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Applications of cryogenic method to water vapor sampling from ambient air for isotopes analysis 低温法在环境空气中水蒸气取样用于同位素分析中的应用
Q4 Engineering Pub Date : 2016-12-30 DOI: 10.4217/OPR.2016.38.4.339
Songyi Kim, Yeongcheol Han, S. Hur, Jeonghoon Lee
Stable water vapor isotopes have been utilized as a tracer for studying atmospheric global circulations, climate change and paleoclimate with ice cores. Recently, since laser spectroscopy has been available, water vapor isotopes can be measured more precisely and continuously. Studies of water vapor isotopes have been conducted over the world, but it is the early stage in south Korea. For vapor isotopes study, a cryogenic sampling device for water vapor isotopes has been developed. The cryogenic sampling device consists of the dewar bottle, filled with extremely low temperature material and impinger connected with a vacuum pump. Impinger stays put in the dewar bottle to change the water vapor which passes through the inside of impinger into the solid phase as ice. The fact that water vapor has not sampled completely leads to isotopic fractionation in the impinger. To minimize the isotopic fractionation during sampling water vapor, we have tested the method using a serial connection with two sets of impinger device in the laboratory. We trapped 98.02% of water vapor in the first trap and the isotopic difference of the trapped water vapor between two impinger were about 20‰ and 6‰ for hydrogen and oxygen, respectively. Considering the amount of water vapor trapped in each impinger, the isotopic differences for hydrogen and oxygen were 0.33‰ and 0.06‰, respectively, which is significantly smaller than the precision of isotopic measurements. This work can conclude that there is no significant fractionation during water vapor trapping.
稳定的水蒸气同位素作为示踪剂已被用于研究大气全球环流、气候变化和古气候的冰芯。最近,由于有了激光光谱学,可以更精确和连续地测量水蒸气的同位素。世界各地都在进行水蒸气同位素的研究,但在韩国还处于初级阶段。为了研究水蒸气同位素,研制了一种水蒸气同位素低温采样装置。低温取样装置由装满极低温材料的杜瓦瓶和连接真空泵的冲击器组成。撞击器被放置在杜瓦瓶中,使穿过撞击器内部的水蒸气变成固态的冰。水蒸气没有完全取样的事实导致了撞击器中的同位素分馏。为了最大限度地减少水蒸气取样过程中的同位素分馏,我们在实验室中用两套冲击器进行了串联测试。第一个捕集器捕获了98.02%的水蒸气,两个捕集器捕获的水蒸气中氢和氧的同位素差异分别约为20‰和6‰。考虑到每个撞击器捕获的水蒸气量,氢和氧的同位素差异分别为0.33‰和0.06‰,明显小于同位素测量的精度。这项工作可以得出结论,在水蒸气捕获过程中没有显著的分馏。
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引用次数: 2
Research Trend Analysis on International Research Collaboration in Regard to Antarctic Studies 南极研究国际合作研究趋势分析
Q4 Engineering Pub Date : 2016-09-30 DOI: 10.4217/OPR.2016.38.3.209
Duckhee Jang, Yong-Jin Choi, Jin-Young Kim
The purpose of this study is to analyze research activities related to Antarctic science through a bibliographic study and to understand and evaluate the implications. This study is based on 78,445 articles which were retrieved from the Science Citation Index(SCI) database during the period 1998−2015. Through a quantitative analysis and a Social Network Analysis, we made several findings and drew out the implications. First, many countries, in general, have increased multi-national research cooperation in order to enhance research productivity. However, Korea’s cooperative research activity is below the average level. Second, considering the 4 centrality indexes, which are derived from the SNA, Korea had a lower score in terms of centrality indexes. Based on these findings, Korea should formulate a more dynamic or proactive strategy in order to enhance its participation in international research cooperation efforts. Korea, the 10th country to build two or more research bases in Antarctica, should make greater efforts to bring the appropriate level of the phase.
本研究的目的是通过文献研究来分析与南极科学有关的研究活动,并了解和评估其影响。本研究基于1998 - 2015年间从科学引文索引(SCI)数据库中检索的78,445篇文章。通过定量分析和社会网络分析,我们得出了一些发现,并得出了启示。首先,一般来说,许多国家增加了多国研究合作,以提高研究生产力。但是,韩国的合作研究活动低于平均水平。其次,从SNA得出的4个中心性指数来看,韩国的中心性指数得分较低。以这些研究结果为基础,韩国应该制定更积极主动的战略,以加强参与国际研究合作的努力。作为第10个在南极建立2个以上研究基地的国家,韩国应该为达到适当的水平而努力。
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引用次数: 3
Economic Feasibility Study for Commercial Production of Bio-hydrogen 生物氢商业化生产的经济可行性研究
Q4 Engineering Pub Date : 2016-09-30 DOI: 10.4217/OPR.2016.38.3.225
Se-hun Park, Y. Yoo, S. Kang
This project sought to conduct an economic feasibility study regarding the commercial production of bio-hydrogen by the marine hyperthermophilic archaeon, Thermococcus onnurineus NA1 using carbon monoxide-containing industrial off-gas. We carried out the economic evaluation of the biohydrogen production process using the raw material of steel mill by-product gas. The process parameter was as follows: H2 production rate was 5.6 L/L/h; the conversion of carbon monoxide was 60.7%. This project established an evaluation criterion for about 10,000 tonne/year. Inflation factors were considered as 3%. The operating costs were recalculated based on prices in 2014. The total investment required for development was covered 30% by capital and 70% by a loan. The operation cost for the 0.5-year test and integration, and the cost for the first three months in the 50% production period were considered as the working capital in the cost estimation. The costs required for the rental of office space, facilities, and other related costs from the construction through to full-scale production periods were considered as continuing expenses. Materials, energy, waste disposal and other charges were considered as the operating cost of the development system. Depreciation, tax, maintenance and repair, insurance, labor, interest rate charges, general and administrative costs, lubrication and miscellaneous expenses were also calculated. The hydrogen price was set at US$ 4.15/kg for the economic evaluation. As a result, the process was considered to be economical with the payback period of 6.3 years, NPV of 18 billion Won and IRR of 26.7%.
本项目旨在就利用含一氧化碳的工业废气,利用海洋超嗜热古细菌热球菌(Thermococcus onnurineus NA1)商业化生产生物氢进行经济可行性研究。对以炼钢厂副产气为原料的生物制氢工艺进行了经济评价。工艺参数为:产氢速率为5.6 L/L/h;一氧化碳的转化率为60.7%。本项目建立了约1万吨/年的评价标准。通货膨胀因素考虑为3%。运营成本根据2014年的价格重新计算。开发所需的总投资30%由资本支付,70%由贷款支付。在成本估算中,将0.5年试验集成的运行成本和50%生产期前三个月的成本作为营运资金。从建造到全面生产期间租用办公空间、设施和其他有关费用所需的费用被视为持续费用。材料、能源、废物处理和其他费用被认为是开发系统的运行成本。折旧、税收、维护和维修、保险、劳动力、利率、一般和行政费用、润滑和杂项费用也被计算在内。为了进行经济评估,氢的价格设定为每公斤4.15美元。因此,投资回收期为6.3年,NPV为180亿韩元,IRR为26.7%,具有经济性。
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引用次数: 2
Summary of 2014 JCOMM Pilot Inter-Comparison Project for Seawater Salinity Measurements 2014年JCOMM海水盐度测量中试比对项目综述
Q4 Engineering Pub Date : 2016-09-30 DOI: 10.4217/OPR.2016.38.3.247
Jung-Han Lee, Eun-soo Kim, Yong-Kuk Lee
The inter-comparison project for seawater salinity measurements, in which 25 laboratories from 16 countries took part, was conducted by JCOMM (Joint WMO/IOC Technical Commission for Oceanography and Marine Meteorology) for the first time in 2014. Two seawater samples of different salinity values ranging from 30−35 and 20−25 for Sample A and Sample B respectively and which had sufficient homogeneity and stability were distributed to all participants. Participants measured the salinity in their own laboratories at least 3 times and reported the results. Statistical treatments were applied to the results to assess discrepancies among laboratories. 20 out of the 25 laboratories used laboratory salinometers and statistics for this group were denoted as belonging to group α; while 5 out of the 25 laboratories used hand-held measuring instruments and statistics for this group were denoted as belonging to group β. Bias described as discrepancy among laboratories in group α was within ± 0.001 and expanded uncertainty (k = 2) was in the vicinity of 0.002. The bias and the uncertainty of Korea Institute of Ocean Science and Technology (KIOST), in group α, were 0.000 and 0.002, respectively. The biases of group β were greater than group α because of constraints related to instrument accuracy. Biases from 3 laboratories in group β exceed the accuracy specification of the corresponding instruments. Considering that the uncertainty of Standard Seawater (SSW) is of the order 0.001 to 0.002, the inter-comparison results show that 16 laboratories among the 25 laboratories made high quality measurements, largely indistinguishable from one another.
2014年,JCOMM (WMO/IOC海洋学和海洋气象学联合技术委员会)首次开展了海水盐度测量相互比较项目,有来自16个国家的25个实验室参与。样品A和样品B的盐度值分别为30 ~ 35和20 ~ 25,具有足够的均匀性和稳定性。参与者在自己的实验室中测量了至少3次盐度,并报告了结果。对结果进行统计处理,以评估实验室之间的差异。25个实验室中有20个使用实验室盐度计,该组的统计数据被标记为属于α组;而25个实验室中有5个使用手持式测量仪器,该组的统计数据被表示为属于β组。α组实验室间差异所描述的偏差在±0.001以内,扩展不确定度(k = 2)在0.002附近。在α组中,韩国海洋科学技术研究院(KIOST)的偏倚和不确定度分别为0.000和0.002。由于仪器精度的限制,β组的偏倚大于α组。β组中3个实验室的偏差超过了相应仪器的精度规范。考虑到标准海水(SSW)的不确定度在0.001 ~ 0.002之间,对比结果表明,25个实验室中有16个实验室的测量质量较高,彼此之间基本无法区分。
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引用次数: 0
Assessment of Persistent Organic and Heavy Metal Contamination in Busan Coast: Application of Sediment Quality Index 釜山海岸持久性有机和重金属污染评价:沉积物质量指数的应用
Q4 Engineering Pub Date : 2016-09-30 DOI: 10.4217/OPR.2016.38.3.171
G. Han, S. Hong, W. Shim, K. Ra, Kyung-Tae Kim, S. Ha, Mi Jang, G. Kim
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引用次数: 6
CVM을 이용한 바다낚시 자원풍도 증가에 대한 지불의사액 추정에 관한 연구 利用CVM增加海钓资源丰度的支付预期研究
Q4 Engineering Pub Date : 2016-09-30 DOI: 10.4217/OPR.2016.38.3.235
남종오, 박철형
The purpose of this study is to estimate the Willingness To Payment (WTP) of sea-anglers regarding the increase in the abundance of fish resources resulting from the Korean vessel buy-back program using the contingent valuation method. Data was collected through sample surveys of 352 seaanglers across the nation in 2015. If a 20% increase in the abundance of fish resources resulted from the vessel buy-back program, WTP estimates of sea-anglers per recreational fishing trip were 9,570 won on truncated mean, 16,528 won on mean, and 35,830 won on median, respectively. Additionally, when the number of annual total recreational fishing trips in Korea were estimated as 22,700 thousand trips, the annual increase in national welfare through recreational fishing was estimated to be 217.2 billion won on the truncated mean, 375.2 billion won on the mean, and 813.3 billion won on the median, respectively.
本研究的目的是利用条件估值法估计韩国渔船回购计划所带来的鱼类资源丰度增加对海洋垂钓者的支付意愿(WTP)。数据是通过2015年对全国352名渔民的抽样调查收集的。如果因船舶回购计划而增加20%的鱼类资源,每次休闲钓鱼的WTP分别为截断平均值9570韩元、平均值16528韩元、中位数35830韩元。另外,如果以每年227万次的休闲钓鱼次数为标准计算,每年通过休闲钓鱼带来的国民福利增加额的截尾平均值为2172亿韩元,平均值为3752亿韩元,中间值为8133亿韩元。
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引用次数: 0
Reconstruction of Nitrate Utilization Rate Change Based on Diatom-bound Nitrogen Isotope Values in the Central Slope Area of the Bering Sea during the Early Pleistocene (2.4-1.25 Ma) 早更新世(2.4-1.25 Ma)白令海中央斜坡区硅藻结合氮同位素值重建硝酸盐利用率变化
Q4 Engineering Pub Date : 2016-09-30 DOI: 10.4217/OPR.2016.38.3.195
Sunghan Kim, B. Khim
Because the high latitude region in the North Pacific is characterized by high primary production in the surface water enriched with nutrients, it is important to understand the variation of surface water productivity and associated nutrient variability in terms of global carbon cycle. Surface water productivity change or its related nutrient utilization rate during the Northern Hemisphere Glaciation (NHG; ca. 2.73 Ma) has been reported, but little is known about such circumstances under gradual climate cooling since the NHG. Bulk nitrogen isotope (δ 15 N bulk ) of sedimentary organic matter has been used for the reconstruction of nutrient utilization rate in the surface water. However, sedimentary organic matter experiences diagenesis incessantly during sinking through the water column and after burial within the sediments. Thus, in this study we examine the degree of nitrate utilization rate during the early Pleistocene (2.4−1.25 Ma) since the NHG, using the diatom-bound nitrogen isotope (δ 15 N db ), which is known to be little influenced by diagenesis, from Site U1343 in the Bering slope area. δ 15 N db values range from ~0.5 to 5.5‰, which is lower than δ 15 N bulk values, but they vary with larger amplitude. Variation patterns between δ 15 N db values and biogenic opal concentration are generally consistent, which indicates that the nitrate utilization rate is closely related to opal productivity change in the surface water. A positive correlation between opal productivity and nitrate utilization rate was observed, which is different from the other high latitude regions in the North Pacific. The main reason for this contrasting relationship is that the primary production in the surface water at Site U1343 is influenced mostly by the degree of sea ice formation. Still, although concerns about diagenetic alteration have been avoided by using δ 15 N db , the effects of the preservation state of biogenic opal and the speciesdependent isotopic fractionation on δ 15 N db should be assessed in the future studies.
由于北太平洋高纬度地区具有丰富养分的地表水初级生产力高的特点,因此从全球碳循环的角度了解地表水生产力的变化及其相关的养分变异具有重要意义。北半球冰期地表水生产力变化及其相关养分利用率大约2.73 Ma)已经有报道,但是对于自NHG以来气候逐渐变冷的情况知之甚少。利用沉积有机质体积氮同位素(δ 15 N体积)重建了地表水的养分利用率。然而,沉积有机质在通过水柱下沉和埋藏于沉积物中后,经历了不断的成岩作用。因此,本研究利用白令海陆坡区U1343遗址的硅藻结合氮同位素(δ 15 N db)研究了NHG以来早更新世(2.4 ~ 1.25 Ma)的硝酸盐利用程度,该同位素已知受成岩作用影响较小。δ 15 N db值在~0.5 ~ 5.5‰之间,低于δ 15 N bulk值,但变化幅度较大。δ 15 N db值与生物成因蛋白石浓度的变化规律基本一致,表明硝酸盐利用率与地表水蛋白石生产力变化密切相关。与北太平洋其他高纬度地区不同,该地区蛋白石产量与硝酸盐利用率呈显著正相关。形成这种对比关系的主要原因是U1343站点地表水的初级产量主要受海冰形成程度的影响。尽管利用δ 15 N db可以避免对成岩蚀变的担忧,但生物成因蛋白石的保存状态和物种依赖的同位素分馏对δ 15 N db的影响应在未来的研究中进行评估。
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引用次数: 1
Impact of Outliers on the Statistical Measures of the Environmental Monitoring Data in Busan Coastal Sea 离群值对釜山沿海环境监测数据统计度量的影响
Q4 Engineering Pub Date : 2016-06-30 DOI: 10.4217/OPR.2016.38.2.149
Hong-Yeon Cho, Ki-Seop Lee, Soon-Mo Ahn
The statistical measures of the coastal environmental data are used in a variety of statistical inferences, hypothesis tests, and data-driven modeling. If the measures are biased, then the statistical estimations and models may also be biased and this potential for bias is great when data contain some outliers defined as extraordinary large or small data values. This study aims to suggest more robust statistical measures as alternatives to more commonly used measures and to assess the performance these robust measures through a quantitative evaluation of more typical measures, such as in terms of locations, spreads, and shapes, with regard to environmental monitoring data in the Busan coastal sea. The detection of outliers within the data was carried out on the basis of Rosner’s test. About 5−10% of the nutrient data were found to contain outliers based on Rosner’s test. After removal (zero-weighting) of the outliers in the data sets, the relative change ratios of the mean and standard deviation between before and after outlier-removal conditions revealed the figures 13 and 33%, respectively. The variation magnitudes of skewness and kurtosis are 1.36 and 8.11 in a decreasing trend, respectively. On the other hand, the change ratios for more robust measures regarding the mean and standard deviation are 3.7−10.5%, and the variation magnitudes of robust skewness and kurtosis are about only 2−4% of the magnitude of the non-robust measures. The robust measures can be regarded as outlier-resistant statistical measures based on the relatively small changes in the scenarios before and after outlier removal conditions.
沿海环境数据的统计度量用于各种统计推断、假设检验和数据驱动建模。如果测量是有偏差的,那么统计估计和模型也可能是有偏差的,当数据包含一些异常值(定义为异常大或异常小的数据值)时,这种偏差的可能性很大。本研究旨在提出更可靠的统计措施,作为更常用措施的替代方案,并通过对釜山沿海环境监测数据中更典型的措施(如地点、分布和形状)的定量评估,评估这些可靠措施的性能。在Rosner检验的基础上对数据中的异常值进行检测。根据Rosner的测试,大约5 - 10%的营养数据被发现含有异常值。数据集中的离群值去除(零加权)后,离群值去除前后的均值和标准差的相对变化率分别为图13和33%。偏度和峰度的变异量分别为1.36和8.11,呈减小趋势。另一方面,更为稳健的均值和标准差的变化率为3.7 ~ 10.5%,稳健偏度和峰度的变化幅度仅为非稳健措施的2 ~ 4%。鲁棒性措施可以看作是基于异常值去除条件前后情景变化相对较小的抗异常值统计措施。
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引用次数: 4
Interannual Variability of the Water Masses Observed in the Tropical Northwestern Pacific 热带西北太平洋观测到的水团年际变化
Q4 Engineering Pub Date : 2016-06-30 DOI: 10.4217/OPR.2016.38.2.161
Eunji Choi, D. Jeon
The interannual variability of the water masses was analyzed from the CTD data measured in the tropical northwestern Pacific from 2006 to 2014. There are two typical water masses NPTW and NPIW that reveal the interannual variability in the survey area, in addition to two other water masses; the surface water mass TSW with a large seasonal variability and the deep water mass AACDW with a constant temperature-salinity characteristic at the depths deeper than 2,000 meters. In 2012 and 2014 NPTW was the most widely extended horizontally and thicker than 100 meters vertically, which was found over the entire survey area. However, NPTW was reduced and became much narrower in 2009 than in the other years. NPIW seemed to expand southwards from the north of 21˚N to 15oN in 2008 and in 2012, which showed the salinity minimum in 2013 (< 34.15 psu). The sea surface height estimated by Absolute Dynamic Topography (ADT) approximately along 135˚E section showed the high peaks (> 1.45 dyn•m) between 16˚N and 18˚N during the periods between 2007 and 2009 and between 2012 and 2013; the former peak lasted wider and longer in latitude and time (about three times) than the latter. The vertical section of the geostrophic currents in the upper 1,000 meters shows that there was a mesoscale pattern of repeated eastward and westward flows a few times in some years (2010 and 2014), which seemed to disappear in some other years (2008 and 2012); the former was closely related to the mesoscale eddies and the latter implied the pattern with the permanent currents. The persistent eastward flow between 17oN and 19oN seems to be related to the Subtropical Countercurrent (STCC).
利用2006 - 2014年热带西北太平洋CTD观测资料分析了水团的年际变化。调查区有两个典型水团NPTW和NPIW,另外还有两个水团反映了年际变化;表层水质量TSW具有较大的季节变化,深层水质量AACDW在2000米以上具有恒温-盐度特征。2012年和2014年NPTW水平延伸范围最广,垂直厚度超过100米,覆盖了整个调查区域。然而,与其他年份相比,NPTW在2009年减少并缩小了很多。NPIW在2008年和2012年有从21°N以北向15°N向南扩展的趋势,其中盐度最小值出现在2013年(< 34.15 psu)。2007 ~ 2009年和2012 ~ 2013年,沿135˚E剖面的绝对动力地形(ADT)估算的海面高度在16˚N ~ 18˚N之间出现峰值(> 1.45 dyn•m);前者的高峰在纬度和时间上比后者更宽更长(约为后者的三倍)。1000 m以上地转流垂直剖面显示,在某些年份(2010年和2014年)存在数次东向和西向反复流动的中尺度格局,而在另一些年份(2008年和2012年)则似乎消失了;前者与中尺度涡旋密切相关,后者与恒流密切相关。17oN和19oN之间持续的东流可能与副热带逆流有关。
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引用次数: 0
Effects of Recombinant Aquaporin 3 and Seawater Acclimation on the Expression of Aquaporin 3 and 8 mRNAs in the Parr and Smolt Stages of Rainbow Trout, Oncorhynchus mykiss 重组水通道蛋白3和海水驯化对虹鳟幼期和幼期水通道蛋白3和8 mrna表达的影响
Q4 Engineering Pub Date : 2016-06-30 DOI: 10.4217/OPR.2016.38.2.103
Na Na Kim, Young Jae Choi, S. Lim, Bong-Seok Kim, C. Choi
This study aimed to examine the role of two aquaporin isoforms (AQP3 and AQP8) in response to the hyperosmotic challenge of transitioning from freshwater (FW) to seawater (SW) during parr and smoltification (smolt) using the rainbow trout, Oncorhynchus mykiss. We examined the changes in the expression of AQPs mRNAs in the gills and intestine of the parr and smolt stages of rainbow trout transferred from FW to SW using quantitative real-time PCR in an osmotically changing environment [FW, SW, and recombinant AQP3 (rAQP3) injection at two dosage rates]. Correspondingly, AQPs were greater during smoltification than during parr stages in the rainbow trout. Plasma osmolality and gill Na⁺/K⁺-ATPase activity increased when the fish were exposed to SW, but these parameters decreased when the fish were exposed to SW following treatment with rAQP3 during the transition to seawater. Our results suggest that AQPs play an important role in water absorbing mechanisms associated with multiple AQP isoforms in a hyperosmotic environment.
本研究旨在研究两种水通道蛋白(AQP3和AQP8)在虹鳟交配和孵化(smolt)期间从淡水(FW)过渡到海水(SW)的高渗挑战中的作用。在渗透变化的环境下,我们使用实时荧光定量PCR检测了虹鳟鱼从FW转移到SW的幼鱼期和幼鱼期的鳃和肠道中AQPs mrna的表达变化[FW、SW和重组AQP3 (rAQP3)注射两种剂量率]。相应的,虹鳟鱼在孵育期AQPs比交配期要高。当鱼暴露于SW时,血浆渗透压和鳃Na + /K + - atp酶活性升高,但在过渡到海水的过程中,用rAQP3处理SW后,这些参数降低。我们的研究结果表明,在高渗环境中,AQP在与多种AQP亚型相关的吸水机制中发挥重要作用。
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引用次数: 1
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Ocean and Polar Research
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