Advances in Colloid and Interface Science最新文献

Functional foods or drugs based on probiotics have gained unprecedented attention and development due to the increasingly clear relationship between probiotics and human health. Probiotics can regulate intestinal microbiota, dynamically participating in various physiological activities to directly affect human health. Some probiotic-based functional preparations have shown great potential in treating multiple refractory diseases. Currently, the survival and activity of probiotic cells in complex environments in vitro and in vivo have taken priority, and various encapsulation systems based on food-derived materials have been designed and constructed to protect and deliver probiotics. However, traditional encapsulation technology cannot achieve precise protection for a single probiotic, which makes it unable to have a significant effect after release. In this case, single-cell encapsulation systems can be assembled based on biological interfaces to protect and functionalize individual probiotic cells, maximizing their physiological activity. This review discussed the arduous challenges of probiotics in food processing, storage, human digestion, and the commonly used probiotic encapsulation system. Besides, a novel technology of probiotic encapsulation was introduced based on single-cell coating, namely, “armor probiotics”. We focused on the classification, structural design, and functional characteristics of armor coatings, and emphasized the essential functional characteristics of armor probiotics in human health regulation, including regulating intestinal health and targeted bioimaging and treatment of diseased tissues. Subsequently, the benefits, limitations, potential challenges, as well as future direction of armor probiotics were put forward. We hope this review may provide new insights and ideas for developing a single-cell probiotics encapsulating system.

Supported membranes and mixed matrix membranes have a limitation of harming the mass transfer due to the incompatibility between the support layer or the matrix and the active components of the membrane. Self-standing membranes, which could structurally abandon the support layer, altogether avoid the adverse effect, thus greatly facilitating the transmembrane mass transfer process. However, the abandonment of the support layer also reduces the membrane's mechanical properties and formability. In this review, our emphasis will be on self-standing membranes within the realm of materials and separation engineering. We will explore the materials employed in the fabrication of self-standing membranes, highlighting their ability to simultaneously enhance membrane performance and promote self-standing characteristics. Additionally, we will delve into the diverse techniques utilized for crafting self-standing membranes, encompassing interfacial polymerization, filtration, solvent casting, Langmuir-Blodgett & layer-by-layer assembly, electrospinning, compression, etc. Throughout the discussion, the merits and drawbacks associated with each of these preparation methods were elucidated. We also provide a brief overview of the applications of self-standing membranes, including water purification, gas separation, organic solvent nanofiltration, electrochemistry, and membrane reactor, as well as a brief description of the general strategies for performance enhancement of self-standing membranes. Finally, the current status of self-standing membranes and the challenges they may encounter were discussed.

Photonic crystals (PCs) play an increasingly significant role in anti-counterfeiting, sensors, displays, and other fields due to their tunable structural colors produced by light manipulation of photonic stop bands. Flexible self-supporting photonic crystals (FSPCs) eliminate the requirement for conventional structures to rely on the existence of hard substrates, as well as the problem of poor mechanical qualities caused by the stiffness of the building blocks. Meanwhile, diverse production techniques and materials provide FSPCs with varied stimulus-responsive color-changing capacities, thus they have received an abundance of focus. This review summarizes the preparation strategies and variable structural colors of FSPCs. First, a series of preparation strategies by integrating polymers with PCs are summarized, including assembly of colloidal spheres on flexible substrates, polymer packaging, polymer-based direct assembly, nanoimprinting, and 3D printing. Subsequently, variable structural colors of FSPCs with different stimulations, such as viewing angle, chemical stimulation (solvents, ions, pH, biomolecules, etc.), temperature, mechanical/magnetic stress, and light, are described in detail. Finally, the outlook and challenges regarding FSPCs are presented, and several potential directions for their fabrication and application are discussed. It's believed that FSPCs will be a valuable platform for advancing the practical implementation of optical metamaterials.

Metal-organic frameworks (MOFs) and MXenes have gained prominence in the queue of advanced material research. Both materials' outstanding physical and chemical characteristics prominently promote their utilization in diverse fields, especially the electrochemical energy storage (EES) domain. The collective contribution of extremely high specific surface area (SSA), customizable pores, and abundant active sites propose MOFs as integral materials for EES devices. However, conventional MOFs endure low conductivity, constraining their utility in practical applications. The development of hybrid materials via integrating MOFs with various conductive materials stands out as an effective approach to improvising MOF's conductivity. MXenes, formulated as two-dimensional (2D) carbides and nitrides of transition metals, fall in the category of the latest 2D materials. MXenes possess extensive structural diversity, impressive conductivity, and rich surface chemical characteristics. The electrochemical characteristics of MOF@MXene hybrids outperform MOFs and MXenes individually, credited to the synergistic effect of both components. Additionally, the MOF derivatives coupled with MXene, exhibiting unique morphologies, demonstrate outstanding electrochemical performance. The important attributes of MOF@MXene hybrids, including the various synthesis protocols, have been summarized in this review. This review delves into the architectural analysis of both MOFs and MXenes, along with their advanced hybrids. Furthermore, the comprehensive survey of the latest advancements in MOF@MXene hybrids as electroactive material for supercapacitors (SCs) is the prime objective of this review. The review concludes with an elaborate discussion of the current challenges faced and the future outlooks for optimizing MOF@MXene composites.

The rapid proliferation and infection of bacteria, especially multidrug-resistant bacteria, have become a great threat to global public health. Focusing on the emergence of “super drug-resistant bacteria” caused by the abuse of antibiotics and the insufficient and delayed early diagnosis of bacterial diseases, it is of great research significance to develop new technologies and methods for early targeted detection and treatment of bacterial infection. The exceptional effects of metal nanoparticles based on their unique physical and chemical properties make such systems ideal for the detection and treatment of bacterial infection both in vitro and in vivo. Metal nanoparticles also have admirable clinical application prospects due to their broad antibacterial spectrum, various antibacterial mechanisms and excellent biocompatibility. Herein, we summarized the research progress concerning the mechanism of metal nanoparticles in terms of antibacterial activity together with the detection of bacterial. Representative achievements are selected to illustrate the proof-of-concept in vitro and in vivo applications. Based on these observations, we also give a brief discussion on the current problems and perspective outlook of metal nanoparticles in the diagnosis and treatment of bacterial infection.

Air bubbles are a common occurrence in both natural and industrial settings and are a significant topic in the fields of physics, chemistry, engineering, and medicine. The physical phenomena of the contact between bubbles and submerged solid surfaces, as well as the locomotion behavior of bubbles, are worth exploring. Bubbles are generated in an unbounded liquid environment and rise due to unbalanced external forces. Bubbles of different diameters follow different ascending paths, after which they approach, touch, collide, bounce, and finally adsorb to the solid surface, forming a stable three-phase contact line (TPCL). The bubbles are in an unstable state due to the unbalanced external forces on the solid surface and the effects generated by the two-phase contact surface, resulting in different locomotion behaviors on the solid surface. Studying the formation, transport, aggregation, and rupture behaviors of bubbles on solid surfaces can enable the controllable operation of bubbles. This, in turn, can effectively reduce the loss of mechanical apparatus in agro-industrial production activities and improve corresponding production efficiency. Recent research has shown that the degree of bubble wetting on a solid surface is a crucial factor in the locomotion behavior of bubbles on that surface. This has led to significant progress in the study of bubble wetting, which has in turn greatly advanced our understanding of bubble behavior. Based on this, exploring the manipulation process of the directional motion of bubbles is a promising research direction. The locomotion behavior of bubbles on solid surfaces can be controlled by changing external conditions, leading to the integration of bubble behavior in various scientific and technological fields. Studying the dynamics of bubbles in liquids with infinite boundaries is worthwhile. Additionally, the manipulation process and mode of these bubbles is a popular research direction.

Skin has strong self-regenerative capacity, while severe skin defects do not heal without appropriate treatment. Therefore, in order to cover the wound sites and hasten the healing process, wound dressings are required. Hydrogels have emerged as one of the most promising candidates for wound dressings because of their hydrated and porous molecular structure. Chitosan (CS) with biocompatibility, oxygen permeability, hemostatic and antimicrobial properties is beneficial for wound treatment and it can generate self-healing hydrogels through reversible crosslinks, from dynamic covalent bonding, such as Schiff base bonds, boronate esters, and acylhydrazone bonds, to physical interactions like hydrogen bonding, electrostatic interaction, ionic bonding, metal-coordination, host–guest interactions, and hydrophobic interaction. Therefore, various chitosan-based self-healing hydrogel dressings have been prepared in recent years to cope with increasingly complex wound conditions. This review's objective is to provide comprehensive information on the self-healing mechanism of chitosan-based hydrogel wound dressings, discuss their advanced functions including antibacterial, conductive, anti-inflammatory, anti-oxidant, stimulus-responsive, hemostatic/adhesive and controlled release properties, further introduce their applications in the promotion of wound healing in two categories: acute and chronic (infected, burn and diabetic) wounds, and finally discuss the future perspective of chitosan-based self-healing hydrogel dressings for wound healing.

MXenes belong to one of the recently developed advanced materials with tremendous potential for diverse sensing applications. To date, various types of MXene-based materials have been developed to generate direct/indirect ultrasensitive sensing signals against various forms of analytes via fluorescence quenching or enhancement. In this work, the fluorescence sensing/biosensing capabilities of the MXene-based materials have been explored and evaluated against a list of ionic/emerging pollutants in environment and food matrices. The suitability of an MXene-based sensing approach is also validated through the assessment of the performance based on the basic quality assurance parameters, e.g., limit of detection (LOD), sensing range, and response time. Accordingly, the best performing MXene-based materials are selected and recommended for the given target(s) to help facilitate their scalable applications under real-world conditions.

The growing field of nanotechnology has witnessed numerous advancements over the past few years, particularly in the development of engineered nanoparticles. Compared with bulk materials, metal nanoparticles possess more favorable properties, such as increased chemical activity and toxicity, owing to their smaller size and larger surface area. Metal nanoparticles exhibit exceptional stability, specificity, sensitivity, and effectiveness, making them highly useful in the biomedical field. Metal nanoparticles are in high demand in biomedical nanotechnology, including Au, Ag, Pt, Cu, Zn, Co, Gd, Eu, and Er. These particles exhibit excellent physicochemical properties, including amenable functionalization, non-corrosiveness, and varying optical and electronic properties based on their size and shape. Metal nanoparticles can be modified with different targeting agents such as antibodies, liposomes, transferrin, folic acid, and carbohydrates. Thus, metal nanoparticles hold great promise for various biomedical applications such as photoacoustic imaging, magnetic resonance imaging, computed tomography (CT), photothermal, and photodynamic therapy (PDT). Despite their potential, safety considerations, and regulatory hurdles must be addressed for safe clinical applications. This review highlights advancements in metal nanoparticle surface engineering and explores their integration with emerging technologies such as bioimaging, cancer therapeutics and nanomedicine. By offering valuable insights, this comprehensive review offers a deep understanding of the potential of metal nanoparticles in biomedical research.

Light-driven heterogeneous processes are promising approaches for diagnosing and treating Alzheimer's disease (AD) by regulating its relevant biomolecules. The molecular understanding of the heterogeneous interface environment and its interaction with target biomolecules is important. This review critically appraises the advances in AD early diagnosis and therapy employing heterogeneous light-driven redox processes, encompassing photoelectrochemical (PEC) biosensing, photodynamic therapy, photothermal therapy, PEC therapy, and photoacoustic therapy. The design strategies for heterogeneous interfaces based on target biomolecules and applications are also compiled. Finally, the remaining challenges and future perspectives are discussed. The present review may promote the fundamental understanding of AD diagnosis and therapy and facilitate interdisciplinary studies at the junction of nanotechnology and bioscience.