Coordination Chemistry Reviews最新文献

{"title":"Design and Engineering of Metal-Organic Frameworks for Energy Conversion and Environmental Remediation","authors":"K. Aravinthkumar ,&nbsp;S. Gokul Eswaran ,&nbsp;Shuchen Hsieh ,&nbsp;Shuling Hsieh ,&nbsp;A. Santhana Krishna Kumar ,&nbsp;C. Raja Mohan","doi":"10.1016/j.ccr.2026.217582","DOIUrl":"10.1016/j.ccr.2026.217582","url":null,"abstract":"<div><div>Recent technological advancements, rising energy crises, and environmental pollution have prompted the development and synthesis of innovative materials for efficient energy conversion and water purification in order to fulfil society's clean energy and water needs. A variety of pollutants have grown more persistent in aquatic environments. The inappropriate use of dyes and antibiotics, as well as their inadequate digestion in organisms, results in their discharge into aquatic habitats, which has harmed human health. Therefore, effective removal of textiles and pharmaceuticals, especially dyes and antibiotics, from wastewater and polluted water bodies is of significant interest to research communities across the world. Besides, the depletion of fossil fuels increases the demand for renewable energy sources. Since solar energy is the most abundant and endless energy source, it provides an environmentally friendly alternative to fossil fuels. Metal-organic frameworks (MOFs), which are porous crystalline hybrid materials formed by the linkage of metal centers (clusters) and organic linkers (organic ligands), have been identified as a highly active research domain for more than a decade due to their wide range of applications as photocatalytic and photovoltaic. In the present research domain, the research community has been drawn to emerging MOFs by their distinctive properties, which include a large surface area, controllable morphologies, tunable porosities, layer-by-layer design, high-quality crystalline products, outstanding inorganic-organic nature, and incredible diversity in functionalities. In this review, the latest developments in the use of MOFs and their derivatives in a variety of solar cell technologies, such as dye-sensitized, perovskite, and organic solar cells, are methodically described. These MOF-based photovoltaic systems have shown remarkable potential for enhancing sunlight-to-electricity conversion efficiency and improving stability. In addition, the utilization of MOFs and their derivatives as photocatalysts is a highly effective approach for breaking down dye and antibiotic residues in water. Key improvements and modifications, such as stronger interfacial contact, enhanced light harvesting, and improved charge separation, have been emphasized to develop potent photocatalysts that significantly enhance the removal of dyes and antibiotics. The environmental factors influencing photocatalytic degradation activity, such as photocatalyst concentration, pollutant concentration, solution pH, light intensity, reaction temperature, Fenton reagent, and scavengers, were thoroughly discussed, assisting in the design of an ideal photoreactor with high photocatalytic efficiency and a cost-effective process. Furthermore, the remaining significant challenges in the aforementioned domains are addressed, and potential future research endeavours in the development of MOFs are also outlined.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"555 ","pages":"Article 217582"},"PeriodicalIF":23.5,"publicationDate":"2026-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146076408","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Thermocatalytic CO2 cycloaddition with epoxides by d-block metal complexes: Mechanistic insights, ligand design, and catalytic trends","authors":"Shahzad Rasheed ,&nbsp;Shezma Shakeel Ahmed ,&nbsp;Sahar Sadiq ,&nbsp;Yong Yang ,&nbsp;Ghayoor Abbas Chotana ,&nbsp;Qandeel Almas","doi":"10.1016/j.ccr.2026.217640","DOIUrl":"10.1016/j.ccr.2026.217640","url":null,"abstract":"<div><div>The rising concentration of CO₂ in the atmosphere has intensified efforts to convert it into value-added chemicals. Among various strategies, the cycloaddition of CO₂ with epoxides to produce cyclic carbonates represents an atom-efficient and industrially relevant transformation. This review provides a mechanism-anchored survey of thermocatalytic CO₂ activation by d-block metal complexes, focusing on developments over the past fifteen years. Particular attention is paid to how oxidation state, ligand architecture, and/or secondary coordination sphere affect activity and selectivity. Both terminal and internal epoxides are evaluated to highlight performance gaps and design priorities. Key ligand families, including salen and salophen scaffolds, Schiff bases, porphyrins, and N-heterocyclic carbenes (NHCs), have enabled significant advances, with electronic tuning and steric design improving reactivity under mild conditions (≤100 °C, ≤5 bar CO₂). Bimetallic and multinuclear complexes are highlighted for their synergistic behavior, which impacts turnover numbers (TON) and turnover frequencies (TOF) while broadening substrate scope. Mechanistic insights are evaluated to identify rate-determining steps and to guide rational catalyst design. The review also benchmarks representative systems across the d-block, identifying state-of-the-art examples as models for future development. Persistent challenges, including reliance on harsh conditions (&gt;120 °C, &gt;10 bar CO₂), low enantioselectivity, limited activity with internal epoxides, and catalyst recyclability, are discussed alongside emerging directions such as secondary-sphere engineering, halide-free nucleophiles, and integration with CO₂ capture. Together, these perspectives outline pathways toward efficient and industrially viable d-block catalysts for CO₂ utilization.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"555 ","pages":"Article 217640"},"PeriodicalIF":23.5,"publicationDate":"2026-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146076410","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Single- and multi-metal engineered, functionalized hybrid biochars for heavy metal adsorption: synthesis, structure-function relationships, and coordination mechanisms","authors":"Dharma Raj Kandel ,&nbsp;Prem Gaudel ,&nbsp;Milan Babu Poudel ,&nbsp;Wooseop Yun ,&nbsp;Jaewoo Lee","doi":"10.1016/j.ccr.2025.217521","DOIUrl":"10.1016/j.ccr.2025.217521","url":null,"abstract":"<div><div>Heavy metals pose a serious threat to global water systems due to their toxicity, persistence, and strong bioaccumulative potential in ecosystems and humans. Among various remediation strategies, adsorption is regarded one of the most effective and versatile approaches. Biochar (BC) has gained significant attention as a sustainable and low-cost adsorbent owing to its simple preparation, tunable porosity, high surface area, and intrinsic functional groups. However, pristine BC often exhibits limited adsorption efficiency toward diverse metal ions, necessitating targeted engineering and surface modification. To address this, two modification approaches, namely metal-based nano-architected BC (NA-BC) and surface-functionalized BC (f-BC), have emerged as leading platforms. NA-BCs are synthesized from either single metals (<em>e</em>.<em>g</em>., oxides, hydroxides, and metal-organic frameworks) or multi-metal systems (<em>e</em>.<em>g</em>., layered double hydroxides, spinel oxides), with magnesium, manganese, calcium, aluminum, zinc, and iron commonly used as precursors for their low toxicity, cost-effectiveness, and chemical versatility. Meanwhile, surface functionalization introduces hydroxyl, amino, sulfonic, thiol, carboxylic, and phosphate groups <em>via</em> inorganic or organic modifications, yielding f-BCs and f-NA-BCs with tunable porosity, enriched surface functionalities, and enhanced stability. These features collectively improve adsorption capacity, selectivity, and reusability. The heavy metal removal by BC composites involves physisorption and chemisorption, including pore diffusion, electrostatic attraction, chelation/coordination, ion exchange, precipitation, and redox reactions, which can be validated through XRD, FTIR, XPS, and DFT analyses. Looking ahead, advancing scalability, environmental safety, and machine-learning-guided material design will be crucial for developing next-generation engineered BCs capable of practical implementation in fixed-bed filters in disaster-affected zones and industrial wastewater treatment.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"555 ","pages":"Article 217521"},"PeriodicalIF":23.5,"publicationDate":"2026-01-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146072739","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Programmable Zn-based nanozymes","authors":"Xingtan Zhu ,&nbsp;Yanguo Guo ,&nbsp;Tiedong Sun","doi":"10.1016/j.ccr.2026.217630","DOIUrl":"10.1016/j.ccr.2026.217630","url":null,"abstract":"<div><div>Programmable nanocatalytic systems represent an emerging frontier that integrates nanotechnology, catalytic science, and stimuli-responsive materials to achieve precise control over catalytic behaviors through the synergistic interplay of external stimuli and internal modular architectures. Among various nanozymes, Zn-based nanozymes have recently gained significant research attention owing to their excellent biocompatibility, low toxicity, and highly tunable catalytic properties. This review presents a survey of programmable nanocatalytic systems driven by Zn-based nanozymes, covering recent advances in synthesis strategies, modular design principles, and mechanisms for precise catalytic regulation. It also explores their diverse applications across biomedical, environmental, and energy-related fields. Furthermore, the review provides a critical discussion on prevailing challenges and future research directions, spanning from fundamental mechanistic studies to the rational design of efficient, stable, and translation-ready systems. By consolidating current knowledge and highlighting pathways for innovation, this work aims to serve as a foundational reference for accelerating the development and practical deployment of Zn-based nanozyme technologies.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"555 ","pages":"Article 217630"},"PeriodicalIF":23.5,"publicationDate":"2026-01-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146071865","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Donor-acceptor type metal-organic frameworks: Synthesis, unique advantages, and applications","authors":"Hong-Guang Jin ,&nbsp;Yong-Tao Liu ,&nbsp;Peng-Cheng Zhao ,&nbsp;Huapeng Sun","doi":"10.1016/j.ccr.2026.217631","DOIUrl":"10.1016/j.ccr.2026.217631","url":null,"abstract":"<div><div>Metal-organic frameworks (MOFs) have become one of the star materials in diverse fields benefiting from their obvious advantages of tailorable topology structures, adjustable pore sizes, and abundant active sites. However, the intrinsic charge and energy transfer (CT and EnT) efficiencies of MOFs are still limited due to the lack of specific CT and EnT pathways that leads to inevitable charge recombination and energy loss. In recent years, to tackle this issue, the donor-acceptor (D-A) type MOFs with integrated electron/energy donor and acceptor units wherein extended carrier lifetime could be achieved, have made great progress. In this review, the synthetic strategies of D-A type MOFs are first outlined. Then the unique advantages of D-A type MOFs including photo- and electroconductivity are discussed. Subsequently, the applications of D-A type MOFs in luminophores, fluorescent sensors, photocatalysis, photothermal conversion, magnetism, and X-ray detection and imaging are systematically summarized. Finally, the challenges and prospects on the development of D-A MOFs are presented. This review aims to inspire more incisive research in the design and development of D-A MOFs with improved performance for multifunctional applications.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"555 ","pages":"Article 217631"},"PeriodicalIF":23.5,"publicationDate":"2026-01-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146072738","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Molecularly imprinted catalysts for pollutants degradation: principle, process, application, toxicological effect, and prospect","authors":"Zhimin Liu,&nbsp;Rong Fan,&nbsp;Yuanyuan Wan,&nbsp;Xiaolan Zhang,&nbsp;Shihan Gao,&nbsp;Zhigang Xu","doi":"10.1016/j.ccr.2026.217629","DOIUrl":"10.1016/j.ccr.2026.217629","url":null,"abstract":"<div><div>Environmental pollutants, often present at low concentrations and pose a serious threat to ecological security. Traditional treatment techniques are constrained by poor selectivity, low efficiency and high susceptibility to interference from complex matrices. Molecular imprinting technology (MIT), characterized by exceptional selectivity in specific recognition and a simplified yet precise fabrication process, is increasingly emerging as a promising tool in the environment monitoring field. By integrating with various catalytic factors, molecularly imprinted catalysts (MICs) offer an effective solution to this challenge. This review systematically summarizes the underlying principles of photocatalysis, electrocatalysis, and enzyme-mimicking catalysis in MICs. Furthermore, it highlights the recent advances in various forms of MICs and their practical applications in pollutant degradation for the first time. The potential toxicity and environmental impact of MICs materials and their degradation products are also critically evaluated. This work aims to inspire novel applications of MIT in catalysis, offer methodological insights into the effective removal of persistent pollutants, and provide a forward-looking perspective to encourage further exploration by emerging researchers in this interdisciplinary field.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"555 ","pages":"Article 217629"},"PeriodicalIF":23.5,"publicationDate":"2026-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146072748","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Green synthesis and biomedical applications of CuO/MgO nanocomposite: Antibacterial, antioxidant, and antidiabetic efficacies","authors":"S. Priyadharshini ,&nbsp;M. Karnan ,&nbsp;M. Ayyanar ,&nbsp;C. Jenipher ,&nbsp;Arun Thirumurugan ,&nbsp;N. Chidhambaram","doi":"10.1016/j.ccr.2026.217637","DOIUrl":"10.1016/j.ccr.2026.217637","url":null,"abstract":"<div><div>Oxidative stress and its associated complications pose serious threats to human health, demonstrating the pressing need for effective redox-active materials. This study presents the biogenic synthesis of a redox-active Copper oxide/Magnesium oxide (CuO/MgO) nanocomposite using <em>Citrus limonium</em> extract and evaluates its antibacterial, antioxidant, and antidiabetic activities, along with CuO nanoparticles for comparison. X-ray diffraction (XRD) analysis divulges the interwoven CuO and MgO phase in a single matrix with a crystallite size of 44 nm. Fourier transform infrared (FTIR) spectra expose the vibrational bands at 864, 678, and 570 cm⁻¹, corresponding to Cu<img>O, Mg<img>O, and Cu–O–Mg. Optical analysis reveals a bandgap energy of 1.47 eV for the CuO/MgO composite, higher than 1.29 eV observed for CuO nanoparticles, indicating the improved visible-light absorption. Morphological examination reveals irregular aggregates with porous surface texture of the CuO/MgO composite. X-ray photoelectron spectroscopy (XPS) analysis substantiates the Cu²⁺, Mg²⁺, and O²⁻ oxidation states of rudiments in the nanocomposite. Biologically, the CuO/MgO nanocomposite exhibits potential antibacterial activity against <em>S. epidermidis</em> and <em>E. coli</em>, with inhibition zones of 27.4 ± 0.15 mm and 25.2 ± 0.1 mm, respectively, and shows enhanced antioxidant activity with IC₅₀ values of 140.72 ± 0.6 μg/mL. Furthermore, it demonstrates stronger inhibition of α-amylase and α-glucosidase enzymes, 79.8% and 86.1%, respectively, compared to CuO nanoparticles. Overall, this study confirms that the CuO/MgO nanocomposite, synthesized via a green approach, exhibits enhanced structural, optical, and biological properties, making it a promising candidate for biomedical applications targeting oxidative stress-related disorders.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"555 ","pages":"Article 217637"},"PeriodicalIF":23.5,"publicationDate":"2026-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146071869","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Well-defined group 12 metal complexes for CO2 functionalisation","authors":"Geetika Gupta ,&nbsp;Sandip Munshi ,&nbsp;Samuel Dagorne","doi":"10.1016/j.ccr.2026.217636","DOIUrl":"10.1016/j.ccr.2026.217636","url":null,"abstract":"<div><div>The present contribution comprehensively reviews well-defined group 12 metal complexes that react with CO₂, an area primarily dominated by Zn(II) complexes. Discrete Zn(II) complexes have received significant attention for both stoichiometric and catalytic CO₂ functionalisation over the past 15 years, although initial stoichiometric studies in this area date back to the 1980s. Catalytic Zn-based CO₂ functionalisation, most notably including hydrosilylation/boration catalysis and cyclic carbonates formation from CO₂ and epoxides, has recently been extensively studied. Very recent developments on the use of Zn-based systems for electro- and photocatalytic CO₂ reduction catalysis are also noteworthy. Besides its chronological importance, stoichiometric CO₂ fixation by various Zn species remains an attractive research line, for instance, to better understand the structure and function of Zn-containing enzymes such as carbonic anhydrase. The diverse aspects of Zn-based CO₂ functionalisation, along with the associated Zn complexes, are thus discussed herein. Finally, the few Cd(II) and Hg(II) complexes known to react with CO₂ are reviewed.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"555 ","pages":"Article 217636"},"PeriodicalIF":23.5,"publicationDate":"2026-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146072746","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Integration of graphitic carbon nitrides with coordination complexes for photocatalytic applications","authors":"Charul Sharma ,&nbsp;Binitendra Naath Mongal","doi":"10.1016/j.ccr.2026.217612","DOIUrl":"10.1016/j.ccr.2026.217612","url":null,"abstract":"<div><div>Graphitic carbon nitride (g-C₃N₄), a metal free polymeric semiconductor is attracting great attention due to lower band-gap (∼2.7 eV), charge separation efficiency, chemically inert and non-toxic nature in presence of abundant earth elements. However, pure g-C₃N₄ suffers from limited visible-light absorption and charge recombination limiting its photocatalytic efficiency. To overcome these issues, recent research has been focused on formation of heterojunctions with g-C₃N₄. This review article focuses on integration of g-C₃N₄ with metal complexes to improve its photocatalytic efficiency. The innovative methods for preparing the hybrid photocatalysts with g-C₃N₄ and molecular metal complexes via covalent and non-covalent interactions with its effect on surface chemistry and electronic structure have been thoroughly discussed. Furthermore, the article focuses on structural design of the prepared composites, interfacial charge transfer between g-C₃N₄ and metal complexes, along with their applications in photocatalytic CO₂ reduction, H₂ evolution, organic conversions and dye degradation. The comprehensive review will help in identifying pathways for effective utilization of g-C₃N₄/metal complex composites in driving various photocatalytic reactions.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"555 ","pages":"Article 217612"},"PeriodicalIF":23.5,"publicationDate":"2026-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146072747","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Solid-state NMR characterization of weak interactions in molecular crystals","authors":"Chiara Sabena ,&nbsp;Chiara Rosso ,&nbsp;Téodor Iftemie ,&nbsp;Roberto Gobetto ,&nbsp;David L. Bryce ,&nbsp;Michele R. Chierotti","doi":"10.1016/j.ccr.2026.217610","DOIUrl":"10.1016/j.ccr.2026.217610","url":null,"abstract":"<div><div>Weak non-covalent interactions, including hydrogen bonds, π–π stacking, and the diverse family of σ-hole interactions (halogen, chalcogen, pnictogen, tetrel, osme, and matere bonds), govern the structure, stability, and properties of molecular crystals. Solid-state Nuclear Magnetic Resonance (SSNMR) spectroscopy provides an unparalleled means of probing these interactions at the atomic level by directly sensing local electronic environments, independent of long-range order. This review surveys recent advances (approximately since 2020) in SSNMR methodologies for detecting, characterizing, and quantifying weak interactions in molecular solids. Particular emphasis is placed on developments in high-field and ultrafast magic-angle spinning (MAS) instrumentation, as well as novel pulse sequences that enhance access to key nuclei involved in non-covalent bonding. SSNMR observables, such as chemical shifts, dipolar and <em>J</em> couplings, quadrupolar parameters, and relaxation rates, are shown to provide quantitative insight into the interaction strength, geometry, and dynamics of hydrogen-bonded, π-stacked, and σ-hole-bonded systems. The review also discusses the synergistic integration of SSNMR with diffraction (single-crystal and powder X-ray diffraction, electron diffraction) and computational methods (Crystal Structure Prediction, DFT calculations, molecular dynamics simulations, machine learning models), yielding a multidimensional framework for elucidating structure–property relationships in both crystalline and disordered materials. Special attention is devoted to complex environments such as multicomponent crystals, host–guest assemblies, and amorphous dispersions. Looking ahead, continued advances in ultrahigh-field instrumentation, pulse-sequence design, and NMR crystallography promise to transform SSNMR from a diagnostic into a predictive tool for supramolecular chemistry and crystal engineering, bridging microscopic interactions with macroscopic material behaviour.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"555 ","pages":"Article 217610"},"PeriodicalIF":23.5,"publicationDate":"2026-01-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146072752","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}