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Mass Transfer Coefficient of Extraction of Anthocyanin from Mangosteen Peel (Garcinia mangostana L.) with Ethanol-HCl as Solvent 乙醇-盐酸萃取芒果皮花青素的传质系数
Pub Date : 2022-11-13 DOI: 10.31315/e.v19i3.8008
Zubaidi Achmad, Faizah Hadi, S. Kholisoh
Anthocyanin is a natural pigment that causes the purple skin of the mangosteen fruit. This study aimed to observe the effect of temperature, stirring time, and ethanol concentration in ethanol–HCl solvent on anthocyanins produced from the mangosteen peel extraction process and determine the value of its mass transfer coefficient. The laboratory work was conducted with mangosteen peel powder extracted with ethanol solvent containing 1% HCl solution using an extraction apparatus set. The mangosteen rind is cleaned and then mashed until it passes the size of -60+80 mesh. Then 50 g of mangosteen rind powder was put into a three-neck flask along with ethanol solution with various concentrations of 55%, 65%, 75%, 85%, and 95%, each containing 1% HCl. Extraction was carried out at various stirring times of 3, 4, 5, 6, and 7 hours with temperature variations of 30, 40, 50, 60, and 70oC. Each product was distilled at a temperature of <60oC. Anthocyanin content were analyzed by spectrophotometric method. The results showed that the optimum conditions at the extraction temperature of 50oC with stirring time for 4 hours and 95% ethanol concentration in ethanol–HCl solvent with anthocyanin content obtained of 9,8377.10-4 (g anthocyanin/g solvent) and kC of 0,00781 g/(cm2.hour).
花青素是一种天然色素,可导致山竹果实的紫色表皮。本研究旨在观察温度、搅拌时间和乙醇-盐酸溶剂中乙醇浓度对山竹皮提取过程中产生的花青素的影响,并测定其传质系数。使用提取装置组,用含有1%HCl溶液的乙醇溶剂提取山竹皮粉末进行实验室工作。将山竹皮清洗干净,然后捣碎,直到它达到-60+80目的大小。然后将50g山竹皮粉末与各种浓度为55%、65%、75%、85%和95%的乙醇溶液一起放入三颈烧瓶中,每个乙醇溶液含有1%HCl。萃取在3、4、5、6和7小时的不同搅拌时间下进行,温度变化为30、40、50、60和70℃。每种产品在<60℃的温度下蒸馏。采用分光光度法测定花青素含量。结果表明,在提取温度为50℃、搅拌时间为4小时、乙醇浓度为95%的乙醇-盐酸溶剂中,花青素含量为98377.10-4(g花青素/g溶剂),kC为000781 g/(cm2.hour)的最佳条件下。
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引用次数: 0
Potency of Alluvial Mineral of Luk Ulo River with XRD and AAS in Kebakalan Village Kebumen 用x射线衍射和原子吸收光谱分析克布门克巴卡兰村鲁克乌洛河冲积矿物的效力
Pub Date : 2022-11-13 DOI: 10.31315/e.v19i3.7826
E. Nursanto, Afroza Pratiwi, Eddy Winarno, B. Sugiarto, R. Mirahati
: Based on petrographic data, XRD, and fluid inclusions, it was interpreted that the quartz veins associated with low sulfide in Karangsambung area underwent 2 stages of system change from mesothermal system to epithermal system. This showed the potential mineral contained in the material, especially in the Luk Ulo River where there were alluvial deposits. To determine the mineral and material composition contained in alluvial material in Luk Ulo River, Kebakalan Village, AAS and XRD were used. This research was limited only to testing Au, Ag, and Cu from 2 samples, namely sample A for sand and sample B for rock. XRD results on samples A and B showed that quartz (SiO 2 ) had the highest percentage (30-50%) compared to other minerals. While the results of the AAS tests showed that the highest Au and Ag contents were in sample B and Cu in sample A with total of 19.30 g/ton Au, 8.67 g/ton Ag, and 62.88 g/ton Cu. Meanwhile, the lowest total Au and Ag were in sample A and Cu was in sample B which amounted to Au 11.32 g/ton, Ag 2.77 g/ton, and Cu 34.86 g/ton.
根据岩石学资料、XRD和流体包裹体分析,认为卡朗三峰地区低硫化物石英脉经历了中温系统到低温系统2个阶段的体系变化。这表明材料中含有潜在的矿物,特别是在有冲积矿床的鲁克乌洛河中。采用原子吸收光谱法(AAS)和x射线衍射法(XRD)测定了克巴卡兰村陆克乌洛河冲积物中的矿物和物质组成。本研究仅对2个样品进行Au、Ag、Cu的检测,分别为砂样A和岩石样B。样品A和样品B的XRD结果表明,石英(sio2)所占比例最高(30-50%)。原子吸收光谱分析结果表明,样品B中Au和Ag含量最高,样品A中Cu含量最高,Au含量为19.30 g/t, Ag含量为8.67 g/t, Cu含量为62.88 g/t。同时,样品A中Au和Ag总量最低,样品B中Cu总量最低,Au为11.32 g/t, Ag为2.77 g/t, Cu为34.86 g/t。
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引用次数: 0
Adsorption Equilibrium of Methylene Blue By Activated Carbon From Post-Anthesis Male Flower Palm Oil Waste 活性炭对花后雄花棕榈油废弃物中亚甲基蓝的吸附平衡
Pub Date : 2022-11-07 DOI: 10.31315/e.v19i3.8055
Yuli Ristianingsih, Indriana Lestari, Alit Istiani
: Methylene blue (MB) is wastewater from the textile industry. This dye is difficult to degrade naturally because it has a benzene group in its chemical chain. There are several ways to reduce waste, one of the economical ways is by using adsorption. In this study, MB was adsorbed using activated carbon from post-anthesis male flower palm oil (PAMF) waste which was activated using potassium hydroxide (KOH). The adsorption process was carried out at various temperatures (30, 40, and 50℃). The results showed that the addition of a KOH activator could increase the sorption capacity of methylene blue by 25.64%. The optimum temperature is suitable for the adsorption process of methylene blue with activated carbon of PAMF waste activated by KOH at a temperature of 30℃ with an adsorption capacity of 58.4793%. The adsorption equilibrium mechanism was studied using two types of adsorption isotherm models, namely the Langmuir and Freundlich models. Based on the data obtained, the MB adsorption process on activated carbon was compatible with the Freundlich model an R 2 of 0.9557.
:亚甲基蓝(MB)是纺织工业的废水。这种染料很难自然降解,因为它的化学链上有一个苯基团。减少废物有几种方法,其中一种经济的方法是使用吸附法。本研究利用氢氧化钾活化的花后雄花棕榈油(PAMF)废弃物中的活性炭吸附MB。吸附过程在不同温度(30、40和50℃)下进行。结果表明,加入KOH活化剂可使亚甲基蓝的吸附量提高25.64%。KOH活化PAMF废弃物活性炭对亚甲基蓝的最适吸附温度为30℃,吸附量为58.4793%吸附等温线模型,即Langmuir和Freundlich模型。根据所得数据,MB在活性炭上的吸附过程符合Freundlich模型,R2为0.9557。
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引用次数: 0
Improving Stability of Anthocyanin Extracted from Ipomoea batatas by Co-pigmentation 共色素沉淀法提高巴豆花青素的稳定性
Pub Date : 2022-10-26 DOI: 10.31315/e.v19i3.7660
Rachma Tia Evitasari, G. Budiarti
Public awareness of the dangers of using synthetic dyes has started to boost the prestige of natural dyes. The limitation of natural dyes is one of the causes of the limited use of natural dyes commercially. This research utilized purple sweet potato (Ipomoea batatas L.) as a source of anthocyanins. The purpose of this study was the stabilization of anthocyanins from purple sweet potato through the co-pigmentation process. The first stage is the extraction of natural anthocyanin dyes from purple sweet potatoes using the microwave-assisted method, then stabilization of anthocyanins through a co-pigmentation process with variations in the addition of arabic gum, Fe-Alginate, and catechins at various concentrations as Total Anthocyanin Content (TAC), and stability test. The higher the concentration value of the co-pigmenting agent added to the extract, the higher the color shift, indicated by a decrease in the TAC value. The best copigmentation was obtained with green tea containing catechin concentration of 0.01 ml green tea/20 ml extract. with a TAC value of 0.1499 mg/L. Stabilization test against storage, co-pigmentation with catechins in green tea gave the best stability. While the stability against heating and oxidation, co-pigmentation with gum arabic will stabilize the condition of anthocyanin extracts.
公众对使用合成染料的危险性的认识已经开始提高天然染料的声望。天然染料的局限性是天然染料商业使用受限的原因之一。本研究利用紫甘薯(Ipomoea batatas L.)作为花青素的来源。本研究的目的是通过共色素沉淀过程稳定紫甘薯花青素。第一阶段是使用微波辅助方法从紫甘薯中提取天然花青素染料,然后通过共沉淀过程稳定花青素,加入不同浓度的阿拉伯树胶、褐藻酸铁和儿茶素,如总花青素含量(TAC),并进行稳定性测试。添加到提取物中的共色素化剂的浓度值越高,由TAC值的降低指示的色移就越高。用含有儿茶素浓度为0.01毫升绿茶/20毫升提取物的绿茶可获得最佳的副作用。TAC值为0.1499mg/L。稳定性试验表明,绿茶中与儿茶素共色素沉着的稳定性最好。同时,与阿拉伯树胶共色素沉着对加热和氧化的稳定性将稳定花青素提取物的条件。
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引用次数: 0
Energy Audit of Flouresen Lights at School Building C III Floor Politeknik Negeri Semarang 三宝垄国家理工大学C三层教学楼荧光灯的能源审计
Pub Date : 2022-09-30 DOI: 10.32497/eksergi.v18i3.3890
S. Supriyo, M. Margana, Wiwik Purwati W, S. Suwarti, M. Mulyono

Energy audit is very necessary to calculate the level of energy consumption of a building or buildings. The research includes the amount of energy consumption based on the initial energy audit and detailed energy audit as well as saving opportunities based on conditions in the field. Based on the initial energy audit, the value of the Energy Consumption Intensity (IKE) is 0.699 kWH/m2month, while in the detailed audit the IKE value is 0.935 kWH/m2month. Based on the results of a detailed energy audit, the lighting measurement of 325 lux still meets the requirements for a classroom with a standard between 250 lux to 500 lux.


能源审计对于计算一栋或多栋建筑的能源消耗水平是非常必要的。该研究包括基于初始能源审计和详细能源审计的能源消耗量,以及基于该领域条件的节约机会。根据初始能源审计,能源消耗强度(IKE)值为0.699 kWH/m2月,而在详细审计中,IKE值为0.935 kWH/m2。根据详细的能源审计结果,325勒克斯的照明测量仍然符合标准在250勒克斯到500勒克斯之间的教室的要求。
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引用次数: 1
Comparative Analysis of Windings and Vector Groups in 20/0.4 kV Distribution Transformers at CV. Centrado Prima 20/0.4 kV配电变压器绕组和矢量组的比较分析。Centrado首席
Pub Date : 2022-09-30 DOI: 10.32497/eksergi.v18i3.3765
Taopik Hidayat, Brainvendra Widi Dionova, Sinka Wilyanti, M. N. Mohammed
Turn ratio test is a comparison test of the number of secondary turns with the primary turns on the transformer. The turns ratio and group vector testing is one of the routine transformer tests. This test generally uses the Transformer Turns Ratio (TTR) test tool, the test equipment used sometimes experiences technical and non-technical problems so a comparative test method is needed to get a good analysis. The research method used is observational research and literature study, namely analyzing the transformer to be studied by conducting TTR testing in two ways, namely testing with test equipment and three-phase low voltage sources, aiming to obtain a very good level of accuracy. The test results were analyzed and compared with theory and calculations, with reference to the IEC 60076-1 standard. The results of the comparison of windings and group vectors using TTR 100 test equipment and a 3-phase low voltage source (TVR) show the same conclusions as the results of the analysis, where the first transformer sample is in normal condition and meets the requirements. SPLN D3.002-1:2007 or IEC Standard 60076-1. While the second sample transformer is in an abnormal condition in the W winding where the difference value is above 0.5%.
匝数比试验是变压器二次匝数与一次匝数的比较试验。匝比和群矢量试验是变压器的常规试验之一。本试验一般采用变压器匝比(TTR)试验工具,所使用的试验设备有时会遇到技术和非技术问题,因此需要一种比较试验的方法来得到很好的分析。研究方法为观察研究法和文献研究法,即通过TTR测试对待研究变压器进行分析,采用测试设备测试和三相低压源测试两种方式进行TTR测试,目的是获得非常好的准确度。参考IEC 60076-1标准,对试验结果进行了理论和计算分析比较。使用ttr100测试设备和三相低压源(TVR)对绕组和群矢量进行比较的结果与分析结果一致,其中第一个变压器样品状态正常,满足要求。SPLN D3.002-1:2007或IEC标准60076-1。而第二个样品变压器在W绕组异常,差值在0.5%以上。
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引用次数: 2
Biogas Desulfurization Using Iron Gram Waste Machining Practicum Process at The Department of Mechanical Engineering, Politeknik Negeri Semarang 三宝垄国家理工大学机械工程系采用铁克废料加工实践工艺进行沼气脱硫
Pub Date : 2022-09-30 DOI: 10.32497/eksergi.v18i3.3785
Nanang Apriandi, W. Widyaningsih, M. Margana, M. Surindra, S. Supriyo, Nadia Tasya Ayu Luthfiana

The important matter about biogas as an alternative energy source was the presence of hydrogen sulfide (H2S) which is very corrosive. The biogas desulfurization process was absolutely necessary to reduce the risk of damage to the equipment. For small-scale applications, the selection of the type of adsorbent became important to reduce additional costs. One alternative material that can be used was iron gram waste. The aim of this study was to investigate the use of iron gram waste resulting from the machining practicum process at the Department of Mechanical Engineering, Politeknik Negeri Semarang as an alternative material for making adsorbents. Iron gram waste was processed into Iron (III) Oxide (Fe2O3) and Iron (III) Hydroxide (Fe(OH)3), formed into billets with an average billet mass of 250 gr. The performance test of the adsorbent in the biogas desulfurization process was carried out under conditions of variation in the flow rate of biogas feed 1, 2, and 3 liters per minute, and the volume of biogas purified in one process was 50 liters. As a result, the most optimum performance was obtained in the test with a feed biogas flow rate of 1 liter/minute, with a percentage reduction in H2S levels contained in the biogas by an average of 82,56%.

沼气作为替代能源的一个重要问题是,它含有腐蚀性很强的硫化氢(H2S)。沼气脱硫过程对于降低设备损坏的风险是绝对必要的。对于小规模应用,选择吸附剂的类型对于减少额外成本变得非常重要。另一种可用的替代材料是铁克废料。本研究的目的是研究利用机械工程系机械加工实习过程中产生的铁克废料作为制造吸附剂的替代材料。将铁克废渣加工成氧化铁(Fe2O3)和氢氧化铁(Fe(OH)3),形成平均质量为250克的钢坯。在沼气进料1、2、3升/分流速变化的条件下,对吸附剂在沼气脱硫过程中的性能进行了试验,一次工艺净化的沼气体积为50升。结果表明,当进料沼气流量为1升/分钟时,沼气中H2S含量平均降低82,56%,获得了最佳性能。
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引用次数: 1
Monitoring of iot-based Wind and Solar Hybrid Power Plants for Agricultural Irrigation Systems 农业灌溉系统中基于iot的风能和太阳能混合发电厂的监测
Pub Date : 2022-09-30 DOI: 10.32497/eksergi.v18i3.3892
B. Prasetiyo, W. Widyaningsih, Yusuf Dewantoro H, S. Suwarti

The use of renewable energy, one of which is Hybrid Power Plants  (PLTH). The PLTH used in this study is a wind and solar power plant. To keep the plant from being damaged and prevent a decrease in tool performance, PLTH was developed based on the Internet of Things (IoT).  IoT will later monitor the performance of the plant.  In this study using the ESP32 TTGO SIM800L microcontroller, the sensors used were DC voltage sensors, current sensors (ACS712), wind speed sensors (anemometers), wind direction sensors (wind vanes), and water flow sensors.  The research began with designing the relationship between components, working on monitoring and programming systems on software, installing outdoor sensors and installing monitoring systems, and ending with data observations.   The results  obtained on the observation of data, the best error percentage values  are presented by various sensors with values less than 6%.



可再生能源的使用,其中之一是混合动力发电厂(PLTH)。本研究中使用的PLTH是一个风能和太阳能发电厂。为了防止工厂受损并防止工具性能下降,PLTH是基于物联网(IoT)开发的。物联网稍后将监测工厂的性能。在这项使用ESP32 TTGO SIM800L微控制器的研究中,使用的传感器包括直流电压传感器、电流传感器(ACS712)、风速传感器(风速计)、风向传感器(风向标)和水流传感器。这项研究从设计组件之间的关系开始,在软件上开发监控和编程系统,安装室外传感器和监控系统,并以数据观测结束。根据对数据的观测结果,各种传感器给出了小于6%的最佳误差百分比值。
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引用次数: 0
Comparison of the Use of NaOH and KOH Activators in the Manufacture of Activated Carbon from Cassava Peel (Manihot utilissima) NaOH和KOH活化剂在木薯皮活性炭生产中的应用比较
Pub Date : 2022-08-28 DOI: 10.31315/e.v19i2.7245
Mitha Puspitasari, Wibiana Wulan Nandari, Faizah Hadi
: Cassava (Manihot utilissima) is a staple food beside rice and corn for Indonesian people. Cassava peel is a waste of cassava processing agroindustries such as tapioca flour industry, fermentation industry, and staple food industry. This waste contains a fairly high carbon element of 59,31%. Cassava peel has the potential to be used as raw material for activated carbon because of its high carbon content. Activated carbon production involved some steps such as preparing raw materials, carbonization, activation, neutralization, and analysis of water content, ash, iodine number, and analysis of the pore surface area of activated carbon. Activated carbon was activated using NaOH and KOH with concentrations of 0.1; 0,2; 0,3; 0,4; and 0,5N. The results showed that activated carbon which activated with 0,4N NaOH and 0,5N KOH provided the closest parameter with SNI 06-3730-1995 standard. The use of NaOH activator can increase the surface area of activated carbon compared to KOH activator.
:木薯(Manihot utilisima)是印度尼西亚人除了大米和玉米之外的主食。木薯皮是木薯加工农业的废弃物,如木薯粉工业、发酵工业和主食工业。这种废物含有相当高的碳元素,占59.31%。木薯皮由于含碳量高,具有作为活性炭原料的潜力。活性炭的生产包括原料制备、炭化、活化、中和、含水量、灰分、碘值分析、活性炭孔表面积分析等步骤。使用浓度为0.1的NaOH和KOH活化活性炭;0,2;0.3;0.4;和0.5N。结果表明,用0,4N NaOH和0,5N KOH活化的活性炭提供了最接近SNI 06—3730—1995标准的参数。与KOH活化剂相比,使用NaOH活化剂可以增加活性炭的表面积。
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引用次数: 0
Utilization of Nanochitosan as Adsorbent of Mercury (Hg) in Gold Ore Processing Waste 纳米壳聚糖吸附金矿废弃物中的汞
Pub Date : 2022-08-17 DOI: 10.31315/e.v19i2.6862
Nadhifa Aliyya Himawan, H. Darmokoesoemo, Totok Ardiarto, A. Prasetya, Badrud Tamam Ibnu Ali
Mercury pollution in gold ore processing wastewater can cause environmental and health problems. A large amount of mercury pollution causes neurological disease, paralysis, loss of sense of taste, irregular speech, and death. One effective method to reduce mercury amount in the environment is adsorption. Adsorption performance is affected by several factors such as surface area of material, deacetylation degree (DD), and adsorption condition, which is indicated by contact time and mercury concentration. Nanochitosan is used in this research. Effect of deacetylation degree (85%; 87%; 95%), contact time (30;60;90;120 minutes), and variation of mercury concentration (5;10;15;20;25;30 ppm) on adsorption performance was investigated in this research. Nanochitosan in this research is characterized by FTIR, SEM-EDX, BET-BJH, and pH PZC. AAS measures adsorption performance in this research. The result shows that nanochitosan, which has the best adsorption performance, is nanochitosan with a deacetylation degree of 95%, at a contact time of 60 minutes, and mercury concentration is 15 ppm.
金矿石加工废水中的汞污染会造成环境和健康问题。大量的汞污染会导致神经系统疾病、瘫痪、味觉丧失、语言不规则和死亡。减少环境中汞含量的一种有效方法是吸附。吸附性能受材料表面积、脱乙酰化程度(DD)、吸附条件等因素的影响,主要表现为接触时间和汞浓度。纳米壳聚糖用于本研究。脱乙酰度的影响(85%;87%;研究了接触时间(30、60、90、120分钟)和汞浓度(5、10、15、20、25、30 ppm)对吸附性能的影响。利用FTIR、SEM-EDX、BET-BJH和pH PZC对纳米壳聚糖进行了表征。原子吸收光谱法测定吸附性能。结果表明,在接触时间为60分钟、汞浓度为15 ppm时,脱乙酰度为95%的纳米壳聚糖具有最佳的吸附性能。
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引用次数: 0
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