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Microbial fermentation in co-ensiling forage-grain ratoon rice and maize to improve feed quality and enhance the sustainability of rice-based production systems 微生物发酵在饲料粮、口粮、水稻和玉米共青贮中的应用,以提高饲料质量和增强水稻生产系统的可持续性
IF 12.4 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-02-24 DOI: 10.1016/j.resenv.2025.100205
Ye Liu , Qilong Zhou , Changli Ji , Jiangcheng Mu , Yimei Wang , Matthew Tom Harrison , Ke Liu , Yafan Zhao , Quanzhi Zhao , Jing Zhang , Ting Peng
To enhance the quality of forage-grain ratoon rice (FGR) and promote the sustainable development of both rice and livestock industries in southern China, this study investigates the microbial fermentation dynamics of co-ensiling FGR with maize or sorghum-sudangrass hybrid. Results demonstrate that co-ensiling with maize significantly improved fermentation quality, reducing fiber content and enhancing lactic acid production, compared with sorghum-sudangrass hybrid. The optimal FGR-to-maize ratio of 75:25 yielded the lowest neutral detergent fiber and acid detergent fiber values and the highest lactic acid concentration (39.37 g/kg DM). Co-ensiling promoted the growth of beneficial lactic acid bacteria (LAB), particularly Lactobacillaceae and Sporolactobacillaceae, thus enhancing fermentation efficiency. Additionally, inoculation with Lactobacillus plantarum improved silage stability by promoting LAB growth and inhibiting the growth of undesirable Enterobacter species. This study offers a sustainable strategy to optimize rice straw utilization for livestock feed, reduce dependence on imported forages, and support agricultural sustainability in China.
为提高饲料稻品质,促进南方水稻和畜牧业的可持续发展,研究了饲料稻与玉米或高粱-苏丹草杂交种共青贮的微生物发酵动态。结果表明,与高粱-苏丹草杂交品种相比,与玉米共青贮显著改善了发酵品质,降低了纤维含量,提高了乳酸产量。以75:25的fgr /玉米比例为最佳,中性洗涤纤维和酸性洗涤纤维值最低,乳酸浓度最高(39.37 g/kg DM)。共青贮促进了有益乳酸菌(LAB)的生长,尤其是乳酸杆菌科(Lactobacillaceae)和孢乳杆菌科(Sporolactobacillaceae),从而提高了发酵效率。此外,接种植物乳杆菌通过促进乳酸菌生长和抑制不良肠杆菌种类的生长来提高青贮的稳定性。本研究为优化秸秆作为牲畜饲料的利用,减少对进口饲料的依赖,支持中国农业可持续发展提供了可持续策略。
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引用次数: 0
Recent advancements in prospective life cycle assessment: Current practices, trends, and implications for future research 前瞻性生命周期评估的最新进展:当前的实践、趋势和对未来研究的影响
IF 12.4 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-02-24 DOI: 10.1016/j.resenv.2025.100203
Anissa Nurdiawati, Basit A. Mir, Sami G. Al-Ghamdi
Prospective Life Cycle Assessment (pLCA) is gaining interest due to its inherent future-oriented feature, which is an essential component of every decision-oriented life cycle assessment. Previous studies have highlighted challenges in conducting pLCA for emerging technologies, categorizing them into issues of comparability, data availability, scaling, and uncertainty and propose general frameworks to address these challenges. Accordingly, the application of pLCA is rapidly growing in recent years, with emerging methods addressing the limitations, and improving pLCA. This review study aims to compile and analyze emerging pLCA methods from scientific literature, identifying best practices and limitations to guide future research. It discusses methodological advancements in pLCA, including prospective life cycle inventory (pLCI) database, foreground modeling, scenario development and prospective life cycle impact assessment, offering insights for practitioners. While changes in background systems are increasingly addressed in pLCA studies, some, particularly earlier or less systematic ones, fall short of fully integrating nuanced future scenarios. The reviewed studies highlight that incorporating future scenarios related to the transformation of energy, material, transport, and industrial systems can significantly influence LCA outcomes, reinforcing the importance of explicitly integrating such scenarios into pLCA to ensure reliable and meaningful results. To ensure robust LCA studies, it is important to consider the use of pLCI databases, accounting for varying technology maturity levels, their improvement and diffusion rate, and incorporating spatial considerations. Yet, integrating pLCI databases with standard LCA tools remains complex, with a lack of practitioner guidance. Moreover, the interlinkage between climate change and various impact categories is a key source of uncertainty in future assessments, highlighting the need to improve both prospective inventory modeling and impact assessment. The findings call for future research to further explore the spatiotemporal effect of climate change on pLCA quantification, developing future-oriented characterization factors, expanding pLCI databases, as well as enhancing the applicability of pLCA studies through the integration of new analytical tools and models.
前瞻性生命周期评估(pLCA)由于其固有的面向未来的特征而受到人们的关注,它是每一种面向决策的生命周期评估的重要组成部分。先前的研究强调了对新兴技术进行pLCA的挑战,将它们分为可比性、数据可用性、可扩展性和不确定性等问题,并提出了解决这些挑战的一般框架。因此,近年来pLCA的应用迅速增长,新兴的方法解决了pLCA的局限性,并改进了pLCA。本综述旨在整理和分析科学文献中出现的pLCA方法,确定最佳实践和局限性,以指导未来的研究。它讨论了pLCA方法上的进步,包括前瞻性生命周期清单(pLCI)数据库、前景建模、场景开发和前瞻性生命周期影响评估,为从业者提供了见解。虽然pLCA研究越来越多地涉及背景系统的变化,但有些研究,特别是较早或较不系统的研究,未能充分整合细微的未来情景。回顾的研究强调,纳入与能源、材料、运输和工业系统转型相关的未来情景可以显著影响LCA结果,强调了将这些情景明确整合到pLCA中的重要性,以确保可靠和有意义的结果。为了确保可靠的LCA研究,重要的是要考虑pLCI数据库的使用,考虑不同的技术成熟度水平、它们的改进和扩散速度,并结合空间因素。然而,将pLCI数据库与标准LCA工具集成仍然很复杂,缺乏从业者的指导。此外,气候变化与各种影响类别之间的相互联系是未来评估中不确定性的主要来源,这突出表明需要改进前瞻性清单建模和影响评估。未来的研究应进一步探索气候变化对pLCA量化的时空影响,开发面向未来的表征因子,扩展pLCI数据库,并通过整合新的分析工具和模型来增强pLCA研究的适用性。
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引用次数: 0
A life cycle thinking-based environmental risk framework for screening sustainable feedstocks in early-stage bioeconomy projects 基于生命周期思维的早期生物经济项目可持续原料筛选环境风险框架
IF 12.4 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-02-20 DOI: 10.1016/j.resenv.2025.100201
George Bishop , Carmen Girón-Domínguez , James Gaffey , Maeve Henchion , Réamonn Fealy , Jesko Zimmermann , Wriju Kargupta , David Styles
Understanding the environmental impacts of bio-based feedstock production is essential for sustainable bioeconomy development. Consequential life cycle assessment (LCA) evaluates environmental sustainability, often identifying “hidden” impacts incurred through market displacements. However, it is often impractical to screen multiple bioeconomy feedstocks and value chains using full consequential LCA early in project conceptualisation, owing to high requirements in terms of time, data, and expertise. As a result, critical environmental risks may not be discovered until too late in project development to redirect investment towards more sustainable options. This paper introduces the Bio-based feedstock Environmental Risk Assessment (Bio-ERA) Framework, designed to support early screening of potential upstream environmental risks associated with increased demand for bio-based feedstocks. The Bio-ERA Framework comprises a decision tree that systematically guides stakeholders through consequential life cycle thinking, elucidating sometimes hidden (indirect) pathways of impact among feedstock sourcing decisions. Seven important environmental aspects are addressed: Finite Resource Inputs, Greenhouse Gas (GHG) Emissions, Air Quality, Water Quality, Ecosystem Diversity, Terrestrial Carbon Storage, and Indirect Land Use Change. Criteria are proposed to structure evaluation of (i) probability and (ii) severity of environmental impact, in relation to four categories of feedstock: primary (determining product), high-value by-product, low-value by-product, and waste. Example applications demonstrate how the framework can generate an environmental risk profile for specific feedstocks sourced in specific contexts. Bio-ERA does not avoid the need for detailed LCA evaluation of full bioeconomy value chains, but promotes deeper interrogation and awareness of potential environmental risks associated with feedstock sourcing, in a manner that is accessible to all stakeholders. This could support earlier screening of strategic investment decisions necessary to develop a sustainable bioeconomy.
了解生物基原料生产对环境的影响对可持续生物经济发展至关重要。后续生命周期评估(LCA)评估环境的可持续性,通常识别由市场置换引起的“隐藏”影响。然而,由于在时间、数据和专业知识方面的高要求,在项目概念化的早期使用完整的相应LCA筛选多种生物经济原料和价值链通常是不切实际的。因此,在项目开发过程中发现严重的环境风险可能为时已晚,无法将投资转向更可持续的选择。本文介绍了生物基原料环境风险评估(Bio-ERA)框架,旨在支持早期筛选与生物基原料需求增加相关的潜在上游环境风险。Bio-ERA框架包括一个决策树,系统地指导利益相关者通过相应的生命周期思维,阐明原料采购决策中有时隐藏的(间接的)影响途径。七个重要的环境方面:有限资源投入、温室气体(GHG)排放、空气质量、水质、生态系统多样性、陆地碳储量和间接土地利用变化。针对四类原料(主要(决定产品)、高价值副产品、低价值副产品和废物),提出了对(i)环境影响的可能性和(ii)严重程度进行结构评估的标准。示例应用程序演示了该框架如何为来自特定环境的特定原料生成环境风险概况。Bio-ERA并没有避免对整个生物经济价值链进行详细的LCA评估的需要,而是以所有利益相关者都可以访问的方式,促进对与原料采购相关的潜在环境风险的更深入的询问和认识。这可以支持早期筛选发展可持续生物经济所需的战略投资决策。
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引用次数: 0
Nitrogen reduction with green manure roots return maintains spring wheat yield and alleviates soil N2O emission in saline-alkali agroecosystem 绿肥还根降氮维持了春小麦产量,缓解了盐碱农业生态系统土壤N2O排放
IF 12.4 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-02-20 DOI: 10.1016/j.resenv.2025.100202
Fangdi Chang , Hongyuan Zhang , Peiyi Zhao , Na Zhao , Jiashen Song , Ru Yu , Jing Wang , Xiquan Wang , Dongxun Han , Hanjiang Liu , Jie Zhou , Yuyi Li
The growing global demand for grain drives a greater need for nitrogen (N) input. Yet, it contributes to nitrous oxide (N2O) emissions, aggravating global climate change. To tackle this dual challenge of fulfilling crop demands while maintaining or reducing N2O emissions, a field study was performed in wheat-green manure cropping system to assess the effects of varying fertilizer application (N100, N90 and N80: N fertilizer reduced by 0%, 10% and 20%) combined with green manure return strategy (GMR: green manure roots return, GMRS: green manure roots and shoots return), and wheat fallow after harvest (CK) on wheat yield and yield stability from 2020 to 2024, N2O emissions, as well as N2O emission intensity from 2022 to 2024. Results showed that, although N fertilizer combined with green manure return strategy increased spring wheat yield by 8%–22% by increasing soil mineral N contents, it decreased yield stability compared with CK. Soil N2O emissions were mainly negatively and positively regulated by pH and NO3-N content in saline-alkali soil, respectively. N80 decreased cumulative soil N2O emission and N2O intensity by 20% and 10% compared with N100, respectively. Irrespective of the variations in N fertilizer levels, GMR decreased cumulative N2O emission and N2O intensity by 20%–34% and 22%–38% compared with GMRS, respectively. Overall, the findings highlighted N fertilizer reduced by 20% (160 kg N ha −1) with green manure roots returned in relative to normal rate (200 kg N ha −1) is a viable option to ensure spring wheat yield and alleviate soil N2O emission in saline-alkali agroecosystem.
全球粮食需求的增长推动了对氮(N)投入的更大需求。然而,它导致一氧化二氮(N2O)排放,加剧了全球气候变化。为了解决在满足作物需求的同时保持或减少N2O排放的双重挑战,在小麦-绿肥种植系统中进行了一项实地研究,以评估不同施肥(N100、N90和N80:氮肥减少0%、10%和20%)与绿肥返还策略(GMR:绿肥根返还,GMRS:绿肥根、芽回归)和小麦收获后休耕(CK)对2020 - 2024年小麦产量及产量稳定性、2022 - 2024年N2O排放及N2O排放强度的影响。结果表明,虽然氮肥配绿肥还田策略通过提高土壤矿质氮含量使春小麦产量提高8% ~ 22%,但与对照相比,其产量稳定性下降。盐碱地土壤N2O排放主要受pH和NO3−-N含量的负向和正向调节。与N100相比,N80使土壤累积N2O排放量和N2O强度分别降低20%和10%。无论氮肥水平如何变化,与GMR相比,GMR的累积N2O排放量和N2O强度分别降低了20% ~ 34%和22% ~ 38%。总体而言,研究结果表明,在盐碱农业生态系统中,减少20%的氮肥(160 kg N ha - 1),同时以正常水平(200 kg N ha - 1)还根,是保证春小麦产量和减少土壤N2O排放的可行选择。
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引用次数: 0
Assessing ecosystem service losses—A review of progress and problems 评估生态系统服务损失——进展与问题综述
IF 12.4 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-02-17 DOI: 10.1016/j.resenv.2025.100194
Hanjie Wang , Xiulong Zhang , Jianhua Zhang , Jianwen Yin , Weikai Bao
The assessment of ecosystem service losses is crucial for ecological impact assessment and the practice of ecological compensation restoration projects. However, few studies on assessing losses have focused on ecosystem services, and the existing knowledge is fragmented. This review synthesizes the research status, methods, and key findings in the field. It outlines the research status by categorizing studies into human, natural and comprehensive disturbance assessments by disturbance events. A basic framework for future research is established by summarizing assessment procedures and methods. Comparisons of the magnitude of losses and analyses of driving factors in existing studies have been discussed, and recommendations for future research directions have been proposed. Research indicates that since 2010, studies related to this topic have gradually increased, with a predominant focus on the losses caused by human disturbance. Regulatory services are the most frequently assessed type. Most results suggest that the magnitude of losses varies across different types of ecosystem services, ecosystems, and stages of ecosystem degradation. The regularity of these losses remains to be explored. Land use and climate change are two major driving factors, and distinguishing between their impacts is crucial. Therefore, future research should enhance assessments at multiple scales, promote more accurate assessments from aspects of data acquisition and evaluation methods, and deepen the exploration of loss regularity and drivers. This review fills the gap in systematic understanding of ecosystem service losses, offering a comprehensive reference for further research and the establishment of standards for ecological restoration and compensation.
生态系统服务功能损失评价是生态影响评价和生态补偿修复工程实践的重要内容。然而,评估损失的研究很少关注生态系统服务,而且现有的知识是碎片化的。本文综述了该领域的研究现状、方法和主要发现。通过对干扰事件进行人为干扰评估、自然干扰评估和综合干扰评估,概述了研究现状。通过对评估程序和方法的总结,建立了未来研究的基本框架。讨论了现有研究中损失幅度的比较和驱动因素的分析,并对未来的研究方向提出了建议。研究表明,自2010年以来,与该主题相关的研究逐渐增多,主要关注人为干扰造成的损失。监管服务是最常被评估的类型。大多数结果表明,不同类型的生态系统服务、生态系统和生态系统退化阶段的损失幅度不同。这些损失的规律性还有待研究。土地利用和气候变化是两个主要驱动因素,区分它们的影响至关重要。因此,未来的研究应加强多尺度的评估,从数据采集和评估方法方面推动更准确的评估,深化对损失规律和驱动因素的探索。该综述填补了系统认识生态系统服务功能损失的空白,为进一步研究和建立生态恢复与补偿标准提供了综合参考。
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引用次数: 0
Introducing the concept of “resource scapes” to account for water, energy and biomass resources’ nexus dependencies and governance 引入“资源景观”的概念,以解释水、能源和生物质资源的关联依赖关系和治理
IF 12.4 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-02-10 DOI: 10.1016/j.resenv.2025.100199
Zeeshan Tahir Virk , Jessica Fennell , Ali Torabi Haghighi , Bjorn Klove
Existing methods for resource nexus analysis do not cover all aspects of complex resource management problems. Key methodological challenges include setting the scale, scope, and resolution of a nexus analysis, as well as adequately representing the quantity and quality of resource interactions. Additionally, determining the degree of collaborative governance for resource management, accounting for the role of existing policies, and developing robust scenarios for future predictions are also crucial constraints. To address these limitations, we developed a conceptual model of the resources nexus for Otta valley in Norway, an area characterized by resource use trade-offs across interconnected systems. We introduced the concept of “resource scapes” which is the physical availability, key interactions, management networks, and policies governing a resource at a specific time and place. We defined resource scapes for water, energy, and biomass resources in the studied area. Employing stock and flow loops, social network analysis, material flow accounting, and policy reviews, we developed the model in a layered topology using the coupled component modeling approach. In addition, we developed future resource scenarios nested within national pathways – the Norwegian nexus pathways (NNPs) – aligned with the five globally adopted shared-socioeconomic pathways (SSPs), using a narrative downscaling approach. Our results show that annual variations in resource balances are connected to changing externalities. A low Network External-Internal (EI) index (0.392) indicates weak overall collaborative governance of nexus resources. Our modeling framework (1) addresses limitations in current nexus methods, (2) facilitates testing of alternative policy interventions under future scenarios, and (3) provides a framework for development of integrated assessment models. This approach merges the concept of nexus governance with integrated assessment modeling, thereby enhancing the application of nexus approach for efficient resource management which will be crucial in future as climate and socioeconomic conditions evolve.
现有的资源关系分析方法不能涵盖复杂资源管理问题的所有方面。关键的方法挑战包括设置关系分析的规模、范围和解决方案,以及充分表示资源相互作用的数量和质量。此外,确定资源管理的协作治理程度、考虑现有政策的角色以及为未来预测开发健壮的场景也是关键的限制因素。为了解决这些限制,我们为挪威的Otta山谷开发了一个资源联系的概念模型,该地区的特点是在相互关联的系统之间进行资源使用权衡。我们介绍了“资源场景”的概念,即物理可用性、关键交互、管理网络和在特定时间和地点管理资源的策略。我们在研究区域定义了水、能源和生物质资源的资源景观。利用库存和流量循环、社会网络分析、物料流会计和政策审查,我们使用耦合组件建模方法在分层拓扑中开发了模型。此外,我们开发了嵌套在国家路径中的未来资源情景-挪威联系路径(NNPs) -与全球采用的五个共享社会经济路径(ssp)保持一致,使用叙事缩小方法。我们的研究结果表明,资源平衡的年度变化与外部性的变化有关。网络外部-内部(EI)指数较低(0.392)表明网络资源整体协同治理较弱。我们的建模框架(1)解决了当前联系方法的局限性,(2)促进了未来情景下替代政策干预的测试,(3)为开发综合评估模型提供了框架。这种方法将关联治理的概念与综合评估建模相结合,从而加强了关联方法在有效资源管理方面的应用,随着气候和社会经济条件的发展,这在未来将至关重要。
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引用次数: 0
Dynamic mechanisms of land use spatial conflicts in mining cities: A case study of Xintai City, China 矿业城市土地利用空间冲突动态机制研究——以新泰市为例
IF 12.4 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-02-06 DOI: 10.1016/j.resenv.2025.100197
Yang Zheng , Kao Wang , Runmei Hao
With resource extraction and transformational development, the hindering effect of land use spatial conflict (LUSC) on mining city development is significant, highlighting the importance of exploring the dynamic mechanism of LUSC for sustainable development. This study integrates the multidimensional attributes of LUSC, constructs a LUSC assessment framework based on “element- pattern-effect”, and proposes theoretical hypotheses on the dynamic mechanism of LUSC. Taking Xintai City, a typical mining city in China, as an example, we analyzed the characteristics of LUSC evolution from 2000 to 2020 and explored the impact mechanism of LUSC by using the SEM model. Results show that the high risk of LUSC in mining cities is clustered in mining-city intertwined zones, and the growth rate of LUSC risk increases significantly with the transition period. The dynamic mechanisms of LUSC in mining cities are mutually driven by natural and anthropogenic factors and are dominated by anthropogenic factors. On the impact pathway, ecological environment, socio-economic environment, and resource extraction have stable and significant direct effects on LUSC. With improvements in technology and policy, the constraints on land use imposed by the natural environment have gradually decreased, and the impacts on LUSC are mostly indirect. This study proposes a research framework for the dynamic mechanism of LUSC in mining cities to provide theoretical guidance and suggestions for promoting urban transformation and development.
随着资源的开采和转型发展,土地利用空间冲突对矿业城市发展的阻碍作用显著,凸显了探索土地利用空间冲突的动力机制对矿业城市可持续发展的重要性。本研究整合了LUSC的多维属性,构建了基于“要素-模式-效应”的LUSC评价框架,并对LUSC的动力机制提出了理论假设。以中国典型矿业城市新泰市为例,运用SEM模型分析了2000 - 2020年新泰市土地资源承载力的演化特征,探讨了土地资源承载力的影响机制。结果表明:矿业城市水土流失风险高发区集聚在矿城交织区,且随着过渡期的过渡,水土流失风险增长率显著提高;矿业城市土地利用变化的动力机制受自然和人为因素的共同驱动,并以人为因素为主。在影响路径上,生态环境、社会经济环境和资源开采对水土保持具有稳定而显著的直接影响。随着技术和政策的进步,自然环境对土地利用的制约逐渐减弱,对土地利用的影响多为间接影响。本研究提出了矿业城市土地利用效益动态机制的研究框架,为促进城市转型发展提供理论指导和建议。
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引用次数: 0
Public water risk concerns triggered by energy-transition-mineral mining 能源转型矿产开采引发的公共水风险担忧
IF 12.4 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-02-06 DOI: 10.1016/j.resenv.2025.100196
Zipeng Lin , Peng Wang , Linbin Tang , Zilin Wang , Jon Mckechnie , Bo Li , Wei-Qiang Chen , Faith Ka Shun Chan
The intensifying demand for energy transition minerals (ETMs) has triggered global concern over water-related issues in mining regions. However, localized and generalizable metrics are lacking to help companies and governments manage social licenses to operate (SLO). In this study, we propose an analytical method that combines digital media data from the Global Database of Events, Language, and Tone (GDELT) with high-resolution mining data to analyze social awareness. LightGBM with Shapley additive explanations models are introduced to uncover key factors influencing public sentiment. This approach was applied to analyze media attention and public sentiment on five categories of water issues across 12 mineral types and 511 mines from 2016 to 2023. Our findings show a 40% increase in water-related events linked to ETM mining since 2020. Regions such as East and Southeast Asia, and Central and South America exhibit rising but negative sentiment, while public discontent in Southern Africa remains consistently high. Cobalt, platinum, and vanadium have the most negative sentiment, particularly concerning water quality and pollution. Manganese shows the most negative sentiment due to concerns over drought and desertification. Model results indicate that the Goldstein scale of events, which reflects the magnitude of cooperation or conflict, was the most influential factor in shaping public sentiment. Precipitation has a significant positive impact on sentiment in drought- and flood-related events, while higher runoff improved sentiment in drought events but negatively affected flood- and water quality-related events. Socio-economic factors, such as educational expenditure and unemployment rates, also demonstrated varied effects across categories. Finally, this study introduces the water sentiment index (WSI) as a proxy for water-related SLO concerns, offering a new tool to track social awareness in ETM regions and providing actionable insights for policymakers and stakeholders to mitigate social risks and ensure sustainable mining practices.
对能源转型矿物的需求日益增加,引起了全球对矿区水相关问题的关注。然而,缺乏本地化和通用的指标来帮助公司和政府管理社会运营许可证(SLO)。在这项研究中,我们提出了一种分析方法,将来自全球事件、语言和语气数据库(GDELT)的数字媒体数据与高分辨率挖掘数据相结合,以分析社会意识。引入LightGBM和Shapley加性解释模型,揭示影响公众情绪的关键因素。运用该方法分析了2016 - 2023年12种矿产类型、511个矿山对5类水问题的媒体关注度和公众情绪。我们的研究结果显示,自2020年以来,与ETM采矿有关的水相关事件增加了40%。东亚和东南亚以及中南美洲等地区的负面情绪有所上升,而南部非洲的公众不满情绪仍居高不下。钴、铂和钒的负面情绪最为强烈,尤其是在水质和污染方面。由于对干旱和沙漠化的担忧,锰表现出最负面的情绪。模型结果表明,反映合作或冲突程度的戈尔茨坦事件规模是影响公众情绪的最重要因素。降水对干旱和洪水相关事件的情绪有显著的积极影响,而较高的径流改善了干旱事件的情绪,但对洪水和水质相关事件产生了负面影响。社会经济因素,如教育支出和失业率,也显示出不同类别的影响。最后,本研究引入了水情绪指数(WSI)作为与水相关的SLO关注的代理,为跟踪ETM地区的社会意识提供了一种新工具,并为政策制定者和利益相关者提供了可操作的见解,以减轻社会风险并确保可持续的采矿实践。
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引用次数: 0
Electric-field-induced assists in the preferential extraction of lithium from spent LiFePO4 电场诱导有利于从废LiFePO4中优先提取锂
IF 12.4 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-02-06 DOI: 10.1016/j.resenv.2025.100198
Shangpei Yong, Yan Lin
Due to the advantages of high energy density, high conversion efficiency, and rapid response speed associated with power lithium batteries, there has been a significant expansion in their use. However, industry forecasts indicate that if large quantities of waste lithium-ion batteries are not managed properly, it could lead to serious environmental pollution issues as these batteries reach the end of their life cycle. Therefore, developing highly efficient and environmentally friendly recycling technologies is urgently needed. This paper proposes a green and efficient selective lithium extraction process integrating leaching technology with electrochemical methods. This approach enables the separation of Li and FePO4 within an electrolyte through electric field assistance while effectively minimizing waste liquid generation. The effects of various factors on Li and Fe’s leaching rates were investigated using orthogonal and single factor experiments. Under optimal conditions, the leaching rate of Li reached 98.85%, while that for Fe was only 0.22%, resulting in a selectivity ratio (Li/Fe) of 99.78%, which demonstrates successful selective extraction of lithium. Furthermore, we assessed the feasibility of this experiment through potentiometric-pH diagrams. We elucidated its mechanism using XPS, XRD, and SEM. Unlike conventional destructive leaching methods, the Li extraction process facilitated by the electric-field-induced assistance resembles the charging process of LiFePO4 batteries. Ultimately, Li was recovered as Li2CO3, while Fe and P present in the slag were subsequently retrieved as FePO4 with battery-grade purity through a hydrothermal method. This study presents an environmentally sustainable and economically viable approach for recovering spent LiFePO4 batteries.
由于动力锂电池具有能量密度高、转换效率高、响应速度快等优点,其应用得到了显著的扩展。但是,业界预测,如果对大量废弃锂离子电池管理不当,可能会导致严重的环境污染问题,因为这些电池将达到其生命周期的终点。因此,迫切需要开发高效环保的回收技术。本文提出了一种将浸出技术与电化学技术相结合的绿色高效的选择性提锂工艺。这种方法可以通过电场辅助在电解质中分离Li和FePO4,同时有效地减少废液的产生。采用正交试验和单因素试验研究了各因素对锂、铁浸出率的影响。在最优条件下,锂的浸出率可达98.85%,而铁的浸出率仅为0.22%,选择性比(Li/Fe)为99.78%,表明锂的选择性提取成功。此外,我们通过电位- ph图评估了该实验的可行性。利用XPS、XRD、SEM等手段对其机理进行了分析。与传统的破坏性浸出方法不同,电场诱导辅助下的锂提取过程类似于LiFePO4电池的充电过程。最终,Li被回收为Li2CO3,而存在于炉渣中的Fe和P随后通过水热法回收为电池级纯度的FePO4。本研究提出了一种环境可持续和经济可行的回收废旧磷酸铁锂电池的方法。
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引用次数: 0
Comprehensive reviews on technological and life cycle environmental aspects of solar–thermal adsorption refrigerator 太阳能热吸附式制冷机技术及全生命周期环境研究综述
IF 12.4 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-02-06 DOI: 10.1016/j.resenv.2025.100195
Jun-Ki Choi , Anup Paudel , Bipin Karki , Katie Bradley , Natalie Quinn , Amy Ciric
Refrigeration has significantly enhanced human well-being but comes with notable environmental impacts, particularly due to ozone-depleting substances and hydrofluorocarbons with high global warming potential. Solar Thermal Adsorption Refrigeration (STAR) has emerged as a promising alternative, especially in rural and off-grid regions where conventional refrigeration systems face energy limitations. This paper provides a comprehensive review of recent advancements in adsorption refrigeration technologies, including novel adsorbents like activated carbon–ethanol, metal–organic frameworks (MOFs), and composite materials designed to overcome critical challenges in heat and mass transfer. A particular emphasis is placed on the size limitations of adsorbers and the thermal efficiency of working pairs. Additionally, we critically analyze the life cycle environmental impacts of adsorption refrigeration systems, evaluating their sustainability compared to conventional vapor compression technologies. Unlike previous reviews, this paper integrates both technological developments and life cycle assessments, offering a unique perspective on STAR’s viability for sustainable refrigeration solutions. Finally, we present two novel bench-scale STAR systems, compare their environmental performance to traditional systems, and highlight key design improvements that address scalability challenges.
制冷大大提高了人类的福祉,但也带来了显著的环境影响,特别是由于臭氧消耗物质和具有高全球变暖潜力的氢氟碳化合物。太阳能热吸附制冷(STAR)已成为一种有前途的替代方案,特别是在农村和离网地区,传统制冷系统面临能源限制。本文综述了吸附式制冷技术的最新进展,包括活性炭-乙醇等新型吸附剂、金属-有机框架(mof)和复合材料,旨在克服传热传质方面的关键挑战。特别强调的是吸附剂的尺寸限制和工作对的热效率。此外,我们批判性地分析了吸附制冷系统的生命周期对环境的影响,与传统蒸汽压缩技术相比,评估了其可持续性。与之前的评论不同,本文整合了技术发展和生命周期评估,为STAR可持续制冷解决方案的可行性提供了独特的视角。最后,我们提出了两种新型的实验规模STAR系统,比较了它们与传统系统的环境性能,并强调了解决可扩展性挑战的关键设计改进。
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引用次数: 0
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Resources Environment and Sustainability
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