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Exploring agrosilvopastoral systems as pathways toward sustainable transitions in Italian egg production: evidence from farm accountability and consumers’ willingness to pay 探索农林业系统作为意大利鸡蛋生产可持续转型的途径:来自农场问责制和消费者支付意愿的证据
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-01-01 Epub Date: 2025-12-29 DOI: 10.1016/j.resenv.2025.100286
Emanuele Blasi , Eleonora Sofia Rossi , Lorenzo Fosci , Angelo Martella
Debates revolving around food systems sustainability and farming production efficiency often depict animal production as intensive farming practices that are resource-inefficient and environmentally harmful. Agroecological approaches that value virtuous combinations of plants and animals in mixed farming conditions may support a citizen's reconciliation with animal farming, better addressing sustainability and ethics of farming. The study assesses the feasibility of transitioning to more sustainable production models by analysing poultry farming in synergy with permanent and aromatic crops, facing challenges such as environmental impact and animal welfare. This research explores the adoption of AgroSilvoPastoral Systems (ASPS), that combine plants and animals, to increase animal welfare as well as biodiversity and to reduce negative externalities. The research involved an Italian laying hen organic farm as an empirical case study. By investigating how this change can be addressed and supported by both sides of the supply chain (production and market) this study aims at proposing a novel metric for socio-economic assessments of ASPS. A gross margin evaluation and a choice experiment were utilized to determine if the changes in structural costs for producers were offset by consumers' willingness to pay for products derived from these systems. The findings indicate that implementing ASPS in egg production at a large scale could lead to a competitive advantage in the market while also promoting sustainable and environmentally friendly practices. In addition, engaging farmers in the decision-making process through a participatory approach facilitate the adoption and more efficient management of these systems, enhancing the probability of success.
围绕粮食系统可持续性和农业生产效率的辩论往往将动物生产描述为资源效率低下且对环境有害的集约化农业实践。重视在混合农业条件下植物和动物的良性组合的农业生态方法可能支持公民与动物农业的和解,更好地解决农业的可持续性和道德问题。该研究通过分析面临环境影响和动物福利等挑战的家禽养殖与永久性和芳香作物的协同作用,评估了向更可持续的生产模式过渡的可行性。本研究探讨了采用农业-森林-畜牧业系统(ASPS),将植物和动物结合起来,以增加动物福利和生物多样性,并减少负面外部性。本研究以意大利一家蛋鸡有机农场为实证案例。通过调查供应链双方(生产和市场)如何应对和支持这一变化,本研究旨在为asp的社会经济评估提出一种新的指标。利用毛利率评估和选择实验来确定生产者结构性成本的变化是否被消费者支付这些系统衍生产品的意愿所抵消。研究结果表明,在鸡蛋生产中大规模实施ASPS可以在市场上获得竞争优势,同时还可以促进可持续和环境友好的做法。此外,通过参与式方法使农民参与决策过程有助于采用和更有效地管理这些系统,从而提高成功的可能性。
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引用次数: 0
Manure and bio-manure substitutions of chemical fertilizers mitigate long-term nitrous oxide emissions from vegetable production systems 有机肥和生物肥替代化肥可减少蔬菜生产系统长期排放的一氧化二氮
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-01-01 Epub Date: 2025-12-26 DOI: 10.1016/j.resenv.2025.100283
Qianqian Zhang , Linghui Liu , Gunina Anna , Pengpeng Duan , Yongchun Li , Scott X. Chang , Zhengqin Xiong
Substituting chemical fertilizers with manure or bio-manure (manure inoculated with microbes) offers a promising strategy to mitigate nitrous oxide (N2O) emissions, yet the underlying mechanisms remained unclear. Through a five-year field study employing isotopocule (δ15NSPN2O and δ18ON2O/H2O) mapping, we elucidated that a 50 % substitution with manure or bio-manure significantly decreased cumulative N2O emissions by suppressing production of nitrification- and nitrifier-denitrification- and heterotrophic denitrification (HD)-derived N2O, and promoted N2O reduction to N2 in denitrification. In contrast, 20 % substitutions failed to achieve sustained mitigation. Bio-manure initially exhibited stronger N2O mitigation than manure, but this mitigation effect disappeared over time due to a N2O production–consumption offsetting effect in HD. Specifically, relative to manure, bio-manure stimulated HD-driven N2O production in association with increasing abundances of HD-related genes (nirK, nirS, fungi-nirK) and potential denitrification rates. Bio-manure often maintained a higher capacity for N2O reduction, evidenced by lower (nirK + nirS + Fungi-nirK)/(nosZ) ratios and unreduced N2O fraction. Critically, substitutions enhanced crop yields, with manure increasing yields by 8–21 % and bio-manure by 19–30 % compared to conventional fertilizer. Consequently, our study revealed that 50 % bio-manure substitution is an effective strategy for mitigating N2O emissions and enhancing yields from vegetable production systems, providing actionable insights for sustainable resource management and climate change mitigation.
用粪肥或生物粪(接种了微生物的粪肥)代替化肥是一种很有前景的减少一氧化二氮(N2O)排放的策略,但潜在的机制尚不清楚。通过为期5年的同位素(δ15NSPN2O和δ18ON2O/H2O)作图,研究人员发现,用粪肥或生物粪肥替代50%,通过抑制硝化、硝化反硝化和异养反硝化(HD)衍生的N2O的产生,显著降低了N2O的累积排放,并促进了N2O在反硝化过程中还原为N2。相比之下,20%的替代未能实现持续的缓解。生物粪肥最初表现出比粪肥更强的N2O缓解效果,但随着时间的推移,由于HD中N2O生产-消耗抵消效应,这种缓解效果消失了。具体而言,相对于粪肥,生物粪通过增加hd相关基因(nirK, nirS,真菌-nirK)的丰度和潜在的反硝化速率来刺激hd驱动的N2O生成。生物粪肥通常保持较高的N2O还原能力,表现为较低的(nirK + nirS +真菌-nirK)/(nosZ)比率和未还原的N2O分数。重要的是,替代肥料提高了作物产量,与常规肥料相比,粪肥增产8 - 21%,生物粪增产19 - 30%。因此,我们的研究表明,50%的生物粪替代是减少N2O排放和提高蔬菜生产系统产量的有效策略,为可持续资源管理和减缓气候变化提供了可行的见解。
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引用次数: 0
Heavy metal transformation in livestock manure (co-)pyrolysis: pathways toward safe biochar and sustainable agriculture 畜禽粪便(共)热解中的重金属转化:通往安全生物炭和可持续农业的途径
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-01-01 Epub Date: 2025-12-26 DOI: 10.1016/j.resenv.2025.100284
Fengxiao Zhao , Hongyuan Chen , Danni Li , Dong Liang , Xianhai Zeng , Rui Shan , Haoran Yuan , Yong Chen
Livestock manure is enriched with heavy metals such as copper, zinc, and cadmium due to feed additives and intensive farming practices. Inadequate management can lead to soil accumulation, nutrient cycle disruption, and ecosystem risks. Pyrolysis, as a versatile thermochemical process, simultaneously enables pollutant control, energy recovery, nutrient recycling, and heavy metal stabilization. This review integrates mechanistic insights with sustainability-oriented evaluation, linking thermochemical transformations to agricultural applications and policy frameworks. We examine thermal-induced changes in heavy metal speciation and mobility, highlighting stabilization through encapsulation, complexation, and mineralization, while also critically assessing sequential extraction methods. The synergistic effects of co-pyrolysis and mineral additives are further discussed. By bridging molecular-scale mechanisms with sustainable resource management, this work provides a cross-disciplinary perspective to guide safe biochar reuse, integrated manure management, and broader sustainability goals.
由于饲料添加剂和集约化耕作方式,牲畜粪便富含铜、锌和镉等重金属。管理不当可能导致土壤积累、养分循环中断和生态系统风险。热解作为一种多功能的热化学过程,可以同时实现污染物控制、能量回收、养分循环和重金属稳定。这篇综述结合了机械的见解和面向可持续性的评价,将热化学转化与农业应用和政策框架联系起来。我们研究了热诱导的重金属形态和迁移的变化,强调了通过包封、络合和矿化的稳定,同时也严格评估了顺序提取方法。进一步讨论了共热解与矿物添加剂的协同作用。通过将分子尺度机制与可持续资源管理相结合,本研究为指导生物炭的安全再利用、粪便综合管理和更广泛的可持续发展目标提供了跨学科的视角。
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引用次数: 0
Toward a modular and integrated approach to lithium-ion battery recycling: from fragmentation to strategic research globalization 迈向锂离子电池回收的模块化和集成方法:从碎片化到战略研究全球化
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-01-01 Epub Date: 2026-01-12 DOI: 10.1016/j.resenv.2026.100294
Elza Bontempi
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引用次数: 0
Long–term application of agricultural amendments regulate the assembly of different bacterial sub–communities and growth of multi–species biofilms in paddy soils 长期施用农用改良剂可调节水稻土中不同细菌亚群落的聚集和多物种生物膜的生长
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-01-01 Epub Date: 2025-12-28 DOI: 10.1016/j.resenv.2025.100287
Sheng Zhao , Yi Wen , Hao Sheng , Junpeng Lou , Chuan Peng , Yu Jiang , Yuqing Tang , Shanpeng Liu , Kai Ouyang
Long–term agricultural amendments are widely employed to enhance soil quality and ecological sustainability. However, their effects on the assembly processes of bacterial sub–communities and on multispecies biofilm development remain poorly understood. In a seven–year field experiment, we investigated the impact of lime (L) and organic fertilizer (OF) amendments on the assembly mechanisms of abundant, moderate, and rare bacterial taxa in paddy soil, as well as on the formation and growth of multispecies biofilms. Our results demonstrated that both amendments significantly increased biofilm biomass, enhancing biofilm thickness by 0.72– to 1.33–fold, and shifted microbial niche adaptation. Assembly processes, assessed via the Normalized Stochasticity Ratio (NST), exhibited contrasting patterns among taxa: for the whole and rare bacterial communities, NST increased from 45.3 % to 68.9 % and from 48.3 % to 71.3 % under OF, and from 44.3 % to 55.7 % and from 47.8 % to 57.2 % under L, indicating a shift from deterministic toward stochastic process. In contrast, moderate taxa showed decreased stochasticity, with NST declining from 70.0 % to 43.2 % under OF and from 77.4 % to 58.3 % under L. Organic fertilization also enhanced soil multifunctionality by 2.37–fold and increased bacterial network complexity by 77 %. Soil pH was identified as the key driver governing both bacterial community assembly and multispecies biofilm growth. These findings provide novel insights into how long–term agricultural amendments modulate biofilm dynamics and bacterial assembly processes in soil ecosystems.
长期农业改良剂被广泛用于提高土壤质量和生态可持续性。然而,它们对细菌亚群落组装过程和多物种生物膜发育的影响仍然知之甚少。通过为期7年的田间试验,研究了石灰和有机肥对水稻土中丰富、中等和稀有细菌类群聚集机制的影响,以及对多物种生物膜形成和生长的影响。结果表明,这两种改性剂均显著增加了生物膜生物量,使生物膜厚度增加了0.72 ~ 1.33倍,并改变了微生物生态位适应。通过归一化随机比(NST)评估,不同分类群的组装过程呈现出不同的模式:对于整个和稀有细菌群落,在OF下,NST从45.3%增加到68.9%和48.3%增加到71.3%,在L下,NST从44.3%增加到55.7%和47.8%增加到57.2%,表明由确定性过程向随机过程转变。有机肥处理下,土壤的NST从70.0%下降到43.2%,从77.4%下降到58.3%;有机肥处理下,土壤的多功能性提高了2.37倍,细菌网络复杂性提高了77%。土壤pH被认为是控制细菌群落聚集和多物种生物膜生长的关键驱动因素。这些发现为长期农业改良剂如何调节土壤生态系统中的生物膜动力学和细菌组装过程提供了新的见解。
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引用次数: 0
Spatio-temporal exposure of photovoltaic farms to typhoon disasters for sustainable development in China's Coastal Regions 中国沿海地区光伏电站对台风灾害的时空暴露及其可持续发展
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-01 Epub Date: 2025-09-20 DOI: 10.1016/j.resenv.2025.100272
Luguang Jiang , Ye Liu , Liwen Yang , Huixia Zhao
The climate-adaptive solar energy planning contributes directly to the United Nations Sustainable Development Goals 7 and 13. The juxtaposition of China's leadership in global PV expansion and the escalating climate risks in its coastal regions underscores the importance of aligning PV layout with risk mitigation. This study utilizes Landsat imagery to analyze the spatiotemporal changes of PV distribution in China's coastal regions, and assesses the effect of typhoon disasters to PV. Key findings reveal that by the end of 2023, the total PV area in coastal regions reached approximately 1962.89 ​km2. Notably, provinces north of the Yangtze River hosted more than twice the PV area of those to the south. Rapid expansion began post-2015, with PV area more than doubling between 2020 and 2023. From a disaster risk perspective, about 20 ​% of China's coastal land area faces high typhoon risk, with 16 ​% of existing PV area located in high-risk regions. The East China Sea and South China Sea coasts exhibit the highest concentration of extreme-risk regions. Encouragingly, 82.15 ​% of recent PV expansion occurred in low-to-medium-risk regions, indicating that current layout strategies already account for typhoon threats. Looking ahead, the Bohai Sea coast, Yellow Sea coast, and coasts near the Nansha Islands present relatively low risk, making them preferable for future offshore PV projects. In contrast, the East and South China Sea coasts remain high-risk regions, necessitating cautious planning for offshore PV development.
气候适应性太阳能规划直接有助于实现联合国可持续发展目标7和13。中国在全球光伏扩张方面处于领先地位,而沿海地区气候风险不断升级,这两者并存,凸显了将光伏布局与风险缓解相结合的重要性。利用陆地卫星影像分析了中国沿海地区PV分布的时空变化,并评估了台风灾害对PV的影响。重点研究结果表明,到2023年底,沿海地区光伏总面积约为1962.89 km2。值得注意的是,长江以北省份的光伏面积是长江以南省份的两倍多。2015年后开始快速扩张,光伏面积在2020年至2023年间增长了一倍以上。从灾害风险的角度来看,中国约20%的沿海陆地面积面临台风高风险,16%的现有光伏面积位于高风险地区。东海和南海是极端风险区最集中的地区。令人鼓舞的是,最近82.15%的光伏扩张发生在低至中等风险地区,这表明目前的布局策略已经考虑到了台风的威胁。展望未来,渤海沿岸、黄海沿岸和南沙群岛附近沿海风险相对较低,是未来海上光伏项目的首选。相比之下,东海和南海沿岸仍然是高风险地区,需要谨慎规划海上光伏发展。
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引用次数: 0
From waste to worth: Biochar and hemp fiber synergy for carbon-sequestering and durable recycled aggregate concrete 从废物到价值:生物炭和大麻纤维协同碳封存和耐用的再生骨料混凝土
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-01 Epub Date: 2025-08-30 DOI: 10.1016/j.resenv.2025.100265
Huanyu Li , Ning Zhang , Jian Yang , Brilliantika Fusi Nur Rahmasari , Yuhang Du , Lei Wang
Recycled aggregate concrete is prone to significant drying shrinkage, which hinders its broader adoption and the sustainable recycling of construction and demolition waste. This study presents a novel internal curing strategy using activated coconut biochar (10%–30%) and hemp fiber (10–30 mm) to simultaneously address shrinkage and strength deficits. Experimental findings demonstrate that mix-sized biochar improves both the fresh and hardened properties of the concrete when compared to using small or large biochar particles alone. Notably, while the incorporation of biochar reduces fluidity due to water absorption and increased inter-particle friction, both flexural and compressive strengths were enhanced – by up to 34% and 28%, respectively – with increasing biochar content and fiber length, as a result of matrix densification and fiber-bridging effects. The synergy between biochar and hemp fibers facilitates internal curing by lowering the local water–cement ratio during hardening and promoting cement hydration through both internal curing and nucleation effects. Despite a rapid early-stage increase in drying shrinkage, the combined addition of biochar and hemp fiber ultimately achieves a remarkable reduction of up to 96%. Furthermore, increasing biochar dosage and fiber length enhances matrix compactness, substantially reducing water absorption. This, in turn, improves resistance to chloride penetration by obstructing ion transport pathways. Concrete modified with 30% biochar and 30 mm-long hemp fibers demonstrates significant potential for carbon emission reduction, achieving decreases of 4.4 kg CO2 eq./m3/MPa in compressive scenario and 23.8 kg CO2 eq./m3/MPa in flexural scenario. Overall, this study advances the understanding of shrinkage mitigation mechanisms and offers a scalable pathway for the development of high-performance, low-carbon recycled aggregate concrete.
再生骨料混凝土容易出现显著的干燥收缩,这阻碍了其更广泛的采用和建筑和拆除废物的可持续回收。本研究提出了一种新的内部固化策略,使用活性椰子生物炭(10%-30%)和大麻纤维(10-30毫米)同时解决收缩和强度缺陷。实验结果表明,与单独使用小颗粒或大颗粒生物炭相比,混合尺寸的生物炭改善了混凝土的新鲜和硬化性能。值得注意的是,虽然生物炭的掺入由于吸水和颗粒间摩擦的增加而降低了流动性,但由于基质致密化和纤维桥接效应,随着生物炭含量和纤维长度的增加,抗弯和抗压强度分别提高了34%和28%。生物炭和大麻纤维之间的协同作用通过降低硬化过程中局部水灰比促进水泥内部固化,并通过内部固化和成核作用促进水泥水化。尽管在干燥收缩的快速早期阶段增加,生物炭和大麻纤维的组合添加最终实现了显著的减少高达96%。此外,增加生物炭用量和纤维长度可提高基质密实度,大幅降低吸水率。这反过来又通过阻碍离子传输途径提高了对氯离子渗透的抵抗力。30%生物炭和30mm长的大麻纤维改性混凝土具有显著的碳减排潜力,在压缩情况下减少4.4 kg CO2当量/m3/MPa,在弯曲情况下减少23.8 kg CO2当量/m3/MPa。总的来说,这项研究促进了对收缩减缓机制的理解,并为高性能、低碳再生骨料混凝土的发展提供了一条可扩展的途径。
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引用次数: 0
Co-fermentation of broccoli waste with distillers dried grains with solubles and cornmeal: Focusing on variations in fermentation profile and bacterial community 花椰菜废弃物与酒糟、干谷物、可溶物和玉米粉共发酵:重点研究发酵剖面和细菌群落的变化
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-01 Epub Date: 2025-09-10 DOI: 10.1016/j.resenv.2025.100267
Lili Wang , Chongpeng Bi , Jingkai Liu , Chi Ma , Sujiang Zhang , Qingwei Meng , Anshan Shan
Anaerobic fermentation of broccoli waste is constrained by its high moisture content, necessitating co-fermentation with absorbent co-substrates to achieve sustainable feed conversion and reduce environmental pollution. Therefore, this study investigated how various substrates affect broccoli waste fermentation, with a focus on the fermentation profile and bacterial community. Specifically, the fermentation quality, protein content, and bacterial community were evaluated in broccoli waste co-fermented with distillers dried grains with solubles (DDGS) or cornmeal at dry matter levels of 250–450 g/kg (adjusted by mass ratios). Notably, co-fermentation significantly (P < 0.05) decreased the pH value and nonprotein-N and ammonia-N contents and inhibited effluent formation. Co-fermentation with DDGS significantly decreased (P < 0.05) the nonprotein-N and ammonia-N contents compared with the cornmeal co-fermentation group. The highest lactic acid content was achieved in the DS5 (83.4% broccoli waste and 16.6% DDGS) group. Additionally, co-fermentation with DDGS decreased the diversity of bacteria and abundance of undesirable microorganisms and increased the abundance of specialist Lactobacillaceae. Notably, Lactobacillus plantarum was the dominant microbial biomarker in the DS5 treatment group. Moreover, co-fermentation reduced the complexity of bacterial co-occurrence networks but increased their modularity and competing interactions. Co-fermentation upregulated the carbohydrate and amino acid metabolic pathways, with the DS5 treatment exhibiting the highest relative abundance of L-lactate dehydrogenase. Leuconostoc and Lactococcus were identified as key bacteria in the DDGS-mediated downregulation of protein hydrolysis and upregulation of lactic acid production, respectively. Conclusively, the DS5 treatment improved the clean recycling of broccoli waste, correlating with optimized endpoint bacterial community properties.
西兰花废弃物的厌氧发酵受到其高含水量的限制,需要与吸附性共底物共发酵,以实现可持续的饲料转化,减少环境污染。因此,本研究研究了不同基质对西兰花废物发酵的影响,重点研究了发酵特征和细菌群落。在干物质水平为250 ~ 450 g/kg(按质量比调整)的条件下,对花椰菜废渣与酒糟和可溶物(DDGS)或玉米粉共发酵的发酵品质、蛋白质含量和细菌群落进行了评价。值得注意的是,共发酵显著(P < 0.05)降低了pH值、非蛋白氮和氨氮含量,抑制了出水的形成。与玉米粉共发酵组相比,DDGS共发酵显著降低了非蛋白氮和氨氮含量(P < 0.05)。乳酸含量最高的是DS5组(西兰花废料83.4%,DDGS 16.6%)。此外,与DDGS共发酵减少了细菌的多样性和不良微生物的丰度,增加了专业乳酸杆菌科的丰度。值得注意的是,植物乳杆菌是DS5治疗组的主要微生物生物标志物。此外,共发酵降低了细菌共发生网络的复杂性,但增加了它们的模块化和竞争相互作用。共发酵上调了碳水化合物和氨基酸代谢途径,其中DS5处理的l -乳酸脱氢酶相对丰度最高。Leuconostoc和Lactococcus分别被鉴定为ddgs介导的蛋白水解下调和乳酸生成上调的关键菌。综上所述,DS5处理提高了西兰花废弃物的清洁回收,并与优化的终点细菌群落特性相关。
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引用次数: 0
A novel hydrolase biomanufacturing-driven strategy for boosting production of volatile fatty acids and vivianite in iron-rich waste activated sludge fermentation 一种新的水解酶生物制造驱动策略在富铁废物活性污泥发酵中促进挥发性脂肪酸和活菌石的生产
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-01 Epub Date: 2025-08-30 DOI: 10.1016/j.resenv.2025.100264
Xiaodong Xin , Linjuan Li , Boyu Lu , Lei Liu , Liguo Zhang , Yue Yang , Wei Li , Qian Liu , Junguo He , Ganfeng He , Sihao Lv , Wangwang Yan , Liwen Luo
Efficient sludge pretreatment methods that minimize reliance on costly chemical or energy inputs have garnered significant attention, as waste-activated sludge (WAS) disposal occupied nearly 50% of operational expenses in wastewater treatment plants (WWTPs) which displayed a poor sustainability in current practices. In this study, a novel strategy utilizing bio-manufactured hydrolases (primarily protease and α-amylase, produced by Aspergillus oryzae based on waste molasses cultivation) was proposed to enhance the solubilization of iron-rich WAS by releasing biodegradable organic matters [a net soluble chemical oxygen demand (COD) of 840 ± 14 mg/L release after 8 h] and disrupting extracellular polymeric substances (EPS) via loosing EPS proteins structure and increase hydrophilicity. The volatile fatty acids (VFAs) production reached a peak level of 4380 ± 24.6 mg COD/L, accompanied by an optimal orthophosphate release of 7.79 ± 0.31 mg/L through fermentation enhanced by such enzymatic pretreatment. Moreover, the relative fraction of P in vivianite, assessed as non-apatite inorganic phosphorous (NAIP), increased by 10.12%. The bio-manufactured hydrolases not only enhanced overall microbial diversity, but also enriched key microbial populations—including​ hydrolyzing bacteria (e.g. Chloroflexi and Actinobacteria), major acidogens (e.g. Petrimonas, Jeotgalibaca, Proteiniclasticum, and Macellibacteroides), and iron-reducing genera (i.e. Ercella and Desulfovibrio). Furthermore, this strategy upregulated the relative abundance of functional genes related to carbohydrate and amino acid metabolism, and reduced the competitive interference of Ca2+ ions on soluble phosphorus availability by favoring Fe(II)-P complexation, thereby synergistically enhancing VFAs production and vivianite formation. This study presents an efficient, economically favorable pretreatment strategy to enhance the recovery of carbon (C) and phosphorus (P) from iron-rich WAS, with demonstrating a strong application sustainability.
有效的污泥预处理方法,最大限度地减少了对昂贵的化学或能源投入的依赖,已经引起了人们的极大关注,因为废物活性污泥(WAS)处理占据了废水处理厂(WWTPs)近50%的运营费用,在目前的实践中表现出较差的可持续性。本研究提出了一种利用生物水解酶(主要是蛋白酶和α-淀粉酶,由米曲霉在废糖蜜培养基础上产生)的新策略,通过释放可生物降解的有机物[8 h后释放840±14 mg/L的净可溶性化学需氧量(COD)]和通过破坏细胞外聚合物(EPS)蛋白结构和增加亲水性来增强富铁was的增溶性。经酶促发酵,挥发性脂肪酸(VFAs)的峰值COD为4380±24.6 mg/L,正磷酸盐的最佳释放量为7.79±0.31 mg/L。磷灰石中磷的相对含量为非磷灰石无机磷(NAIP),增加了10.12%。生物制造的水解酶不仅增强了总体微生物多样性,而且丰富了关键微生物种群,包括水解细菌(如氯氟菌和放线菌)、主要酸化菌(如petronas、Jeotgalibaca、Proteiniclasticum和Macellibacteroides)和铁还原属(如Ercella和Desulfovibrio)。此外,该策略上调了与碳水化合物和氨基酸代谢相关的功能基因的相对丰度,并通过有利于Fe(II)-P络合减少Ca2+离子对可溶性磷有效性的竞争性干扰,从而协同促进VFAs的产生和活菌体的形成。本研究提出了一种高效、经济的预处理策略,可提高富铁WAS中碳(C)和磷(P)的回收率,并具有较强的应用可持续性。
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引用次数: 0
Interfacial oxygen nanobubble for mitigating the methane emissions from aquatic ecosystems: A review 界面氧纳米泡减少水生生态系统甲烷排放的研究进展
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-01 Epub Date: 2025-08-06 DOI: 10.1016/j.resenv.2025.100256
Qingnan Chu , Xiangyu Liu , Detian Li , Shuai Yin , Ping He , Wenjuan Li , Chengrong Chen , Zhimin Sha
Methane (CH4) emissions from aquatic ecosystems, including wetlands, freshwater bodies, and rice paddies, contribute significantly to global warming due to CH4’s high global warming potential. Traditional CH4 mitigation strategies, such as mechanical aeration, sediment capping, and vegetation management, face challenges related to high costs, inefficiency in oxygen delivery, and ecological disturbances. In recent years, interfacial oxygen nanobubbles (IONBs) have emerged as a promising geoengineering solution for reducing CH4 emissions by providing sustained oxygenation in anoxic sediments. Unlike conventional methods, IONBs exhibit high stability, prolonged oxygen retention, and slow, controlled oxygen release, reducing the need for frequent re-application. This sustained oxygenation creates long-lasting aerobic microenvironments that suppress methanogenesis while stimulating methanotrophic CH4 oxidation. Furthermore, IONB-loaded carriers, such as biochars and zeolites, enable targeted oxygenation, improving redox conditions and promoting beneficial microbial shifts. Compared to mechanical aeration, which rapidly dissipates oxygen, or chemical amendments requiring repeated treatments, IONBs provide a low-maintenance, cost-effective alternative with minimal ecological disruption. This review explores the physicochemical properties of IONBs, their mechanisms of action in altering sedimentary biogeochemical processes, and their potential applications in mitigating CH4 flux from different aquatic ecosystems. Despite their potential, challenges remain in optimizing oxygen-loading capacity, assessing long-term ecological impacts, and scaling up production. Future research should focus on refining the oxygen-loading capacity of IONBs, integrating them with existing mitigation approaches, and evaluating their role in global climate policies. As an innovative and sustainable tool, IONBs hold great promise for advancing wetland conservation, reducing agricultural CH4 emissions, and climate change mitigation efforts.
湿地、淡水水体和稻田等水生生态系统的甲烷(CH4)排放具有较高的全球变暖潜势,对全球变暖有重要贡献。传统的CH4缓解策略,如机械曝气、沉积物封顶和植被管理,面临着与成本高、氧气输送效率低和生态干扰相关的挑战。近年来,界面氧纳米气泡(IONBs)已成为一种有前途的地球工程解决方案,通过在缺氧沉积物中提供持续的氧化来减少CH4的排放。与传统方法不同,ionb具有高稳定性、长时间的氧保留和缓慢、可控的氧释放,减少了频繁重新应用的需要。这种持续的氧化创造了持久的有氧微环境,抑制甲烷生成,同时刺激甲烷营养化CH4氧化。此外,离子b负载载体,如生物炭和沸石,可以实现靶向氧化,改善氧化还原条件,促进有益微生物的转移。与快速耗散氧气的机械曝气或需要重复处理的化学修正相比,ionb提供了一种维护成本低、成本效益高的替代方案,对生态的破坏最小。本文综述了ionb的物理化学性质、改变沉积生物地球化学过程的作用机制及其在减少不同水生生态系统CH4通量方面的潜在应用。尽管具有潜力,但在优化氧负荷能力、评估长期生态影响和扩大生产方面仍存在挑战。未来的研究应侧重于改进ionb的载氧能力,将其与现有的减缓方法相结合,并评估其在全球气候政策中的作用。作为一种创新和可持续的工具,ionb在促进湿地保护、减少农业甲烷排放和减缓气候变化方面前景广阔。
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Resources Environment and Sustainability
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