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TRIGLYCINE SULPHATE DYNAMICS OF DOMAINS IN RELATION WITH TEMPERATURE AND BIAS FIELD 硫酸甘油三酯结构域的动力学与温度和偏置场的关系
Pub Date : 2021-01-01 DOI: 10.56082/annalsarsciphyschem.2021.1.29
H. Alexandru, Marinel Dan, C. Ganea
Triglycine sulphate crystal (TGS) is a hybrid organic-inorganic ferroelectric crystal with a large electronic band-gap, transparent in visible spectra. It has large applications in electronics, as thermal IR detector. Pure and doped TGS crystals of 3-5 cm linear dimensions were grown at constant temperature in the paraelectric phase (52 oC), by slow solvent evaporation. Pure TGS samples show non-reproducible values of permittivity and losses in the ferroelectric phase after the “excursion” in the paraelectric phase. Walking up and down the crystal temperature, using a special program, the permitivity and losses were automatically recorded and analyzed. There is a continuous decrease of permittivity towards an equilibrium value during a long period of time. Previous AFM measurements from the literature have revealed peculiar aspects of domain dynamics. The relaxation process of permittivity was considered according to the equation er = A - B exp(-t/t). However, surprisingly, there is not a unique relaxation time t. For the first 500 sec (or so), the relaxation time is t » 7 minutes, while between the next time decades 1.000 - 10.000 - 100.000 sec, it is approximately 1 hour and 8 h respectively. The process is related with the ferroelectric domain’s dynamics, which are more or less strongly pined by dislocations or some other lattice defects.
硫酸甘油三酯晶体(TGS)是一种有机-无机杂化铁电晶体,具有较大的电子带隙,可见光谱透明。它在电子领域有广泛的应用,如热红外探测器。通过缓慢的溶剂蒸发,在52℃的准电相中恒温生长出线性尺寸为3-5 cm的纯和掺杂TGS晶体。纯TGS样品在准电相“偏移”后,铁电相的介电常数和损耗值不可重现。在晶体温度上下行走时,使用专用程序自动记录和分析介电常数和损耗。在很长一段时间内,介电常数不断地向一个平衡值下降。以前的AFM测量从文献中揭示了域动力学的特殊方面。根据方程er = A - B exp(-t/t)考虑介电常数的弛豫过程。然而,令人惊讶的是,没有一个唯一的弛豫时间t。在前500秒(大约),弛豫时间为t»7分钟,而在接下来的几十年中,1.000 - 10.000 - 100.000秒,分别约为1小时和8小时。这一过程与铁电畴的动力学有关,而铁电畴的动力学或多或少受到位错或其他晶格缺陷的强烈影响。
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引用次数: 1
ADVANCED NANOMATERIALS AND COATED SURFACES FOR ORTHOPEDIC IMPLANTS – A REVIEW 用于骨科植入物的先进纳米材料和涂层表面综述
Pub Date : 2021-01-01 DOI: 10.56082/annalsarsciphyschem.2021.2.53
Reka Balint, A. Mocanu, G. Tomoaia, S. Riga, M. Tomoaia-Cotisel
Critical-sized defects in bone induced by trauma have in numerous presented cases difficult challenges to the current treatment for bone repair. The main purpose of bone tissue engineered scaffolds is to use advanced materials to promote the natural healing process of bone which does not easily occur in critical-sized defects or on metallic implants. A synthetic bone scaffold and a coating on Ti implants must be biocompatible and biodegradable to allow the native tissue integration, and mimic the chemical composition and structure of native bone. In addition to being physically and chemically biomimetic, an ideal scaffold and the coating layers on metallic implants must be capable of releasing essential physiologic elements, like Mg, Zn, Sr and Si, and also containing bioactive molecules (e.g., collagen, COL) to accelerate extracellular matrix production and tissue integration. Also, these advanced materials might be doped with drugs (e.g., antibiotics, such as vancomycin) to prevent undesired biological response such as infections, especially with Staphylococcus aureus, S. aureus. Various biomaterials include hydroxyapatite (HAP) ceramics or multifunctional hydroxyapatite substituted with Mg, Zn, Sr and Si, mf-HAP, polymers, such as poly lactic acid (PLA, approved for medical applications by Food and Drug Administration, US FDA, and collagen, or their mixtures as biomimetic composites which have been investigated for their potential as bone scaffold materials and coatings on metallic implants. This article briefly reviews the physical and chemical characteristics of used advanced materials and describes the key-technologies in mimicking the physical and chemical environment of bone using synthetic materials, and provides an over view of local drug delivery as it pertains to bone tissue engineering.
在许多病例中,创伤引起的骨缺损对目前的骨修复治疗提出了困难的挑战。骨组织工程支架的主要目的是使用先进的材料来促进骨的自然愈合过程,这在临界尺寸的缺陷或金属植入物上不易发生。合成骨支架和钛植入物的涂层必须具有生物相容性和可生物降解性,以允许天然组织整合,并模拟天然骨的化学成分和结构。除了在物理和化学上具有仿生性外,理想的支架和金属植入物的涂层必须能够释放必需的生理元素,如Mg、Zn、Sr和Si,并且还含有生物活性分子(如胶原蛋白、COL),以加速细胞外基质的产生和组织整合。此外,这些先进的材料可能掺杂药物(例如,抗生素,如万古霉素),以防止不希望的生物反应,如感染,特别是金黄色葡萄球菌,金黄色葡萄球菌。各种生物材料包括羟基磷灰石(HAP)陶瓷或多功能羟基磷灰石取代Mg, Zn, Sr和Si, mf-HAP,聚合物,如聚乳酸(PLA),经美国食品和药物管理局批准用于医疗应用,胶原蛋白,或其混合物作为仿生复合材料,已被研究其作为骨支架材料和金属植入物涂层的潜力。本文简要综述了目前常用的先进材料的物理化学特性,介绍了利用合成材料模拟骨的物理化学环境的关键技术,并对骨组织工程领域的局部给药进行了综述。
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引用次数: 2
NICOLAE IORGA HISTORY – A DUTY TO MANKIND 尼古拉·奥尔加的历史,是对人类的责任
Pub Date : 2021-01-01 DOI: 10.56082/annalsarscihist.2021.1.76
Jipa Rotaru
Nicolae Iorga's historical work, elaborated in the course of half a century, represents, by the vastness of his concerns, by the richness of the themes addressed, by the valuable results reached, a priceless scientific and cultural treasure given by the Romanian scholar to national and universal history.
尼古拉·约尔加(Nicolae Iorga)在半个世纪的时间里精心编写的历史著作,以其广泛的关注、丰富的主题和宝贵的成果,代表了这位罗马尼亚学者为国家和世界历史贡献的一笔无价的科学和文化财富。
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引用次数: 0
SELECTING A SURFACE PREPARATION TREATMENT ON A MEDIUM ENTROPY Ti-Zr-Ta-Ag ALLOY 中熵Ti-Zr-Ta-Ag合金表面处理方法的选择
Pub Date : 2021-01-01 DOI: 10.56082/annalsarsciphyschem.2021.2.23
Radu Nartita, D. Ionita, I. Demetrescu, M. Enăchescu
All metallic alloys undergo some surface pretreatment before coating deposition. This preparation step influences the surface roughness and can also change the surface chemical composition, therefore influencing the coating adhesion and the physicochemical characteristics of the coated alloy. Choosing an appropriate surface pretreatment can maximize the coated alloys performances. In this work, we aimed to comparatively analyze the surface of the Ti-Zr-Ta-Ag alloy before and after two different surface pretreatments. The surface composition and morphology were investigated using atomic force microscopy, scanning electron microscopy, and energy dispersive spectroscopy, while surface energy and mechanical properties were investigated using contact angle measurement and Vickers hardness test.
所有的金属合金在镀层沉积前都要经过一定的表面预处理。该制备步骤会影响表面粗糙度,也会改变表面化学成分,从而影响涂层附着力和涂层合金的物理化学特性。选择合适的表面预处理可以最大限度地提高涂层合金的性能。在这项工作中,我们旨在对比分析两种不同表面预处理前后的Ti-Zr-Ta-Ag合金的表面。采用原子力显微镜、扫描电镜和能量色散光谱研究了表面组成和形貌,采用接触角测量和维氏硬度测试研究了表面能和力学性能。
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引用次数: 2
The Black Sea in Romanian Oceanographic Research 罗马尼亚海洋学研究中的黑海
Pub Date : 2021-01-01 DOI: 10.56082/annalsarscihist.2021.2.73
A. Bologa
Romania, as a maritime state, after being separated from the Black Sea coast for 400 years, until the War of Independence in 1877, has a tradition in the marine sciences for over 100 years. The illustrious ancestors of Romanian oceanography, especially biological oceanography, are Emil Racoviță, Grigore Antipa and Ioan Borcea. From an oceanographic point of view, E. Racovitza distinguished himself as a biologist of the famous Antarctic multinational expedition, under the command of Captain Adrien de Gerlache, from Belgium, aboard the vessel Belgica, between 1997 and 1998. G. Antipa is the founder of the Bio-Oceanographic Institute in Constanța (1932) and of the Biological Research Station in Caliacra (currently in Bugaria) and in this context he held the positions of organizer, general administrator and director general of the State Fisheries, as the second national delegate of Romania at the International Commission for the Scientific Exploration of the Mediterranean Sea (CIESM), and as rapporteur for the Black Sea, Marmara and the Eastern Mediterranean, as well as organizer of the first Congress and General Assembly of CIESM in Romania in Bucharest in 1935. I. Borcea's main scientific achievement is the creation of the Marine Zoological Station in Agigea, in 1926, which bears his name to this day, with the maintenance of close collaborative relations in the field of marine biology, especially with France and Italy. The main marine research institutions, namely the Marine Zoological Station “Professor Ioan Borcea”, the Bio-Oceanographic Institute, which later became the Fisheries Research Station “Dr. Grigore Antipa”, the Marine Biology Sector from Constanța of the “Traian Săvulescu” Institute of Biology from Bucharest, the Oceanographic Research Station from Constanța and Sulina and the Marine Sedimentology Laboratory, affiliated to the Geological Institute of Romania, merged into the Romanian Marine Research Institute (RMRI) from Constanța on March 1, 1970. The succesor of RMRI since 1990 is the National Institute for Marine Research and Development “Grigore Antipa”, in the same headquarters (Bd. Mamaia No. 300, RO-900581 Constanța). A definite confirmation of the value of the results of the Romanian marine research, over time, is, among others, the close professional relationships with CIESM, continued to the present. Thus, Romania has further promoted and supports marine research at national, regional and international level.
罗马尼亚作为一个海洋国家,在与黑海沿岸分离了400年之后,直到1877年的独立战争,在海洋科学方面有100多年的传统。罗马尼亚海洋学,特别是生物海洋学的杰出祖先是Emil Racoviță, Grigore Antipa和Ioan Borcea。从海洋学的角度来看,E. Racovitza是著名的南极多国探险队的生物学家,在1997年至1998年期间,由来自比利时的Adrien de Gerlache船长指挥,乘坐“比利时号”(Belgica)。G. Antipa是Constanța生物海洋学研究所(1932年)和卡拉克拉生物研究站(现位于保加利亚)的创始人,在此背景下,他曾担任组织者、国家渔业总局局长和总干事,担任罗马尼亚在国际地中海科学探索委员会(CIESM)的第二任国家代表,并担任黑海、马尔马拉和东地中海报告员。也是1935年在罗马尼亚布加勒斯特举办的中欧经济和社会管理委员会第一届代表大会和大会的组织者。Borcea的主要科学成就是1926年在Agigea建立了海洋动物站,该站至今以他的名字命名,并在海洋生物学领域保持了密切的合作关系,特别是与法国和意大利。主要的海洋研究机构,即海洋动物学站“Ioan Borcea教授”、生物海洋学研究所(后来成为渔业研究站“Grigore Antipa博士”)、布加勒斯特“Traian surivulescu”生物研究所海洋生物学部门(Constanța)、海洋学研究站(Constanța和Sulina)以及隶属于罗马尼亚地质研究所的海洋沉积学实验室,1970年3月1日从Constanța并入罗马尼亚海洋研究所(RMRI)。自1990年以来,RMRI的继任者是国家海洋研究与发展研究所“Grigore Antipa”,位于同一总部(Bd. Mamaia No. 300, RO-900581 Constanța)。长期以来,罗马尼亚海洋研究成果的价值得到肯定的是,除其他外,与海洋科学研究委员会的密切专业关系一直持续到现在。因此,罗马尼亚在国家、区域和国际各级进一步促进和支持海洋研究。
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引用次数: 0
On the situation of the national economy during the Antonescu regime (september 1940 - august 1944) 安东内斯库政权时期的国民经济状况(1940年9月—1944年8月)
Pub Date : 2021-01-01 DOI: 10.56082/annalsarscihist.2021.2.66
Mihai D. Drecin
"The present paper provides a brief presentation of the evolution of Romania’s national economy in the period September 1940 - August 1944, as indicate the published bibliography and unpublished archive documents of the time. It addresses the national economy and the policy of “Romanianization”, aimed at transferring the industrial and commercial enterprises and assets owned by Jews, Greeks, Armenians and Italians or Romanian citizens belonging to the aforementioned ethnic groups, to state ownership. Command of these economic enterprises was given by the state to the so-called ""commissioners of Romanianization"". They had to organize the economy in order to meet the needs of the anti-Soviet front. In reality, the Romanian state wanted to protect the local capital, regardless of the ethnicity of the owner/owners, from the offensive of the German capital which sought to regain its privileged and dominant positions from 1914-1916. The economy of the Antonescu regime, rid of the legionary Romanianization commissioners, who sought only to enrich themselves in connivance with the Jewish owners, pursued a strict planning of the war economy, in order to obtain maximum quantities of products and good quality for the supply of the ”Eastern Front” and of the cities, and to counter the economic sabotage set up by the Communist Party of Romania, which was illegal and totally subordinated to the interests of the USSR."
“本文件简要介绍了1940年9月至1944年8月期间罗马尼亚国民经济的演变情况,其中包括当时已出版的参考书目和未出版的档案文件。它涉及国民经济和“罗马尼亚化”政策,其目的是将属于上述族裔群体的犹太人、希腊人、亚美尼亚人、意大利人或罗马尼亚公民所拥有的工商业企业和资产转为国家所有。国家把这些经济企业的指挥权交给所谓的“罗马尼亚化专员”。他们必须组织经济以满足反苏战线的需要。实际上,罗马尼亚政府想要保护当地的首都,不管所有者/所有者的种族,不受德国首都的进攻,德国首都试图从1914年到1916年恢复其特权和统治地位。安东内斯库政权的经济的军团士兵Romanianization专员,寻求只有丰富自己与犹太老板默许,追求战争的一个严格的计划经济,为了获得最大数量的产品和高质量的供应在“东部战线”的城市,和应对经济破坏共产党建立的罗马尼亚,这是非法的,完全服从于苏联的利益。”
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引用次数: 0
The Struggle of the Communist Regime with the Past and its Personalities: Two Studies Case: Ion I.C. Bratianu and Nicolae Iorga 共产主义政权与过去及其个性的斗争:两个研究案例:Ion I.C. Bratianu和Nicolae Iorga
Pub Date : 2021-01-01 DOI: 10.56082/annalsarscihist.2021.2.42
Ion Zainea
Găsirea unui drum propriu al puterii de la Bucureşti, începută în ultimii ani ai regimului Dej, presupunea racordarea la tradiţiile şi valorile naţionale româneşti, precum şi recuperarea "moştenirii culturale", cu precădere a celei interbelice. Reconsiderarea trecutului falsificat şi debarasarea de molozul grosier al epocii staliniste, a devenit sarcina principală a istoriografiei române după 1966. Totul însă trebuia să se desfăşoare într-un mod controlat, cu arma "criticii de clasă" şi numai în termenii acceptaţi de regim. Studiul nostru are la bază constatările instituţiei de cenzură, în sintezele realizate în anii 1969 şi 1972 asupra scrisului istoric în intervalul 1966-1972.
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引用次数: 0
MODELING OF DOSE RATES IN CASE OF A RADIOLOGICAL INCIDENT AT THE IFIN-HH INTERMEDIARY GRAPHITE STORAGE 在ifin-hh中间石墨储存库发生放射性事件时剂量率的建模
Pub Date : 2021-01-01 DOI: 10.56082/annalsarsciphyschem.2021.1.48
A. Pavelescu, M. Pavelescu
The low and intermediate level activity wastes resulted from decommissioning of the VVR-S nuclear research reactor belonging to the “Horia Hulubei” National Institute for R&D in Physics and Nuclear Engineering (IFIN-HH), are kept in an intermediary storage facility. The storage is located on the premises of the Institute near Bucharest, Romania and includes activated graphite from the reactor thermal column. In case of a very low probability hypothetical atmospheric radiological dispersal incident such as an unexpected fire, despite all the implemented safety measures, there is a certain radiological risk for the workers and general public due to potential ingestion or inhalation or contact with the radioactive aerosols released on a certain range from the storage building. For estimating the total gamma dose intake and adequate countermeasures for workers and public members, the JRODOS (Real-time On-line Decision Support) code system for off-site emergency management after nuclear accidents was used in the paper.
属于“霍里亚葫芦北”国家物理与核工程研发研究所(IFIN-HH)的VVR-S核研究堆退役后产生的低、中水平活动废物保存在中间储存设施中。该储存库位于罗马尼亚布加勒斯特附近的研究所馆舍内,储存库包括来自反应堆热柱的活性石墨。如果发生极低概率的假想大气辐射扩散事件,例如意外火灾,尽管实施了所有安全措施,但由于可能摄入或吸入或接触从储存建筑物释放的一定范围内的放射性气溶胶,对工作人员和公众存在一定的辐射风险。为了估计工作人员和公众的总γ剂量摄入和适当的对策,本文使用了核事故后场外应急管理的JRODOS(实时在线决策支持)代码系统。
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引用次数: 0
BEHAVIOR OF PLANTS AND MICROORGANISMS IN THE PRESENCE OF INORGANIC POLLUTANTS 植物和微生物在无机污染物存在下的行为
Pub Date : 2021-01-01 DOI: 10.56082/annalsarsciphyschem.2021.2.7
Mariana Minuț, Mihaela Roșca, P. Cozma, M. Diaconu, M. Gavrilescu
Rapid industrialization along with the use of modern practices in agriculture led to the discharge into the environment of various pollutants from which metals and metalloids are the most identified. The presence of metals in soil affects soil fertility, the growth and development of plants, and finally causing different negative effects on human health such respiratory problems, damage to endocrine and nervous systems and other dysfunction. Over time, various techniques have been used to remove pollutants from contaminated media, but most of these techniques are expensive, produce secondary contaminants and modify the structure and fertility of the soil. Thus, in recent years considerable attention has been accorded to biological methods. Plants and microorganisms may exhibit different behavior and degree of tolerance in the presence of metals.
快速的工业化以及现代农业实践的使用导致各种污染物排放到环境中,其中金属和类金属最为明显。土壤中金属的存在影响土壤肥力、植物生长发育,最终对人体健康造成各种负面影响,如呼吸系统问题、内分泌和神经系统损害以及其他功能障碍。随着时间的推移,人们使用了各种技术来从污染的介质中去除污染物,但这些技术大多数都很昂贵,会产生二次污染物,并改变土壤的结构和肥力。因此,近年来对生物方法给予了相当大的注意。植物和微生物在金属的存在下可能表现出不同的行为和程度的耐受性。
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引用次数: 0
NICOLAE IORGA AND THE SPECIAL RELATIONSHIP WITH THE 9TH HUNTERS REGIMENT DURING THE WAR FOR THE REUNIFICATION OF THE ROMANIAN NATION 在罗马尼亚国家统一战争期间,尼古拉·约尔加与第9猎人团的特殊关系
Pub Date : 2021-01-01 DOI: 10.56082/annalsarscihist.2021.1.66
Ion I. Solcanu
The special relationship between the great historian and patriot Nicolae Iorga and the 9th Hunters Regiment was founded on two elements, both of a subjective nature; 1. the high regard in which the historian duly held officer Gheorghe Rasoviceanu, battalion commander and subsequently commander of the 9th Hunters Regiment for five years, from October, 7th 1916 to October 7th 1921; 2. the presence of his son, Petre Iorga, and his sonin-law, officer Dimitrie Chirescu, future general (married to Florica Iorga) in the 9th Hunters Regiment. We find Second Lieutenant Petre N. Iorga in the Regiment, as Head of the Intelligence Office from June 16th 1917, taking part in the great battle of Mărășești, Muncelu and Poienile Popii (July-August 1917) and captain Dimitrie Chirescu from August 15th 1916 and the autumn of 1919. It was only natural then for the great historian to take such an interest in the Regiment and to nervously and eagerly follow its development throughout this period.
伟大的历史学家和爱国者尼古拉·约尔加与第9猎团之间的特殊关系建立在两个因素之上,这两个因素都是主观的;1. 从1916年10月7日到1921年10月7日,这位历史学家对营长、后来担任第9猎团团长的乔治·拉索维切亚努军官给予了高度的尊重;2. 他的儿子,彼得·约尔加,和他的女婿,军官迪米特里·奇雷斯库,未来的将军(娶了弗罗里卡·约尔加)在第9猎人团。从1917年6月16日起,我们发现该团的少尉彼得·n·约尔加(Petre N. Iorga)担任情报局局长,参加了Mărășești, Muncelu和Poienile Popii的伟大战役(1917年7月至8月),从1916年8月15日到1919年秋天,上尉迪米特里·奇雷斯库(Dimitrie Chirescu)。当时,这位伟大的历史学家对这个团产生了如此浓厚的兴趣,并紧张而急切地关注着它在整个时期的发展,这是很自然的。
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引用次数: 0
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Annals Series on History and Archaeology Academy of Romanian Scientists
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