Coordination Chemistry Reviews最新文献

{"title":"Fabrication of MXene-based membranes and their application in per- and polyfluorinated substances removal: Comparison with commercial membranes, challenges, and future improvements","authors":"Roham Ghanbari ,&nbsp;Di Wu ,&nbsp;Philippe M. Heynderickx","doi":"10.1016/j.ccr.2024.216253","DOIUrl":"10.1016/j.ccr.2024.216253","url":null,"abstract":"<div><div>In the past decade, <em>per</em>- and polyfluorinated substances (PFAS) have garnered significant attention due to their widespread presence and detrimental environmental and health impacts. These compounds exhibit exceptional hydrophobicity, oleophobicity, chemical stability, and resistance to biodegradation, posing a significant threat to living organisms, particularly mammals. Numerous technologies have been employed for PFAS removal in which membrane filtration stands out as a highly effective approach, capable of removing different types of PFAS (anionic, cationic, and zwitterionic) with efficiencies exceeding 99 %. The advent of MXenes, a class of two-dimensional transition metal nitrides, oxycarbides, carbonitrides, and carbides, has revolutionized water treatment. MXene-based membranes, with their diverse elemental structure and ability to accommodate multiple surface functional groups, offer exceptional promise for PFAS removal. For the first time, all studies about PFAS removal <em>via</em> MXene-based membranes were summarized in this review article, and their performance was compared to commercial membranes. Moreover, the fabrication methods of MXene-based membranes were discussed in details. Finally, authors have given numerous suggestions about the future of PFAS removal <em>via</em> MXene-based membranes and explained what is missing currently.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216253"},"PeriodicalIF":20.3,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142536539","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Exploring the nature’s discriminating factors behind the selection of molybdoenzymes and tungstoenzymes depending on the biological environment","authors":"Udita Das ,&nbsp;Ankita Das ,&nbsp;Asim K. Das","doi":"10.1016/j.ccr.2024.216290","DOIUrl":"10.1016/j.ccr.2024.216290","url":null,"abstract":"<div><div>Pterin based molybdenum cofactor found in the molybdenum dependent enzymes catalyzes the oxo-transferase and hydroxylase activity. For tungsten, the pterin based tungsten cofactor is known for the similar biological low potential redox activities in anaerobic conditions in thermophilic microorganisms. Nature's selection of tungsten and molybdenum for the different working conditions is rationalized in terms of their relative bioavailabilities, thermodynamic stabilities of their compounds, kinetic inertness and the difference in relativistic effect experienced by these two congeners. The relativistic effect is the most important factor to justify the tungsten <em>vs.</em> molybdenum selectivity in different enzymes. The non-innocent dithiolene based pterin ligand tunes the biological redox activity of the enzymes by stabilising +4, +5 and +6 oxidation states of molybdenum and tungsten. In fact, it acts as a ‘redox buffer’ in their catalytic mechanism. Mechanistic aspects of the enzymatic activity are more investigated for the Mo-dependent enzymes compared to those of W-dependent enzymes. Strong controversies regarding the mechanisms of activity of the enzymes like Mo/W-FDH (formate dehydrogenase), Mo-Cu-CODH (carbon monoxide dehydrogenase), W-AOR (aldehyde oxidoreductase), W-AH (acetylene hydratase), W-BCRs (benzoyl-CoA-reductases), <em>etc.</em>, indicate that this field is still an active area of research.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216290"},"PeriodicalIF":20.3,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142539893","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Transition metal-based heterojunctions for alkaline electrocatalytic water splitting","authors":"Chengshuang Xu ,&nbsp;Ying Hong ,&nbsp;Zhong Li ,&nbsp;Xiaotong Di ,&nbsp;Wenjun Wang ,&nbsp;Xiaochen Dong ,&nbsp;Xiaozhou Mou","doi":"10.1016/j.ccr.2024.216287","DOIUrl":"10.1016/j.ccr.2024.216287","url":null,"abstract":"<div><div>Electrocatalytic water splitting is an attractive strategy for generating hydrogen energy, involving the hydrogen evolution reaction (HER) at cathode and the oxygen evolution reaction (OER) at anode. Given the sluggish reaction kinetics often observed in alkaline electrolytes, there is a critical need for catalysts that can lower the energy barrier and accelerate the reaction rates. Transition metal-based catalysts hold significant potential to replace conventional noble metal catalysts due to their earth abundance, cost-effectiveness, and adjustable activity. To achieve electrocatalytic activity similar to, or even surpassing, that of precious metals, constructing heterogeneous structures proves to be an effective strategy. Within a heterojunction, the two components work synergistically to promote the electrocatalytic process. The lattice strain and electron transfer in a heterojunction can modulate the electronic structure of active sites, optimizing the adsorption of reaction intermediates and accelerating reaction kinetics. In this review, we offer an overview of the characteristics, types, characterization and synthesis methods of heterojunctions. Additionally, we delve into the application of heterojunctions in HER, OER, and overall water splitting. Finally, we present an overview of the existing challenges in developing heterojunctions and offer a perspective on the prospective utilization of heterojunctions for hydrogen generation.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216287"},"PeriodicalIF":20.3,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142539894","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Metal–organic frameworks for one-step ethylene purification from multi-component hydrocarbon mixtures","authors":"Yan Han ,&nbsp;Linyao Wang ,&nbsp;Yuanbin Zhang ,&nbsp;Banglin Chen","doi":"10.1016/j.ccr.2024.216291","DOIUrl":"10.1016/j.ccr.2024.216291","url":null,"abstract":"<div><div>Ethylene (C₂H₄) is extremely important as one of the world's largest chemical commodity. A variety of light hydrocarbon gases (C₁-C₃) and carbon dioxide (CO₂) coexist with C₂H₄ in the production, which need to be removed to produce polymer grade C₂H₄. Conventional thermal-driven distillation separation processes consume large amounts of energy, which has prompted the creation of energy-efficient adsorption separation techniques that utilize physical adsorbents. Metal-organic frameworks (MOFs) have great potential in the separation and purification of ethylene due to their vast surface area, large porosity and highly customizable pores. The purification of C₂H₄ from multi-component mixtures is more related to the real hydrocarbon industry than the extensively studied separation of ideal binary mixtures, but more challenging for the design of desirable MOFs. To date, there is a noticeable absence of a comprehensive discussion of advancements in the separation of ethylene from multi-component mixtures using MOF adsorbents. This review offers a detailed overview of the ongoing developments in the creation of MOFs for multi-component C₂H₄ purification applications, which include the purification of C₂H₄ from ternary, quaternary, quinary, senary, septenary and octary hydrocarbon mixtures. Ternary-component separations include C₂H₂/C₂H₄/C₂H₆ separation and C₂H₂/CO₂/C₂H₄ separation while quaternar-component separations include C₂H₂/C₂H₄/CO₂/C₂H₆ separation and C₂H₂/C₂H₄/C₃H₄/1-C₄H₆ separation. Particularly, the merits and innovations of MOFs in the single-step purification of C₂H₄ from complex mixtures will be examined. This includes insights into the mechanisms of separation and the overarching tactics devised to enhance the performance of the separation process. Moreover, this review will outline the possible hurdles faced when shifting MOFs from the domain of scholarly inquiry to practical industrial application, and to encapsulate the outlook for this swiftly progressing area of study.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216291"},"PeriodicalIF":20.3,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142539896","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Progress in metal-organic frameworks (MOFs) as multifunctional material: Design, synthesis and anticorrosion performance techniques","authors":"Kashif Rahmani Ansari ,&nbsp;Ambrish Singh ,&nbsp;Muhammad Younas ,&nbsp;Ismat H. Ali ,&nbsp;Yuanhua Lin","doi":"10.1016/j.ccr.2024.216294","DOIUrl":"10.1016/j.ccr.2024.216294","url":null,"abstract":"<div><div>In the past few years, researchers have emphasized the development of metal-organic frameworks (MOFs), which are made up of metallic ions and organic compounds as ligands. MOFs have an extensive list of potential applications as corrosion-inhibiting nanomaterials due to inherent notable characteristics, which include an enormous effective area, pore size manipulation, changeable behavior and molecular framework, and a wide range of potentially active domains. The current review focuses on the latest research on the utilization of metal-organic frameworks as anti-corrosive material. Herein, this review focuses on the latest research progress of MOF-based corrosion protection materials and reviews their anticorrosion performance, including the commonly concerned synthesis approaches of MOFs for corrosion protection with their respective advantages and shortcomings, the different anticorrosion applications, latest techniques used for screening MOF corrosion inhibition performance and the presented challenges that need to be conquered in practical applications. Meanwhile, we explained the corrosion protection mechanisms of MOFs when serve as inhibitors, nano-containers, and surface protecting coatings. At the end of this review, the future outlooks of MOFs for corrosion protection is provided, we hope this review will illuminate the achievement of high performed anticorrosion MOFs and offer new ideas for the development of MOF-based materials for future corrosion protection application.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216294"},"PeriodicalIF":20.3,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142539895","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Cuproptosis nanomedicine in cancer therapy: Novel insights and future perspectives","authors":"Lu Wang ,&nbsp;Jingxuan Piao ,&nbsp;Hengkai Qi ,&nbsp;Chu Qiao ,&nbsp;Qiqiang Guo ,&nbsp;Minjie Wei ,&nbsp;Zhenhua Li","doi":"10.1016/j.ccr.2024.216284","DOIUrl":"10.1016/j.ccr.2024.216284","url":null,"abstract":"<div><div>Cuproptosis, a new type of copper-triggered programmed cell death, has recently emerged as a promising target for cancer treatment. The nanomedicine-based targeting of cuproptosis has experienced significant advancements, attracting enormous interest and opening new avenues for developing novel therapeutics. In this review, we provide a comprehensive summary of the biology of copper, its critical roles in cancer biology, and the molecular mechanisms underlying cuproptosis. We also offer insight into recent progress in nanomedicine-triggered cuproptosis, a potent and proof-of-concept application in innovative therapeutic strategies. Finally, we highlight future perspectives and challenges, including the clinical translation of cancer nanomedicine and new cuproptosis-mediated emerging paradigms.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216284"},"PeriodicalIF":20.3,"publicationDate":"2024-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142519632","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Electronic structure modulation in Prussian blue and its analogs: Progress and challenges in perspective of energy-related catalysis","authors":"Baghendra Singh ,&nbsp;Yogita Arya ,&nbsp;Goutam Kumar Lahiri ,&nbsp;Arindam Indra","doi":"10.1016/j.ccr.2024.216288","DOIUrl":"10.1016/j.ccr.2024.216288","url":null,"abstract":"<div><div>Prussian blue, a more than three hundred years old inorganic coordination polymer, has drawn immense interest in the field of energy conversion. Prussian blue (PB) and Prussian blue analogs (PBAs) have been extensively used for water oxidation, hydrogen evolution, oxygen reduction, nitrogen reduction reaction, etc. In addition, PB and PBAs were explored as the cocatalysts for photocatalytic and photoelectrochemical energy conversion processes. Although initial studies focused on the development of morphology, porosity, surface area, accessible catalytic sites, core-shell structure, etc., the tuning of the electronic structure was found to largely influence the electrochemical features of PB and PBAs. The inter-valence charge transport in PB and PBAs through the –CN bridge can also be modulated by altering the electronic structure of the metal sites. This, in turn, offers a significant modification of its properties as a cocatalyst when combined with a semiconductor. The present review article addresses the effect of electronic structural modulation in PB and PBAs to improve its electrocatalytic and cocatalytic activities. The recent achievements and challenges in designing PBAs and their application in energy conversion have been highlighted along with potential future advancements. Special emphasis has been given to understanding structural aspects and the subsequent establishment of a structure-activity relationship for energy conversion processes.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216288"},"PeriodicalIF":20.3,"publicationDate":"2024-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142488643","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Interfacial adhesion in flexible electronics: Materials, structures and applications","authors":"Mingyang Lu ,&nbsp;Jia You ,&nbsp;Mengjie Gao ,&nbsp;Wendong Li ,&nbsp;Cancan Zhang ,&nbsp;Bolin Zhu ,&nbsp;Chong Peng ,&nbsp;Shiteng Wu ,&nbsp;Dazhenlamu ,&nbsp;Wei Ren ,&nbsp;Guangxian Li ,&nbsp;Chuan Fei Guo ,&nbsp;Junlong Yang","doi":"10.1016/j.ccr.2024.216278","DOIUrl":"10.1016/j.ccr.2024.216278","url":null,"abstract":"<div><div>Flexible electronics, featuring low thinness, high conformability, multifunctionality, and high portability, have revolutionized the interaction experiences of human beings. This emerging technology is also ushering in groundbreaking advancements in intelligent manufacturing, humanoid robots, and digital medicine. However, the diverse functionalities and applications of flexible electronics often require integration of multilayer interfaces in devices. The assembly of such multilayer and multimaterial structures frequently faces challenges of interfacial incompatibilities of interfaces, including the mismatch in mechanical properties, chemistry, and functionalities. These challenges can compromise the long-term reliability and efficiency of either the interfaces in a device or the interface between a device and human tissues/robots. A seamlessly integrated flexible electronic device not only mitigates the risk of interfacial delamination but also enhances the mechanical stability of the device in dynamic or multifaceted environments. This manuscript offers an exhaustive review on tough interfaces in flexible electronics enabled by physical interactions, covalent chemical bonds or structural designs. Moreover, considering their primary applications — skin-wearables, implantable, and robotics — we delve into the latest breakthroughs, persistent challenges, and pragmatic strategies associated with reinforced adhesive interfaces. Such a discussion furnishes invaluable perspectives for the conceptualization and fabrication of highly durable flexible devices.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216278"},"PeriodicalIF":20.3,"publicationDate":"2024-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142489014","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"SERS-based microfluidic sensor for sensitive detection of circulating tumor markers: A critical review","authors":"Yeru Wang ,&nbsp;Rongke Gao ,&nbsp;Changbiao Zhan ,&nbsp;Huakun Jia ,&nbsp;Xiaozhe Chen ,&nbsp;Yang Lu ,&nbsp;Yujie Feng ,&nbsp;Liandong Yu","doi":"10.1016/j.ccr.2024.216289","DOIUrl":"10.1016/j.ccr.2024.216289","url":null,"abstract":"<div><div>Cancer ranks as the second leading cause of death worldwide, and many researchers have found that early screening and diagnosis greatly reduce cancer-related mortality. The use of circulating tumor markers (CTMs) in cancer diagnostics is well warranted, given the potential for CTMs to provide valuable insights into the occurrence and development of cancer. The past two decades have witnessed remarkable advancements in microfluidics based on surface-enhanced Raman spectroscopy (SERS) in the field of biomedicine. It has become a well-established technology for CTM detection. Throughout this review, recent developments of SERS-based microfluidic technology within the realm of CTM detection, including classification, identification, and capture methods, detection mode, as well as novel strategies and applications, have been highlighted. The purpose is to emphasize the importance of detection methods rooted in SERS-based microfluidic technology in biomedicine, as well as to promote their expansion towards various applications.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216289"},"PeriodicalIF":20.3,"publicationDate":"2024-10-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142487282","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Recent advances of piezoelectric materials used in sonodynamic therapy of tumor","authors":"Hezhe Huang,&nbsp;Yuqing Miao,&nbsp;Yuhao Li","doi":"10.1016/j.ccr.2024.216282","DOIUrl":"10.1016/j.ccr.2024.216282","url":null,"abstract":"<div><div>Piezoelectric materials, recognized as unique functional materials due to their ability to interconvert mechanical and electrical energy, have demonstrated broad application prospects in the biomedical field. Particularly in cancer therapy, piezoelectric materials serve as sonosensitizers that generate internal electric fields under ultrasonic-induced mechanical force, modulating the migration of electrons and holes, and subsequently triggering surface redox reactions to enhance the efficacy of sonodynamic therapy (SDT). SDT, as an emerging non-invasive treatment modality, showcases distinctive advantages such as high tissue penetration, strong spatiotemporal controllability, and low treatment costs due to the synergistic interaction between ultrasound and sonosensitizers. This review systematically discusses various types of piezoelectric materials, with a focus on the recent research progress, mechanisms of action, and optimization strategies of novel materials like perovskites in the SDT domain. Additionally, the applications of piezoelectric materials in the combined treatment of SDT with other therapies are introduced, and the prospects and potential of these materials in tumor sonodynamic therapy are highlighted. By delving into the fundamental principles of the piezoelectric effect and its mechanistic role in SDT, this review offers new perspectives and insights into the biomedical applications of piezoelectric materials.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216282"},"PeriodicalIF":20.3,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142486757","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}