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Interfacial oxygen nanobubble for mitigating the methane emissions from aquatic ecosystems: A review 界面氧纳米泡减少水生生态系统甲烷排放的研究进展
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-08-06 DOI: 10.1016/j.resenv.2025.100256
Qingnan Chu , Xiangyu Liu , Detian Li , Shuai Yin , Ping He , Wenjuan Li , Chengrong Chen , Zhimin Sha
Methane (CH4) emissions from aquatic ecosystems, including wetlands, freshwater bodies, and rice paddies, contribute significantly to global warming due to CH4’s high global warming potential. Traditional CH4 mitigation strategies, such as mechanical aeration, sediment capping, and vegetation management, face challenges related to high costs, inefficiency in oxygen delivery, and ecological disturbances. In recent years, interfacial oxygen nanobubbles (IONBs) have emerged as a promising geoengineering solution for reducing CH4 emissions by providing sustained oxygenation in anoxic sediments. Unlike conventional methods, IONBs exhibit high stability, prolonged oxygen retention, and slow, controlled oxygen release, reducing the need for frequent re-application. This sustained oxygenation creates long-lasting aerobic microenvironments that suppress methanogenesis while stimulating methanotrophic CH4 oxidation. Furthermore, IONB-loaded carriers, such as biochars and zeolites, enable targeted oxygenation, improving redox conditions and promoting beneficial microbial shifts. Compared to mechanical aeration, which rapidly dissipates oxygen, or chemical amendments requiring repeated treatments, IONBs provide a low-maintenance, cost-effective alternative with minimal ecological disruption. This review explores the physicochemical properties of IONBs, their mechanisms of action in altering sedimentary biogeochemical processes, and their potential applications in mitigating CH4 flux from different aquatic ecosystems. Despite their potential, challenges remain in optimizing oxygen-loading capacity, assessing long-term ecological impacts, and scaling up production. Future research should focus on refining the oxygen-loading capacity of IONBs, integrating them with existing mitigation approaches, and evaluating their role in global climate policies. As an innovative and sustainable tool, IONBs hold great promise for advancing wetland conservation, reducing agricultural CH4 emissions, and climate change mitigation efforts.
湿地、淡水水体和稻田等水生生态系统的甲烷(CH4)排放具有较高的全球变暖潜势,对全球变暖有重要贡献。传统的CH4缓解策略,如机械曝气、沉积物封顶和植被管理,面临着与成本高、氧气输送效率低和生态干扰相关的挑战。近年来,界面氧纳米气泡(IONBs)已成为一种有前途的地球工程解决方案,通过在缺氧沉积物中提供持续的氧化来减少CH4的排放。与传统方法不同,ionb具有高稳定性、长时间的氧保留和缓慢、可控的氧释放,减少了频繁重新应用的需要。这种持续的氧化创造了持久的有氧微环境,抑制甲烷生成,同时刺激甲烷营养化CH4氧化。此外,离子b负载载体,如生物炭和沸石,可以实现靶向氧化,改善氧化还原条件,促进有益微生物的转移。与快速耗散氧气的机械曝气或需要重复处理的化学修正相比,ionb提供了一种维护成本低、成本效益高的替代方案,对生态的破坏最小。本文综述了ionb的物理化学性质、改变沉积生物地球化学过程的作用机制及其在减少不同水生生态系统CH4通量方面的潜在应用。尽管具有潜力,但在优化氧负荷能力、评估长期生态影响和扩大生产方面仍存在挑战。未来的研究应侧重于改进ionb的载氧能力,将其与现有的减缓方法相结合,并评估其在全球气候政策中的作用。作为一种创新和可持续的工具,ionb在促进湿地保护、减少农业甲烷排放和减缓气候变化方面前景广阔。
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引用次数: 0
Spatio-temporal evolution of sloping farmland and identification of its erosion risk management and control zones in the Three Gorges Reservoir Area, China 三峡库区坡耕地时空演变及侵蚀风险管控区划
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-08-06 DOI: 10.1016/j.resenv.2025.100255
Lidong Pan, Yun Chen, Dongmei Shi, Jiayong Gao, Yufu Jiang, Fangyuan Liu
Sloping farmland in the Three Gorges Reservoir Area (TGRA) is crucial for national food and ecological security. In this study, methods such as terrain gradient classification, kernel density estimation, and erosion risk identification model were used to analyze the spatio-temporal evolution and influencing factors of sloping farmland in the TGRA during 1990–2020, and its erosion risk control areas were identified. The sloping farmland in the TGRA exhibited spatial distribution characteristics of more in the central and western regions, less in the eastern region, with a high degree of fragmentation. It was concentrated in areas with slopes of 8–25° and altitudes of 200–1000 m, accounting for approximately 63% and 80% of sloping farmland, respectively. In the last 30 years, the distribution of sloping farmland with slopes >15° and altitudes >1000 m has gradually decreased and shifted to areas of 8–15° and 400–800 m, respectively. The sloping farmland has decreased by 343.93 km2, mainly converted into forest land, grassland, paddy field, and construction land. Slope and altitude were the main natural factors affecting the spatio-temporal evolution of sloping farmland, while the urbanization rate and disposable income of rural residents were the key human influence factors. Sloping farmland above the high-risk level of erosion was mainly distributed in counties such as Wuxi, Kaizhou, Wushan, Fengjie, Yunyang, and Wanzhou, concentrated in the terrain gradient area with slopes of 10–35° and altitudes of 200–1000 m, with the most distribution at 15–25° and 200–400 m. For these high erosion risk areas, prioritized regulation should be carried out for sloping farmland. These findings can optimize the use of sloping farmland resources, strengthening the prevention and control of erosion risks, and promoting the sustainable agricultural development.
三峡库区坡耕地是关系到国家粮食安全与生态安全的重要区域。采用地形梯度分类、核密度估算、侵蚀风险识别模型等方法,对1990-2020年青藏高原坡耕地时空演变特征及影响因素进行了分析,并对其侵蚀风险控制区进行了划分。TGRA坡耕地呈现中西部多、东部少、破碎化程度高的空间分布特征。主要分布在坡度为8 ~ 25°、海拔为200 ~ 1000 m的地区,分别约占坡耕地面积的63%和80%。近30年来,坡度为15°和海拔为1000 m的坡耕地分布逐渐减少,分别向8-15°和400-800 m地区转移。坡耕地减少343.93 km2,主要转化为林地、草地、水田和建设用地。坡度和海拔是影响坡耕地时空演变的主要自然因素,城市化率和农村居民可支配收入是影响坡耕地时空演变的主要人为因素。侵蚀高风险等级以上坡耕地主要分布在无锡、开州、巫山、奉节、云阳、万州等县,集中在坡度10 ~ 35°、海拔200 ~ 1000 m的地形梯度区,15 ~ 25°、200 ~ 400 m分布最多。对于这些高侵蚀风险地区,应优先对坡耕地进行治理。研究结果对优化坡耕地资源利用,加强水土流失风险防控,促进农业可持续发展具有重要意义。
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引用次数: 0
Revealing long-term dynamics and spatiotemporal drivers of anthropogenic nutrients inputs in China: The effects of dietary and socioeconomic factors 揭示中国人为营养素投入的长期动态和时空驱动因素:饮食和社会经济因素的影响
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-08-06 DOI: 10.1016/j.resenv.2025.100259
Jia Liu, Wei Gao, Fen Guo, Yuan Zhang, Yanpeng Cai
Anthropogenic nutrient inputs in developing countries have substantially shaped global nutrient balance pattern for the past decades, responsible for the expanding eutrophication and pollutions. The massive alteration of socioeconomic factors and dietary habit make it difficult to identify their specific impacts on nutrient balance. This study utilized the net anthropogenic nitrogen (NANI) and phosphorus (NAPI) inputs models to calculate human induced nitrogen (N) and phosphorus (P) inputs in China from 1949 to 2022, and applied the XGBoost–SHAP algorithm to estimate the driving forces of socio–economic and dietary structure on them. Our findings revealed that both nutrient inputs peaked around 2014–2015 before declining and fertilizer application was the primary contributor (56% for N, 63% for P) from 1949 to 2022. Great variation of NANI and NAPI evolution patten was found in different regions. Eastern and southern provinces (e.g., Henan, Shanghai) had the highest inputs, while western regions (e.g., Tibet) had the lowest, correlating with economic and population density disparities. Spatial clustering highlighted the need for region–specific nutrient management strategies. Dietary shifts showed increased animal–based food consumption (6.89–fold rise) and urban–rural disparities, with developed regions exceeding recommended intake levels. Driving factors for NANI and NAPI differed by regions of different development stage. Urbanization and GDP were dominant drivers in developed areas (Type I), while population was key in less–developed regions (Type II). These findings underscore the importance of tailored policies to address nutrient pollution and dietary impacts, and provide new insights for formulating nutrient mitigation strategies.
过去几十年来,发展中国家的人为营养投入在很大程度上影响了全球营养平衡格局,造成了富营养化和污染的扩大。社会经济因素和饮食习惯的巨大变化使得很难确定它们对营养平衡的具体影响。利用净人为氮(NANI)和净磷(NAPI)投入模型,计算1949 - 2022年中国人为氮(N)和磷(P)投入,并应用XGBoost-SHAP算法估算社会经济结构和饮食结构对二者的驱动力。研究结果表明,在1949年至2022年期间,两种养分投入均在2014-2015年达到峰值,然后下降,化肥施用是主要贡献者(氮占56%,磷占63%)。不同区域NANI和NAPI的演化模式存在较大差异。东部和南部省份(如河南、上海)的投入最高,而西部地区(如空间聚类)则突出了对区域特定营养管理战略的需求。饮食变化表明,动物性食品消费增加(增长6.89倍),城乡差距加大,发达地区的摄入量超过了建议水平。不同地区不同发展阶段的NAPI和NANI的驱动因素存在差异。在发达地区(第一类),城市化和GDP是主要驱动因素,而在欠发达地区(第二类),人口是主要驱动因素。这些发现强调了解决营养污染和饮食影响的量身定制政策的重要性,并为制定营养缓解战略提供了新的见解。
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引用次数: 0
Determinants of secondhand consumer choices on C2C online marketplace: Product-specific analysis in Japan C2C在线市场中二手消费者选择的决定因素:日本特定产品分析
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-08-06 DOI: 10.1016/j.resenv.2025.100250
Dami Moon , Kiyo Kurisu , Kiyotaka Tahara
This study hypothesizes that the relative importance of factors influencing the acceptance of secondhand products varies by product type. This premise was explored through a Japanese consumer survey analyzing factors influencing both adoption and rejection as well as key acceptance criteria across thirty diverse product types. The results revealed nuanced attitudes toward secondhand items. Hygiene and cleanliness were paramount for items with direct skin contact, while privacy concerns dominated for tablets. Notably, childhood-related items were often kept for sentimental value rather than being reused. Bulky furniture and small electronics were frequently stored or discarded due to the perceived inconvenience of reuse procedures. The study identified two consumer acceptance factors in online C2C markets: (1) the product condition and functional assurance and (2) product information and market appeal. Consumer decisions prioritized different factors depending on product type: hygiene-sensitive items required consideration of both factors, everyday wear showed less sensitivity to either, electronics emphasized product information and appeal, and life-stage products prioritized condition and functionality. These diverse preferences highlight the importance of product-specific strategies, which can foster consumer trust and facilitate robust secondhand transactions. Ultimately, by building trust, streamlining transactions, and acknowledging diverse product needs, businesses and policymakers can promote reuse and drive widespread adoption of secondhand products towards a sustainable consumption system.
本研究假设影响二手产品接受度的因素的相对重要性因产品类型而异。这一前提是通过一项日本消费者调查来探讨的,该调查分析了影响采用和拒绝的因素,以及30种不同产品类型的关键接受标准。调查结果揭示了人们对二手物品的微妙态度。对于直接接触皮肤的物品来说,卫生和清洁是最重要的,而对于平板电脑来说,隐私问题则是最重要的。值得注意的是,与童年有关的物品往往是出于情感价值而不是重复使用。由于认为再使用程序不方便,笨重的家具和小型电子设备经常被储存或丢弃。本研究确定了在线C2C市场的两个消费者接受因素:(1)产品状况和功能保证;(2)产品信息和市场吸引力。根据产品类型,消费者会优先考虑不同的因素:对卫生敏感的产品需要考虑这两个因素,日常穿着对其中任何一个都不太敏感,电子产品强调产品信息和吸引力,而生命阶段的产品优先考虑条件和功能。这些不同的偏好突出了特定产品策略的重要性,这可以培养消费者的信任,促进强劲的二手交易。最终,通过建立信任、简化交易和承认不同的产品需求,企业和政策制定者可以促进二手产品的再利用,并推动二手产品的广泛采用,形成可持续的消费体系。
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引用次数: 0
Divert or donate? Early experiences with California’s attempt to reduce organic waste and food insecurity 转移还是捐赠?加州尝试减少有机废物和食品不安全的早期经验
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-08-06 DOI: 10.1016/j.resenv.2025.100252
Yulia Lamoureaux , Charles J. Corbett , Scott Rodilitz , Edward S. Spang
Food waste poses significant environmental and societal challenges, with an estimated 30% of global food production lost or wasted along the supply chain, threatening both environmental sustainability and food security. The United Nations’ Sustainable Development Goal 12.3 aims to halve global food waste by 2030, linking waste reduction to hunger alleviation. California sought to address both priorities simultaneously through Senate Bill (SB) 1383, a novel organic waste law. This article contributes to the literature on food loss and waste (FLW) mitigation by examining tensions between SB 1383’s dual goals: diverting organic waste from landfills and redistributing surplus food to communities in need. While SB 1383 is a progressive policy, its implementation has revealed conflicts between these objectives. We assess the impact of SB 1383 on stakeholder compliance with its food waste reduction and recovery requirements. Specifically, we examine the two key objectives of this regulation: (1) mitigating climate change by diverting organic waste from landfills, and (2) addressing food insecurity by redistributing recovered food to communities in need. We interviewed 37 stakeholders, including food recovery organizations, jurisdiction representatives, and edible food generators involved in implementation. Additionally, we analyzed the distribution of Local Assistance Grant funds across California counties and between the policy’s dual goals. Our findings indicate a stronger focus on waste diversion than food recovery, and an uneven distribution of funding, with rural areas facing greater challenges in adapting to SB 1383’s requirements. We conclude by highlighting tensions in FLW policy design that seeks to advance multiple, sometimes competing, goals.
食物浪费构成了重大的环境和社会挑战,据估计,全球30%的粮食产量在供应链上损失或浪费,对环境可持续性和粮食安全构成威胁。联合国可持续发展目标12.3旨在到2030年将全球食物浪费减半,将减少浪费与缓解饥饿联系起来。加州试图通过参议院1383号法案(一项新的有机废物法)同时解决这两个优先事项。本文通过研究sb1383的双重目标之间的紧张关系,为减轻粮食损失和浪费(FLW)的文献做出贡献:从垃圾填埋场转移有机废物,并将剩余粮食重新分配给有需要的社区。虽然sb1383是一项进步的政策,但它的实施暴露了这些目标之间的冲突。我们评估SB 1383对利益相关者遵守其减少食物浪费和回收要求的影响。具体来说,我们研究了该法规的两个关键目标:(1)通过从垃圾填埋场转移有机废物来缓解气候变化;(2)通过将回收的食物重新分配给有需要的社区来解决粮食不安全问题。我们采访了37个利益相关者,包括参与实施的食品回收组织、司法管辖区代表和食用食品生产商。此外,我们还分析了加州各县的地方援助补助金的分配情况,以及该政策的双重目标之间的分配情况。我们的研究结果表明,废物转移比食物回收更受重视,而且资金分配不均,农村地区在适应SB 1383的要求方面面临更大的挑战。最后,我们强调了FLW政策设计中的紧张关系,这种紧张关系寻求推进多个(有时是相互竞争的)目标。
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引用次数: 0
Nitrogen recovery from digestate via stripping–scrubbing using citric acid: Potential effects of recirculation and postdigestion on additional biogas recovery, and assessment of the fertilizer potential of end-products 利用柠檬酸通过剥脱洗涤从消化物中回收氮:再循环和消化后对额外沼气回收的潜在影响,以及最终产品肥料潜力的评估
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-08-06 DOI: 10.1016/j.resenv.2025.100258
Thaís Guedes Silveira , Rahim Molaey , Çağrı Akyol , Nick Sweygers , Nimisha Edayilam , Sofie Houtmeyers , Erik Meers , Lise Appels
This study investigated nitrogen (N) recovery from digestate via the N-stripping–scrubbing process and the effects of digestate recirculation and postdigestion on biogas yield during digestate posttreatment. Citric acid was tested as an alternative scrubbing agent to conventional sulfuric acid, forming ammonium citrate (AC) instead of ammonium sulfate (AS). In a cascade approach, the N release dynamics of the resulting by-products and end-products (scrubbing waters (AC, AS) and manure digestate-derived products) in amended soils were assessed via soil incubation tests to obtain a reliable estimation of the N value of these potential biobased fertilizers in comparison to that of commercial synthetic fertilizer (calcium ammonium nitrate (CAN)). The recirculation of the digestate resulted in a limited effect on additional biogas yield; however, up to a 47.2% increase in biogas yield was achieved during postdigestion at a stripping temperature of 70 °C, where 86% of the ammonia was removed from the digestate at pH 9.5. The use of citric acid as a scrubbing agent resulted in 80.6% ammonia recovery, which was slightly lower than when sulfuric acid was used (87.5%). Soil incubation tests showed N-net release values in the following order: AS (91%) > CAN (85%) > the liquid fraction (LF) of raw digestate (RD) (73%) > AC (70%) > RD (64%) > LF of N-stripped digestate (SD) (23%) > SD (12%). These results indicate the high N-fertilizing potential of AS, RD and its LF, and AC, highlighting the benefit of using citric acid as a novel and more sustainable scrubbing agent.
本研究探讨了溶氮-洗涤工艺对沼液中氮的回收,以及沼液后处理过程中沼液循环和消化后对沼气产量的影响。用柠檬酸代替常规硫酸,制备柠檬酸铵(AC)代替硫酸铵(as)。在级联方法中,通过土壤培养试验评估了改良土壤中产生的副产品和最终产物(洗涤水(AC, AS)和粪便消化产物衍生产品)的N释放动态,以获得这些潜在生物基肥料与商业合成肥料(硝酸铵钙(CAN))的N值的可靠估计。消化液的再循环对额外的沼气产量影响有限;然而,在溶出温度为70°C的消化后,沼气产量增加了47.2%,其中86%的氨在pH为9.5的消化池中被去除。使用柠檬酸作为洗涤剂,氨回收率为80.6%,略低于使用硫酸的87.5%。土壤培养试验结果显示,氮净释放值依次为:AS (91%) > CAN (85%) >;生消化液液体部分(LF) (RD) (73%) > AC (70%) > RD (64%) >;脱氮消化液LF (SD) (23%) >; SD(12%)。这些结果表明,AS、RD及其LF和AC具有较高的施氮潜力,突出了使用柠檬酸作为一种新型且更可持续的洗涤剂的好处。
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引用次数: 0
A sustainable strategy for upcycling spent NCM into Li1.2Ni0.13Co0.13Mn0.54O2 cathode material for advanced lithium-ion batteries 废NCM升级为先进锂离子电池正极材料Li1.2Ni0.13Co0.13Mn0.54O2的可持续策略
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-08-06 DOI: 10.1016/j.resenv.2025.100257
Jing Sun, Wenxin Chen, Shuo Lu, Zhanlong Song, Wenlong Wang, Xiqiang Zhao, Yanpeng Mao
The recycling paradigm for spent lithium-ion batteries is undergoing fundamental transformation, as traditional recycling approaches that prioritize the extraction of valuable metals increasingly confront process complexity and marginal economic viability. Herein, we propose a sustainable upcycling strategy that directly converts spent LiNixCoyMn1xyO2 (SNCM) into high-performance lithium-rich manganese-based cathode material (i.e., Li1.2Ni0.13Co0.13Mn0.54O2, LNCM) through an innovative integrated approach. Crucially, microwave-assisted acetic acid leaching facilitates the effective and eco-friendly conversion of SNCM into soluble Ni/Co/Mn acetate, which can be then directly co-precipitated with oxalic acid to produce an oxalate precursor, simultaneously generating acetic acid that can be reused in the microwave-assisted leaching process, enabling a closed-loop for the leaching reagent. The pH of the leach solution emerges as a critical parameter, significantly influencing the co-precipitation process as well as the structural and morphological properties of the precursor. Through systematic optimization of precursor via pH adjustment and a two-stage calcination with a 5% excess of Li2CO3, the regenerated LNCM-7.5 (pH = 7.5) exhibits a well-ordered layered structure (c/a = 5.0016) with minimal cation mixing (I003/I104 = 1.46), uniform particle morphology, enhanced Li+ diffusion and thereby exceptional cycling stability-delivering 165.7 mAh g1 at 1 C after 100 cycles with 89.01% capacity retention, performance parity with virgin materials synthesized from commercial acetates. This work not only demonstrates the feasibility of upcycling SNCM into high-performance LNCM cathodes, but also establishes a sustainable and economically viable solution for advancing circular economy practices in the energy storage industry, mitigating resource scarcity and pollution.
废旧锂离子电池的回收模式正在发生根本性的转变,因为传统的回收方法优先考虑提取有价值的金属,越来越多地面临工艺复杂性和边际经济可行性的问题。在此,我们提出了一种可持续的升级回收策略,通过创新的集成方法直接将废LiNixCoyMn1−x−yO2 (SNCM)转化为高性能富锂锰基正极材料(即Li1.2Ni0.13Co0.13Mn0.54O2, LNCM)。重要的是,微波辅助乙酸浸出有助于SNCM有效且环保地转化为可溶的Ni/Co/Mn醋酸盐,然后可以直接与草酸共沉淀生成草酸前体,同时生成可在微波辅助浸出过程中重复使用的乙酸,从而实现浸出试剂的闭环。浸出液的pH值是一个关键参数,它对共沉淀过程以及前驱体的结构和形态特性有重要影响。通过调整pH值对前驱体进行系统优化,并在过量5% Li2CO3的条件下进行两段煅烧,再生的LNCM-7.5 (pH = 7.5)呈现出有序的层状结构(c/a = 5.0016),阳离子混合最少(I003/I104 = 1.46),颗粒形态均匀,Li+扩散增强,因此具有优异的循环稳定性——在1℃下循环100次后,容量保持率为89.01%,可输送165.7 mAh g - 1。性能与商业醋酸酯合成的原始材料相当。这项工作不仅证明了将SNCM升级为高性能LNCM阴极的可行性,而且还为推进储能行业的循环经济实践,缓解资源短缺和污染建立了可持续和经济可行的解决方案。
{"title":"A sustainable strategy for upcycling spent NCM into Li1.2Ni0.13Co0.13Mn0.54O2 cathode material for advanced lithium-ion batteries","authors":"Jing Sun,&nbsp;Wenxin Chen,&nbsp;Shuo Lu,&nbsp;Zhanlong Song,&nbsp;Wenlong Wang,&nbsp;Xiqiang Zhao,&nbsp;Yanpeng Mao","doi":"10.1016/j.resenv.2025.100257","DOIUrl":"10.1016/j.resenv.2025.100257","url":null,"abstract":"<div><div>The recycling paradigm for spent lithium-ion batteries is undergoing fundamental transformation, as traditional recycling approaches that prioritize the extraction of valuable metals increasingly confront process complexity and marginal economic viability. Herein, we propose a sustainable upcycling strategy that directly converts spent LiNi<span><math><msub><mrow></mrow><mrow><mi>x</mi></mrow></msub></math></span>Co<span><math><msub><mrow></mrow><mrow><mi>y</mi></mrow></msub></math></span>Mn<span><math><msub><mrow></mrow><mrow><mn>1</mn><mo>−</mo><mi>x</mi><mo>−</mo><mi>y</mi></mrow></msub></math></span>O<sub>2</sub> (SNCM) into high-performance lithium-rich manganese-based cathode material (i.e., Li<span><math><msub><mrow></mrow><mrow><mn>1</mn><mo>.</mo><mn>2</mn></mrow></msub></math></span>Ni<span><math><msub><mrow></mrow><mrow><mn>0</mn><mo>.</mo><mn>13</mn></mrow></msub></math></span>Co<span><math><msub><mrow></mrow><mrow><mn>0</mn><mo>.</mo><mn>13</mn></mrow></msub></math></span>Mn<span><math><msub><mrow></mrow><mrow><mn>0</mn><mo>.</mo><mn>54</mn></mrow></msub></math></span>O<sub>2</sub>, LNCM) through an innovative integrated approach. Crucially, microwave-assisted acetic acid leaching facilitates the effective and eco-friendly conversion of SNCM into soluble Ni/Co/Mn acetate, which can be then directly co-precipitated with oxalic acid to produce an oxalate precursor, simultaneously generating acetic acid that can be reused in the microwave-assisted leaching process, enabling a closed-loop for the leaching reagent. The pH of the leach solution emerges as a critical parameter, significantly influencing the co-precipitation process as well as the structural and morphological properties of the precursor. Through systematic optimization of precursor via pH adjustment and a two-stage calcination with a 5% excess of Li<sub>2</sub>CO<sub>3</sub>, the regenerated LNCM-7.5 (pH <span><math><mo>=</mo></math></span> 7.5) exhibits a well-ordered layered structure (<em>c</em>/<em>a</em> <span><math><mo>=</mo></math></span> 5.0016) with minimal cation mixing (I<sub>003</sub>/I<sub>104</sub>\u0000 <span><math><mo>=</mo></math></span> 1.46), uniform particle morphology, enhanced Li<span><math><msup><mrow></mrow><mrow><mo>+</mo></mrow></msup></math></span> diffusion and thereby exceptional cycling stability-delivering 165.7 mAh g<span><math><msup><mrow></mrow><mrow><mo>−</mo><mn>1</mn></mrow></msup></math></span> at 1 C after 100 cycles with 89.01% capacity retention, performance parity with virgin materials synthesized from commercial acetates. This work not only demonstrates the feasibility of upcycling SNCM into high-performance LNCM cathodes, but also establishes a sustainable and economically viable solution for advancing circular economy practices in the energy storage industry, mitigating resource scarcity and pollution.</div></div>","PeriodicalId":34479,"journal":{"name":"Resources Environment and Sustainability","volume":"22 ","pages":"Article 100257"},"PeriodicalIF":7.8,"publicationDate":"2025-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144885520","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Urban agriculture supports China’s vegetable supply without raising greenhouse gas emissions 都市农业在不增加温室气体排放的情况下支持了中国的蔬菜供应
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-08-06 DOI: 10.1016/j.resenv.2025.100254
Yuanchao Hu , Prajal Pradhan , Haoran Zhang , Zhen Wang , Qianyuan Huang , Qiqi Jia , Xihong Lian , Chao Xu , Rui Yang , Yuxi Tian , Zhibang Xu , Limin Jiao , Jürgen P. Kropp
Measuring the production potential and environmental sustainability of urban agriculture in developing countries highlights the value of promoting it. We constructed a new dataset of urban productive spaces for 124 large Chinese cities, which includes indoor balconies, rooftops, urban open spaces, and courtyards. In particular, if moderately exploited, approximately 18% of the 13 million rooftops could be planted, considering factors such as building height, age, rooftop slope, occupation, and other restrictions. Applying both greenhouse and open-air cultivation techniques in all the spaces, about 30% (7%–198% across cities) of urban vegetable demand could be met. However, urban agriculture has little potential in greenhouse gas emission mitigation, with the average intensity (0.30 kgCO2e/kg) being similar to traditional agriculture (0.31 kgCO2e/kg), even if several system-wide benefits, such as reduced food miles, were considered. Despite the multiple benefits, conducting urban agriculture requires massive water, substrate, metal, and plastic inputs. We demonstrate that high-tech urban agriculture can have a lower GHG intensity, but it is essential to consider agroclimatic conditions and promote more sustainable practices.
衡量发展中国家城市农业的生产潜力和环境可持续性,凸显了促进城市农业的价值。我们为中国124个大城市构建了一个新的城市生产空间数据集,包括室内阳台、屋顶、城市开放空间和庭院。特别是,如果适度开发,考虑到建筑物高度、年龄、屋顶坡度、占用和其他限制等因素,1300万个屋顶中约有18%可以种植。在所有空间采用温室和露天栽培技术,可满足约30%(城市范围为7%-198%)的城市蔬菜需求。然而,城市农业在减缓温室气体排放方面几乎没有潜力,其平均强度(0.30千克二氧化碳当量/千克)与传统农业(0.31千克二氧化碳当量/千克)相似,即使考虑到减少食物里程等若干全系统效益。尽管有多种好处,但开展城市农业需要大量的水、基质、金属和塑料投入。我们证明高科技都市农业可以降低温室气体强度,但必须考虑农业气候条件并促进更可持续的做法。
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引用次数: 0
Livestock rearing as a key component of mitigation efforts for non-CO2 greenhouse gas emissions in global crop-livestock system 牲畜饲养是减缓全球作物-牲畜系统非二氧化碳温室气体排放努力的关键组成部分
IF 12.4 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-07-10 DOI: 10.1016/j.resenv.2025.100248
Li Zheng , Qingwen Zhang , Ji Chen , Baojing Gu , Xiaoying Zhan , Bowei Yu , Yulong Shi , Hafiz Athar Hussain , Xuekai Jing
Non-carbon dioxide greenhouse gas (non-CO2 GHG) emissions from global crop-livestock systems, primarily driven by enteric fermentation and manure-related emissions, pose significant challenges to climate mitigation. Identifying emission hotspots and simulating future mitigation potential are crucial for achieving agricultural carbon neutrality. Constructed a comprehensive dataset spanning 138 countries (1961–2020), integrating FAO statistics, literature-derived emission factors, and socioeconomic data, this study quantified spatiotemporal emission trends and identified decoupling patterns between emissions and economic development. The Logarithmic Mean Divisia Index (LMDI) was used to decompose drivers and six scenarios (BAU (Baseline), RSA (Rearing Structure Adjustment), LMO (Livestock Management Optimization), BMPs-30% and BMPs-50% (best management practices with a manure substitution ratio of 30% or 50%), and NMA (No Manure Application)) were developed to assess mitigation potential. Results revealed that global non-CO2 GHG emissions from crop-livestock systems increased by 61.9% from 2696.5 to 4365.0 Mt CO2-eq. yr−1 from 1961 to 2020, with India, Brazil, China, and the United States accounting for about 40% of total emissions in 2020. Significant decoupling occurred in developed countries, such as the United States, around in 1985 at approximately $10,000 per-capita GDP. In developing countries like China, significant decoupling was evident around in 1990 at approximately $3000 per-capita GDP. Ambitious scenarios (BMPs-50%) could reduce global emissions by 3.2–6.7 Gt CO2-eq. yr−1 by 2060, with major contributions from India (671.3 Mt CO2-eq. yr−1), Brazil (494.2 Mt CO2-eq. yr−1), China (486.1 Mt CO2-eq. yr−1), and the USA (238.8 Mt CO2-eq. yr−1). The findings confirmed the decoupling of non-CO2GHG emissions within crop-livestock systems from economic growth in developed countries but highlight persistent challenges in developing regions. Strategic shifts toward monogastric livestock, manure recycling, and dietary transitions emerge as critical pathways for aligning food security with carbon neutrality goals.
全球作物-牲畜系统的非二氧化碳温室气体(非co2 GHG)排放主要由肠道发酵和粪便相关排放驱动,对减缓气候变化构成重大挑战。确定排放热点和模拟未来的缓解潜力对于实现农业碳中和至关重要。本研究构建了涵盖138个国家(1961-2020年)的综合数据集,整合了粮农组织统计数据、文献导出的排放因子和社会经济数据,量化了排放的时空趋势,并确定了排放与经济发展之间的脱钩模式。采用对数平均划分指数(LMDI)对驱动因素进行分解,并制定了6个情景(BAU(基线)、RSA(饲养结构调整)、LMO(牲畜管理优化)、bmp -30%和bmp -50%(粪肥替代率为30%或50%的最佳管理实践)和NMA(不施用粪肥))来评估缓解潜力。结果显示,全球作物-牲畜系统的非二氧化碳温室气体排放量从2696.5亿吨二氧化碳当量增加到4365.0亿吨二氧化碳当量,增加了61.9%。到2020年,印度、巴西、中国和美国约占总排放量的40%。显著的脱钩发生在发达国家,比如美国,1985年左右人均GDP约为1万美元。在像中国这样的发展中国家,显著的脱钩在1990年左右的人均GDP约为3000美元时是明显的。雄心勃勃的方案(bmp -50%)可以使全球排放量减少3.2-6.7亿吨二氧化碳当量。到2060年,印度将做出主要贡献(6.713亿吨二氧化碳当量)。年−1),巴西(4.942亿吨二氧化碳当量)。年−1),中国(4.861亿吨二氧化碳当量)。年−1),美国(2.388亿吨二氧化碳当量)。年−1)。研究结果证实了发达国家作物-牲畜系统内的非二氧化碳温室气体排放与经济增长的脱钩,但强调了发展中地区持续存在的挑战。向单胃制牲畜、粪便循环利用和饮食转变的战略转变成为使粮食安全与碳中和目标保持一致的关键途径。
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引用次数: 0
Rotation reshapes sustainable potato production in dryland by reducing environmental footprints synergistically enhancing soil health 轮作通过减少环境足迹,协同增强土壤健康,重塑旱地马铃薯的可持续生产
IF 12.4 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-07-10 DOI: 10.1016/j.resenv.2025.100247
Hanyou Xie , Weiyan Wang , Ping He , Wencheng Ding , Xinpeng Xu , Xuelian Tan , Xiaowei Liu
Sustainable agricultural production encounters significant challenges in balancing economic returns with environmental sustainability, particularly in the ecologically fragile dryland regions of Northwest China. This study employed life cycle assessment (LCA) and comprehensive evaluation index (CEI) to identify the optimal cropping system among potato continuous cropping (PC), wheat/green manure-potato (WgP), pea/green manure-potato (PgP), and wheat/green manure-pea/green manure-potato (WgPgP) in the study region. Furthermore, the non-dominated sorting genetic algorithm II (NSGA-II) was used to optimize regional cropping structure. The results indicated that crop rotations improved the soil health index by 13.1%–63.4%, increased the potato yield by 15.0%–38.2%, enhanced net economic benefits (NEB) by 30.6%–41.9%, and boosted net ecological economic benefits (NEEB) by 36.3%–47.6% compared to PC. Additionally, crop rotations reduced water consumption by 11.2%–26.1% and greenhouse gas (GHG) emissions by 33.6%–59.3%, while improving the potato nutrient use efficiency by 12.8%–38.4%. The CEI rankings indicated that PgP (41.5%) was the highest, followed by WgPgP (33.2%), WgP (17.3%), and PC (9.7%). Expanding the PgP rotation in Northwest China could significantly reduce nutrient and water inputs, decrease GHG and reactive nitrogen (Nr) emissions, and enhance productivity and profitability. This study provides a practical pathway for sustainable food production in dryland agricultural regions by emphasizing the pivotal role of crop rotation in improving soil health and mitigating GHG and Nr emissions.
可持续农业生产在平衡经济效益和环境可持续性方面面临重大挑战,特别是在生态脆弱的西北旱地地区。采用生命周期评价(LCA)和综合评价指数(CEI)对研究区马铃薯连作(PC)、小麦/绿肥-马铃薯(WgP)、豌豆/绿肥-马铃薯(PgP)和小麦/绿肥-豌豆/绿肥-马铃薯(WgPgP)的最优种植制度进行了优选。采用非支配排序遗传算法II (NSGA-II)对区域种植结构进行优化。结果表明,轮作使土壤健康指数提高了13.1% ~ 63.4%,马铃薯产量提高了15.0% ~ 38.2%,净经济效益提高了30.6% ~ 41.9%,净生态经济效益提高了36.3% ~ 47.6%。此外,作物轮作减少了11.2% ~ 26.1%的水分消耗和33.6% ~ 59.3%的温室气体排放,提高了12.8% ~ 38.4%的养分利用效率。CEI排名显示,PgP最高(41.5%),其次是WgPgP(33.2%)、WgP(17.3%)和PC(9.7%)。在西北地区扩大PgP轮作可以显著减少养分和水分投入,减少温室气体和活性氮(Nr)排放,提高生产力和盈利能力。本研究通过强调轮作在改善土壤健康、减少温室气体和Nr排放中的关键作用,为旱地农业区的可持续粮食生产提供了切实可行的途径。
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引用次数: 0
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