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Fire Risk of Polyethylene (PE)-Based Foam Blocks Used as Interior Building Materials and Fire Suppression through a Simple Surface Coating: Analysis of Vulnerability, Propagation, and Flame Retardancy 用于室内建筑材料的聚乙烯(PE)基泡沫块的火灾风险及通过简单表面涂层灭火:脆弱性、传播性和阻燃性分析
IF 3.2 3区 农林科学 Q2 ECOLOGY Pub Date : 2023-09-08 DOI: 10.3390/fire6090350
Yongtae Jeon, Jungwoo Park, Jongyoung Park, Chan-Yong Kang
Building fires can spread through surface combustion of both combustible and interior finishing materials. Recently, the use of foam blocks as interior materials for high-rise residential buildings has increased. However, as foam blocks are primarily composed of polyethylene, they are not flame-retardant and can readily burn and the fire can spread, leading to large-scale damage. Herein, the fire hazard and diffusion characteristics of foam blocks were compared with those of flame-retardant and general wallpapers to confirm the risk of fire. The fire risk of the foam blocks was confirmed using flammability, cone calorimetry, and spread-of-flame analyses. Based on a comparative analysis of the fire risk of foam blocks, the average total heat release was 11.2 MJ/m. This is approximately three times higher than the average heat release rate of the flame-retardant wallpaper and approximately two times higher than that of the general wallpaper. The foam blocks ignited rapidly owing to fire and generated large amounts of combustion gas and heat. To prevent such a fire, 5 wt% montmorillonite (MMT) was simply coated after surface modification to suppress the occurrence of fire. Various flame-retardant materials, surface modifications, and fire safety systems must be developed to prevent fire hazards.
建筑火灾可通过可燃材料和室内装饰材料的表面燃烧蔓延。近年来,泡沫砌块作为高层住宅内部材料的使用有所增加。然而,由于泡沫块主要由聚乙烯组成,它们不阻燃,很容易燃烧,火灾可能蔓延,导致大规模破坏。本文将泡沫砌块的火灾危险性和扩散特性与阻燃壁纸和普通壁纸进行了比较,以确定其火灾风险。通过可燃性、锥形量热法和火焰蔓延分析,确认了泡沫块的火灾风险。根据对泡沫砌块火灾风险的比较分析,平均总放热量为11.2MJ/m。这大约是阻燃壁纸的平均热释放速率的三倍,并且大约是普通壁纸的两倍。泡沫块由于火灾而迅速点燃,并产生大量燃烧气体和热量。为了防止这种火灾,在表面改性后简单地涂覆5wt%的蒙脱石(MMT)以抑制火灾的发生。必须开发各种阻燃材料、表面改性和消防安全系统,以防止火灾危险。
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引用次数: 0
Evaluation of Air Quality inside Self-Contained Breathing Apparatus Used by Firefighters 消防员自给式呼吸器内部空气质量评价
IF 3.2 3区 农林科学 Q2 ECOLOGY Pub Date : 2023-09-06 DOI: 10.3390/fire6090347
S. Kim, Seunghon Ham
(1) Background: When a fire breaks out, combustibles are burned and toxic substances such as carbon monoxide (CO), polycyclic aromatic hydrocarbons (PAH), benzene, and hydrogen cyanide are produced. The purpose of this study is to evaluate the air quality inside self-contained breathing apparatus (SCBA) by comparing it to that in the environment where the SCBA charger is installed. (2) Methods: The design of this study was a simulation-based case-control experiment study, and the experiment was conducted at two fire stations located on land and on water. When charging the SCBA, it was differentiated according to the presence or absence of exposure to harmful substances and the degree of exposure. The air quality inside the SCBA in the charging room installed in the fire station garages located on land and in the water, which were not completely isolated from harmful substances, was evaluated. CO, carbon dioxide (CO2), water, and oil mist were measured and analyzed to determine the air quality inside the SCBA. (3) Results: In the case of land firefighting stations, the mean CO among the SCBA internal air quality items was 20 times higher than the outside the SCBA, and higher than the safe range in the group with the highest exposure at the sites of firefighting buildings completely isolated from hazardous substances. The CO levels of all items of water were analyzed to be higher than the safe range in the floating fire station. (4) Conclusions: It was confirmed that the installation environment of an SCBA charging room can affect the safety of the charged internal air quality components. The results of this study can be actively used for the operation and management of SCBA charging room environments when building firefighting buildings in the future for the hygiene, safety, and health of firefighters.
(1) 背景:火灾发生时,可燃物被燃烧,产生一氧化碳(CO)、多环芳烃(PAH)、苯和氰化氢等有毒物质。本研究的目的是通过将自给式呼吸器(SCBA)与安装SCBA充电器的环境中的空气质量进行比较,来评估其内部的空气质量。(2) 方法:本研究采用基于模拟的病例对照实验研究,在陆地和水面两个消防站进行实验。当给SCBA充电时,根据是否接触有害物质和接触程度进行区分。对安装在陆地和水中消防站车库中的充电室SCBA内的空气质量进行了评估,这些车库没有完全与有害物质隔离。对CO、二氧化碳(CO2)、水和油雾进行测量和分析,以确定SCBA内的空气质量。(3) 结果:在陆地消防站的情况下,SCBA内部空气质量项目中的平均CO是SCBA外部的20倍,并且高于在与危险物质完全隔离的消防建筑现场暴露量最高的组中的安全范围。经分析,浮式消防站所有水的CO含量均高于安全范围。(4) 结论:SCBA充气室的安装环境会影响充气内部空气质量部件的安全。为了消防员的卫生、安全和健康,本研究结果可积极用于未来建造消防建筑时SCBA充电室环境的操作和管理。
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引用次数: 0
Experimental Study on Combustion Behavior of U-Shaped Cables with Different Bending Forms and Angles U型电缆不同弯曲形式和角度燃烧特性的实验研究
IF 3.2 3区 农林科学 Q2 ECOLOGY Pub Date : 2023-09-06 DOI: 10.3390/fire6090348
Changkun Chen, Wuhao Du, Tong Xu
Cables are usually bent into a U-shape to cross obstacles during installation: this includes the upward-bending mode (UBM) and the downward-bending mode (DBM). An experimental study was conducted to investigate the combustion behavior of U-shaped cables with the above bending forms and different angles. The ignition point was set in the middle of the U-shaped cables and the temperature distribution, flame spread rate (FSR), mass loss rate (MLR), flame dimensional characteristics, etc. were measured and analyzed. The results showed that FSR and MLR are positively related to the bending angles, and the FSR is the highest in UBM 90°, close to 6.51 cm/min, which is four times higher than that in the bending angle 0° condition. In the UBM, the heat radiation and convection from the cable flame to the unburned region were more intense and the “eruptive fire phenomenon” occurred during the combustion process, leading to a sharp increase in the FSR in a short time. However, the thermal convection and radiation from the burning region to the unburned region were weakened in the DBM. Meanwhile, the molten outer sheath (PE) would flow along the cables, heating and igniting the unburned region in the DBM. In addition, the FSR, MLR, and peak temperature increased in the UBM compared to the DBM. The highest flame temperature occurred in UBD 90°, approximately 1023 °C.
电缆在安装过程中通常会弯曲成u型,以方便穿越障碍物。u型电缆分为上行弯曲和下行弯曲两种。对上述不同弯曲形式和不同弯曲角度的u形电缆的燃烧特性进行了实验研究。将着火点设置在u型电缆的中间,测量并分析了其温度分布、火焰蔓延速率(FSR)、质量损失率(MLR)、火焰尺寸特性等。结果表明,FSR和MLR与弯曲角度呈正相关,其中弯曲角度为90°时FSR最高,接近6.51 cm/min,是弯曲角度为0°时的4倍。在UBM中,电缆火焰向未燃烧区域的热辐射和对流更为强烈,燃烧过程中出现“喷火现象”,导致FSR在短时间内急剧增加。而燃烧区向非燃烧区的热对流和辐射在DBM中减弱。同时,熔融的外护套(PE)会沿着电缆流动,加热并点燃DBM中未燃烧的区域。此外,与DBM相比,UBM的FSR、MLR和峰值温度都有所增加。最高火焰温度发生在UBD 90°,约为1023°C。
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引用次数: 0
Summer Compound Drought-Heat Extremes Amplify Fire-Weather Risk and Burned Area beyond Historical Thresholds in Chongqing Region, Subtropical China 夏季复合干热极端事件使重庆地区火灾天气风险和烧伤面积超过历史阈值
IF 3.2 3区 农林科学 Q2 ECOLOGY Pub Date : 2023-09-05 DOI: 10.3390/fire6090346
Lucas Gutiérrez Rodríguez, Yingpeng He, Mengqi Sun, Yinan Yao, Víctor Resco de Dios
Global warming is associated with an increase in compound drought-heat events (CDHEs), leading to larger and more extreme fire-weather risk in mesic forests. Wildfire activity in subtropical China, under the influence of monsoonal rainfall, was historically limited to dry winters and rare in rainy summers. Here, we seek to test whether this area is on the brink of a major change in its fire regime characterized by larger fire seasons, extending into the summer, leading to increases in fire activity (burned area). We analyze fire activity in Chongqing Municipality (46,890 km2), an important area of subtropical China hosting the Three Gorges Reservoir Area. We observed significant increases in summer forest fires under anomalous dry-hot summer conditions, where the total burned area was 3–6 times the historical annual mean (previously confined to the winter season). Vapor pressure deficit (VPD), an indicator of hot and dry weather conditions (i.e., fire-weather risk), was a strong predictor of fire activity, with larger wildfires occurring on days where VPD was higher than 3.5 kPa. Results indicate that a major wildfire activity expansion may occur in the area due to climate change and the widening time window of fire-weather risk, unless strong fire prevention and local adaptation policies are implemented.
全球变暖与复合干热事件(CDHEs)的增加有关,导致mesic森林中更大和更极端的火灾天气风险。历史上,受季风降水影响,中国亚热带地区的野火活动仅限于冬季干燥,夏季多雨罕见。在这里,我们试图测试该地区是否处于火灾状态发生重大变化的边缘,其特征是火灾季节更长,持续到夏季,导致火灾活动(燃烧面积)增加。我们分析了重庆市(46,890平方公里)的火灾活动,这是中国亚热带重要的区域,承载着三峡库区。我们观察到,在异常的夏季干热条件下,夏季森林火灾显著增加,其中总燃烧面积是历史年平均水平的3-6倍(以前仅限于冬季)。蒸汽压差(VPD)是干热天气条件(即火灾天气风险)的一个指标,是火灾活动的一个强有力的预测指标,在VPD高于3.5 kPa的日子发生较大的野火。结果表明,除非实施强有力的防火和地方适应政策,否则由于气候变化和火灾天气风险时间窗的扩大,该地区可能会发生重大的野火活动扩张。
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引用次数: 0
An Experimental Study for Deriving Fire Risk Evaluation Factors for Cables in Utility Tunnels 公用工程隧道电缆火灾危险性评价因子的实验研究
IF 3.2 3区 农林科学 Q2 ECOLOGY Pub Date : 2023-09-01 DOI: 10.3390/fire6090342
Hyun Jeong Seo, Yon Ha Chung, Tae Jung Song
In this study, we performed three tests to measure the fire-retardant performance of power cables installed in utility tunnels. The standards we applied for testing are ISO 5660-1, NES 713, and IEEE 1202. Specifically, we performed a cone calorimetric analysis, calculated the toxicity index, and measured the flame spread length on material surfaces. Even though the same fire-retardant chemical composites were applied, various differences in fire-retardant performance were found depending on the chemical properties of the cable sheath and insulation. We also found that gaseous substances generated during the burning of cables can serve as important risk assessment factors in fires. We determined that, in addition to the heat generated when the cable burns, the toxic gases emitted at this time can also be a risk factor. This is because it is important to consider any potential risk to a person entering as part of an initial response to an event or accident involving cables installed in utility tunnels. Moreover, in the event of a fire in the cable, there is a risk of hazardous substances flowing into the city center as toxic gases are released. Therefore, we determined that the risk of hazardous gases emitted during cable fire should be reflected in the fire-retardant performance standard.
在这项研究中,我们进行了三项测试,以测量安装在公用工程隧道中的电力电缆的阻燃性能。我们用于测试的标准是ISO 5660-1、NES 713和IEEE 1202。具体而言,我们进行了锥形量热分析,计算了毒性指数,并测量了材料表面的火焰蔓延长度。尽管使用了相同的阻燃化学复合材料,但根据电缆护套和绝缘层的化学性能,阻燃性能存在各种差异。我们还发现,电缆燃烧过程中产生的气体物质可以作为火灾的重要风险评估因素。我们确定,除了电缆燃烧时产生的热量外,此时排放的有毒气体也可能是一个风险因素。这是因为,作为对涉及安装在公用工程隧道中的电缆的事件或事故的初步响应的一部分,考虑人员进入的任何潜在风险是很重要的。此外,如果电缆发生火灾,由于有毒气体的释放,危险物质有流入市中心的风险。因此,我们确定电缆火灾过程中排放的有害气体的风险应反映在阻燃性能标准中。
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引用次数: 0
Fertile Island Soils Promote the Restoration of Shrub Patches in Burned Areas in Arid Saline Land 肥沃的海岛土壤促进干旱盐碱地烧毁地区灌木斑块的恢复
IF 3.2 3区 农林科学 Q2 ECOLOGY Pub Date : 2023-09-01 DOI: 10.3390/fire6090341
Shilin Wang, Xiaojun Wang, Wen-xia Cao
Shrub encroachment and expansion have been widely reported globally and are particularly severe in arid saline land. Shrubs in harsh habitats have fertile island effects, but the promoting effect of fertile island soil on shrub patch restoration remains unclear. To clarify the role of fertile island soils in shrub patch recovery, we took single Tamarix ramosissima shrubs with different volume sizes (3.62–80.21 m3) as experimental subjects. The fertile island effect was quantified, and the 5-year natural recovery of shrub patches in the burned area was measured. The results strongly support that shrubs formed a fertile island soil in unburned areas; soil nutrient content beneath the canopy was 1.34–3.09 times higher than those outside the shrubs, while the soil salinity was 0.03–0.48 times lower than that of intercanopy spaces. The diversity of herbaceous plants beneath shrubs was significantly lower than that of outside shrubs, while the herbage biomass first increased and then decreased with the increase in the volume of shrubs. The maximum biomass of herbage was found when the shrub volume was 30.22 m3, but oversized shrubs could inhibit the growth of herbage. In terms of burned area, the recovery of burned area mainly depends on resprouts and seedlings. The mean values of seedling density, height, coverage, and biomass beneath the canopies were 0.47, 2.53, 2.11, and 5.74 times higher, respectively, than those of the intercanopy spaces. The results of the structural equation models showed the weight coefficient of the fertile island soils for the vegetation recovery in burned shrubland was 0.45; low salinity contributed more to vegetation recovery than high nutrient and moisture contents. Thus, compared with intercanopy spaces, shrub patches reinforce fertile island effects through direct and indirect effects and enhance the recovery of shrubland vegetation in the burned area. Our results demonstrate the positive implications of shrub expansion in the context of global climate change and also deepen the understanding of the sustainable development of burned shrubland.
灌木的入侵和扩张已在全球广泛报道,在干旱盐碱地尤其严重。恶劣生境灌木具有肥沃岛屿效应,但肥沃岛屿土壤对灌木斑块恢复的促进作用尚不清楚。为了阐明岛屿肥沃土壤在灌丛斑块恢复中的作用,我们以不同体积大小(3.62 ~ 80.21 m3)的柽柳灌木为实验对象。定量分析了丰饶岛效应,测定了灌木林斑块的5年自然恢复情况。研究结果有力地支持了灌木在未烧毁地区形成了肥沃的岛土;林冠下土壤养分含量比灌木外高1.34 ~ 3.09倍,土壤盐分比林冠间低0.03 ~ 0.48倍。灌丛下草本植物多样性显著低于灌丛外,牧草生物量随灌丛体积的增加先增加后减少。当灌木体积为30.22 m3时,牧草生物量最大,但过大的灌木会抑制牧草的生长。在烧毁面积方面,烧毁面积的恢复主要依靠复苗和幼苗。林下幼苗密度、高度、盖度和生物量的平均值分别是林间的0.47倍、2.53倍、2.11倍和5.74倍。结构方程模型计算结果表明:海岛肥沃土对灌木林植被恢复的权重系数为0.45;低盐度对植被恢复的贡献大于高养分和水分含量。因此,与冠间空间相比,灌木斑块通过直接和间接效应强化了肥沃岛效应,促进了灌木林植被的恢复。研究结果揭示了全球气候变化背景下灌木扩张的积极意义,也加深了对被烧毁灌木地可持续发展的认识。
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引用次数: 0
Wildland–Urban Interface: Definition and Physical Fire Risk Mitigation Measures, a Systematic Review 荒地-城市界面:定义和物理火灾风险缓解措施,系统综述
IF 3.2 3区 农林科学 Q2 ECOLOGY Pub Date : 2023-09-01 DOI: 10.3390/fire6090343
Flavio Taccaliti, R. Marzano, Tina L. Bell, E. Lingua
Due to the associated fire risk, the wildland–urban interface (WUI) has drawn the attention of researchers and managers from a range of backgrounds. From a land management point of view, it is important to identify the WUI to determine areas to prioritise for fire risk prevention. It is also important to know the fire risk mitigation measures available to select the most appropriate for each specific context. In this systematic review, definitions of the WUI were investigated and physical mitigation measures for reducing the risk of fire were examined from a land management perspective. The PRISMA 2020 Statement was applied to records published until 31 December 2022 and retrieved from the Web of Science, Scopus, and other research engines. A total of 162 publications from scientific journals and the grey literature were scrutinised and selected for analysis. Only publications providing an original definition of the WUI or proposing physical measures to reduce fire risk at the interface were retained, while those relating to emergency management and social perception were not considered. The risk of bias was reduced by internal cross-assessment by the research team. Definitions of the WUI (n = 40 publications) changed according to the research objective, varying broadly in identification of the anthropogenic and the wildland components of the interface. Terminology varied according to the definition, and the term wildland–human interface (WHI) was found to be more comprehensive than WUI. Methodological definitions of the interface ranged from using aggregated data through to identification of the buildings at risk in the interface with considerable precision. Five categories of physical fire risk mitigation measures (n = 128 publications) were identified: clearance distances, landscaping, wildland fuel management, land planning, and buildings design and materials. The most effective measures were those applied at early stages of urban development, and maintenance of assets and vegetation is crucial for preparedness. This review represents an analysis of scientific evidence on which land managers can base their actions to reduce the fire hazard risk in the WUI. The number of studies investigating the WUI is considerable, but experimental studies and quantitative results are scarce, and better communication and coordination among research groups and land management agencies is advisable. This systematic review was not registered.
由于相关的火灾风险,荒地-城市界面(WUI)引起了来自各种背景的研究人员和管理人员的注意。从土地管理的角度来看,确定WUI以确定火灾风险预防的优先区域是很重要的。了解可用于选择最适合每种特定情况的火灾风险缓解措施也很重要。在这篇系统综述中,调查了WUI的定义,并从土地管理的角度审查了降低火灾风险的物理缓解措施。PRISMA 2020声明适用于截至2022年12月31日发布的记录,并从科学网、Scopus和其他研究引擎中检索。对来自科学期刊和灰色文献的162篇出版物进行了仔细审查和分析。只保留了提供WUI原始定义或提出减少接口火灾风险的物理措施的出版物,而没有考虑与应急管理和社会认知有关的出版物。研究小组通过内部交叉评估降低了偏倚的风险。WUI的定义(n=40份出版物)根据研究目标而变化,在界面的人为成分和荒地成分的识别方面差异很大。根据定义,术语各不相同,发现“荒地-人类界面”(WHI)一词比“WUI”更全面。接口的方法定义从使用汇总数据到相当精确地识别接口中的风险建筑。确定了五类物理火灾风险缓解措施(n=128份出版物):净空距离、景观美化、荒地燃料管理、土地规划以及建筑设计和材料。最有效的措施是在城市发展的早期阶段采取的措施,维护资产和植被对做好准备至关重要。这篇综述代表了对科学证据的分析,土地管理者可以根据这些证据采取行动来降低WUI的火灾风险。调查WUI的研究数量相当多,但实验研究和定量结果很少,研究小组和土地管理机构之间更好的沟通和协调是可取的。这一系统性审查没有登记。
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引用次数: 0
Identification Methodology for Chemical Warehouses Dealing with Flammable Substances Capable of Causing Firewater Pollution 处理可引起火水污染的可燃物质的化学品仓库的识别方法
IF 3.2 3区 农林科学 Q2 ECOLOGY Pub Date : 2023-09-01 DOI: 10.3390/fire6090345
Maxim Kátai-Urbán, Tibor Bíró, L. Kátai-Urbán, F. Varga, Zsolt Cimer
Major accidents involving flammable substances can lead to significant environmental damage. The operators of chemical warehouses—in order to prevent and mitigate harmful environmental impacts—based on fire prevention strategies should apply “firewater pollution prevention” (FPP) measures. The identification of affected warehouses already in operation is an important law enforcement task. Therefore, the authors—based on the assessment of firewater run-off scenarios—propose a simple and easy-to-use dangerous establishment identification procedure and methodology based on event tree analysis and indexing preliminary risk analysis approaches. Two independent expert groups validated—in the case of 10 facilities—the index components of the approach. The testing of the applicability of the approach took place in parallel with the analyses of the Hungarian operator’s practice. The research results—covering the inspection of 24 facilities—can assist the operators in the effective and unified implementation of FPP measures. In the case of 14 facilities, it was necessary to introduce FPP measures, which highlight the need to improve the law enforcement compliance of identified operators. The investigation results can also contribute to increases in the fire and environmental safety performance of chemical warehouses, which ensures a higher level of environmental protection and people’s health near chemical warehouses.
涉及易燃物质的重大事故会导致严重的环境破坏。为了防止和减轻基于防火策略的有害环境影响,化学仓库的经营者应采取“防火水污染预防”措施。识别已在运作的受影响仓库是一项重要的执法任务。因此,作者在对消防水径流情景评估的基础上,提出了一种基于事件树分析和索引初步风险分析方法的简单易用的危险场所识别程序和方法。两个独立专家组验证了该方法的指数组成部分(在10个设施的情况下)。对该方法适用性的测试与对匈牙利运营商实践的分析同时进行。研究结果涵盖了24个设施的检查,可以帮助运营商有效、统一地实施FPP措施。在14个设施的情况下,有必要引入FPP措施,这突出了需要改善已确定运营商的执法合规情况。调查结果还有助于提高化学品仓库的消防和环境安全性能,从而确保化学品仓库附近的环境保护和人们的健康水平更高。
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引用次数: 0
The Effectiveness of Pressure Safety Valves in Chemical Supply Systems to Prevent Fire, Explosion and Overpressure in the Korean Semiconductor Industry 韩国半导体行业化学品供应系统中压力安全阀预防火灾、爆炸和超压的有效性
IF 3.2 3区 农林科学 Q2 ECOLOGY Pub Date : 2023-09-01 DOI: 10.3390/fire6090344
Kyeong-Seok Oh, Euittum Jeong, Woo Sub Shim, Jong-Bae Baek
This study was conducted to review the safety and appropriateness of PSV (Pressure Safety Valve) installation in the supply tank, which is a pressure vessel included in supply systems dedicated to supplying the acid/alkaline substances used in the Korean semiconductor manufacturing process. Three aspects of design, risk assessment, and regulations were reviewed to determine if there is a source of pressure higher than the maximum allowable working pressure (MAWP) of the supply tank that could cause fires, explosions, and overpressure. In the case of the design review, all 17 overpressure scenarios described in API Standard 521, i.e., pressure-relieving and depressuring systems, were reviewed, and there was no overpressure scenario above the maximum allowable working pressure (MAWP). Then, the risk assessment, i.e., the Hazard and Operability Study (HAZOP) technique, was used, and as a result of reviewing all possible risk situations, we can state that there were no overpressure scenarios that can exceed the design pressure of the supply tank; thus, we decided that the installation of a PSV on top of the supply tank is unnecessary. Finally, accident prevention measures against overpressure, such as the KS B 6750-3 system design and the Korean Industrial Standard, were reviewed from a legal point of view. It was confirmed that the hazardous chemical supply system for the semiconductor industry designed in this study has several protective functions to prevent fires, explosions, and overpressure. As a result of reviewing the above three aspects, it can be said that there is no need to install a pressure safety valve in a pressure vessel storing hazardous chemicals.
本研究旨在审查供应罐中PSV(压力安全阀)安装的安全性和适当性,供应罐是一种压力容器,包含在专门供应韩国半导体制造过程中使用的酸性/碱性物质的供应系统中。审查了设计、风险评估和法规的三个方面,以确定是否存在高于供应罐最大允许工作压力(MAWP)的压力源,从而可能导致火灾、爆炸和超压。在设计审查的情况下,审查了API标准521中描述的所有17种超压情况,即减压和减压系统,没有超过最大允许工作压力(MAWP)的超压情况。然后,使用了风险评估,即危险与可操作性研究(HAZOP)技术,作为审查所有可能风险情况的结果,我们可以声明不存在可能超过供应罐设计压力的超压情况;因此,我们决定在供应罐顶部安装PSV是不必要的。最后,从法律角度对KS B 6750-3系统设计和韩国工业标准等超压事故预防措施进行了评述。经证实,本研究中设计的半导体行业危险化学品供应系统具有多种保护功能,可防止火灾、爆炸和超压。回顾以上三个方面,可以说没有必要在储存危险化学品的压力容器中安装压力安全阀。
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引用次数: 1
Engineering Attributes of Ternary Geopolymer Mortars Containing High Volumes of Palm Oil Fuel Ash: Impact of Elevated Temperature Exposure 含有大量棕榈油燃料灰的三元地质聚合物砂浆的工程特性:高温暴露的影响
IF 3.2 3区 农林科学 Q2 ECOLOGY Pub Date : 2023-08-30 DOI: 10.3390/fire6090340
Ghasan Fahim Huseien, Z. Kubba, S. K. Ghoshal
Geopolymer mortars made from various waste products can appreciably reduce carbon dioxide emissions and landfill-related issues, making them viable substitutes for ordinary Portland cement, a workhorse in the concrete industry. Thus, a series of ternary geopolymer mortars were made and characterized to determine the effects of exposure to elevated temperatures (from room temperature up to 900 °C) on their engineered (residual compressive strength, weight loss, and slant shear bond strength) and microstructural properties. These mortars, which contain fly ash, ground blast furnace slag, and a high volume of palm oil fuel ash, were designed to activate via the incorporation of an alkali activator solution at a low concentration (molarity of 4). The elevated temperature-mediated deterioration of the ternary geopolymer mortar was quantified using Fourier transform infrared spectroscopy, X-ray diffraction, scanning electron microscopy, and thermogravimetric analysis. The results revealed an improvement in the ternary geopolymer mortars’ resistance against elevated temperatures when the palm oil fuel ash level in the mortar matrix was raised from 50 to 70% and when slag was replaced by fly ash. It was asserted that the proposed ternary geopolymer mortars may contribute to the advancement of green concretes demanded by the construction sectors.
由各种废物制成的地质聚合物砂浆可以显著减少二氧化碳排放和垃圾填埋相关问题,使其成为混凝土行业主力军普通硅酸盐水泥的可行替代品。因此,制备并表征了一系列三元地质聚合物砂浆,以确定暴露于高温(从室温到900°C)对其工程(残余抗压强度、重量损失和倾斜剪切粘结强度)和微观结构性能的影响。这些砂浆含有粉煤灰、高炉矿渣和大量棕榈油燃料灰,设计用于通过掺入低浓度(摩尔浓度为4)的碱性活化剂溶液进行活化。使用傅里叶变换红外光谱、X射线衍射、扫描电子显微镜和热重分析对三元地质聚合物砂浆的高温介导的劣化进行了量化。结果表明,当砂浆基质中的棕榈油燃料灰含量从50%提高到70%时,以及当矿渣被粉煤灰取代时,三元地质聚合物砂浆的耐高温性能有所提高。有人断言,拟议的三元地质聚合物砂浆可能有助于推进建筑行业所需的绿色混凝土。
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Fire-Switzerland
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