper contains the summary of 1543 handwritten pages on surface tension by Eötvös, including the on-line availability of all pdf files. Note also, that Eötvös used g = 10.0 m/s² for acceleration due gravity and so he over-estimated his surface tension values and also his Eötvös constant by about 2.0%. The corrected Eötvös constant using his measured values but the correct g-value would be “0.222” vs his published value of “0.227”. Probably this uncertainty in the value of g was one of the motives that pushed Eötvös to study gravity after 1886.