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Improved deep mixed kernel randomized network for wind speed prediction 改进的深度混合核随机化网络风速预测
4区 环境科学与生态学 Q3 ENERGY & FUELS Pub Date : 2023-09-20 DOI: 10.1093/ce/zkad042
Vijaya Krishna Rayi, Ranjeeta Bisoi, S P Mishra, P K Dash
Abstract Forecasting wind speed is an extremely complicated and challenging problem due to its chaotic nature and its dependence on several atmospheric conditions. Although there are several intelligent techniques in the literature for wind speed prediction, their accuracies are not yet very reliable. Therefore, in this paper, a new hybrid intelligent technique named the deep mixed kernel random vector functional-link network auto-encoder (AE) is proposed for wind speed prediction. The proposed method eliminates manual tuning of hidden nodes with random weights and biases, providing prediction model generalization and representation learning. This reduces reconstruction error due to the exact inversion of the kernel matrix, unlike the pseudo-inverse in a random vector functional-link network, and shortens the execution time. Furthermore, the presence of a direct link from the input to the output reduces the complexity of the prediction model and improves the prediction accuracy. The kernel parameters and coefficients of the mixed kernel system are optimized using a new chaotic sine–cosine Levy flight optimization technique. The lowest errors in terms of mean absolute error (0.4139), mean absolute percentage error (4.0081), root mean square error (0.4843), standard deviation error (1.1431) and index of agreement (0.9733) prove the efficiency of the proposed model in comparison with other deep learning models such as deep AEs, deep kernel extreme learning machine AEs, deep kernel random vector functional-link network AEs, benchmark models such as least square support vector machine, autoregressive integrated moving average, extreme learning machines and their hybrid models along with different state-of-the-art methods.
风速预报由于其混沌性和对多种大气条件的依赖,是一个极其复杂和具有挑战性的问题。虽然文献中有几种用于风速预测的智能技术,但它们的准确性还不是很可靠。为此,本文提出了一种新的用于风速预测的混合智能技术——深度混合核随机向量函数链网络自编码器(AE)。该方法消除了对具有随机权重和偏差的隐藏节点的人工调整,提供了预测模型的泛化和表示学习。与随机向量函数链接网络中的伪逆不同,这减少了由于核矩阵的精确反转而导致的重构误差,并缩短了执行时间。此外,从输入到输出的直接链接的存在降低了预测模型的复杂性,提高了预测精度。采用一种新的混沌正弦余弦列维飞行优化技术对混合核系统的核参数和核系数进行了优化。在平均绝对误差(0.4139)、平均绝对百分比误差(4.0081)、均方根误差(0.4843)、标准差误差(1.1431)和一致性指数(0.9733)方面的最小误差证明了该模型与其他深度学习模型(如深度ae、深度核极限学习机ae、深度核随机向量函数链接网络ae、最小二乘支持向量机等基准模型)相比的有效性。自回归综合移动平均、极限学习机及其混合模型以及不同的最先进的方法。
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引用次数: 0
Mitigation of the impacts of electric vehicle charging on energy-star ratings for residential buildings in India 缓解电动汽车充电对印度住宅建筑能源之星评级的影响
4区 环境科学与生态学 Q3 ENERGY & FUELS Pub Date : 2023-09-13 DOI: 10.1093/ce/zkad041
Rakesh Dalal, Devender Kumar Saini
Abstract The star-labelling programme for residential buildings was introduced by India in 2020 and applies to all residential buildings with no lower limit on the built-up area or electrical demand. The energy-star label for a residential building is awarded against the notified standard by the regulatory body and electric vehicles (EVs) have not been accommodated as a load for residential buildings. The energy consumption of an existing residential building is taken from a study already carried out and compared with the requirement of the Indian residential star-labelling programme with an EV as a plugged-in load. An annual energy gap of 6060 kWh for the existing residential buildings considered in this study for five-star building energy labels increases to 7784 kWh if the EV load is added to the building load. The residential building will lose two energy stars if it caters to the EV load and, to bridge this energy gap, the replacement of existing electrical appliances with five-star-rated energy appliances, employing grid-connected rooftop solar photovoltaics (PV) and retrofit of the building envelope are considered. The techno-economic potential of rooftop solar PV and building envelope retrofitting for existing residential buildings is explored using RETScreen® and eQUEST software, respectively. The study establishes that the installation of rooftop solar PV can accommodate the additional load of EVs and can bridge half and three-quarters of the energy gap to achieve five energy stars for an existing building with and without EVs, respectively. It is the most economical option among the options explored in this study. The target Energy Performance Index is achievable by high-end energy consumers (12 000 kWh/year) by additional measures, the replacement of inefficient electrical appliances and building envelope retrofitting in addition to the installation of rooftop solar PV.
印度于2020年推出住宅建筑星级标签计划,适用于所有住宅建筑,没有建筑面积或电力需求的下限。住宅建筑的能源之星标签是根据监管机构的公告标准颁发的,而住宅建筑没有容纳电动汽车作为负荷。现有住宅建筑的能源消耗取自一项已经进行的研究,并与印度住宅星级标签计划的要求进行了比较,其中电动汽车作为插入式负载。如果将电动汽车负荷加入建筑负荷中,本研究考虑的现有住宅建筑五星级建筑能源标签的年能源缺口为6060千瓦时,则增加到7784千瓦时。如果住宅楼满足电动汽车负荷,将失去两颗能源之星。为了弥补这一能源差距,考虑将现有电器更换为五星级能源电器,采用并网屋顶太阳能光伏发电(PV)和改造建筑围护结构。利用RETScreen®和eQUEST软件分别探讨了现有住宅屋顶太阳能光伏和建筑围护结构改造的技术经济潜力。该研究表明,安装屋顶太阳能光伏可以容纳电动汽车的额外负荷,可以弥合一半和四分之三的能源缺口,分别为有电动汽车和没有电动汽车的现有建筑达到五星级能源。这是本研究探索的方案中最经济的方案。高端能源消费者可透过额外措施、更换效率低下的电器及加装楼宇围护结构,以及安装屋顶太阳能光伏装置,达到能源表现指数的目标(每年12 000千瓦时)。
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引用次数: 0
Investigating energy policies to boost grid-connected rooftop solar PV in Sudan 研究能源政策以促进苏丹屋顶太阳能光伏并网
4区 环境科学与生态学 Q3 ENERGY & FUELS Pub Date : 2023-09-13 DOI: 10.1093/ce/zkad044
Tarig Z Ahmed, Ayah Mohamed, Mawahib Eltayeb Ahmed, Ahmed Osman Elamin Abdalgader, Mohamed G Hassan-Sayed
Abstract Grid-connected rooftop solar photovoltaic (PV) systems can reduce the energy demand from the grid and significantly increase the power available to it. However, rooftop solar PV has not yet been widely adopted in many sub-Saharan African countries, such as Sudan, although they are endowed with high solar radiation and in dire need of additional power. This paper investigates risks and policies to increase grid-connected rooftop solar PV adoption in Sudan. A simplified United Nations Development Program Derisking Renewable Energy Investment framework is adopted to investigate this over three stages. For Stage 1, a list of risks and barriers was produced based on a literature review of solar PV studies in Sudan and interviews with nine stakeholders. Affordability was the risk most often mentioned (eight times from nine interviewees), followed by concerns about poor utility grid infrastructure. For Stage 2, policy de-risking instruments and financial de-risking instruments were listed to overcome the barriers. These include the introduction of net metering, the use of a third-party organization to monitor policy implementation, upgrade of the grid infrastructure, public awareness campaigns and energy-saving schemes. For Stage 3, the levelized cost of electricity was estimated for a typical 2-kW rooftop PV system without policies (0.11 $/kWh) and with a net-metering policy (0.07 $/kWh).
摘要屋顶太阳能光伏并网系统可以减少电网的能源需求,并显著增加电网的可用功率。然而,屋顶太阳能光伏尚未在许多撒哈拉以南非洲国家广泛采用,例如苏丹,尽管这些国家具有高太阳辐射并且迫切需要额外的电力。本文研究了增加苏丹屋顶并网太阳能光伏采用的风险和政策。采用了简化的联合国开发计划署降低可再生能源投资风险框架,分三个阶段对此进行调查。在第一阶段,根据对苏丹太阳能光伏研究的文献综述和对九个利益相关者的访谈,编制了一份风险和障碍清单。可负担性是最常被提及的风险(9位受访者中有8次提到),其次是对电网基础设施薄弱的担忧。对于第二阶段,列出了政策去风险工具和金融去风险工具来克服障碍。这些措施包括引入净计量、利用第三方组织监督政策实施、电网基础设施升级、公众意识运动和节能计划。对于第三阶段,估计了典型的2千瓦屋顶光伏系统在没有政策(0.11美元/千瓦时)和有净计量政策(0.07美元/千瓦时)的平准化电力成本。
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引用次数: 0
Optimal control of a hybrid microgrid for hydrogen-based heat supply using deep reinforcement learning 基于深度强化学习的氢基供热混合微电网最优控制
4区 环境科学与生态学 Q3 ENERGY & FUELS Pub Date : 2023-09-13 DOI: 10.1093/ce/zkad038
Robin Heckmann
Abstract Green hydrogen is considered one of the key technologies of the energy transition, as it can be used to store surpluses from renewable energies in times of high solar radiation or wind speed for use in dark lulls. This paper examines the decarbonization potential of hydrogen for the heating industry. Worldwide, 99% of hydrogen is produced from fossil fuels, because hydrogen derived from renewable energy sources remains prohibitively expensive compared with its conventional counterpart. However, due to the expansion of renewable energy sources and the current energy crisis of conventional energy sources, hydrogen from renewable energy sources is becoming more and more economical. To optimize the efficiency of green hydrogen production and make it more price-competitive, the author simulates a hydrogen production plant consisting of a photovoltaic plant, a power grid, hydrogen storage, an electrolyser, a natural gas purchase option, a district heating plant and households. Using the deep deterministic policy gradient algorithm from deep reinforcement learning, the plant is designed to optimize itself by simulating different production scenarios and deriving strategies. The connected district heating plant is used to map how hydrogen can be optimally used for heat supply. A demonstrable outcome of this paper is that the utilization of deep deterministic policy gradient, over the course of a full year, can result in a competitive production of hydrogen derived from renewable or stored energy sources for the heating industry as a natural gas substitute.
绿色氢被认为是能源转型的关键技术之一,因为它可以在太阳辐射高或风速大的时候储存可再生能源的盈余,以便在黑暗的平静中使用。本文探讨了氢在供热工业中的脱碳潜力。在世界范围内,99%的氢是由化石燃料产生的,因为与传统燃料相比,从可再生能源中提取的氢仍然过于昂贵。然而,由于可再生能源的扩张和当前常规能源的能源危机,可再生能源制氢正变得越来越经济。为了优化绿色制氢的效率,使其更具价格竞争力,作者模拟了一个由光伏电站、电网、储氢器、电解槽、天然气购买选项、区域供热厂和家庭组成的制氢工厂。利用深度强化学习的深度确定性策略梯度算法,通过模拟不同的生产场景并推导策略来优化工厂。连接的区域供热厂用于绘制氢气如何最佳地用于供热的地图。本文的一个可证明的结果是,利用深度确定性政策梯度,在整整一年的过程中,可以导致从可再生能源或储存能源中获得氢气的竞争性生产,作为供暖行业的天然气替代品。
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引用次数: 0
The UAE’s energy system and GHG emissions: pathways to achieving national goals by 2050 阿联酋的能源系统和温室气体排放:实现2050年国家目标的途径
4区 环境科学与生态学 Q3 ENERGY & FUELS Pub Date : 2023-09-13 DOI: 10.1093/ce/zkad040
Ammar Hummieda, Ali Bouabid, Karim Moawad, Ahmad Mayyas
Abstract In recent years, the United Arab Emirates (UAE) has developed strategies to increase renewable power generation and reduce emissions to net zero by 2050. Electricity generation and energy-intensive industries (EII) have the largest potentials for emission reduction. Therefore, an up-to-date inventory of greenhouse gas emissions and a study of the pathways to achieving the 2050 targets are essential. This study focuses on power production and EII (aluminium, steel and cement). The structure of these sectors is modelled and simulated up to 2050 using a system dynamics (SD) methodology. The SD model is validated to reflect the real-world state of the system using the emissions inventory projections as reference modes. Nineteen mitigation policies are considered in the selected sectors and four policy scenarios were simulated. The results show that implementing the Energy Strategy 2050 in the power sector can result in a reduction of 63.5% in emissions in that sector, which translates into a reduction of 33.5% overall by 2050. Additionally, implementing all identified mitigation strategies to full utilization in EII yields a 94% reduction in that sector, which translates into a 78% reduction overall. Decarbonizing the aluminium industry yields the highest emissions reductions, followed by power production, then cement and finally steel. In the best-case scenario, 22.1% of the business-as-usual emissions are still released and further decarbonization—mainly in the power sector—will be required. This is achievable given the trajectory of the UAE’s successful nuclear energy programme and the prospect of utilizing carbon capture, utilization and storage even further.
近年来,阿拉伯联合酋长国(UAE)制定了增加可再生能源发电和到2050年将净零排放的战略。发电和能源密集型工业(EII)的减排潜力最大。因此,最新的温室气体排放清单和实现2050年目标的途径研究至关重要。这项研究的重点是电力生产和EII(铝、钢和水泥)。使用系统动力学(SD)方法对这些部门的结构进行建模和模拟,直至2050年。使用排放清单预测作为参考模式,验证了SD模型以反映系统的实际状态。在选定的部门中考虑了19项缓解政策,并模拟了4种政策情景。结果表明,在电力部门实施2050年能源战略可以使该部门的排放量减少63.5%,到2050年总体减少33.5%。此外,实施所有已确定的缓解战略以充分利用环境影响评价,可使该部门减少94%的排放量,从而使总体排放量减少78%。铝工业脱碳的排放量最高,其次是电力生产,然后是水泥,最后是钢铁。在最好的情况下,仍有22.1%的排放量照常排放,进一步的脱碳——主要是在电力部门——将是必需的。考虑到阿联酋成功的核能计划的发展轨迹,以及进一步利用碳捕获、利用和储存的前景,这是可以实现的。
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引用次数: 0
Renewable energy in Benin: current situation and future prospects 贝宁的可再生能源:现状和未来前景
4区 环境科学与生态学 Q3 ENERGY & FUELS Pub Date : 2023-09-13 DOI: 10.1093/ce/zkad039
Romain Akpahou, Lena D Mensah, David A Quansah
Abstract To provide clean energy at a lower cost to their citizens, all nations of the world are striving to increase their energy production in an environmentally friendly way. Benin has also joined this dynamic by considerably increasing its green energy production efforts in recent years. The country has a huge undeveloped renewable-energy (RE) potential that can contribute considerably to its national energy production capacity. This paper summarizes the current RE situation in Benin and examines its future prospects. The current energy situation of the country is discussed, followed by an examination of its electricity demand-and-supply situation. The country has been found to depend heavily on natural gas and petroleum products from neighbouring countries and has ~41% of national electricity access. However, the government is taking considerable steps to implement RE projects in the country. The study analyzes government targets in the energy sector with existing policies and institutional frameworks. Recommendations are made for the benefit of the government, the private sector and other actors in order to developing the RE potential of Benin.
为了以更低的成本向国民提供清洁能源,世界各国都在努力以环保的方式增加能源生产。贝宁也加入了这一动态,近年来大大增加了其绿色能源生产的努力。该国拥有巨大的未开发的可再生能源潜力,可以为其国家能源生产能力做出重大贡献。本文总结了贝宁可再生能源的现状,并对其未来前景进行了展望。讨论了该国目前的能源情况,然后审查了其电力需求和供应情况。人们发现该国严重依赖邻国的天然气和石油产品,并拥有约41%的全国电力供应。然而,政府正在采取相当大的步骤在该国实施可再生能源项目。该研究利用现有政策和体制框架分析了政府在能源领域的目标。为了开发贝宁的可再生能源潜力,本报告提出了有利于政府、私营部门和其他行为者的建议。
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引用次数: 0
Experimental study on hybridization of a PV–TEG system for electrical performance enhancement using heat exchangers, energy, exergy and economic levelized cost of energy (LCOE) analysis 利用热交换器、能源、火用和经济平化能源成本(LCOE)分析提高PV-TEG系统电性能的混合实验研究
4区 环境科学与生态学 Q3 ENERGY & FUELS Pub Date : 2023-08-01 DOI: 10.1093/ce/zkad023
Mohammed A Qasim, Vladimir I Velkin, Sergey E Shcheklein
Abstract The concept of employing thermoelectric generators (TEGs) to recover energy from waste heat has gained popularity, with applications that range from milliwatt to kilowatt levels of output power. In this study, a hybrid photovoltaic panel and thermoelectric generator (HPVTEG) system consisting of an integrated heat exchanger, a commercial polycrystalline silicon photovoltaic (PV) panel and a commercial bismuth telluride TEG was proposed. Here, TE components can be used to cool PV modules, increasing their output power via the Seebeck effect. The main finding is that the hybrid system has a reduced average temperature of 16.01°C. The average power of the stand-alone PV panel is 28.06 W, but that of the HPVTEG system is 32.76 W, which is an increase of 4.7 W. The conversion efficiency and power of the hybrid system increased by 16.7% and 16.4%, respectively, compared with a stand-alone PV panel. The HPVTEG system achieved an average exergy efficiency of 12.79% compared with 10.98% for a stand-alone PV panel. According to the calculation results, the levelized cost of energy (LCOE) of the stand-alone PV panel can range from 0.06741 to 0.10251 US$/kWh depending on how many days it is in operation, while the LCOE of the HPVTEG system can range from 0.06681 to 0.10160 US$/kWh.
利用热电发电机(teg)从废热中回收能量的概念已经得到了普及,其应用范围从毫瓦到千瓦的输出功率。在这项研究中,提出了一种由集成热交换器、商用多晶硅光伏(PV)面板和商用碲化铋TEG组成的混合光伏板和热电发电机(HPVTEG)系统。在这里,TE组件可以用来冷却光伏组件,通过塞贝克效应增加其输出功率。主要发现是混合系统的平均温度降低了16.01°C。单机光伏板的平均功率为28.06 W,而HPVTEG系统的平均功率为32.76 W,增加了4.7 W。与独立光伏面板相比,混合系统的转换效率和功率分别提高了16.7%和16.4%。HPVTEG系统的平均火用效率为12.79%,而独立光伏板的平均火用效率为10.98%。根据计算结果,独立光伏板的平准化能源成本(LCOE)根据其运行天数的不同,可以在0.06741 ~ 0.10251美元/千瓦时之间,而HPVTEG系统的LCOE可以在0.06681 ~ 0.10160美元/千瓦时之间。
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引用次数: 0
Power quality assessment in different wind power plant models considering wind turbine wake effects 考虑尾流效应的不同风电场模型的电能质量评价
4区 环境科学与生态学 Q3 ENERGY & FUELS Pub Date : 2023-08-01 DOI: 10.1093/ce/zkad033
Mohsen Khatamiaghda, Saeed Bahraminejad, Roohollah Fadaeinedjad
Abstract The intense increase in the installed capacity of wind farms has required a computationally efficient dynamic equivalent model of wind farms. Various types of wind-farm modelling aim to identify the accuracy and simulation time in the presence of the power system. In this study, dynamic simulation of equivalent models of a sample wind farm, including single-turbine representation, multiple-turbine representation, quasi-multiple-turbine representation and full-turbine representation models, are performed using a doubly-fed induction generator wind turbine model developed in DIgSILENT software. The developed doubly-fed induction generator model in DIgSILENT is intended to simulate inflow wind turbulence for more accurate performance. The wake effects between wind turbines for the full-turbine representation and multiple-turbine representation models have been considered using the Jensen method. The developed model improves the extraction power of the turbine according to the layout of the wind farm. The accuracy of the mentioned methods is evaluated by calculating the output parameters of the wind farm, including active and reactive powers, voltage and instantaneous flicker intensity. The study was carried out on a sample wind farm, which included 39 wind turbines. The simulation results confirm that the computational loads of the single-turbine representation (STR), the multiple-turbine representation and the quasi-multiple-turbine representation are 1/39, 1/8 and 1/8 times the full-turbine representation model, respectively. On the other hand, the error of active power (voltage) with respect to the full-turbine representation model is 74.59% (1.31%), 43.29% (0.31%) and 7.19% (0.11%) for the STR, the multiple-turbine representation and the quasi-multiple representation, respectively.
摘要随着风电场装机容量的急剧增加,需要一种计算效率高的风电场动态等效模型。各种类型的风电场建模旨在确定在电力系统存在的情况下的精度和仿真时间。本研究利用DIgSILENT软件开发的双馈感应发电机风力机模型,对某样例风电场的等效模型进行了动态仿真,包括单机表示、多机表示、准多机表示和全机表示模型。DIgSILENT中开发的双馈感应发电机模型旨在模拟入流风湍流,以获得更准确的性能。采用Jensen方法考虑了全机表示和多机表示模型中风力机之间的尾迹效应。该模型根据风电场的布局,提高了风机的抽油功率。通过计算风电场的输出参数,包括有功功率、无功功率、电压和瞬时闪变强度,对上述方法的准确性进行了评价。这项研究是在一个风电场样本上进行的,其中包括39个风力涡轮机。仿真结果表明,单涡轮表示、多涡轮表示和准多涡轮表示的计算负荷分别是全涡轮表示模型的1/39、1/8和1/8。另一方面,STR、多机表示和准多机表示的有功功率(电压)相对于全机表示模型的误差分别为74.59%(1.31%)、43.29%(0.31%)和7.19%(0.11%)。
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引用次数: 0
Simultaneous allocation of renewable energy sources and custom power quality devices in electrical distribution networks using artificial rabbits optimization 利用人工兔子优化配电网中可再生能源和定制电能质量装置的同步分配
4区 环境科学与生态学 Q3 ENERGY & FUELS Pub Date : 2023-07-31 DOI: 10.1093/ce/zkad019
Ranga Rao Chegudi, Balamurugan Ramadoss, Ramakoteswara Rao Alla
Abstract This study suggests an optimal renewable energy source (RES) allocation and distribution-static synchronous compensator (D-STATCOM) and passive power filters (PPFs) for an electrical distribution network (EDN) to improve its performance and power quality (PQ). First, the latest metaheuristic artificial rabbits optimization (ARO) is used to locate and size solar photovoltaic (PV), wind turbine (WT) and D-STATCOM units. In the second stage, ratings of single-tuned PPFs and D-STATCOMs at the RESs are determined, considering non-linear loads in the network. The multi-objective function reduces power loss, improves the voltage stability index (VSI) and limits total harmonic distortion. Simulations using the IEEE 33-bus EDN compared the ARO results with those of previous studies. In the first scenario, ideally integrated D-STATCOMs, PVs and WTs reduced losses by 34.79%, 64.74% and 94.15%, respectively. VSI increases from 0.6965 to 0.7749, 0.8804 and 0.967. The optimal WT integration of the first scenario outperformed the PVs and D-STATCOMs. The second step optimizes the WTs and PQ devices for non-linear loads. WTs and D-STATCOMs reduce the maximum total harmonic distortion of the voltage waveform by 5.21% with non-linear loads to 3.23%, while WTs and PPFs reduce it to 4.39%. These scenarios demonstrate how WTs and D-STATCOMs can improve network performance and PQ. The computational efficiency of ARO is compared to that of the pathfinder algorithm, future search algorithm, butterfly optimization algorithm and coyote optimization algorithm. ARO speeds up convergence and improves solution quality and comprehension.
摘要:本文提出了一种优化的可再生能源(RES)分配和分配方法——静态同步补偿器(D-STATCOM)和无源电力滤波器(ppf),以提高配电网(EDN)的性能和电能质量(PQ)。首先,采用最新的元启发式人工兔子优化算法(ARO)对太阳能光伏(PV)、风力发电(WT)和D-STATCOM单元进行定位和尺寸确定。在第二阶段,考虑到网络中的非线性负载,确定单调谐ppf和d - statcom在RESs的额定值。多目标函数降低了功率损耗,提高了电压稳定指数(VSI),限制了总谐波失真。使用IEEE 33总线的EDN进行仿真,将ARO结果与先前的研究结果进行了比较。在第一种情况下,理想地集成d - statcom、pv和wt分别减少了34.79%、64.74%和94.15%的损耗。VSI从0.6965上升到0.7749、0.8804和0.967。第一种方案的最佳WT集成优于pv和d - statcom。第二步针对非线性负载优化WTs和PQ器件。在非线性负载下,WTs和d - statcom将电压波形的最大总谐波失真降低5.21%至3.23%,而WTs和ppf将其降低至4.39%。这些场景展示了wt和d - statcom如何提高网络性能和PQ。将ARO算法的计算效率与探路者算法、未来搜索算法、蝴蝶优化算法和郊狼优化算法进行了比较。ARO加快了收敛速度,提高了解决方案的质量和可理解性。
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引用次数: 0
Origin of hydrogen in aromatic and olefin products derived from (Al-) MCM-41 catalysed co-pyrolysis of glucose and polypropylene via isotopic labelling 通过同位素标记研究(Al-) MCM-41催化葡萄糖和聚丙烯共热解产物中氢的来源
4区 环境科学与生态学 Q3 ENERGY & FUELS Pub Date : 2023-03-23 DOI: 10.1093/ce/zkac059
Junjie Xue, Jiankun Zhuo, Yifan Wu, Mingnuo Jin, Mufei Sun, Qiang Yao
Abstract Catalytic co-pyrolysis of biomass and plastic is an effective method to improve bio-oil produced by biomass pyrolysis. To further exploit the synergistic mechanism between biomass and plastic, co-pyrolysis of polypropylene (PP) and deuterated glucose (G) (1:1 wt%) over mesoporous catalysts MCM-41 (M) and Al-MCM-41(Al) was studied using a thermal gravimetric analyser (TGA) and pyrolysis–gas chromatography–mass spectrometry. The findings show that M and Al overlap the decomposition of PP and G, making synergy possible. With catalysts M and Al, the yield of olefins increases sharply to 36.75% and 13.66% more than the calculated value. Additionally, hydrogen transfers from G to 4C–13C olefins and aromatic products are influenced by the catalysts. Without a catalyst, there is no deuterium in all the co-pyrolytic products. However, catalysts M and Al can help transfer one to four deuterium atoms from G to the products. M and Al provide the pool for the intermediates of PP and G to form synergetic products. Additionally, Al helps break the carbon chain and transfer more deuterium into the products by reducing carbon atoms.
摘要生物质与塑料催化共热解是改善生物质热解生产生物油的有效方法。为了进一步探索生物质与塑料之间的协同作用机制,采用热重分析仪(TGA)和热解-气相色谱-质谱联用技术研究了介孔催化剂MCM-41(M)和Al-MCM-41(Al)对聚丙烯(PP)和氘化葡萄糖(G) (1:1 wt%)的共热解。研究结果表明,M和Al重叠分解PP和G,使协同作用成为可能。在M和Al催化剂的作用下,烯烃收率比计算值分别提高了36.75%和13.66%。此外,氢从G到4C-13C烯烃和芳香产物的转移也受到催化剂的影响。没有催化剂,所有的共热解产物中都没有氘。然而,催化剂M和Al可以帮助将1到4个氘原子从G转移到产物中。M和Al为PP和G的中间体形成协同产物提供了池。此外,人工智能有助于打破碳链,并通过减少碳原子将更多的氘转移到产品中。
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Clean Energy
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