首页 > 最新文献

Neft i gaz最新文献

英文 中文
MESOPOROUS ALUMINOSILICATES AS PROMISING CARRIERS OF CATALYSTS FOR PETROCHEMICAL PROCESSES 介孔硅铝酸盐是很有前途的石油化工催化剂载体
Pub Date : 2022-12-30 DOI: 10.37878/2708-0080/2022-6.10
A. Abdrassilov, K. Abdildina, G. Vassilina, I. A. Klassen, N. Zabara, D. Baidulla
Nowadays there is a number of research papers and a certain interest in some mesoporous materials and the study of their properties. Mesoporous materials have every chance to become components of industrial heterogeneous catalysts. Catalysts based on mesoporous aluminosilicates are widely used in the petrochemical industry for hydrogenation, reforming, hydroisomerization, hydrocracking, hydrodearomatization, etc. In this article mesoporous aluminosilicates (MAS) were synthesized by copolycondensation of tetraethylortosilicate and secondary aluminum butoxide. Hexadecylamine was used as a template. The physico-chemical characteristics of a synthesized structured mesoporous aluminosilicate and a bifunctional catalyst based on it were studied by nitrogen adsorption/desorption, X-ray diffraction, SEM and TPDA. It was found that the obtained samples have an ordered mesoporous structure and possess the necessary strength and concentration of acid centers for use as acid components of bifunctional catalysts of various petrochemical processes.
目前,一些介孔材料及其性质的研究已经引起了一定的兴趣。介孔材料完全有可能成为工业非均相催化剂的组成部分。介孔硅铝酸盐催化剂在石油化工中广泛应用于加氢、重整、加氢异构、加氢裂化、加氢脱芳等反应。采用四乙基硅酸盐与仲氧化铝的共聚法制备了介孔硅酸铝(MAS)。十六烷基胺作为模板。采用氮吸附/脱附、x射线衍射、扫描电镜和TPDA等手段研究了合成的结构介孔硅酸铝及其双功能催化剂的理化性质。结果表明,所得样品具有有序的介孔结构,并具有必要的酸中心强度和浓度,可作为各种石化工艺双功能催化剂的酸组分。
{"title":"MESOPOROUS ALUMINOSILICATES AS PROMISING CARRIERS OF CATALYSTS FOR PETROCHEMICAL PROCESSES","authors":"A. Abdrassilov, K. Abdildina, G. Vassilina, I. A. Klassen, N. Zabara, D. Baidulla","doi":"10.37878/2708-0080/2022-6.10","DOIUrl":"https://doi.org/10.37878/2708-0080/2022-6.10","url":null,"abstract":"Nowadays there is a number of research papers and a certain interest in some mesoporous materials and the study of their properties. Mesoporous materials have every chance to become components of industrial heterogeneous catalysts. Catalysts based on mesoporous aluminosilicates are widely used in the petrochemical industry for hydrogenation, reforming, hydroisomerization, hydrocracking, hydrodearomatization, etc. In this article mesoporous aluminosilicates (MAS) were synthesized by copolycondensation of tetraethylortosilicate and secondary aluminum butoxide. Hexadecylamine was used as a template. The physico-chemical characteristics of a synthesized structured mesoporous aluminosilicate and a bifunctional catalyst based on it were studied by nitrogen adsorption/desorption, X-ray diffraction, SEM and TPDA. It was found that the obtained samples have an ordered mesoporous structure and possess the necessary strength and concentration of acid centers for use as acid components of bifunctional catalysts of various petrochemical processes.","PeriodicalId":272594,"journal":{"name":"Neft i gaz","volume":"39 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"116087829","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
EXPERIENCE IN THE IMPLEMENTATION OF WATER-GAS EXPOSURE TECHNOLOGY IN THE FIELDS 有油气田水气暴露技术实施经验
Pub Date : 2022-12-30 DOI: 10.37878/2708-0080/2022-6.05
S. Zakenov, L. Nurshakhanova
Deterioration of the qualitative and quantitative characteristics of the hydrocarbon resource base leads to an increase in the share of hard-to-recover reserves. In an environment where the share of hard-to-recover oil reserves in the oil industry is steadily increasing, the need to create effective methods to increase oil recovery is acute. The method of flooding at the present stage of the development of the oil industry is considered the most progressive, meeting the basic principles of oil field development. However, during flooding, a large proportion of oil reserves remains in the reservoir, and therefore, technologies are currently being sought and developed in all major oil companies that will increase the oil recovery coefficient. Currently, there is a growing interest in the application of the technology of water-gas exposure to oil formations to increase oil production. This is due to the fact that the water-gas effects combine the positive aspects of well-known oil production technologies, such as flooding and the method of pumping hydrocarbon gas into the reservoir. Experimental and theoretical studies have established that one of the most effective methods of oil recovery can be methods based on injection of hydrocarbon gases and water-gas mixtures into the reservoir. Experiments were conducted to study the mechanism of displacement and determine the coefficient of displacement of oil by gases and water in various combinations in relation to some fields. The experiments were carried out under conditions as close as possible to reservoir conditions: recombined or reservoir oil samples, core from productive deposits were used. The pressure and temperatures corresponded to their reservoir values. As the results of experiments, the increase in the oil displacement coefficient depends on the type of gas injected (hydrocarbon equilibrium and nonequilibrium with reservoir oil, acidic, inert, etc.) and modification of the injection technology of agents (sequential, alternate, joint). To study the expected results of testing the technology of water-gas exposure at the Kalamkas field, the experience of using this method at other fields is considered. The paper presents an analysis of the experience of implementing the technology of water-gas exposure at various locations. A review analysis of the results of the technology implementation was carried out to determine the advantages and possibilities of using the technology of watergas exposure in the conditions of the Mangystau field.
油气资源基础定性和定量特征的恶化导致难以开采储量的比例增加。在石油行业中,难以开采的石油储量所占的份额正在稳步增加,因此迫切需要创造有效的方法来提高石油采收率。在石油工业发展的现阶段,驱油方法被认为是最先进的,符合油田开发的基本原则。然而,在驱油过程中,很大一部分石油储量仍留在储层中,因此,目前各大石油公司都在寻求和开发提高采收率系数的技术。目前,人们对油气暴露技术的应用越来越感兴趣,以提高石油产量。这是由于水气效应结合了众所周知的采油技术的积极方面,如驱油和向储层中泵入碳氢气体的方法。实验和理论研究表明,向储层注入烃类气体和水气混合物是最有效的采油方法之一。针对部分油田进行了驱替机理研究,确定了不同组合的气水驱油系数。实验是在尽可能接近油藏条件的条件下进行的:使用复合油或油藏油样品,取自生产性矿床的岩心。压力和温度对应于它们的储层值。实验结果表明,驱油系数的提高取决于注气类型(烃类平衡和非平衡与储层油、酸性、惰性等)和注气技术的改进(顺序、交替、联合)。为了研究Kalamkas油田水气暴露技术测试的预期结果,考虑了该方法在其他油田的应用经验。本文分析了不同地点实施水气暴露技术的经验。对技术实施的结果进行了回顾分析,以确定在Mangystau油田条件下使用水暴露技术的优势和可能性。
{"title":"EXPERIENCE IN THE IMPLEMENTATION OF WATER-GAS EXPOSURE TECHNOLOGY IN THE FIELDS","authors":"S. Zakenov, L. Nurshakhanova","doi":"10.37878/2708-0080/2022-6.05","DOIUrl":"https://doi.org/10.37878/2708-0080/2022-6.05","url":null,"abstract":"Deterioration of the qualitative and quantitative characteristics of the hydrocarbon resource base leads to an increase in the share of hard-to-recover reserves. In an environment where the share of hard-to-recover oil reserves in the oil industry is steadily increasing, the need to create effective methods to increase oil recovery is acute. The method of flooding at the present stage of the development of the oil industry is considered the most progressive, meeting the basic principles of oil field development. However, during flooding, a large proportion of oil reserves remains in the reservoir, and therefore, technologies are currently being sought and developed in all major oil companies that will increase the oil recovery coefficient. Currently, there is a growing interest in the application of the technology of water-gas exposure to oil formations to increase oil production. This is due to the fact that the water-gas effects combine the positive aspects of well-known oil production technologies, such as flooding and the method of pumping hydrocarbon gas into the reservoir. Experimental and theoretical studies have established that one of the most effective methods of oil recovery can be methods based on injection of hydrocarbon gases and water-gas mixtures into the reservoir. Experiments were conducted to study the mechanism of displacement and determine the coefficient of displacement of oil by gases and water in various combinations in relation to some fields. The experiments were carried out under conditions as close as possible to reservoir conditions: recombined or reservoir oil samples, core from productive deposits were used. The pressure and temperatures corresponded to their reservoir values. As the results of experiments, the increase in the oil displacement coefficient depends on the type of gas injected (hydrocarbon equilibrium and nonequilibrium with reservoir oil, acidic, inert, etc.) and modification of the injection technology of agents (sequential, alternate, joint). To study the expected results of testing the technology of water-gas exposure at the Kalamkas field, the experience of using this method at other fields is considered. The paper presents an analysis of the experience of implementing the technology of water-gas exposure at various locations. A review analysis of the results of the technology implementation was carried out to determine the advantages and possibilities of using the technology of watergas exposure in the conditions of the Mangystau field.","PeriodicalId":272594,"journal":{"name":"Neft i gaz","volume":"26 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"129180777","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
EVOLUTION AND ROLE OF THE DEWAXING PROCESS IN OIL REFINING 脱蜡过程在石油炼制中的演变及作用
Pub Date : 2022-12-30 DOI: 10.37878/2708-0080/2022-6.07
I. Klassen, K. Abdildina, Zh.Y. Zakirov
Currently, the dewaxing process is used throughout the oil industry. There is a lot of research and interest in this process as necessary in the production of fuels for cold regions, as well as lubricating oils. For dewaxing, mesoporous high-silica zeolites with different structures have been used for a long time, offering sufficient activity in the process. Dewaxing can be divided into several types and is actively used not only in the oil industry, but also in biology and medicine. In this article, an overview of the dewaxing process development stages and the most popular research on this topic was made, various indicators and physicochemical parameters were considered.
目前,脱蜡工艺应用于整个石油工业。在寒冷地区生产燃料和润滑油的过程中,有很多研究和兴趣是必要的。在脱蜡过程中,不同结构的介孔高硅沸石已被长期使用,在脱蜡过程中具有足够的活性。脱蜡可分为几种类型,不仅在石油工业中得到积极应用,而且在生物和医学中也得到积极应用。本文综述了脱蜡工艺的发展阶段和目前研究的热点,综合考虑了各种指标和理化参数。
{"title":"EVOLUTION AND ROLE OF THE DEWAXING PROCESS IN OIL REFINING","authors":"I. Klassen, K. Abdildina, Zh.Y. Zakirov","doi":"10.37878/2708-0080/2022-6.07","DOIUrl":"https://doi.org/10.37878/2708-0080/2022-6.07","url":null,"abstract":"Currently, the dewaxing process is used throughout the oil industry. There is a lot of research and interest in this process as necessary in the production of fuels for cold regions, as well as lubricating oils. For dewaxing, mesoporous high-silica zeolites with different structures have been used for a long time, offering sufficient activity in the process. Dewaxing can be divided into several types and is actively used not only in the oil industry, but also in biology and medicine. In this article, an overview of the dewaxing process development stages and the most popular research on this topic was made, various indicators and physicochemical parameters were considered.","PeriodicalId":272594,"journal":{"name":"Neft i gaz","volume":"3 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134260067","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
USE OF A SPECIAL LOG COMPLEX FOR STUDYING THE PROPERTIES OF RESERVOIR FLUIDS AND ROCKS OF THE SEDIMENTS OF THE CRETACEOUS AND JURASSIC AGES OF THE ARYSTANOVSKOYE FIELD 使用一种特殊的测井复合体来研究arystanovskoye油田白垩纪和侏罗纪时期的储层流体和沉积岩的性质
Pub Date : 2022-12-30 DOI: 10.37878/2708-0080/2022-6.01
B. Durmagambetov, R.А. Tulebayeva, А.ZH. Mukhanov
The properties of formation fluids and reservoir rocks of the Cretaceous and Jurassic periods deposits of the Arystanovskoye field are given in the article. In the A-418 well drilled within a new poorly explored area, the special well logging methods have been used to assess the prospects of the area and identify possible watering out: multi-frequency electromagnetic propagation logging (MEPL) Dielectric Scanner and high resolution nuclear magnetic logging (NML) CMR-Plus. Properties of formation fluids and reservoir rocks of the Cretaceous and Jurassic deposits of the Arystanovskoye field were determined using these methods. The qualitative characters of reservoirs were used for reservoir quality discrimination such as: decreased values of natural radioactivity, volume density and hydrogen content, clay cake availability, availability of radial penetration profile by electrical resistivity diagrams. The results of the research can be used during the selection of development targets, the selection of methods for hydrocarbons recovery. The relevance of this study is confirmed by the fact that the Arystanovskoye field is currently under development. The research of reservoir rocks in the new A-418 well within the 801–3095m interval will help to perform the reserves update and choose the production method.
本文介绍了阿利斯坦诺夫斯科耶油田白垩系和侏罗系地层流体和储集岩的性质。在a -418井的新勘探区内,采用了特殊的测井方法,即多频电磁传播测井(MEPL)、介电扫描仪和高分辨率核磁测井(NML) CMR-Plus,对该地区的前景进行了评估,并确定了可能的水淹。利用这些方法测定了Arystanovskoye油田白垩系和侏罗系地层流体和储层岩石的性质。利用储层的自然放射性、体积密度和含氢量的降低值、泥饼有效性、电阻率图径向穿透剖面有效性等定性特征进行储层质量判别。研究结果可用于开发目标的选择、油气开采方法的选择。Arystanovskoye油田目前正在开发,这一事实证实了这项研究的相关性。对A-418新井801 ~ 3095m段储层岩进行研究,有助于储量更新和生产方式选择。
{"title":"USE OF A SPECIAL LOG COMPLEX FOR STUDYING THE PROPERTIES OF RESERVOIR FLUIDS AND ROCKS OF THE SEDIMENTS OF THE CRETACEOUS AND JURASSIC AGES OF THE ARYSTANOVSKOYE FIELD","authors":"B. Durmagambetov, R.А. Tulebayeva, А.ZH. Mukhanov","doi":"10.37878/2708-0080/2022-6.01","DOIUrl":"https://doi.org/10.37878/2708-0080/2022-6.01","url":null,"abstract":"The properties of formation fluids and reservoir rocks of the Cretaceous and Jurassic periods deposits of the Arystanovskoye field are given in the article. In the A-418 well drilled within a new poorly explored area, the special well logging methods have been used to assess the prospects of the area and identify possible watering out: multi-frequency electromagnetic propagation logging (MEPL) Dielectric Scanner and high resolution nuclear magnetic logging (NML) CMR-Plus. Properties of formation fluids and reservoir rocks of the Cretaceous and Jurassic deposits of the Arystanovskoye field were determined using these methods. The qualitative characters of reservoirs were used for reservoir quality discrimination such as: decreased values of natural radioactivity, volume density and hydrogen content, clay cake availability, availability of radial penetration profile by electrical resistivity diagrams. The results of the research can be used during the selection of development targets, the selection of methods for hydrocarbons recovery. The relevance of this study is confirmed by the fact that the Arystanovskoye field is currently under development. The research of reservoir rocks in the new A-418 well within the 801–3095m interval will help to perform the reserves update and choose the production method.","PeriodicalId":272594,"journal":{"name":"Neft i gaz","volume":"240 2 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"121093510","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
INFLUENCE OF THE NATURE OF THE ALUMINUM SOURCE ON THE PHYSICO-CHEMICAL CHARACTERISTICS OF THE CARRIER OF CATALYTIC SYSTEMS FOR THE PETROCHEMICAL INDUSTRY 铝源性质对石油化工催化体系载体理化特性的影响
Pub Date : 2022-12-30 DOI: 10.37878/2708-0080/2022-6.14
G.K. VASSILINA, A.K. ABDRASSILOVA
In the oil refining industry of the Republic of Kazakhstan, catalysts based on synthetic zeolites are mainly used. However, it was found that catalysts of this type have a number of disadvantages. For example, most of them have pore sizes in the micropore range, which is the reason for diffusion limitations. The solution to this problem can be found by creating catalysts based on mesoporous aluminosilicate. Mesostructured aluminosilicates are widely used as catalysts for petrochemical processes due to their high specific surface area, highly ordered pore structure and narrow pore size distribution and the possibility of regulating the size of their pores during synthesis. Mesoporous aluminosilicates are widely used as catalysts for petrochemical processes due to their high specific surface area, highly ordered pore structure and narrow pore size distribution and the possibility of regulating the size of their pores during synthesis. The article presents the synthesis of mesoporous aluminosilicates by copolycondensation of tetraethylortosilicate with various sources of aluminum: secondary aluminum butoxide (MAS-1) and aluminum triisopropoxide (MAS-2). The presence of a mesoporous and ordered structure in the synthesized aluminosilicates was confirmed by the data of low-temperature nitrogen adsorption/ desorption, X-ray diffraction and FT-IR. Acidic data were investigated by the method of infrared spectroscopy of the Fourier transform with diffuse reflection (DRIFT). It is shown that the nature of the aluminum source affects both the specific surface area and porosity, and the acidic characteristics of the synthesized mesoporous aluminosilicates.
在哈萨克斯坦共和国的炼油工业中,主要使用基于合成沸石的催化剂。然而,人们发现这种类型的催化剂有许多缺点。例如,它们的孔径大多在微孔范围内,这是扩散受限的原因。解决这一问题的方法是制备基于介孔硅酸铝的催化剂。介观结构硅铝酸盐具有高比表面积、高度有序的孔隙结构和狭窄的孔径分布以及在合成过程中调节孔隙大小的可能性等优点,被广泛用作石油化工过程的催化剂。介孔硅铝酸盐具有高比表面积、高度有序的孔隙结构和狭窄的孔径分布以及在合成过程中调节孔隙大小的可能性等优点,在石油化工过程中被广泛用作催化剂。本文介绍了四乙基硅酸盐与不同来源的铝——次生丁氧化铝(MAS-1)和三异丙醇铝(MAS-2)共聚合成介孔硅酸铝。通过低温氮吸附/脱附、x射线衍射和红外光谱分析,证实了合成的硅铝酸铝具有介孔有序结构。采用漫反射傅里叶变换红外光谱法(DRIFT)对酸性数据进行了研究。结果表明,铝源的性质影响了合成的介孔硅酸盐铝的比表面积和孔隙率,并影响了其酸性特性。
{"title":"INFLUENCE OF THE NATURE OF THE ALUMINUM SOURCE ON THE PHYSICO-CHEMICAL CHARACTERISTICS OF THE CARRIER OF CATALYTIC SYSTEMS FOR THE PETROCHEMICAL INDUSTRY","authors":"G.K. VASSILINA, A.K. ABDRASSILOVA","doi":"10.37878/2708-0080/2022-6.14","DOIUrl":"https://doi.org/10.37878/2708-0080/2022-6.14","url":null,"abstract":"In the oil refining industry of the Republic of Kazakhstan, catalysts based on synthetic zeolites are mainly used. However, it was found that catalysts of this type have a number of disadvantages. For example, most of them have pore sizes in the micropore range, which is the reason for diffusion limitations. The solution to this problem can be found by creating catalysts based on mesoporous aluminosilicate. Mesostructured aluminosilicates are widely used as catalysts for petrochemical processes due to their high specific surface area, highly ordered pore structure and narrow pore size distribution and the possibility of regulating the size of their pores during synthesis. Mesoporous aluminosilicates are widely used as catalysts for petrochemical processes due to their high specific surface area, highly ordered pore structure and narrow pore size distribution and the possibility of regulating the size of their pores during synthesis. The article presents the synthesis of mesoporous aluminosilicates by copolycondensation of tetraethylortosilicate with various sources of aluminum: secondary aluminum butoxide (MAS-1) and aluminum triisopropoxide (MAS-2). The presence of a mesoporous and ordered structure in the synthesized aluminosilicates was confirmed by the data of low-temperature nitrogen adsorption/ desorption, X-ray diffraction and FT-IR. Acidic data were investigated by the method of infrared spectroscopy of the Fourier transform with diffuse reflection (DRIFT). It is shown that the nature of the aluminum source affects both the specific surface area and porosity, and the acidic characteristics of the synthesized mesoporous aluminosilicates.","PeriodicalId":272594,"journal":{"name":"Neft i gaz","volume":"22 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"130055152","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
STUDY OF THE EFFICIENCY OF OIL DISPLACEMENT PROCESS BY POLYMERS OF DIFFERENT GRADES 不同等级聚合物驱油效果的研究
Pub Date : 2022-12-30 DOI: 10.37878/2708-0080/2022-6.11
G. Moldabayeva, A. Syzdykov, K. Bissembayeva, A. Khadiyeva, G. Sabyrbayeva
Currently, a large number of fields with high-viscosity oil are being developed. Increasing the degree of oil recovery from the subsoil of developed fields using effective methods of active influence is an important scientific and technical task for employees of oil producing enterprises. One of the most effective and promising methods for stabilizing oil production is physical and chemical technologies based on the injection of polymer compositions. Therefore, the authors of the article pursue the goal - to investigate the effectiveness of the use of polymer compositions for further recommendation for use in fields with high-viscosity oils and formations containing hard-to-recover reserves. The article provides an analysis of the results of the study of polymers, namely GL-50 and R-1 on rock samples of various well depths. In this regard, an experiment was carried out to displace oil with various displacing reagents. During the oil displacement experiment with various displacement reagents, the water saturation of the sample and the displacement efficiency were determined. Particular attention is paid to the rate of advancement of the flow of polymers and the propagation of molecules through pores of different diameters. The main goal of this experiment was to determine a more effective polymer for enhanced oil recovery. Comparison of oil displacement efficiency at the stages of polymer injection is given. In the course of the study, the results of determining the displacement coefficients of GL-50 and R-1 polymers were obtained. From the results obtained, it can be assumed that polymer grades have a significant impact on the degree of efficiency of the oil displacement process.
目前,大量高粘度油田正在开发中。利用积极影响的有效方法提高已开发油田底土采油程度,是采油企业员工面临的一项重要科技任务。以注入聚合物成分为基础的物理和化学技术是稳定石油生产最有效和最有前途的方法之一。因此,本文的作者追求的目标是研究聚合物组合物的有效性,以进一步推荐在高粘度油田和含有难以开采储量的地层中使用聚合物组合物。本文分析了聚合物GL-50和R-1在不同井深岩石样品上的研究结果。为此,进行了不同驱替剂驱油实验。在不同驱替试剂的驱油实验中,测定了样品的含水饱和度和驱替效率。特别注意的是聚合物流动的推进速度和分子通过不同直径的孔的传播。该实验的主要目的是确定一种更有效的聚合物,以提高原油采收率。比较了注聚合物各阶段的驱油效率。在研究过程中,得到了GL-50和R-1聚合物位移系数的测定结果。从得到的结果可以推测,聚合物等级对驱油过程的效率程度有显著影响。
{"title":"STUDY OF THE EFFICIENCY OF OIL DISPLACEMENT PROCESS BY POLYMERS OF DIFFERENT GRADES","authors":"G. Moldabayeva, A. Syzdykov, K. Bissembayeva, A. Khadiyeva, G. Sabyrbayeva","doi":"10.37878/2708-0080/2022-6.11","DOIUrl":"https://doi.org/10.37878/2708-0080/2022-6.11","url":null,"abstract":"Currently, a large number of fields with high-viscosity oil are being developed. Increasing the degree of oil recovery from the subsoil of developed fields using effective methods of active influence is an important scientific and technical task for employees of oil producing enterprises. One of the most effective and promising methods for stabilizing oil production is physical and chemical technologies based on the injection of polymer compositions. Therefore, the authors of the article pursue the goal - to investigate the effectiveness of the use of polymer compositions for further recommendation for use in fields with high-viscosity oils and formations containing hard-to-recover reserves. The article provides an analysis of the results of the study of polymers, namely GL-50 and R-1 on rock samples of various well depths. In this regard, an experiment was carried out to displace oil with various displacing reagents. During the oil displacement experiment with various displacement reagents, the water saturation of the sample and the displacement efficiency were determined. Particular attention is paid to the rate of advancement of the flow of polymers and the propagation of molecules through pores of different diameters. The main goal of this experiment was to determine a more effective polymer for enhanced oil recovery. Comparison of oil displacement efficiency at the stages of polymer injection is given. In the course of the study, the results of determining the displacement coefficients of GL-50 and R-1 polymers were obtained. From the results obtained, it can be assumed that polymer grades have a significant impact on the degree of efficiency of the oil displacement process.","PeriodicalId":272594,"journal":{"name":"Neft i gaz","volume":"26 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126444793","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
ABOUT OIL AND GAS POTENTIAL OF THE ARYSKUM DEPRESSION OF THE SOUTH TORGAI SEDIMENTARY BASIN 托尔盖盆地南部aryskum凹陷油气潜力探讨
Pub Date : 2022-10-30 DOI: 10.37878/2708-0080/2022-5.04
R. Madisheva, V. S. Portnov
The article discusses laboratory studies carried out to compare the composition of oils from Mesozoic and pre-Mesozoic formations: a comprehensive analysis of the molecular composition of oils by chromatography-mass spectrometry; separation and identification of the composition of alkanes by gas-liquid chromatography; NMR-spectroscopic determination of the fragment composition of oils; mass spectrometry was used to determine the isotopic composition of carbon, which identifies the genesis of hydrocarbons in relation to the zones of oil and gas formation. As a result of the study, the laboratory data were obtained, which made it possible to reveal the similarity between oils from deposits of different ages within the graben-synclines, namely, close values of geochemical parameters and the relative content of individual classes of biomarkers made it possible to assume the genetic unity of oils from the Lower Cretaceous and Proterozoic of the Akshabulak graben-syncline and genetic unity of oils from the Lower Cretaceous and Paleozoic of the Aksai horst anticline. The value of the pristane/ phytane ratios indicates a common environment for the formation of the initial organic matter within the structures - suboxidizing conditions in the Akshabulak graben syncline and oxidizing conditions in the Aksai horst anticline, and the existence of a higher redox potential in the Bosingen graben-syncline. Gas- liquid chromatography data showed a slight difference in the thermal transformation of the studied oils, which were classified as "mature". The results of NMR spectrometry in combination with other methods indicate the genetic unity of oils from the Lower Cretaceous and Proterozoic of the Akshabulak graben- syncline and the genetic unity of oils from the Lower Cretaceous and Paleozoic of the Aksai horst anticline. A comparative analysis of the carbon isotopic composition of oils from the Jurassic and Cretaceous deposits of the Aryskum depression and oils from various basins of the world showed a similar range of their variations and a possible genetic relationship of these oils with organic matter of the sapropel type.
本文讨论了为比较中生代和前中生代地层油的组成而进行的实验室研究:用色谱-质谱法综合分析油的分子组成;气液色谱法分离鉴定烷烃的组成核磁共振光谱法测定油的碎片组成质谱法测定了碳的同位素组成,从而确定了与油气形成区有关的碳氢化合物的成因。研究结果为揭示地堑-向斜不同年代沉积的油的相似性提供了实验数据,即:地球化学参数的接近值和各类生物标记物的相对含量使得我们可以假设阿克沙布拉克地堑向斜下白垩统和元古界的原油和阿克赛地垒背斜下白垩统和古生界的原油的成因是一致的。原石/植烷比值值表明,两套构造具有共同的初始有机质形成环境——阿克沙布拉克地堑向斜的亚氧化条件和阿克赛地垒背斜的氧化条件,博辛根地堑向斜具有较高的氧化还原电位。气液色谱数据显示,所研究的油的热转化略有差异,被归类为“成熟”。结合其他方法的核磁共振光谱分析结果表明,阿克沙布拉克地堑-向斜下白垩统和元古界的原油和阿克赛地堑-向斜下白垩统和古生界的原油具有统一的成因。通过对Aryskum坳陷侏罗系和白垩系原油与世界各盆地原油碳同位素组成的对比分析,发现其碳同位素组成的变化范围相似,并认为这些原油可能与泥岩型有机质有一定的成因关系。
{"title":"ABOUT OIL AND GAS POTENTIAL OF THE ARYSKUM DEPRESSION OF THE SOUTH TORGAI SEDIMENTARY BASIN","authors":"R. Madisheva, V. S. Portnov","doi":"10.37878/2708-0080/2022-5.04","DOIUrl":"https://doi.org/10.37878/2708-0080/2022-5.04","url":null,"abstract":"The article discusses laboratory studies carried out to compare the composition of oils from Mesozoic and pre-Mesozoic formations: a comprehensive analysis of the molecular composition of oils by chromatography-mass spectrometry; separation and identification of the composition of alkanes by gas-liquid chromatography; NMR-spectroscopic determination of the fragment composition of oils; mass spectrometry was used to determine the isotopic composition of carbon, which identifies the genesis of hydrocarbons in relation to the zones of oil and gas formation. As a result of the study, the laboratory data were obtained, which made it possible to reveal the similarity between oils from deposits of different ages within the graben-synclines, namely, close values of geochemical parameters and the relative content of individual classes of biomarkers made it possible to assume the genetic unity of oils from the Lower Cretaceous and Proterozoic of the Akshabulak graben-syncline and genetic unity of oils from the Lower Cretaceous and Paleozoic of the Aksai horst anticline. The value of the pristane/ phytane ratios indicates a common environment for the formation of the initial organic matter within the structures - suboxidizing conditions in the Akshabulak graben syncline and oxidizing conditions in the Aksai horst anticline, and the existence of a higher redox potential in the Bosingen graben-syncline. Gas- liquid chromatography data showed a slight difference in the thermal transformation of the studied oils, which were classified as \"mature\". The results of NMR spectrometry in combination with other methods indicate the genetic unity of oils from the Lower Cretaceous and Proterozoic of the Akshabulak graben- syncline and the genetic unity of oils from the Lower Cretaceous and Paleozoic of the Aksai horst anticline. A comparative analysis of the carbon isotopic composition of oils from the Jurassic and Cretaceous deposits of the Aryskum depression and oils from various basins of the world showed a similar range of their variations and a possible genetic relationship of these oils with organic matter of the sapropel type.","PeriodicalId":272594,"journal":{"name":"Neft i gaz","volume":"50 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122007222","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
ASSESSMENT OF OIL AND GAS POTENTIAL IN PRIMORSKAYA ZONE OF CARBONATE UPLIFT OF SOUTHERN PRECASPIAN SEDIMENTARY BASIN 里海前沉积盆地南部碳酸盐岩隆起带滨海带油气潜力评价
Pub Date : 2022-10-30 DOI: 10.37878/2708-0080/2022-5.01
H. Abilkhasimov
The results of lithofacies studies and paleogeographic reconstructions of the Late DevonianEarly Visean stage and stratigraphic evolution of the Primorskaya zone of uplifts in the south of Precaspian Basin are presented. The complex geological structure of the region is mainly due to the influence of tectonic, volcanic and denudation processes on sedimentation. The spatial distribution of carbonate accumulations in the Primorskaya zone of the Precaspian Basin is determined by the different duration of sedimentation stages and the block structure of the basement. The results of the deep wells drilled in the recent years have made it possible to refine the internal geological structure, justification of new exploration objects in the Late Devonian strata and reevaluate the oil and gas potential and petroleum resources in the south of the Precaspian depression. After recent exploration works, the geological model for the onshore prospective structure traps has been improved, additionally prospective exploration objects have been predicted in the shelf of the Caspian Sea. The most of potential petroleum resources of the Primorskaya zone is the resources of the new offshore exploration objects in Caspian Sea. Non-structural traps can accumulate gigantic hydrocarbon volumes. This is a new highly prospective hydrocarbon exploration direction in the Precaspian Basin
本文介绍了里海盆地南部晚泥盆世—早维斯世的岩相研究和古地理重建成果以及滨海隆升带的地层演化。该区地质构造复杂,主要是受构造、火山和剥蚀作用的影响。滨海盆地滨海带碳酸盐岩成藏的空间分布是由不同沉积阶段和基底块体构造决定的。近年来深井钻探取得的成果,为完善里海坳陷南部晚泥盆世地层内部地质构造、确定新的勘探对象、重新评价里海坳陷南部油气潜力和油气资源提供了可能。通过近年来的勘探工作,完善了陆上远景构造圈闭地质模型,预测了里海陆架的远景勘探对象。滨海地区的大部分潜在石油资源是里海海上新勘探目标的资源。非构造圈闭可聚集巨大的油气体积。这是一个新的极具勘探前景的油气勘探方向
{"title":"ASSESSMENT OF OIL AND GAS POTENTIAL IN PRIMORSKAYA ZONE OF CARBONATE UPLIFT OF SOUTHERN PRECASPIAN SEDIMENTARY BASIN","authors":"H. Abilkhasimov","doi":"10.37878/2708-0080/2022-5.01","DOIUrl":"https://doi.org/10.37878/2708-0080/2022-5.01","url":null,"abstract":"The results of lithofacies studies and paleogeographic reconstructions of the Late DevonianEarly Visean stage and stratigraphic evolution of the Primorskaya zone of uplifts in the south of Precaspian Basin are presented. The complex geological structure of the region is mainly due to the influence of tectonic, volcanic and denudation processes on sedimentation. The spatial distribution of carbonate accumulations in the Primorskaya zone of the Precaspian Basin is determined by the different duration of sedimentation stages and the block structure of the basement. The results of the deep wells drilled in the recent years have made it possible to refine the internal geological structure, justification of new exploration objects in the Late Devonian strata and reevaluate the oil and gas potential and petroleum resources in the south of the Precaspian depression. After recent exploration works, the geological model for the onshore prospective structure traps has been improved, additionally prospective exploration objects have been predicted in the shelf of the Caspian Sea. The most of potential petroleum resources of the Primorskaya zone is the resources of the new offshore exploration objects in Caspian Sea. Non-structural traps can accumulate gigantic hydrocarbon volumes. This is a new highly prospective hydrocarbon exploration direction in the Precaspian Basin","PeriodicalId":272594,"journal":{"name":"Neft i gaz","volume":"43 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126843116","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
THE USE OF MODERN INFORMATION TECHNOLOGY TO IMPROVE THE EFFICIENCY OF PRODUCTION UNIT OPERATORS IN EMERGENCY SITUATIONS 利用现代信息技术提高生产单位操作员在紧急情况下的工作效率
Pub Date : 2022-10-30 DOI: 10.37878/2708-0080/2022-5.06
A. B. Uali, O. Korsun, A. Naukenova, E. Glukhova, M. A. Glukhov
The article deals with specialized software to support the work of production unit operator at refineries. Operators use an emergency response plan to eliminate accidents. These Emergency Response Plans (ERPs) are developed in accordance with the regulatory and legal documents of the Republic of Kazakhstan. However, the amount of information contained in the ERP is quite large. Therefore, printed on paper ERP are quite cumbersome, which makes it difficult to find the necessary algorithm of actions in an emergency situation. The proposed software is an interactive application and can be installed on a variety of electronic media - tablets, smartphones and desktop computers. This allows operators to quickly select and open the necessary algorithm of actions, and also expands training possibilities for operators, which is important for reducing the risk of erroneous actions in accidents and emergencies in production units of oil refineries. The application has been developed in Java-script language using JSON format. The interactive application was experimentally tested in «PetroKazakhstan Oil Production» LLP. The experiment showed that the time spent by the operator on elimination of accidents when using the developed specialized software was on average 15% less than when working with the plan printed on paper, and 30% less than when working with the plan in memory. These experiments also showed that the software almost completely eliminated operator errors. This confirms the effectiveness of the developed interactive application in practice.
本文论述了支持炼油厂生产单元操作员工作的专用软件。操作人员使用应急响应计划来消除事故。这些应急计划是根据哈萨克斯坦共和国的规章和法律文件制定的。然而,ERP所包含的信息量是相当大的。因此,打印在纸上的ERP相当繁琐,在紧急情况下很难找到必要的行动算法。拟议的软件是一种交互式应用程序,可以安装在各种电子媒体上——平板电脑、智能手机和台式电脑。这使得操作人员可以快速选择和打开必要的操作算法,同时也扩大了对操作人员的培训可能性,这对于降低炼油厂生产单元在事故和紧急情况下错误操作的风险非常重要。本应用程序采用JSON格式,采用Java-script语言开发。该交互式应用程序在«PetroKazakhstan Oil Production»LLP中进行了实验测试。实验表明,使用开发的专用软件时,操作人员在消除事故上花费的时间比使用打印在纸上的计划平均少15%,比使用存储计划平均少30%。这些实验还表明,该软件几乎完全消除了操作员的错误。这证实了所开发的交互式应用在实践中的有效性。
{"title":"THE USE OF MODERN INFORMATION TECHNOLOGY TO IMPROVE THE EFFICIENCY OF PRODUCTION UNIT OPERATORS IN EMERGENCY SITUATIONS","authors":"A. B. Uali, O. Korsun, A. Naukenova, E. Glukhova, M. A. Glukhov","doi":"10.37878/2708-0080/2022-5.06","DOIUrl":"https://doi.org/10.37878/2708-0080/2022-5.06","url":null,"abstract":"The article deals with specialized software to support the work of production unit operator at refineries. Operators use an emergency response plan to eliminate accidents. These Emergency Response Plans (ERPs) are developed in accordance with the regulatory and legal documents of the Republic of Kazakhstan. However, the amount of information contained in the ERP is quite large. Therefore, printed on paper ERP are quite cumbersome, which makes it difficult to find the necessary algorithm of actions in an emergency situation. The proposed software is an interactive application and can be installed on a variety of electronic media - tablets, smartphones and desktop computers. This allows operators to quickly select and open the necessary algorithm of actions, and also expands training possibilities for operators, which is important for reducing the risk of erroneous actions in accidents and emergencies in production units of oil refineries. The application has been developed in Java-script language using JSON format. The interactive application was experimentally tested in «PetroKazakhstan Oil Production» LLP. The experiment showed that the time spent by the operator on elimination of accidents when using the developed specialized software was on average 15% less than when working with the plan printed on paper, and 30% less than when working with the plan in memory. These experiments also showed that the software almost completely eliminated operator errors. This confirms the effectiveness of the developed interactive application in practice.","PeriodicalId":272594,"journal":{"name":"Neft i gaz","volume":"14 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"114688843","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
INCREASING EFFICIENCY OF THE DISPLACEMENT OF HIGHLY RESINOUS OILS BY POLYMER SOLUTIONS 提高聚合物溶液驱替高树脂油的效率
Pub Date : 2022-10-30 DOI: 10.37878/2708-0080/2022-5.07
G. Moldabaeva, A. Syzdykov, А.А. Zakirov, А.H. Karshiev, S. Abileva, L. Igamberdieva
The article presents the experimental results of studies of the filtration properties of oils from fields with a high content of asphaltene-resinous substances. Experimental studies of the filtration process of deposits with a high content of asphaltene-resinous substances have established that in low-permeability, unlike high-permeability reservoirs, the beginning of filtration proceeds according to a nonlinear law, and with an increase in the pressure gradient, the nonlinearity turns into a straight line corresponding to the Darcy law. In addition, the results of experimental studies on the displacement of oil from fields with a high content of asphaltene-resinous substances by polymer solutions on artificially created reservoir models are presented to determine the concentration of the polymer solution and the size of the slug to increase oil recovery from reservoirs. Experimental research on oil displacement by polymeric solutions were carried out on reservoir models filled with quartz sand, while the analyzed deposits are represented by carbonate limestone rocks. The results obtained on the oil displacement by polymer solutions on reservoir models with terrigenous reservoirs are considered possible for use on objects with carbonate reservoirs with a qualitative justification for the introduction of the polymer flooding method. Experimental studies on the oil displacement from fields with a high content of asphalteneresinous substances with a thickened water rim have established that this method gives the greatest increase in anhydrous and ultimate oil recovery, within a change in the concentration of the polymer solution of 0.2-0.4%, with a rim size of more than 70% of the oil-saturated reservoir volume. Studies on the displacement of high-viscosity oils with polymer solutions have shown that the use of this method of increasing the oil recovery factor in practice is not always economically feasible, due to the need to provide high injection pressures and a high concentration of an expensive polymer solution.
本文介绍了高沥青质-树脂物质油田油过滤性能的实验研究结果。高沥青质-树脂类油藏过滤过程的实验研究表明,与高渗透油藏不同,低渗透油藏的过滤开始遵循非线性规律,随着压力梯度的增大,非线性转变为一条符合达西定律的直线。此外,本文还介绍了在人工油藏模型上用聚合物溶液驱油高沥青质-树脂物质油田的实验研究结果,以确定聚合物溶液的浓度和段塞的尺寸,以提高油藏的采收率。在以石英砂充填的储层模型上进行了聚合物溶液驱油实验研究,分析的储层为碳酸盐岩灰岩。聚合物驱在陆源油藏模型上的驱油结果被认为可以应用于碳酸盐岩油藏,为引入聚合物驱方法提供了定性的依据。对高含油量沥青质物质加厚水环油田的驱油实验研究表明,该方法在聚合物溶液浓度变化0.2-0.4%的范围内,可以最大程度地提高无水采收率和最终采收率,且水环尺寸大于含油饱和油藏体积的70%。用聚合物溶液驱油的研究表明,由于需要提供高注入压力和高浓度昂贵的聚合物溶液,在实践中使用这种提高采收率的方法并不总是经济可行的。
{"title":"INCREASING EFFICIENCY OF THE DISPLACEMENT OF HIGHLY RESINOUS OILS BY POLYMER SOLUTIONS","authors":"G. Moldabaeva, A. Syzdykov, А.А. Zakirov, А.H. Karshiev, S. Abileva, L. Igamberdieva","doi":"10.37878/2708-0080/2022-5.07","DOIUrl":"https://doi.org/10.37878/2708-0080/2022-5.07","url":null,"abstract":"The article presents the experimental results of studies of the filtration properties of oils from fields with a high content of asphaltene-resinous substances. Experimental studies of the filtration process of deposits with a high content of asphaltene-resinous substances have established that in low-permeability, unlike high-permeability reservoirs, the beginning of filtration proceeds according to a nonlinear law, and with an increase in the pressure gradient, the nonlinearity turns into a straight line corresponding to the Darcy law. In addition, the results of experimental studies on the displacement of oil from fields with a high content of asphaltene-resinous substances by polymer solutions on artificially created reservoir models are presented to determine the concentration of the polymer solution and the size of the slug to increase oil recovery from reservoirs. Experimental research on oil displacement by polymeric solutions were carried out on reservoir models filled with quartz sand, while the analyzed deposits are represented by carbonate limestone rocks. The results obtained on the oil displacement by polymer solutions on reservoir models with terrigenous reservoirs are considered possible for use on objects with carbonate reservoirs with a qualitative justification for the introduction of the polymer flooding method. Experimental studies on the oil displacement from fields with a high content of asphalteneresinous substances with a thickened water rim have established that this method gives the greatest increase in anhydrous and ultimate oil recovery, within a change in the concentration of the polymer solution of 0.2-0.4%, with a rim size of more than 70% of the oil-saturated reservoir volume. Studies on the displacement of high-viscosity oils with polymer solutions have shown that the use of this method of increasing the oil recovery factor in practice is not always economically feasible, due to the need to provide high injection pressures and a high concentration of an expensive polymer solution.","PeriodicalId":272594,"journal":{"name":"Neft i gaz","volume":"89 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"130849164","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Neft i gaz
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1