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MICROFACIES AND GEOCHEMICAL CHARACTERISTICSOF THE UPPER DEVONIAN KT-III CARBONATE, EASTERN EDGE OF PRECASPIAN BASIN 前里海盆地东缘上德文KT-III碳酸盐岩的微地层和地球化学特征
Pub Date : 2023-06-15 DOI: 10.37878/2708-0080/2023-3.03
A. Zhanserkeyeva
Deeply buried Devonian sediments of the eastern edge of Precaspian Basin are widely extended; Upper Devonian reef-like deposits can be identified according to seismic surveys and poorly characterized by core material. In the present study depositional environment, predominant biota and diagenetic characteristics of the KT-III carbonate formation are described in order to evaluate reservoir potential. The paper presents the results of determining the mineral composition, geochemical features, sedimentological (identification and description of microfacies) and diagenetic characteristics of the Upper Devonian carbonate sediments of the Urikhtau area (KT-III).
前里海盆地东缘深埋的泥盆纪沉积物广泛延伸;根据地震勘测可以确定上泥盆纪礁状沉积物,但岩心材料对其特征描述不清。本研究描述了 KT-III 碳酸盐地层的沉积环境、主要生物群和成岩特征,以评估储层潜力。本文介绍了确定乌里克陶地区(KT-III)上泥盆统碳酸盐沉积物的矿物成分、地球化学特征、沉积学(微地层的识别和描述)和成岩特征的结果。
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引用次数: 0
CHARACTERISTICS OF THE STRUCTURAL ELEVATIONS MAHAT AND PRIBREZHNOYE ARE LOCALIZED WITHIN THE ZHAZGURLI DEPRESSION 位于扎兹古里洼地的马哈特和普里布列日诺耶结构高地的特征
Pub Date : 2023-06-15 DOI: 10.37878/2708-0080/2023-3.05
E. Merekeyeva, K. Kozhakhmet, A. Alekseyev, A. Seydaliev
The statistics of 3D field seismic work parameters with the use of new methods of attribute analysis for the extraction of structural features were made. In tectonic terms, the study area is timed to the central part of the South-Mangyshlak trough. The structures of the Mahat and Pribrezhnoye are located within the Zhazgurli Depression and the Greater Mangyshlak Flexura.
利用提取构造特征的属性分析新方法,对三维野外地震工作参数进行了统计。从构造角度看,研究区域位于南-曼吉斯拉克海槽的中部。Mahat 和 Pribrezhnoye 构造位于 Zhazgurli 凹陷和大 Mangyshlak 凸台内。
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引用次数: 0
GEOCHEMICAL CHARACTERISTICS OF THE DOMANIKOID-TYPE LATE DEVONIAN STRATA OF THE KOBLANDY-TAMDY UPLIFT 寇布兰-坦米提隆起带晚泥盆世域状地层地球化学特征
Pub Date : 2022-12-30 DOI: 10.37878/2708-0080/2022-6.02
A. Zhanserkeyeva, I. Afonin
The article presents the lithological and geochemical characteristics of the Upper Devonian sediments of the Koblandy structure in the northeastern part of the Precaspian Basin. Based on the core data from the Koblandy-3 well from the Upper Devonian strata of the presalt complex, the results of RockEval and isotopic analysis are presented. Intervals of kerogen-siliceous-carbonate rocks enriched in organic matter have been established, which, according to a complex of microand macrocharacteristics, can be attributed to domanikoid-type sediments. The Domanikoid highcarbon formation of the neighboring Volga-Ural Basin is an effective source rock. The generative potential of the established domanikoid-type sediments of the Koblandy-3 well is characterized by high TOC values of 0.1-5.7%, the Production Index (PI) varies from 0.1-0.3, which corresponds to the oil window. Three lithotypes of domanikoid-type sediments deposited in predominantly deep marine environment have been established. The association of potential reef bodies in the vicinity of domanikoid-type source rocks indicate in favor of petroleum system within the upper Devonian presalt complex of the Koblandy-Tamdy uplift zone
本文介绍了里海盆地东北部科布兰提构造上泥盆统沉积物的岩性和地球化学特征。根据盐下杂岩上泥盆统koblandi -3井岩心资料,介绍了岩心岩石分析和同位素分析结果。建立了富含有机质的干酪根-硅质-碳酸盐岩层段,根据其微观和宏观特征的复合体,可将其归属于陆块类沉积物。邻近的伏尔加-乌拉尔盆地的Domanikoid高碳组是有效的烃源岩。Koblandy-3井已建立的domanikoids型沉积物具有较高的TOC值(0.1 ~ 5.7%),生产指数(PI)在0.1 ~ 0.3之间,对应于产油窗口。建立了三种主要沉积于深海环境的海陆类岩型。在domanikotype烃源岩附近的潜在礁体组合表明,在koblandi - tamdy隆起带上泥盆统盐下杂岩内存在油气系统
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引用次数: 0
THE ROLE OF THE BINDER IN THE COMPOSITION OF CATALYSTS FOR THE HYDROISOMERIZATION PROCESS 粘合剂在加氢异构化过程催化剂组成中的作用
Pub Date : 2022-12-30 DOI: 10.37878/2708-0080/2022-6.13
K. Abdildina, G. Vassilina, I. Klassen
The authors of the publication synthesized bifunctional catalysts based on mesoporous aluminosilicates (MAS) with different binder contents (80 and 65%, respectively) in two ways: the first method consisted in mixing the synthesized aluminosilicate with preliminarily activated bentonite, which was then promoted. Whereas, according to the second method, the synthesized mesoporous aluminosilicate was first promoted, only then mixed with bentonite. The synthesis of bifunctional bimetallic catalysts was carried out using the wet impregnation technique. Acid and physicochemical characteristics were studied using the DRIFT method, TPD-NH3 and the standard nitrogen adsorption/desorption method. It was found that the samples of catalysts with the ratio MAS:H-bentonite = 35:65, prepared according to the first method, have optimal acid characteristics and physicochemical properties.
本文采用两种方法合成了基于不同粘结剂含量(分别为80%和65%)的介孔硅酸铝(MAS)的双功能催化剂:第一种方法是将合成的硅酸铝与初步活化的膨润土混合,然后对其进行促进。而第二种方法是先促进合成介孔铝硅酸盐,然后再与膨润土混合。采用湿浸渍法制备了双功能双金属催化剂。采用DRIFT法、TPD-NH3法和标准氮吸附/解吸法研究了其酸性和理化特性。结果表明,采用第一种方法制备的MAS: h -膨润土= 35:65的催化剂样品具有最佳的酸特性和理化性能。
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引用次数: 0
DEVELOPMENT OF AIR SUPPLY DEVICE FOR DRILLING WELLS WITH BACKWASHING USING AIRLIFT 气举反冲洗钻井送风装置的研制
Pub Date : 2022-12-30 DOI: 10.37878/2708-0080/2022-6.03
M. Biletskiy, B. Ratov, V. Khomenko, E. Koroviaka, B. F. Sabirov, B. Borash
In the work, a comparative analysis of the main methods of creating backwash during well drilling was carried out: using a centrifugal pump and using an airlift. A comprehensive research method was used, including a review and synthesis of scientific and patent publications, analytical studies of methods for creating backwash during well drilling. Their advantages and disadvantages are revealed. The greatest attention is paid to drilling of large-diameter wells with backwash, which is widespread in foreign countries in the development of groundwater reserves. The presented materials showed a clear advantage of this method over others, both in terms of the quantity and quality of produced water, and in terms of well operation. It is shown that, under local conditions, the advantages of this method can have a particularly pronounced effect, and its disadvantages will manifest themselves to a minimal extent. The advantages of rotary backflushing over other drilling methods can be considered proven. It will provide a sharp increase in the utilization rate of local groundwater resources, which is the main problem of local groundwater supply. The need for widespread implementation of this method is obvious. The influence of the upward flow rate of the drilling fluid and its density on the maximum depth of drilling with backwash using an airlift has been studied. An improved device of the circulation system for drilling wells with backwash using an airlift has been developed. Thanks to its use, it becomes possible to use commercially available drill pipes with conventional connections. This allows you to increase the drilling speed by reducing the time spent on tripping operations.
在工作中,对钻井过程中产生反冲洗的主要方法:离心泵和气举法进行了对比分析。采用了综合研究方法,包括对科学和专利出版物的回顾和综合,对钻井过程中产生反冲的方法进行分析研究。揭示了它们的优点和缺点。大直径反冲洗井是开采地下水最受重视的方法,在国外地下水储量开发中应用广泛。所提供的材料表明,无论是在产出水的数量和质量方面,还是在井的操作方面,这种方法都明显优于其他方法。结果表明,在局部条件下,这种方法的优点可以产生特别明显的效果,而其缺点将在最小程度上表现出来。旋转反冲洗相对于其他钻井方法的优势可以被认为是经过验证的。它将大大提高当地地下水资源的利用率,这是当地地下水供应的主要问题。显然,需要广泛实施这种方法。研究了钻井液向上流速及其密度对气举反冲钻进最大深度的影响。研制了一种改进的气举式反冲洗钻井循环系统装置。由于它的使用,可以使用传统连接的市售钻杆。这可以通过减少起下钻作业的时间来提高钻井速度。
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引用次数: 0
PHYSICO-CHEMICAL FEATURES OF AROMATIZATION OF LOWER ALKANE С3 – С4 ON HIGH SILICA ZEOLITE CATALYSTS MODIFIED WITH Zn, LA AND P ADDITIVES Zn、LA和P改性高硅沸石催化剂上低烷烃芳构化С3 - С4的物理化学特性
Pub Date : 2022-12-30 DOI: 10.37878/2708-0080/2022-6.12
A. Temirova
The physicochemical characteristics of zeolite-containing catalysts modified by the introduction of zinc, lanthanum and phosphorus, as well as their activity in the aromatization of propane-butane fractions, have been studied. The maximum amount of aromatic hydrocarbons (43.6%) in the processing of the propane-butane fraction is formed on the Zn-La-P-ZSM-Al2 O3 catalyst at 500 °C, while the selectivity for aromatic hydrocarbons is 80.0%. When processing the propane- propylene fraction in the temperature range of 400-600°C, the yield of aromatic hydrocarbons on the Zn-La-P-ZSM-Al2O3 catalyst is significantly higher compared to other studied catalysts. The activity of catalysts in the processing of light hydrocarbons mainly depends on the structure and state of active centers and the conditions of the process. The results of the study of catalysts by electron microscopy and thermal desorption of ammonia showed that acid sites coexist with metal sites on the surface of the developed catalysts. The composition of acid sites can include metals in various degrees of oxidation, fixed both inside the zeolite cavities and on their outer side. The most active, stable KTG-4 catalyst (Zn-La-P-ZSM-Al2 O3 ) is recommended for pilot testing at gas and oil refineries when processing propane-butane fraction and gases released during catalytic cracking into aromatic hydrocarbons.
研究了锌、镧、磷改性的含沸石催化剂的理化性质及其在丙烷-丁烷馏分芳构化反应中的活性。在500℃的zn - la - p - zsm - al2o3催化剂上,丙烷丁烷馏分的芳香烃生成量最大,为43.6%,芳香烃的选择性为80.0%。在400 ~ 600℃范围内处理丙烷-丙烯馏分时,Zn-La-P-ZSM-Al2O3催化剂上芳烃的产率明显高于其他催化剂。轻烃加工过程中催化剂的活性主要取决于活性中心的结构和状态以及加工条件。对催化剂的电镜和氨热解吸研究结果表明,所研制的催化剂表面酸位与金属位共存。酸位的组成可以包括不同程度氧化的金属,固定在沸石腔的内部和外部。最活跃、最稳定的KTG-4催化剂(zn - la - p - zsm - al2o3)被推荐用于天然气和炼油厂在处理丙烷-丁烷馏分和催化裂化过程中释放的气体时进行中试。
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引用次数: 0
MOSSBAUER AND X-RAY FLUORESCENCE STUDIES OF FLY ASH BASED PROPPANTS 粉煤灰基支撑剂的穆斯堡尔和x射线荧光研究
Pub Date : 2022-12-30 DOI: 10.37878/2708-0080/2022-6.06
A. Shokanov, A. Kyrykbayeva, B. Suleimenov
This article discusses the results of the study of proppants obtained from domestic raw materials - bauxite, kaolin and white clay, sand, as well as fly ash by nuclear gamma resonance spectroscopy (the Mossbauer effect) and X-ray fluorescence analysis. The hyperfine structure, electronic states and elemental composition of proppants are given. The results of the study of volatile ash obtained during pulverized coal burning of Ekibastuz, Shubarkul, Karazhyralinsky deposits at thermal power plants are analyzed. According to the results of the studies, various combinations of complex phases and the elemental composition of proppants were determined using Mossbauer spectroscopy and X-ray fluorescence analysis. The Mossbauer measurements were carried out on the MS1104Em spectrometer in the constant acceleration mode with a 57Co source in a chromium matrix at room temperature. The elemental composition of samples of proppants based on fly ash was determined using an energy dispersive X-ray fluorescence spectrometer (RFS) at the EDX-7000 installation of SHIMADZU.
本文讨论了用核磁共振波谱法(穆斯堡尔效应)和x射线荧光分析对国产铝土矿、高岭土、白粘土、沙子和粉煤灰等原料制备的支撑剂的研究结果。给出了支撑剂的超精细结构、电子态和元素组成。分析了热电厂Ekibastuz、Shubarkul、Karazhyralinsky煤粉燃烧过程中挥发性灰分的研究结果。根据研究结果,利用穆斯堡尔光谱和x射线荧光分析确定了支撑剂的各种复相组合和元素组成。在室温条件下,用57Co源在铬基体中以恒定加速模式在MS1104Em光谱仪上进行了穆斯堡尔测量。在岛津公司的EDX-7000装置上,使用能量色散x射线荧光光谱仪(RFS)测定了基于粉煤灰的支撑剂样品的元素组成。
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引用次数: 0
TECHNOLOGY OF PRODUCTION OF WATERPROOFING MATERIALS BASED ON ASPHALT-RESINOUS-PARAFFIN DEPOSITS AND POLYMERS 基于沥青-树脂-石蜡沉积物和聚合物的防水材料生产技术
Pub Date : 2022-12-30 DOI: 10.37878/2708-0080/2022-6.08
P. Tanzharikov, A. Tashimova
Complexes for processing, utilization and neutralization of oil wastes do not allow to significantly reduce the volume of oil wastes and eliminate objects of temporary disposal of oil wastes. Therefore, it is necessary to minimize the runoff of waste sent for recycling, with maximum distribution and use of a group of wastes with useful properties. It is necessary to build a centralized or decentralized network of installations for the disposal of solid oil wastes. The article discusses the ways of disposal of oil wastes in the course of research and promising solutions. The composition of the formed ASF at the Akshabulak field has been verified, the composition has been determined and studied.
处理、利用和中和油废物的综合设施不能显著减少油废物的体积,不能消除油废物临时处置的对象。因此,有必要尽量减少送去回收的废物的径流,最大限度地分配和利用一组具有有用特性的废物。有必要建立集中或分散的固体油类废物处置设施网络。本文讨论了研究过程中油类废弃物的处理方法和解决方案。对Akshabulak油田已形成的ASF的组成进行了验证,并对其组成进行了测定和研究。
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引用次数: 0
STUDY OF THE RHEOLOGICAL PROPERTIES OF COMPOSITE POLYMER STABILIZERS FOR DRILLING FLUIDS 复合聚合物钻井液稳定剂的流变性能研究
Pub Date : 2022-12-30 DOI: 10.37878/2708-0080/2022-6.09
Z. Artykova, О.К. Beysenbayev, S. Sakibayeva, К.S. Nadirov
This article presents the results of experimental data on the preparation of a composite heatresistant reagent for drilling fluids, including a modified copolymer based on polyacrylonitrile (by hydrolysis in the absence of a mixture of sodium hydroxide) and vinylsulfonic acid. A thermally stable composite reagent to polyvalent cations has been obtained, which reduces filtration and improves the anti-wear properties of clay suspensions. The values of the optimal reaction time and temperature were determined, the viscosity of the sampled polymer solutions was determined. The ratio of monomers and modification conditions are selected, this ensures a high conversion of monomers, and also increases the yield of the final product. The synthesized polymer of acrylonitrile and in the presence of fatty acids of gossypol resin and sulfuric acid in the pH = 3.5-5.5, with subsequent modification. The synthesized water-soluble polymer has a diphilic structure throughout the structure, the macromolecules of which contain a hydrophobic group and a hydrophilic part. They are able to adsorb and lower the interfacial free energy, which allows them to be classified as high-molecular surfactants.
本文介绍了制备一种钻井液复合耐热试剂的实验数据结果,包括一种基于聚丙烯腈(在没有氢氧化钠混合物的情况下通过水解)和乙烯基磺酸的改性共聚物。制备了一种热稳定的多价阳离子复合剂,减少了粘土悬浮液的过滤,提高了其抗磨性能。确定了最佳反应时间和温度,测定了所得聚合物溶液的粘度。通过对单体配比和改性条件的选择,既保证了单体的高转化率,又提高了最终产品的收率。在pH = 3.5-5.5的条件下,合成丙烯腈聚合物并在棉酚树脂和硫酸的脂肪酸存在下,进行后续改性。所合成的水溶性聚合物在整个结构中具有二亲性结构,其大分子中含有疏水基团和亲水部分。它们能够吸附并降低界面自由能,这使得它们可以被归类为高分子表面活性剂。
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引用次数: 0
HYDRO-MECHANICAL DRILLING OF WELLS 水力机械钻井
Pub Date : 2022-12-30 DOI: 10.37878/2708-0080/2022-6.04
T. Mendebaev, N. Smashov, ZH.K. Nurkhanova
The solution to the problems of the construction of deep wells is possible when creating downhole tools on a fundamentally new ideological basis, involving physical principles, technical solutions unconventional in the field of drilling equipment. It is important to take into account the energy resources that increase with depth. Following this concept, based on the tasks of geological exploration, a downhole layout has been developed and introduced into the production of drilling wells, with design features and technological capabilities focused on a comprehensive solution to the problems of well wiring. Structurally, the downhole layout aimed at maximizing the potential energy of the working fluid is universal, designed for drilling wells with core sampling of increased diameter (100 mm or more), and with a solid face. In addition to the outer pipe and core receiver, the downhole layout is equipped with diamond drill heads with a stepped matrix, with a separate system of flushing channels, collectively realizing the effect of hydro-mechanical destruction of rocks. By introducing into the composition of the bottom-hole layout, converting the ascending flow into a rotational-ascending one, the problem of removing sludge from under the end of the stepped matrix is effectively solved. Production tests of the downhole layout with core sampling were carried out at the polymetals deposit of Central Kazakhstan, solid face during drilling of groundwater wells in the territory of the Almaty region. According to the results of production tests, it was found that the hydro-mechanical destruction of rocks is especially effective in combination with diamond drill heads with a stepped matrix. The presence of a turbulator-expander in the bottom-hole layout made it possible to significantly increase the amount of incoming sludge of drilled rock in the well sump, especially when drilling wells with a solid face. In comparable geological and technical conditions of drilling wells, serial core sets HQ with a drilling diameter of 95.6 mm had the following indicators: energy consumption – 2.1-2.4 kW / hour, core yield with a diameter of 63 mm – 93%, specific lumpiness of the core – 5-8 pcs / per linear meter of drilling, drilling was carried out at an axial load of 2200-2500 kgf, rotation speed 500-700 rpm. Similar indicators of the downhole layout: energy consumption – 1.2-1.5 kW / hour, core yield – 98-100% with a diameter of 112 mm, specific lumpiness – 2-3 pieces, axial load – 700-900 kgf, rotation speed – 300-400 rpm.
在全新的思想基础上创造井下工具,包括钻井设备领域的物理原理和非常规技术解决方案,就有可能解决深井施工问题。重要的是要考虑到随深度增加的能量资源。根据这一概念,基于地质勘探的任务,开发了一种井下布局,并将其引入到钻井生产中,其设计特点和技术能力侧重于全面解决井布线问题。从结构上讲,旨在使工作流体势能最大化的井下布置是通用的,适用于岩心取样直径增大(100mm或更大)、工作面坚固的井。除了外管和岩心接收器外,井下布置还配备了阶梯式矩阵的金刚石钻头,并配有单独的冲洗通道系统,共同实现了水力机械破坏岩石的效果。通过引入井底布置的组成,将上升流转化为旋转上升流,有效地解决了阶梯式基质末端下污泥的去除问题。在阿拉木图地区地下水井钻探过程中,在哈萨克斯坦中部多金属矿床固体工作面进行了岩心取样的井下布置生产试验。生产试验结果表明,与阶梯型金刚石钻头配合使用,对岩石的水-力破坏尤为有效。在井底布置中使用涡轮膨胀器,可以显著增加进入井池的已钻岩石污泥量,特别是在实心面钻井时。在可比较的钻井地质和技术条件下,钻径95.6 mm的HQ系列岩心组的能耗为2.1 ~ 2.4 kW / h,钻径63 mm的岩心产量为93%,岩心比块度为5 ~ 8个/每直线米,钻轴向载荷为2200 ~ 2500 kgf,转速为500 ~ 700 rpm。井下布置的类似指标:能耗1.2-1.5 kW / h,岩心产量98-100%,直径为112 mm,比块度2-3片,轴向载荷700-900 kgf,转速300-400 rpm。
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引用次数: 0
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