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Study on heat transfer law of low temperature oxidation of coal under convection condition 对流条件下煤的低温氧化传热规律研究
IF 4.9 2区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-11-08 DOI: 10.1016/j.ijthermalsci.2024.109522
Junhong Si , Zihao Zhao , Yiqiao Wang , Huan Mao
Coal oxidation in the goaf generates heat accumulation influenced by airflow, leading to heat transfer within the porous coal structure. This study experimentally investigates the heat transfer characteristics of coal under convective conditions. A temperature migration rate measurement device was developed, and a formula for calculating the temperature migration rate was derived using the steady-state heat conduction differential equation and experimental data. The study examines the effects of temperature and airflow on the temperature migration rate and heat transfer characteristics. The experimental results indicate that the heat transfer effect of coal at low temperatures is minimal and volatile. As the temperature increases, efficiency improves, and heat transfer stabilizes. Airflow facilitates coal's heat transfer, causing the temperature generated by coal oxidation to concentrate on the downwind side. Additionally, airflow inhibits coal oxidation at low temperatures, while high temperatures promote it. Furthermore, the temperature migration rate of coal decreases with increasing temperature, initially decreases and then increases with rising airflow at low temperatures, whereas the opposite trend is observed at high temperatures.
煤炭在煤层中氧化产生的热量受气流影响而积聚,导致多孔煤炭结构内部的热量传递。本研究通过实验研究了对流条件下煤炭的传热特性。开发了温度迁移率测量装置,并利用稳态热传导微分方程和实验数据推导出了温度迁移率计算公式。研究探讨了温度和气流对温度迁移率和传热特性的影响。实验结果表明,煤在低温下的传热效果很小,且不稳定。随着温度的升高,效率提高,传热趋于稳定。气流有利于煤的传热,使煤氧化产生的温度集中在下风侧。此外,气流在低温时抑制煤的氧化,而在高温时则促进煤的氧化。此外,煤的温度迁移率随着温度的升高而降低,在低温时随着气流的上升先降低后升高,而在高温时则呈相反趋势。
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引用次数: 0
Revealing the flame inhibition effect of phytic acid (PA) by PIV measurements and detailed chemical kinetic modeling of counterflow CH4/PA/air flames 通过逆流 CH4/PA/空气火焰的 PIV 测量和详细化学动力学模型揭示植酸 (PA) 的火焰抑制效果
IF 4.9 2区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-10-30 DOI: 10.1016/j.ijthermalsci.2024.109505
Haoran Jiang, Yong Hu, Yong Jiang, Ke Yu, Rong Qiu
As industrialization continues to deepen, polymers have become ubiquitous in daily life. However, their flammable characteristics pose significant safety risks. Therefore, supporting the global goal of sustainable development necessitates the development of high-performance, environmentally friendly flame retardants. Biomass phytic acid (PA) has emerged as a promising option because of its high phosphorus content and excellent biocompatibility. However, its combustion behaviors and chemical kinetic mechanisms remain unclear. In this study, quantum chemical calculation methods were used to construct a detailed PA chemical reaction kinetic model. A series of experiments were conducted to validate the model and evaluate PA's flame suppression effect. Utilizing a counterflow flame burner and particle image velocimetry (PIV), the inhibitory effect of various PA concentrations was examined based on the laminar flame speed of CH4/PA/Air mixture. The results revealed that a merely 0.2 % addition of PA could reduce the laminar flame speed by 38.9 %, demonstrating its significant flame suppression effect. Building on the foundational GRI-Mech 3.0 and integrating PA's pyrolysis and reaction mechanism, this study developed for the first time a detailed chemical model of CH4/PA/Air combustion. This model integrated PA's thermal decomposition module and thermodynamic data via ab-initio quantum chemical calculations, thereby accurately predicting global kinetic indicators such as laminar flame speed. Results suggested that the key reactions, such as PO2+H + M→HOPO + M, HOPO2+H→PO2+H2O, and HOPO + OH→PO2+H2O primarily influenced the laminar flame speed. Moreover, the CFD simulation elucidated the complex interaction between PA and flame structures. A detailed analysis of the spatial distribution of key parameters such as temperature, combustion radicals, and effective inhibition radicals unveiled the PA's flame suppression mechanism in support of the practical application of this eco-friendly flame retardant.
随着工业化的不断深入,聚合物在日常生活中无处不在。然而,它们的易燃特性带来了极大的安全风险。因此,要支持全球可持续发展目标,就必须开发高性能的环保型阻燃剂。生物质植酸(PA)因其高磷含量和出色的生物相容性而成为一种前景广阔的选择。然而,其燃烧行为和化学动力学机制仍不清楚。本研究采用量子化学计算方法构建了详细的 PA 化学反应动力学模型。为了验证该模型并评估 PA 的火焰抑制效果,进行了一系列实验。利用逆流火焰燃烧器和粒子图像测速仪(PIV),根据 CH4/PA/Air 混合物的层流火焰速度考察了不同浓度 PA 的抑制效果。结果表明,仅添加 0.2% 的 PA 就能使层流火焰速度降低 38.9%,显示了其显著的火焰抑制效果。本研究以 GRI-Mech 3.0 为基础,结合 PA 的热分解和反应机理,首次建立了 CH4/PA/Air 燃烧的详细化学模型。该模型通过非原位量子化学计算,整合了 PA 的热分解模块和热力学数据,从而准确预测了层流火焰速度等全局动力学指标。结果表明,PO2+H+M→HOPO+M、HOPO2+H→PO2+H2O、HOPO+OH→PO2+H2O 等关键反应主要影响层焰速度。此外,CFD 模拟还阐明了 PA 与火焰结构之间复杂的相互作用。对温度、燃烧自由基和有效抑制自由基等关键参数空间分布的详细分析揭示了 PA 的火焰抑制机理,为这种环保型阻燃剂的实际应用提供了支持。
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引用次数: 0
Thermal characteristics of a double-tube heat exchanger with different twist directions of the inner oval tube 内椭圆管扭转方向不同的双管热交换器的热特性
IF 4.9 2区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-10-30 DOI: 10.1016/j.ijthermalsci.2024.109481
KeWei Song , Zhen Tian , Xiang Wu , Qiang Zhang , Kun Zhang , BingDong Gu
A new configuration featuring an inner oval tube with alternating twist directions is proposed to improve the thermal performance of double-tube heat exchangers. This design enhances the heat transfer efficiency by inducing longitudinal vortices within the annular space, thereby disrupting the boundary layer on the heat transfer surface, promoting fluid mixing, and significantly augmenting heat transfer. Numerical simulations were conducted to investigate the effects of alternating twist directions of the inner oval tube on thermal performance. The results demonstrate that alternating twist direction of the inner tube creates more pronounced vortices, significantly enhances heat transfer performance compared with the conventional tubes. This novel oval tube led to a substantial enhancement of up to 173.6 % in the Nu, with a corresponding increase of 96.4 % in the f. At Re = 2600, the highest thermal performance factor of the reported annular tube with an alternately twisted oval inner tube can reach up to 2.18, indicating a 118 % improvement in overall heat transfer performance. Fitted correlations for Nu and f are provided to facilitate engineering applications.
为了提高双管热交换器的热性能,我们提出了一种新的结构,其特点是内椭圆管具有交替的扭曲方向。这种设计通过在环形空间内诱发纵向涡流来提高传热效率,从而破坏传热表面的边界层,促进流体混合,显著增强传热效果。我们进行了数值模拟,以研究椭圆形内管交替扭曲方向对热性能的影响。结果表明,内管的交替扭曲方向会产生更明显的涡流,与传统管道相比,能显著提高传热性能。在 Re = 2600 条件下,报告的带有交替扭曲椭圆形内管的环形管的最高热性能系数可达 2.18,表明整体传热性能提高了 118%。为方便工程应用,提供了 Nu 和 f 的拟合相关性。
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引用次数: 0
Investigating radiation, toxic and hot gases fire hazards in large-scale storage tanks for oil derivatives with and without wind conditions 调查有风和无风条件下大型石油衍生物储罐的辐射、有毒和高温气体火灾危险性
IF 4.9 2区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-10-30 DOI: 10.1016/j.ijthermalsci.2024.109504
Ghassem Heidarinejad, Mohammadreza Eftekhari, Mohammad Safarzadeh, Mohammad Zabetian Targhi
The primary objective of this study is to examine various fire scenarios occurring within storage tanks containing three standard refinery-produced fuels: gasoline, kerosene, and crude oil. Additionally, the aim is to analyze the emissions of CO and CO₂ pollutants, the temperature of hot gases, and the radiation emissions resulting from the combustion of fuel tanks, considering real-scale tanks with diameters of 25, 50, and 75 m. This research introduces innovation by concurrently comparing the abovementioned hazards under varying environmental conditions, considering the presence or absence of wind as a critical factor influencing hazard propagation. In addition, the radiation effect is identified as the most significant hazard near the storage tanks. Furthermore, wind can intensify radiation levels in the direction of its movement, with a noticeable impact. Increasing wind speed from zero to 15 m/s results in a 1.5-fold increase in the safety distance. Without wind, CO and CO2, along with high gas temperatures, do not pose destructive threats. However, wind causes these hazards to extend closer to the Earth's surface. Under wind speeds of 15 m/s, these hazards reach a height of approximately 5 m above the ground. Notably, gasoline fuel is recognized as more perilous.
本研究的主要目的是检查在装有汽油、煤油和原油这三种标准炼油厂生产燃料的储油罐内发生的各种火灾情况。此外,本研究还旨在分析一氧化碳和一氧化碳污染物的排放、高温气体的温度以及燃料储罐燃烧产生的辐射排放,并考虑了直径分别为 25 米、50 米和 75 米的实际规模储罐。本研究通过同时比较不同环境条件下的上述危害,并将风的存在与否作为影响危害传播的关键因素进行了创新。此外,辐射效应被认为是储油罐附近最主要的危害。此外,风会增强其移动方向的辐射水平,并产生明显影响。风速从 0 米/秒增加到 15 米/秒,会导致安全距离增加 1.5 倍。在没有风的情况下,一氧化碳和二氧化碳以及气体高温不会造成破坏性威胁。然而,风会使这些危害更接近地球表面。在风速为 15 米/秒的情况下,这些危害会达到距地面约 5 米的高度。值得注意的是,汽油燃料被认为更具危险性。
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引用次数: 0
On the accuracy of Eulerian-Lagrangian CFD simulations for spray evaporation in turbulent flow 论欧拉-拉格朗日 CFD 模拟湍流中喷雾蒸发的精度
IF 4.9 2区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-10-30 DOI: 10.1016/j.ijthermalsci.2024.109461
Lili Xia , Hamid Montazeri , Bert Blocken
CFD simulation of droplet evaporation in turbulent flows is challenging as the accuracy and reliability of the results strongly depend on the available sub-models and their modeling parameters. This study presents a systematic sensitivity analysis focused on the impact of the most widely used discrete random walk (DRW) model, the constant time scale coefficient (CL), the turbulence model, and the drag coefficient model. CFD simulations with the Eulerian-Lagrangian approach are employed. The analysis is based on grid-sensitivity analysis and validation with measurements of spray evaporation in a heated turbulent airflow. The results show that using the DRW model leads to a good agreement between the CFD results and the experimental data of droplet size and droplet mean velocity, attributed to the turbulent fluctuations inducing droplet dispersion. The best performance is observed for the standard k-ε turbulence model with CL = 0.30 and 0.45. This is mainly attributed to the reasonable interaction time between droplets and turbulent eddies at these CL values. The three drag coefficient models (i.e., Spherical, Ischii-Zuber, and Grace) lead to similar results due to the low droplet Reynolds number.
湍流中液滴蒸发的 CFD 模拟极具挑战性,因为结果的准确性和可靠性在很大程度上取决于可用的子模型及其建模参数。本研究针对最广泛使用的离散随机漫步(DRW)模型、恒定时间尺度系数(CL)、湍流模型和阻力系数模型的影响进行了系统的敏感性分析。采用欧拉-拉格朗日方法进行 CFD 模拟。分析基于网格敏感性分析以及加热湍流气流中喷雾蒸发测量的验证。结果表明,使用 DRW 模型可使 CFD 结果与液滴大小和液滴平均速度的实验数据保持良好的一致性,这归因于湍流波动诱导了液滴的分散。CL = 0.30 和 0.45 的标准 k-ε 湍流模型的性能最佳。这主要是因为在这些 CL 值下,液滴与湍流涡旋之间的相互作用时间比较合理。由于液滴雷诺数较低,三种阻力系数模型(即球形模型、Ischii-Zuber 模型和 Grace 模型)的结果相似。
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引用次数: 0
Comparative performance analysis of microchannel heat sink with different geometric structures 不同几何结构微通道散热器的性能对比分析
IF 4.9 2区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-10-29 DOI: 10.1016/j.ijthermalsci.2024.109495
Zhixuan Liang , Haiping Wen , Qiming Lv , Wen Su , Changhong Wang
This paper analyses the characteristics of temperature, velocity and pressure loss of various channel configurations with identical Reynolds Number Re. A comparative analysis is conducted to assess substrate temperature and convection heat dissipation area. Furthermore, the optimal composite microchannel heat sink design is identified leveraging entropy generation theory and a comprehensive performance evaluation. Simulation results reveal that the pressure loss of microchannel with rectangular cross-sectional cavities (MC-RCSC) is the lowest whereas microchannel with ribs and secondary channels (MC-RSOC) experiences the highest. The flow rate of MC-RSOC is uniform and better mixed with the aid of the backflow phenomenon. In terms of average outlet temperature, in descending order, the microchannels are ranked as follows: MC-RCSC > microchannel with rectangular grooves and side wall ribs (MC-RGSW) > microchannel with rectangular grooves and alternating ribs (MC-RGA) > microchannel with rectangular grooves (MC-RG) > MC-RSOC. Regarding the performance factor, Pf, of MC-RSOC, MC-RCSC and MC-RG are all greater than 1, while the Pf of MC-RGA and MC-RGSW are less than 1 at low Re. The Pf of MC-RSOC is the highest. Flow rate is found to have a marginal impact on the temperature drop. Sgen,ΔP is an order of magnitude smaller than Sgen,ΔT, Sgen of MC-RSOC is the smallest. The comprehensive comparison of entropy generation and performance shows that MC-RSOC is the best composite structure.
本文分析了雷诺数 Re 相同的各种通道配置的温度、速度和压力损失特性。通过对比分析,评估了基底温度和对流散热面积。此外,利用熵生成理论和综合性能评估,确定了最佳复合微通道散热器设计。仿真结果表明,带矩形截面空腔的微通道(MC-RCSC)的压力损失最小,而带肋骨和次级通道的微通道(MC-RSOC)的压力损失最大。借助回流现象,MC-RSOC 的流速均匀,混合效果更好。就平均出口温度而言,微通道的降序排列如下:MC-RCSC;带矩形槽和侧壁肋条的微通道(MC-RGSW);带矩形槽和交替肋条的微通道(MC-RGA);带矩形槽的微通道(MC-RG);MC-RSOC。在低 Re 条件下,MC-RSOC、MC-RCSC 和 MC-RG 的性能系数 Pf 均大于 1,而 MC-RGA 和 MC-RGSW 的 Pf 均小于 1。MC-RSOC 的 Pf 最高。流量对温降的影响微乎其微。Sgen,ΔP 比 Sgen,ΔT 小一个数量级,MC-RSOC 的 Sgen 最小。熵产生和性能的综合比较表明,MC-RSOC 是最佳的复合结构。
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引用次数: 0
Design of the pre-controlled thermal-electric ultra-conductive metamaterials without extra energy payloads 设计无需额外能量载荷的预控热电超导超材料
IF 4.9 2区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-10-28 DOI: 10.1016/j.ijthermalsci.2024.109494
Huolei Feng , Wenyi Ma , Yushan Ni
The passive thermal-electric ultra-conductive metamaterials (PTUM) consisting of bulk natural materials are reported, which possess the local pre-controlled thermal-electric ultra-conductivities without extra energy payloads. Based on the local resistances regulated by the vertical transport channels, the thermal-electric effective parameters at the circular channel-interphase region are derived. Then, we present a method to make the designed channel suitable for both tempetature and electric potential fields simultaneously and analyze some manipulation factors modulating the thermal-electric ultra-conductivities. Based on the modulation effects, the PTUM with different pre-controlled parameters could be constructed by changing the height of the channels, which are demonstrated by the numerical simulations. Additionally, in order to validate the reliability of the construction theories, the normalized theoretical temperatures and electric potentials are provided to make a fair contrast with the normalized corresponding simulated values. The good coincidence between the simulated values and theoretical solutions indicates that we can realize the local thermal-electric ultra-conductivities by introducing the channels with different heights. Furthermore, we present some applications of pre-controlled PTUM to reveal the passive thermal-electric ultra-conductive effects and the utilization directions, such as the thermal-electric ultra-conductive metal plate and the ultra-conductive thermal-electric concentrator and cloak. This paper may provide a method to achieve the passive ultra-conductive metamaterials suitable for both temperature and electric potential fields simultaneously using the natural materials in general application environments.
本文报道了由块状天然材料组成的无源热电超导超材料(PTUM),这种超材料具有局部预控热电超导性,无需额外的能量载荷。根据垂直传输通道调节的局部电阻,我们推导出了圆形通道相间区域的热电有效参数。然后,我们提出了一种使所设计的通道同时适用于温度场和电势场的方法,并分析了一些调节热电超导的操作因素。基于调制效应,我们可以通过改变通道的高度来构建具有不同预控参数的 PTUM,并通过数值模拟进行了验证。此外,为了验证构建理论的可靠性,还提供了归一化的理论温度和电动势,以便与归一化的相应模拟值进行公平对比。模拟值与理论解之间的良好吻合表明,我们可以通过引入不同高度的通道来实现局部热电超导。此外,我们还介绍了预控 PTUM 的一些应用,以揭示被动热电超导效应和利用方向,如热电超导金属板、超导热电聚光器和斗篷等。本文可为在一般应用环境中利用天然材料同时实现适合温度场和电势场的被动超导超材料提供一种方法。
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引用次数: 0
Numerical investigations of heat transfer and pressure drop in packed bed duct exposed to forced convection boundaries under local thermal non-equilibrium conditions 局部热非均衡条件下暴露于强制对流边界的填料床风道中传热和压降的数值研究
IF 4.9 2区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-10-28 DOI: 10.1016/j.ijthermalsci.2024.109475
Suhas Jagtap, Manish Mishra
The present study is a 2-D numerical study which discusses the thermohydraulic performance of packed bed duct under local thermal non-equilibrium and steady state conditions exposed to forced convection boundaries (BC-6). The numerical model is well validated with the experimental work reported in the literature and found to be accurate enough to perform further parametric investigations. The analysis is done to see the effect of different ball diameter (5 mm, 9 mm and 11 mm), bed porosity, heat transfer fluid (air, water and engine oil - Pr = 0.70–645) and ball material (EPS, steel and bronze) on heat transfer and fluid flow characteristics in turbulent flow region of Reynolds number ranging from 900 to 14,320. The numerical results obtained using commercial CFD software COMSOL shows that, the heat transfer coefficient and pressure drop in packed bed increases with increase in ball diameter, thermal conductivity of ball and bed porosity which is exactly reverse as reported in literature for BC-1 to BC-5. The maximum thermal performance factor with bronze particles is 2.45 and 24.5 times more than stainless steel and EPS particles respectively for larger particle size and bed porosity. Engine oil exhibits significantly higher heat transfer coefficient (9.7 × 105 W/m2K) and pressure drop (3.3 × 106 Pa) compared to water (40,126 W/m2K and 2028 Pa) and air (600 W/m2K and 250 Pa) respectively. Overall, the combination of water as heat transfer fluid along with bronze particles of larger diameter and larger bed porosity emerges as the optimal choice for enhancing heat transfer in the packed duct exposed to forced convection boundary condition BC-6.
本研究是一项二维数值研究,讨论了受强制对流边界(BC-6)影响的填料床风道在局部热非平衡态和稳态条件下的热流体力学性能。数值模型与文献中报道的实验工作进行了很好的验证,发现其精确度足以进行进一步的参数研究。在雷诺数为 900 到 14320 的紊流区域,分析了不同的球直径(5 毫米、9 毫米和 11 毫米)、床层孔隙率、导热液体(空气、水和机油 - Pr = 0.70-645)和球材料(EPS、钢和青铜)对传热和流体流动特性的影响。使用商用 CFD 软件 COMSOL 得出的数值结果表明,填料床中的传热系数和压降随球直径、球导热系数和床层孔隙率的增加而增加,这与文献中 BC-1 至 BC-5 的报道正好相反。在颗粒尺寸和床层孔隙率较大的情况下,青铜颗粒的最大热性能系数分别是不锈钢和 EPS 颗粒的 2.45 倍和 24.5 倍。与水(40126 W/m2K 和 2028 Pa)和空气(600 W/m2K 和 250 Pa)相比,发动机油的传热系数(9.7 × 105 W/m2K)和压降(3.3 × 106 Pa)明显更高。总之,在强制对流边界条件 BC-6 下,水作为导热流体与直径较大、床层孔隙率较大的青铜颗粒相结合,是增强填料管道传热的最佳选择。
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引用次数: 0
Performance of photovoltaic panels with different inclinations under uniform thermal loading 均匀热负荷下不同倾斜度的光伏电池板的性能
IF 4.9 2区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-10-24 DOI: 10.1016/j.ijthermalsci.2024.109489
Yu Wang , Chengming Xiao , Chiara Bedon
Integrating photovoltaic (PV) panels with different tilt angles in building envelopes or roofs is widely employed for environmental sustainability. However, little is known about the influence of different tilt angles on the thermal failure of the photovoltaic façades or roofs in fire conditions. A total of 15 four-edge shielded PV panels (300 × 300 × 4.7 mm3), with five different inclinations of 0°, 15°, 30°, 45° and 60°, were heated to fail using a uniform radiant panel. Measurements were taken to track glass thermal breakage, surface temperatures, incident heat flux and failure characteristics. The glass fracture and pyrolysis of the internal thermoplastic materials were observed under thermal radiation. The average breakage time of glass in PV panels showed an increasing trend with increasing inclination of the PV panels. Moreover, when the PV panels were tilted beyond 30°, the time to failure increased more significantly. The maximum temperature difference and heat flux that the PV panels can withstand were primarily measured within the range of 61–84 °C and 8–15 kW/m2, respectively. Finally, the test results were simulated by a finite element method (FEM) model, calculating the heat transfer and thermal stress of PV panels: the average errors concerning temperature distributions and failure times were smaller than 15 % compared with the experimental results.
为了实现环境的可持续发展,在建筑围护结构或屋顶中广泛采用不同倾斜角度的光伏(PV)板。然而,人们对不同倾斜角度在火灾条件下对光伏外墙或屋顶热失效的影响知之甚少。共使用 15 块四边屏蔽光伏板(300 × 300 × 4.7 mm3),有 0°、15°、30°、45° 和 60°五种不同的倾斜角度,使用均匀辐射板加热至失效。对玻璃热破裂、表面温度、入射热通量和失效特征进行了跟踪测量。在热辐射条件下,观察了玻璃破裂和内部热塑性材料热解的情况。光伏板玻璃的平均破裂时间随着光伏板倾斜度的增加而呈上升趋势。此外,当光伏板倾斜度超过 30° 时,玻璃破裂时间的增加更为显著。光伏板可承受的最大温差和热通量主要是在 61-84 °C 和 8-15 kW/m2 范围内测得的。最后,用有限元法(FEM)模型模拟了测试结果,计算了光伏板的传热和热应力:与实验结果相比,温度分布和失效时间的平均误差小于 15%。
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引用次数: 0
Understanding photo-thermal and melting mechanisms in optical charging of nano and micro particles laden organic PCMs 了解纳米和微粒有机 PCM 光充电过程中的光热和熔化机制
IF 4.9 2区 工程技术 Q1 ENGINEERING, MECHANICAL Pub Date : 2024-10-23 DOI: 10.1016/j.ijthermalsci.2024.109493
Domala Sai Suhas, Vikrant Khullar
Engineering efficient optical charging process necessitates efficient photo-thermal energy conversion, transfer, as well as storage of the incident solar radiant energy. The present work is a determining step in deciphering, quantifying, and understanding the aforementioned steps involved in the optical charging of PCMs. Herein, the effect of particle size, concentration and thermochromism have been critically investigated. In particular, detailed optical characterization and photo-thermal experimentation pertinent to non-thermochromic nanoparticles laden PCM (referred to as NP-PCM) and thermochromic micro capsules laden PCM (referred to as TMCP-PCM) has been undertaken. Detailed optical analysis points out that opposed to NP-PCM, TMCP-PCM significantly scatter the incident radiations – the diffuse transmittance (at room temperature) in the two cases being approximately 2 % and 39 % respectively. Furthermore, whereas, optical properties of non-thermochromic nanoparticles are nearly invariant to temperature changes; in the case of thermochromic microcapsules, the magnitude of scattering further increases and diffuse transmittance reaches as high as 51 % at elevated temperatures. Although, thermochromism helps in enhancing the penetration depth at elevated temperatures, but, due to significant fraction of scattering, the photo-thermal energy conversion is not that effective. In terms of temperature field, spatial-temporal temperature distribution curves reveal that temperature spread (in the liquid phase) in case of optical charging of non-thermochromic particles (carbon soot nanoparticles) laden PCMs is significantly high (as high as approximately 24 °C) relative to that observed in case of thermochromic particles (microcapsules) laden PCMs (approximately, 4 °C). The magnitude of the temperature spread (being representative of the deviation from thermostatic optical charging) clearly points out that opposed to non-thermochromic laden PCMs, nearly thermostatic optical charging can be achieved in case of thermochromic particles laden PCMs.
Furthermore, in case of optical charging without thermochromic assistance, the temperature spread, peak temperatures and the melting rates increase with increase in particles concentration. Whereas, in the latter case, although the temperature spread and peak temperatures are nearly independent; the melting rates do depend on the particles’ concentration. Overall, the present work is a significant step towards accelerated-thermostatic thermal energy storage.
要实现高效的光学充电过程,就必须对入射的太阳辐射能量进行高效的光热能量转换、传输和存储。本研究是破译、量化和理解 PCM 光学充电过程中上述步骤的决定性一步。在此,我们对颗粒大小、浓度和热致变色的影响进行了严格研究。特别是对非热致变色纳米颗粒负载 PCM(简称 NP-PCM)和热致变色微胶囊负载 PCM(简称 TMCP-PCM)进行了详细的光学表征和光热实验。详细的光学分析表明,与 NP-PCM 相反,TMCP-PCM 会明显散射入射辐射--两种情况下的漫射透过率(室温下)分别约为 2 % 和 39 %。此外,非热致变色纳米粒子的光学特性几乎不受温度变化的影响;而在热致变色微胶囊中,散射的幅度进一步增大,在高温下的漫射透过率高达 51%。虽然热致变色有助于提高高温下的穿透深度,但由于散射量很大,光热能量转换的效果并不理想。就温度场而言,空间-时间温度分布曲线显示,与载热致变色粒子(微胶囊)的情况(约 4 °C)相比,非热致变色粒子(碳烟纳米粒子)载 PCM 光充电情况下(液相)的温度分布明显较高(高达约 24 °C)。温度差的大小(代表偏离恒温光学充电的程度)清楚地表明,与不含热致变色粒子的 PCM 相比,含热致变色粒子的 PCM 几乎可以实现恒温光学充电。而在后一种情况下,虽然温度分布和峰值温度几乎无关,但熔化率确实取决于颗粒浓度。总之,本研究是向加速恒温热能储存迈出的重要一步。
{"title":"Understanding photo-thermal and melting mechanisms in optical charging of nano and micro particles laden organic PCMs","authors":"Domala Sai Suhas,&nbsp;Vikrant Khullar","doi":"10.1016/j.ijthermalsci.2024.109493","DOIUrl":"10.1016/j.ijthermalsci.2024.109493","url":null,"abstract":"<div><div>Engineering efficient optical charging process necessitates efficient photo-thermal energy conversion, transfer, as well as storage of the incident solar radiant energy. The present work is a determining step in deciphering, quantifying, and understanding the aforementioned steps involved in the optical charging of PCMs. Herein, the effect of particle size, concentration and thermochromism have been critically investigated. In particular, detailed optical characterization and photo-thermal experimentation pertinent to non-thermochromic nanoparticles laden PCM (referred to as NP-PCM) and thermochromic micro capsules laden PCM (referred to as TMCP-PCM) has been undertaken. Detailed optical analysis points out that opposed to NP-PCM, TMCP-PCM significantly scatter the incident radiations – the diffuse transmittance (at room temperature) in the two cases being approximately 2 % and 39 % respectively. Furthermore, whereas, optical properties of non-thermochromic nanoparticles are nearly invariant to temperature changes; in the case of thermochromic microcapsules, the magnitude of scattering further increases and diffuse transmittance reaches as high as 51 % at elevated temperatures. Although, thermochromism helps in enhancing the penetration depth at elevated temperatures, but, due to significant fraction of scattering, the photo-thermal energy conversion is not that effective. In terms of temperature field, spatial-temporal temperature distribution curves reveal that temperature spread (in the liquid phase) in case of optical charging of non-thermochromic particles (carbon soot nanoparticles) laden PCMs is significantly high (as high as approximately 24 °C) relative to that observed in case of thermochromic particles (microcapsules) laden PCMs (approximately, 4 °C). The magnitude of the temperature spread (being representative of the deviation from thermostatic optical charging) clearly points out that opposed to non-thermochromic laden PCMs, nearly thermostatic optical charging can be achieved in case of thermochromic particles laden PCMs.</div><div>Furthermore, in case of optical charging without thermochromic assistance, the temperature spread, peak temperatures and the melting rates increase with increase in particles concentration. Whereas, in the latter case, although the temperature spread and peak temperatures are nearly independent; the melting rates do depend on the particles’ concentration. Overall, the present work is a significant step towards accelerated-thermostatic thermal energy storage.</div></div>","PeriodicalId":341,"journal":{"name":"International Journal of Thermal Sciences","volume":"208 ","pages":"Article 109493"},"PeriodicalIF":4.9,"publicationDate":"2024-10-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142539316","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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International Journal of Thermal Sciences
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