首页 > 最新文献

Hanneng Cailiao/Chinese Journal of Energetic Materials最新文献

英文 中文
纳米KClO 4 /CNTs的制备及其与铝粉爆燃发光强度的测定 纳米KClO 4 /CNTs的制备及其与铝粉爆燃发光强度的测定
Q3 Engineering
Hanneng Cailiao/Chinese Journal of Energetic Materials
Pub Date : 2016-01-01 DOI: 10.11943/j.issn.1006-9941.2016.10.009
霸书红, 关雪楠, 邹彤, 程林, 张庆利, 王树涛, 杜雪峰
{"title":"纳米KClO 4 /CNTs的制备及其与铝粉爆燃发光强度的测定","authors":"霸书红, 关雪楠, 邹彤, 程林, 张庆利, 王树涛, 杜雪峰","doi":"10.11943/j.issn.1006-9941.2016.10.009","DOIUrl":"https://doi.org/10.11943/j.issn.1006-9941.2016.10.009","url":null,"abstract":"","PeriodicalId":35753,"journal":{"name":"Hanneng Cailiao/Chinese Journal of Energetic Materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75628513","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
3,3′-二氨基-4,4′-氧化偶氮呋咱的热分解行为及热力学性质 3,3′-二氨基-4,4′-氧化偶氮呋咱的热分解行为及热力学性质
Q3 Engineering
Hanneng Cailiao/Chinese Journal of Energetic Materials
Pub Date : 2016-01-01 DOI: 10.11943/J.ISSN.1006-9941.2016.12.009
何乃珍, 索志荣, 郭蓉, 张勇, 刘如沁
{"title":"3,3′-二氨基-4,4′-氧化偶氮呋咱的热分解行为及热力学性质","authors":"何乃珍, 索志荣, 郭蓉, 张勇, 刘如沁","doi":"10.11943/J.ISSN.1006-9941.2016.12.009","DOIUrl":"https://doi.org/10.11943/J.ISSN.1006-9941.2016.12.009","url":null,"abstract":"","PeriodicalId":35753,"journal":{"name":"Hanneng Cailiao/Chinese Journal of Energetic Materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84614766","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
CF 3 SO 3 H/H 2 O喷射结晶制备纳米TATB CF 3 SO 3 H/H 2 O喷射结晶制备纳米TATB
Q3 Engineering
Hanneng Cailiao/Chinese Journal of Energetic Materials
Pub Date : 2016-01-01 DOI: 10.11943/J.ISSN.1006-9941.2016.10.008
王彦群, 王军, 杨光成
{"title":"CF 3 SO 3 H/H 2 O喷射结晶制备纳米TATB","authors":"王彦群, 王军, 杨光成","doi":"10.11943/J.ISSN.1006-9941.2016.10.008","DOIUrl":"https://doi.org/10.11943/J.ISSN.1006-9941.2016.10.008","url":null,"abstract":"","PeriodicalId":35753,"journal":{"name":"Hanneng Cailiao/Chinese Journal of Energetic Materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73779365","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
5,5′-联四唑-1,1′-二氧-1,2,4-三氮唑含能离子盐的合成、表征及热行为 5,5′-联四唑-1,1′-二氧-1,2,4-三氮唑含能离子盐的合成、表征及热行为
Q3 Engineering
Hanneng Cailiao/Chinese Journal of Energetic Materials
Pub Date : 2016-01-01 DOI: 10.11943/j.issn.1006-9941.2016.10.005
尚宇, 金波, 刘强强, 彭汝芳, 赵凤起, 赵钧, 张青春, 楚士晋
{"title":"5,5′-联四唑-1,1′-二氧-1,2,4-三氮唑含能离子盐的合成、表征及热行为","authors":"尚宇, 金波, 刘强强, 彭汝芳, 赵凤起, 赵钧, 张青春, 楚士晋","doi":"10.11943/j.issn.1006-9941.2016.10.005","DOIUrl":"https://doi.org/10.11943/j.issn.1006-9941.2016.10.005","url":null,"abstract":"","PeriodicalId":35753,"journal":{"name":"Hanneng Cailiao/Chinese Journal of Energetic Materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88180151","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
新型绿色起爆药1,1′-二羟基-5,5′-联四唑钾的晶体结构及性能研究 新型绿色起爆药1,1′-二羟基-5,5′-联四唑钾的晶体结构及性能研究
Q3 Engineering
Hanneng Cailiao/Chinese Journal of Energetic Materials
Pub Date : 2016-01-01 DOI: 10.11943/J.ISSN.1006-9941.2016.12.007
张至斌, 尹磊, 李彤, 秦涧, 殷昕, 张建国
{"title":"新型绿色起爆药1,1′-二羟基-5,5′-联四唑钾的晶体结构及性能研究","authors":"张至斌, 尹磊, 李彤, 秦涧, 殷昕, 张建国","doi":"10.11943/J.ISSN.1006-9941.2016.12.007","DOIUrl":"https://doi.org/10.11943/J.ISSN.1006-9941.2016.12.007","url":null,"abstract":"","PeriodicalId":35753,"journal":{"name":"Hanneng Cailiao/Chinese Journal of Energetic Materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88429660","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
CL-20/HMX共晶与共混物的分子动力学模拟 CL-20/HMX共晶与共混物的分子动力学模拟
Q3 Engineering
Hanneng Cailiao/Chinese Journal of Energetic Materials
Pub Date : 2016-01-01 DOI: 10.11943/J.ISSN.1006-9941.2016.04.002
陶俊, 王晓峰, 赵省向, 刁小强, 王彩玲, 韩仲熙
为比较六硝基六氮杂异戊兹烷（CL-20）／环四亚甲基四硝胺（HMX）的共晶与共混物的性能，分别构建了CL-20：HMX摩尔比为2：1的共晶结构及共混物结构。用分子动力学（MD）方法模拟了CL-20／HMX的共晶体系及共混体系的力学性能、结构稳定性及径向分布函数。模拟及计算结果表明：CL-20／HMX共晶工艺能显著改善体系的抗形变能力及延展性。共晶结构的弹性模量要显著大于共混结构。最大键长（Lmax）的排序为：CL-20／HMX共混〉e-CL-20〉β-HMX〉CL-20／HMX共晶。以范德华力为主的作用力“敏化”了CL-20／HMX共混体系的结构。CL-20／HMX共晶结构的内聚能密度（CED）值要远远大于CL-20／HMX共混结构的CED值。CL-20／HMX共晶体系中存在着长度相对较短CH…O氢键导致其感度较低。
为比较六硝基六氮杂异戊兹烷（CL-20）／环四亚甲基四硝胺（HMX）的共晶与共混物的性能，分别构建了CL-20：HMX摩尔比为2：1的共晶结构及共混物结构。用分子动力学（MD）方法模拟了CL-20／HMX的共晶体系及共混体系的力学性能、结构稳定性及径向分布函数。模拟及计算结果表明：CL-20／HMX共晶工艺能显著改善体系的抗形变能力及延展性。共晶结构的弹性模量要显著大于共混结构。最大键长（Lmax）的排序为：CL-20／HMX共混〉e-CL-20〉β-HMX〉CL-20／HMX共晶。以范德华力为主的作用力“敏化”了CL-20／HMX共混体系的结构。CL-20／HMX共晶结构的内聚能密度（CED）值要远远大于CL-20／HMX共混结构的CED值。CL-20／HMX共晶体系中存在着长度相对较短CH…O氢键导致其感度较低。
{"title":"CL-20/HMX共晶与共混物的分子动力学模拟","authors":"陶俊, 王晓峰, 赵省向, 刁小强, 王彩玲, 韩仲熙","doi":"10.11943/J.ISSN.1006-9941.2016.04.002","DOIUrl":"https://doi.org/10.11943/J.ISSN.1006-9941.2016.04.002","url":null,"abstract":"为比较六硝基六氮杂异戊兹烷（CL-20）／环四亚甲基四硝胺（HMX）的共晶与共混物的性能，分别构建了CL-20：HMX摩尔比为2：1的共晶结构及共混物结构。用分子动力学（MD）方法模拟了CL-20／HMX的共晶体系及共混体系的力学性能、结构稳定性及径向分布函数。模拟及计算结果表明：CL-20／HMX共晶工艺能显著改善体系的抗形变能力及延展性。共晶结构的弹性模量要显著大于共混结构。最大键长（Lmax）的排序为：CL-20／HMX共混〉e-CL-20〉β-HMX〉CL-20／HMX共晶。以范德华力为主的作用力“敏化”了CL-20／HMX共混体系的结构。CL-20／HMX共晶结构的内聚能密度（CED）值要远远大于CL-20／HMX共混结构的CED值。CL-20／HMX共晶体系中存在着长度相对较短CH…O氢键导致其感度较低。","PeriodicalId":35753,"journal":{"name":"Hanneng Cailiao/Chinese Journal of Energetic Materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72839250","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
1,1-二苦氨基-2,2-二硝基乙烯的合成及性能预估 1,1-二苦氨基-2,2-二硝基乙烯的合成及性能预估
Q3 Engineering
Hanneng Cailiao/Chinese Journal of Energetic Materials
Pub Date : 2016-01-01 DOI: 10.11943/J.ISSN.1006-9941.2016.06.001
贾亚楠, 申程, 王鹏程, 陆明
以2，4，6-三硝基氯苯,1，1-二氨基-2，2-二硝基乙烯（FOX-7）为原料，咪唑与氟化钾作为催化剂，缩合合成了1，1-二苦氨基-2，2-二硝基乙烯（TFT），熔点为225～226℃，收率71．3％。采用红外光谱、核磁共振、质谱对其进行了表征。通过差示扫描量热研究了其热性能，热分解温度为331．3℃，热稳定性优于FOX-7。用Monte-Carlo方法估算其理论密度为1．85g·cm^-1，用Kamlet—Jacobs公式估算其爆热为1751．26J·g^-1，爆速为8．83km·s^-1，爆压为36．25GPa；撞击感度H50的计算值为156cm。理论计算的结果说明该材料较FOX-7钝感，爆压高于FOX-7。
以2，4，6-三硝基氯苯,1，1-二氨基-2，2-二硝基乙烯（FOX-7）为原料，咪唑与氟化钾作为催化剂，缩合合成了1，1-二苦氨基-2，2-二硝基乙烯（TFT），熔点为225～226℃，收率71．3％。采用红外光谱、核磁共振、质谱对其进行了表征。通过差示扫描量热研究了其热性能，热分解温度为331．3℃，热稳定性优于FOX-7。用Monte-Carlo方法估算其理论密度为1．85g·cm^-1，用Kamlet—Jacobs公式估算其爆热为1751．26J·g^-1，爆速为8．83km·s^-1，爆压为36．25GPa；撞击感度H50的计算值为156cm。理论计算的结果说明该材料较FOX-7钝感，爆压高于FOX-7。
{"title":"1,1-二苦氨基-2,2-二硝基乙烯的合成及性能预估","authors":"贾亚楠, 申程, 王鹏程, 陆明","doi":"10.11943/J.ISSN.1006-9941.2016.06.001","DOIUrl":"https://doi.org/10.11943/J.ISSN.1006-9941.2016.06.001","url":null,"abstract":"以2，4，6-三硝基氯苯,1，1-二氨基-2，2-二硝基乙烯（FOX-7）为原料，咪唑与氟化钾作为催化剂，缩合合成了1，1-二苦氨基-2，2-二硝基乙烯（TFT），熔点为225～226℃，收率71．3％。采用红外光谱、核磁共振、质谱对其进行了表征。通过差示扫描量热研究了其热性能，热分解温度为331．3℃，热稳定性优于FOX-7。用Monte-Carlo方法估算其理论密度为1．85g·cm^-1，用Kamlet—Jacobs公式估算其爆热为1751．26J·g^-1，爆速为8．83km·s^-1，爆压为36．25GPa；撞击感度H50的计算值为156cm。理论计算的结果说明该材料较FOX-7钝感，爆压高于FOX-7。","PeriodicalId":35753,"journal":{"name":"Hanneng Cailiao/Chinese Journal of Energetic Materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78105021","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
含能材料中间体3,7,10-三氧代-2,4,6,8,9,11-六苄基-2,4,6,8,9,11-六氮杂[3,3,3]螺桨烷（HBPTO）的合成、表征及工艺改进 含能材料中间体3,7,10-三氧代-2,4,6,8,9,11-六苄基-2,4,6,8,9,11-六氮杂[3,3,3]螺桨烷（HBPTO）的合成、表征及工艺改进
Q3 Engineering
Hanneng Cailiao/Chinese Journal of Energetic Materials
Pub Date : 2016-01-01 DOI: 10.11943/J.ISSN.1006-9941.2016.08.007
王锡杰, 毕福强, 肖川, 王伯周, 张俊林, 周诚, 胡银
3,7,10-三氧代-2,4,6,8,9,11-六苄基-2,4,6,8,9,11-六氮杂[3,3,3]螺桨烷（HBPTO）是合成高能量密度材料2,4,6,8,9,11-六硝基-2,4,6,8,9,11-六氮杂[3,3,3]螺桨烷的关键中间体。以尿酸（UC）和铁氰化钾为起始原材料,经氧化-加成、缩合、取代反应等合成了目标化合物HBPTO,总收率8.58%。用1H NMR, 13C NMR, FT-IR, MS及元素分析对其结构进行了表征。探讨了中间体二氨基甘脲（DAGU）的合成反应机理,揭示了其微观反应过程。优化了合成DAGU的工艺条件。改进了3,7,10-三氧代-2,4,6,8,9,11-六氮杂[3,3,3]螺桨烷（PTO）的合成工艺。自行设计了经DAGU与N,N′-羰基二咪唑的一步缩合反应合成PTO的新方法; 优化合成DAGU的最佳工艺条件为： n（UC）∶n（K3Fe（CN）3）=1∶4.2,反应温度为25 ℃,反应时间为0.5 h,收率为43.2%。
3,7,10-三氧代-2,4,6,8,9,11-六苄基-2,4,6,8,9,11-六氮杂[3,3,3]螺桨烷（HBPTO）是合成高能量密度材料2,4,6,8,9,11-六硝基-2,4,6,8,9,11-六氮杂[3,3,3]螺桨烷的关键中间体。以尿酸（UC）和铁氰化钾为起始原材料,经氧化-加成、缩合、取代反应等合成了目标化合物HBPTO,总收率8.58%。用1H NMR, 13C NMR, FT-IR, MS及元素分析对其结构进行了表征。探讨了中间体二氨基甘脲（DAGU）的合成反应机理,揭示了其微观反应过程。优化了合成DAGU的工艺条件。改进了3,7,10-三氧代-2,4,6,8,9,11-六氮杂[3,3,3]螺桨烷（PTO）的合成工艺。自行设计了经DAGU与N,N′-羰基二咪唑的一步缩合反应合成PTO的新方法; 优化合成DAGU的最佳工艺条件为： n（UC）∶n（K3Fe（CN）3）=1∶4.2,反应温度为25 ℃,反应时间为0.5 h,收率为43.2%。
{"title":"含能材料中间体3,7,10-三氧代-2,4,6,8,9,11-六苄基-2,4,6,8,9,11-六氮杂[3,3,3]螺桨烷（HBPTO）的合成、表征及工艺改进","authors":"王锡杰, 毕福强, 肖川, 王伯周, 张俊林, 周诚, 胡银","doi":"10.11943/J.ISSN.1006-9941.2016.08.007","DOIUrl":"https://doi.org/10.11943/J.ISSN.1006-9941.2016.08.007","url":null,"abstract":"3,7,10-三氧代-2,4,6,8,9,11-六苄基-2,4,6,8,9,11-六氮杂[3,3,3]螺桨烷（HBPTO）是合成高能量密度材料2,4,6,8,9,11-六硝基-2,4,6,8,9,11-六氮杂[3,3,3]螺桨烷的关键中间体。以尿酸（UC）和铁氰化钾为起始原材料,经氧化-加成、缩合、取代反应等合成了目标化合物HBPTO,总收率8.58%。用1H NMR, 13C NMR, FT-IR, MS及元素分析对其结构进行了表征。探讨了中间体二氨基甘脲（DAGU）的合成反应机理,揭示了其微观反应过程。优化了合成DAGU的工艺条件。改进了3,7,10-三氧代-2,4,6,8,9,11-六氮杂[3,3,3]螺桨烷（PTO）的合成工艺。自行设计了经DAGU与N,N′-羰基二咪唑的一步缩合反应合成PTO的新方法; 优化合成DAGU的最佳工艺条件为： n（UC）∶n（K3Fe（CN）3）=1∶4.2,反应温度为25 ℃,反应时间为0.5 h,收率为43.2%。","PeriodicalId":35753,"journal":{"name":"Hanneng Cailiao/Chinese Journal of Energetic Materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79111662","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
1,1′-二羟基-5,5′-联四唑金属盐的制备及热分解动力学 1,1′-二羟基-5,5′-联四唑金属盐的制备及热分解动力学
Q3 Engineering
Hanneng Cailiao/Chinese Journal of Energetic Materials
Pub Date : 2016-01-01 DOI: 10.11943/j.issn.1006-9941.2016.06.004
王杰群, 王鹏程, 陆明
1，1’-二羟基-5，5’-联四唑类化合物是近年来高能钝感材料研究的热点，为研究这类化合物的热安全性，用差示扫描量热法（DSC）和热重法（TG）在升温速率分别为5，10，15，20K·min^-1的条件下研究了1，1’-二羟基-5，5’-联四唑钴盐（1，1’-BTOCo）、铜盐（1，1’-BTOCu）和铅盐（1，1’-BTOPb）的热分解过程。分别用Kissinger法和Ozawa法计算了三种盐的表观活化能（Ek和E0）、指前因子（Ak），得到其热分解动力学参数和热分解机理函数。结果表明，1，1’-BTOCo的Ek=162．35kJ·mol^-1，Ak=1．83×10^15s^-1，TSADT=534．46K，Tbpp=542．22K；1，1’-BTOCu的EK=217．95kJ·mol^-1，AK=12．58×10^20s^-1，乙DT=527．56K，Tbpp=539．11K；1，1’-BTOPb的EK=223．52kJ·mol^-1，AK=4．24×10^20s^-1，TSADT=525．87K，Tbpp=580．00K。
1，1’-二羟基-5，5’-联四唑类化合物是近年来高能钝感材料研究的热点，为研究这类化合物的热安全性，用差示扫描量热法（DSC）和热重法（TG）在升温速率分别为5，10，15，20K·min^-1的条件下研究了1，1’-二羟基-5，5’-联四唑钴盐（1，1’-BTOCo）、铜盐（1，1’-BTOCu）和铅盐（1，1’-BTOPb）的热分解过程。分别用Kissinger法和Ozawa法计算了三种盐的表观活化能（Ek和E0）、指前因子（Ak），得到其热分解动力学参数和热分解机理函数。结果表明，1，1’-BTOCo的Ek=162．35kJ·mol^-1，Ak=1．83×10^15s^-1，TSADT=534．46K，Tbpp=542．22K；1，1’-BTOCu的EK=217．95kJ·mol^-1，AK=12．58×10^20s^-1，乙DT=527．56K，Tbpp=539．11K；1，1’-BTOPb的EK=223．52kJ·mol^-1，AK=4．24×10^20s^-1，TSADT=525．87K，Tbpp=580．00K。
{"title":"1,1′-二羟基-5,5′-联四唑金属盐的制备及热分解动力学","authors":"王杰群, 王鹏程, 陆明","doi":"10.11943/j.issn.1006-9941.2016.06.004","DOIUrl":"https://doi.org/10.11943/j.issn.1006-9941.2016.06.004","url":null,"abstract":"1，1’-二羟基-5，5’-联四唑类化合物是近年来高能钝感材料研究的热点，为研究这类化合物的热安全性，用差示扫描量热法（DSC）和热重法（TG）在升温速率分别为5，10，15，20K·min^-1的条件下研究了1，1’-二羟基-5，5’-联四唑钴盐（1，1’-BTOCo）、铜盐（1，1’-BTOCu）和铅盐（1，1’-BTOPb）的热分解过程。分别用Kissinger法和Ozawa法计算了三种盐的表观活化能（Ek和E0）、指前因子（Ak），得到其热分解动力学参数和热分解机理函数。结果表明，1，1’-BTOCo的Ek=162．35kJ·mol^-1，Ak=1．83×10^15s^-1，TSADT=534．46K，Tbpp=542．22K；1，1’-BTOCu的EK=217．95kJ·mol^-1，AK=12．58×10^20s^-1，乙DT=527．56K，Tbpp=539．11K；1，1’-BTOPb的EK=223．52kJ·mol^-1，AK=4．24×10^20s^-1，TSADT=525．87K，Tbpp=580．00K。","PeriodicalId":35753,"journal":{"name":"Hanneng Cailiao/Chinese Journal of Energetic Materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78988848","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
四硝基乙酰胺酸(TNAA)的合成及热性能 四硝基乙酰胺酸(TNAA)的合成及热性能
Q3 Engineering
Hanneng Cailiao/Chinese Journal of Energetic Materials
Pub Date : 2016-01-01 DOI: 10.11943/J.ISSN.1006-9941.2016.12.008
黄晓川, 郭涛, 王子俊, 刘敏, 秦明娜, 邱少君
{"title":"四硝基乙酰胺酸(TNAA)的合成及热性能","authors":"黄晓川, 郭涛, 王子俊, 刘敏, 秦明娜, 邱少君","doi":"10.11943/J.ISSN.1006-9941.2016.12.008","DOIUrl":"https://doi.org/10.11943/J.ISSN.1006-9941.2016.12.008","url":null,"abstract":"","PeriodicalId":35753,"journal":{"name":"Hanneng Cailiao/Chinese Journal of Energetic Materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79475864","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
首页 上一页 下一页 尾页
类型
全部 化学•材料 生命科学 医学 物理 工程技术 环境•农林 材料科学 地球科学 法学 管理学 化学 环境科学与生态学 计算机科学 教育学 经济学 农林科学 人文科学 生物学 数学 物理与天体物理 心理学 综合性期刊 其他 工业工程 理学 历史学 农学 文学 信息工程
数据库
全部 ACS Publications Elsevier ieeexplore Springer The Royal Society of Chemistry Wiley
期刊
Hanneng Cailiao/Chinese Journal of Energetic Materials
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
﹀
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整，为了账户安全，请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号：481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们：info@booksci.cn
Book学术提供免费学术资源搜索服务，方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1