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Verification of the Walkley Black Method Test for Determination of Organic Carbon Elements in Palm Oil Empty Fruit Bunch Waste Fertilizer 棕榈油空果束废肥中有机碳元素测定的Walkley黑法试验验证
Pub Date : 2022-08-10 DOI: 10.31315/e.v19i3.7267
Wakhid Khoirul Umar, Fandika Agustiyar, A. Rahma
: Many solid wastes from palm oil processing are empty fruit bunches, but their utilization is still limited. o ne of the uses of Oil Palm Empty Fruit Bunches ( OPEFB ) is organic fertilizer. The organic carbon method was verified on organic fertilizer from OPEFB waste using a UV-Vis Spectrophotometer. This study aims to verify the method of testing organic carbon on OPEFB fertilizer. Determination of carbon content in OPEFB fertilizer refers to the Association of Analytical Communities (AOAC) with the Walkley Black method. The results of the organic carbon test on OPEFB fertilizer show that the correlation coefficient (r) obtained is 100% , and the % RSD value of 0.40% means that the value is below 2/3 CV Horwitz of 4.72. accuracy with a value of 106.99%. The LOD is 2.45, and the LOQ is 8.17. Therefore, the limit value of the instrument is obtained by the LOD value of 2.49 and the LOQ of 8.32; the test results obtained indicate that it has complied with the conditions with acceptance. The test results for determining organic carbon in OPEFB fertilizer using the Walkley Black method showed valid results, so the method can be used to test organic carbon levels in OPEFB fertilizer.
:棕榈油加工产生的许多固体废物都是空的果串,但它们的利用仍然有限。油棕榈空果包(OPEFB)的用途之一是有机肥料。采用紫外-可见分光光度计对OPEFB废弃物中的有机肥料进行了有机碳法验证。本研究旨在验证有机碳在OPEFB肥料上的测试方法。OPEFB肥料中碳含量的测定参考分析群落协会(AOAC)的Walkley-Black方法。有机碳在OPEFB肥料上的测试结果表明,获得的相关系数(r)为100%,%RSD值为0.40%意味着该值低于4.72的2/3 CV Horwitz。准确度为106.99%。LOD为2.45,LOQ为8.17。因此,仪器的限值由LOD值2.49和LOQ值8.32得出;试验结果表明,符合验收条件。Walkley-Black法测定OPEFB肥料中有机碳的试验结果是有效的,该方法可用于OPEFB肥料有机碳含量的测定。
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引用次数: 0
Acid Tar Waste Beneficiation Through Blending with Coal 酸性焦油废弃物与煤混合选矿
Pub Date : 2022-07-31 DOI: 10.31315/e.v19i2.6346
D. Musademba, D. Simbi, P. K. Kuipa
The possibility of blending acid tar waste with coal as a beneficiation method was explored in this work. It was essential to first establish the material properties of the acid tar and coal samples together with that of the blends in terms of proximate analyses. The acid tar waste to coal blending ratios of 3:1, 1:1 and 1:3 were used. It was observed that acid tar waste exhibited high volatile and moisture content with low ash and carbon content when compared with coal. When compared with coal; a 3:1 blending ratio exhibited 56.9 % and 7.6 % reduction in ash and fixed carbon respectively and on the contrary a 38.1 % increase in volatile matter was observed. An opposite trend was obtained with 1:3 blend ratio. The 1:1 blend ratio was found to decrease the volatile and ash content by 8.3 % and 52.7 % respectively whilst fixed carbon boosted by 4.2 %. The choice for the blending ratio to apply is a trade-off between fixed carbon and volatile matter. If volatile matter is of any significance then a 3:1 mixture would be ideal; such a mixture will aid in easier ignition of coal.  On the other hand a 1:3 binary mixture yields a higher fixed carbon fraction, whose effect is to boost the calorific value of the fuel, an excellent factor for combustion. Overall however, it makes economic sense to blend coal with acid tar waste for enhancing sustainability.
探讨了酸焦油废与煤共混选矿的可能性。首先根据近似分析确定酸焦油和煤样品的材料特性以及混合物的材料特性是至关重要的。酸焦油废煤配煤比例分别为3:1、1:1和1:3。结果表明,与煤相比,酸焦油废渣挥发分和水分含量高,灰分和碳含量低。与煤相比;当配比为3:1时,灰分和固定碳分别减少56.9%和7.6%,而挥发分则增加38.1%。当混合比例为1:3时,则相反。结果表明,以1:1的掺合比例掺合后,挥发物和灰分含量分别降低8.3%和52.7%,固定碳含量提高4.2%。混合比例的选择是固定碳和挥发物之间的权衡。如果挥发性物质有任何意义,那么3:1的混合物将是理想的;这种混合物有助于使煤更容易着火。另一方面,1:3的二元混合物产生更高的固定碳分数,其效果是提高燃料的热值,这是燃烧的一个极好的因素。然而,总的来说,将煤与酸焦油废料混合以提高可持续性具有经济意义。
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引用次数: 0
Modification of Natural Carbolic Acid from Arpus wit Lemongrass Essential oil as a Disinfectant 用香茅精油对阿耳普斯天然石炭酸进行消毒液改性
Pub Date : 2022-07-28 DOI: 10.31315/e.v0i0.6036
Wibiana Wulan Nandari, Faizah Hadi, Mitha Puspitasari, Susanti Rina Nugraheni, Titik Mahargiani
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引用次数: 0
Characteristics and Applications of Sea Water Reverse Osmosis Reject Water of PT Cirebon Electric Power as Voltaic Cell Electrolyte and Salt Raw Material 海水反渗透废水作为光伏电池电解液和盐原料的特性及应用
Pub Date : 2022-07-26 DOI: 10.31315/e.v19i2.5361
D.A. Pramudikto, S. Nugroho, Agik Dwika Putra, Ilham Satria Raditya Putra, S. Setyawan, T. Ariyanto
Sea Water Reverse Osmosis (SWRO) reject water produced by PT Cirebon Electric Power has not been optimally utilized. In this research, a study of the characteristics of SWRO reject water was carried out to determine important properties such as turbidity, conductivity, pH and salinity. This characteristic is important as a basis for consideration of SWRO reject water applications. In addition, data were taken from a fairly long period of 5 years of SWRO operation (2016-2021) so that the consistency of the data can be known. The results showed that SWRO reject water had low turbidity (0.18±0.08 NTU), high conductivity of ca. 76.000 µS/cm, neutral pH and high salinity (4.6±0.3%). The study of the utilization of SWRO reject water was then carried out, namely as an electrolyte for salt water lamps and as raw material for making salt. The results showed that SWRO reject water can be used as an electrolyte for salt water lamps which produces a voltage potential up to 1.4 Volts (20% higher than seawater electrolyte). As a raw material for salt, the salt produced has excellent characteristics (eg 99% NaCl) and complies with SNI 3556:2016, except for the KIO3 content.
PT Cirebon电力公司生产的海水反渗透(SWRO)废水没有得到最佳利用。在本研究中,对SWRO污水的特性进行了研究,以确定浊度、电导率、pH和盐度等重要特性。这一特性是考虑SWRO拒绝水应用的重要基础。此外,数据取自SWRO运行的相当长的5年时间(2016-2021年),以便了解数据的一致性。结果表明,SWRO污水具有低浊度(0.18±0.08 NTU)、高电导率(约76.000µS/cm)、中性pH和高盐度(4.6±0.3%)等特点。然后对SWRO废水的利用进行了研究,即作为盐水灯的电解液和制盐的原料。结果表明,SWRO废液可作为盐水灯的电解液,产生高达1.4伏的电压电位(比海水电解液高20%)。作为盐的原料,生产的盐具有优异的特性(如99% NaCl),符合SNI 3556:2016,除了KIO3含量。
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引用次数: 0
Isotherm and Adsorption Thermodynamics Cross-Linked Chitosan Microcapsules of Kalium Pershulphate to Methyl Orange Dye 过硫酸盐钾交联壳聚糖微胶囊对甲基橙染料的等温吸附热力学研究
Pub Date : 2022-07-26 DOI: 10.31315/e.v19i2.6163
Endang Sulistyawati, Heni Anggorowati, Nadia Rochmah K.P, Navyta Ariardini
: Modeling of isotherm and adsorption thermodynamics in this study, leads to the determination of the classification of adsorption isotherms and the determination of the amount of energy and entropy to determine the impeccability of the process. As an adsorbent, a potassium persulfate crosslinked chitosan microcapsule was synthesized through a microencaptulation process using a solvent evaporation method with a carboxy methyl cellulose CMC coating. The characteristics of the chitosan microcapsules that were formed had a degree of deacetylation of 53,92 %, and a bn mutant diameter around 1-100 µm. Test materials used azo methyl orange dyes, which are often found in industrial waste and laboratory waste. Observations were made with variations in the concentration of methyl orange solution 5, 7,5, 10, 12,5, 15, 17,5 and 20 ppm at temperatures of 30, 40 and 50 ° C. calculation results show that the adsorption isotherm model obtained approaches the Langmuir isotherm model. The results of the analysis of temperature effects obtained positive Gibbs energy change values (ΔG) so that the adsorption process takes place non-spontaneously. The values of enthalpy change (ΔH) and entropy change (ΔS) of 33,86 kJ / mol and 0,0899 kJ / mol.K. This indicates that adsorption occurs chemically adsorption, is endothermic and adsorbat is not completely adsorbed.
在本研究中对等温线和吸附热力学进行建模,从而确定吸附等温线的分类,并确定能量和熵的量,以确定过程的无懈可施。以过硫酸钾交联壳聚糖为吸附剂,采用溶剂蒸发法制备了羧甲基纤维素CMC包覆的微胶囊。制备的壳聚糖微胶囊脱乙酰度为53.92%,突变体直径约为1-100µm。测试材料使用偶氮甲基橙染料,这种染料经常在工业废物和实验室废物中发现。在温度为30、40和50℃时,对甲基橙溶液5、7、5、10、12、5、15、17、5和20 ppm的浓度进行了观察,计算结果表明,所得吸附等温线模型接近Langmuir等温线模型。温度效应分析的结果得到了正的吉布斯能变化值(ΔG),使得吸附过程非自发发生。焓变(ΔH)和熵变(ΔS)分别为33,86 kJ / mol和0,0899 kJ / mol。这表明吸附发生化学吸附,是吸热的,吸附剂没有完全吸附。
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引用次数: 0
Mass Transfer Coefficient Extraction of Oleoresin from Zodia Leaf (Evodia suaveolens) with Ethanol Solvent Using Ultrasonic Cleaner 超声波清洗乙醇溶剂传质系数法提取油树脂
Pub Date : 2022-07-26 DOI: 10.31315/e.v19i2.7286
Siswanti Siswanti, Ratri Saviatri, Jeremy Adi Pratama
The Aedes sp mosquito is a vector of Dengue Hemorrhagic Fever (DHF) and chikungunya which are still commonly found in Indonesia. To control DHF, natural insecticides from plants can be used. Zodia plants (Evodia suaveolens) can be used as natural insecticides because they contain essential oils that mosquitoes do not like. To obtain oleoresin with optimal quality and quantity, extraction can be carried out using ultrasonic waves. To design an efficient extractor, mass transfer coefficient data is needed. Until now, the data is still difficult to obtain. The experiment was carried out using an ultrasonic cleaner, by observing the concentration of oleoresin for various leaf mass ratios of 4, 6, 8, 10, and 12 grams, extracted with 300 mL ethanol for 900 seconds. Concentration observations were also carried out for a time variation of 90 - 900 seconds, with 90 seconds intervals. The best extraction results were tested using GC-MS, to determine the components in the oleoresin. To determine the mass transfer coefficient (Kc) is to make a relationship between concentration and time for the best ratio of leaf weight and ethanol volume.Based on research that has been done with 300 mL of ethanol and extraction time of 900 seconds, the highest concentration was 0.0120 gr/mL, for the experiment using a leaf weight of 12 gr. The largest percentage (%) of oleoresin that could be extracted was 88.5%, for the experiment the leaf weight was 2 g. The optimum mass transfer coefficient (Kc) is 0.161088 1/minute. These data were obtained for the experiment of the relationship between concentration and time. Oleoresin from Zodia leaves contains 20.61% nerolidol. This compound has effectiveness as a mosquito repellent.
伊蚊是登革热和基孔肯雅病的媒介,在印度尼西亚仍然很常见。为了控制DHF,可以使用来自植物的天然杀虫剂。Zodia植物(Evodia suaveolens)可以用作天然杀虫剂,因为它们含有蚊子不喜欢的精油。为了获得最佳质量和数量的油树脂,可以使用超声波进行提取。为了设计高效的提取器,需要传质系数数据。到目前为止,数据仍然很难获得。使用超声波清洁器进行实验,通过观察用300mL乙醇提取900秒的不同叶质量比为4、6、8、10和12克的油树脂浓度。还进行了浓度观测,时间变化为90-900秒,间隔为90秒。采用气相色谱-质谱联用技术测定了油树脂的最佳提取结果。确定传质系数(Kc)是为了确定叶重和乙醇体积的最佳比例的浓度和时间之间的关系。根据用300毫升乙醇和900秒提取时间进行的研究,对于使用12克叶重的实验,最高浓度为0.0120克/毫升。可以提取的油树脂的最大百分比(%)为88.5%,对于实验,叶重为2克。最佳传质系数(Kc)为0.161088 1/分钟。这些数据是为了实验浓度和时间之间的关系而获得的。Zodia叶中的油树脂含有20.61%的橙花内酯。这种化合物具有驱蚊的功效。
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引用次数: 0
The Effect of Adding Activated Sludge and Types of Series Circuit Systems Microbial Fuel Cell (MFC) Using Chinese Food Restaurant Wastewater 添加活性污泥和串联系统类型的微生物燃料电池(MFC)对中餐厅废水的处理效果
Pub Date : 2022-04-08 DOI: 10.31315/e.v19i1.6479
D. Jaya, T. W. Widayati, Singgih Adi Nugroho, Firda Ellysa
Electricity consumption expands every year. However, in Indonesia, electricity is still highly dependent on conventional energy sources such as coal. A microbial fuel cell (MFC) is one of the alternative inventions that consists of a series of tools which converts chemical energy into electrical energy in the presence of microbial metabolism. In addition to produce electrical energy, it may also help to solve environmental issues by dealing with waste. This research was purposed to investigate the potency of Chinese food restaurant waste as substrate to generate electricity in microbial fuel cell. The research was done in three stages: wastewater preparation, assembly of MFC tools in various circuits, and running MFC processes. Results showed that the best electrical average (1.02 V) was found in the treatment system without active sludge. The best circuit was in the system in 4 series, which obtained a maximum voltage of 3.76 V and the largest power density of 62.66  mW/m2. In addition, with the addition of active sludge, biological oxygen demand (BOD) of the wastewater could be lowered up to 29.27%, and chemical oxygen demand (COD) up to 51.58%. Total suspended solid (TSS) could be decreased up to 49% on the sample withoud sludge addition.
用电量每年都在增长。然而,在印度尼西亚,电力仍然高度依赖煤炭等传统能源。微生物燃料电池(MFC)是由一系列在微生物代谢存在的情况下将化学能转化为电能的工具组成的替代发明之一。除了生产电能,它还可以通过处理废物来帮助解决环境问题。本研究旨在探讨中餐餐厨废弃物作为基质在微生物燃料电池中发电的效能。研究分三个阶段进行:废水制备、MFC工具在各种回路中的组装和MFC工艺的运行。结果表明,在没有活性污泥的处理系统中,电平均值最佳(1.02V)。最佳电路在4个串联的系统中,获得了3.76V的最大电压和62.66mW/m2的最大功率密度。此外,加入活性污泥后,废水的生物需氧量(BOD)可降低29.27%,化学需氧量(COD)可降低51.58%。
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引用次数: 0
Renewable Energy from Pyrolysis of Pine Wood with Zeolite Catalyst 沸石催化松木热解的可再生能源
Pub Date : 2022-04-05 DOI: 10.31315/e.v19i1.4564
Zubaidi Achmad, Abdullah Kunta Arsa, B. Alfitamara, Alfia Virgiandini
Renewable energy becomes a hot issue on the decrease of fossil energy reserves that can not be renewed. To answer the challenge of the availability of these energy a study was performed in a high-temperature cracking process from pine wood to obtain fuel oil or so-called pyrolysis. The purpose of this study was to determine the yield, physical properties, and the calorific value of the pyrolysis results. Pyrolysis process is done by varying the percentage of mordenite-type zeolite catalyst as much as  0% b/b, 2% b/b, and 4% b/b, with a mass of 100 grams of pine wood that passes sieving each sample to 50 mesh. Before use, the catalysts physically activated by heating at a temperature of 500°C and chemically activated using HCl to enhance the activity of the zeolite. Pyrolysis carried out at 400°C, 450°C, 500°C, and 550°C. After the analysis, bio-oil obtained optimum yield of 43.77142% by mass of the catalyst 4% b/b and a temperature of 500 °C. Physical properties obtained in the form of density 1.094723 g/ml, 2.96 cP viscosity, and 58°C flash point. While the highest calorific value on the condition of the catalyst 4% and the reaction temperature 550°C is 26045.50 kJ/kg.
随着无法更新的化石能源储量的减少,可再生能源成为一个热点问题。为了应对这些能源可用性的挑战,在松木的高温裂解过程中进行了一项研究,以获得燃料油或所谓的热解。本研究的目的是确定热解结果的产率、物理性质和热值。热解过程是通过改变丝光沸石型沸石催化剂的百分比来完成的,所述丝光沸石型催化剂的百分比高达0%b/b、2%b/b和4%b/b,质量为100克松木,通过将每个样品筛分至50目。使用前,催化剂通过在500°C的温度下加热进行物理活化,并使用HCl进行化学活化,以提高沸石的活性。在400°C、450°C、500°C和550°C下进行热解。经过分析,在500°C的温度下,生物油获得了催化剂4%b/b质量的43.77142%的最佳产率。以密度1.094723 g/ml、2.96 cP粘度和58°C闪点的形式获得的物理性能。在催化剂用量为4%、反应温度为550°C的条件下,最高热值为26045.50 kJ/kg。
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引用次数: 1
Pengaruh Variasi Konsentrasi NaNO3 pada Medium Raoof terhadap Kultivasi Spirulina Platensis Raoof培养基对螺旋藻NaNO3变异浓度的影响
Pub Date : 2022-04-05 DOI: 10.31315/e.v19i1.6581
Iqbal Syaichurrozi, Wardalia Wardalia, Sharfan Dwicahyanto, Yustinus Selis Toron
Nutrition is one of the factors that affect the growth of Spirulina platensis. The cultivation medium proposed by Raoof is a modified version of Zarrouk medium. Raoof medium requires less nutrients than Zarrouk medium but the biomass produced is almost the same. This study was conducted to vary the concentration of NaNO3 of 0.5; 1.5; 2.5; 3.5 g/L in Raoof medium to study its effect on growth and biomass composition of S. platensis. At each concentration of NaNO3 of 0.5; 1.5; 2.5; 3.5 g/L obtained the highest biomass concentration of 0.6425; 0.6455; 0.6745; 0,5193 g/L on days 12, 12, 12, 10. Concentration of NaNO3 of 2.5 g/L resulted in the highest specific growth rate of 0.1371/day and the lowest double time of 5.0566 days. In general, increasing the concentration of NaNO3 from 0.5 to 2.5 g/L increased the protein content from 33.30 to 36.98%. The addition of higher NaNO3 (3.5 g/L) actually decreased the protein content to 35.52%.
营养是影响螺旋藻生长的因素之一。拉奥夫提出的培养基是Zarrouk培养基的改良版。Raoof培养基比Zarrouk培养基需要更少的营养,但产生的生物量几乎相同。进行这项研究是为了改变0.5的NaNO3的浓度;1.5;2.5;在Raoof培养基中培养3.5g/L,研究其对S.platensis生长和生物量组成的影响。在NaNO3的每个浓度为0.5时;1.5;2.5;3.5g/L得到最高生物量浓度0.6425;0.6455;0.6745;第12、12、12和10天为05193 g/L。NaNO3浓度为2.5g/L时,比生长速率最高,为0.1371天,最低加倍时间为5.0566天。一般来说,将NaNO3的浓度从0.5 g/L增加到2.5 g/L,蛋白质含量从33.30%增加到36.98%。添加更高的NaNO3(3.5 g/L)实际上将蛋白质含量降低到35.52%。
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引用次数: 0
Production of biodiesel from waste cooking oil using heterogeneous catalyst 利用多相催化剂从废食用油中生产生物柴油
Pub Date : 2022-04-05 DOI: 10.31315/e.v0i0.6132
D. Jaya, Tunjung Wahyu Widayati, Hanum Salsabiela, Muhammad Fathan Abdul Majid
The world's oil reserves are running low, which makes the government also implement a mandatory B30 policy starting in early 2020. With this policy, it is necessary to develop energy by utilizing renewable energy such as vegetable oil that can be converted into biodiesel. Waste cooking oil is one of the vegetable oils that has the potential to be processed into biodiesel because the use of waste cooking oil in Indonesia is still not developed. In this study, we report the yield of biodiesel from waste cooking oil with variations in the ratio of the number of moles and weight of heterogeneous catalysts. Biodiesel is made by esterification and transesterification with a heterogeneous catalyst (CaO), then a separation process is carried out to separate the biodiesel produced from the by-product in the form of glycerol. The separated biodiesel is then analyzed for density, viscosity, flash point, and pour point. The results showed that the best biodiesel was at a mole ratio of 1:24 with 3% CaO catalyst. Based on the analysis data, this biodiesel has the largest yield of 72.49% with a viscosity value of 4.9806 cSt, a flash point value of 72.5 oC, a pour point value of 0 oC, and a density value of 0.8662 g/ml and calorific value. 8837,302 cal/gram. With the results of the analysis, that are in accordance with the quality standards of SNI 7182:2015.
世界石油储量正在减少,这使得政府也从2020年初开始实施强制性的B30政策。根据这一政策,有必要利用可再生能源开发能源,如可以转化为生物柴油的植物油。废弃食用油是一种有潜力加工成生物柴油的植物油,因为印尼对废弃食用油的使用尚未开发。在这项研究中,我们报道了废食用油中生物柴油的产量,以及多相催化剂的摩尔数和重量比的变化。生物柴油是用多相催化剂(CaO)通过酯化和酯交换制备的,然后进行分离过程,将副产物中产生的生物柴油以甘油的形式分离出来。然后分析分离出的生物柴油的密度、粘度、闪点和倾点。结果表明,在CaO用量为3%的条件下,生物柴油的最佳配比为1:24。根据分析数据,该生物柴油的最大产率为72.49%,粘度值为4.9806 cSt,闪点为72.5℃,倾点为0℃,密度值为0.8662 g/ml,热值为0.8662%。8837302卡/克。根据分析结果,认为符合SNI 7182:2015的质量标准。
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引用次数: 0
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