Journal of Industrial and Engineering Chemistry最新文献

{"title":"Methyl carnosate as a sustainable antioxidant for enhancing oxidation stability in soybean oil-based dielectric fluids","authors":"Yingying Shu,&nbsp;Chaofan Wang,&nbsp;Zhengyong Huang,&nbsp;Changheng Li,&nbsp;Feipeng Wang,&nbsp;Jian Li","doi":"10.1016/j.jiec.2025.08.008","DOIUrl":"10.1016/j.jiec.2025.08.008","url":null,"abstract":"<div><div>Natural ester dielectric fluids are eco-friendly alternatives to petroleum-based dielectrics, but oxidative instability from unsaturated bonds limits operational lifespan in transformers. While carnosic acid (CA) enhances soybean oil (SO) oxidation resistance, it introduces unacceptable dielectric loss and acidity. This challenge was addressed through the development of methyl carnosate (MC), a CA derivative that reduces acidity and dielectric loss while retaining the antioxidant catechol moiety. Thermal analysis and electron paramagnetic resonance (EPR) spectroscopy show MC significantly improves SO oxidation stability without compromising dielectric properties. MC-doped SO exhibits &gt; 10 °C higher oxidation onset temperature and delayed thermo-oxidative decomposition due to potent radical scavenging. Conformational analysis and bond dissociation enthalpy calculations reveal that MC’s dominant conformation, stabilized by intramolecular hydrogen bonding, facilitates preferential H-donation from the hydroxyl group ortho to the aliphatic ring, confirming sacrificial antioxidant behavior. MC is a promising eco-friendly antioxidant for natural ester dielectrics, enhancing longevity and performance.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"155 ","pages":"Pages 598-605"},"PeriodicalIF":5.9,"publicationDate":"2025-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146147578","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Dynamic combustion characteristics of wood biomass particles with an integrated spiral heat-conducting ring: Enhanced hydrogen production by heat recirculation","authors":"Wei Xu,&nbsp;Huaming Dai","doi":"10.1016/j.jiec.2025.07.061","DOIUrl":"10.1016/j.jiec.2025.07.061","url":null,"abstract":"<div><div>Converting biomass into hydrogen provides a carbon–neutral route to meet energy demand and curb climate change. This paper proposed a novel reactor design that integrated wood particles with a spiral heat-conducting ring to enhance the conversion efficiency of biomass. The effects of wood species and spiral heat-conducting ring parameters were investigated on product concentration and combustion temperature under different operating conditions. The results showed that the increasing of air velocity improved the combustion temperature, and the maximum hydrogen was obtained at 6 cm/s. The syngas production tended to increase as the height of wood particles decreased. Meanwhile, the addition of a Ni spiral heat-conducting ring increased the hydrogen concentration to 11.4 %, indicating a maximum growth rate of 122.6 %. Moreover, when the ring wire diameter decreased, the hydrogen concentration rose first and then declined. And a longer ring height extended the reaction path and increased the syngas yield. The corresponding results provided valuable insights to optimize the reactor geometry and operating conditions.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"155 ","pages":"Pages 486-511"},"PeriodicalIF":5.9,"publicationDate":"2025-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146147540","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Flexible multi-radiation shielding sponges based on pyridine-anchored boron nitride and bismuth halide composites","authors":"Hyeon-Kwang Kim ,&nbsp;Seok-Gyu Kang ,&nbsp;Dae-Seong Kwon ,&nbsp;Beom-Gyeong Seo ,&nbsp;Nazmul Hossain ,&nbsp;Shanmugam Mahalingam ,&nbsp;Junghwan Kim","doi":"10.1016/j.jiec.2025.08.001","DOIUrl":"10.1016/j.jiec.2025.08.001","url":null,"abstract":"<div><div>The development of lightweight, flexible, and multifunctional shielding materials is crucial for mitigating the complex radiation environment in space, comprising high-energy X-rays, protons, and secondary neutrons. In this study, we present a porous composite consisting of polydimethylsiloxane (PDMS), pyridine-functionalized boron nitride nanosheets (Py-BNN), and bismuth iodide (BiI₃) for enhanced multi-radiation shielding. Pyridine functionalization improves BNN dispersion in PDMS by enhancing interfacial compatibility, yielding a more uniform filler network. The porous architecture facilitates uniform BiI₃ adsorption throughout the matrix, thereby enhancing the attenuation of X-rays. Thermal analysis shows an elevated decomposition onset temperature of 504.3 °C for Py-BNN/PDMS, compared to 475.8 °C for BNN/PDMS and 445.7 °C for pure PDMS, indicating enhanced thermal stability from improved filler dispersion. Infrared thermography further confirms improved thermal conductivity. X-ray shielding results reveal the Py-BNN/PDMS/BiI₃ composite exhibits the highest linear attenuation coefficient (4.26  cm⁻¹) and the lowest half-value layer (0.163  cm), outperforming BNN/PDMS/BiI₃ and PDMS/BiI₃. Proton beam tests also show superior attenuation in Py-BNN/PDMS/BiI₃, attributed to the uniform dispersion of Py-BNN in the PDMS porous structures. Overall, the proposed composite achieves lightweight structure, thermal robustness, and effective shielding against multiple radiation types, demonstrating strong potential for next-generation aerospace radiation protection.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"155 ","pages":"Pages 542-550"},"PeriodicalIF":5.9,"publicationDate":"2025-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146147091","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Enhanced ice-phobic properties, harnessing a moisture-cure castor oil-derived silanized polyurethane coating","authors":"F.S. Hosseini,&nbsp;M. Shariatmadar,&nbsp;P. Gholamhosseini,&nbsp;M. Mahdavian","doi":"10.1016/j.jiec.2025.08.007","DOIUrl":"10.1016/j.jiec.2025.08.007","url":null,"abstract":"<div><div>An ice-phobic polyurethane (PU) coating from castor oil, modified with 3-aminopropyltriethoxysilane, has been developed. The castor oil-derived silanized polyurethane prepolymer (PreCOPU-Si) was synthesized using controlled reactions and characterized through advanced techniques, in comparison to the unsilanized prepolymer (PreCOPU). Moisture-cured coatings (COPU-Si and COPU) showed successful silane group incorporation. Ice adhesion tests revealed significantly reduced adhesion strength for COPU-Si: 0.2 MPa (normal tension) and 0.05 MPa (shear tension), compared to unmodified COPU (1.2 MPa and 0.17 MPa). Enhanced hydrophobicity was confirmed via water contact angle measurements and freezing studies, demonstrating reduced ice adhesion and stable droplet shapes. COPU-Si exhibited improved mechanical properties and strong adhesion (&gt;10 MPa) to fiberglass (FG), positioning this castor oil-derived silanized polyurethane coating as a sustainable, high-performance solution for ice-phobic applications.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"155 ","pages":"Pages 585-597"},"PeriodicalIF":5.9,"publicationDate":"2025-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146147577","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Evaluating sono-photo-fenton and photocatalytic performance of ternary InVO4/BiVO4/FeVO4 composite for tetracycline degradation in water","authors":"Priya Dhull ,&nbsp;Komal Poonia ,&nbsp;Sonu Sonu ,&nbsp;Pankaj Raizada ,&nbsp;Tansir Ahamad ,&nbsp;Savas Kaya ,&nbsp;Konstantin Katin ,&nbsp;Sourbh Thakur ,&nbsp;Chaudhery Mustansar Hussain ,&nbsp;Pardeep Singh","doi":"10.1016/j.jiec.2025.07.063","DOIUrl":"10.1016/j.jiec.2025.07.063","url":null,"abstract":"<div><div>The present work evaluated the efficacy of a Sono-Photo-Fenton technique using ternary vanadate InVO₄/BiVO₄/FeVO₄ for the degradation of tetracycline (TCL), a persistent pharmaceutical pollutant. A comprehensive evaluation of the ultrasound (US), Visible light (Vis-L), and advanced oxidation processes (AOPs) along with H₂O₂ and InVO₄/BiVO₄/FeVO₄ photocatalysts to elucidate synergistic effects and underlying mechanisms. The photocatalyst was prepared and characterized through several analytical methods, such as FESEM and TEM, and XRD to investigate their morphology and crystal size, revealing an average size of 271.9 nm, which confirms the uniformity of the synthesized particles. The electronic structure and band alignments of the InVO₄/BiVO₄/FeVO₄ photocatalyst were elucidated through DFT simulations, Tauc-plot, and Mott-Schottky (MS) analysis. Further, Electron spin resonance (ESR) analysis provides insights into the charge migration route during the proposed dual s-scheme mechanism. Significant degradation efficiency of 98.28 % was achieved under optimized conditions: H₂O₂ + InVO₄/BiVO₄/FeVO₄ dosage of 80 mg, ultrasonic frequency of 20 kHz, Vis-L power of 500 W, and a reaction time of 120 min. Degradation kinetics confirmed a pseudo-first-order reaction with rate constant of 0.036 min⁻¹, and the TCL degradation pathway was elucidated by LC-MS analysis, confirming the breakdown of TCL into CO₂, H₂O, and other inorganic substances. This study highlights the potential of energy-driven irradiation using three techniques US + Vis-L + H₂O₂-InVO₄/BiVO₄/FeVO₄ i.e., Sono-Photo-Fenton process using ternary vanadate as a promising strategy for the treatment of pharmaceutical contaminants in wastewater, offering insights into the mechanisms of enhanced degradation.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"155 ","pages":"Pages 512-524"},"PeriodicalIF":5.9,"publicationDate":"2025-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146147541","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Structurally self-assembled organic coating with remarkable anti-corrosion performance: Theoretical prediction and experimental validation","authors":"M’bark Elhaid ,&nbsp;Aisha H. Al-Moubaraki ,&nbsp;Jamilah M. Al-Ahmari ,&nbsp;Azza A. Al-Ghamdi ,&nbsp;Rachid Tihmmou ,&nbsp;Omar Id El Mouden ,&nbsp;Noureddine Elboughdiri ,&nbsp;Rachid Salghi ,&nbsp;Maryam Chafiq ,&nbsp;Abdelkarim Chaouiki ,&nbsp;Young Gun Ko ,&nbsp;Mohamed Abboud","doi":"10.1016/j.jiec.2025.07.062","DOIUrl":"10.1016/j.jiec.2025.07.062","url":null,"abstract":"<div><div>Despite the engineering potential offered by the integration of hybrid (organic and inorganic) materials, organic compounds with metal surfaces, in protecting corrosion-prone metals from harsh conditions, the interaction mechanisms between these components and their in-situ formation to induce nature-inspired composites remain insufficiently understood. In this study, an environmentally friendly organic coating (OC) was developed and applied to carbon steel (CS) substrates via a dip-coating process using an aqueous solution containing 2-amino-4-(4-chlorophenyl)-1-(1,3-dihydroxy-2-(hydroxymethyl)propan-2-yl)-5-oxo-1,4,5,6,7,8-hexahydroquinoline-3-carbonitrile (oh-HQc) compound. Surface characterization techniques, including SEM-EDX and FTIR, confirmed the successful deposition and chemical integrity of the as-synthesized OC. These results also demonstrate a strong interfacial affinity of oh-HQc molecules for the CS surface, facilitating the nucleation of a petal-like structure through active adsorption sites onto the CS surface. Subsequently, the fundamental formation mechanism governing the nucleation and oh-HQc self-assembly behavior, reactivity, and their adsorption behavior were analyzed based on advanced theoretical calculations. Owing to the oh-HQc donor–acceptor sites, the tested system with three oh-HQc fragments promotes the controlled growth of uniformly distributed flower-like structures via molecular self-assembly and inter/intra-fragmentation interactions. The as-fabricated OC was exposed to different aggressive media, including 1.0 HCl, 3.5 wt% NaCl, and 1.0 M H₂SO₄ environments to evaluate their electrochemical, short-term/long-term stability, and anticorrosion performance. This flower-like structure demonstrated superior anticorrosion performance, achieving an inhibition efficiency of approximately 95 % in 1.0 M HCl, 90 % in 3.5 % NaCl, and 51 % in H₂SO₄ environments. Our eco-conscious approach paves the way for a deeper exploration of the structural and functional potential of hydroxyquinoline (HQ) derivatives in the fabrication of advanced organic materials, not only characterized by remarkable properties but also benefiting from facile synthetic methodology, which is of paramount importance for industrial implementation.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"155 ","pages":"Pages 525-541"},"PeriodicalIF":5.9,"publicationDate":"2025-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146147090","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Optimizing flow capacitive deionization: a review of advances in flow channel geometry and active material selection","authors":"Shajjadur Rahman Shajid ,&nbsp;Monjur Mourshed ,&nbsp;Shah Tanvir Alam Rimon ,&nbsp;Md. Golam Kibria","doi":"10.1016/j.jiec.2025.08.003","DOIUrl":"10.1016/j.jiec.2025.08.003","url":null,"abstract":"<div><div>Flow capacitive deionization (FCDI) is emerging as a promising desalination technology, offering continuous operation, high water recovery (up to 97 %), and lower energy consumption than conventional methods. The performance of FCDI systems is primarily influenced by two critical factors: active electrode materials and flow channel geometries. These elements govern ion transport, charge transfer efficiency, and energy consumption. Although material and channel design improvements are often studied separately, their combined effect plays a pivotal role in optimizing performance and warrants integrated evaluation. This review focuses on recent advancements in both areas, consolidating progress in electrode material innovations and flow channel designs. Reported improvements include enhanced average salt removal rates (∼3.29 μmol cm² min⁻¹) and energy recovery efficiencies reaching 36 %. By presenting these developments, the review provides insights to guide future research and design strategies, reinforcing FCDI’s potential as a sustainable and scalable solution for high-salinity and large-scale water desalination applications.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"155 ","pages":"Pages 209-239"},"PeriodicalIF":5.9,"publicationDate":"2025-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146147539","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Anodization creates superhydrophobic surfaces with excellent anticorrosion and anti-icing properties using a mixture of ammonium fluoride and citric acid","authors":"Zhirong Zhang,&nbsp;Shuxian Ha,&nbsp;Guoxi Zhang","doi":"10.1016/j.jiec.2025.07.060","DOIUrl":"10.1016/j.jiec.2025.07.060","url":null,"abstract":"<div><div>A superhydrophobic surface with a hierarchical micro-nano structure was successfully fabricated on a titanium substrate via an economical anodization process using a 0.3 wt% NH₄F and 2 wt% C₆H₈O₇ electrolyte solution, followed by subsequent chemical modifications. The influence of anodic oxidation parameters, including oxidation time and voltage, on the morphology and wettability of the superhydrophobic surfaces was systematically investigated and optimized. Experimental results demonstrate that both oxidation time and voltage significantly affect the surface morphology and wettability. By adjusting these parameters, complex hierarchical structures such as nanopores, nanoclusters, micro/nano spherical particles and flower-like micro/nano protrusion structures can be precisely engineered on the titanium substrate. The optimal conditions for achieving a superhydrophobic surface are an oxidation voltage ranging from 30 to 70 V and an oxidation time ranging from 40 to 100 min. Under these conditions, the maximum water contact angle reached ∼163.4°, while the minimum sliding angle was ∼1°. The developed superhydrophobic surface not only exhibits superior anti-corrosion and anti-icing properties but also demonstrates low adhesion to water droplets, outstanding self-cleaning capabilities, and long-term stability.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"155 ","pages":"Pages 476-485"},"PeriodicalIF":5.9,"publicationDate":"2025-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146147069","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Two-dimensional MXenes as emerging multifunctional material for next-generation and sustainable application","authors":"Kefayat Ullah ,&nbsp;Muhammad Shah Zeb ,&nbsp;Wasifullah Khan ,&nbsp;Salman Alam ,&nbsp;Amin ur Rashid ,&nbsp;Won Chun Oh","doi":"10.1016/j.jiec.2025.07.058","DOIUrl":"10.1016/j.jiec.2025.07.058","url":null,"abstract":"<div><div>MXenes, two-dimensional transition metal carbides, nitrides, and carbonitrides, have rapidly emerged as promising multifunctional materials for advanced energy applications owing to their unique combination of metallic conductivity, hydrophilicity, and tunable surface chemistry. MXenes are materials obtained by selectively etching MAX phases (a family of layered compounds) and have desirable properties such as a high surface area, many active sites, and mechanical stability, ultimately making them promising materials for use in energy storage and sustainable systems. Here, we highlighted the most desirable application in energy production and storage devices. Surface termination plays a very important role in enhancing the optical and electrical properties of MXenes. The purpose of this brief study was to evaluate and highlight the advantages and disadvantages of 2D materials, MXenes, by extensively going over the principles and listing the possibilities in this growing field.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"155 ","pages":"Pages 147-163"},"PeriodicalIF":5.9,"publicationDate":"2025-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146147380","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Engineering of resin-based hard carbon with interconnected nanoparticles for enhanced sodium ion transport capability","authors":"Jia-Hang Li,&nbsp;Cheng-Qiu Deng,&nbsp;Chen Sun,&nbsp;Qiang Sun","doi":"10.1016/j.jiec.2025.07.059","DOIUrl":"10.1016/j.jiec.2025.07.059","url":null,"abstract":"<div><div>Resin-based hard carbon has become an ideal choice for the anode material of sodium-ion batteries due to its tunable microstructure and high sodium storage capacity. However, rational structural modulation to optimize its sodium-ion transport capability and improve its rate performance remains a critical challenge. In this study, a resorcinol–formaldehyde resin precursor was innovatively employed to construct a 3D interconnected spherical hard carbon framework. This structure establishes continuous conductive pathways, significantly enhancing charge transfer kinetics. And particle size variation was achieved through a solvent regulation strategy. Systematic investigations reveal that reducing particle size effectively shortens sodium-ion diffusion distances, leading to enhanced rate capability. The optimized anode demonstrates stable cyclability with capacity retention of 277.6 mAh g⁻¹ after 400 cycles at 0.1 A g⁻¹, while maintaining reversible capacity of 182.9 mAh g⁻¹ after 400 cycles under 0.5 A g⁻¹.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"155 ","pages":"Pages 468-475"},"PeriodicalIF":5.9,"publicationDate":"2025-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146147089","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}