Synergy refers to the degree to which the same measure produces simultaneous reductions in CO₂ and pollutant emissions at the industrial parks. Assessing the synergy can inform key management policies and measures critical for advancing emission reduction efforts. However, the overall impact of industrial symbiosis on the synergy remains unclear due to the lack of a systematic quantitative method for embedding network topology into synergy measurement. Therefore, we proposed the Complex Network Analysis-Synergistic Assessment method (CNA-SA), which integrates the symbiotic relationships among enterprises within the industrial chain to assess the contribution of industrial symbiosis to synergy quantitatively. By combining CNA-SA with scenario analysis, this study also quantitatively compares the relative merits of different symbiosis modes that promote synergy. The results from typical industrial parks indicate that industrial symbiosis among enterprises can enhance synergy by at least 5.49 % to 102.63 %. Furthermore, the synergy of CO2 and pollutant reductions was more strongly influenced by the integrity of the industrial chain than its diversity. Extending the existing industrial chain will increase the synergy from 0.67 to at least 0.80, yielding greater improvements with less effort compared to establishing new industrial chains. These results support ecologically guided park design, help managers identify opportunities for emission reduction and development pathways, and provide technical support for achieving synergy of CO₂ and pollutant reductions.
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