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Direct and indirect mechanisms through which low-carbon technology imports enhance green total factor productivity 低碳技术进口提高绿色全要素生产率的直接和间接机制
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-03-01 Epub Date: 2026-03-04 DOI: 10.1016/j.resenv.2026.100318
Peiyu Wang , Xiyan Mao , Xianjin Huang , Christina Prell
Under the global consensus on mitigating climate change and managing environmental risks, low-carbon technology (LCT) imports have emerged as a new driver of green economic growth. Although the economic and environmental benefits of LCT trade are widely recognized, the mechanisms through which imports enhance green total factor productivity (GTFP) remain insufficiently understood. This study develops a theoretical framework to explain how LCT imports promote green growth through trade spillovers and structural optimization. Using panel data covering 101 countries and 124 LCT products from 2001 to 2022, this study employs mediation and moderation models to examine the transmission mechanisms and key influencing factors. The results show that LCT imports enhance GTFP mainly through knowledge diffusion rather than technology spillovers. LCT imports facilitate energy structure optimization, which drives GTFP improvement, but they do not fundamentally change the industrial structure. Moreover, maintaining stable trade linkages with technologically advanced partners amplifies this positive effect. These findings uncover the mechanisms by which LCT trade fosters green productivity and provide scientific insights to inform LCT trade policies.
在减缓气候变化和管理环境风险的全球共识下,低碳技术(LCT)进口已成为绿色经济增长的新动力。尽管LCT贸易的经济和环境效益已得到广泛认可,但进口提高绿色全要素生产率(GTFP)的机制仍未得到充分了解。本研究建立了一个理论框架来解释LCT进口如何通过贸易溢出和结构优化促进绿色增长。本研究利用2001 - 2022年101个国家124种LCT产品的面板数据,运用中介和调节模型,考察了其传导机制和关键影响因素。结果表明,低成本商品进口对GTFP的提升主要是通过知识扩散而非技术溢出。LCT进口有利于能源结构优化,从而带动GTFP提升,但并未从根本上改变产业结构。此外,与技术先进的伙伴保持稳定的贸易联系会扩大这种积极影响。这些发现揭示了LCT贸易促进绿色生产力的机制,并为LCT贸易政策提供了科学见解。
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引用次数: 0
Assessing the carbon reduction potential of municipal solid waste incineration at the county level in China 中国县级城市生活垃圾焚烧减碳潜力评价
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-03-01 Epub Date: 2026-02-10 DOI: 10.1016/j.resenv.2026.100310
Fangyi Li , Qi Zhang , Wu Xie , Zhen Shao , Jingjing Li
Municipal solid waste (MSW) incineration plants play a crucial role both in waste-to-energy sector and “Zero-waste Cities” construction in China. As the number and capacity of waste incineration plants (WIPs) are increasing rapidly, their expansion process and carbon reduction effect in history and future deserve in-depth research. This study examines the historical and future expansion of WIPs and their carbon reduction potential at the county level. We employ a machine learning framework combining two models: a Bayesian neural network (BNN) model to predict the probability of new WIP allocation and an explainable machine learning model to identify key factors driving county-level carbon emissions from waste disposal. It finds that the growth of WIPs from 202 to 902 during 2015-2022 has significantly reduced carbon emissions from 129.0 Mt CO2-eq to 91.1 Mt CO2-eq. Based on the BNN model, there will be 1,408 WIPs serving 2,492 county-level administrative units in 2035. The RF model with feature analysis demonstrates that landfill ratio, incineration ratio, population, and geographic location primarily influence the carbon emissions of waste disposal at the county level. Scenario analysis shows the temporal and spatial distribution of carbon reduction potential: the north and central regions have the largest carbon reduction potential in the country due to the rapid growth of WIPs, while a shift in spatial priority for carbon reduction is identified from municipal districts to counties. The findings provide targeted insights to address regional imbalances and guide infrastructure planning towards sustainable waste management and the low-carbon transition.
城市生活垃圾焚烧厂在垃圾发电和中国“零垃圾城市”建设中发挥着至关重要的作用。随着垃圾焚烧厂数量和容量的快速增长,其历史和未来的扩张过程和减碳效果值得深入研究。本研究考察了县域范围内wip的历史和未来扩展及其碳减排潜力。我们采用了一个结合两个模型的机器学习框架:一个贝叶斯神经网络(BNN)模型来预测新的在制品分配的概率,一个可解释的机器学习模型来识别驱动县级废物处理碳排放的关键因素。研究发现,在2015-2022年期间,wip从202增长到902,使碳排放量从1.29亿吨二氧化碳当量显著减少到9110亿吨二氧化碳当量。根据BNN模型,到2035年将有1408个wip服务于2492个县级行政单位。特征分析的RF模型表明,填埋率、焚烧率、人口和地理位置主要影响县域垃圾处理碳排放。情景分析显示了碳减排潜力的时空分布特征:由于WIPs的快速增长,北部和中部地区的碳减排潜力最大,而碳减排的空间优先级则从市辖区向县转移。研究结果为解决区域不平衡问题提供了有针对性的见解,并指导基础设施规划朝着可持续废物管理和低碳转型的方向发展。
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引用次数: 0
Future changes in CO2 emissions in the shift to electric mobility in countries with varied levels of zero-emission vehicle policies 未来各国在向电动汽车转变过程中二氧化碳排放量的变化,其零排放汽车政策水平各不相同
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-03-01 Epub Date: 2026-03-04 DOI: 10.1016/j.resenv.2026.100316
Shuai Pan , Yicheng Xu , Zitian Li , Lewis M. Fulton , H. Oliver Gao
Electric vehicle (EV) adoption has been viewed widely as a promising climate mitigation strategy, whereas the pace and scale of EV transition varies significantly in worldwide regions. This study examines recent policy dynamics in the global EV transition, employing the timing and magnitude of reductions in transport non-energy costs as key policy variables. Through systematic quantitative analysis using the Global Change Analysis Model (GCAM), this study evaluates how different policy strengths shape EV transition pathways and their potential for energy savings and emission reductions. Results indicate that a uniform 20% reduction in non-energy costs for passenger electric cars worldwide from 2035 onward could increase EV penetration during the corresponding period from approximately 25–50% to around 70–85%. Such widespread adoption is expected to substantially lower future energy consumption and CO2 emissions in the U.S., Europe, and China, while also helping curb rising emission trends in India, Southeast Asia, and Western Africa. Implementing the same 20% cost reduction in China as early as 2025 can effectively replicate its recent rapid growth in EV penetration. For the European Union, a phased cost-reduction approach (10% in 2030, rising to 30% from 2035) would likely enable it to meet the clean mobility target outlined in its 2025 Automotive Package, namely a 90% reduction in tailpipe emissions from 2035 onward. The use of battery EVs increases electricity consumption, but such impact remains modest. The popularity of fuel cell EVs can push up hydrogen demand, which makes expansion of green hydrogen production necessary. Results suggest the necessity of providing support like technological assistance and financial investment from leading automotive markets (e.g., the U.S., Europe, and China) to developing countries, to ensure a global, inclusive, and equitable EV transition.
电动汽车(EV)的采用已被广泛视为一种有前景的气候减缓战略,然而,电动汽车转型的速度和规模在全球各地区差异很大。本研究考察了全球电动汽车转型的最新政策动态,将运输非能源成本降低的时间和幅度作为关键政策变量。通过使用全球变化分析模型(GCAM)进行系统定量分析,本研究评估了不同政策优势如何影响电动汽车转型路径及其节能减排潜力。结果表明,从2035年起,全球乘用车非能源成本统一降低20%,将使同期电动汽车普及率从约25-50%提高到70-85%左右。如此广泛的采用预计将大大降低美国、欧洲和中国未来的能源消耗和二氧化碳排放,同时也有助于遏制印度、东南亚和西非不断上升的排放趋势。最早在2025年在中国实施同样的20%成本削减,可以有效地复制其最近电动汽车普及率的快速增长。对于欧盟来说,分阶段降低成本的方法(2030年为10%,从2035年起上升到30%)可能使其能够实现其2025年汽车计划中概述的清洁出行目标,即从2035年起减少90%的尾气排放。电池电动汽车的使用增加了电力消耗,但这种影响仍然不大。燃料电池电动汽车的普及可以推动氢的需求,这使得扩大绿色氢生产成为必要。研究结果表明,有必要从主要汽车市场(如美国、欧洲和中国)向发展中国家提供技术援助和金融投资等支持,以确保全球、包容和公平的电动汽车转型。
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引用次数: 0
Balancing land planning priorities for ecological conservation and renewable energy development through multi-objective land planning in China 基于多目标土地规划平衡生态保护与可再生能源发展的土地规划重点
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-03-01 Epub Date: 2026-02-10 DOI: 10.1016/j.resenv.2026.100303
Ke Wang , Wenxiang Wu , Haimeng Liu , Xueqin Zhang , Xinshuai Ren , Maochou Liu , Jiahui Cheng , Jing Geng , Bo Yang
Balancing ecological conservation with renewable energy development is a critical challenge in China, where the rapid expansion of renewable energy is indispensable for achieving carbon neutrality but increasingly intensifies conflicts with conservation. To balance these conflicts, we developed a multi-objective land planning framework that integrates high-resolution spatial data on biodiversity, ecosystem services, vulnerable carbon stocks, and renewable energy potentials. Within this framework, we implemented three land-use scenarios representing distinct policy preferences—Conservation-First, Energy-First, and Multi-Zones (equal weighting of conservation and energy objectives)—to allocate land optimally and quantify the trade-offs between ecological conservation and renewable energy development. Our results revealed that without ecological safeguards, renewable energy expansion would place more than 2 million km2 of land at risk and expose 901.31 Gt of vulnerable carbon, while also threatening the nation's highly irreplaceable species habitats—which, although covering only about 80 km2, are extremely sensitive to land-use change. In contrast, the Multi-Zones scenario reduces carbon exposure by ∼30 Gt, safeguards 10% more critical habitats, and preserves nearly 90% (642.5 GW) of national objective of renewable energy. The trade-offs induced by wind and solar energy are concentrated in northern and eastern Inner Mongolia and southern Xizang provinces, while hydropower-related trade-offs occur mainly in the highly elevated regions of Yunnan province, highlighting areas where adaptive conservation strategies and conflict-sensitive energy planning are most needed. Based on these findings, we proposed region-specific strategies to guide policies that align China's dual carbon commitments with Ecological Conservation Redline and support the achievement of SDG 7 and SDG 15.
平衡生态保护与可再生能源的发展是中国面临的一项重大挑战。在中国,可再生能源的快速扩张是实现碳中和不可或缺的,但与保护的冲突日益加剧。为了平衡这些冲突,我们开发了一个多目标土地规划框架,该框架整合了生物多样性、生态系统服务、脆弱碳储量和可再生能源潜力的高分辨率空间数据。在此框架下,我们实施了代表不同政策偏好的三种土地使用情景——节约优先、能源优先和多分区(节约和能源目标的同等权重),以优化土地配置,量化生态保护与可再生能源发展之间的权衡。研究结果表明,如果没有生态保障,可再生能源的扩张将使超过200万平方公里的土地面临风险,并暴露9013.1 Gt的脆弱碳,同时也威胁到国家高度不可替代的物种栖息地,这些栖息地虽然仅覆盖约80平方公里,但对土地利用变化极为敏感。相比之下,多区域情景减少了约30亿吨的碳暴露,多保护了10%的关键栖息地,并保持了近90%(642.5吉瓦)的国家可再生能源目标。风能和太阳能引起的权衡主要集中在内蒙古北部和东部以及西藏南部,而水电相关的权衡主要发生在云南省的高海拔地区,突出了最需要适应性保护战略和冲突敏感型能源规划的地区。基于这些发现,我们提出了针对区域的战略,以指导政策,使中国的双碳承诺与生态保护红线保持一致,并支持实现可持续发展目标7和可持续发展目标15。
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引用次数: 0
Evaluate the resilience of ecological networks under node attack scenarios to reveal the cross-scale transmission characteristics 评估节点攻击情景下生态网络的弹性,揭示跨尺度传播特征
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-03-01 Epub Date: 2026-02-11 DOI: 10.1016/j.resenv.2026.100308
Zhe Li , Wei Wu , Xianggang Zhao , Shiqi Tian , Kai Li , Yufan Wu , Linjuan Li
Investigating the scale transmission mechanisms of ecological networks (ENs) resilience is critical for designing adaptive planning and policies to mitigate multi-scale anthropogenic pressures. Accordingly, an analysis framework applicable to multi-level scales was developed, taking the provincial, city cluster and city scales as a nested hierarchy, constructing structural ENs (based on Morphological Spatial Pattern Analysis) and functional ENs (based on the ecological importance and sensitivity evaluation), then evaluating their resilience and cross-scale transmission characteristics using a node attack model. Results showed structural and functional ENs were most stable at city scale, with stability weakening as scale increased. Complete removal of city scale patches caused a larger decline in provincial scale resilience (0.19 and 0.15 for structural and functional ENs) than in the city cluster scale (0.08 and 0.09 for structural and functional ENs). The provincial scale resilience only decreased 0.07 for structural ENs when city cluster scale patches were removed completely, lower than complete removal of city scale patches, but it showed extreme vulnerability at the initial stage. ENs resilience exhibited cascading fragility, removing finer scale patches can trigger asymmetric cross-scale transmission, and the re-stabilization could be achieved through sacrificial degradation of secondary nodes and reconfiguration of peripheral corridors. It emphasized the critical need for tiered conservation strategies and coordinated management across scales to enhance ENs stability. The proposed framework provides a transferable tool for multi-scale ENs optimization, supporting biodiversity conservation and sustainable development goals.
研究生态网络弹性的尺度传递机制对于设计适应性规划和政策以减轻多尺度人为压力至关重要。据此,构建了适用于多尺度的分析框架,将省、城市群和城市尺度作为一个嵌套层次,分别构建基于形态空间格局分析的结构性网络和基于生态重要性和敏感性评价的功能性网络,并利用节点攻击模型评价其弹性和跨尺度传播特征。结果表明:城市尺度下,结构生态系统和功能生态系统最稳定,稳定性随城市尺度的增大而减弱;完全去除城市尺度斑块导致省级尺度恢复力的下降幅度(结构和功能网络分别为0.19和0.15)大于城市群尺度恢复力的下降幅度(结构和功能网络分别为0.08和0.09)。当城市群尺度斑块完全移除时,结构性网络的省级尺度恢复力仅降低0.07,低于完全移除城市尺度斑块,但在初始阶段表现出极度脆弱性。生态系统弹性表现为级联脆弱性,去除较细尺度斑块可触发非对称跨尺度传递,通过牺牲次级节点退化和外围廊道重构可实现再稳定。报告强调,迫切需要采取分层保护战略和跨尺度协调管理,以增强生态系统的稳定性。该框架为多尺度生态系统优化提供了可转移的工具,支持生物多样性保护和可持续发展目标。
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引用次数: 0
Ecosystem health responses to tourism activities in the Qinghai-Tibet Plateau: Nonlinear relationships and mechanism 青藏高原生态系统健康对旅游活动的响应:非线性关系与机制
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-03-01 Epub Date: 2026-02-08 DOI: 10.1016/j.resenv.2026.100305
Linlin Xu , Hu Yu , Linsheng Zhong
Rapid tourism development in ecologically fragile regions poses a risk of exceeding ecosystem self-regulation capabilities. To promote the coordination of conservation and development, this study aims to explore the nonlinear relationship between ecosystem health and tourism activities. This study established a tourism activity intensity index and employed a machine learning model to simulate ecological responses on the Qinghai-Tibet Plateau. The results reveal that the response of ecosystem health to tourism activity is characterized by distinct nonlinear features. While ecosystem health maintains relative stability under low-to-moderate disturbance, it suffers accelerated degradation once the intensity exceeds critical thresholds. Specifically, quantitative thresholds were identified at the kilometer-grid scale (0.134) and the trajectory-point scale (0.337), suggesting a scale-dependent resilience mechanism. Natural geographical conditions and tourism organization patterns jointly shape diverse nonlinear response patterns. These insights bridge the gap between theoretical carrying capacity and quantitative estimation, offering practical references for defining the safe operating space in high-altitude areas.
生态脆弱地区旅游业的快速发展带来了生态系统自我调节能力超出的风险。为了促进保护与发展的协调,本研究旨在探讨生态系统健康与旅游活动之间的非线性关系。本文建立了旅游活动强度指数,并利用机器学习模型对青藏高原的生态响应进行了模拟。结果表明,生态系统健康对旅游活动的响应具有明显的非线性特征。虽然生态系统健康在低至中度干扰下保持相对稳定,但一旦强度超过临界阈值,它就会加速退化。具体而言,在公里网格尺度(0.134)和轨迹点尺度(0.337)上确定了定量阈值,表明弹性机制依赖于尺度。自然地理条件和旅游组织模式共同塑造了多样化的非线性响应模式。这些见解弥合了理论承载能力与定量估算之间的差距,为确定高海拔地区的安全作业空间提供了实践参考。
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引用次数: 0
Enhanced biomass utilization efficiency reshapes spatiotemporal shifts of China's HANPP 生物质利用效率的提升重塑了中国HANPP的时空变化
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-03-01 Epub Date: 2026-02-06 DOI: 10.1016/j.resenv.2026.100307
Yike Li , Jing Gao , Yunpeng Shi , Yan Wu , Heng Xu , Jia Zhou , Tao Lu
Escalating global population and economic expansion are fueling unprecedented demand for natural resources, making a robust understanding of human impacts on biomass flows critical for achieving the Sustainable Development Goals. The Human Appropriation of Net Primary Production (HANPP) is a key metric for quantifying human effects on ecosystem biomass flows; however, a lack of research on the dynamics of HANPP utilization efficiency has likely led to an overestimation of biomass resource pressure and an oversight of the separation between HANPP and socioeconomic development driven by improvements in utilization efficiency. To fill these gaps, we generated annual 1-km HANPP maps for China (1990–2022) and developed a two-dimensional conceptual framework to characterize dynamic interactions between biomass utilization and retention. Our findings show that, during the early period of socioeconomic development (1990–2000), biomass utilization and retention exhibited a trade-off, marked by a low utilization efficiency of 55.33%. Subsequently, with the growth of socio-ecological systems, strong demand fueled a steady increase in NPP utilization intensity—yet enhanced biomass utilization efficiency simultaneously mitigated this upward trend by reducing NPP losses, with utilization efficiency rising from 64.16% (2000–2010) to 73.94% (2010–2022). This efficiency-driven shift not only moved utilization-retention interactions toward coordination but also facilitated the separation of HANPP from socioeconomic development. Our findings underscore the need for strategies to enhance biomass utilization efficiency, thereby supporting sustainable resource use.
全球人口不断增长和经济扩张正在推动对自然资源的空前需求,因此,深入了解人类对生物质流动的影响对实现可持续发展目标至关重要。净初级生产的人类占用(HANPP)是量化人类对生态系统生物量流量影响的关键指标;然而,由于缺乏对生物质资源利用效率动态的研究,可能导致对生物质资源压力的高估,并忽视了利用效率提高驱动的生物质资源利用与社会经济发展之间的分离。为了填补这些空白,我们绘制了中国(1990-2022)每年1公里的HANPP地图,并开发了一个二维概念框架来表征生物质利用和保留之间的动态相互作用。结果表明,在社会经济发展初期(1990 ~ 2000年),生物量利用与生物量保留呈权衡关系,利用效率较低,为55.33%。随后,随着社会生态系统的发展,强劲的需求推动了NPP利用强度的稳步增长,而生物质利用效率的提高同时通过减少NPP损失来缓解这一上升趋势,利用效率从2000-2010年的64.16%上升到2010-2022年的73.94%。这种效率驱动的转变不仅使利用-保留相互作用朝着协调的方向发展,而且促进了HANPP与社会经济发展的分离。我们的研究结果强调需要制定提高生物质利用效率的战略,从而支持资源的可持续利用。
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引用次数: 0
Biodiversity loss from rare earth production for green technologies in China: a global supply chain perspective 中国绿色技术稀土生产造成的生物多样性损失:全球供应链视角
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-03-01 Epub Date: 2026-02-26 DOI: 10.1016/j.resenv.2026.100314
Xuanru Zhou , Gengyuan Liu , Hongxiu Li , Weicen Chang , Qipeng Deng , Marco Casazza
Rare earth elements (REEs) are indispensable raw materials for green technologies, but their production process may cause significant ecological pressure. As the world's major supplier of REEs, China undertakes most of the mining and refining tasks, but it is unclear whether the Chinese rare earth supply chain has an impact on biodiversity and what part is due to foreign consumption and what part is domestic consumption. Here, we developed BLARES, a dynamic assessment framework that combines system dynamics with life cycle biodiversity impact accounting, to evaluate the impact of China's rare earth supply chain on biodiversity during the period from 2000 to 2060 under four SSP scenarios. We used mean species abundance (MSA) to measure the impact, covering land occupation and climate-driven pathways, and considering ecological time lag factors. The results show a clear ecological debt pattern. In the medium term, biodiversity pressure increases or remains high because the marginal effects brought by upstream expansion are released. Only when the used inventory of green technology products in rare earths is accumulated to stabilize the replacement of fossil energy, will the impact of the rare earth supply chain on biodiversity show a net improvement. Compared to the baseline value in 2000, the cumulative avoided biodiversity loss has exceeded 4 × 107 MSA·ha·yr by 2060. The net impact turns positive around 2040, and the cumulative net impact reaches zero around 2049, indicating a significant delay in ecological compensation. The time when the carbon balance occurs is earlier than that of biodiversity compensation, suggesting that net zero carbon emissions do not necessarily mean zero ecological emissions. From the perspective of final demand attribution, for every 1% increase in overseas demand, China's annual net biodiversity loss increases by approximately 0.031%, while for every 1% increase in the use of rare earth elements for green deployment in China, it decreases by about 0.84%. Our research results do not support the simplistic claim that “the more deployment, the better”. The transition path should be evaluated using the time of ecological compensation and the peak of medium-term pressure, rather than solely based on the final carbon emission results.
稀土元素是绿色技术不可缺少的原材料,但其生产过程可能造成巨大的生态压力。作为全球稀土的主要供应国,中国承担了大部分的开采和提炼任务,但目前尚不清楚中国的稀土供应链是否对生物多样性产生影响,以及哪些部分来自国外消费,哪些部分来自国内消费。本文基于系统动力学和生命周期生物多样性影响会计相结合的动态评估框架BLARES,对4种SSP情景下2000 - 2060年中国稀土供应链对生物多样性的影响进行了评估。我们使用平均物种丰度(MSA)来衡量影响,包括土地占用和气候驱动路径,并考虑生态滞后因素。结果显示出明显的生态债务格局。从中期来看,由于上游扩张带来的边际效应得到释放,生物多样性压力增大或保持在较高水平。只有积累稀土中绿色科技产品的使用库存,稳定替代化石能源,稀土供应链对生物多样性的影响才会出现净改善。与2000年基线值相比,到2060年累计避免的生物多样性损失已超过4 × 107 MSA·ha·年。净影响在2040年左右转为正影响,累计净影响在2049年左右为零,表明生态补偿出现明显延迟。碳平衡发生的时间早于生物多样性补偿发生的时间,说明净零碳排放并不一定意味着零生态排放。从最终需求归因的角度来看,海外需求每增加1%,中国每年的生物多样性净损失约增加0.031%,而中国稀土元素绿色部署使用量每增加1%,每年的生物多样性净损失约减少0.84%。我们的研究结果并不支持“部署越多越好”的简单说法。应根据生态补偿时间和中期压力峰值对过渡路径进行评价,而不应仅根据最终的碳排放结果进行评价。
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引用次数: 0
Synergistic carbon–silicate hierarchical biochar from waste activated sludge for high-performance flow-electrode capacitive deionization 从废活性污泥中提取的协同碳-硅酸盐分级生物炭用于高效流动电极电容去离子
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-03-01 Epub Date: 2026-02-10 DOI: 10.1016/j.resenv.2026.100309
Yifan He , Wenchao Xue , Kang Xiao , Qiuju Wang , Guoren Xu
This study investigates the efficiency of biochar derived from waste activated sludge (WAS) as an electrode material in flowing-electrode capacitive deionization (FCDI), demonstrating improved desalination performance compared to commercial activated carbon (AC). The WAS-derived biochar (B-800-KH-1), synthesized via 2-h pyrolysis at 800 °C followed by KOH activation at a mass ratio of 1:1, exhibits a hierarchical micro/mesoporous architecture with an average pore diameter of 9.22 nm, a mesopore volume ratio of 76.57% and a disorder/graphite bands intensity ratio of 1.18. Moreover, the embedded silicate framework within the biochar synergistically interacts with the carbon phase, promoting ion pathways, and mitigating charge transfer resistance. Optimized operation of the FCDI system using the prepared B-800-KH-1 electrode achieved a maximum salt removal rate of 1.92 ± 0.23 μmol/cm2·min and an average removal rate of 1.24 ± 0.07 μmol/cm2·min, representing increments of approximately 56.1% and 7.8%, respectively, over commercial AC. Additionally, it demonstrated an energy-normalized salt removal of 8.35 ± 0.26 μmol/J at a 5.0 wt% carbon content and an applied voltage of 1.2 V. These findings highlight that high desalination efficiency is not solely dictated by total carbon content or specific surface area; rather, the interplay of mesoporous carbon domains with the silicate network and hierarchical pore connectivity drives enhanced electrosorption. Utilizing of WAS as a biochar precursor not only provides an effective electrode material but also offers a sustainable solution for WAS management, paving the way for advanced and environmentally cost-effective conscious desalination technologies.
本研究研究了从废活性污泥(WAS)中提取的生物炭作为流动电极电容去离子(FCDI)的电极材料的效率,与商业活性炭(AC)相比,显示了更好的海水淡化性能。在800℃条件下经2 h热解、KOH活化、质量比为1:1合成的生物炭(B-800-KH-1)具有微孔/介孔结构,平均孔径为9.22 nm,介孔体积比为76.57%,无序带/石墨带强度比为1.18。此外,生物炭内嵌入的硅酸盐框架与碳相协同作用,促进离子途径,减轻电荷转移阻力。利用制备的B-800-KH-1电极优化后,fdi系统的最大除盐率为1.92±0.23 μmol/cm2·min,平均除盐率为1.24±0.07 μmol/cm2·min,分别比商用交流电提高约56.1%和7.8%。此外,在5.0 wt%碳含量和1.2 V电压下,fdi系统的能量标准化除盐率为8.35±0.26 μmol/J。这些发现强调,高脱盐效率并不仅仅取决于总碳含量或比表面积;更确切地说,介孔碳畴与硅酸盐网络和分层孔连性的相互作用驱动了电吸附的增强。利用WAS作为生物炭前体不仅提供了一种有效的电极材料,而且为WAS管理提供了一种可持续的解决方案,为先进且具有环保成本效益的海水淡化技术铺平了道路。
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引用次数: 0
Optimizing minimum dataset for soil degradation assessment in dryland of southern China: A two-step approach 中国南方旱地土壤退化评价最小数据集优化:两步法
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-03-01 Epub Date: 2026-02-24 DOI: 10.1016/j.resenv.2026.100315
Yefeng Jiang, Xi Guo
Soil degradation is a critical global challenge, and its accurate assessment is fundamental to advancing sustainable soil management and ensuring food security. The minimum dataset (MDS) has been widely adopted in soil degradation assessments, typically constructed using various statistical and machine learning techniques. However, a lack of systematic comparisons among these methods introduces substantial uncertainty into degradation evaluations. Here, we propose a two-step approach to optimize MDS construction using 99 dryland red soil samples from Ji'an, China, and the analysis of 30 physical, chemical, and biological indicators. First, machine learning algorithms—including Decision Tree, Random Forest, Gradient Boosting Regression Tree (GBRT), and Extreme Gradient Boosting—were employed for feature selection. Subsequently, indicator weighting and scoring functions were applied to assess the degree of soil degradation. Our results demonstrate that the proposed two-step approach outperforms both conventional statistical dimensionality reduction techniques (i.e., principal component and K-means cluster analyses) and the direct application of machine learning models. Multiple model evaluation metrics—including the coefficient of determination, error metrics, statistical tests, and correlation with crop yield—consistently indicate that the MDS derived from the GBRT-based two-step approach is highly suitable for rapid characterization of dryland red soil degradation. This MDS comprises organic carbon, microaggregates, bulk density, field capacity, urease, nitrate nitrogen, available phosphorus, available potassium, and total phosphorus. The assessment further revealed that dryland soils in the study area were generally at a moderate degradation level, primarily driven by the combined effects of climatic, soil, topographic, and anthropogenic factors. This study validates the two-step approach as an effective tool for assessing dryland red soil degradation and offers new insights for the development of a global soil degradation monitoring system.
土壤退化是一项重大的全球挑战,准确评估土壤退化对推进可持续土壤管理和确保粮食安全至关重要。最小数据集(MDS)在土壤退化评估中被广泛采用,通常使用各种统计和机器学习技术构建。然而,这些方法之间缺乏系统的比较,给退化评价带来了很大的不确定性。本文以吉安市99个旱地红壤样品为研究对象,通过对30个物理、化学和生物指标的分析,提出了两步优化MDS构建的方法。首先,采用决策树、随机森林、梯度增强回归树(GBRT)和极端梯度增强等机器学习算法进行特征选择。随后,应用指标加权和评分函数对土壤退化程度进行评价。我们的研究结果表明,提出的两步方法优于传统的统计降维技术(即主成分和k均值聚类分析)和机器学习模型的直接应用。多个模型评估指标(包括决定系数、误差指标、统计检验和与作物产量的相关性)一致表明,基于gbr2步法的MDS非常适合于旱地红壤退化的快速表征。该MDS包括有机碳、微团聚体、体积密度、田间容量、脲酶、硝酸盐氮、有效磷、有效钾和总磷。研究区旱地土壤总体处于中度退化状态,主要受气候、土壤、地形和人为因素的综合影响。该研究验证了两步法作为评估旱地红壤退化的有效工具,并为全球土壤退化监测系统的发展提供了新的见解。
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Resources Environment and Sustainability
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