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Surface texture characterization for thin-wall NASA HR-1 Fe–Ni–Cr alloy using laser powder directed energy deposition (LP-DED) 利用激光粉末定向能沉积(LP-DED)表征NASA HR-1 Fe-Ni-Cr薄壁合金表面织构
Q2 ENGINEERING, INDUSTRIAL Pub Date : 2022-05-01 DOI: 10.1016/j.aime.2022.100084
Paul R. Gradl , Angelo Cervone , Eberhard Gill

Additive Manufacturing (AM) offers new design and manufacturing opportunities of thin-wall microchannel heat exchangers for aerospace and industrial applications. Laser Powder Directed Energy Deposition (LP-DED) is an AM process providing large scale manufacturing of thin-wall microchannel heat exchangers. Successful industrialization of the LP-DED process requires critical quantification and understanding of the metallurgical, geometric, and process limitations. Specifically, understanding the as-built surface texture, inclusive of roughness and waviness, is significant due to its effects on the friction factor and pressure drop within a heat exchanger. This experimental study completed a design of experiments (DOE) to determine the critical build parameters that impact surface texture for enclosed thin-wall samples. This study summarizes the characterization work of the LP-DED process for 1 mm enclosed walls with an Fe–Ni–Cr (NASA HR-1) alloy. The LP-DED parameters including laser power, powder feedrate, travel speed, layer height, and rotary atomized powder feedstock were modified in the experiment. An evaluation of the DOE samples and resulting surface texture is provided along with conclusions from these experiments. Results indicate that 3D areal and 2D profile (directional) surface texture is estimated by 2x the powder diameter that becomes captured or partially melted on the trailing edge of the melt pool. The fine powder showed a higher sensitivity to parameter changes but resulted in a higher density material and 23% reduction in roughness. Surface texture was also shown to vary between closed channel shapes (internal) due to ricochets, recirculation, and higher volume of powder available to bond compared to external (outer) surfaces. The understanding of the LP-DED process as-built surface texture is essential to fluid flow applications such as heat exchanges and can modify performance for enhanced heat transfer or can be a detriment to pressure drop.

增材制造(AM)为航空航天和工业应用的薄壁微通道热交换器提供了新的设计和制造机会。激光粉末定向能沉积(LP-DED)是一种可大规模制造薄壁微通道热交换器的增材制造工艺。LP-DED工艺的成功产业化需要对冶金、几何和工艺限制进行关键的量化和理解。具体来说,了解建成后的表面纹理,包括粗糙度和波浪形,是非常重要的,因为它会影响热交换器内的摩擦系数和压降。本实验研究完成了实验设计(DOE),以确定影响封闭薄壁样品表面纹理的关键构建参数。本研究总结了Fe-Ni-Cr (NASA HR-1)合金1 mm封闭壁的LP-DED工艺的表征工作。实验中对激光功率、进给粉速度、行程速度、层高、旋转雾化粉料等参数进行了修改。对DOE样品和由此产生的表面纹理进行了评估,并提供了这些实验的结论。结果表明,通过在熔池尾缘捕获或部分熔化的粉末直径的2倍来估计三维面状和二维轮廓(方向)表面纹理。细粉对参数变化的敏感性较高,但密度较高,粗糙度降低23%。由于反弹、再循环和与外部(外部)表面相比可粘合的粉末体积较大,表面纹理在封闭通道形状(内部)之间也有所不同。对LP-DED工艺的表面结构的理解对于热交换等流体流动应用至关重要,可以改变性能以增强传热,也可以损害压降。
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引用次数: 3
The effects of extrusion parameters and blend composition on the mechanical, rheological and thermal properties of LDPE/PS/PMMA ternary polymer blends 挤出参数和共混物组成对LDPE/PS/PMMA三元共混物力学、流变和热性能的影响
Q2 ENGINEERING, INDUSTRIAL Pub Date : 2022-05-01 DOI: 10.1016/j.aime.2021.100067
Y. Ding , C. Abeykoon , Yasith S. Perera

Polymer blending is one of the popular methods for producing tailor-made materials by combining the properties of individual polymers. Binary polymer blends have quite commonly been used over the past few decades. Recently, researchers have shifted their focus towards ternary polymer blends and this study aims to investigate a ternary polymer blend system consisting of low-density polyethylene (LDPE), polystyrene (PS) and polymethyl methacrylate (PMMA). The LDPE/PS/PMMA blend was processed by melt blending using a twin-screw extruder. The effects of the extrusion process parameters (i.e., screw speed and barrel set temperatures) and the blend composition on the mechanical, rheological and thermal properties of the polymer blend and the degree of crystallinity of the LDPE matrix were studied. Three different screw speeds (i.e., 50 rpm, 100 rpm and 150 rpm), two different barrel set temperatures (i.e., 200 °C and 220 °C), and two different component mass ratios (i.e., 70/10/20 and 70/20/10) were studied. The results showed that the tensile properties of the LDPE/PS/PMMA blend were significantly influenced by its microstructure. Yield strength and Young's modulus decreased at first and then increased with increasing screw speed. The blend processed at a barrel set temperature of 220 °C was found to have better tensile properties than the blend processed at 200 °C. Furthermore, the blend with a PS content of 10 wt% possessed better tensile properties than the blend with a PS content of 20 wt%. Regardless of the blend compositions and the process settings, the LDPE/PS/PMMA blends reported better mechanical properties than those of pure LDPE with a Young's Modulus of 240 MPa and a yield stress of 10.47 MPa. The rheology of the blend was also significantly affected by the process parameters and the blend composition. However, different process parameters and mass ratios did not indicate a significant influence on the melting temperature (around 109.5 °C) and the degradation initiation temperature (around 252.3 °C) of the LDPE/PS/PMMA blend, but both the melting temperature and the degradation initiation temperature of the ternary blend were found to be slightly lower than those of pure LDPE. The degree of crystallinity of the LDPE matrix was also affected by both the screw speed and the barrel set temperature. The results revealed that, better mechanical properties can be achieved by blending PS and PMMA with LDPE without significantly affecting the thermal properties compared to those of pure LDPE.

聚合物共混是通过结合单个聚合物的性能来生产定制材料的流行方法之一。在过去的几十年里,二元聚合物共混物已经被广泛使用。近年来,研究人员将重点转向三元聚合物共混体系,本研究旨在研究由低密度聚乙烯(LDPE)、聚苯乙烯(PS)和聚甲基丙烯酸甲酯(PMMA)组成的三元聚合物共混体系。采用双螺杆挤出机对LDPE/PS/PMMA共混物进行熔融共混加工。研究了挤出工艺参数(螺杆转速、料筒设定温度)和共混物组成对聚合物共混物的力学性能、流变性能和热性能以及LDPE基体结晶度的影响。研究了三种不同的螺杆转速(即50 rpm, 100 rpm和150 rpm),两种不同的筒体设定温度(即200°C和220°C)以及两种不同的组分质量比(即70/10/20和70/20/10)。结果表明,LDPE/PS/PMMA共混物的拉伸性能受到其微观结构的显著影响。随着螺杆转速的增加,屈服强度和杨氏模量先减小后增大。在220°C的桶设定温度下加工的共混物比在200°C下加工的共混物具有更好的拉伸性能。此外,PS含量为10 wt%的共混物比PS含量为20 wt%的共混物具有更好的拉伸性能。无论共混物的组成和工艺设置如何,LDPE/PS/PMMA共混物的力学性能均优于纯LDPE,杨氏模量为240 MPa,屈服应力为10.47 MPa。共混物的流变性也受工艺参数和共混物组成的显著影响。然而,不同的工艺参数和质量比对LDPE/PS/PMMA共混物的熔融温度(109.5℃左右)和降解起始温度(252.3℃左右)没有显著影响,但发现三元共混物的熔融温度和降解起始温度均略低于纯LDPE。螺杆转速和料筒设定温度对LDPE基体的结晶度也有影响。结果表明,与纯LDPE相比,PS和PMMA与LDPE共混可以获得更好的力学性能,而热性能没有明显影响。
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引用次数: 9
Effect of temperature history during additive manufacturing on crystalline morphology of PEEK 增材制造温度历史对PEEK结晶形貌的影响
Q2 ENGINEERING, INDUSTRIAL Pub Date : 2022-05-01 DOI: 10.1016/j.aime.2022.100085
Austin Lee , Mathew Wynn , Liam Quigley , Marco Salviato , Navid Zobeiry

Additive manufacturing parameters of high-performance polymers greatly affect the thermal history and consequently quality of the end-part. For fused deposition modeling (FDM), this may include printing speed, filament size, nozzle, and chamber temperatures, as well as build plate temperature. In this study, the effect of thermal convection inside a commercial 3D printer on thermal history and crystalline morphology of polyetheretherketone (PEEK) was investigated using a combined experimental and numerical approach. Using digital scanning calorimetry (DSC) and polarized optical microscopy (POM), crystallinity of PEEK samples was studied as a function of thermal history. In addition, using finite element (FE) simulations of heat transfer, which were calibrated using thermocouple measurements, thermal history of parts during virtual 3D printing was evaluated. By correlating the experimental and numerical results, the effect of printing parameters and convection on thermal history and PEEK crystalline morphology was established. It was found that the high melting temperature of PEEK, results in fast melt cooling rates followed by short annealing times during printing, leading to relatively low degree of crystallinity (DOC) and small crystalline morphology.

高性能聚合物的增材制造参数极大地影响了热历史,从而影响了端部的质量。对于熔融沉积建模(FDM),这可能包括打印速度,灯丝尺寸,喷嘴和腔室温度,以及构建板温度。在本研究中,采用实验和数值相结合的方法研究了商用3D打印机内部热对流对聚醚醚酮(PEEK)热历史和结晶形态的影响。利用数字扫描量热仪(DSC)和偏光显微镜(POM)研究了PEEK样品的结晶度与热历史的关系。此外,利用热电偶测量校准的传热有限元模拟,评估了虚拟3D打印过程中零件的热历史。通过对比实验和数值结果,确定了打印参数和对流对PEEK结晶形貌和热历史的影响。研究发现,PEEK的熔融温度高,导致打印过程中熔体冷却速度快,退火时间短,结晶度(DOC)相对较低,结晶形态较小。
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引用次数: 10
A review of frameworks, methods and models for the evaluation and engineering of factory life cycles 工厂生命周期评估与工程的框架、方法与模型综述
Q2 ENGINEERING, INDUSTRIAL Pub Date : 2022-05-01 DOI: 10.1016/j.aime.2022.100083
Antal Dér , Lennart Hingst , Peter Nyhuis , Christoph Herrmann

Factories are complex systems, which are characterized by interlinked and overlapping life cycles of the constituent factory elements. Within this context, the heterogeneity of these life cycles results in life cycle complexity and corresponding conflicts and trade-offs that need to be addressed in decision situations during the planning and operation of factory systems. Also with respect to the transformation need towards environmental sustainability, there is a need for methods and tools for life cycle oriented factory planning and operation. This paper systematically reviews existing life cycle concepts of factory systems as well as frameworks, models and methods for the evaluation and engineering of factory life cycles. In order to respond to the above challenges, a general understanding about the factory life cycle, e.g. life cycle stages, related activities and interdependencies, is developed and action areas of life cycle engineering are discussed that could supplement factory planning. Following that, the paper presents an integrated, model-based evaluation and engineering framework of factory life cycles.

工厂是一个复杂的系统,其特征是组成工厂要素的生命周期相互联系和重叠。在这种情况下,这些生命周期的异质性导致了生命周期的复杂性和相应的冲突和权衡,需要在工厂系统规划和运行的决策情况下加以解决。此外,就环境可持续性的转型需求而言,需要以生命周期为导向的工厂规划和运营的方法和工具。本文系统地回顾了现有的工厂系统生命周期概念,以及工厂生命周期评估和工程的框架、模型和方法。为了应对上述挑战,对工厂生命周期的一般理解,例如生命周期阶段,相关活动和相互依赖关系,被开发,并讨论了生命周期工程的行动领域,可以补充工厂规划。在此基础上,提出了一个集成的、基于模型的工厂生命周期评估与工程框架。
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引用次数: 7
Friction stir spot welding of similar and dissimilar high density polyethylene and polypropylene sheets 同类或异类高密度聚乙烯、聚丙烯片材的搅拌摩擦点焊
Q2 ENGINEERING, INDUSTRIAL Pub Date : 2022-05-01 DOI: 10.1016/j.aime.2022.100076
Andro A.E. Sidhom, Soheir A.R. Naga, A.M. Kamal

Development and modernization in joining and welding techniques of plastic materials have attracted much attention in the field of scientific research and industry. Friction stir welding and friction stir spot welding, nowadays, have gained a significant advantage over other joining techniques due to the ease of operation, with no need for any adhesives or external heaters, and the use of non-consumable tools. In this research, the friction stir spot welding process of similar and dissimilar polymeric materials (polypropylene and high density polyethylene) was investigated experimentally. The effect of tool rotational speed and dwell time on the lap shear strength was studied, while the tool plunging rate, plunging depth, and tool geometry were kept constant during all tests.

The welding of dissimilar polypropylene to high density polyethylene was successfully performed within the range of 1400–3500 rpm rotational speeds; however, it was unsuccessful with 800 rpm.

Moreover, the friction stir spot welding of similar polyethylene and polypropylene was studied, and the optimum welding conditions were 3500 rpm with a dwell time of 40 s, and 800 rpm with a dwell time of 120 s for polypropylene and polyethylene respectively.

塑料材料的连接和焊接技术的发展和现代化已经引起了科研和工业领域的广泛关注。搅拌摩擦焊和搅拌摩擦点焊,如今,由于易于操作,不需要任何粘合剂或外部加热器,以及使用非消耗性工具,已经获得了比其他连接技术显著的优势。本研究对相似和不同聚合物材料(聚丙烯和高密度聚乙烯)的搅拌摩擦点焊工艺进行了实验研究。研究了刀具转速和停留时间对搭接剪切强度的影响,所有试验均保持刀具切入速度、切入深度和刀具几何形状不变。在1400 ~ 3500rpm转速范围内,成功地完成了异种聚丙烯与高密度聚乙烯的焊接;然而,它在800转时失败了。此外,对相似材料聚乙烯和聚丙烯的搅拌摩擦点焊进行了研究,聚丙烯和聚乙烯的最佳焊接条件分别为3500转/分钟、停留时间40 s和800转/分钟、停留时间120 s。
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引用次数: 6
Machine Learning based quality prediction for milling processes using internal machine tool data 基于机器学习的铣削过程质量预测,使用内部机床数据
Q2 ENGINEERING, INDUSTRIAL Pub Date : 2022-05-01 DOI: 10.1016/j.aime.2022.100074
A. Fertig, M. Weigold, Y. Chen

Machine tools are increasingly being equipped with edge computing solutions to record internal drive signals with high frequency. A large amount of available data may be used to develop new data-driven approaches to process optimization and quality monitoring. This paper presents a new approach to predict the quality of finished workpieces for three-axis milling processes with end mills. For this purpose, internal machine tool data provided by an edge computing solution was recorded and used to develop a Machine Learning based method for quality prediction. For the preparation of the data, an introduced domain knowledge-based slicing algorithm is applied, which allows the recorded data to be automatically and precisely assigned to the corresponding geometric elements on the workpiece. During data-driven modeling, 9 Machine Learning algorithms are compared to 4 Deep Learning architectures for multivariate time series classification. The results show that ensemble methods like Random Forest and Extra Trees as well as the Deep Learning algorithms InceptionTime and ResNet reach the best performances for the use case of data-based quality prediction.

机床越来越多地配备边缘计算解决方案,以记录高频的内部驱动信号。大量可用数据可用于开发新的数据驱动方法,以实现流程优化和质量监控。提出了一种利用立铣刀对三轴铣削加工成品质量进行预测的新方法。为此,记录由边缘计算解决方案提供的内部机床数据,并用于开发基于机器学习的质量预测方法。在数据准备方面,引入了基于领域知识的切片算法,使记录的数据能够自动精确地分配到工件上相应的几何元素上。在数据驱动建模过程中,将9种机器学习算法与4种深度学习架构进行了多变量时间序列分类的比较。结果表明,随机森林和额外树等集成方法以及深度学习算法InceptionTime和ResNet在基于数据的质量预测用例中达到了最佳性能。
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引用次数: 8
A data mining approach for continuous battery cell manufacturing processes from development towards production 从开发到生产的连续电池制造过程的数据挖掘方法
Q2 ENGINEERING, INDUSTRIAL Pub Date : 2022-05-01 DOI: 10.1016/j.aime.2022.100078
Erik Rohkohl , Malte Schönemann , Yury Bodrov , Christoph Herrmann

Battery cells are central components of electric vehicles determining their operational characteristics, such as driving range, power output, and safety. Automotive OEMs undertake the necessary efforts to ensure the integration of safe and high-performance battery cells in their electrified fleets. In addition, an increased sustainable awareness of their customers and governmental policies force them to not only focus on operational goals, but rather on environmental aspects as well. Especially, battery cell manufacturing is associated with various negative environmental impacts (e.g. carbon dioxide emission). Therefore, this study develops a concept facilitating the development of novel continuous processes in battery cell manufacturing by enabling virtual experiments and an automatic optimization of economic and ecologic targets. Virtual experiments are enabled by training data-driven models that transfer the gained knowledge from development to large-scale production. The concept includes an inline-capable controller adjusting set points of process parameters with respect to a cost model quantifying product quality and environmental aspects. The validity of the proposed concept is demonstrated with data acquired from real battery cell production chain covering a continuous mixing process.

电池是电动汽车的核心部件,决定着电动汽车的运行特性,如行驶里程、功率输出和安全性。汽车原始设备制造商采取了必要的努力,以确保在其电动车队中集成安全和高性能的电池。此外,对客户和政府政策的可持续意识的增强迫使他们不仅关注业务目标,而且也关注环境方面。特别是,电池制造与各种负面环境影响(例如二氧化碳排放)有关。因此,本研究提出了一个概念,通过实现虚拟实验和经济和生态目标的自动优化,促进电池制造中新的连续过程的发展。虚拟实验是通过训练数据驱动的模型实现的,这些模型将获得的知识从开发转移到大规模生产。该概念包括一个内联控制器,可根据量化产品质量和环境方面的成本模型调整工艺参数的设定点。通过实际电池生产链中连续混合过程的数据验证了所提概念的有效性。
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引用次数: 3
Proposal of an innovative ergonomic SMED model in an automotive steel springs industrial unit 在汽车钢弹簧工业装置中提出一种创新的符合人体工程学的SMED模型
Q2 ENGINEERING, INDUSTRIAL Pub Date : 2022-05-01 DOI: 10.1016/j.aime.2022.100075
Maria Afonso , Ana Teresa Gabriel , Radu Godina

Faced with globalization, high competition, and the demands of a market in constant dynamism, companies strive to adopt measures for increasing their productivity, among which Lean Manufacturing stands out. Although this set of strategies allows optimizing the production by reducing waste, the literature review showed that, in several organizations, the implementation of Lean does not reflect positive impacts on productivity. It is frequently related to the superficial nature of the approach: the tools and methods are applied, but the repercussions on the workers are commonly neglected. In response, companies seek to implement Risk Management policies to assess injury risk factors for operators during task execution. This study highlights the importance of integrating Lean Manufacturing and Ergonomics principles into organizations to increase productivity and improve working conditions simultaneously. Therefore, by identifying improvement opportunities using the VSM tool, this work aims to implement an innovative and systematic intervention model, which enables the integrated application of Single-Minute Exchange of Dies (SMED) and ergonomic analysis in a metallurgical factory. To this end, the innovative Ergonomic SMED (ESMED) Model is proposed, comprising six steps, which, in this study, focus on the setup operations of a molding machine and by including Rapid Upper Limb Assessment (RULA), Rapid Entire Body Assessment (REBA), Job Strain Index (JSI), Key Indicator Methods (KIM), and Shoaf's Model methods. Based on the results obtained, it is possible to evidence the usefulness and effectiveness of the proposed model in this scenario, emphasizing the 55% reduction in setup time and the extreme attenuation of the level of Work-Related Musculoskeletal Disorders (WMSDs) risk in workers.

面对全球化、激烈的竞争和不断动态的市场需求,企业努力采取措施提高生产率,其中精益制造脱颖而出。虽然这组策略允许通过减少浪费来优化生产,但文献综述表明,在一些组织中,精益的实施并没有反映出对生产率的积极影响。这通常与方法的表面性质有关:工具和方法被应用,但对工人的影响通常被忽视。作为回应,公司寻求实施风险管理政策,以评估作业人员在任务执行过程中的伤害风险因素。本研究强调了将精益生产和人体工程学原理整合到组织中以同时提高生产力和改善工作条件的重要性。因此,通过使用VSM工具识别改进机会,本工作旨在实现一种创新和系统的干预模型,该模型能够在冶金工厂中集成应用单分钟换模(SMED)和人体工程学分析。为此,提出了创新的人体工学SMED (ESMED)模型,该模型包括六个步骤,在本研究中,重点关注成型机的设置操作,包括快速上肢评估(RULA),快速全身评估(REBA),工作压力指数(JSI),关键指标方法(KIM)和Shoaf模型方法。根据所获得的结果,有可能证明在这种情况下提出的模型的有用性和有效性,强调设置时间减少55%,工人中与工作相关的肌肉骨骼疾病(WMSDs)风险水平的极度衰减。
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引用次数: 10
Laser directed energy deposition of AISI 316L stainless steel: The effect of build direction on mechanical properties in as-built and heat-treated conditions 激光定向能沉积AISI 316L不锈钢:成形和热处理条件下成形方向对力学性能的影响
Q2 ENGINEERING, INDUSTRIAL Pub Date : 2022-05-01 DOI: 10.1016/j.aime.2022.100079
Jeferson T. Pacheco , Vitor H. Meura , Paulo Rafael A. Bloemer , Marcelo T. Veiga , Osmar C. de Moura Filho , Alexandre Cunha , Moisés F. Teixeira

The purpose of this study was to evaluate the effect of build direction on the mechanical properties of AISI 316L stainless steel using the Laser Directed Energy Deposition (L-DED) process, in the as-built and heat-treated conditions. The test specimens were manufactured in vertical and horizontal directions for tensile and impact tests. In addition, analysis test specimens cube-shaped were manufactured for microstructural and microhardness evaluation. The microstructure in the as-built condition showed a combination of cellular, equiaxial dendritic, cellular dendritic and columnar dendritic, while the microstructure in the heat-treated condition showed a homogeneous characteristic, composed by differently sized grains. The microhardness evaluation in the heat-treated condition presented a reduction of 26.52% compared to the as-build condition. The ultimate tensile strength of horizontal test specimens in the as-built condition was 4.86% higher than the heat-treated condition, whereas the ultimate tensile strength of vertical test specimens in the as-built condition was 5.55% higher than the heat-treated condition. The impact resistance of horizontal test specimens in the heat-treated condition was 12.36% higher than the as-built condition, whereas the impact resistance of vertical test specimens in the heat-treated condition was 18.92% higher than the as-built condition. Briefly, the build direction directly affects the mechanical properties of components manufactured through the L-DED process, and it is possible to improve certain mechanical properties, such as ductility and toughness, through heat treatment.

本研究的目的是利用激光定向能沉积(L-DED)工艺,在制造和热处理条件下,评估构建方向对AISI 316L不锈钢力学性能的影响。试样分别在垂直和水平方向制作,用于拉伸和冲击试验。此外,还制作了立方体的分析试样,用于显微组织和显微硬度评估。铸态组织表现为胞状枝晶、等轴枝晶、胞状枝晶和柱状枝晶的组合,而热处理态组织表现为不同尺寸晶粒组成的均匀性特征。热处理条件下的显微硬度评价与铸态相比降低了26.52%。水平状态下试件的极限抗拉强度比热处理状态高4.86%,垂直状态下试件的极限抗拉强度比热处理状态高5.55%。水平试件在热处理状态下的抗冲击性比建成状态高12.36%,垂直试件在热处理状态下的抗冲击性比建成状态高18.92%。简而言之,构建方向直接影响通过L-DED工艺制造的部件的机械性能,并且可以通过热处理来改善某些机械性能,例如延展性和韧性。
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引用次数: 11
Investigating sodium phosphate binders for foundry production 研究铸造生产用磷酸钠粘结剂
Q2 ENGINEERING, INDUSTRIAL Pub Date : 2022-05-01 DOI: 10.1016/j.aime.2022.100082
R. Liutyi , I. Petryk , M. Tyshkovets , O. Myslyvchenko , D. Liuta , М. Fyodorov

The results of theoretical and practical research on the synthesis of sodium phosphates from its inorganic salts and the use of these phosphates as binders for the manufacture of molds and cores are presented.

In order to find variants of sodium phosphate synthesis, the processes of interaction of orthophosphoric acid H3PO4 with sodium salts of different types (Na2CO3 carbonate (salt of chemically weak acid), NaCl chloride (salt of chemically strong acid) and tripolyphosphate Na5P3O10 (polyphosphoric salt)) were analyzed. The regularities of the formation of sodium phosphates in all three systems and the conversion of these phosphates when heated in the range from 20 to 1000 оС have been researched.

For the first time, thermodynamic parameters were established and the process of obtaining sodium phosphate through the chemical interaction of orthophosphoric acid with sodium chloride was implemented in the laboratory.

It has also been shown that the chemical interaction of sodium tripolyphosphate with orthophosphoric acid forms the strongest binder, which is a disodium pyrophosphate Na2Н2P2O7.

Synthesized sodium phosphates have an optimal set of functional properties for using in foundry technologies. They provide high strength in compositions with refractory quartz filler and have sufficient thermal stability. Experimentally established, foundry cores based on synthesized binders provide high quality cast surfaces and are easily removed from the internal cavities of cast parts.

介绍了以无机盐为原料合成磷酸钠的理论和实践研究结果,并介绍了磷酸钠作为黏合剂用于模具和芯材制造的研究结果。为了寻找合成磷酸钠的变异,分析了正磷酸H3PO4与不同类型的钠盐(Na2CO3碳酸盐(化学弱酸盐)、氯化钠(化学强酸盐)和三聚磷酸钠Na5P3O10(多磷酸盐))的相互作用过程。研究了三种体系中磷酸钠的形成规律以及在20 ~ 1000℃范围内加热时磷酸钠的转化情况оС。首次建立了热力学参数,并在实验室中实现了正磷酸与氯化钠化学相互作用制得磷酸钠的过程。还表明,三聚磷酸钠与正磷酸的化学相互作用形成最强的粘合剂,即焦磷酸二钠Na2Н2P2O7。合成的磷酸钠具有较好的功能性能,可用于铸造工艺。他们提供高强度的组合物与耐火石英填料,并有足够的热稳定性。实验证明,基于合成粘合剂的铸造芯提供了高质量的铸造表面,并且很容易从铸件的内腔中去除。
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引用次数: 2
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Advances in Industrial and Manufacturing Engineering
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