Pub Date : 2024-06-13DOI: 10.1016/j.jiec.2024.06.021
Syed Muhammad Wajahat ul Hasnain, Ahmad Salam Farooqi, Bamidele Victor Ayodele, Herma Dina Setiabudi, Abid Salam Farooqi, Rayed S. Alshareef, Bawadi Abdullah
Palm Oil Fuel Ash (POFA) is massively produced by numerous palm oil mills worldwide, creating an environmental waste disposal problem. Notably, POFA serves as a cost-effective alternative silica source instead of the expensive tetraethyl orthosilicate (TEOS). This research focused on synthesizing SBA-15 from POFA waste and examining the effect of promoters on POFA-derived SBA-15-supported Ni-based catalysts. The 10 wt% Ni/SBA-15-POFA catalyst was sequentially impregnated with promoters having 1 wt% loading of Zr, Ce, La, and Cr. The catalysts were tested for CO methane reforming (CMR) at 800 °C for 8 hours while maintaining a stoichiometric feed ratio. Various characterization techniques, including XRD, FESEM, XPS, H-TPR, CO-TPD, and BET analysis were employed to assess the catalyst physicochemical properties. The addition of promoter changed the properties of catalyst. Except for Cr-promoted catalyst, the addition of promoters positively impacted catalytic performance, activity, and stability. XRD analysis showed that Cr addition had detrimental effects on the crystallite structure of the Ni/SBA-15-POFA catalyst. In contrast, Zr, Ce, and La additions significantly reduced the crystallite size and improved active metal dispersion. Overall, the Zr-promoted catalyst exhibited the best performance in terms of activity and stability, with a CH conversion of 90 % and CO conversion of 94.4 %. The spent catalyst characterization, including XRD, FESEM, O-TPO, and RAMAN, showed that promoter addition significantly reduced carbon deposition. The stable and superior perfromance of Zr-promoted catalyst was attributed to the production of MWCNTs. Conversely, the rapid deactivation of the unpromoted catalyst may be due to the formation of amorphous carbon, which tends to quickly block active sites and reduce the catalytic activity.
{"title":"Synthesis, characterization, and catalytic performance of Ni supported on sustainable POFA-derived SBA-15 for hydrogen-rich syngas from CO2 reforming of methane","authors":"Syed Muhammad Wajahat ul Hasnain, Ahmad Salam Farooqi, Bamidele Victor Ayodele, Herma Dina Setiabudi, Abid Salam Farooqi, Rayed S. Alshareef, Bawadi Abdullah","doi":"10.1016/j.jiec.2024.06.021","DOIUrl":"https://doi.org/10.1016/j.jiec.2024.06.021","url":null,"abstract":"Palm Oil Fuel Ash (POFA) is massively produced by numerous palm oil mills worldwide, creating an environmental waste disposal problem. Notably, POFA serves as a cost-effective alternative silica source instead of the expensive tetraethyl orthosilicate (TEOS). This research focused on synthesizing SBA-15 from POFA waste and examining the effect of promoters on POFA-derived SBA-15-supported Ni-based catalysts. The 10 wt% Ni/SBA-15-POFA catalyst was sequentially impregnated with promoters having 1 wt% loading of Zr, Ce, La, and Cr. The catalysts were tested for CO methane reforming (CMR) at 800 °C for 8 hours while maintaining a stoichiometric feed ratio. Various characterization techniques, including XRD, FESEM, XPS, H-TPR, CO-TPD, and BET analysis were employed to assess the catalyst physicochemical properties. The addition of promoter changed the properties of catalyst. Except for Cr-promoted catalyst, the addition of promoters positively impacted catalytic performance, activity, and stability. XRD analysis showed that Cr addition had detrimental effects on the crystallite structure of the Ni/SBA-15-POFA catalyst. In contrast, Zr, Ce, and La additions significantly reduced the crystallite size and improved active metal dispersion. Overall, the Zr-promoted catalyst exhibited the best performance in terms of activity and stability, with a CH conversion of 90 % and CO conversion of 94.4 %. The spent catalyst characterization, including XRD, FESEM, O-TPO, and RAMAN, showed that promoter addition significantly reduced carbon deposition. The stable and superior perfromance of Zr-promoted catalyst was attributed to the production of MWCNTs. Conversely, the rapid deactivation of the unpromoted catalyst may be due to the formation of amorphous carbon, which tends to quickly block active sites and reduce the catalytic activity.","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":null,"pages":null},"PeriodicalIF":6.1,"publicationDate":"2024-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141518137","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-01DOI: 10.1016/j.jiec.2024.06.016
Sara A. Sadek, S. Al‐Jubouri
{"title":"Highly efficient oil-in-water emulsion separation based on innovative stannic oxide/polyvinylchloride (SnO2/PVC) microfiltration membranes","authors":"Sara A. Sadek, S. Al‐Jubouri","doi":"10.1016/j.jiec.2024.06.016","DOIUrl":"https://doi.org/10.1016/j.jiec.2024.06.016","url":null,"abstract":"","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":null,"pages":null},"PeriodicalIF":6.1,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141414161","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-01DOI: 10.1016/j.jiec.2024.06.010
K. Dhanabalan, Kanakaraj Aruchamy, Ganesan Sriram, T. Sadhasivam, Tae Hwan Oh
{"title":"Recent recycling methods for spent cathode materials from lithium-ion batteries: A review","authors":"K. Dhanabalan, Kanakaraj Aruchamy, Ganesan Sriram, T. Sadhasivam, Tae Hwan Oh","doi":"10.1016/j.jiec.2024.06.010","DOIUrl":"https://doi.org/10.1016/j.jiec.2024.06.010","url":null,"abstract":"","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":null,"pages":null},"PeriodicalIF":6.1,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141415007","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-01DOI: 10.1016/j.jiec.2024.06.015
C. Lim, Seo Gyeong Jeong, Naeun Ha, Seong-shik Myeong, Chung Gi Min, Yunhua Yu, Xiaoping Yang, Young-Seak Lee
{"title":"Plasma-mediated f-doped activated carbon embedded with N and S atoms for the effective removal of CO2 gas","authors":"C. Lim, Seo Gyeong Jeong, Naeun Ha, Seong-shik Myeong, Chung Gi Min, Yunhua Yu, Xiaoping Yang, Young-Seak Lee","doi":"10.1016/j.jiec.2024.06.015","DOIUrl":"https://doi.org/10.1016/j.jiec.2024.06.015","url":null,"abstract":"","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":null,"pages":null},"PeriodicalIF":6.1,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141399081","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-01DOI: 10.1016/j.jiec.2024.06.014
B. Sung, Min-Tae Jeon, Hee-Kyung Kim, Ah Rum Baek, Dong-Seon Kim, Soyeon Kim, Minsup Kim, Dong-kyu Kim, Do-Geun Kim, Yongmin Chang
{"title":"Microglial activation-sensitive gadolinium complex as a potential MRI contrast agent for Alzheimer’s disease diagnosis","authors":"B. Sung, Min-Tae Jeon, Hee-Kyung Kim, Ah Rum Baek, Dong-Seon Kim, Soyeon Kim, Minsup Kim, Dong-kyu Kim, Do-Geun Kim, Yongmin Chang","doi":"10.1016/j.jiec.2024.06.014","DOIUrl":"https://doi.org/10.1016/j.jiec.2024.06.014","url":null,"abstract":"","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":null,"pages":null},"PeriodicalIF":6.1,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141397214","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A review on the application of perovskite catalysts for sulfate radical-based advanced oxidation processes","authors":"Ziyi Chen, Junyuan Guo, Quanhong Li, Yujing You, Zhiying Kuang, Lei Gao","doi":"10.1016/j.jiec.2024.06.007","DOIUrl":"https://doi.org/10.1016/j.jiec.2024.06.007","url":null,"abstract":"","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":null,"pages":null},"PeriodicalIF":6.1,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141400107","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-01DOI: 10.1016/j.jiec.2024.06.012
Jeong Min Seo, Hyun-tae Song, Ye-na Choi, Yu-jeong Yang, Hyun Dong Kim, Kwan-Young Lee, Dong Ju Moon
{"title":"Catalytic decomposition of HFC-134a over metal oxide and phosphate catalysts to VDF: Reaction pathways of CH4 addition","authors":"Jeong Min Seo, Hyun-tae Song, Ye-na Choi, Yu-jeong Yang, Hyun Dong Kim, Kwan-Young Lee, Dong Ju Moon","doi":"10.1016/j.jiec.2024.06.012","DOIUrl":"https://doi.org/10.1016/j.jiec.2024.06.012","url":null,"abstract":"","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":null,"pages":null},"PeriodicalIF":6.1,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141400716","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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