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Landscape perforation in life cycle assessment: Method development with global application to quarries and mines 生命周期评价中的景观射孔:采石场和矿山全球应用方法开发
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-01-01 DOI: 10.1016/j.resenv.2026.100293
Carla R.V. Coelho , Jan P. Lindner , Ottar Michelsen , Henrik G. Smith
Human appropriation of land reduces the quality and continuity of remaining natural habitat, affecting species fecundity, survival, and movements, which must be accounted for in impact assessments. Effective decision-making for sustainable land-use and resource extraction requires methods that represent the ecological impacts of human activities on surrounding landscapes. We propose a method that draws on the concept of landscape perforation, treats the land use in focus as the non-habitat, and quantifies adjacent human pressures by adapting the Human Footprint Index. The method aligns with the contention that disturbances in otherwise intact landscapes result in disproportionate ecological effects. We used a conservative intersection (algebraic product t-norm from fuzzy logic) to model the relationship between pressures that modify and those that do not. Inspired by landscape ecology's relative importance of spatial process to land transformation, we assumed a negatively sloped logistic function for pressures that modify the land cover, and a negative linear relationship for pressures that do not modify land cover. The index was applied to 102,646 quarries and mines, sourced from OpenStreetMap, quantifying their perforation potential. Developed in the context of life cycle assessment to quantify potential impacts of supply chains, a case study of steel illustrates its application from a product perspective. The method supports a proactive approach by equipping decision-makers with one more layer of information regarding “what is around” a land use. Globally applicable, it emphasizes transdisciplinary solutions for sustainable production, environmental stress assessment, and strategic resource planning with a spatially explicit component.
人类占用土地降低了剩余自然栖息地的质量和连续性,影响了物种的繁殖力、生存和迁徙,这些都必须在影响评估中加以考虑。可持续土地利用和资源开采的有效决策需要反映人类活动对周围景观的生态影响的方法。我们提出了一种方法,利用景观穿孔的概念,将重点土地利用视为非栖息地,并通过适应人类足迹指数来量化邻近的人类压力。该方法与这样一种观点一致,即对原本完好无损的景观的干扰会导致不成比例的生态影响。我们使用一个保守的交集(模糊逻辑的代数乘积t-范数)来模拟改变压力和不改变压力之间的关系。受景观生态学空间过程对土地转化的相对重要性的启发,我们假设改变土地覆盖的压力为负斜率逻辑函数,而不改变土地覆盖的压力为负线性关系。该指数应用于来自OpenStreetMap的102,646个采石场和矿山,量化了它们的射孔潜力。在生命周期评估的背景下开发,以量化供应链的潜在影响,钢铁的案例研究从产品的角度说明了它的应用。该方法通过为决策者提供关于土地使用“周围情况”的多一层信息,支持了一种积极主动的方法。它在全球范围内适用,强调可持续生产、环境压力评估和具有空间明确成分的战略资源规划的跨学科解决方案。
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引用次数: 0
Exploring agrosilvopastoral systems as pathways toward sustainable transitions in Italian egg production: evidence from farm accountability and consumers’ willingness to pay 探索农林业系统作为意大利鸡蛋生产可持续转型的途径:来自农场问责制和消费者支付意愿的证据
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-01-01 DOI: 10.1016/j.resenv.2025.100286
Emanuele Blasi , Eleonora Sofia Rossi , Lorenzo Fosci , Angelo Martella
Debates revolving around food systems sustainability and farming production efficiency often depict animal production as intensive farming practices that are resource-inefficient and environmentally harmful. Agroecological approaches that value virtuous combinations of plants and animals in mixed farming conditions may support a citizen's reconciliation with animal farming, better addressing sustainability and ethics of farming. The study assesses the feasibility of transitioning to more sustainable production models by analysing poultry farming in synergy with permanent and aromatic crops, facing challenges such as environmental impact and animal welfare. This research explores the adoption of AgroSilvoPastoral Systems (ASPS), that combine plants and animals, to increase animal welfare as well as biodiversity and to reduce negative externalities. The research involved an Italian laying hen organic farm as an empirical case study. By investigating how this change can be addressed and supported by both sides of the supply chain (production and market) this study aims at proposing a novel metric for socio-economic assessments of ASPS. A gross margin evaluation and a choice experiment were utilized to determine if the changes in structural costs for producers were offset by consumers' willingness to pay for products derived from these systems. The findings indicate that implementing ASPS in egg production at a large scale could lead to a competitive advantage in the market while also promoting sustainable and environmentally friendly practices. In addition, engaging farmers in the decision-making process through a participatory approach facilitate the adoption and more efficient management of these systems, enhancing the probability of success.
围绕粮食系统可持续性和农业生产效率的辩论往往将动物生产描述为资源效率低下且对环境有害的集约化农业实践。重视在混合农业条件下植物和动物的良性组合的农业生态方法可能支持公民与动物农业的和解,更好地解决农业的可持续性和道德问题。该研究通过分析面临环境影响和动物福利等挑战的家禽养殖与永久性和芳香作物的协同作用,评估了向更可持续的生产模式过渡的可行性。本研究探讨了采用农业-森林-畜牧业系统(ASPS),将植物和动物结合起来,以增加动物福利和生物多样性,并减少负面外部性。本研究以意大利一家蛋鸡有机农场为实证案例。通过调查供应链双方(生产和市场)如何应对和支持这一变化,本研究旨在为asp的社会经济评估提出一种新的指标。利用毛利率评估和选择实验来确定生产者结构性成本的变化是否被消费者支付这些系统衍生产品的意愿所抵消。研究结果表明,在鸡蛋生产中大规模实施ASPS可以在市场上获得竞争优势,同时还可以促进可持续和环境友好的做法。此外,通过参与式方法使农民参与决策过程有助于采用和更有效地管理这些系统,从而提高成功的可能性。
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引用次数: 0
Manure and bio-manure substitutions of chemical fertilizers mitigate long-term nitrous oxide emissions from vegetable production systems 有机肥和生物肥替代化肥可减少蔬菜生产系统长期排放的一氧化二氮
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-01-01 DOI: 10.1016/j.resenv.2025.100283
Qianqian Zhang , Linghui Liu , Gunina Anna , Pengpeng Duan , Yongchun Li , Scott X. Chang , Zhengqin Xiong
Substituting chemical fertilizers with manure or bio-manure (manure inoculated with microbes) offers a promising strategy to mitigate nitrous oxide (N2O) emissions, yet the underlying mechanisms remained unclear. Through a five-year field study employing isotopocule (δ15NSPN2O and δ18ON2O/H2O) mapping, we elucidated that a 50 % substitution with manure or bio-manure significantly decreased cumulative N2O emissions by suppressing production of nitrification- and nitrifier-denitrification- and heterotrophic denitrification (HD)-derived N2O, and promoted N2O reduction to N2 in denitrification. In contrast, 20 % substitutions failed to achieve sustained mitigation. Bio-manure initially exhibited stronger N2O mitigation than manure, but this mitigation effect disappeared over time due to a N2O production–consumption offsetting effect in HD. Specifically, relative to manure, bio-manure stimulated HD-driven N2O production in association with increasing abundances of HD-related genes (nirK, nirS, fungi-nirK) and potential denitrification rates. Bio-manure often maintained a higher capacity for N2O reduction, evidenced by lower (nirK + nirS + Fungi-nirK)/(nosZ) ratios and unreduced N2O fraction. Critically, substitutions enhanced crop yields, with manure increasing yields by 8–21 % and bio-manure by 19–30 % compared to conventional fertilizer. Consequently, our study revealed that 50 % bio-manure substitution is an effective strategy for mitigating N2O emissions and enhancing yields from vegetable production systems, providing actionable insights for sustainable resource management and climate change mitigation.
用粪肥或生物粪(接种了微生物的粪肥)代替化肥是一种很有前景的减少一氧化二氮(N2O)排放的策略,但潜在的机制尚不清楚。通过为期5年的同位素(δ15NSPN2O和δ18ON2O/H2O)作图,研究人员发现,用粪肥或生物粪肥替代50%,通过抑制硝化、硝化反硝化和异养反硝化(HD)衍生的N2O的产生,显著降低了N2O的累积排放,并促进了N2O在反硝化过程中还原为N2。相比之下,20%的替代未能实现持续的缓解。生物粪肥最初表现出比粪肥更强的N2O缓解效果,但随着时间的推移,由于HD中N2O生产-消耗抵消效应,这种缓解效果消失了。具体而言,相对于粪肥,生物粪通过增加hd相关基因(nirK, nirS,真菌-nirK)的丰度和潜在的反硝化速率来刺激hd驱动的N2O生成。生物粪肥通常保持较高的N2O还原能力,表现为较低的(nirK + nirS +真菌-nirK)/(nosZ)比率和未还原的N2O分数。重要的是,替代肥料提高了作物产量,与常规肥料相比,粪肥增产8 - 21%,生物粪增产19 - 30%。因此,我们的研究表明,50%的生物粪替代是减少N2O排放和提高蔬菜生产系统产量的有效策略,为可持续资源管理和减缓气候变化提供了可行的见解。
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引用次数: 0
Toward a modular and integrated approach to lithium-ion battery recycling: from fragmentation to strategic research globalization 迈向锂离子电池回收的模块化和集成方法:从碎片化到战略研究全球化
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-01-01 DOI: 10.1016/j.resenv.2026.100294
Elza Bontempi
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引用次数: 0
Heavy metal transformation in livestock manure (co-)pyrolysis: pathways toward safe biochar and sustainable agriculture 畜禽粪便(共)热解中的重金属转化:通往安全生物炭和可持续农业的途径
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-01-01 DOI: 10.1016/j.resenv.2025.100284
Fengxiao Zhao , Hongyuan Chen , Danni Li , Dong Liang , Xianhai Zeng , Rui Shan , Haoran Yuan , Yong Chen
Livestock manure is enriched with heavy metals such as copper, zinc, and cadmium due to feed additives and intensive farming practices. Inadequate management can lead to soil accumulation, nutrient cycle disruption, and ecosystem risks. Pyrolysis, as a versatile thermochemical process, simultaneously enables pollutant control, energy recovery, nutrient recycling, and heavy metal stabilization. This review integrates mechanistic insights with sustainability-oriented evaluation, linking thermochemical transformations to agricultural applications and policy frameworks. We examine thermal-induced changes in heavy metal speciation and mobility, highlighting stabilization through encapsulation, complexation, and mineralization, while also critically assessing sequential extraction methods. The synergistic effects of co-pyrolysis and mineral additives are further discussed. By bridging molecular-scale mechanisms with sustainable resource management, this work provides a cross-disciplinary perspective to guide safe biochar reuse, integrated manure management, and broader sustainability goals.
由于饲料添加剂和集约化耕作方式,牲畜粪便富含铜、锌和镉等重金属。管理不当可能导致土壤积累、养分循环中断和生态系统风险。热解作为一种多功能的热化学过程,可以同时实现污染物控制、能量回收、养分循环和重金属稳定。这篇综述结合了机械的见解和面向可持续性的评价,将热化学转化与农业应用和政策框架联系起来。我们研究了热诱导的重金属形态和迁移的变化,强调了通过包封、络合和矿化的稳定,同时也严格评估了顺序提取方法。进一步讨论了共热解与矿物添加剂的协同作用。通过将分子尺度机制与可持续资源管理相结合,本研究为指导生物炭的安全再利用、粪便综合管理和更广泛的可持续发展目标提供了跨学科的视角。
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引用次数: 0
Long–term application of agricultural amendments regulate the assembly of different bacterial sub–communities and growth of multi–species biofilms in paddy soils 长期施用农用改良剂可调节水稻土中不同细菌亚群落的聚集和多物种生物膜的生长
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2026-01-01 DOI: 10.1016/j.resenv.2025.100287
Sheng Zhao , Yi Wen , Hao Sheng , Junpeng Lou , Chuan Peng , Yu Jiang , Yuqing Tang , Shanpeng Liu , Kai Ouyang
Long–term agricultural amendments are widely employed to enhance soil quality and ecological sustainability. However, their effects on the assembly processes of bacterial sub–communities and on multispecies biofilm development remain poorly understood. In a seven–year field experiment, we investigated the impact of lime (L) and organic fertilizer (OF) amendments on the assembly mechanisms of abundant, moderate, and rare bacterial taxa in paddy soil, as well as on the formation and growth of multispecies biofilms. Our results demonstrated that both amendments significantly increased biofilm biomass, enhancing biofilm thickness by 0.72– to 1.33–fold, and shifted microbial niche adaptation. Assembly processes, assessed via the Normalized Stochasticity Ratio (NST), exhibited contrasting patterns among taxa: for the whole and rare bacterial communities, NST increased from 45.3 % to 68.9 % and from 48.3 % to 71.3 % under OF, and from 44.3 % to 55.7 % and from 47.8 % to 57.2 % under L, indicating a shift from deterministic toward stochastic process. In contrast, moderate taxa showed decreased stochasticity, with NST declining from 70.0 % to 43.2 % under OF and from 77.4 % to 58.3 % under L. Organic fertilization also enhanced soil multifunctionality by 2.37–fold and increased bacterial network complexity by 77 %. Soil pH was identified as the key driver governing both bacterial community assembly and multispecies biofilm growth. These findings provide novel insights into how long–term agricultural amendments modulate biofilm dynamics and bacterial assembly processes in soil ecosystems.
长期农业改良剂被广泛用于提高土壤质量和生态可持续性。然而,它们对细菌亚群落组装过程和多物种生物膜发育的影响仍然知之甚少。通过为期7年的田间试验,研究了石灰和有机肥对水稻土中丰富、中等和稀有细菌类群聚集机制的影响,以及对多物种生物膜形成和生长的影响。结果表明,这两种改性剂均显著增加了生物膜生物量,使生物膜厚度增加了0.72 ~ 1.33倍,并改变了微生物生态位适应。通过归一化随机比(NST)评估,不同分类群的组装过程呈现出不同的模式:对于整个和稀有细菌群落,在OF下,NST从45.3%增加到68.9%和48.3%增加到71.3%,在L下,NST从44.3%增加到55.7%和47.8%增加到57.2%,表明由确定性过程向随机过程转变。有机肥处理下,土壤的NST从70.0%下降到43.2%,从77.4%下降到58.3%;有机肥处理下,土壤的多功能性提高了2.37倍,细菌网络复杂性提高了77%。土壤pH被认为是控制细菌群落聚集和多物种生物膜生长的关键驱动因素。这些发现为长期农业改良剂如何调节土壤生态系统中的生物膜动力学和细菌组装过程提供了新的见解。
{"title":"Long–term application of agricultural amendments regulate the assembly of different bacterial sub–communities and growth of multi–species biofilms in paddy soils","authors":"Sheng Zhao ,&nbsp;Yi Wen ,&nbsp;Hao Sheng ,&nbsp;Junpeng Lou ,&nbsp;Chuan Peng ,&nbsp;Yu Jiang ,&nbsp;Yuqing Tang ,&nbsp;Shanpeng Liu ,&nbsp;Kai Ouyang","doi":"10.1016/j.resenv.2025.100287","DOIUrl":"10.1016/j.resenv.2025.100287","url":null,"abstract":"<div><div>Long–term agricultural amendments are widely employed to enhance soil quality and ecological sustainability. However, their effects on the assembly processes of bacterial sub–communities and on multispecies biofilm development remain poorly understood. In a seven–year field experiment, we investigated the impact of lime (L) and organic fertilizer (OF) amendments on the assembly mechanisms of abundant, moderate, and rare bacterial taxa in paddy soil, as well as on the formation and growth of multispecies biofilms. Our results demonstrated that both amendments significantly increased biofilm biomass, enhancing biofilm thickness by 0.72– to 1.33–fold, and shifted microbial niche adaptation. Assembly processes, assessed via the Normalized Stochasticity Ratio (NST), exhibited contrasting patterns among taxa: for the whole and rare bacterial communities, NST increased from 45.3 % to 68.9 % and from 48.3 % to 71.3 % under OF, and from 44.3 % to 55.7 % and from 47.8 % to 57.2 % under L, indicating a shift from deterministic toward stochastic process. In contrast, moderate taxa showed decreased stochasticity, with NST declining from 70.0 % to 43.2 % under OF and from 77.4 % to 58.3 % under L. Organic fertilization also enhanced soil multifunctionality by 2.37–fold and increased bacterial network complexity by 77 %. Soil pH was identified as the key driver governing both bacterial community assembly and multispecies biofilm growth. These findings provide novel insights into how long–term agricultural amendments modulate biofilm dynamics and bacterial assembly processes in soil ecosystems.</div></div>","PeriodicalId":34479,"journal":{"name":"Resources Environment and Sustainability","volume":"23 ","pages":"Article 100287"},"PeriodicalIF":7.8,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145928560","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ecological risks of combination of multiple pollutants at environmentally relevant concentrations: Insights from the changes in life history traits, gut microbiota, and transcriptomic responses in Daphnia magna 多种污染物在环境相关浓度下组合的生态风险:来自大水蚤生活史特征、肠道微生物群和转录组反应变化的见解
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-01 DOI: 10.1016/j.resenv.2025.100281
Qiuxuan Sun , Songying Dai , Yunfei Dai , Yunfei Sun , Jin-Sol Lee , Kai Lyu , Jae-Seong Lee , Zhou Yang
Aquatic organisms are normally exposed to waters where multiple pollutants coexist. Although the concentration of each single pollutant in natural waters is extremely low and may not have harmful effects, the combined effects of multiple low concentration pollutants may cause substantial harm to Daphnia. Therefore, we selected 11 kinds of pollutants including microplastics, antibiotics, heavy metals, agricultural and industrial pollutants, and then exposed Daphnia magna to the combination of these pollutants at the environmental concentrations (ng L−1-μg L−1 range) to evaluate the possible negative effects. Results showed the combination of multiple pollutants significantly decreased heart rate, body size, survival, and fecundity of D. magna and delayed maturation. In the filial generation constantly exposed to the pollutant combination, the growth, survival, and reproduction further decreased. The diversity of the gut microbiota decreased, but the abundance of bacteria with functions related to xenobiotics degradation increased under the pollutant combination. The expressions of genes related to antioxidant, xenobiotics catabolism, and energy absorption were upregulated by the pollutant combination, with downregulating expressions of the genes related to cell division and nitrogen metabolism, which reveals the underlying mechanism of the harmful effects of multiple pollutants on life history traits of D. magna. This study demonstrated the ecological risks of multiple pollutants at environmentally relevant concentrations to D. magna, providing a new perspective for evaluating the consequences of low environmental pollution in natural waters.
水生生物通常暴露在多种污染物共存的水域中。虽然天然水体中每种单一污染物的浓度极低,可能不会产生有害影响,但多种低浓度污染物的综合作用可能对水蚤造成实质性危害。因此,我们选择了包括微塑料、抗生素、重金属、农业和工业污染物在内的11种污染物,并在环境浓度(ng L−1 ~ μg L−1范围内)将大水蚤暴露于这些污染物的组合中,以评估可能产生的负面影响。结果表明,多种污染物的组合显著降低了大鼠的心率、体型、存活率和繁殖力,并延迟了成熟时间。在不断暴露于污染物组合的子代中,生长、生存和繁殖进一步下降。在污染物组合下,肠道菌群的多样性下降,但具有外源降解相关功能的细菌丰度增加。污染物组合上调了抗氧化、外源分解代谢和能量吸收相关基因的表达,下调了细胞分裂和氮代谢相关基因的表达,揭示了多种污染物对D. magna生命史性状有害影响的潜在机制。本研究揭示了多种污染物在环境相关浓度下对D. magna的生态风险,为自然水体低环境污染后果评价提供了新的视角。
{"title":"Ecological risks of combination of multiple pollutants at environmentally relevant concentrations: Insights from the changes in life history traits, gut microbiota, and transcriptomic responses in Daphnia magna","authors":"Qiuxuan Sun ,&nbsp;Songying Dai ,&nbsp;Yunfei Dai ,&nbsp;Yunfei Sun ,&nbsp;Jin-Sol Lee ,&nbsp;Kai Lyu ,&nbsp;Jae-Seong Lee ,&nbsp;Zhou Yang","doi":"10.1016/j.resenv.2025.100281","DOIUrl":"10.1016/j.resenv.2025.100281","url":null,"abstract":"<div><div>Aquatic organisms are normally exposed to waters where multiple pollutants coexist. Although the concentration of each single pollutant in natural waters is extremely low and may not have harmful effects, the combined effects of multiple low concentration pollutants may cause substantial harm to <em>Daphnia</em>. Therefore, we selected 11 kinds of pollutants including microplastics, antibiotics, heavy metals, agricultural and industrial pollutants, and then exposed <em>Daphnia magna</em> to the combination of these pollutants at the environmental concentrations (ng L<sup>−1</sup>-μg L<sup>−1</sup> range) to evaluate the possible negative effects. Results showed the combination of multiple pollutants significantly decreased heart rate, body size, survival, and fecundity of <em>D. magna</em> and delayed maturation. In the filial generation constantly exposed to the pollutant combination, the growth, survival, and reproduction further decreased. The diversity of the gut microbiota decreased, but the abundance of bacteria with functions related to xenobiotics degradation increased under the pollutant combination. The expressions of genes related to antioxidant, xenobiotics catabolism, and energy absorption were upregulated by the pollutant combination, with downregulating expressions of the genes related to cell division and nitrogen metabolism, which reveals the underlying mechanism of the harmful effects of multiple pollutants on life history traits of <em>D</em>. <em>magna</em>. This study demonstrated the ecological risks of multiple pollutants at environmentally relevant concentrations to <em>D</em>. <em>magna</em>, providing a new perspective for evaluating the consequences of low environmental pollution in natural waters.</div></div>","PeriodicalId":34479,"journal":{"name":"Resources Environment and Sustainability","volume":"22 ","pages":"Article 100281"},"PeriodicalIF":7.8,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145690900","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Nonlinear threshold effects of territorial space use on land ecological security along China's land borders: a multi-scale zonal governance pathway 国土空间利用对中国陆地边界土地生态安全的非线性阈值效应:一个多尺度的区域治理路径
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-01 DOI: 10.1016/j.resenv.2025.100282
Guobin Ma , Rucheng Lu , Tongsheng Fan , Pengcheng Wang , Yiyun Li
<div><div>TSU (territorial space use) constitutes the foundational behavior of human economic and social activities upon the land. Investigating the threshold effect of multi-scale TSU on LES (land ecological security) is essential for scientifically constructing a border ecological barrier management system within the framework of integrated development and security planning. Currently, spatial governance of territorial space in China's border areas utilizes the "three districts and three lines" as its core framework, implementing rigid spatial controls through the ecological protection red line, cultivated land and permanent basic farmland boundaries, and the urban development boundary. Concurrently, the main functional area strategy is employed to promote differentiated development. However, these border areas face dual pressures stemming from ecological fragility and intensive human activity: the northern border is threatened by ecological degradation in arid regions; soil erosion affects more than half of the northwest border area; and rocky desertification in the southwest border region contributes to the desertification of cultivated land and the loss of soil fertility. Consequently, a significant spatial mismatch and structural imbalance exist between land use patterns and ecological security requirements.</div><div>By employing a BRT (Boosted Regression Trees) model and SEM (Structural Equation Model), this study identified and categorized the influence of major TSU types on LES. Subsequently, hierarchical governance of LES thresholds was implemented through SLR (Segmented Linear Regression). Concurrently, we employ the SOM-K-means clustering method to execute zonal control of the predominant types of TSU. The results show that (1) from 2008 to 2023, the proportion of OE (Other ecological space) in the types of TSU is the highest at 32.764 ​%, which is concentrated in the Northern border and the Northwestern border; OE→ WE (Water ecological space) reflects the systematic tendency of transformation; and the spatial transfer of the three regions is mainly dominated by Agriculture→Urban and Ecology→Urban. (2) From 2008 to 2023, LES at different scales is characterized by ‘high in the North and low in the West,’ and SP (Social protection), EM (Economic drive), and SS (Ecological support) in each border region show strong effects on LES, with AP (Agricultural production space), GE (Grassland ecological space), OE, and FE (Forest ecological space) thresholds for LES of 0.457, 0.425, 0.330 and 0.345, respectively, 0.330, 0.348. (3) In 2023, the grid scale is mainly dominated by WE, FE, AP et al., and the distribution of its KCA (key conservation areas) is as high as 38.713 ​%; the county and city scales are mainly composed of FEL (Forest ecological space dominant type), APL(Agricultural production space dominant type), GEL (Grassland ecological space dominant type), and OEL (Other ecological space dominant type) to form the spatial pattern of t
国土空间利用是人类在土地上进行经济社会活动的基本行为。研究多尺度TSU对土地生态安全的阈值效应,对于科学构建综合开发与安全规划框架下的边境生态屏障管理体系具有重要意义。目前,中国边境地区国土空间治理以“三区三线”为核心框架,通过生态保护红线、耕地和永久基本农田边界、城市发展边界实施刚性空间管控。同时,实施主体功能区战略,促进差异化发展。然而,这些边境地区面临着来自生态脆弱性和密集人类活动的双重压力:北部边境受到干旱地区生态退化的威胁;西北边区一半以上受到水土流失的影响;西南边区的石漠化是造成耕地沙漠化和土壤肥力流失的主要原因。因此,土地利用方式与生态安全需求之间存在明显的空间失配和结构失衡。本研究采用BRT (boosting Regression Trees)模型和SEM (Structural Equation model)模型,对主要TSU类型对LES的影响进行了识别和分类。随后,通过SLR(分段线性回归)实现LES阈值的分层治理。同时,我们采用SOM-K-means聚类方法对TSU的优势类型进行分区控制。结果表明:(1)2008 - 2023年,其他生态空间在城市群类型中所占比例最高,为32.764%,主要集中在北部边境和西北边境;OE→WE(水生态空间)体现了系统的转型趋势;三个区域的空间转移以农业→城市与生态→城市为主。(2) 2008 - 2023年,各边区不同尺度的生态环境效率呈现“北高西低”的特征,社会保障、经济驱动和生态支持对生态环境效率的影响较强,AP(农业生产空间)、GE(草地生态空间)、OE和FE(森林生态空间)的生态环境效率阈值分别为0.457、0.425、0.330和0.345、0.330、0.348。(3) 2023年网格尺度以WE、FE、AP等为主,其重点保护区(KCA)分布高达38.713%;县域和市域尺度主要由森林生态空间优势型(FEL)、农业生产空间优势型(APL)、草地生态空间优势型(GEL)和其他生态空间优势型(OEL)构成国土空间格局,其中县域的修复修复区(RRA)比例最高(42.244%),市域的KCA占37.686 %。根据“分区控制+分层治理”的综合治理分区,我们提出了一种细致入微的治理方法,称为“网格-县-市”。这一办法旨在为可持续利用领土空间以及协调边境地区的安全和发展提供一个基本的理论框架和决策基准。
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引用次数: 0
Technology to utilise and suppress weeds for sustainable maize production 玉米可持续生产的杂草利用和抑制技术
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-01 DOI: 10.1016/j.resenv.2025.100279
Kaixian Wu , Shiyong Zhou , Guang Zeng , Hongli Yang , Bozhi Wu
Throughout agricultural history, controlling weeds to prevent yield loss has been a longstanding focus. However, a practical technology that leverages weeds as a beneficial biological resource without compromising crop yields has remained elusive. Our study proposes and evaluates an innovative integrated technology to utilise and suppress weeds (ITUSW) for sustainable maize cultivation. In brief, maize was planted in ultrawide rows (100 cm apart) with two plants per hill on strip-tillage beds. Interrow weeds were allowed to grow naturally. These weeds were mowed during the seedling, tillering, and flowering stages. The mowed material, combined with the previous year's maize stover that was laid on the interrows, was then used as mulch over the maize rows and eventually returned to the soil through the practice of strip-tillage. Our five-year field study suggest that maize yields under the ITUSW treatment did not differ from those achieved by the plastic film mulching for weeding (MFW), chemical weeding (CW), chemical weeding plus straw return (CWSR), and mechanical weeding by hand hoeing (MHW)(p ​> ​0.05) treatments, yet they significantly surpassed those of the chemical weeding combined with straw mulching (CWSM)(p ​< ​0.05) treatment. Importantly, the above-ground intra-row weed biomass under the ITUSW was notably reduced compared to the MFW treatment, resembling the levels observed in other treatments. Conversely, the inter-row weed biomass experienced substantial increases of up to 448 g/m2 through maize growth season, specifically by 9.89-, 5.14-, 4.36-, and 3.51-fold in contrast to the SWSM, CW, MHW, and MFW, treatments respectively (p ​< ​0.05). Our series of supplementary experiments confirmed that weeds beyond a 25 cm radius do not induce yield loss (p ​< ​0.05). Moreover, ITUSW designed with a wide row layout, strip tillage, inter-row weed mowing, and intra-row weed mulching eliminated competition from inter-row weeds and achieved the resource utilisation of inter-row weeds, such as soil improvement and biomass mulching. Besides, ITUSW is compatible with winter crops such as wheat. Consequently, ITUSW shows potential to replace chemical herbicides in maize production, and weeds are redefined from foes to allies, propelling agriculture towards enhanced sustainability.
纵观农业历史,控制杂草以防止产量损失一直是一个长期关注的焦点。然而,利用杂草作为一种有益的生物资源而不影响作物产量的实用技术仍然难以实现。我们的研究提出并评价了一种创新的综合利用和抑制杂草技术(ITUSW),用于玉米的可持续种植。简而言之,玉米以超宽行(间隔100厘米)种植,每山两株,在带状耕作床上种植。杂草被允许自然生长。这些杂草在幼苗、分蘖和开花阶段被修剪。割下的材料,加上前一年铺在玉米垄上的玉米秸秆,然后被用作玉米垄的覆盖物,最后通过条带耕作的做法返回土壤。5年田间研究表明,ITUSW处理玉米产量与地膜除草(MFW)、化学除草(CW)、化学除草加秸秆还田(CWSR)和手锄机械除草(MHW)处理差异不显著(p > 0.05),但显著优于化学除草加秸秆覆盖(CWSM)处理(p < 0.05)。重要的是,与MFW处理相比,ITUSW处理的地上行内杂草生物量显著减少,与其他处理的水平相似。相反,玉米生长季行间杂草生物量显著增加,最高达448 g/m2,分别比SWSM、CW、MHW和MFW处理增加了9.89倍、5.14倍、4.36倍和3.51倍(p < 0.05)。我们的一系列补充试验证实,半径超过25 cm的杂草不会导致产量损失(p < 0.05)。此外,ITUSW采用宽行布局、条形耕作、行间除草和行内杂草覆盖设计,消除了行间杂草的竞争,实现了行间杂草的资源利用,如土壤改良和生物质覆盖。此外,ITUSW与小麦等冬季作物兼容。因此,ITUSW显示了在玉米生产中取代化学除草剂的潜力,杂草被从敌人重新定义为盟友,推动农业向增强可持续性发展。
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引用次数: 0
In-situ synthesizing CoONAl-C catalysts from spent LiCoO2 batteries and tobacco stems biomass: nearly 100 ​% peroxymonosulfate utilization 从废LiCoO2电池和烟草茎生物质中原位合成CoONAl-C催化剂:近100%过氧单硫酸盐利用率
IF 7.8 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-11-07 DOI: 10.1016/j.resenv.2025.100280
Teng Guo , Xiaoya Gao , Xingxin Yang , Jiatian Wang , Yucheng Yin , Yaoran Hu , Yue Luo , Yongming Luo
Strategic metal recovery from spent lithium-ion batteries (LIBs) is urgently required novel technologies with high efficiency, low environmental impact, and strong economic viability. This study proposes a tobacco stems biomass assisted strategy that directly converts spent LiCoO2 into advanced functional Co-based catalyst in water treatment. Benefited from the biomass pyrolysis, Co-based catalyst was first in-situ doped with metal (Al) and non-metal (C and N) to obtain CoONAl-C catalysts. The prepared CoONAl-C achieved nearly 100 ​% peroxymonosulfate (PMS) utilization efficiency, which exhibited a persulfate per mass pollutants normalized kinetic rate constant surpassing reported water treatment systems by 2–42 times. The co-doping of metal (Al) and non-metal (C and N) not only shortened the bond length between PMS and Co-O but also upward shifted the d-band center close to Fermi-level. The alteration of Co active sites' electronic distribution via Co-N coordination, combined with loading and reduction of biomass pyrolysis, significantly promoted Co(II)/Co(III) redox cycles. This synergy boosted PMS adsorption-activation and Fenton-like catalytic activity, ultimately driving O-O bond cleavage to generate reactive oxygen species for efficient degradation of emerging contaminants. Moreover, the practical applicability of CoONAl-C was supported by its high stability over seven cycles, minimal ion leaching, reduced toxicity of intermediates, and effective operation in real water samples. This study addressed the high PMS consumption bottleneck in water treatment, contributing to the sustainable utilization of spent LIBs and waste biomass.
从废旧锂离子电池(LIBs)中战略性回收金属,迫切需要高效、低环境影响、经济可行性强的新技术。本研究提出了一种烟草茎生物质辅助策略,直接将废LiCoO2转化为高级功能性co基催化剂用于水处理。得益于生物质热解,co基催化剂首先原位掺杂金属(Al)和非金属(C和N),得到CoONAl-C催化剂。制备的CoONAl-C对过氧单硫酸盐(PMS)的利用率接近100%,每质量污染物的过硫酸盐归一化动力学速率常数是现有水处理系统的2-42倍。金属(Al)和非金属(C和N)的共掺杂不仅缩短了PMS与Co-O之间的键长,而且使d带中心向上移动,接近费米能级。通过Co- n配位改变Co活性位点的电子分布,结合生物质热解的加载和还原,显著促进Co(II)/Co(III)氧化还原循环。这种协同作用提高了PMS吸附活化和fenton类催化活性,最终推动O-O键裂解产生活性氧,从而有效降解新出现的污染物。此外,CoONAl-C在7次循环中具有很高的稳定性,离子浸出最小,中间体毒性降低,并且在实际水样中有效运行,这支持了它的实用性。该研究解决了水处理中PMS消耗高的瓶颈,有助于废lib和废生物质的可持续利用。
{"title":"In-situ synthesizing CoONAl-C catalysts from spent LiCoO2 batteries and tobacco stems biomass: nearly 100 ​% peroxymonosulfate utilization","authors":"Teng Guo ,&nbsp;Xiaoya Gao ,&nbsp;Xingxin Yang ,&nbsp;Jiatian Wang ,&nbsp;Yucheng Yin ,&nbsp;Yaoran Hu ,&nbsp;Yue Luo ,&nbsp;Yongming Luo","doi":"10.1016/j.resenv.2025.100280","DOIUrl":"10.1016/j.resenv.2025.100280","url":null,"abstract":"<div><div>Strategic metal recovery from spent lithium-ion batteries (LIBs) is urgently required novel technologies with high efficiency, low environmental impact, and strong economic viability. This study proposes a tobacco stems biomass assisted strategy that directly converts spent LiCoO<sub>2</sub> into advanced functional Co-based catalyst in water treatment. Benefited from the biomass pyrolysis, Co-based catalyst was first in-situ doped with metal (Al) and non-metal (C and N) to obtain CoON<sub>Al</sub>-C catalysts. The prepared CoON<sub>Al</sub>-C achieved nearly 100 ​% peroxymonosulfate (PMS) utilization efficiency, which exhibited a persulfate per mass pollutants normalized kinetic rate constant surpassing reported water treatment systems by 2–42 times. The co-doping of metal (Al) and non-metal (C and N) not only shortened the bond length between PMS and Co-O but also upward shifted the d-band center close to Fermi-level. The alteration of Co active sites' electronic distribution via Co-N coordination, combined with loading and reduction of biomass pyrolysis, significantly promoted Co(II)/Co(III) redox cycles. This synergy boosted PMS adsorption-activation and Fenton-like catalytic activity, ultimately driving O-O bond cleavage to generate reactive oxygen species for efficient degradation of emerging contaminants. Moreover, the practical applicability of CoON<sub>Al</sub>-C was supported by its high stability over seven cycles, minimal ion leaching, reduced toxicity of intermediates, and effective operation in real water samples. This study addressed the high PMS consumption bottleneck in water treatment, contributing to the sustainable utilization of spent LIBs and waste biomass.</div></div>","PeriodicalId":34479,"journal":{"name":"Resources Environment and Sustainability","volume":"22 ","pages":"Article 100280"},"PeriodicalIF":7.8,"publicationDate":"2025-11-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145525851","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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Resources Environment and Sustainability
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