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Geographical profiling of wood samples via ATR-FTIR spectroscopy and machine learning algorithms: Application in wood forensics 通过 ATR-FTIR 光谱和机器学习算法对木材样本进行地理剖面分析:木材取证中的应用
Q3 Medicine Pub Date : 2024-12-01 Epub Date: 2024-06-17 DOI: 10.1016/j.fsir.2024.100377
Suraj Garg, Akanksha Sharma, Vishal Sharma

Illegal activities associated with deforestation for the lumber and furniture industries pose significant threats to plant and animal biodiversity, as well as natural resources. Accurate identification of wood sources is vital, yet traditional laboratory techniques often fall short in precisely determining the chemical composition of samples for classification. This study aims to leverage ATR-FTIR spectroscopy alongside machine learning algorithms to construct a robust model for discerning the geographical origins of wood samples from India. By systematically comparing various machine learning classifiers, we address the limitations of subjective visual interpretation and evaluate their accuracy using wood spectral data. Logistic regression emerges as the most effective classifier for distinguishing Eucalyptus (75 % accuracy), Dalbergia (68 % accuracy), and Populus (81.5 % accuracy) species. Through a methodology encompassing data pre-processing, classifier selection, and performance evaluation, this research offers promising tools for combating challenges posed by illegal wood trafficking and transportation. The outcomes hold significant potential for enhancing wildlife crime prevention efforts by facilitating the tracing illicit timber sources, apprehension of perpetrators, and implementation of preventive measures.

为木材和家具行业砍伐森林的非法活动对动植物生物多样性和自然资源构成了严重威胁。准确识别木材来源至关重要,但传统的实验室技术往往无法精确确定样本的化学成分,从而无法进行分类。本研究旨在利用 ATR-FTIR 光谱和机器学习算法来构建一个强大的模型,用于辨别印度木材样本的地理来源。通过系统地比较各种机器学习分类器,我们解决了主观视觉解读的局限性,并利用木材光谱数据评估了它们的准确性。逻辑回归是区分桉树(准确率为 75%)、山茱萸(准确率为 68%)和杨树(准确率为 81.5%)树种最有效的分类器。这项研究通过数据预处理、分类器选择和性能评估等方法,为应对非法木材贩运和运输带来的挑战提供了前景广阔的工具。这些成果有助于追踪非法木材来源、逮捕犯罪者和实施预防措施,从而为加强野生动物犯罪预防工作提供了巨大的潜力。
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引用次数: 0
Technical Report A light touch; Reviewing the relative effectiveness of light sources and physical/chemical techniques for fingermark retrieval in casework 技术报告:轻触;审查光源和物理/化学技术在个案工作中提取指痕的相对有效性
Q3 Medicine Pub Date : 2024-12-01 Epub Date: 2024-11-09 DOI: 10.1016/j.fsir.2024.100391
Nicholas Marsh , Karen Marsh , Lisa Hall , Ruth Buckley , Stephen Bleay
This study reviewed the efficacy of non-contact light source examinations of serious crime scenes using ultraviolet A (UVA) light, bespoke white light and lasers, compared with subsequent powdering or chemical enhancements. Twenty-six examinations of serious crime scenes or motor vehicles were analysed, from which 655 areas of retrieved fingermark or friction ridge detail1 where reported on. It was found that undertaking a light source examination revealed equivalent numbers of marks to aluminium powder and chemical enhancements, with only a 4 % duplication rate between optical and physical/chemical techniques suggesting that both approaches are supplementary and should be used sequentially to each other.
本研究审查了使用紫外线 A (UVA)、定制白光和激光对严重犯罪现场进行非接触式光源检查的效果,并与随后的粉末处理或化学强化进行了比较。对 26 个严重犯罪现场或机动车辆进行了分析,从中报告了 655 个区域的指痕或摩擦纹细节1。结果发现,光源检查所发现的痕迹数量与铝粉和化学增强技术相当,光学技术和物理/化学技术的重复率仅为 4%,这表明这两种方法都是辅助性的,应依次使用。
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引用次数: 0
From death to the Virgin birth: Multi-analytical investigation of a suspected 16th century painting 从死亡到圣母诞生对一幅疑似 16 世纪绘画的多重分析调查
Q3 Medicine Pub Date : 2024-12-01 Epub Date: 2024-11-07 DOI: 10.1016/j.fsir.2024.100392
Michelle G. Carlin , Nicola Grimaldi
A painting depicting St John the Baptist prior to his brutal execution, until recently, was held in storage at the Bowes Museum in the North of England, UK. Owing to weakened joins in the wood panel the painting was marked for art conservation treatments, examination and analysis. However, other than the fact that the records show it purchased in Italy in the late nineteenth century by museum founders John and Joséphine Bowes, little else is known of the work. Through a combination of chemical testing and technical art history, further knowledge of the painting has been established. Preparation of cross sections of paint was carried out, as well as chemical testing involving pyrolysis gas chromatography – mass spectrometry (py-GCMS) and attenuated total reflectance – Fourier transform infrared spectroscopy (ATR-FTIR), lead white, chalk and linseed oil as binder were identified. The presence of an aged natural resin on the surface of the painting, presence of a thick gesso ground layer, as well as examination of the wood panel construction provided insight into the techniques used in the artwork and that they are comparable with late Medieval to early Renaissance period methods. During examination of the cross-section images, it was noted that there was a second preparatory ground layer in the central part of the sequence; this feature prompted further multi-spectral photography and analysis. X-radiography a commonly used technique for painting analysis surprisingly revealed an entirely different image depicting a nativity scene which had been previously completely concealed by the painting of St John we see today. Although an unexpected discovery still presents some unanswered questions such as who the original artist was and why was the panel so radically reworked. This investigation began with the depiction of the imminent death of the St John the Baptist and ended with the virgin birth. This analytical methodology was applied in technical art history but may also have applications in forensic investigations of suspected fraudulent works of art.
直到最近,一幅描绘施洗者圣约翰被残忍处死前的画作一直保存在英国英格兰北部的鲍斯博物馆。由于木板的接合处受损,这幅画被标记为需要进行艺术保护处理、检查和分析。然而,除了记录显示博物馆创始人约翰和约塞芬-鲍斯于 19 世纪末在意大利购买了这幅画之外,人们对这幅作品知之甚少。通过化学测试和技术艺术史的结合,我们对这幅画有了进一步的了解。我们制备了油漆的横截面,并通过热解气相色谱-质谱法(py-GCMS)和衰减全反射-傅立叶变换红外光谱法(ATR-FTIR)进行了化学测试,确定了作为粘合剂的铅白、白垩和亚麻籽油。画作表面存在老化的天然树脂、厚厚的石膏粉底层,以及对木板结构的检查,让我们了解到艺术品中使用的技术,这些技术可与中世纪晚期至文艺复兴早期的方法相媲美。在检查横截面图像时,我们注意到在序列的中央部分有第二层准备地面层;这一特征促使我们进一步进行多光谱摄影和分析。X 射线摄影是一种常用的绘画分析技术,它出人意料地发现了一幅完全不同的图像,描绘的是耶稣诞生的场景,而这幅图像之前完全被我们今天看到的圣约翰画作所掩盖。尽管这一发现出乎意料,但仍然存在一些未解之谜,例如原作者是谁,为什么这幅画会被如此彻底地重新加工。这项调查从描绘施洗者圣约翰濒临死亡开始,以童贞女降生结束。这种分析方法适用于技术艺术史,但也可用于对涉嫌欺诈的艺术品进行法医调查。
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引用次数: 0
Results of the 2023 rapid DNA multi-laboratory study – RapidINTEL Plus sample cartridge 2023快速DNA多实验室研究结果- RapidINTEL Plus样品盒
Q3 Medicine Pub Date : 2024-12-01 Epub Date: 2024-12-04 DOI: 10.1016/j.fsir.2024.100396
Erica L. Romsos , Lilliana I. Moreno , Douglas R. Hares
Identical sensitivity and mixture sample sets were provided to six external laboratories to evaluate the recent enhancements to the Rapid DNA technology for crime scene-type samples. Data were returned to the Federal Bureau of Investigation and the National Institute of Standards and Technology for review and analysis. Manual interpretation (modified Rapid DNA analysis) was conducted on all samples to assess the success of genotyping for both full profiles and the 20 Combined DNA Index System (CODIS) core STR loci using 18 total cellular DNA input amounts ranging from 102.4 ng to 0.025 ng. Two-person and three-person mixtures at varying ratios for two total DNA inputs were analyzed and observed allele percentages were compared to expected allele percentages.
向六个外部实验室提供了相同的灵敏度和混合样本集,以评估最近对犯罪现场类型样本的快速DNA技术的改进。数据被送回联邦调查局和国家标准与技术研究所进行审查和分析。对所有样本进行人工解释(改进的快速DNA分析),以评估完整谱和20个组合DNA索引系统(CODIS)核心STR位点的基因分型成功,使用18个总细胞DNA输入量,范围为102.4 ng至0.025 ng。分析了两种总DNA输入的不同比例的两人和三人混合,并将观察到的等位基因百分比与预期的等位基因百分比进行了比较。
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引用次数: 0
A rectal foreign body with giant bladder stone; An autopsy case of unusual autoerotic death 直肠异物伴巨大膀胱结石;一例不寻常的自体死亡尸检病例
Q3 Medicine Pub Date : 2024-12-01 Epub Date: 2024-08-29 DOI: 10.1016/j.fsir.2024.100385
Tadashi Hosoya , Kazuki Harada , Jun Kanetake

A man in his 60 s, who had experienced sustained abdominal pain intermittently for three years, lost consciousness and was transferred to an emergency hospital, where he was pronounced dead. In the forensic autopsy, a giant bladder stone measuring 6.5 × 6.0 × 4.0 cm was found adhering to an aluminum eyeliner that penetrated the anterior wall of his rectum. This might have induced pyelonephritis in the left kidney, resulting in sepsis. The deceased may have inserted the eyeliner for sexual stimulation. However, the eyeliner did not injure the peritoneum and no peritonitis occurred, which probably prevented acute sepsis immediately after insertion. The exact time of penetration was undetermined; however, the rectal foreign body may have been retained for three years. This case suggests that sexual activity should be considered a possible manner of death, even if it took place several years previously.

一名 60 多岁的男子间歇性持续腹痛三年后失去知觉,被紧急送往医院,并被宣布死亡。法医验尸时发现,一颗 6.5 × 6.0 × 4.0 厘米的巨型膀胱结石附着在穿透其直肠前壁的铝制眼线笔上。这可能诱发了左肾的肾盂肾炎,导致败血症。死者可能是为了性刺激而插入眼线笔的。然而,眼线笔没有伤及腹膜,也没有发生腹膜炎,这可能避免了插入后立即发生急性败血症。插入的确切时间无法确定;不过,直肠异物可能已经保留了三年。该病例表明,即使性活动发生在几年前,也应将其视为可能的死亡方式。
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引用次数: 0
The impact of filling procedure for labial augmentation (FPLA) therapy on the stability of lip print: A longitudinal study 唇部填充术(FPLA)对唇印稳定性的影响:纵向研究
Q3 Medicine Pub Date : 2024-12-01 Epub Date: 2024-07-14 DOI: 10.1016/j.fsir.2024.100382
Asmaa F. Sharif , Kawther AlShaikh , Nada AlQuraishi , Inas I. Abdelgawad

Lip print identification is one of the forensic identification tools recognized a long time ago. Few studies investigated the stability of lip prints, particularly the changes attributed to time or aging. To our knowledge, no previous studies speculated the changes in lip print following lip augmentation therapy, which has increased over the last few years. Therefore, the current study aimed to investigate the effect of lip augmentation therapy on lip print stability. The current study was a prospective longitudinal study that enrolled female volunteers who underwent a filling procedure for labial augmentation. A total of 24 volunteers' prints were analyzed using Suzuki and Tsuchihashi classification. Participants showed a mean age of 27.5 ± 6.0 years. The current study showed that no two lips exhibited the same pattern. Moreover, although the filling procedure for labial augmentation (FPLA) therapy preserved the predominant groove pattern, it significantly influenced the frequency of lip patterns in all lip quadrants. A significant decline in the number of lip grooves, notably Types I and I' was noticed. However, the predominant groove pattern was preserved. Quadrants A and D were the least affected lip parts. Type I′ was the predominant lip pattern over the study population, representing 83.3 %, followed by Type I, representing 16.7 % before and 12.5 % after augmentation without a statistically significant difference (p = 0.317). On the other side, Type III was the least presented pattern. The upper lip score had decreased significantly after augmentation from 71.5 ± 10.8–65.8 ± 10.2, and the lower lip score had decreased significantly from 67.4 ± 13.7–64.9 ± 13.5. Consequently, the overall lips score had decreased significantly from 139.0 ± 22.9–130.7 ± 21.1 after augmentation (p < 0.001). So, we recommend adopting more than one criterion to report a reliable, repeatable lip print, including the frequency of lip lines besides the predominant pattern. However, we advise giving more attention to the distinguished lip patterns (Types II, III, IV, and V) and considering the FPLA as one of the lip print modifiers.

唇纹鉴定是很早以前就被认可的法医鉴定工具之一。很少有研究调查唇印的稳定性,特别是由于时间或老化引起的变化。据我们所知,以前的研究都没有推测丰唇治疗后唇纹的变化,而丰唇治疗在过去几年中有所增加。因此,本研究旨在探讨丰唇疗法对唇部纹路稳定性的影响。本研究是一项前瞻性纵向研究,研究对象是接受了丰唇填充术的女性志愿者。研究人员使用铃木和土桥分类法对 24 名志愿者的唇印进行了分析。参与者的平均年龄为(27.5 ± 6.0)岁。本次研究显示,没有两张嘴唇表现出相同的模式。此外,虽然丰唇填充术(FPLA)疗法保留了主要的沟纹模式,但却显著影响了所有唇象限的唇纹频率。我们注意到唇沟的数量明显减少,尤其是 I 型和 I'型。不过,主要的唇沟形态仍得以保留。A 象限和 D 象限是受影响最小的唇部部位。在研究人群中,I′型是最主要的唇沟形态,占 83.3%,其次是 I 型,在丰唇前和丰唇后分别占 16.7% 和 12.5%,差异无统计学意义(P = 0.317)。另一方面,III 型是最少出现的形态。丰唇后,上唇评分从 71.5 ± 10.8-65.8 ± 10.2 显著下降,下唇评分从 67.4 ± 13.7-64.9 ± 13.5 显著下降。因此,丰唇后嘴唇的总分从 139.0 ± 22.9-130.7 ± 21.1 显著下降(p < 0.001)。因此,我们建议采用一种以上的标准来报告可靠、可重复的唇纹,包括主要唇纹以外的唇纹出现频率。不过,我们建议更多地关注杰出的唇纹(II、III、IV 和 V 型),并将 FPLA 视为唇纹修饰因素之一。
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引用次数: 0
Epidermal ridge sweat pore density: A forensic approach to sex determination 表皮脊汗孔密度:性别鉴定的法医方法
Q3 Medicine Pub Date : 2024-12-01 Epub Date: 2024-07-04 DOI: 10.1016/j.fsir.2024.100378
Jaisleen Kaur, Meenal Dhall

Determining the sex from an unidentified fingerprint recovered from a crime scene can assist in narrowing down the pool of potential suspects. The present study was conducted with the aim of determining sex using fingerprint epidermal ridge sweat pore density among the Indian population. For this purpose, plain prints from both the left and right thumbs were obtained from a total of 396 participants (191 males and 205 females), aged between 18 and 35 years, who were randomly selected for the study. Sweat pores were counted in a region of 3 × 3 mm2. Data were analyzed using SPSS (Statistical Product and Service Solutions) version 26 for Windows and Microsoft Office Excel 365. The likelihood ratio (LR) was calculated to obtain the probability inferences of sex based on the number of sweat pores. Analysis revealed that a fingerprint containing ≤ 45 pores/9 mm2 is more likely to be of male origin while one containing ≥ 49 pores/9 mm2 is more likely to be of female origin. Moreover, the difference in the number of pores was found to be statistically significant between the two biological sexes. The methodology employed in this study helps demarcate a uniform region in all the samples thereby eliminating variability due to pattern type and recurving ridges.

从犯罪现场提取的不明指纹中确定性别有助于缩小潜在嫌疑人的范围。本研究旨在利用印度人指纹表皮脊汗孔密度来确定性别。为此,研究人员随机选取了 396 名年龄在 18 至 35 岁之间的参与者(191 名男性和 205 名女性)的左手和右手拇指采集指纹。在 3 × 3 平方毫米的区域内对汗孔进行计数。数据使用 SPSS(统计产品与服务解决方案)Windows 版本 26 和 Microsoft Office Excel 365 进行分析。根据汗孔数量计算似然比(LR),得出性别概率推断。分析表明,汗孔数≤ 45 个/9 平方毫米的指纹更有可能是男性指纹,而汗孔数≥ 49 个/9 平方毫米的指纹更有可能是女性指纹。此外,研究还发现,两种生物性别在毛孔数量上的差异具有统计学意义。本研究采用的方法有助于在所有样本中划定一个统一的区域,从而消除因图案类型和凹脊而产生的差异。
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引用次数: 0
A preliminary evaluation of the effects of aquatic environments on the recovery of fingermarks on porous substrates 水生环境对多孔底质上指痕复原影响的初步评估
Q3 Medicine Pub Date : 2024-12-01 Epub Date: 2024-09-10 DOI: 10.1016/j.fsir.2024.100387
Amanda A. Frick , Ian Yi Liang Lim , Paola A. Magni

Latent fingermark detection can become increasingly difficult in the weeks following deposition, due to chemical and physical changes influenced by environment. There has been increased research interest into ageing mechanisms of fingermark residue, however these studies have typically been conducted in dry, indoors conditions. Less information is available regarding degradation processes that may occur in scenarios involving water and the potential longevity of porous substrates under such conditions. A pilot study was conducted to investigate the performances of Oil Red O (ORO) and physical developer (PD) on samples submerged in different aquatic environments in a laboratory setting. Charged fingermarks from three donors were deposited on copy paper and immersed in either salt water or freshwater; still or with water flow. Samples were treated at multiple intervals (1, 12, 20 and 40 days) after submersion. Results showed that high quality of development could be achieved up to 40 days after immersion. The overall performances of ORO and PD were generally unaffected in the early stages of the study. Physical and chemical degradation of both latent residue and substrate were observed, which were increased by salt and water movement. While PD appeared to be less affected by potential chemical changes, it was less effective than ORO due to substrate degradation in moving salt water. These results present the first steps towards better understanding the practical effects of degradation processes specific to fingermarks on porous substrates underwater.

由于化学和物理变化会受到环境的影响,在沉积后的几周内,潜伏指痕的检测会变得越来越困难。人们对指痕残留物老化机制的研究兴趣日益浓厚,但这些研究通常是在干燥的室内条件下进行的。关于在有水的情况下可能发生的降解过程以及多孔基质在这种条件下的潜在寿命的信息较少。我们进行了一项试验性研究,以调查油红 O(ORO)和物理显影剂(PD)在实验室环境中浸没在不同水生环境中的样本上的性能。将三个供体的带电指印沉积在复印纸上,然后浸入盐水或淡水中;静止或有水流。在浸没后的多个时间间隔(1、12、20 和 40 天)对样本进行处理。结果表明,浸泡 40 天后可获得高质量的发育。在研究的早期阶段,ORO 和 PD 的总体性能一般不受影响。潜伏残留物和基质都出现了物理和化学降解,盐和水的流动加剧了这种降解。虽然 PD 似乎受潜在化学变化的影响较小,但由于基质在流动的盐水中降解,其效果不如 ORO。这些结果为更好地了解指痕在水下多孔基底上特有的降解过程的实际效果迈出了第一步。
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引用次数: 0
Medico-legal analysis of the correlation between head trauma and aneurysm rupture: A case report 头部外伤与动脉瘤破裂之间相关性的医学法律分析:病例报告
Q3 Medicine Pub Date : 2024-12-01 Epub Date: 2024-10-18 DOI: 10.1016/j.fsir.2024.100390
Emanuele Capasso, Gaetano Di Donna, Roberto Cortese, Verdiana De Caro, Fabio Policino
We present the case of a 54 years old man who was found in a state of confusion and a forehead wound. Transported to the closest E.R., a brain CT scan showed massive subarachnoid hemorrhage and an angiographic exam showed a ruptured aneurysm of the cavernous siphon. Death occurred 4 days after admission. The autopsy showed the presence of a linear wound on the forehead which was considered a sharp force injury. The aneurysm rupture was therefore considered as a consequence of the head trauma associated to the frontal wound. In the medico-legal analysis of the case primary importance was given to the distinction between potential homicide, suicide or accident. In the end, based on the morphological features of the forehead wound, this case was defined as of potentially homicidal nature, so that the responsible of stab wound should be considered accountable for the man’s death.
本病例是一名 54 岁的男性,被发现时神志不清,前额有伤口。送往最近的急诊室后,脑部 CT 扫描显示大量蛛网膜下腔出血,血管造影检查显示海绵虹吸管动脉瘤破裂。患者在入院 4 天后死亡。尸检显示前额有一条线状伤口,被认为是锐器所伤。因此,动脉瘤破裂被认为是与前额伤口相关的头部外伤造成的。在对该病例进行医学-法律分析时,最重要的是区分可能是他杀、自杀还是意外事故。最后,根据前额伤口的形态特征,该病例被界定为潜在的他杀性质,因此刺伤者应被视为该男子死亡的罪魁祸首。
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引用次数: 0
Survey of bloodstain pattern analysts regarding pattern classifications on assorted fabrics 关于各种织物上血迹图案分类的血迹图案分析师调查
Q3 Medicine Pub Date : 2024-12-01 Epub Date: 2024-11-20 DOI: 10.1016/j.fsir.2024.100394
Dylan J. Drazdik , David M. Hammond , Travis J. Worst , Crystal M. Oechsle
Because bloodstain pattern analysis (BPA) on absorbent surfaces, such as fabrics, is far more complex than its application on hard, nonporous surfaces, pattern type may be interpreted differently between fabric substrates and by analysts with more or less experience. Four bloodstain pattern types (impact spatter, transfer, drip stains, and cast-off) were created on seven fabrics (cotton, satin polyester, rayon, blended polyester/spandex, blended nylon/spandex, blended modal/polyester/spandex, and terry cloth), foamboard, or butcher paper and then photographed. A survey questionnaire that asked respondents to classify 16 patterns as to general pattern type, specific pattern type, and directionality was developed and disseminated among bloodstain pattern analysts. Respondents (n = 32, divided into five experience levels) classified the bloodstains differently based upon amounts of training and experience, the pattern type, and the substrate type. The ability to accurately classify the specific pattern type overall (p-value < 0.0002) as wells as on fabric (p-value < 0.001) was dependent upon respondent experience level. The more experienced respondents were less likely to specifically classify patterns than the less experienced respondents (p-value < 0.001). Furthermore, the ability to accurately classify the specific pattern type was dependent upon whether the pattern had been created on fabric or some other substrate (p-value < 0.0000000001). However, if the proper morphology was present in the stain, it was found that BPA on certain fabrics was possible. This finding supports the need for further research and the development of guidelines and standards for bloodstain pattern analysis on fabric materials.
由于织物等吸收性表面上的血迹模式分析(BPA)比在坚硬、无孔表面上的应用要复杂得多,因此不同织物基材和经验丰富或经验不足的分析人员对模式类型的解释也可能不同。我们在七种织物(棉、缎纹聚酯、人造丝、混纺聚酯/氨纶、混纺尼龙/氨纶、混纺莫代尔/涤纶/氨纶和毛圈布)、泡沫板或肉纸上绘制了四种血迹图案类型(撞击飞溅、转移、滴渍和脱落),然后进行拍照。我们编制了一份调查问卷,要求受访者对 16 种图案的一般图案类型、特定图案类型和方向性进行分类,并向血迹图案分析人员分发。受访者(n = 32,分为五个经验等级)根据培训和经验的多少、图案类型和基质类型对血迹进行了不同的分类。受访者准确分类特定图案类型(p 值为 0.0002)和织物(p 值为 0.001)的能力取决于受访者的经验水平。与经验较少的受访者相比,经验较多的受访者不太可能对图案进行具体分类(p 值为 0.001)。此外,准确划分图案类型的能力还取决于图案是在织物上还是在其他基质上绘制的(p 值为 0.0000000001)。不过,如果污渍中存在适当的形态,则可以发现某些织物上可能含有双酚 A。这一发现支持了进一步研究和制定织物材料血迹图案分析指南和标准的必要性。
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引用次数: 0
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Forensic Science International: Reports
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