Advances in Colloid and Interface Science最新文献_第3页

Composites of hydroxyapatite and their application in adsorption, medicine and as catalysts 羟基磷灰石复合材料及其在吸附、医药和催化剂方面的应用

IF 15.9 1区化学 Q1 CHEMISTRY, PHYSICAL

Advances in Colloid and Interface Science

Pub Date : 2024-10-10 DOI: 10.1016/j.cis.2024.103308

Adrianna Biedrzycka, Ewa Skwarek

Composites of hydroxyapatite, recognized by its peculiar crystal architecture and distinctive attributes showcased the potential in adsorbing heavy metal ions and radioactive elements as well as selected organic substances. In this paper, the intrinsic mechanism of adsorption by composites hydroxyapatite was proved for the first time. Subsequently, selectivity and competitiveness of composites of hydroxyapatite for a variety of environments containing various interferences from cations, anions, and organic molecules are elucidated. Next, composites of hydroxyapatite were further categorized according to their morphological dimensions. Adsorption properties and intrinsic mechanisms were investigated based on different morphologies. It was shown that although composites of hydroxyapatite were characterized by excellent adsorption capacity and cost-effectiveness, their application is often challenging due to inherent fragility and agglomeration, technical problems required for their handling as well as difficulty in recycling. Finally, to address these issues, the paper discusses the tendency of hydroxyapatite composites to adsorb heavy metal ions and radioactive elements as well as the limitations of their applications. Summarizing the limitations and future directions of modification of HAP in the field of heavy metal ions and different substances contamination abatement, the paper provides insightful perspectives for its gradual improvement and rational application.

羟基磷灰石复合材料因其奇特的晶体结构和独特的属性，在吸附重金属离子、放射性元素和特定有机物方面具有巨大潜力。本文首次证明了羟基磷灰石复合材料的内在吸附机理。随后，阐明了羟基磷灰石复合材料对各种含有阳离子、阴离子和有机分子干扰的环境的选择性和竞争性。接下来，根据羟基磷灰石复合材料的形态尺寸对其进行了进一步分类。根据不同的形态研究了吸附特性和内在机制。研究表明，尽管羟基磷灰石复合材料具有出色的吸附能力和成本效益，但由于其固有的脆弱性和团聚性、处理所需的技术问题以及回收困难，其应用往往具有挑战性。最后，针对这些问题，本文讨论了羟基磷灰石复合材料吸附重金属离子和放射性元素的趋势及其应用的局限性。本文总结了羟基磷灰石复合材料在重金属离子和不同物质污染消减领域的局限性和未来改性方向，为其逐步完善和合理应用提供了深刻的视角。

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引用次数: 0

Breaking barriers in electrodeposition: Novel eco-friendly approach based on utilization of deep eutectic solvents 打破电沉积障碍：基于利用深共晶溶剂的新型环保方法。

IF 15.9 1区化学 Q1 CHEMISTRY, PHYSICAL

Advances in Colloid and Interface Science

Pub Date : 2024-10-09 DOI: 10.1016/j.cis.2024.103310

A. Kityk , V. Pavlik , M. Hnatko

This review article provides a comprehensive examination of the innovative approaches emerging from using deep eutectic solvents (DESs) in electrodeposition techniques. Through an in-depth exploration of fundamental principles, the study highlights the advantages of DESs as electrolytes, including reduced toxicity, enhanced control over deposition parameters, and specific influences on morphology. By showcasing specific studies and experimental findings, the article offers tangible evidence of the superior performance of DES-based electrodeposition methods. Key findings reveal that DESs utilization enables eco-friendly electrodeposition of noble metal and transition metal coatings, coatings of their alloys and composites, as well as electrodeposition of semiconductor and photovoltaic alloy coatings; while also addressing challenges such as hydrogen evolution in conventional electrolytes. Notably, DES-based electrolytes facilitate the formation of electrodeposits with unique nanostructures and improve the stability of colloidal systems for composite coatings. The article contains invaluable tables detailing electrolyte compositions, electrodeposition conditions, and deposition results for a diverse array of metals, alloys, and composites, serving as a practical handbook for researchers and industry practitioners. In conclusion, the review underscores the transformative impact of DESs on electrodeposition techniques and emphasizes the prospects for future advancements in surface modification and material synthesis.

这篇综述文章全面探讨了在电沉积技术中使用深共晶溶剂 (DES) 的创新方法。通过对基本原理的深入探讨，该研究强调了 DESs 作为电解质的优势，包括降低毒性、增强对沉积参数的控制以及对形态的特定影响。通过展示具体的研究和实验结果，文章提供了基于 DES 的电沉积方法性能优越的具体证据。主要研究结果表明，利用 DES 可以实现贵金属和过渡金属镀层、其合金和复合材料镀层的环保型电沉积，以及半导体和光伏合金镀层的电沉积；同时还能解决传统电解质中的氢演化等难题。值得注意的是，基于 DES 的电解质有助于形成具有独特纳米结构的电沉积物，并提高了用于复合涂层的胶体系统的稳定性。文章包含宝贵的表格，详细介绍了各种金属、合金和复合材料的电解质成分、电沉积条件和沉积结果，是研究人员和行业从业人员的实用手册。总之，这篇综述强调了 DES 对电沉积技术的变革性影响，并强调了未来在表面改性和材料合成方面的发展前景。

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引用次数: 0

Surface freezing of cationic surfactant-adsorbed films at the oil-water interface: Impact on oil-in-water emulsion and pickering emulsion stability 阳离子表面活性剂吸附膜在油水界面的表面冻结：对水包油乳液和酸洗乳液稳定性的影响。

IF 15.9 1区化学 Q1 CHEMISTRY, PHYSICAL

Advances in Colloid and Interface Science

Pub Date : 2024-10-09 DOI: 10.1016/j.cis.2024.103309

Hiroki Matsubara , Yuhei Tokiwa , Akihiro Masunaga , Hiromu Sakamoto , Kazuki Shishida , Kouki Ohshima , Albert Prause , Michael Gradzielski

When n-alkanes or n-alcohols coexist with surfactants that have similar chain lengths, they can form mixed surface-frozen films at the oil-water interface. In this review, we first explain the basic characteristics of this surface freezing transition mainly from a thermodynamic viewpoint. Then, we discussed the effect of surface freezing of a cationic surfactant (cetyltrimethylammonium chloride: CTAC) with tetradecane, hexadecane, or hexadecanol on the kinetic stability of the oil-in-water (O/W) emulsions. We show that the surface frozen film not only increases the kinetic stability of the O/W emulsions but also stably encapsulates coexisting organic molecules in the oil core. Finally, we will introduce one of our recent works in which we observed that the exchange between silica nanoparticles and CTAC molecules occurs at the surface of Pickering emulsions when the oil-water interfacial tension is lowered by the surface freezing. The resulting detachment of silica particles from the oil-water interface broke the Pickering emulsion. The advantages of controlling the stability of O/W emulsions via the use of surface-frozen film are discussed in comparison with normal surfactant emulsifiers in the conclusion part of the review.

当正构烷烃或正构醇与具有相似链长的表面活性剂共存时，它们会在油水界面形成混合表面冻结膜。在这篇综述中，我们首先主要从热力学角度解释了这种表面冻结转变的基本特征。然后，我们讨论了阳离子表面活性剂（十六烷基三甲基氯化铵：CTAC）与十四烷、十六烷或十六醇表面冻结对水包油（O/W）乳液动力学稳定性的影响。我们的研究表明，表面冷冻膜不仅能提高水包油型乳液的动力学稳定性，还能将共存的有机分子稳定地包裹在油芯中。最后，我们将介绍我们的一项最新研究成果，其中我们观察到，当表面冷冻降低油水界面张力时，硅纳米颗粒和 CTAC 分子之间的交换会在皮克林乳液表面发生。二氧化硅颗粒由此脱离油水界面，从而破坏了皮克林乳液。本综述的结论部分讨论了与普通表面活性剂乳化剂相比，通过使用表面冻结膜来控制 O/W 型乳液稳定性的优势。

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引用次数: 0

Preparation strategies, properties highlights, and emerging applications across environmental, biological, and energy industries of silver-loaded graphitic carbon nitride: A critical review 载银氮化石墨碳的制备策略、特性亮点以及在环境、生物和能源行业的新兴应用：重要综述

IF 15.9 1区化学 Q1 CHEMISTRY, PHYSICAL

Advances in Colloid and Interface Science

Pub Date : 2024-10-05 DOI: 10.1016/j.cis.2024.103307

Che Quang Cong , Le Minh Huong , Nguyen Minh Dat , Nguyen Thanh Hoai Nam , Hoang An , Nguyen Duy Hai , Nguyen Hung Vu , Nguyen Huu Hieu

In light of escalating environmental pollution and tremendous energy shortage, the development of multifunctional materials with diverse applications across biomedical and energy production platforms has become imperative. Among this domain, nanostructured heterogeneous composites based on semiconductors are exclusively promising owing to their distinct configurations. Notably, graphitic carbon nitride (g-C₃N₄ (CN)) has drawn substantial interest as a sustainable candidate with surface functionality, electron-rich nature, and interconnected conjugation system along the polymeric matrix. To address the remaining limitations in sub-optimal visible light absorption and rapid charge recombination, the decoration of plasmonic metals, particularly silver (Ag) nanostructures, on bare CN has been reported to induce considerable synergistic promotions. This review highlights the major advancements and challenges in designing silver-loaded graphitic carbon nitride (Ag/CN (ACN)). Fundamentals in typical synthetic strategies, such as hydrothermal, co-precipitation, or chemical reduction, for ACN heterostructures are summarized. The appearance of Ag also influences the inherent properties of CN, as emphasized through alterations in structural as well as electronic behaviors in many studies. We expect that this study can deepen insights into multiple extending applications of ACN regarding environmental, biological, and energy industries, thanks to its favorable well-rounded attributions.

鉴于日益严重的环境污染和巨大的能源短缺，开发在生物医学和能源生产平台上具有多种应用的多功能材料已势在必行。在这一领域中，基于半导体的纳米结构异质复合材料因其独特的构造而独具前景。值得注意的是，石墨氮化碳（g-C3N4 (CN)）作为一种可持续的候选材料，因其表面功能性、富电子性以及与聚合物基体相互连接的共轭体系而备受关注。为了解决剩余的次优可见光吸收和快速电荷重组限制，有报道称在裸 CN 上装饰等离子金属，特别是银（Ag）纳米结构，可产生相当大的协同促进作用。本综述重点介绍设计银载氮化石墨碳（Ag/CN (ACN)）的主要进展和挑战。综述了水热法、共沉淀法或化学还原法等 ACN 异质结构典型合成策略的基本原理。银的出现也会影响氯化萘的固有特性，这在许多研究中通过结构和电子行为的改变得到了强调。我们希望这项研究能加深人们对 ACN 在环境、生物和能源行业的多种扩展应用的了解，这要归功于其良好的全面属性。

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引用次数: 0

Recent advancements in bioadhesive self-healing hydrogels for effective chronic wound care 用于有效慢性伤口护理的生物粘性自愈合水凝胶的最新进展。

IF 15.9 1区化学 Q1 CHEMISTRY, PHYSICAL

Advances in Colloid and Interface Science

Pub Date : 2024-10-05 DOI: 10.1016/j.cis.2024.103306

Parinaz Nezhad-Mokhtari , Masoud Hasany , Mohammad Kohestanian , Alireza Dolatshahi-Pirouz , Morteza Milani , Mehdi Mehrali

Chronic wounds are a critical and costly complication that affects millions of patients each year, especially patients suffering from diabetes, and constitute a serious global healthcare problem that needs immediate attention. In this direction, novel dressings that can integrate appropriate physicochemical and biological features, mechanical durability, and the capacity for therapy are of great clinical importance. For instance, self-healable hydrogels, with antibacterial activity and high tissue adhesion, have attracted increasing attention for wound management applications. Despite their potential, existing self-healable hydrogel networks exhibit limitations in mechanical strength and adhesion, tissue regeneration, antibacterial efficacy, and scalability, indicating a need for further improvement in the field. This review focuses on exactly these recent advances in the field with a special focus on self-healing adhesive hydrogel-based wound dressings as well as their structures, construction strategies, adhesion mechanisms, and emerging usage in the wound healing field. By shedding light on these developments, we aim to contribute to the ongoing pursuit of enhanced solutions for chronic wound care.

慢性伤口是一种严重而昂贵的并发症，每年影响着数百万患者，尤其是糖尿病患者，是一个需要立即关注的严重的全球医疗保健问题。在这方面，能将适当的物理化学和生物特性、机械耐久性和治疗能力融为一体的新型敷料具有重要的临床意义。例如，具有抗菌活性和高组织粘附性的自愈合水凝胶在伤口管理方面的应用已引起越来越多的关注。尽管具有潜力，但现有的自愈合水凝胶网络在机械强度和粘附性、组织再生、抗菌功效和可扩展性等方面都存在局限性，表明该领域需要进一步改进。本综述的重点正是该领域的最新进展，尤其关注基于自愈合粘合剂的水凝胶伤口敷料及其结构、构造策略、粘合机制和在伤口愈合领域的新兴应用。通过揭示这些发展，我们希望为不断追求更佳的慢性伤口护理解决方案做出贡献。

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引用次数: 0

Droplet evaporation on super liquid-repellent surfaces: A controllable approach for supraparticle fabrication 超级憎液表面上的液滴蒸发：超微粒制造的可控方法。

IF 15.9 1区化学 Q1 CHEMISTRY, PHYSICAL

Advances in Colloid and Interface Science

Pub Date : 2024-09-30 DOI: 10.1016/j.cis.2024.103305

Xiaojing Wang , Yuechang Lian , Siyuan Xiang , Shengyang Tao , Michael Kappl , Wendong Liu

Supraparticles are agglomerates of nano- and/or microparticles with sizes ranging from tens to hundreds of microns, making them more accessible for handling and recovery than the building blocks. Supraparticles not only inherit the properties and functions of primary particles but also exhibit characteristics such as high porosity, large specific surface area, and improved functionalities, which can be attributed to the synergism, coupling, and co-localization among the constituents. Therefore, supraparticles hold promising applications in catalysis, drug delivery, sensing, etc. Among the various synthesizing strategies, evaporating droplets on a liquid-repellent surface is proposed as an effective approach to fabricate supraparticles with unique structural features and functions. The boundary conditions of such droplet-confinement methods significantly drive the formation of supraparticles by reducing or avoiding the use of solvents or processing liquids, which further accelerates the development and utilization of supraparticles. This paper presents an overview of recent developments in the fabrication of supraparticles by evaporating droplets on liquid-repellent surfaces. The review focuses on the evaporation processes on lubricant and superhydrophobic surfaces, structural regulation, and applications of supraparticles. Finally, an outlook on the future directions of evaporation on liquid-repellent surfaces mediated supraparticle fabrication is presented.

超微粒子是纳米和/或微米粒子的团聚体，其大小从几十微米到几百微米不等，与构件相比，更易于处理和回收。超微粒子不仅继承了原生粒子的特性和功能，而且还表现出高孔隙率、大比表面积和更好的功能等特性，这些特性可归因于各成分之间的协同、耦合和共定位。因此，超微粒在催化、药物输送、传感等领域具有广阔的应用前景。在各种合成策略中，在憎液表面蒸发液滴被认为是制造具有独特结构特征和功能的超微粒的有效方法。通过减少或避免使用溶剂或加工液，这种液滴凝聚方法的边界条件极大地推动了超微粒的形成，从而进一步加快了超微粒的开发和利用。本文概述了通过在憎液表面蒸发液滴来制造超微粒的最新进展。综述的重点是润滑剂和超疏水表面的蒸发过程、结构调节以及超级微粒的应用。最后，展望了憎液表面蒸发介导超微粒制造的未来发展方向。

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引用次数: 0

Recent advances and applications of stimuli-responsive nanomaterials for water treatment: A comprehensive review 用于水处理的刺激响应纳米材料的最新进展和应用：综述

IF 15.9 1区化学 Q1 CHEMISTRY, PHYSICAL

Advances in Colloid and Interface Science

Pub Date : 2024-09-26 DOI: 10.1016/j.cis.2024.103304

Iman Salahshoori , Amirhosein Yazdanbakhsh , Majid Namayandeh Jorabchi , Fatemeh Zare Kazemabadi , Hossein Ali Khonakdar , Amir H. Mohammadi

The development of stimuli-responsive nanomaterials holds immense promise for enhancing the efficiency and effectiveness of water treatment processes. These smart materials exhibit a remarkable ability to respond to specific external stimuli, such as light, pH, or magnetic fields, and trigger the controlled release of encapsulated pollutants. By precisely regulating the release kinetics, these nanomaterials can effectively target and eliminate contaminants without compromising the integrity of the water system. This review article provides a comprehensive overview of the advancements in light-activated and pH-sensitive nanomaterials for controlled pollutant release in water treatment. It delves into the fundamental principles underlying these materials' stimuli-responsive behaviour, exploring the design strategies and applications in various water treatment scenarios. In particular, the article indicates how integrating stimuli-responsive nanomaterials into existing water treatment technologies can significantly enhance their performance, leading to more sustainable and cost-effective solutions. The synergy between these advanced materials and traditional treatment methods could pave the way for innovative approaches to water purification, offering enhanced selectivity and efficiency. Furthermore, the review highlights the critical challenges and future directions in this rapidly evolving field, emphasizing the need for further research and development to fully realize the potential of these materials in addressing the pressing challenges of water purification.

刺激响应型纳米材料的开发为提高水处理工艺的效率和效果带来了巨大希望。这些智能材料能够对特定的外部刺激（如光、pH 值或磁场）做出反应，并触发封装污染物的受控释放。通过精确调节释放动力学，这些纳米材料可以在不损害水系统完整性的情况下有效地锁定和消除污染物。这篇综述文章全面概述了用于水处理中污染物可控释放的光活化和 pH 值敏感纳米材料的研究进展。文章深入探讨了这些材料刺激响应行为的基本原理，探讨了各种水处理方案的设计策略和应用。文章特别指出，将刺激响应纳米材料集成到现有的水处理技术中，可以显著提高这些技术的性能，从而提供更具可持续性和成本效益的解决方案。这些先进材料与传统处理方法之间的协同作用可为水净化的创新方法铺平道路，提供更高的选择性和效率。此外，综述还强调了这一快速发展领域的关键挑战和未来方向，强调需要进一步研究和开发，以充分发挥这些材料在应对水净化紧迫挑战方面的潜力。

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引用次数: 0

Advancements in ionic liquid-based corrosion inhibitors for sustainable protection strategies: from experimental to computational insights 离子液体型缓蚀剂在可持续保护战略方面的进展：从实验到计算的见解

IF 15.9 1区化学 Q1 CHEMISTRY, PHYSICAL

Advances in Colloid and Interface Science

Pub Date : 2024-09-17 DOI: 10.1016/j.cis.2024.103303

Pankaj Kumar , Krister Holmberg , Isha Soni , Nasarul Islam , Manish Kumar , Pooja Shandilya , Mika Sillanpää , Vinay Chauhan

The global corrosion cost is estimated to be around 2.5 trillion USD, which is more than 3 % of the global GDP. Against this background, large efforts have been made to find effective corrosion inhibitors. Ionic liquids (ILs) are nowadays regarded as reliable functional materials and one of the most promising classes of anticorrosion agents. Not only are they efficient in preventing corrosion of iron and other metals, but they are also relatively inexpensive, need no solvents, and are non-toxic to humans This review addresses both experimental and theoretical investigations conducted to IL-based corrosion inhibitors (CIs). It covers various ILs used, synthesis methods, and their performance in diverse corrosive environments. Electrochemical techniques like EIS and potentiodynamic polarization, along with computational approaches including quantum chemical calculations and DFT, provide valuable insights into corrosion inhibition mechanisms and the interactions between anticorrosion agents-surfaces. The synergistic combination of experimental and theoretical approaches enhances our understanding of corrosion inhibition, enabling the design and optimization of effective and sustainable corrosion protection strategies. This review consolidates the existing knowledge on ionic liquid-based corrosion inhibitors, highlights the key findings from both experimental and theoretical investigations, and points out possible directions for further studies in this area.

据估计，全球腐蚀成本约为 2.5 万亿美元，超过全球 GDP 的 3%。在此背景下，人们一直在努力寻找有效的缓蚀剂。离子液体（IL）如今被视为可靠的功能材料和最有前途的防腐剂之一。它们不仅能有效防止铁和其他金属的腐蚀，而且价格相对低廉，不需要溶剂，对人体无毒本综述涉及对基于离子液体的腐蚀抑制剂（CIs）进行的实验和理论研究。它涵盖了所使用的各种 IL、合成方法及其在各种腐蚀环境中的性能。EIS 和电位极化等电化学技术以及量子化学计算和 DFT 等计算方法为了解缓蚀机理以及防腐剂与表面之间的相互作用提供了宝贵的见解。实验方法和理论方法的协同结合增强了我们对缓蚀的理解，有助于设计和优化有效、可持续的腐蚀防护策略。本综述整合了有关离子液体型缓蚀剂的现有知识，重点介绍了实验和理论研究的主要发现，并指出了该领域进一步研究的可能方向。

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引用次数: 0

A review of ion scattering spectroscopy studies at liquid interfaces with noble gas ion projectiles 惰性气体离子射弹在液体界面上的离子散射光谱研究综述

IF 15.9 1区化学 Q1 CHEMISTRY, PHYSICAL

Advances in Colloid and Interface Science

Pub Date : 2024-09-10 DOI: 10.1016/j.cis.2024.103302

Anand Kumar , Gunther G. Andersson

Ion scattering spectroscopy (ISS) is an analytical tool that provides direct structural, topographical, and atomic compositional information at interfaces when ions are used as projectiles. Since its development in 1967, ISS is commonly used to obtain quantitative information about solid interfaces. Over the last couple of decades, ISS has emerged as an important technique to probe liquid interfaces and their studies employing ISS has become not uncommon, more so with Neutral impact collision ion scattering spectroscopy (NICISS). Therefore, here the principle of ISS with a particular focus on NICISS and its data evaluation are summarised while reviewing some important studies at vapor-liquid interfaces that provide direct information for molecular orientation of liquids (including ionic liquids), composition and distribution of atoms (or solutes) and charges as a function of depth to gain vast variety of thermodynamical information. Employing ISS such information can be achieved with high depth resolution of ∼1–2 Å (depending on the nature of the experiment). These examples highlight the significance of ISS and show potential for its application for studies related to specific ion effects, atmospheric reaction in aerosol and sea water droplets, and even determining the fate of environmental pollutants like heavy metal ions and per-fluoroalkyl substances (PFAS). Furthermore, some limitations of ISS are also discussed relating to investigation of high-vapor pressure liquids and probing buried interfaces like liquid-liquid interfaces while presenting progresses made in probing solid-liquid interfaces.

离子散射光谱法（ISS）是一种分析工具，当离子被用作射弹时，它能直接提供界面的结构、地形和原子成分信息。自 1967 年开发以来，离子散射光谱通常用于获取固体界面的定量信息。在过去的几十年中，ISS 已成为探测液体界面的重要技术，利用 ISS 对其进行研究的情况并不少见，中性撞击碰撞离子散射光谱（NICISS）更是如此。因此，本文总结了 ISS 的原理，重点介绍了 NICISS 及其数据评估，同时回顾了一些重要的汽液界面研究，这些研究为液体（包括离子液体）的分子取向、原子（或溶质）的组成和分布以及电荷随深度的变化提供了直接信息，从而获得了大量热力学信息。利用 ISS 可以获得 1-2 Å 的高深度分辨率（取决于实验的性质）。这些例子凸显了 ISS 的重要性，并显示了其在与特定离子效应、气溶胶和海水液滴中的大气反应，甚至确定重金属离子和全氟烷基物质 (PFAS) 等环境污染物归宿相关的研究中的应用潜力。此外，还讨论了 ISS 在研究高蒸汽压液体和探测液-液界面等埋藏界面方面的一些局限性，同时介绍了在探测固-液界面方面取得的进展。

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引用次数: 0

Phenylboronic acid-functionalized biomaterials for improved cancer immunotherapy via sialic acid targeting 苯硼酸功能化生物材料通过硅唾液酸靶向改善癌症免疫疗法

IF 15.9 1区化学 Q1 CHEMISTRY, PHYSICAL

Advances in Colloid and Interface Science

Pub Date : 2024-09-06 DOI: 10.1016/j.cis.2024.103301

Ashok Kumar Jangid, Kyobum Kim

Phenylboronic acid (PBA) is recognized as one of the most promising cancer cell binding modules attributed to its potential to form reversible and dynamic boronic ester covalent bonds. Exploring the advanced chemical versatility of PBA is crucial for developing new anticancer therapeutics. The presence of a specific Lewis acidic boron atom-based functional group and a Π-ring-connected ring has garnered increasing interest in the field of cancer immunotherapy. PBA-derivatized functional biomaterials can form reversible bonds with diols containing cell surface markers and proteins. This review primarily focuses on the following topics: (1) the importance and versatility of PBA, (2) different PBA derivatives with pKa values, (3) specific key features of PBA-mediated biomaterials, and (4) cell surface activity for cancer immunotherapy applications. Specific key features of PBA-mediated materials, including sensing, bioadhesion, and gelation, along with important synthesis strategies, are highlighted. The utilization of PBA-mediated biomaterials for cancer immunotherapy, especially the role of PBA-based nanoparticles and PBA-mediated cell-based therapeutics, is also discussed. Finally, a perspective on future research based on PBA-biomaterials for immunotherapy applications is presented.

苯硼酸（PBA）具有形成可逆动态硼酸酯共价键的潜力，因此被认为是最有前途的癌细胞结合模块之一。探索 PBA 的高级化学多功能性对于开发新的抗癌疗法至关重要。基于硼原子的特定路易斯酸官能团和Π-环连接环的存在在癌症免疫疗法领域引起了越来越多的兴趣。PBA 衍生功能生物材料可与含有细胞表面标记物和蛋白质的二元醇形成可逆键。本综述主要关注以下主题：(1) PBA 的重要性和多功能性，(2) 不同 PBA 衍生物的 pKa 值，(3) PBA 介导的生物材料的具体关键特征，以及 (4) 用于癌症免疫疗法的细胞表面活性。重点介绍了 PBA 介导材料的具体关键特征，包括传感、生物粘附和凝胶化，以及重要的合成策略。此外，还讨论了将 PBA 介导的生物材料用于癌症免疫疗法的问题，特别是基于 PBA 的纳米粒子和 PBA 介导的细胞疗法的作用。最后，展望了基于 PBA 生物材料的免疫疗法应用的未来研究。

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引用次数: 0