首页 > 最新文献

Proceedings of the 1st International MIPAnet Conference on Science and Mathematics最新文献

英文 中文
Characterization of Physical Properties and Morphological Ruberized Asphalt Paving Blocks based on Bituminous Coal and Concentrated Natural Rubber Latex 以烟煤和天然浓缩胶乳为基材的橡胶化沥青路面砌块的物理性能和形态表征
Riri Indah, Nitami Harahap, Darwin Yunus Nasution
: This research about the characterization physical properties and morphological ruberized asphalt paving block using asphalt as a binder replacement and utilization of natural resources such as bituminous coal and natural rubber latex concentrate (NRLC). This research aims to determine the optimum value of physical properties and learn the effect of morphological control on the paving block that have been prepared. Morphological control with varied the composition asphalt, bituminous coal, and natural rubber latex concentrate that mixed using by an internal mixer with addition of aggregates and additive agents such as dicumyl peroxide as an initiator and divinylbenzene as a crosslinker. After the mixing process, then the mixture on shaping/forming process. The result of physical properties obtained optimum value at the variation of composition asphalt : bituminous coal : natural rubber latex concentrate (70:25:5)(Paving Block E). The percentage of water absorption is 0.85 % and compressive strenght is 154.23 Kgf (0.605 Mpa). At this optimum variation of composition has been characterized the morphological using by Scanning Electron Microscopy (SEM) which is the result of surface morphology showed the mixture compactly and most effective homogenity of the mixture.
本文研究了以沥青为粘结剂的橡胶沥青路面砌块的表征、物理性能和形态,以及对烟煤和天然胶乳精矿(NRLC)等自然资源的替代和利用。本研究旨在确定物理性能的最佳值,并了解形态控制对已制备的铺装块的影响。形态控制由不同组成的沥青、烟煤和天然胶乳浓缩物通过内部混合器混合使用,并添加集料和添加剂,如过氧化二氨基作为引发剂和二乙烯基苯作为交联剂。混合工艺完成后,再对混合物进行定型/成型工艺。物理性能结果在沥青:烟煤:天然胶乳浓缩物(70:25:5)(铺装块E)配比变化时获得最佳值,吸水率为0.85%,抗压强度为154.23 Kgf (0.605 Mpa)。在这一最佳变化的组成已表征形态学使用扫描电子显微镜(SEM),这是表面形貌的结果显示混合物紧密和最有效的均匀性混合物。
{"title":"Characterization of Physical Properties and Morphological Ruberized Asphalt Paving Blocks based on Bituminous Coal and Concentrated Natural Rubber Latex","authors":"Riri Indah, Nitami Harahap, Darwin Yunus Nasution","doi":"10.5220/0010132700002775","DOIUrl":"https://doi.org/10.5220/0010132700002775","url":null,"abstract":": This research about the characterization physical properties and morphological ruberized asphalt paving block using asphalt as a binder replacement and utilization of natural resources such as bituminous coal and natural rubber latex concentrate (NRLC). This research aims to determine the optimum value of physical properties and learn the effect of morphological control on the paving block that have been prepared. Morphological control with varied the composition asphalt, bituminous coal, and natural rubber latex concentrate that mixed using by an internal mixer with addition of aggregates and additive agents such as dicumyl peroxide as an initiator and divinylbenzene as a crosslinker. After the mixing process, then the mixture on shaping/forming process. The result of physical properties obtained optimum value at the variation of composition asphalt : bituminous coal : natural rubber latex concentrate (70:25:5)(Paving Block E). The percentage of water absorption is 0.85 % and compressive strenght is 154.23 Kgf (0.605 Mpa). At this optimum variation of composition has been characterized the morphological using by Scanning Electron Microscopy (SEM) which is the result of surface morphology showed the mixture compactly and most effective homogenity of the mixture.","PeriodicalId":257157,"journal":{"name":"Proceedings of the 1st International MIPAnet Conference on Science and Mathematics","volume":"49 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126571808","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Anti-fungal Activity Methanolic Extract of Calliandra calothyrsus against Storage Fungi Isolated from Dried-stored Spices calothyrsus甲醇提取物对香料干燥贮藏真菌的抑菌活性研究
K. Nurtjahja, A. Pasaribu
{"title":"Anti-fungal Activity Methanolic Extract of Calliandra calothyrsus against Storage Fungi Isolated from Dried-stored Spices","authors":"K. Nurtjahja, A. Pasaribu","doi":"10.5220/0010612600002775","DOIUrl":"https://doi.org/10.5220/0010612600002775","url":null,"abstract":"","PeriodicalId":257157,"journal":{"name":"Proceedings of the 1st International MIPAnet Conference on Science and Mathematics","volume":"8 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"124506954","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Analysis of Arsenic in Purple cabbage (Brassica oleracea var. Capitata} L) after the Eruption of Mount Sinabung using Atomic Absorption Spectrophotometer 锡纳邦火山爆发后紫甘蓝(Brassica oleracea var. Capitata} L)中砷的原子吸收分光光度法分析
B. Cahyady, .. Suharman, M. Taufik, Z. Alfian, M. Razali, D. Ardilla
: The negative impact after the eruption of Mount Sinabung is the exposure of heavy metals to plants and animals around the mountain. The heavy metal commonly contained in vegetables is Arsenic. Many of the people around Mount Sinabung work as cabbage farmers. Cabbage plants that have many benefits, especially in medicine are purple cabbage ( Brassica oleracea var. Capitata L ). This work aims to analyze the levels of arsenic contained in purple cabbage after the eruption of Mount Sinabung. The sampling technique uses simple random sampling. Sampling was carried out at 5 points of collection which is 50 m from Mount Sinabung. In this work, Dry destruction method was developed using HCl and nitric acid. Instrument Atomic Absorption Spectrophotometers (AAS) equipped with Vapor Hydride Generation Acessories were developed to analyze Arsenic levels. At a wavelength of 193.7 nm, The concentration of arsenic in purple cabbage was obtained at the sampling points 1, 2, 3, 4, and 5 respectively: 0.4755, 0.5808, 0.6534, 0.5517, 0, 5481 mg / Kg. This result is lower than the maximum limit of arsenic contamination in vegetables, which is 1.0 mg / Kg. (SNI No. 7387: 2009).
△锡纳朋火山爆发后的负面影响是对周围植物和动物的重金属暴露。蔬菜中常见的重金属是砷。锡纳朋山附近的许多人都是白菜农。卷心菜植物有很多好处,特别是在医药上是紫甘蓝(芸苔甘蓝var. Capitata L)。此次工作的目的是分析锡纳朋火山爆发后紫白菜中砷的含量。抽样技术使用简单的随机抽样。在距锡纳朋山50米的5个收集点进行了抽样。本文研究了用盐酸和硝酸进行干破坏的方法。研制了配有蒸汽氢化物发生附件的原子吸收分光光度计(AAS)。在193.7 nm波长下,紫色白菜中砷在采样点1、2、3、4、5处的浓度分别为:0.4755、0.5808、0.6534、0.5517、0、5481 mg / Kg。这一结果低于蔬菜中砷污染的最高限量1.0 mg / Kg。(SNI编号7387:2009)。
{"title":"Analysis of Arsenic in Purple cabbage (Brassica oleracea var. Capitata} L) after the Eruption of Mount Sinabung using Atomic Absorption Spectrophotometer","authors":"B. Cahyady, .. Suharman, M. Taufik, Z. Alfian, M. Razali, D. Ardilla","doi":"10.5220/0010614200002775","DOIUrl":"https://doi.org/10.5220/0010614200002775","url":null,"abstract":": The negative impact after the eruption of Mount Sinabung is the exposure of heavy metals to plants and animals around the mountain. The heavy metal commonly contained in vegetables is Arsenic. Many of the people around Mount Sinabung work as cabbage farmers. Cabbage plants that have many benefits, especially in medicine are purple cabbage ( Brassica oleracea var. Capitata L ). This work aims to analyze the levels of arsenic contained in purple cabbage after the eruption of Mount Sinabung. The sampling technique uses simple random sampling. Sampling was carried out at 5 points of collection which is 50 m from Mount Sinabung. In this work, Dry destruction method was developed using HCl and nitric acid. Instrument Atomic Absorption Spectrophotometers (AAS) equipped with Vapor Hydride Generation Acessories were developed to analyze Arsenic levels. At a wavelength of 193.7 nm, The concentration of arsenic in purple cabbage was obtained at the sampling points 1, 2, 3, 4, and 5 respectively: 0.4755, 0.5808, 0.6534, 0.5517, 0, 5481 mg / Kg. This result is lower than the maximum limit of arsenic contamination in vegetables, which is 1.0 mg / Kg. (SNI No. 7387: 2009).","PeriodicalId":257157,"journal":{"name":"Proceedings of the 1st International MIPAnet Conference on Science and Mathematics","volume":"35 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"124509899","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Variation HCl Concentration on Natural Zeolite Dealumination to the Content of Liquid Smoke Compounds by Hydrodeoxygenation Process 天然沸石脱铝过程中HCl浓度变化对加氢脱氧液烟化合物含量的影响
S. Gea, .. Andriayani, A. Haryono, Abdul Malik, Reka Mustika Sari, Junifa Layla Sihombing, Ahmad Nasir Pulungan, Rachmad Fauzi, Boy Attaurrazaq
: Recently, for its direct use as a renewable energy resource of pyrolysis biomass, liquid smoke has received increased attention. Unfornatunately, the composition of liquid smoke is very complex that cause to obvious changes in chemical properties of the liquid smoke. Therefore, the hydrodeoxygenation method required to handle this issue. The Objective of this research was the hydrodeoxygenation of liquid smoke to remove oxygenated compounds with decreased concentration of ketones and increased phenol concentration using sarulla natural zeolite dialuminated with 3M, 5M and 7M HCl concentrations at 90°C in the H 2 atmosphere. Characterization of hydrodeoxygenation product was analyzed content by gas chromatography-mass spectrometry (GC-MS). The results showed a decrease in phenol content and a rise in carbonyl at 7 M HCl dealumination while 5 M HCl dealumination increased phenol content and reduced carbonyl compounds. Treatment with concentration of 5 M HCl results in a better content of liquid smoke.
近年来,液态烟因其作为热解生物质的可再生能源而受到越来越多的关注。不幸的是,液体烟雾的成分非常复杂,导致液体烟雾的化学性质发生了明显的变化。因此,需要采用加氢脱氧法来处理此问题。本研究的目的是在90°C的h2气氛中,利用3M、5M和7M HCl浓度的双铝化天然沸石对液体烟雾进行加氢脱氧,去除酮浓度降低、酚浓度增加的含氧化合物。采用气相色谱-质谱联用技术(GC-MS)分析了加氢脱氧产物的含量。结果表明,7 M HCl脱铝处理后,苯酚含量降低,羰基含量升高,而5 M HCl脱铝处理后,苯酚含量升高,羰基含量降低。用浓度为5 M的HCl处理可使烟液含量提高。
{"title":"Effect of Variation HCl Concentration on Natural Zeolite Dealumination to the Content of Liquid Smoke Compounds by Hydrodeoxygenation Process","authors":"S. Gea, .. Andriayani, A. Haryono, Abdul Malik, Reka Mustika Sari, Junifa Layla Sihombing, Ahmad Nasir Pulungan, Rachmad Fauzi, Boy Attaurrazaq","doi":"10.5220/0010152300002775","DOIUrl":"https://doi.org/10.5220/0010152300002775","url":null,"abstract":": Recently, for its direct use as a renewable energy resource of pyrolysis biomass, liquid smoke has received increased attention. Unfornatunately, the composition of liquid smoke is very complex that cause to obvious changes in chemical properties of the liquid smoke. Therefore, the hydrodeoxygenation method required to handle this issue. The Objective of this research was the hydrodeoxygenation of liquid smoke to remove oxygenated compounds with decreased concentration of ketones and increased phenol concentration using sarulla natural zeolite dialuminated with 3M, 5M and 7M HCl concentrations at 90°C in the H 2 atmosphere. Characterization of hydrodeoxygenation product was analyzed content by gas chromatography-mass spectrometry (GC-MS). The results showed a decrease in phenol content and a rise in carbonyl at 7 M HCl dealumination while 5 M HCl dealumination increased phenol content and reduced carbonyl compounds. Treatment with concentration of 5 M HCl results in a better content of liquid smoke.","PeriodicalId":257157,"journal":{"name":"Proceedings of the 1st International MIPAnet Conference on Science and Mathematics","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"130338337","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Effect of Gambir Adhesive Level and Hot Press Temperature on Physical and Mechanical Properties of Bamboo Particleboard 胶粘剂水平和热压温度对竹刨花板物理力学性能的影响
T. Sucipto, R. Widyorini, T. A. Prayitno, G. Lukmandaru
: Gambir is the extract of leaves sap and young twigs of gambir plants, which contains tannin.Gambir-formaldehyde adhesives have been applied to the particleboards, butsome properties of particleboard produced did not meetthe standard.In this study, gambir adhesives (without formaldehyde) were applied to the bamboo particleboard.The dimension of particleboard was 25x25x1 cm, and the board density target was set at 0.8 g/cm3. Three kinds of adhesive levels (10, 20, 30%) and four kinds of hot-press temperature (160, 180, 200, 220 o C) were used for particleboard production. The research aimed to investigatethe effect of gambir adhesive level and hot-press temperature on the physical and mechanical properties of the bambooparticleboard. The physical and mechanical properties of particleboards were then evaluated and compared to the JIS A5908-2003 standard.The study showed that adhesive level and hot-press temperature affected significantly on thickness swelling, water absorption, internal bond, modulus of rupture and modulus of elasticityof particleboard, while the effect of an adhesive level factor was also significant on density properties.Interaction between adhesive level and hot-press temperature factor only affected significantly on water absorption. Particleboards with hot-press temperatures of 200 o C and 220 o C have better properties than others.The high hot-press temperature has exceeded the melting point of the catechin (174-178 o C), furthermore, the gambir adhesive becomes hardened and cured. The most optimal bamboo particleboard is particleboard with 220 o C hot-press temperature and adhesive level of 30%, based on the best of particleboard properties compared to JIS A5908-2003.
Gambir是Gambir植物的叶液和嫩枝的提取物,含有单宁。甘比甲醛胶粘剂已应用于刨花板,但生产出来的刨花板有些性能不符合标准。本研究将甘山木胶粘剂(无甲醛)应用于竹刨花板。刨花板尺寸为25x25x1 cm,板材密度目标设定为0.8 g/cm3。刨花板生产采用三种胶粘剂水平(10、20、30%)和四种热压温度(160、180、200、220℃)。研究了胶粘剂水平和热压温度对竹刨花板物理力学性能的影响。然后评估刨花板的物理和机械性能,并与JIS A5908-2003标准进行比较。研究表明,胶粘剂水平和热压温度对刨花板的厚度膨胀、吸水率、内粘接、断裂模量和弹性模量有显著影响,胶粘剂水平对密度性能也有显著影响。胶粘剂水平与热压温度因子的交互作用仅对吸水率有显著影响。热压温度为200℃和220℃的刨花板性能较好。高热压温度已经超过儿茶素的熔点(174-178℃),而且冈比尔胶粘剂变得硬化和固化。最佳的竹刨花板是热压温度为220℃,胶粘剂水平为30%的刨花板,以最佳刨花板性能为基础,与JIS A5908-2003进行比较。
{"title":"The Effect of Gambir Adhesive Level and Hot Press Temperature on Physical and Mechanical Properties of Bamboo Particleboard","authors":"T. Sucipto, R. Widyorini, T. A. Prayitno, G. Lukmandaru","doi":"10.5220/0010182800002775","DOIUrl":"https://doi.org/10.5220/0010182800002775","url":null,"abstract":": Gambir is the extract of leaves sap and young twigs of gambir plants, which contains tannin.Gambir-formaldehyde adhesives have been applied to the particleboards, butsome properties of particleboard produced did not meetthe standard.In this study, gambir adhesives (without formaldehyde) were applied to the bamboo particleboard.The dimension of particleboard was 25x25x1 cm, and the board density target was set at 0.8 g/cm3. Three kinds of adhesive levels (10, 20, 30%) and four kinds of hot-press temperature (160, 180, 200, 220 o C) were used for particleboard production. The research aimed to investigatethe effect of gambir adhesive level and hot-press temperature on the physical and mechanical properties of the bambooparticleboard. The physical and mechanical properties of particleboards were then evaluated and compared to the JIS A5908-2003 standard.The study showed that adhesive level and hot-press temperature affected significantly on thickness swelling, water absorption, internal bond, modulus of rupture and modulus of elasticityof particleboard, while the effect of an adhesive level factor was also significant on density properties.Interaction between adhesive level and hot-press temperature factor only affected significantly on water absorption. Particleboards with hot-press temperatures of 200 o C and 220 o C have better properties than others.The high hot-press temperature has exceeded the melting point of the catechin (174-178 o C), furthermore, the gambir adhesive becomes hardened and cured. The most optimal bamboo particleboard is particleboard with 220 o C hot-press temperature and adhesive level of 30%, based on the best of particleboard properties compared to JIS A5908-2003.","PeriodicalId":257157,"journal":{"name":"Proceedings of the 1st International MIPAnet Conference on Science and Mathematics","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"125738428","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Toxigenic and Non-toxigenic Aspergillus Flavus Strains Isolated from Candlenut (Aleurites Moluccana) in North Sumatera 北苏门答腊核桃产毒和非产毒黄曲霉菌株的分离
Ngalo Putri Ginting, K. Nurtjahja
: This study was conducted to investigate contamination of Aspergillus flavus strains in distribution chains of candlenut ( Aleuritaes moluccana ). Dried-stored unshelled candlenut were collected from farmers, collectors and distributors at 3 Ragencies in North Sumatra (Regency of Karo, Deli Serdang and Langkat) during harvest period (February to April 2019). One and half kilogram of candlenut was taken from each of the distribution chains. Kernel moisture content were determined by distillation. Population each of A. flavus strain was enumerated by a dilution method followed by a pour plate in dichloran 18% glycerol agar (DG18) medium. Culture method in agar medium containing 10% coconut milk was used to determine toxigenicity of A. flavus . Their toxigenicity also was determined molecularly using specific primers for amplifying regulatory ( aflR ) and structural genes ( nor-1, ver-1, omt-1 ) that determine aflatoxin biosynthesis. Results showed that moisture content of candlenut kernels at the level of farmers, collectors and distributors in Regency of Karo, Deli Serang and Langkat was above 5%. A total of 38 strains of A. flavus were isolated and 37 of the strains were toxigenic (aflatoxin producers). The average of A. flavus population (cfu/g) on candlenut at farmers was the lowest and the highest population was at distributor chain.
本研究旨在调查黄曲霉菌株在核桃(aleuritae moluccana)销售链中的污染情况。在收获期间(2019年2月至4月),从北苏门答腊岛(卡罗摄政、德里Serdang和兰凯特)的3个机构的农民、收集者和分销商处收集了干燥储存的无壳蜡烛。从每个分销链上拿走了1.5公斤的蜡烛。用蒸馏法测定籽粒含水量。采用稀释法,然后在二氯18%甘油琼脂(DG18)培养基中,用平板进行计数。采用含有10%椰奶的琼脂培养基培养法测定黄曲霉的毒力。利用扩增调控基因(aflR)和决定黄曲霉毒素生物合成的结构基因(nor-1, ver-1, omt-1)的特异引物,对它们的毒性进行了分子测定。结果表明,在Karo县、Deli Serang县和Langkat县,农民、采集者和销售者水平上的核桃仁含水量均在5%以上。共分离到38株黄曲霉,其中37株产毒(产生黄曲霉毒素)。甜饼上黄曲霉平均种群数(cfu/g)在农户处最低,在经销链处最高。
{"title":"Toxigenic and Non-toxigenic Aspergillus Flavus Strains Isolated from Candlenut (Aleurites Moluccana) in North Sumatera","authors":"Ngalo Putri Ginting, K. Nurtjahja","doi":"10.5220/0010613200002775","DOIUrl":"https://doi.org/10.5220/0010613200002775","url":null,"abstract":": This study was conducted to investigate contamination of Aspergillus flavus strains in distribution chains of candlenut ( Aleuritaes moluccana ). Dried-stored unshelled candlenut were collected from farmers, collectors and distributors at 3 Ragencies in North Sumatra (Regency of Karo, Deli Serdang and Langkat) during harvest period (February to April 2019). One and half kilogram of candlenut was taken from each of the distribution chains. Kernel moisture content were determined by distillation. Population each of A. flavus strain was enumerated by a dilution method followed by a pour plate in dichloran 18% glycerol agar (DG18) medium. Culture method in agar medium containing 10% coconut milk was used to determine toxigenicity of A. flavus . Their toxigenicity also was determined molecularly using specific primers for amplifying regulatory ( aflR ) and structural genes ( nor-1, ver-1, omt-1 ) that determine aflatoxin biosynthesis. Results showed that moisture content of candlenut kernels at the level of farmers, collectors and distributors in Regency of Karo, Deli Serang and Langkat was above 5%. A total of 38 strains of A. flavus were isolated and 37 of the strains were toxigenic (aflatoxin producers). The average of A. flavus population (cfu/g) on candlenut at farmers was the lowest and the highest population was at distributor chain.","PeriodicalId":257157,"journal":{"name":"Proceedings of the 1st International MIPAnet Conference on Science and Mathematics","volume":"690 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"133970758","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis of 6-Alyl-8-Methoxy-3-Propyl-1,3-Benzoxazine and 4-Alyl-6-(Dimetilamino)Methyl-2-Methoxy Phenol from Eugenol through Mannich Reaction and Antibacterial Activity Test 丁香酚曼尼希反应合成6-芳烯-8-甲氧基-3-丙基-1,3-苯并恶嗪和4-芳烯-6-(二甲氨基)甲基-2-甲氧基苯酚并进行抑菌活性试验
Sabarmin Perangin-angin, Sajidah Chairi
: 6-alyl-8-methoxy-3-propyl-1,3-benzoxazine and 4-alyl-6-(dimethylamino) methyl-2-methoxy phenol compounds have been synthesized through the Mannich reaction. The 6-alyl-8-methoxy-3-propyl-1,3-benzoxazine compound was synthesized by reacting eugenol, 37% formaldehyde, and propylamine under conditions of reflux with ethanol solvents at 78ºC for 6 hours obtained compounds of 6,116 grams (82.54%). The formation of 6-alyl-8-methoxy-3-propyl-1,3-benzoxazine compound characterized by FT-IR obtained CN stretching vibration at wave number 1242.16 cm-1 and peak molecular ion m/e 247 through GC-MS analysis. The 4-alyl-6-(dimethylamino) methyl-2-methoxy phenol compound was synthesized by reacting eugenol, 37% formaldehyde, and 40% dimethylamine under reflux conditions with ethanol solvents at 78ºC for 90 minutes and obtained compounds of 5,728 grams (86.39%). 4-alyl-6-(dimethylamino) methyl-2-methoxy phenol compound characterized by FT-IR obtained CN and OH stretch vibrations at wave numbers 1242.16 cm-1 and 3410.15 cm-1 and molecular ion peaks m/e 221 through GC-MS analysis. Then the two antibacterial activity tests were carried out on the two compounds using Streptococcus mutans and Escherichia coli bacteria with various concentrations of 10%, 20%, and 30%. The results obtained showed that the 6-alyl-8-methoxy-3-propyl-1,3-benzoxazine and 4-alyl-6-(dimethylamino) methyl-2-methoxy phenol compounds were classified as strong antibacterial.
通过Mannich反应合成了6-芳基-8-甲氧基-3-丙基-1,3-苯并恶嗪和4-芳基-6-(二甲氨基)甲基-2-甲氧基苯酚化合物。在78℃乙醇溶剂回流条件下,丁香酚、37%甲醛和丙胺反应6小时,合成6-烯丙基-8-甲氧基-3-丙基-1,3-苯并杂嗪化合物,得到化合物6116克(82.54%)。FT-IR表征的6-芳烯基-8-甲氧基-3-丙基-1,3-苯并恶嗪化合物的形成通过GC-MS分析得到了CN在波数1242.16 cm-1处的拉伸振动,峰分子离子m/e为247。以丁香酚、37%甲醛和40%二甲胺为原料,在78℃乙醇溶剂回流条件下反应90分钟,合成了4-芳基-6-(二甲胺)甲基-2-甲氧基苯酚化合物,化合物质量为5,728 g(86.39%)。FT-IR表征的4-芳烯基-6-(二甲氨基)甲基-2-甲氧基苯酚化合物通过GC-MS分析得到了CN和OH在波数1242.16 cm-1和3410.15 cm-1和分子离子峰m/e 221处的拉伸振动。然后用10%、20%、30%不同浓度的变形链球菌和大肠杆菌对两种化合物进行两次抑菌活性试验。结果表明,6-烯丙基-8-甲氧基-3-丙基-1,3-苯并恶嗪和4-烯丙基-6-(二甲氨基)甲基-2-甲氧基苯酚化合物为强抗菌化合物。
{"title":"Synthesis of 6-Alyl-8-Methoxy-3-Propyl-1,3-Benzoxazine and 4-Alyl-6-(Dimetilamino)Methyl-2-Methoxy Phenol from Eugenol through Mannich Reaction and Antibacterial Activity Test","authors":"Sabarmin Perangin-angin, Sajidah Chairi","doi":"10.5220/0010205300002775","DOIUrl":"https://doi.org/10.5220/0010205300002775","url":null,"abstract":": 6-alyl-8-methoxy-3-propyl-1,3-benzoxazine and 4-alyl-6-(dimethylamino) methyl-2-methoxy phenol compounds have been synthesized through the Mannich reaction. The 6-alyl-8-methoxy-3-propyl-1,3-benzoxazine compound was synthesized by reacting eugenol, 37% formaldehyde, and propylamine under conditions of reflux with ethanol solvents at 78ºC for 6 hours obtained compounds of 6,116 grams (82.54%). The formation of 6-alyl-8-methoxy-3-propyl-1,3-benzoxazine compound characterized by FT-IR obtained CN stretching vibration at wave number 1242.16 cm-1 and peak molecular ion m/e 247 through GC-MS analysis. The 4-alyl-6-(dimethylamino) methyl-2-methoxy phenol compound was synthesized by reacting eugenol, 37% formaldehyde, and 40% dimethylamine under reflux conditions with ethanol solvents at 78ºC for 90 minutes and obtained compounds of 5,728 grams (86.39%). 4-alyl-6-(dimethylamino) methyl-2-methoxy phenol compound characterized by FT-IR obtained CN and OH stretch vibrations at wave numbers 1242.16 cm-1 and 3410.15 cm-1 and molecular ion peaks m/e 221 through GC-MS analysis. Then the two antibacterial activity tests were carried out on the two compounds using Streptococcus mutans and Escherichia coli bacteria with various concentrations of 10%, 20%, and 30%. The results obtained showed that the 6-alyl-8-methoxy-3-propyl-1,3-benzoxazine and 4-alyl-6-(dimethylamino) methyl-2-methoxy phenol compounds were classified as strong antibacterial.","PeriodicalId":257157,"journal":{"name":"Proceedings of the 1st International MIPAnet Conference on Science and Mathematics","volume":"119 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"132468184","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Influence of the Ethanol Extract of Bitter Vine (Mikania micrantha Kunth.) on the Mortality, the Hatchability of the Eggs and the Larval Growth of Aedes aegypti Linn. 苦藤醇提物对埃及伊蚊死亡率、卵孵化率及幼虫生长的影响。
.. Nursal, A. Hardiansyah
: The research on the impact of the ethanol extract of M. micrantha leaf on the mortality, egg hatchability and larval growth of A. aegypti had been conducted using a Complete Randomized Design (CDR) with five treatments and replications. The mortality tests on 3rd instar larva with concentration treatments of the ethanol extract of M. micrantha leaves at 0.2%,0.4%,0.6%,0.8%, and 0.1%generated a LC 50 value of 0.58%.The ethanol extract of M. micrantha leaves at a sub-lethal concentration of 0,1%,0,2%,0,3%,0,4%,0,5%indicated a significant impact on the mortality, egg hatchability and larval growth (p≤0,05).A sublethal concentration at 0,4% of the plant was effective in suppressing the egg hatchability at a percentage of 41,6%, larval development into pupa at a percentage of 19.5% and pupae transformation into imago a percentage of 63,3%.
采用完全随机设计(CDR), 5个处理和重复,研究了薇甘菊叶乙醇提取物对埃及伊蚊死亡率、卵孵化率和幼虫生长的影响。薇甘菊叶乙醇提取物浓度分别为0.2%、0.4%、0.6%、0.8%和0.1%,对3龄幼虫的死亡率试验,lc50值为0.58%。亚致死浓度分别为0.1%、0.2%、0.3%、0.4%、0.5%的薇甘菊叶乙醇提取物对幼虫的死亡率、卵孵化率和幼虫生长均有显著影响(p≤0.05)。0.4%亚致死浓度对虫卵孵化率的抑制率为41.6%,对幼虫成蛹率的抑制率为19.5%,对蛹成象率的抑制率为63.3%。
{"title":"The Influence of the Ethanol Extract of Bitter Vine (Mikania micrantha Kunth.) on the Mortality, the Hatchability of the Eggs and the Larval Growth of Aedes aegypti Linn.","authors":".. Nursal, A. Hardiansyah","doi":"10.5220/0010204500002775","DOIUrl":"https://doi.org/10.5220/0010204500002775","url":null,"abstract":": The research on the impact of the ethanol extract of M. micrantha leaf on the mortality, egg hatchability and larval growth of A. aegypti had been conducted using a Complete Randomized Design (CDR) with five treatments and replications. The mortality tests on 3rd instar larva with concentration treatments of the ethanol extract of M. micrantha leaves at 0.2%,0.4%,0.6%,0.8%, and 0.1%generated a LC 50 value of 0.58%.The ethanol extract of M. micrantha leaves at a sub-lethal concentration of 0,1%,0,2%,0,3%,0,4%,0,5%indicated a significant impact on the mortality, egg hatchability and larval growth (p≤0,05).A sublethal concentration at 0,4% of the plant was effective in suppressing the egg hatchability at a percentage of 41,6%, larval development into pupa at a percentage of 19.5% and pupae transformation into imago a percentage of 63,3%.","PeriodicalId":257157,"journal":{"name":"Proceedings of the 1st International MIPAnet Conference on Science and Mathematics","volume":"38 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"132997399","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Biodiesel Synthesis from Rubber Seed Oil Via Esterification using H-Zeolit and ZrO2/ZAK Catalysts h -沸石和ZrO2/ZAK催化橡胶籽油酯化合成生物柴油
Tiamina Rahayu, Yunita Sari Nasution, Anggi Lubis, Al Ridha, Agus Lubis, Kembaren Rini, Selly Ahmad Nasir, Pulungan
: Rubber seed oil is a non-edible oil that is very potential as a biodiesel feedstock. The synthesis of biodiesel from rubber seed oil was done by reaction of esterification free fatty acid (FFAs) and transesterification of Triglycerides (TGs) in a single step, which used heterogeneous catalysts. Zeolite is one type of catalyst that has been developed for this process. In this study the catalyst was prepared using Indonesian natural zeolite (ZAK). To increase catalytic activity, zeolite catalyst was loaded with zirconium (Zr) by wet impregnation method, followed by the process of calcination and oxidation at a temperature of 400 o C for 1 hours with gas flow of O 2 and N 2 . ZAK and ZrO 2 /ZAK catalysts were characterized by XRD and SEM-EDS. The catalyst produced has good crystallinity as seen from sharp peaks with high intensity and high levels of Si. The catalyst activity test was done in the process of converting rubber seed oil into biodiesel. The reaction process was carried out at a temperature of 100 o C with a variety of catalyst concentrations: oil1: 2, 1: 4, and 1: 6 and the reaction time varied by 30, 60, and 90 minutes. The most optimum process of biodiesel produced at the ratio of catalyst 1 : 2 with reaction time of 30 minutes showed the biodiesel yield of 67,95%. Biodiesel products were tested for water content, FFA, and density of each is 0,09%, 2,15%, dan 0,89 g/cm 3 . GC analysis shows that the main composition of biodiesel consists of diesel fraction (C 16 -C 20 ) with the most components being methyl linoleic 38,82% and methyl oleat 22,33%.
橡胶籽油是一种非食用油,非常有潜力作为生物柴油的原料。以橡胶籽油为原料,采用多相催化剂,通过游离脂肪酸酯化反应和甘油三酯酯交换反应,一步合成了生物柴油。沸石是为这一过程开发的一种催化剂。本研究采用印尼天然沸石(ZAK)制备催化剂。为了提高催化剂的催化活性,采用湿浸渍法在沸石催化剂上负载锆(Zr),在400℃的温度下,以o2和n2为气流,焙烧氧化1小时。采用XRD和SEM-EDS对ZAK和ZrO 2 /ZAK催化剂进行了表征。从高强度和高硅含量的尖峰可以看出,所制备的催化剂具有良好的结晶度。在橡胶籽油转化为生物柴油的过程中进行了催化剂活性试验。反应温度为100℃,催化剂浓度为油1:2、1:4、1:6,反应时间为30、60、90分钟。在催化剂配比为1:2、反应时间为30 min的条件下,生物柴油的最佳产率为67.95%。生物柴油产品的含水量、游离脂肪酸和密度分别为0.09%、2.15%和0.89 g/ cm3。气相色谱分析表明,生物柴油的主要成分是柴油馏分(c16 - c20),其中甲基亚油酸(38.82%)和甲基油酸(22.33%)的成分最多。
{"title":"Biodiesel Synthesis from Rubber Seed Oil Via Esterification using H-Zeolit and ZrO2/ZAK Catalysts","authors":"Tiamina Rahayu, Yunita Sari Nasution, Anggi Lubis, Al Ridha, Agus Lubis, Kembaren Rini, Selly Ahmad Nasir, Pulungan","doi":"10.5220/0009873600002775","DOIUrl":"https://doi.org/10.5220/0009873600002775","url":null,"abstract":": Rubber seed oil is a non-edible oil that is very potential as a biodiesel feedstock. The synthesis of biodiesel from rubber seed oil was done by reaction of esterification free fatty acid (FFAs) and transesterification of Triglycerides (TGs) in a single step, which used heterogeneous catalysts. Zeolite is one type of catalyst that has been developed for this process. In this study the catalyst was prepared using Indonesian natural zeolite (ZAK). To increase catalytic activity, zeolite catalyst was loaded with zirconium (Zr) by wet impregnation method, followed by the process of calcination and oxidation at a temperature of 400 o C for 1 hours with gas flow of O 2 and N 2 . ZAK and ZrO 2 /ZAK catalysts were characterized by XRD and SEM-EDS. The catalyst produced has good crystallinity as seen from sharp peaks with high intensity and high levels of Si. The catalyst activity test was done in the process of converting rubber seed oil into biodiesel. The reaction process was carried out at a temperature of 100 o C with a variety of catalyst concentrations: oil1: 2, 1: 4, and 1: 6 and the reaction time varied by 30, 60, and 90 minutes. The most optimum process of biodiesel produced at the ratio of catalyst 1 : 2 with reaction time of 30 minutes showed the biodiesel yield of 67,95%. Biodiesel products were tested for water content, FFA, and density of each is 0,09%, 2,15%, dan 0,89 g/cm 3 . GC analysis shows that the main composition of biodiesel consists of diesel fraction (C 16 -C 20 ) with the most components being methyl linoleic 38,82% and methyl oleat 22,33%.","PeriodicalId":257157,"journal":{"name":"Proceedings of the 1st International MIPAnet Conference on Science and Mathematics","volume":"4 6 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128807694","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Bioethanol Production from Lindur Fruit (Burguiera Gymnorrhiza) Strach with Variation of Inoculum Volume of Zymomonas Mobilis 运动单胞菌接种量变化对林德果菌液生产生物乙醇的影响
Hamdan Azhari, Emma Zaidar Nasution, Rumondang Bulan Nasution
{"title":"Bioethanol Production from Lindur Fruit (Burguiera Gymnorrhiza) Strach with Variation of Inoculum Volume of Zymomonas Mobilis","authors":"Hamdan Azhari, Emma Zaidar Nasution, Rumondang Bulan Nasution","doi":"10.5220/0010133100002775","DOIUrl":"https://doi.org/10.5220/0010133100002775","url":null,"abstract":"","PeriodicalId":257157,"journal":{"name":"Proceedings of the 1st International MIPAnet Conference on Science and Mathematics","volume":"101 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"127886312","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Proceedings of the 1st International MIPAnet Conference on Science and Mathematics
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1