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Metal-organic framework-hydrogel composites as emerging platforms for enhanced wound healing applications: Material design, therapeutic strategies, and future prospects 金属有机框架-水凝胶复合材料作为增强伤口愈合应用的新兴平台:材料设计、治疗策略与未来前景
IF 20.3 1区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2024-11-14 DOI: 10.1016/j.ccr.2024.216330
Fereshte Hassanzadeh Afruzi , Majid Abdouss , Ehsan Nazarzadeh Zare , Erfan Rezvani Ghomi , Shima Mahmoudi , Rasoul Esmaeely Neisiany
Wound healing remains a significant global healthcare challenge, particularly for chronic and complex wounds, imposing the development of advanced therapeutic materials with improved functionality and efficacy. The emergence of hybrid and composite materials offers promising solutions to the multifaceted challenges of wound healing, including infection control and tissue regeneration. Metal-organic frameworks (MOFs) have gained attention due to their high porosity, large surface areas, structural tunability, and potential to incorporate therapeutic agents, making them ideal candidates for wound healing applications. Additionally, hydrogels are recognized for their soft, porous, extracellular matrix-like structure, moisturizing properties, and biocompatibility, which make them valuable in wound care. The integration of MOFs with hydrogels creates synergistic hybrid systems that combine the exceptional cargo-loading capacity and controllable degradation of MOFs with the biocompatibility and moisture-retention properties of hydrogels. This results in enhanced wound healing potential compared to the individual components. This article overviews the wound healing process and current therapeutic challenges, surveys the biomedical applications of MOFs and hydrogels individually, and presents their preparation methods. A detailed analysis of MOF-hydrogel composites (MOF-HCs) is provided including their functionality, wound-healing mechanisms, closure capabilities, and biocompatibility. This article also offers critical insights, supported by a thorough review of current research. Finally, the existing challenges and proposed future directions are highlighted, offering valuable perspectives for researchers in the field.
伤口愈合仍然是全球医疗保健领域面临的重大挑战,尤其是对于慢性和复杂伤口而言,这就要求开发功能更强、疗效更好的先进治疗材料。混合材料和复合材料的出现为应对伤口愈合的多方面挑战(包括感染控制和组织再生)提供了前景广阔的解决方案。金属有机框架(MOFs)因其孔隙率高、比表面积大、结构可调以及具有结合治疗剂的潜力而备受关注,成为伤口愈合应用的理想候选材料。此外,水凝胶因其柔软、多孔、类似细胞外基质的结构、保湿特性和生物相容性而得到认可,这使其在伤口护理方面具有重要价值。MOFs 与水凝胶的结合产生了协同混合系统,将 MOFs 卓越的载货能力和可控降解与水凝胶的生物相容性和保湿特性结合在一起。与单个成分相比,它能增强伤口愈合潜力。本文概述了伤口愈合过程和当前的治疗挑战,调查了 MOFs 和水凝胶各自的生物医学应用,并介绍了它们的制备方法。文章详细分析了 MOF-水凝胶复合材料(MOF-HCs),包括其功能性、伤口愈合机制、闭合能力和生物相容性。本文还通过对当前研究的全面回顾,提出了重要见解。最后,文章强调了现有的挑战和建议的未来方向,为该领域的研究人员提供了宝贵的视角。
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引用次数: 0
Unveiling the mysteries of hydrogen spillover phenomenon in hydrogen evolution reaction: Fundamentals, evidence and enhancement strategies 揭开氢进化反应中氢溢出现象的神秘面纱:基本原理、证据和增强策略
IF 20.3 1区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2024-11-13 DOI: 10.1016/j.ccr.2024.216321
Shan Zhao , Zhen-Hong Wang , Jing-Yu Wang , Peng-Fei Wang , Zong-Lin Liu , Jie Shu , Ting-Feng Yi
The phenomenon of hydrogen spillover is a dynamic behavior during catalytic reactions and has been a prominent area of research in the field of thermal catalysis. This concept has become a new focus of research in the field of hydrogen evolution reaction (HER) in recent years. The hydrogen spillover effect has a pivotal effect on modulating the active sites of catalysts and enhancing catalytic activity, which also provides a novel perspective for optimizing HER catalysts. While some advancements have been achieved in understanding the hydrogen spillover phenomenon, the existing review is deficient in a systematic overview of the mechanism of hydrogen spillover occurrence during HER and a summary of the evidence to confirm the occurrence of the hydrogen spillover phenomenon particularly. Furthermore, a comprehensive summary of the specific strategies to optimize the catalytic system using this effect is lacking. In light of the aforementioned considerations, this review aims to conduct a comprehensive summary of the fundamental mechanisms underlying the phenomenon of hydrogen spillover, with a particular focus on the evidence presented in experimental studies. Following a comprehensive examination of the underlying mechanism and supporting evidence, the discussion turns to the question of how the hydrogen spillover effect can be strategically enhanced to optimize the overall performance of HER. Finally, the opportunities and challenges facing this research area are discussed, and potential future research directions are outlined. This review not only enhances comprehension of how hydrogen spillover occurs in the HER process but also offers invaluable theoretical insight and practical strategies for the creation of new and efficient catalysts.
氢溢出现象是催化反应过程中的一种动态行为,一直是热催化领域的一个突出研究领域。近年来,这一概念已成为氢进化反应(HER)领域研究的新焦点。氢溢出效应在调节催化剂活性位点和提高催化活性方面具有举足轻重的作用,这也为优化 HER 催化剂提供了一个新的视角。尽管在理解氢溢出现象方面已经取得了一些进展,但现有综述在系统概述 HER 过程中氢溢出发生的机理以及总结证实氢溢出现象发生的证据方面还存在不足。此外,还缺乏对利用这种效应优化催化系统的具体策略的全面总结。鉴于上述考虑,本综述旨在对氢溢出现象的基本机制进行全面总结,尤其侧重于实验研究中提出的证据。在对基本机制和支持性证据进行全面研究之后,讨论将转向如何从战略上增强氢溢出效应,以优化 HER 的整体性能。最后,讨论了这一研究领域面临的机遇和挑战,并概述了潜在的未来研究方向。这篇综述不仅加深了人们对氢冷反应过程中如何发生氢溢出效应的理解,还为创造新型高效催化剂提供了宝贵的理论见解和实践策略。
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引用次数: 0
Leveraging mechanistic insight to design hydrolytic nanozymes 利用机理洞察力设计水解纳米酶
IF 20.3 1区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2024-11-13 DOI: 10.1016/j.ccr.2024.216340
Ziqi Zhang , Zhen Chen , Yiqing Zhang , Zichang Wang , Dehong Chen , Jing Liu , Zhiling Zhu
Hydrolytic nanozymes have emerged as promising candidates for diverse applications across pharmaceuticals, chemicals, environmental remediation, food, and paper industries. Despite their potential, research on hydrolytic nanozymes remains significantly underdeveloped, accounting for only 14.4 % of all nanozyme studies (1256 papers out of 8737). A critical gap exists in understanding the catalytic mechanisms and design strategies of these nanozymes, hindering their theoretical advancement and practical utilization. This review aims to address this gap by systematically organizing and summarizing the catalytic mechanisms of hydrolytic nanozymes, categorized by structural composition and substrate type, along with the design approaches ranging from biomimetic strategies to the cutting-edge data-driven methods, providing theoretical insights to guide the rational design and efficient development of hydrolytic nanozymes. Furthermore, this review offers perspectives on the future prospects and challenges in the field, aiming to inspire further research and innovation in this rapidly advancing area.
水解纳米酶已成为制药、化工、环境修复、食品和造纸等行业各种应用的有前途的候选物质。尽管水解纳米酶潜力巨大,但其研究仍严重不足,仅占所有纳米酶研究的 14.4%(8737 篇论文中的 1256 篇)。在了解这些纳米酶的催化机理和设计策略方面存在着严重的差距,阻碍了它们的理论进步和实际应用。本综述旨在弥补这一空白,系统地整理和总结了水解纳米酶的催化机理(按结构组成和底物类型分类),以及从仿生策略到前沿数据驱动方法的设计方法,为指导水解纳米酶的合理设计和高效开发提供理论依据。此外,这篇综述还对该领域的未来前景和挑战进行了展望,旨在激发这一快速发展领域的进一步研究和创新。
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引用次数: 0
The roles of β-diketones and their derivatives in the design of photocatalysts β-二酮及其衍生物在光催化剂设计中的作用
IF 20.3 1区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2024-11-13 DOI: 10.1016/j.ccr.2024.216318
Wentao Zhang , Shuangshuang Wei , Guoyang Zhang , Jianghua Yang , Lele Peng , Shujuan Zhang
Organic ligands play pivotal roles in the synthesis and modification of photocatalysts. Small molecular diketones, exemplified by acetylacetone (acac), are a promising class of ligands. Nevertheless, a comprehensive review of their roles in photocatalysis has not yet been conducted. This gap hinders the rational design and application of photocatalysts by using diketones as functional ligands. It is therefore imperative to provide a comprehensive examination of this topic. This review critically summarizes the utilization of acac in photocatalysis from four aspects: the chemical nature and reactivity of acac, the roles of acac in the synthesis and modification of photocatalysts (especially the well-known TiO2), its influence on the photocatalytic processes, and the existing challenges and future prospects for acac-mediated photocatalysis. By providing a critical analysis of the established applications of acac in photocatalysis, we aim to inspire further advancements in the field rooted in fundamental theoretical principles.
有机配体在光催化剂的合成和改性过程中发挥着举足轻重的作用。以乙酰丙酮(acac)为代表的小分子二酮是一类前景广阔的配体。然而,目前尚未对它们在光催化中的作用进行全面研究。这一空白阻碍了使用二酮作为功能配体来合理设计和应用光催化剂。因此,对这一主题进行全面研究势在必行。本综述从四个方面批判性地总结了金合欢在光催化中的应用:金合欢的化学性质和反应性、金合欢在光催化剂(尤其是众所周知的 TiO2)的合成和改性中的作用、金合欢对光催化过程的影响以及金合欢介导的光催化的现有挑战和未来前景。通过对金合欢酸在光催化中的成熟应用进行批判性分析,我们旨在激发该领域在基本理论原则基础上的进一步发展。
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引用次数: 0
Design of electrocatalysts and electrodes for CO2 electroreduction to formic acid and formate 设计将二氧化碳电还原为甲酸和甲酸盐的电催化剂和电极
IF 20.3 1区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2024-11-12 DOI: 10.1016/j.ccr.2024.216322
Dinh Son Tran , Nhu-Nang Vu , Houssam-Eddine Nemamcha , Cedrik Boisvert , Ulrich Legrand , Arthur G. Fink , Fabiola Navarro-Pardo , Cao-Thang Dinh , Phuong Nguyen-Tri
Electrochemical carbon dioxide (CO2) reduction reaction (CO2RR) is gaining attraction as it enables the generation of highly valuable chemicals while mitigating greenhouse gas emissions. Numerous efforts have been dedicated to designing efficient catalysts that selectively reduce CO2 into various chemicals such as formic acid/formate, carbon monoxide, methane, ethylene, and ethanol. The efficiency of the CO2RR is evaluated through selectivity to the desired product, overpotential, current density, and stability. This work reviews emerging strategies to improve the CO2RR performance to produce formate/formic acid by tuning catalyst and electrode structures. The catalyst-developing strategies are discussed in terms of engineering electronic and geometric structures, surface oxidation structure, and enlarging surface active area. The design of gas diffusion electrodes and reactor configuration, which are essential in enhancing the efficiency of the electrochemical system, are also mentioned. Finally, insights and perspectives are given on how to overcome the instability of catalysts and limitations of reactor designs.
电化学二氧化碳(CO2)还原反应(CO2RR)在减少温室气体排放的同时,还能生成极具价值的化学品,因此越来越受到人们的青睐。人们一直致力于设计高效催化剂,将二氧化碳选择性地还原成甲酸/甲酸盐、一氧化碳、甲烷、乙烯和乙醇等各种化学品。CO2RR 的效率通过对所需产物的选择性、过电位、电流密度和稳定性进行评估。本研究综述了通过调整催化剂和电极结构提高 CO2RR 性能以生产甲酸/甲酸的新策略。催化剂开发策略从工程电子和几何结构、表面氧化结构以及扩大表面活性面积等方面进行了讨论。此外,还提到了对提高电化学系统效率至关重要的气体扩散电极和反应器配置的设计。最后,还就如何克服催化剂的不稳定性和反应器设计的局限性提出了见解和展望。
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引用次数: 0
Emerging metal-organic framework-based photocatalysts for solar-driven fuel production 基于金属有机框架的新兴光催化剂,用于太阳能驱动的燃料生产
IF 20.3 1区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2024-11-11 DOI: 10.1016/j.ccr.2024.216292
Chunxue Li , Ning-Yu Huang , Yingkui Yang , Qiang Xu , Guangfu Liao
Metal organic framework (MOF)-based photocatalysts for solar-driven fuel generation have seen significant advancement owing to their structural and porous controllability, high surface area, and distinctive semiconductor property. In this review, the opto-electronic characteristics of MOF-based photocatalysts are firstly introduced. After that, the fabrication strategies for MOF-based photocatalysts are illustrated. Then, some typical MOF-based photocatalysts for energy-related applications are exhibited. Lastly, this review also offers some in-depth perceptions into significant difficulties, advantageous situations, and heuristic possibilities for future improvement. There is no question that the newly developed MOF-based photocatalysts can achieve new innovations for energy-related applications.
基于金属有机框架(MOF)的光催化剂由于其结构和多孔可控性、高比表面积和独特的半导体特性,在太阳能驱动的燃料生产方面取得了重大进展。本综述首先介绍了基于 MOF 的光催化剂的光电特性。然后,阐述了 MOF 基光催化剂的制造策略。然后,展示了一些用于能源相关应用的典型 MOF 基光催化剂。最后,本综述还就重大困难、有利条件和未来改进的启发式可能性提出了一些深入的看法。毫无疑问,新开发的 MOF 基光催化剂可以为能源相关应用带来新的创新。
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引用次数: 0
Nanoprobes based on optical imaging techniques for detecting biomarkers in liver injury diseases 基于光学成像技术的纳米探针用于检测肝损伤疾病的生物标记物
IF 20.3 1区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2024-11-10 DOI: 10.1016/j.ccr.2024.216303
Ye Sun , Jing Wang , Yanyan Zhu , Tingting Han , Yi Liu , Hai-Yan Wang
The liver injury diseases caused by multiple factors have attracted widespread attention and good monitoring strategies are essential in the treatment process. In the past few decades, optical imaging techniques including fluorescence imaging, photoacoustic imaging and magnetic resonance imaging were gradually mastered and applied in clinical diagnosis and treatment of liver injury diseases. Such imaging techniques depend on probes generating signals in response to the critical biomarkers in liver injury diseases, and then the signals can be detected by corresponding instruments. Among them, we consider that nanoprobes with excellent aqueous solubility and biocompatibility have better application prospects. In this review, we focused on discussing the common design strategies, targeted biomarkers, detecting principles and biological applications of nanoprobes that have been developed, and we hope this review can inspire the development of nanoprobes utilized in the field of liver injury treatment.
多种因素导致的肝损伤疾病已引起广泛关注,良好的监测策略在治疗过程中至关重要。在过去的几十年中,包括荧光成像、光声成像和磁共振成像在内的光学成像技术逐渐被掌握并应用于肝损伤疾病的临床诊断和治疗。这些成像技术依赖探针对肝损伤疾病中的关键生物标志物产生响应信号,然后通过相应的仪器对信号进行检测。其中,我们认为具有良好水溶性和生物相容性的纳米探针具有更好的应用前景。在这篇综述中,我们重点讨论了已开发的纳米探针的常见设计策略、靶向生物标记物、检测原理和生物学应用,希望这篇综述能对纳米探针在肝损伤治疗领域的发展有所启发。
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引用次数: 0
Electron-reservoir applications of ferrocenes and other late transition-metal sandwich complexes: Flow batteries, sensing, catalysis, and biomedicine 二茂铁和其他后期过渡金属夹层复合物的电子贮存应用:液流电池、传感、催化和生物医学
IF 20.3 1区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2024-11-09 DOI: 10.1016/j.ccr.2024.216300
Tiansheng Wang , Didier Astruc
This review presents the applications of first-row late transition-metal sandwich complexes, including derivatives of ferrocene, FeCp2 (Cp = η5-C5H5), and of salts of cobalticenium [CoCp2]+ and mixed sandwich complexes [FeCp(η6-arene)]+ as molecular or macromolecular electron reservoirs. Forty-five years ago, the concept of electron reservoirs was proposed for the permethylated 19-electron d7 Fe(I) sandwich complexes, in particular [FeCp(η6-C6Me6)] and [FeCp*(η6-C6Me6)] (Cp* = C5Me5), because they were the electron richest neutral molecules known, given their extremely low ionization potentials, and their ability to stoichiometrically or catalytically transfer one electron to a variety of organic and inorganic substrates. These processes occurred without any breakdown of their molecular structure, so that the cationic 18-electron d6 structure was easily recovered. Thus, in this concept, the robustness of both redox forms of the electron-reservoir redox couple is essential. Later, the concept was extended to isolobal sandwich molecules with various numbers of methyl substituents on the ligands in both the [CoCp2]+ and [FeCp(η6-arene)]+ salts in order to cover a wide range of redox potentials. It was also extended to electron hole reservoirs with the 17-electron d5 cations FeCp2+, FeCp*2+ and [FeCp*(η5-C6Me6)]2+. Along the time, the structural flexibility of these Fe and Co sandwich complexes, bringing about modulation of the redox potentials of the redox systems, enriched the concept and its applications. The latter are summarized here including examples of stoichiometric reactions with monometallic complexes and dendritic metalla-macromolecules, redox-flow metallocene batteries and redox sensing. Catalytic applications include redox catalysis, electrocatalysis, i.e. electron-transfer-chain (ETC) catalysis, and Fenton reaction in nanomedicine of ferrocenes, ferrocene dendrimers and metal-organic-framework (MOF)-ferrocenes, utilized in particular as ferroptosis media. Concluding remarks outline key aspects of applications and offer perspectives.
本综述介绍了第一排晚期过渡金属夹层配合物的应用,包括二茂铁的衍生物 FeCp2(Cp = η5-C5H5)、钴硒盐 [CoCp2]+ 和混合夹层配合物 [FeCp(η6-arene)]+ 作为分子或大分子电子库的应用。四十五年前,有人针对过甲基化的 19 电子 d7 Fe(I)夹心配合物,特别是[FeCp(η6-C6Me6)]和[FeCp*(η6-C6Me6)](Cp* = C5Me5),提出了电子库的概念,因为它们是已知电子最丰富的中性分子,电离电位极低,能够将一个电子按比例或催化转移到各种有机和无机底物上。这些过程的发生不会破坏它们的分子结构,因此很容易恢复阳离子 18 电子 d6 结构。因此,在这一概念中,电子贮藏氧化还原偶的两种氧化还原形式的稳健性至关重要。后来,这一概念被扩展到[CoCp2]+ 和[FeCp(η6-arene)]+ 盐中配体上具有不同数量甲基取代基的孤立夹层分子,以涵盖广泛的氧化还原电位。此外,它还扩展到 17 电子 d5 阳离子 FeCp2+、FeCp*2+ 和 [FeCp*(η5-C6Me6)]2+ 的电子空穴库。随着时间的推移,这些铁和钴夹心复合物结构的灵活性带来了氧化还原体系氧化还原电位的调节,丰富了这一概念及其应用。本文总结了后者的应用,包括单金属络合物和树枝状金属大分子的化学反应、氧化还原流茂金属电池和氧化还原传感。催化应用包括氧化还原催化、电催化,即电子转移链(ETC)催化,以及二茂铁、二茂铁树枝状分子和金属有机框架(MOF)-二茂铁在纳米医学中的芬顿反应,特别是用作铁跃迁介质。结束语概述了应用的主要方面并提出了展望。
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引用次数: 0
Water-soluble stimuli-responsive supramolecular nanoagrochemicals based on macrocycle compounds 基于大环化合物的水溶性刺激响应超分子纳米agrochemicals
IF 20.3 1区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2024-11-09 DOI: 10.1016/j.ccr.2024.216299
Ya-Hui Song , Qiang Bian , Fang Wang , Jinpeng Liu , Yi-Hang Yang , Ying-Ming Zhang , Yu Liu
Agrochemicals are extensively utilized to ameliorate agricultural yield and quality, but they also negatively impact ecological cycle and human health as a consequence of indiscriminate pesticide usage and growing anthropogenic interference. To improve the efficiency and biosafety of existing agrochemicals, the dynamic and reversible nature of host–guest complexation with water-soluble macrocycles has been fully exploited in supramolecular chemistry to construct fascinating nanoassemblies with environmental stimuli-responsiveness. This review mainly focuses on (i) the performance-directed molecular recognition properties of common cavity-bearing macrocycles, including crown ethers, cyclodextrins, calixarenes, cucurbiturils, and pillararenes, toward a wide range of agroactive ingredients; (ii) the developmental updates in the emerging realm of macrocycle-based multistimuli-responsive supramolecular nanoagrochemicals, with an emphasis on their molecular basis, operation mechanism, and application toward a series of chemical (pH and redox), physical (photo and temperature), and biological (enzyme and reactive oxygen species) factors as internal and external stimuli relevant to plants and pests; and (iii) the encumbered challenges and perspectives on the translational development of these environmentally adaptive nanomaterials under realistic field conditions. In the wave of intelligentization of modern agricultural practices, we believe the stimuli-responsive supramolecular nanoagrochemicals is now spurring the impending agri-tech revolution at a global scale.
农用化学品被广泛用于提高农业产量和质量,但由于杀虫剂的滥用和日益严重的人为干扰,它们也对生态循环和人类健康产生了负面影响。为了提高现有农用化学品的效率和生物安全性,超分子化学充分利用了水溶性大环与主客体复配的动态和可逆性质,构建出具有环境刺激响应性的迷人纳米组合体。本综述主要关注 (i) 冠醚、环糊精、钙烯类、葫芦素和支柱烯类等常见空穴大环对多种农业活性成分的性能导向分子识别特性;(ii) 基于大环的多刺激响应超分子纳米农用化学品新兴领域的最新发展情况,重点是其分子基础、作用机理以及在一系列与植物和害虫相关的内外刺激的化学(pH 和氧化还原)、物理(光照和温度)和生物(酶和活性氧)因素方面的应用;以及 (iii) 这些环境适应性纳米材料在现实田间条件下的转化发展所面临的挑战和前景。在现代农业实践智能化的浪潮中,我们相信刺激响应型超分子纳米农用化学品正在全球范围内推动即将到来的农业技术革命。
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引用次数: 0
Host-guest interactions in the confined spaces of metal–organic frameworks: Design principles, characterizations, and applications 金属有机框架密闭空间中的主客体相互作用:设计原理、特性和应用
IF 20.3 1区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Pub Date : 2024-11-08 DOI: 10.1016/j.ccr.2024.216302
Yifang Zhao , Lian Wu , Kun Wu , Rong-Jia Wei , Heng Zeng , Hao Pang , Weigang Lu , Dan Li
Metal–organic frameworks (MOFs) are revolutionizing porous materials with their incredible structures and functionalities that have been extensively explored in many fields. Unlike traditional porous materials, MOFs offer a unique opportunity for precise design and modification of the porosities and pore environments. Their nanoscale confined spaces with specific shapes and surface functionalities can selectively interact with certain guest molecules through host-guest interactions, unlocking enhanced performance and related mechanisms that were previously undiscovered. Through advanced experimental and theoretical techniques, the high crystallinity of MOFs allows for detailed and in-depth studies of the structure-performance relationships, leading to breakthroughs in design and optimization. This review delves into recent advancements in the construction, characterization, and host-guest applications of MOF-based systems, showcasing their design strategies for remarkable functionality, porosity, and flexibility. The latest progress in adsorption, separation, catalysis, energy storage, crystalline sponge (CS), and sensing are discussed, unraveling the endless possibilities of MOFs and their challenges.
金属有机框架(MOFs)以其令人难以置信的结构和功能性为多孔材料带来了革命性的变化,并在许多领域得到了广泛的探索。与传统的多孔材料不同,MOF 为精确设计和改变孔隙率和孔隙环境提供了独特的机会。它们具有特定形状和表面功能的纳米级密闭空间可以通过主客体相互作用选择性地与某些客体分子相互作用,从而释放出以前尚未发现的增强性能和相关机制。通过先进的实验和理论技术,MOFs 的高结晶性允许对结构-性能关系进行详细深入的研究,从而在设计和优化方面取得突破。这篇综述深入探讨了基于 MOF 的系统在构建、表征和主客体应用方面的最新进展,展示了其卓越功能、多孔性和灵活性的设计策略。文章讨论了吸附、分离、催化、储能、结晶海绵 (CS) 和传感领域的最新进展,揭示了 MOFs 的无限可能性及其面临的挑战。
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引用次数: 0
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Coordination Chemistry Reviews
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