Coordination Chemistry Reviews最新文献_第5页

Progress in metal-organic frameworks (MOFs) as multifunctional material: Design, synthesis and anticorrosion performance techniques 作为多功能材料的金属有机框架（MOFs）的研究进展：设计、合成和防腐性能技术

IF 20.3 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2024-10-29 DOI: 10.1016/j.ccr.2024.216294

Kashif Rahmani Ansari , Ambrish Singh , Muhammad Younas , Ismat H. Ali , Yuanhua Lin

In the past few years, researchers have emphasized the development of metal-organic frameworks (MOFs), which are made up of metallic ions and organic compounds as ligands. MOFs have an extensive list of potential applications as corrosion-inhibiting nanomaterials due to inherent notable characteristics, which include an enormous effective area, pore size manipulation, changeable behavior and molecular framework, and a wide range of potentially active domains. The current review focuses on the latest research on the utilization of metal-organic frameworks as anti-corrosive material. Herein, this review focuses on the latest research progress of MOF-based corrosion protection materials and reviews their anticorrosion performance, including the commonly concerned synthesis approaches of MOFs for corrosion protection with their respective advantages and shortcomings, the different anticorrosion applications, latest techniques used for screening MOF corrosion inhibition performance and the presented challenges that need to be conquered in practical applications. Meanwhile, we explained the corrosion protection mechanisms of MOFs when serve as inhibitors, nano-containers, and surface protecting coatings. At the end of this review, the future outlooks of MOFs for corrosion protection is provided, we hope this review will illuminate the achievement of high performed anticorrosion MOFs and offer new ideas for the development of MOF-based materials for future corrosion protection application.

在过去几年中，研究人员重点开发了金属有机框架（MOFs），它由金属离子和作为配体的有机化合物组成。MOFs 具有固有的显著特点，包括巨大的有效面积、孔径可调、可改变的行为和分子框架以及广泛的潜在活性域，因此作为缓蚀纳米材料具有广泛的潜在应用。本综述重点关注利用金属有机框架作为防腐蚀材料的最新研究。本综述重点介绍了基于 MOF 的防腐材料的最新研究进展及其防腐性能，包括人们普遍关注的 MOFs 防腐合成方法及其各自的优缺点、不同的防腐应用领域、用于筛选 MOF 缓蚀性能的最新技术以及在实际应用中需要克服的挑战。同时，我们还解释了 MOFs 作为抑制剂、纳米容器和表面保护涂层时的腐蚀保护机制。在综述的最后，我们对MOFs在腐蚀防护领域的未来发展进行了展望，希望这篇综述能阐明高性能防腐MOFs所取得的成就，并为MOF基材料在未来腐蚀防护应用领域的发展提供新思路。

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引用次数: 0

Cuproptosis nanomedicine in cancer therapy: Novel insights and future perspectives 癌症治疗中的杯突症纳米药物：新见解和未来展望

IF 20.3 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2024-10-26 DOI: 10.1016/j.ccr.2024.216284

Lu Wang , Jingxuan Piao , Hengkai Qi , Chu Qiao , Qiqiang Guo , Minjie Wei , Zhenhua Li

Cuproptosis, a new type of copper-triggered programmed cell death, has recently emerged as a promising target for cancer treatment. The nanomedicine-based targeting of cuproptosis has experienced significant advancements, attracting enormous interest and opening new avenues for developing novel therapeutics. In this review, we provide a comprehensive summary of the biology of copper, its critical roles in cancer biology, and the molecular mechanisms underlying cuproptosis. We also offer insight into recent progress in nanomedicine-triggered cuproptosis, a potent and proof-of-concept application in innovative therapeutic strategies. Finally, we highlight future perspectives and challenges, including the clinical translation of cancer nanomedicine and new cuproptosis-mediated emerging paradigms.

铜突细胞增多症是一种由铜触发的新型程序性细胞死亡，最近已成为一种很有前景的癌症治疗靶点。以纳米药物为基础的杯突症靶向研究取得了重大进展，引起了人们的极大兴趣，并为开发新型疗法开辟了新途径。在这篇综述中，我们全面总结了铜的生物学特性、铜在癌症生物学中的关键作用以及铜氧化的分子机制。我们还深入探讨了纳米药物触发的铜突变的最新进展，这是创新治疗策略中一种有效的概念验证应用。最后，我们强调了未来的前景和挑战，包括癌症纳米药物的临床转化和杯突症介导的新范例。

引用次数: 0

Electronic structure modulation in Prussian blue and its analogs: Progress and challenges in perspective of energy-related catalysis 普鲁士蓝及其类似物的电子结构调制：从能源相关催化的角度看进展与挑战

IF 20.3 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2024-10-24 DOI: 10.1016/j.ccr.2024.216288

Baghendra Singh , Yogita Arya , Goutam Kumar Lahiri , Arindam Indra

Prussian blue, a more than three hundred years old inorganic coordination polymer, has drawn immense interest in the field of energy conversion. Prussian blue (PB) and Prussian blue analogs (PBAs) have been extensively used for water oxidation, hydrogen evolution, oxygen reduction, nitrogen reduction reaction, etc. In addition, PB and PBAs were explored as the cocatalysts for photocatalytic and photoelectrochemical energy conversion processes. Although initial studies focused on the development of morphology, porosity, surface area, accessible catalytic sites, core-shell structure, etc., the tuning of the electronic structure was found to largely influence the electrochemical features of PB and PBAs. The inter-valence charge transport in PB and PBAs through the –CN bridge can also be modulated by altering the electronic structure of the metal sites. This, in turn, offers a significant modification of its properties as a cocatalyst when combined with a semiconductor. The present review article addresses the effect of electronic structural modulation in PB and PBAs to improve its electrocatalytic and cocatalytic activities. The recent achievements and challenges in designing PBAs and their application in energy conversion have been highlighted along with potential future advancements. Special emphasis has been given to understanding structural aspects and the subsequent establishment of a structure-activity relationship for energy conversion processes.

普鲁士蓝是一种具有三百多年历史的无机配位聚合物，在能量转换领域引起了人们的极大兴趣。普鲁士蓝（PB）和普鲁士蓝类似物（PBAs）已被广泛用于水氧化、氢进化、氧还原、氮还原反应等。此外，普鲁士蓝和普鲁士蓝类似物还被探索用作光催化和光电化学能量转换过程的共催化剂。尽管最初的研究主要集中在形貌、孔隙率、表面积、可触及的催化位点、核壳结构等方面，但研究发现电子结构的调整在很大程度上影响着 PB 和 PBA 的电化学特性。通过改变金属位点的电子结构，还可以调节 PB 和 PBA 中通过-CN 桥的价间电荷传输。这反过来又极大地改变了其与半导体结合后作为共催化剂的特性。本综述文章探讨了电子结构调制对 PB 和 PBA 的影响，以改善其电催化和助催化活性。文章重点介绍了设计 PBAs 及其在能量转换中应用的最新成就和挑战，以及未来可能取得的进展。特别强调了对结构方面的理解以及随后建立能量转换过程的结构-活性关系。

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引用次数: 0

Interfacial adhesion in flexible electronics: Materials, structures and applications 柔性电子器件中的界面粘附：材料、结构和应用

IF 20.3 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2024-10-24 DOI: 10.1016/j.ccr.2024.216278

Mingyang Lu , Jia You , Mengjie Gao , Wendong Li , Cancan Zhang , Bolin Zhu , Chong Peng , Shiteng Wu , Dazhenlamu , Wei Ren , Guangxian Li , Chuan Fei Guo , Junlong Yang

Flexible electronics, featuring low thinness, high conformability, multifunctionality, and high portability, have revolutionized the interaction experiences of human beings. This emerging technology is also ushering in groundbreaking advancements in intelligent manufacturing, humanoid robots, and digital medicine. However, the diverse functionalities and applications of flexible electronics often require integration of multilayer interfaces in devices. The assembly of such multilayer and multimaterial structures frequently faces challenges of interfacial incompatibilities of interfaces, including the mismatch in mechanical properties, chemistry, and functionalities. These challenges can compromise the long-term reliability and efficiency of either the interfaces in a device or the interface between a device and human tissues/robots. A seamlessly integrated flexible electronic device not only mitigates the risk of interfacial delamination but also enhances the mechanical stability of the device in dynamic or multifaceted environments. This manuscript offers an exhaustive review on tough interfaces in flexible electronics enabled by physical interactions, covalent chemical bonds or structural designs. Moreover, considering their primary applications — skin-wearables, implantable, and robotics — we delve into the latest breakthroughs, persistent challenges, and pragmatic strategies associated with reinforced adhesive interfaces. Such a discussion furnishes invaluable perspectives for the conceptualization and fabrication of highly durable flexible devices.

柔性电子产品具有轻薄、高适配性、多功能性和高便携性等特点，彻底改变了人类的交互体验。这一新兴技术也为智能制造、仿人机器人和数字医疗带来了突破性进展。然而，柔性电子产品的多种功能和应用往往需要在设备中集成多层接口。这种多层和多材料结构的组装经常面临界面不相容的挑战，包括机械性能、化学性质和功能的不匹配。这些挑战可能会影响设备界面或设备与人体组织/机器人之间界面的长期可靠性和效率。无缝集成的柔性电子设备不仅能降低界面分层的风险，还能增强设备在动态或多元环境中的机械稳定性。本手稿详尽评述了柔性电子器件中通过物理相互作用、共价化学键或结构设计实现的韧性界面。此外，考虑到它们的主要应用（皮肤可穿戴设备、植入式设备和机器人），我们深入探讨了与增强型粘合剂界面相关的最新突破、持续挑战和实用策略。这样的讨论为构思和制造高度耐用的柔性设备提供了宝贵的视角。

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引用次数: 0

SERS-based microfluidic sensor for sensitive detection of circulating tumor markers: A critical review 基于 SERS 的微流控传感器用于灵敏检测循环肿瘤标志物：综述

IF 20.3 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2024-10-23 DOI: 10.1016/j.ccr.2024.216289

Yeru Wang , Rongke Gao , Changbiao Zhan , Huakun Jia , Xiaozhe Chen , Yang Lu , Yujie Feng , Liandong Yu

Cancer ranks as the second leading cause of death worldwide, and many researchers have found that early screening and diagnosis greatly reduce cancer-related mortality. The use of circulating tumor markers (CTMs) in cancer diagnostics is well warranted, given the potential for CTMs to provide valuable insights into the occurrence and development of cancer. The past two decades have witnessed remarkable advancements in microfluidics based on surface-enhanced Raman spectroscopy (SERS) in the field of biomedicine. It has become a well-established technology for CTM detection. Throughout this review, recent developments of SERS-based microfluidic technology within the realm of CTM detection, including classification, identification, and capture methods, detection mode, as well as novel strategies and applications, have been highlighted. The purpose is to emphasize the importance of detection methods rooted in SERS-based microfluidic technology in biomedicine, as well as to promote their expansion towards various applications.

癌症是全球第二大死因，许多研究人员发现，早期筛查和诊断可大大降低癌症相关死亡率。鉴于循环肿瘤标志物 (CTM) 有可能为癌症的发生和发展提供有价值的信息，因此在癌症诊断中使用循环肿瘤标志物 (CTM) 是非常有必要的。过去二十年来，基于表面增强拉曼光谱（SERS）的微流体技术在生物医学领域取得了长足的进步。它已成为一种成熟的 CTM 检测技术。本综述重点介绍了基于 SERS 的微流控技术在 CTM 检测领域的最新发展，包括分类、识别和捕获方法、检测模式以及新型策略和应用。目的是强调基于 SERS 的微流控技术的检测方法在生物医学中的重要性，并促进其向各种应用领域扩展。

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引用次数: 0

Recent advances of piezoelectric materials used in sonodynamic therapy of tumor 用于肿瘤声动力疗法的压电材料的最新进展

IF 20.3 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2024-10-22 DOI: 10.1016/j.ccr.2024.216282

Hezhe Huang, Yuqing Miao, Yuhao Li

Piezoelectric materials, recognized as unique functional materials due to their ability to interconvert mechanical and electrical energy, have demonstrated broad application prospects in the biomedical field. Particularly in cancer therapy, piezoelectric materials serve as sonosensitizers that generate internal electric fields under ultrasonic-induced mechanical force, modulating the migration of electrons and holes, and subsequently triggering surface redox reactions to enhance the efficacy of sonodynamic therapy (SDT). SDT, as an emerging non-invasive treatment modality, showcases distinctive advantages such as high tissue penetration, strong spatiotemporal controllability, and low treatment costs due to the synergistic interaction between ultrasound and sonosensitizers. This review systematically discusses various types of piezoelectric materials, with a focus on the recent research progress, mechanisms of action, and optimization strategies of novel materials like perovskites in the SDT domain. Additionally, the applications of piezoelectric materials in the combined treatment of SDT with other therapies are introduced, and the prospects and potential of these materials in tumor sonodynamic therapy are highlighted. By delving into the fundamental principles of the piezoelectric effect and its mechanistic role in SDT, this review offers new perspectives and insights into the biomedical applications of piezoelectric materials.

压电材料是公认的独特功能材料，具有机械能和电能相互转换的能力，在生物医学领域具有广阔的应用前景。特别是在癌症治疗领域，压电材料可作为声敏剂，在超声波诱导的机械力作用下产生内电场，调节电子和空穴的迁移，进而引发表面氧化还原反应，提高声动力疗法（SDT）的疗效。作为一种新兴的非侵入性治疗方式，声动力疗法具有组织穿透力强、时空可控性强、治疗成本低等独特优势，这得益于超声波与声敏化剂之间的协同作用。本综述系统地讨论了各种类型的压电材料，重点介绍了 SDT 领域中包晶石等新型材料的最新研究进展、作用机制和优化策略。此外，还介绍了压电材料在 SDT 与其他疗法联合治疗中的应用，并强调了这些材料在肿瘤声动力疗法中的前景和潜力。通过深入研究压电效应的基本原理及其在 SDT 中的机理作用，本综述为压电材料的生物医学应用提供了新的视角和见解。

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引用次数: 0

Coordination structure engineering of single atoms derived from MOFs for Electrocatalysis 用于电催化的 MOFs 单原子配位结构工程

IF 20.3 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2024-10-22 DOI: 10.1016/j.ccr.2024.216281

Min Song, Qian Zhang, Guanyu Luo, Hanyu Hu, Deli Wang

Metal-organic frameworks (MOFs) have attracted increasing attention as potential precursors for the synthesis of single atom catalysts (SACs) due to the high specific surface area, adjustable pore size, and ligand structure. Although significant efforts have been made to synthesize MOFs-derived SACs for electrocatalysis, it is still lack of fundamental regulation principles which governing the intrinsic electrocatalytic performance. In this review, the recent advancements in various MOFs-derived SACs are systematically summarized. The correlation between the central metal atoms, coordination atoms, local environment, morphology, and their corresponding electrocatalytic performance, including activity, selectivity and stability, is comprehensively analyzed. Furthermore, advanced characterization techniques are summarized to elucidate the ligand configuration of MOFs-derived SACs. Finally, the major challenges and future research directions for MOFs-derived SACs are proposed. This review provides a comprehensive understanding and updated information on the design of MOFs-derived SACs with well-confined coordination structures.

金属有机框架（MOFs）具有高比表面积、可调孔径和配体结构等特点，是合成单原子催化剂（SACs）的潜在前体，因此受到越来越多的关注。尽管人们在合成用于电催化的 MOFs 衍生 SACs 方面做出了巨大努力，但仍然缺乏制约其内在电催化性能的基本调节原理。本综述系统地总结了各种 MOFs 衍生 SAC 的最新进展。全面分析了中心金属原子、配位原子、局部环境、形态与其相应的电催化性能（包括活性、选择性和稳定性）之间的相关性。此外，还总结了先进的表征技术，以阐明 MOFs 衍生 SAC 的配体构型。最后，提出了 MOFs 衍生 SAC 的主要挑战和未来研究方向。本综述为设计具有良好配位结构的 MOFs 衍生 SAC 提供了全面的了解和最新的信息。

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引用次数: 0

State of the art in organometallic ruthenium metallodrugs for breast cancer treatment: Advances and innovations 有机金属钌金属药物治疗乳腺癌的最新进展：进展与创新

IF 20.3 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2024-10-22 DOI: 10.1016/j.ccr.2024.216252

Elena Domínguez-Jurado , Agustín Lara-Sánchez , Iván Bravo , Alberto Ocaña , Carlos Alonso-Moreno

Cancer is a major health concern and a leading cause of death worldwide. Among all cancer types, breast cancer has the highest incidence rate. The treatment of breast cancer encompasses the use of different drugs, with ruthenium metallodrugs emerging as promising alternatives to platinum derivatives. In this context, organometallic ruthenium(II) compounds are currently the most widely explored.

This review compiles all the organometallic ruthenium compounds described in the literature to date for the treatment of breast cancer. Additionally, it covers the use of ruthenium-based metallodrugs in combination therapy, phototherapy, and nanotechnology.

癌症是一个重大的健康问题，也是全球死亡的主要原因。在所有癌症类型中，乳腺癌的发病率最高。乳腺癌的治疗包括使用不同的药物，而钌金属药物作为铂衍生物的替代品正在崭露头角。在这方面，有机金属钌（II）化合物是目前研究最为广泛的。本综述汇编了迄今为止文献中描述的用于治疗乳腺癌的所有有机金属钌化合物。此外，它还涉及钌基金属药物在联合治疗、光疗和纳米技术中的应用。

引用次数: 0

Design and engineering of MOF/LDH hybrid nanocomposites and LDHs derived from MOF templates for electrochemical energy conversion/storage and environmental remediation: Mechanism and future perspectives 用于电化学能量转换/存储和环境修复的 MOF/LDH 混合纳米复合材料和 MOF 模板衍生的 LDH 的设计与工程：机理与未来展望

IF 20.3 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2024-10-22 DOI: 10.1016/j.ccr.2024.216256

Reza Abazari , Soheila Sanati , Wei Keen Fan , Muhammad Tahir , Susanginee Nayak , Kulamani Parida , Mahmoud El-Shahat , Reda M. Abdelhameed , Dmytro S. Nesterov , Alexander M. Kirillov , Jinjie Qian

The ongoing search for sustainable and renewable energy solutions to combat energy shortages and mitigate environmental pollution remains an urgent priority. It catalyzes the rapid evolution of cutting-edge technologies for energy storage and environmental remediation, hinging on advanced functional materials. In addition to the unprecedentedly high surface area and tunable porous structures of metal-organic frameworks (MOFs), its well-organized frameworks make them ideal templates for designing layered double hydroxides (LDHs) and their hybrids. MOF-derived LDHs boasts improved conductivity, stability, and structural adjustability. While MOF/LDH hybrids expose more active sites, leading to augmented catalytic activity and adsorption performance. Hence, this review provides a deep dive into the prospects of MOF-derived LDHs and MOF/LDH hybrids as materials for green energy production, storage, and environmental applications. The structure-property relationship, synthetic mechanism and procedure for the MOF-templated LDH and MOF/LDH composites are thoroughly reviewed. The fundamentals, reaction mechanism and active sites involved for electrochemical energy production and storage are discussed. A comprehensive review is then conducted on the recent advances in utilizing these materials for energy storage and conversion (batteries, supercapacitors, electrocatalysts), as well as environmental applications. Finally, it highlights the advantages, challenges, and future directions in designing MOF/LDH hybrids and LDHs derived from MOF templates. This review serves as a roadmap on utilizing MOFs as templates/components to synthesize advanced functional materials for the future of energy security and environmental salvation.

当务之急是不断寻求可持续和可再生能源解决方案，以应对能源短缺和减轻环境污染。这推动了以先进功能材料为基础的能源储存和环境修复尖端技术的快速发展。除了金属有机框架（MOFs）前所未有的高表面积和可调多孔结构外，其良好的组织框架使其成为设计层状双氢氧化物（LDHs）及其混合物的理想模板。MOF 衍生的层状双氢氧化物具有更好的导电性、稳定性和结构可调性。而 MOF/LDH 混合物则暴露了更多的活性位点，从而提高了催化活性和吸附性能。因此，本综述深入探讨了 MOF 衍生的 LDHs 和 MOF/LDH 杂化物作为绿色能源生产、储存和环境应用材料的前景。本综述深入探讨了 MOF 引发的 LDH 和 MOF/LDH 复合材料的结构-性能关系、合成机理和过程。讨论了电化学能源生产和储存的基本原理、反应机制和活性位点。然后全面回顾了利用这些材料进行能量存储和转换（电池、超级电容器、电催化剂）以及环境应用的最新进展。最后，它强调了设计 MOF/LDH 混合体和从 MOF 模板衍生的 LDH 的优势、挑战和未来方向。这篇综述为利用 MOFs 作为模板/组分合成先进功能材料提供了路线图，有助于未来的能源安全和环境拯救。

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引用次数: 0

Transformation of metal-organic frameworks (MOFs) under different factors 金属有机框架（MOFs）在不同因素下的转变

IF 20.3 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2024-10-21 DOI: 10.1016/j.ccr.2024.216263

Yilei Xiang , Suosu Wei , Taoxiang Wang , Huang Li , Yan Luo , Bing Shao , Ningyuan Wu , Yiji Su , Linbin Jiang , Jin Huang

Metal-organic frameworks (MOFs) have been widely used in physics, chemistry, and medicine due to their large porosity and adjustable pores, high specific surface area, and good chemical and thermal stability. Most MOFs are structurally stable, but they still undergo morphological transformation and structural transformation under the stimulating factors, and these transformations are unavoidable. In this paper, we focus on the transformations of MOF under the different factors, such as chemistry, electrochemistry, photochemistry, thermochemistry and so on. Structure-property relationship is also discussed. What's more, the future development trends and challenges of MOF are also described.

金属有机框架（MOFs）具有孔隙率大、孔隙可调、比表面积高、化学和热稳定性好等特点，已被广泛应用于物理、化学和医学领域。大多数 MOF 结构稳定，但在刺激因素的作用下仍会发生形态转变和结构转变，这些转变是不可避免的。本文重点探讨了 MOF 在化学、电化学、光化学、热化学等不同因素作用下的转变。此外，还讨论了结构与性能之间的关系。此外，还阐述了 MOF 的未来发展趋势和挑战。

引用次数: 0