Coordination Chemistry Reviews最新文献_第10页

Engineering multidimensional carbon-based electrocatalysts for water splitting: From pristine nanostructures to MOF-, POP-, and MXene-hybrids 工程多维碳基水分解电催化剂：从原始纳米结构到MOF-， POP-和mxene -杂化

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2025-11-20 DOI: 10.1016/j.ccr.2025.217371

Rokhsareh Abedi , Ghasem Barati Darband , Ali Reza Oveisi , Saba Daliran , Amirreza Fathollahi , Hermenegildo Garcia

Hydrogen represents a clean and sustainable energy carrier and a viable alternative to fossil fuels in transportation. Electrochemical water splitting is a particularly promising method for producing high-purity hydrogen from renewable sources, offering a pathway to mitigate both environmental pollution and the global energy crisis. The efficiency of this technology hinges on the performance of electrocatalysts, which lower the reaction barriers for the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). However, designing electrocatalysts that are both highly active and durable remains a formidable challenge, necessitating precise control over their structure and electronic properties. Due to the abundance and affordability, carbon-based nanomaterials are exceptional candidates for this role, owing to their superior electrical conductivity, tunable physicochemical characteristics, and the possibility to introduce active sites. This review comprehensively examines the fundamental mechanisms of HER and OER and elucidates the pivotal function of electrocatalysts. We systematically discuss the properties, advantages, and synthesis of diverse carbon nanostructures, including zero-dimensional (0D), one-dimensional (1D), two-dimensional (2D), and three-dimensional (3D) architectures. Furthermore, we explore advanced nanocomposites derived from carbon-containing platforms, such as metal-organic frameworks (MOFs), covalent organic frameworks (COFs), porous organic polymers (POPs), and MXenes. The efficacy of these carbon-based catalysts for HER and OER is critically evaluated, alongside an analysis of the persistent challenges regarding their stability, efficiency, and scalability. Finally, we present a forward-looking perspective on the remaining challenges and future research directions in the field of carbon-based electrocatalysts for sustainable hydrogen production.

氢是一种清洁、可持续的能源载体，是交通运输中化石燃料的可行替代品。电化学水分解是一种特别有前途的从可再生能源中生产高纯度氢的方法，为减轻环境污染和全球能源危机提供了一条途径。该技术的效率取决于电催化剂的性能，电催化剂降低了析氢反应（HER）和析氧反应（OER）的反应垒。然而，设计既高活性又耐用的电催化剂仍然是一个艰巨的挑战，需要对其结构和电子特性进行精确控制。由于碳基纳米材料的丰富性和可负担性，由于其优越的导电性、可调的物理化学特性以及引入活性位点的可能性，碳基纳米材料是这一角色的特殊候选者。本文综述了HER和OER的基本机理，并阐明了电催化剂的关键作用。我们系统地讨论了各种碳纳米结构的性质、优点和合成，包括零维（0D）、一维（1D）、二维（2D）和三维（3D）结构。此外，我们还探索了由含碳平台衍生的先进纳米复合材料，如金属有机框架（MOFs）、共价有机框架（COFs）、多孔有机聚合物（pop）和MXenes。这些碳基催化剂对HER和OER的功效进行了严格评估，同时分析了其稳定性、效率和可扩展性方面的持续挑战。最后，展望了碳基电催化剂在可持续制氢领域存在的挑战和未来的研究方向。

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引用次数: 0

Engineering heterostructures for electrocatalysis and energy storage: classification, design, computational insights and property modulation 电催化和储能工程异质结构：分类、设计、计算见解和性质调制

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2025-11-20 DOI: 10.1016/j.ccr.2025.217341

Tajala Magray , Yashal Arif , Mithila Thombare , Thomas Ebel , Dattatray S. Dhawale , Pradip Sarawade

Heterostructure engineering involves strategic integration of two or more chemically or structurally distinct materials with well-defined interfaces gained considerable attention owing to its capacity to induce synergistic effects thar are absent in individual constituents. Heterostructure allow deliberate tuning of intrinsic electronic structures, band alignments and interfacial charge redistribution enable superior performance in both energy storage and electrocatalytic activity. Recent advancement in heterostructure demonstrate diverse architectures that enhance the availability of electrochemical active site, accelerate ion diffusion, reduce overpotentials, and improve electrochemical stability. Complementary computational methods such as Density Functional theory (DFT), Molecular Dynamics (MD), and Machine learning (ML), have further deepened understanding of charge transfer mechanisms, built-in electric fields, and diffusion kinetics at heterointerfaces, thereby accelerating the rational design of heterostructure materials. This review provide comprehensive overview of structural, electronic, and electrochemical characteristics of heterostructure, critically examines their synthesis strategies, and highlight their role in advancing EWS and SC technologies.

异质结构工程涉及两种或两种以上具有明确界面的化学或结构上不同的材料的战略性集成，由于其能够诱导单个成分不存在的协同效应，因此受到了相当大的关注。异质结构允许刻意调整固有的电子结构，能带排列和界面电荷重新分配使其在能量存储和电催化活性方面都具有卓越的性能。近年来异质结构研究的进展表明，异质结构可以增强电化学活性位点的可用性，加速离子扩散，降低过电位，提高电化学稳定性。密度泛函理论（DFT）、分子动力学（MD）和机器学习（ML）等互补的计算方法进一步加深了对异质界面上电荷转移机制、内置电场和扩散动力学的理解，从而加速了异质结构材料的合理设计。本文综述了异质结构的结构、电子和电化学特性，批判性地研究了它们的合成策略，并强调了它们在推进EWS和SC技术中的作用。

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引用次数: 0

Design, evolution, and application of halogen, chalcogen, pnictogen, and tetrel bonding catalysts 卤素、氯、烟原和四烷基键合催化剂的设计、发展和应用

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2025-11-19 DOI: 10.1016/j.ccr.2025.217374

Wei Wang , Qingli Song , Yao Wang

Emerging noncovalent interactions—such as halogen bonding (XB), chalcogen bonding (ChB), pnictogen bonding (PnB), and tetrel bonding (TrB)—have been demonstrated as valuable tools in catalysis. These interactions feature highly directional yet weak bonding properties, diverging fundamentally from classical Lewis acid catalysis. Catalyst systems exploiting these noncovalent forces, driven by electrostatic, dispersion, and orbital interactions, facilitate diverse chemical reactions. This review discusses this emerging field from a panoramic perspective of catalyst design, evolution and application. Key design concepts and strategies are summarized to guide the future exploration in this rapidly evolving field.

新兴的非共价相互作用-如卤素键（XB），硫键（ChB），烟原键（PnB）和四元键(TrB) -已被证明是催化的有价值的工具。这些相互作用具有高度定向但弱键性质，从根本上与经典路易斯酸催化不同。催化剂系统利用这些非共价力，由静电、分散和轨道相互作用驱动，促进多种化学反应。本文从催化剂的设计、发展和应用等方面综述了这一新兴领域。总结了关键的设计概念和策略，以指导这个快速发展的领域的未来探索。

引用次数: 0

Fluorescence imaging of FUS biomolecular condensates: From assembly regulation to pathological transition FUS生物分子凝聚物的荧光成像：从组装调节到病理转变

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2025-11-19 DOI: 10.1016/j.ccr.2025.217382

Jinjing Shi , Yan Zhang , Juan Du , Lu Miao , Zhaochao Xu

FUS (Fused in Sarcoma) protein is a crucial RNA-binding protein whose liquid-liquid phase separation (LLPS) behavior plays a key role in cellular physiological functions and the pathogenesis of neurodegenerative diseases. This review systematically summarizes the molecular mechanisms and physiological-pathological functions of FUS condensates, with a particular focus on the applications and challenges of fluorescence imaging techniques in resolving the dynamic processes of FUS phase separation. The integration of appropriate fluorescent labelling strategies (such as fluorescent protein fusion and self-labelling tag techniques) with advanced microscopic imaging technologies (e.g., confocal and super-resolution microscopy) has enabled nanoscale dynamic analysis of FUS biomolecular condensates both in vitro and within living cells, including the dynamic regulation of FUS and the liquid-to-solid transition process, which may first form a shell on the droplet surface. Furthermore, this review discusses the functions of FUS under various stimulatory conditions and the potential mechanisms underlying disease initiation. However, challenges such as labelling specificity, phototoxicity, spatiotemporal resolution limitations, and the integration of multiple regulatory factors in living environments remain to be addressed. Finally, this article prospects future technological directions, including in situ labelling, biosensors, and artificial intelligence-based analysis, aiming to provide new insights for a deeper understanding of FUS phase separation mechanisms and the treatment of related diseases.

FUS （Fused in Sarcoma）蛋白是一种重要的rna结合蛋白，其液-液相分离（LLPS）行为在细胞生理功能和神经退行性疾病的发病机制中起着关键作用。本文系统综述了FUS凝聚物的分子机制和生理病理功能，重点介绍了荧光成像技术在解析FUS相分离动态过程中的应用和挑战。将适当的荧光标记策略（如荧光蛋白融合和自标记标记技术）与先进的显微成像技术（如共聚焦和超分辨率显微镜）相结合，可以在体外和活细胞内对FUS生物分子凝聚物进行纳米级动态分析，包括FUS的动态调控和液固过渡过程，该过程可能首先在液滴表面形成一个壳。此外，本文还讨论了FUS在各种刺激条件下的功能以及疾病发生的潜在机制。然而，诸如标记特异性、光毒性、时空分辨率限制以及生活环境中多种调节因素的整合等挑战仍有待解决。最后，本文展望了未来的技术方向，包括原位标记、生物传感器和基于人工智能的分析，旨在为更深入地了解FUS相分离机制和相关疾病的治疗提供新的见解。

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引用次数: 0

Structure design and applications of Zr-based metal-organic framework nanosheets 锆基金属有机骨架纳米片的结构设计与应用

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2025-11-18 DOI: 10.1016/j.ccr.2025.217380

De-Sheng Zheng, Ming Xu, Wen-Qi Tang, Zhi-Yuan Gu

Zirconium-based metal-organic framework (Zr-MOF) nanosheets, as a distinctive class of porous two-dimensional (2D) materials, exhibit exceptional chemical stability, tunable pore structures, and large surface areas. This review summarizes recent progress in the topological design, synthetic strategies, and functional engineering of Zr-MOF nanosheets. We introduce structural modulation approaches, including Zr-cluster engineering, ligand functionalization, and interlayer stacking regulation, which play critical roles in tailoring their physicochemical properties. Moreover, the applications of Zr-MOF nanosheets in catalysis, biomedicine, sensing, separation, and battery fields are systematically discussed. Finally, current challenges and future research directions are outlined to inspire further innovation and practical deployment of Zr-MOF nanosheets.

锆基金属有机框架（Zr-MOF）纳米片作为一类独特的多孔二维（2D）材料，具有优异的化学稳定性、可调节的孔结构和大表面积。本文综述了Zr-MOF纳米片的拓扑设计、合成策略和功能工程方面的最新进展。我们介绍了结构调制方法，包括zr簇工程，配体功能化和层间堆叠调节，这些方法在调整其物理化学性质中起着关键作用。并对Zr-MOF纳米片在催化、生物医学、传感、分离、电池等领域的应用进行了系统的探讨。最后，展望了Zr-MOF纳米片的未来研究方向和面临的挑战，以期激发Zr-MOF纳米片的进一步创新和实际应用。

引用次数: 0

2D materials in ultrasound-driven cancer therapies: Correlating material characteristics with therapeutic performance 二维材料在超声驱动癌症治疗中的应用：材料特性与治疗效果的相关性

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2025-11-17 DOI: 10.1016/j.ccr.2025.217366

Nam Anh Tran , Hang Thu Ta

Overcoming the limited penetration of phototherapies, ultrasound-based therapies (sonotherapies) have emerged as a promising cancer treatment due to their deep tissue reach and therapeutic efficacy. However, conventional organic sonosensitizers suffer from rapid clearance and poor solubility, limiting their effectiveness. In contrast, nanoscale sono-activatable agents, especially 2D materials, offer unique physicochemical properties, enhanced stability, and superior antitumor performance.

Beyond acting as nanocarriers or passive supports, 2D materials actively participate in sonotherapy and enable the combination of multiple treatment modalities, improving therapeutic synergy. This review first outlines the fundamental principles and conventional applications of sonotherapy. It then focuses on recent advances in 2D materials as sonosensitizers and sonothermal agents, categorizing them based on structural and functional characteristics.

We also discuss the mechanisms of ultrasound activation and how properties such as piezoelectricity, bandgap, and thermal conductivity contribute to treatment outcomes. Strategies to enhance these features—such as atomic doping, defect engineering, and heterojunction construction—are examined in depth. Finally, we highlight current progress, limitations, and challenges in translating 2D material-based sonotherapies into clinical practice.

This review offers a timely and comprehensive perspective on the emerging role of 2D materials in sonotherapy and the critical gaps that must be addressed to enable their clinical adoption.

克服光疗法的局限性，基于超声的治疗（sonotheries）由于其深入组织和治疗效果而成为一种有前途的癌症治疗方法。然而，传统的有机声敏剂存在清除率快、溶解度差的问题，限制了它们的有效性。相比之下，纳米级的声激活剂，特别是二维材料，具有独特的物理化学性质，增强的稳定性和卓越的抗肿瘤性能。除了作为纳米载体或被动支撑，二维材料积极参与超声治疗，使多种治疗方式的组合，提高治疗的协同作用。本文首先概述了超声治疗的基本原理和常规应用。然后重点介绍了作为声敏剂和声温剂的二维材料的最新进展，并根据结构和功能特征对它们进行了分类。我们还讨论了超声激活的机制，以及压电性、带隙和导热性等特性如何影响治疗结果。增强这些特征的策略，如原子掺杂、缺陷工程和异质结的构建，将被深入研究。最后，我们强调了目前的进展，限制和挑战，将二维材料为基础的超声治疗转化为临床实践。这篇综述提供了一个及时和全面的视角，关于二维材料在超声治疗中的新兴作用，以及必须解决的关键差距，以使其临床应用。

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引用次数: 0

The evolving landscape of gold(I)-NHC chemistry: synthesis, characterization, and catalytic activity 金(I)-NHC化学的发展图景：合成、表征和催化活性

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2025-11-17 DOI: 10.1016/j.ccr.2025.217314

Eklakh Ansari , Maroof Ali Khan , Ritesh Sharma , Geeta Singh , Piyush Kumar Sonkar , Anand Ratnam

Au^I-NHC complexes have emerged as pivotal tools in modern organometallic chemistry, owing to their exceptional stability, strong σ-donor properties, and tunable steric and electronic profiles. This review comprehensively surveys recent advances (2019–present) in the synthesis, characterization, and catalytic applications of Au^I-NHC complexes, with particular emphasis on innovative strategies such as silver-free and base-assisted protocols. Key challenges—including ligand design constraints, air/moisture sensitivity, and structural verification difficulties—are critically examined. The discussion highlights the catalytic versatility of these complexes in cycloisomerizations, hydrofunctionalizations, and oxidative couplings, while also addressing persistent limitations such as catalyst deactivation, narrow substrate scope, and unresolved mechanistic questions. Future perspectives focus on advanced ligand design, sustainable synthetic approaches, mechanistic studies, and interdisciplinary applications in materials science and chemical biology. By overcoming current barriers, the field can fully realize the potential of Au^I-NHC systems in catalysis and beyond.

AuI-NHC配合物由于其优异的稳定性、强的σ给体性质和可调的空间和电子谱，已成为现代有机金属化学中的关键工具。本文全面综述了AuI-NHC配合物的合成、表征和催化应用方面的最新进展（2019年至今），特别强调了无银和碱基辅助方案等创新策略。关键挑战-包括配体设计限制，空气/湿度敏感性和结构验证困难-被严格审查。讨论强调了这些配合物在环异构化、氢化官能化和氧化偶联中的催化多功能性，同时也解决了诸如催化剂失活、底物范围狭窄和未解决的机制问题等持续存在的局限性。未来的展望将集中在先进的配体设计，可持续的合成方法，机理研究以及材料科学和化学生物学的跨学科应用。通过克服目前的障碍，该领域可以充分实现AuI-NHC系统在催化及其他领域的潜力。

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引用次数: 0

A review of the recent coordination chemistry and catalytic applications of pyrazole and pyrazolyl transition metal complexes 综述了吡唑和吡唑基过渡金属配合物的配位化学及其催化应用的最新进展

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2025-11-17 DOI: 10.1016/j.ccr.2025.217373

Francis K. Migwi , George S. Nyamato , Stephen O. Ojwach , James Darkwa

The versatile coordination behavior of the pyrazolyl based ligands has given rise to a rich coordination chemistry and applications of their transition metal complexes. This diverse coordination chemistry is largely derived from the ease of fine-tuning the steric and electronic features of these pyrazolyl ligands and their resultant complexes. The pyrazolyl transition metal complexes are thus amenable to a wide range of coordination features, rendering them suitable for various applications such as catalysis, electronic and magnetic devices among others. The current review captures and analyses recent progress and reports on the syntheses, coordination chemistry of the pyrazole and pyrazolyl transition metal complexes and their applications in transition metal catalyzed oligomerization and polymerization, hydrogenation, carbonylation, carbon‑carbon coupling, and biomimetic reactions. The review also presents a critical analyses and comparisons of the current findings with other related non-pyrazolyl transition metal complexes, thus providing insights on the potential of these pyrazolyl metal complexes as catalysts in various organic transformations.

吡唑基配体的多用途配位行为使其具有丰富的配位化学性质和过渡金属配合物的应用。这种多样的配位化学在很大程度上源于这些吡唑基配体及其合成的配合物的空间和电子特征的微调。因此，吡唑基过渡金属配合物具有广泛的配位特征，使其适用于各种应用，如催化、电子和磁性设备等。本文综述了吡唑和吡唑基过渡金属配合物的合成、配位化学及其在过渡金属催化的低聚和聚合、加氢、羰基化、碳-碳偶联和仿生反应中的应用。本文还对目前的发现与其他相关的非吡唑基过渡金属配合物进行了批判性的分析和比较，从而对这些吡唑基金属配合物作为各种有机转化催化剂的潜力提供了见解。

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引用次数: 0

Near-infrared-responsive pyroptosis inducers: From molecular design to multiscale therapeutic platforms 近红外响应焦亡诱导剂：从分子设计到多尺度治疗平台

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2025-11-17 DOI: 10.1016/j.ccr.2025.217375

Jahyun Kim , Hyewon Seo , Dokyoung Kim

Pyroptosis, an inflammatory form of regulated cell death, is increasingly recognized as a promising therapeutic mechanism distinct from apoptosis or necroptosis. Defined by gasdermin-mediated pore formation, pyroptosis results in membrane rupture and cytokine release, outcomes that can be harnessed when combined with the spatiotemporal precision of near-infrared (NIR) light. The optical window of NIR (700–1000 nm) offers deep tissue penetration and reduced collateral damage, making NIR-responsive systems powerful tools for engineering controllable pyroptosis inducers. This review highlights advances in NIR-responsive pyroptosis inducers from a chemistry and materials perspective, with emphasis on three design landscapes: (i) small-molecule engineering, (ii) nanocarrier-based delivery systems, and (iii) functional nanomaterials. At the molecular level, strategies such as donor–acceptor frameworks, π-conjugation extension, heavy atom incorporation, and conformational modulation enhance intersystem crossing, boost reactive oxygen species generation, and extend absorption into the NIR window. Nanocarrier platforms, both synthetic and bio-derived, integrate photothermal dyes, chemotherapeutics, or immune modulators into responsive scaffolds, thereby improving solubility, stability, and tumor selectivity. Beyond carriers, nanomaterials, including transition-metal chalcogenides, plasmonic metals, semiconducting polymers, and metal-organic frameworks (MOF), serve as intrinsic inducers, leveraging bandgap engineering, plasmonic resonance, and catalytic activity to achieve multimodal therapeutic outcomes. We underscore how photophysical design and materials innovation converge to expand the capabilities of NIR-responsive systems. Key challenges remain, including optimizing NIR-II activation, overcoming hypoxia, and balancing photothermal and photodynamic contributions. Nevertheless, the integration of molecular engineering with nanoscale materials design establishes a framework for next-generation photo-responsive systems, positioning NIR-triggered pyroptosis inducers as promising platforms for advanced phototherapeutics.

焦亡是一种受调节的细胞死亡的炎症形式，越来越被认为是一种不同于细胞凋亡或坏死的有前途的治疗机制。由气凝胶介导的孔形成定义，焦亡导致膜破裂和细胞因子释放，当与近红外（NIR）光的时空精度相结合时，可以利用这些结果。近红外的光学窗口（700-1000 nm）提供了深层组织穿透和减少附带损伤，使近红外响应系统成为工程可控焦亡诱导剂的有力工具。本文从化学和材料的角度综述了nir响应型焦亡诱导剂的进展，重点介绍了三个设计领域：(i)小分子工程，（ii）基于纳米载体的递送系统，（iii）功能纳米材料。在分子水平上，诸如供体-受体框架、π共轭扩展、重原子掺入和构象调制等策略增强了系统间的交叉，促进了活性氧的产生，并将吸收扩展到近红外窗口。纳米载体平台，无论是合成的还是生物衍生的，都将光热染料、化疗药物或免疫调节剂整合到反应性支架中，从而提高了溶解度、稳定性和肿瘤选择性。除了载体，纳米材料，包括过渡金属硫族化合物、等离子体金属、半导体聚合物和金属有机框架（MOF），作为内在诱导剂，利用带隙工程、等离子体共振和催化活性来实现多模态治疗结果。我们强调了光物理设计和材料创新如何融合以扩展nir响应系统的能力。关键的挑战仍然存在，包括优化NIR-II激活，克服缺氧，以及平衡光热和光动力贡献。然而，分子工程与纳米级材料设计的整合为下一代光响应系统建立了框架，将nir触发的焦亡诱导剂定位为先进光疗的有前途的平台。

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引用次数: 0

Recent advances in MOF membranes for oil-water separation: From surface and pore engineering to multifunctional applications 油水分离用MOF膜的研究进展：从表面和孔工程到多功能应用

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews

Pub Date : 2025-11-17 DOI: 10.1016/j.ccr.2025.217381

Xiaolan Cao , Yujing Ji , Wenqing Li , Hongyi Gao , Xiaoqi Wang , Ge Wang

Oil-contaminated wastewater poses significant threats to ecological sustainability and public health, resulting in the waste of petroleum resources and economic losses. Simultaneously, high-water-cut oilfields urgently require novel, efficient oil-water separation technologies. This has spurred considerable interest in oil-water separation techniques based on superwetting materials due to their advantages of low cost, high efficiency, and reusability. Metal-organic framework (MOF), as porous hybrid materials featuring high specific surface area, tunable pore structures, customizable surface chemistry, and multifunctional integration capabilities, demonstrate extraordinary potential in oil-water separation. This paper systematically reviews recent advances in multifunctional MOF membranes for oil-water separation, focusing on three key aspects: First, we explore evaluation criteria and key factors influencing the separation performance of MOF membranes. Next, we summarize surface and pore engineering strategies for constructing multifunctional MOF membranes, including surface functionalization techniques, hierarchical assembly methods, gradient channel design, and asymmetric membrane architecture. Furthermore, we elaborate on emerging multifunctional applications of MOF membranes, such as switchable wettability, self-cleaning capabilities, intelligent responses to external stimuli, and synergistic adsorption mechanisms. Finally, we conduct an in-depth analysis of the challenges facing this field and propose prospects for developing next-generation MOF membrane separation systems.

含油废水对生态可持续性和公众健康构成重大威胁，造成石油资源浪费和经济损失。同时，高含水油田迫切需要新型、高效的油水分离技术。这激发了人们对基于超湿材料的油水分离技术的极大兴趣，因为它们具有低成本、高效率和可重复使用的优点。金属有机骨架（MOF）作为一种多孔杂化材料，具有高比表面积、可调节的孔隙结构、可定制的表面化学性质和多功能集成能力，在油水分离领域显示出非凡的潜力。本文系统综述了多功能MOF油水分离膜的研究进展，重点从三个方面进行了综述：首先，探讨了MOF膜分离性能的评价标准和影响膜分离性能的关键因素；接下来，我们总结了构建多功能MOF膜的表面和孔隙工程策略，包括表面功能化技术、分层组装方法、梯度通道设计和不对称膜结构。此外，我们详细阐述了MOF膜的新兴多功能应用，如可切换润湿性、自清洁能力、对外部刺激的智能响应以及协同吸附机制。最后，我们深入分析了该领域面临的挑战，并提出了下一代MOF膜分离系统的发展前景。

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引用次数: 0