Pub Date : 2024-10-19DOI: 10.1016/j.ccr.2024.216280
Yin-sheng Liu , Rui Xue , Bing Yan
Ratiometric fluorescence sensors attract more and more attention in the field of fluorescence sensors due to their excellent properties. The advanced material with high luminescent properties is the key to developing ratiometric fluorescence sensors. The covalent organic frameworks (COFs) stand out as an exceptional candidate for fluorescence sensing due to their expansive specific surface area and abundant active sites. However, the design, preparation, and application of COF-based ratiometric fluorescent sensors still represent a promising area for further development. This review collects the design principle of COFs and summarizes the design idea, sensing mode, and mechanism of COF-based ratiometric fluorescent sensors. Furthermore, the approaches to achieving a more comprehensive application of ratiometric fluorescent sensors with two emission centers are discussed. This review presents the research progress, challenges, and future directions in the field of COFs for fluorescent sensors, which is important for the development of high-performance ratiometric fluorescence sensors and the expansion of the application of COFs.
{"title":"Development and prospects of covalent organic framework-based ratiometric fluorescent sensors","authors":"Yin-sheng Liu , Rui Xue , Bing Yan","doi":"10.1016/j.ccr.2024.216280","DOIUrl":"10.1016/j.ccr.2024.216280","url":null,"abstract":"<div><div>Ratiometric fluorescence sensors attract more and more attention in the field of fluorescence sensors due to their excellent properties. The advanced material with high luminescent properties is the key to developing ratiometric fluorescence sensors. The covalent organic frameworks (COFs) stand out as an exceptional candidate for fluorescence sensing due to their expansive specific surface area and abundant active sites. However, the design, preparation, and application of COF-based ratiometric fluorescent sensors still represent a promising area for further development. This review collects the design principle of COFs and summarizes the design idea, sensing mode, and mechanism of COF-based ratiometric fluorescent sensors. Furthermore, the approaches to achieving a more comprehensive application of ratiometric fluorescent sensors with two emission centers are discussed. This review presents the research progress, challenges, and future directions in the field of COFs for fluorescent sensors, which is important for the development of high-performance ratiometric fluorescence sensors and the expansion of the application of COFs.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216280"},"PeriodicalIF":20.3,"publicationDate":"2024-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142450223","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-17DOI: 10.1016/j.ccr.2024.216268
Shihua Liu , Qiuhong Sun , Nuo Xu , Yawen Wang , Yang Li , Jinhao Li , Zilong Li , Vishnu D. Rajput , Tatiana Minkina , Xianggui Kong , Guangchao Li , Yanjun Lin , Yufei Zhao , Xue Duan
With the advancement of industrial development and urbanization, the indiscriminate discharge of industrial pollutants and wastes containing heavy metals and precious metals poses a significant threat to human health and ecosystems. Despite the widespread use of several traditional therapeutic procedures, these treatments frequently exhibit low efficacy and significant environmental consequences. The extraction and reuse of metal resources in pollutant treatment can effectively alleviate the current resource crisis; however, achieving a balance between recovery efficiency and environmental impact during the extraction process remains a major challenge. To tackle these challenges, emerging treatment materials along with advancements in thermal/photo/electrochemical methods offer additional possibilities for efficiently remediating/mineralizing heavy/precious metal pollution. This paper introduces traditional techniques for treating precious and heavy metals from water and soil while discussing the prospects of new treatment materials as well as effective thermal/photo/electrochemical methods for removing such metals. Furthermore, various strategies for recovering metals from municipal waste and wastewater containing heavy/precious metal are discussed, emphasizing sustainable approaches to enhance recycling performance.
{"title":"Recent advances in the treatment of heavy/precious metal pollution, resource recovery and reutilization: Progress and perspective","authors":"Shihua Liu , Qiuhong Sun , Nuo Xu , Yawen Wang , Yang Li , Jinhao Li , Zilong Li , Vishnu D. Rajput , Tatiana Minkina , Xianggui Kong , Guangchao Li , Yanjun Lin , Yufei Zhao , Xue Duan","doi":"10.1016/j.ccr.2024.216268","DOIUrl":"10.1016/j.ccr.2024.216268","url":null,"abstract":"<div><div>With the advancement of industrial development and urbanization, the indiscriminate discharge of industrial pollutants and wastes containing heavy metals and precious metals poses a significant threat to human health and ecosystems. Despite the widespread use of several traditional therapeutic procedures, these treatments frequently exhibit low efficacy and significant environmental consequences. The extraction and reuse of metal resources in pollutant treatment can effectively alleviate the current resource crisis; however, achieving a balance between recovery efficiency and environmental impact during the extraction process remains a major challenge. To tackle these challenges, emerging treatment materials along with advancements in thermal/photo/electrochemical methods offer additional possibilities for efficiently remediating/mineralizing heavy/precious metal pollution. This paper introduces traditional techniques for treating precious and heavy metals from water and soil while discussing the prospects of new treatment materials as well as effective thermal/photo/electrochemical methods for removing such metals. Furthermore, various strategies for recovering metals from municipal waste and wastewater containing heavy/precious metal are discussed, emphasizing sustainable approaches to enhance recycling performance.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216268"},"PeriodicalIF":20.3,"publicationDate":"2024-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142444359","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-16DOI: 10.1016/j.ccr.2024.216279
Airton G. Bispo-Jr , Nagyla A. Oliveira , Isabela M.S. Diogenis , Fernando A. Sigoli
This review provides a comprehensive examination of circularly polarized luminescence (CPL) in Lanthanide(III) systems, encompassing their historical development, present challenges, and future applications. Starting with early discoveries and key milestones, we trace the evolution of CPL studies, highlighting seminal works and breakthroughs that have shaped current understanding. Special emphasis is placed on the processing of these complexes in both solution and solid-state forms, delineating how different environments affect CPL properties. We delve into the challenges that researchers face in this field, including synthetic hurdles, stability issues, and the need for enhanced dissymmetry factors and emission quantum yields. Additionally, the review explores strategies to overcome these obstacles, such as innovative coordination chemistry design, advanced characterization techniques, and novel processing methods. Finally, we discuss potential applications of Lanthanide(III) CPL complexes, from security and display technologies to biological fingerprint. By providing a historical perspective, identifying current challenges, and outlining future directions, this review aims to serve as a valuable resource for researchers and practitioners in the field of luminescent materials and beyond.
{"title":"Perspectives and challenges in circularly polarized luminescence of lanthanide(III) complexes: From solution-based systems to solid-state applications","authors":"Airton G. Bispo-Jr , Nagyla A. Oliveira , Isabela M.S. Diogenis , Fernando A. Sigoli","doi":"10.1016/j.ccr.2024.216279","DOIUrl":"10.1016/j.ccr.2024.216279","url":null,"abstract":"<div><div>This review provides a comprehensive examination of circularly polarized luminescence (CPL) in Lanthanide(III) systems, encompassing their historical development, present challenges, and future applications. Starting with early discoveries and key milestones, we trace the evolution of CPL studies, highlighting seminal works and breakthroughs that have shaped current understanding. Special emphasis is placed on the processing of these complexes in both solution and solid-state forms, delineating how different environments affect CPL properties. We delve into the challenges that researchers face in this field, including synthetic hurdles, stability issues, and the need for enhanced dissymmetry factors and emission quantum yields. Additionally, the review explores strategies to overcome these obstacles, such as innovative coordination chemistry design, advanced characterization techniques, and novel processing methods. Finally, we discuss potential applications of Lanthanide(III) CPL complexes, from security and display technologies to biological fingerprint. By providing a historical perspective, identifying current challenges, and outlining future directions, this review aims to serve as a valuable resource for researchers and practitioners in the field of luminescent materials and beyond.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216279"},"PeriodicalIF":20.3,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142439955","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-16DOI: 10.1016/j.ccr.2024.216264
Changyu Hu , Dong Jiang , Yin Zhang , Hu Gao , Yihan Zeng , Nithima Khaorapapong , Zhipeng Liu , Yusuke Yamauchi , Mingzhu Pan
As global demand for renewable energy consumption and environmental treatment intensifies, the development of innovative technologies and green materials for catalytic transformation is increasingly critical. Porphyrins, often referred to as the ‘pigments of life’, are notable for their macrocyclic π-conjugated electronic structures and distinctive light excitation/absorption properties. They have been widely used for oxygen transport, photosynthesis, as well as serving enzymatic catalytic centers in biological processes. However, the inherent strong π–π interactions among rigid porphyrin molecules lead to disordered stacking and self-aggregation, diminishing the accessibility of active sites and the efficiency of charge transfer during practical applications. Hybrid porphyrins with multidimensional nano-substrates, like graphene, metal oxide, et al. is a promising strategy that can not only mitigate self-aggregation of porphyrins but also can achieve a synergetic enhancement effect. Selecting suitable substrates and effective bonding interactions between the porphyrins and substrates are critical for achieving the desired performance in specific applications. This review comprehensively summarizes recent advances in porphyrin-based multidimensional nanomaterials (PMNs), focusing on the influence of nanoscale effects, performance enhancements, and their applications in energy conversion, storage, biomedicine, and environmental protection. It delves deeply into the role of interaction forces in boosting interfacial electron transfer for superior catalytic transformations. Additionally, it critically examines the correlations between the high loading and dispersion of porphyrin molecules, emphasizing strategies, structural design, nanoscale effects, and interfacial interactions. Notably, the discussion extends to the mechanistic links between the structure, properties, and applications of PMNs. The review concludes by addressing the critical challenges and future directions in this field.
{"title":"Porphyrins-based multidimensional nanomaterials: Structural design, modification and applications","authors":"Changyu Hu , Dong Jiang , Yin Zhang , Hu Gao , Yihan Zeng , Nithima Khaorapapong , Zhipeng Liu , Yusuke Yamauchi , Mingzhu Pan","doi":"10.1016/j.ccr.2024.216264","DOIUrl":"10.1016/j.ccr.2024.216264","url":null,"abstract":"<div><div>As global demand for renewable energy consumption and environmental treatment intensifies, the development of innovative technologies and green materials for catalytic transformation is increasingly critical. Porphyrins, often referred to as the ‘pigments of life’, are notable for their macrocyclic π-conjugated electronic structures and distinctive light excitation/absorption properties. They have been widely used for oxygen transport, photosynthesis, as well as serving enzymatic catalytic centers in biological processes. However, the inherent strong π–π interactions among rigid porphyrin molecules lead to disordered stacking and self-aggregation, diminishing the accessibility of active sites and the efficiency of charge transfer during practical applications. Hybrid porphyrins with multidimensional nano-substrates, like graphene, metal oxide, et al. is a promising strategy that can not only mitigate self-aggregation of porphyrins but also can achieve a synergetic enhancement effect. Selecting suitable substrates and effective bonding interactions between the porphyrins and substrates are critical for achieving the desired performance in specific applications. This review comprehensively summarizes recent advances in porphyrin-based multidimensional nanomaterials (PMNs), focusing on the influence of nanoscale effects, performance enhancements, and their applications in energy conversion, storage, biomedicine, and environmental protection. It delves deeply into the role of interaction forces in boosting interfacial electron transfer for superior catalytic transformations. Additionally, it critically examines the correlations between the high loading and dispersion of porphyrin molecules, emphasizing strategies, structural design, nanoscale effects, and interfacial interactions. Notably, the discussion extends to the mechanistic links between the structure, properties, and applications of PMNs. The review concludes by addressing the critical challenges and future directions in this field.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216264"},"PeriodicalIF":20.3,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142439954","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-15DOI: 10.1016/j.ccr.2024.216266
Prashanth Venkatesan , Preeti Pal , Siew Suan Ng , Jui-Yen Lin , Ruey-An Doong
Sensitized Triplet-triplet annihilation (sTTA) photon upconversion (UC) represents a cutting-edge technology with far-reaching implications in both sustainable energy and biomedical realms. By capitalizing on the unique properties of excited triplet states, sTTA-UC enables the conversion of low-energy photons into higher-energy counterparts, offering promising solutions for efficient solar energy utilization and transformative biomedical applications. This review offers a comprehensive exploration of sTTA-UC, delving into its fundamental principles, assembly strategies, and key considerations for applications in sustainable energy and biomedicine. Various materials, including silica, clay, polymers, gels, metal-organic frameworks (MOFs), and covalent organic frameworks (COFs), play integral roles in enhancing sTTA efficiency and overcoming challenges such as oxygen quenching. Additionally, the review surveys the diverse applications of sTTA-UC, in photocatalysis, solar energy conversion, biosensing, bioimaging, and therapeutic interventions. These applications underscore the versatility and potential of sTTA-UC across multifaceted domains, promising significant advancements in various scientific and technological fields. Looking towards the future, the review outlines key areas for further exploration and development in sTTA-UC research. Priorities include optimizing materials, enhancing stability, and exploring innovative integration approaches to fully harness the capabilities of sTTA-UC technology. By elucidating the opportunities and challenges inherent in sTTA-UC, this review seeks to inspire researchers to propel the field forward, driving innovation and sustainability in both energy and biomedical sectors.
{"title":"Sensitized triplet-triplet annihilation-based photon upconversion: Assembly strategy and key consideration for sustainable energy and biomedical applications","authors":"Prashanth Venkatesan , Preeti Pal , Siew Suan Ng , Jui-Yen Lin , Ruey-An Doong","doi":"10.1016/j.ccr.2024.216266","DOIUrl":"10.1016/j.ccr.2024.216266","url":null,"abstract":"<div><div>Sensitized Triplet-triplet annihilation (sTTA) photon upconversion (UC) represents a cutting-edge technology with far-reaching implications in both sustainable energy and biomedical realms. By capitalizing on the unique properties of excited triplet states, sTTA-UC enables the conversion of low-energy photons into higher-energy counterparts, offering promising solutions for efficient solar energy utilization and transformative biomedical applications. This review offers a comprehensive exploration of sTTA-UC, delving into its fundamental principles, assembly strategies, and key considerations for applications in sustainable energy and biomedicine. Various materials, including silica, clay, polymers, gels, metal-organic frameworks (MOFs), and covalent organic frameworks (COFs), play integral roles in enhancing sTTA efficiency and overcoming challenges such as oxygen quenching. Additionally, the review surveys the diverse applications of sTTA-UC, in photocatalysis, solar energy conversion, biosensing, bioimaging, and therapeutic interventions. These applications underscore the versatility and potential of sTTA-UC across multifaceted domains, promising significant advancements in various scientific and technological fields. Looking towards the future, the review outlines key areas for further exploration and development in sTTA-UC research. Priorities include optimizing materials, enhancing stability, and exploring innovative integration approaches to fully harness the capabilities of sTTA-UC technology. By elucidating the opportunities and challenges inherent in sTTA-UC, this review seeks to inspire researchers to propel the field forward, driving innovation and sustainability in both energy and biomedical sectors.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216266"},"PeriodicalIF":20.3,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142431784","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-15DOI: 10.1016/j.ccr.2024.216259
Mei Wu , Li Bai , Fengjuan Deng , Jian He , Ke Song , Hu Li
Upgrading biomass-derived platform molecules into valuable chemicals and biofuels is critical in bio-refinery to establish bio-based sustainable chemical processes. Catalytic transfer hydrogenation represents a fascinating strategy for the reductive upgradation of bio-based oxygenated compounds owing to bypassing the potential security risks and tedious safety precautions associated with using flammable and explosive pressurized H2. Organic-inorganic hybrid materials (OIHMs), bearing the merits of strong Lewis acid-base ability, high specific-surface-area and pore size, tunable structure/properties and easy preparation, have been confirmed to be promising catalysts for transfer hydrogenation. In this contribution, an overview of OIHMs in transfer hydrogenation of bio-based oxygenated compounds is presented, which mainly involves diverse organic ligands with oxygen-rich groups like −OH, −COOH, −PO3H2, and − SO3H for constructing OIHMs. The corresponding characterization means for clarifying the structures/properties of OIHMs, structure-reactivity relationships, reaction pathways and/or mechanisms together with catalyst durability are elucidated. In addition, the general challenges and future research on the applications of OIHMs in transfer hydrogenation are also discussed. Expectedly, this review can provide an instructive viewpoint for the rational design and practical application of OIHMs in reductive upgrading of bio-based oxygenated compounds via hydrogen transfer processes.
{"title":"Organic-inorganic hybrid materials for catalytic transfer hydrogenation of biomass-derived carbonyl-containing compounds","authors":"Mei Wu , Li Bai , Fengjuan Deng , Jian He , Ke Song , Hu Li","doi":"10.1016/j.ccr.2024.216259","DOIUrl":"10.1016/j.ccr.2024.216259","url":null,"abstract":"<div><div>Upgrading biomass-derived platform molecules into valuable chemicals and biofuels is critical in bio-refinery to establish bio-based sustainable chemical processes. Catalytic transfer hydrogenation represents a fascinating strategy for the reductive upgradation of bio-based oxygenated compounds owing to bypassing the potential security risks and tedious safety precautions associated with using flammable and explosive pressurized H<sub>2</sub>. Organic-inorganic hybrid materials (OIHMs), bearing the merits of strong Lewis acid-base ability, high specific-surface-area and pore size, tunable structure/properties and easy preparation, have been confirmed to be promising catalysts for transfer hydrogenation. In this contribution, an overview of OIHMs in transfer hydrogenation of bio-based oxygenated compounds is presented, which mainly involves diverse organic ligands with oxygen-rich groups like −OH, −COOH, −PO<sub>3</sub>H<sub>2</sub>, and − SO<sub>3</sub>H for constructing OIHMs. The corresponding characterization means for clarifying the structures/properties of OIHMs, structure-reactivity relationships, reaction pathways and/or mechanisms together with catalyst durability are elucidated. In addition, the general challenges and future research on the applications of OIHMs in transfer hydrogenation are also discussed. Expectedly, this review can provide an instructive viewpoint for the rational design and practical application of OIHMs in reductive upgrading of bio-based oxygenated compounds via hydrogen transfer processes.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216259"},"PeriodicalIF":20.3,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142434170","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-15DOI: 10.1016/j.ccr.2024.216265
Shahzad Ameen , Aleena Tahir , Tanveer ul Haq , Ammar Ahmed Khan , Mira Tul Zubaida Butt , Irshad Hussain , Syed Zajif Hussain , Habib ur Rehman
This review elucidates the pivotal role of polyoxometalates (POMs) in photoelectrochemical (PEC) water splitting, an emerging field with profound implications for sustainable hydrogen production. POMs, characterized by their versatile metal oxide clusters, exhibit remarkable efficacy as co-catalysts, enhancing the efficiency and performance of PEC systems. Through precise modulation of charge separation dynamics and promotion of efficient charge transfer kinetics at the semiconductor-electrolyte interface, POMs significantly augment the overall efficiency of PEC devices. Their inherent attributes, including broad-spectrum light absorption and exceptional chemical stability, underscore their suitability for solar-driven electrolysis, offering a viable pathway towards sustainable hydrogen generation. This review underscores the strategic importance of POMs in optimizing the functionality of key semiconductors employed in PEC, such as BiVO4, CdS, Si, Fe2O3, and TiO2, thereby advancing the frontiers of renewable energy conversion technologies. Additionally, the exploration of innovative strategies for enhancing POM-based photoelectrodes, encompassing tailored surface modifications and synergistic tandem cell configurations, underscores the indispensable role of POMs in catalyzing the transition towards efficient and scalable hydrogen production methodologies.
{"title":"Driving sustainable energy: The role of polyoxometalates (POMs) in photoelectrochemical hydrogen production","authors":"Shahzad Ameen , Aleena Tahir , Tanveer ul Haq , Ammar Ahmed Khan , Mira Tul Zubaida Butt , Irshad Hussain , Syed Zajif Hussain , Habib ur Rehman","doi":"10.1016/j.ccr.2024.216265","DOIUrl":"10.1016/j.ccr.2024.216265","url":null,"abstract":"<div><div>This review elucidates the pivotal role of polyoxometalates (POMs) in photoelectrochemical (PEC) water splitting, an emerging field with profound implications for sustainable hydrogen production. POMs, characterized by their versatile metal oxide clusters, exhibit remarkable efficacy as co-catalysts, enhancing the efficiency and performance of PEC systems. Through precise modulation of charge separation dynamics and promotion of efficient charge transfer kinetics at the semiconductor-electrolyte interface, POMs significantly augment the overall efficiency of PEC devices. Their inherent attributes, including broad-spectrum light absorption and exceptional chemical stability, underscore their suitability for solar-driven electrolysis, offering a viable pathway towards sustainable hydrogen generation. This review underscores the strategic importance of POMs in optimizing the functionality of key semiconductors employed in PEC, such as BiVO<sub>4</sub>, CdS, Si, Fe<sub>2</sub>O<sub>3</sub>, and TiO<sub>2</sub>, thereby advancing the frontiers of renewable energy conversion technologies. Additionally, the exploration of innovative strategies for enhancing POM-based photoelectrodes, encompassing tailored surface modifications and synergistic tandem cell configurations, underscores the indispensable role of POMs in catalyzing the transition towards efficient and scalable hydrogen production methodologies.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216265"},"PeriodicalIF":20.3,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142431785","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The utilization of solar energy to synthesize fuels offers a promising and sustainable solution for energy storage, but inefficient utilization of the solar spectrum and inadequate charge separation currently hinder its commercial viability. Designing and developing efficient photocatalytic materials are fundamental to achieve high energy conversion efficiency. Single atom catalysts (SACs), with well-defined single atoms (SAs) as active sites, have demonstrated excellent intrinsic activity, high atomic utilization efficiency, and a well-understood structure-activity relationship. These catalysts are widely applied in photocatalytic H2 evolution, photoreduction of CO2, photofixation of N2 and photocatalytic H2O2 production. Importantly, compared to other elements, the unpaired electrons of nitrogen atoms are more readily bonded with metal atoms and subsequently form M-N based SACs. In this review, we will present a systematical overview of the synthetic approaches of M-N based SACs in photocatalysis and also discusses the effect of SACs modifications on light responsiveness, carrier transfer dynamics and surface reaction efficiency in photocatalytic systems. Then, we propose the key principles of SACs design and photocatalytic applications based on recent advancements. Finally, we discuss the major challenges and potential opportunities that lie ahead in the development of SACs.
{"title":"Metal-nitrogen coordinated single atomic photocatalysts for solar energy conversion","authors":"Yiqiao Wang , Liling Liao , Gangqiang Zhu , Weiqiang Xie , Qian Zhou , Fang Yu , Hongpeng Zhou , Haiqing Zhou","doi":"10.1016/j.ccr.2024.216254","DOIUrl":"10.1016/j.ccr.2024.216254","url":null,"abstract":"<div><div>The utilization of solar energy to synthesize fuels offers a promising and sustainable solution for energy storage, but inefficient utilization of the solar spectrum and inadequate charge separation currently hinder its commercial viability. Designing and developing efficient photocatalytic materials are fundamental to achieve high energy conversion efficiency. Single atom catalysts (SACs), with well-defined single atoms (SAs) as active sites, have demonstrated excellent intrinsic activity, high atomic utilization efficiency, and a well-understood structure-activity relationship. These catalysts are widely applied in photocatalytic H<sub>2</sub> evolution, photoreduction of CO<sub>2</sub>, photofixation of N<sub>2</sub> and photocatalytic H<sub>2</sub>O<sub>2</sub> production. Importantly, compared to other elements, the unpaired electrons of nitrogen atoms are more readily bonded with metal atoms and subsequently form M-N based SACs. In this review, we will present a systematical overview of the synthetic approaches of M-N based SACs in photocatalysis and also discusses the effect of SACs modifications on light responsiveness, carrier transfer dynamics and surface reaction efficiency in photocatalytic systems. Then, we propose the key principles of SACs design and photocatalytic applications based on recent advancements. Finally, we discuss the major challenges and potential opportunities that lie ahead in the development of SACs.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216254"},"PeriodicalIF":20.3,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142436283","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-12DOI: 10.1016/j.ccr.2024.216251
Wenmin Xiong , Na Song , Xiaowei Mo , Zeyu Zhang , Jinyan Song , Yushi Wang , Junyu Li , Zhilin Yu
Biomaterials aim to address healthy issues and contribute to improve life quality for human beings. Currently available biomaterials have been challenged in performing theranostic objectives under real dynamic physiological conditions and at precise targeting sites. To address this concern, over the past few years in situ formulation of biomaterials has been developed to perform disease diagnosis and therapy in a precise manner involving different components. In this review, we introduced the concept of in situ-formed biomaterials and their design principles, specifically summarizing the progress of in situ-formed biomaterials based on stimulus-responsive self-assembly of peptides in living systems. We highlighted the recent examples of in situ assembling systems of peptides with applications ranging from cancer therapy, anti-inflammation and anti-bacteria, as well as tissue engineering and regeneration. The challenges met by in situ biomaterials and the prospects of in situ peptide assembly towards biomedicines are also discussed, which hopefully elucidates the great potential of in situ-formed biomaterials for future healthcare.
{"title":"In situ formulation of biomaterials for disease therapy: Recent advances in peptide assembly strategies","authors":"Wenmin Xiong , Na Song , Xiaowei Mo , Zeyu Zhang , Jinyan Song , Yushi Wang , Junyu Li , Zhilin Yu","doi":"10.1016/j.ccr.2024.216251","DOIUrl":"10.1016/j.ccr.2024.216251","url":null,"abstract":"<div><div>Biomaterials aim to address healthy issues and contribute to improve life quality for human beings. Currently available biomaterials have been challenged in performing theranostic objectives under real dynamic physiological conditions and at precise targeting sites. To address this concern, over the past few years in situ formulation of biomaterials has been developed to perform disease diagnosis and therapy in a precise manner involving different components. In this review, we introduced the concept of in situ-formed biomaterials and their design principles, specifically summarizing the progress of in situ-formed biomaterials based on stimulus-responsive self-assembly of peptides in living systems. We highlighted the recent examples of in situ assembling systems of peptides with applications ranging from cancer therapy, anti-inflammation and anti-bacteria, as well as tissue engineering and regeneration. The challenges met by in situ biomaterials and the prospects of in situ peptide assembly towards biomedicines are also discussed, which hopefully elucidates the great potential of in situ-formed biomaterials for future healthcare.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216251"},"PeriodicalIF":20.3,"publicationDate":"2024-10-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142415724","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The swift progression of industrialization poses a profound threat to environmental integrity, giving rise to environmental pollution and a consequential imbalance in ecosystems, thereby compromising public health. Consequently, the exigency for environmental remediation has become both urgent and imperative. Within this context, the burgeoning research field of piezoelectric catalysis has ushered in transformative and sustainable advancements in catalytic processes, untethered from the reliance on luminous energy or electricity inputs. This novel approach exhibits efficacy in generating reactive substances tailored to combat refractory contaminations. This comprehensive review delineates state-of-the-art progressions in piezoelectric materials, characterization instruments, mechanisms, and their applications in environmental decontamination. The exploration encompasses piezoelectric catalysis, piezo-photocatalysis, and various piezo-Fenton-like processes, including piezocatalytic H2O2 evolution, piezo-self cycled Fenton-like, and piezocatalytic persulfate and ozonation. A meticulous exposition begins with a detailed analysis of conventional and emerging piezoelectric materials, accompanied by a discussion on effectual and popular characterizations. The subsequent sections delve into the prevailing origin of the piezoelectric effect, prerequisites, improving strategies, and unresolved issues pertaining to the discernment of piezocatalytic mechanisms. Further, this review systematically explores the application of piezoelectric-coupled advanced oxidation processes and their intrinsic mechanisms in organic decontamination, H2O2 evolution, heavy metal reduction, bacterial disinfection, and CO2 reduction. In conclusion, the paper articulates the challenges inherent in piezocatalytic techniques and proposes directions for future development. The aim is to contribute to an enhanced foundational understanding of piezoelectric catalysis and piezoelectric-based Advanced Oxidation Processes (AOPs) as potent tools for addressing contemporary environmental challenges.
{"title":"Piezoelectric effect coupled advanced oxidation processes for environmental catalysis application","authors":"Bofan Zhang , Mengyi Zhao , Kai Cheng , Juanjuan Wu , Shiro Kubuki , Liang Zhang , Yang-Chun Yong","doi":"10.1016/j.ccr.2024.216234","DOIUrl":"10.1016/j.ccr.2024.216234","url":null,"abstract":"<div><div>The swift progression of industrialization poses a profound threat to environmental integrity, giving rise to environmental pollution and a consequential imbalance in ecosystems, thereby compromising public health. Consequently, the exigency for environmental remediation has become both urgent and imperative. Within this context, the burgeoning research field of piezoelectric catalysis has ushered in transformative and sustainable advancements in catalytic processes, untethered from the reliance on luminous energy or electricity inputs. This novel approach exhibits efficacy in generating reactive substances tailored to combat refractory contaminations. This comprehensive review delineates state-of-the-art progressions in piezoelectric materials, characterization instruments, mechanisms, and their applications in environmental decontamination. The exploration encompasses piezoelectric catalysis, piezo-photocatalysis, and various piezo-Fenton-like processes, including piezocatalytic H<sub>2</sub>O<sub>2</sub> evolution, piezo-self cycled Fenton-like, and piezocatalytic persulfate and ozonation. A meticulous exposition begins with a detailed analysis of conventional and emerging piezoelectric materials, accompanied by a discussion on effectual and popular characterizations. The subsequent sections delve into the prevailing origin of the piezoelectric effect, prerequisites, improving strategies, and unresolved issues pertaining to the discernment of piezocatalytic mechanisms. Further, this review systematically explores the application of piezoelectric-coupled advanced oxidation processes and their intrinsic mechanisms in organic decontamination, H<sub>2</sub>O<sub>2</sub> evolution, heavy metal reduction, bacterial disinfection, and CO<sub>2</sub> reduction. In conclusion, the paper articulates the challenges inherent in piezocatalytic techniques and proposes directions for future development. The aim is to contribute to an enhanced foundational understanding of piezoelectric catalysis and piezoelectric-based Advanced Oxidation Processes (AOPs) as potent tools for addressing contemporary environmental challenges.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216234"},"PeriodicalIF":20.3,"publicationDate":"2024-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142405408","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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