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Electromagnetic optimization of piezoelectric ceramic and its application in mechanical antenna 压电陶瓷的电磁优化及其在机械天线中的应用
IF 2.7 Q1 Physics and Astronomy Pub Date : 2024-01-18 DOI: 10.1049/nde2.12077
Song Gao, Liwei Wang, Jingtong Lu, Shuai Zhang, Hongyu Sun, Kai Huang, Jianchun Xu, Yanan Hao

Mechanical antennas have garnered considerable attention due to their ability to address the challenges posed by the significant size and high energy consumption associated with traditional electric antennas when operating at low frequencies. Here, a compact and structurally stable mechanical antenna design is presented. The proposed antenna is constructed using cylindrical piezoelectric ceramics, which have dimensions smaller than 1/1000 of the wavelength. The scrutiny of the influence exerted by the antenna feed area and material thickness on the radiation performance was undertaken, followed by an exhaustive discourse on these effects. Experimental measurements demonstrate the practical functionalities of signal coding, transmission, and reception in the low-frequency communication system. Notably, at a frequency of 288 kHz, a single proposed antenna achieves an effective information transmission distance of 60 m using binary information coding. This remarkable outcome underscores the potential of this design in facilitating the development of portable and cost-effective wireless communication equipment for low-frequency applications.

机械天线能够解决传统电动天线在低频工作时体积大、能耗高的难题,因此备受关注。本文介绍了一种结构紧凑、性能稳定的机械天线设计。该天线采用圆柱形压电陶瓷制成,其尺寸小于波长的 1/1000。我们仔细研究了天线馈电面积和材料厚度对辐射性能的影响,并对这些影响进行了详尽的论述。实验测量证明了低频通信系统中信号编码、传输和接收的实用功能。值得注意的是,在频率为 288 kHz 时,使用二进制信息编码,单个拟议的天线可实现 60 米的有效信息传输距离。这一引人注目的成果凸显了这一设计在促进低频应用领域便携式、低成本无线通信设备开发方面的潜力。
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引用次数: 0
A strong dependence of sputtering power on c-axis oriented aluminium nitride on Si (111): A structural and electrical study 溅射功率对 Si (111) 上 c 轴取向氮化铝的强烈依赖性:结构和电学研究
IF 2.7 Q1 Physics and Astronomy Pub Date : 2024-01-03 DOI: 10.1049/nde2.12076
Sandeep Sanjeeva, Jyothilakshmi Rudresh, K. B. Vinayakumar, K. K. Nagaraja

Growing and controlling the c-axis orientation of the aluminium nitride (AlN) thin film on unheated Si (111) substrates using reactive magnetron sputtering are challenging. Sputtering parameters such as nitrogen concentration and sputtering power were effectively tuned to grow the c-axis oriented AlN thin film. The results show that a low concentration of (25%) N2 is enough for forming AlN at a reduced flow rate, whereas a higher flow rate requires a higher concentration of N2. Low concentration with a low flow rate is preferred to grow AlN at low temperature and power. The poor crystallinity of AlN with (100) orientation was improved by varying the power from 75 to 175 W. The X-ray diffraction results confirmed the improvisation of crystallinity of grown AlN films and indicated the strong dependence of preferred c-axis orientation on sputtering power. Also, the dependence of sputtering power on microstrain and stress was analysed. The surface morphology study by field emission scanning electron microscopy and topography measured by an atomic force microscope shows a dependence on sputtering power. The high c-axis orientation was observed at 175 W with low surface roughness, low leakage current density (2 × 10−9 A/cm2) and low dielectric constant (6.8).

利用反应磁控溅射技术在未加热的硅(111)基板上生长和控制氮化铝(AlN)薄膜的 c 轴取向是一项挑战。我们对氮浓度和溅射功率等溅射参数进行了有效调整,以生长出 c 轴取向的氮化铝薄膜。结果表明,低浓度(25%)的氮气足以在较低的流速下形成氮化铝,而较高的流速则需要较高浓度的氮气。要在低温和低功率条件下生长氮化铝,最好采用低浓度和低流速。X 射线衍射结果证实了生长的 AlN 薄膜结晶度的提高,并表明优先 c 轴取向与溅射功率密切相关。此外,还分析了溅射功率对微应变和应力的影响。通过场发射扫描电子显微镜进行的表面形貌研究和原子力显微镜测量的形貌显示了对溅射功率的依赖性。在表面粗糙度低、漏电流密度低(2 × 10-9 A/cm2)和介电常数低(6.8)的情况下,175 W 时观察到高 c 轴取向。
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引用次数: 0
The effects of chlorotrifluoroethylene (CTFE) units on the dielectric and energy storage properties of P(VDF-CTFE) 三氟氯乙烯 (CTFE) 单元对 P(VDF-CTFE) 介电和储能特性的影响
IF 2.7 Q1 Physics and Astronomy Pub Date : 2024-01-03 DOI: 10.1049/nde2.12075
Haoran Xie, Xi Yuan, Hang Luo, Dou Zhang

Polyvinylidene fluoride-based ferroelectric polymers are favoured in the field of advanced high-energy-storage dielectric capacitors due to their strong spontaneous polarisation and high dielectric constant (εr). It has been confirmed that the ferroelectric behaviour and energy storage performance can be regulated by copolymerising polyvinylidene fluoride with bulky monomers such as chlorotrifluoroethylene, and hexafluoropropylene. Past research based on these copolymers mostly focused on the preparation of composites, yet with limited discussion on the effect of copolymer composition. In this work, a series of P(VDF-CTFE) films with different chlorotrifluoroethylene contents were fabricated through a solution-casting method. The introduction of bulky chlorotrifluoroethylene units can tune the polymer crystal structure and crystallinity, alter the state of polymer chains and the response of dipoles to electric fields, and lead to dramatic changes in dielectric properties, breakdown strength (Eb), and energy storage density (Ue). As a result, the copolymer with a chlorotrifluoroethylene content of 15 wt% obtained the best overall performance, and the Ue reached 16.73 J/cm3 at 650 kV/mm. This work provides a basis for the optimisation of the properties of polyvinylidene fluoride-based ferroelectric polymers and the development of high Ue dielectric.

聚偏氟乙烯基铁电聚合物具有强自发极化性和高介电常数(εr),因此在先进的高储能介质电容器领域备受青睐。研究证实,聚偏氟乙烯与氯三氟乙烯和六氟丙烯等大体积单体共聚可调节铁电行为和储能性能。以往基于这些共聚物的研究大多集中于复合材料的制备,但对共聚物成分的影响讨论有限。在这项研究中,我们通过溶液浇铸法制备了一系列氯代三氟乙烯含量不同的 P(VDF-CTFE)薄膜。引入大体积的三氟氯乙烯单元可以调整聚合物晶体结构和结晶度,改变聚合物链的状态和偶极子对电场的响应,并导致介电性能、击穿强度(Eb)和储能密度(Ue)发生巨大变化。结果,氯三氟乙烯含量为 15 wt% 的共聚物获得了最佳的综合性能,在 650 kV/mm 时,Ue 达到 16.73 J/cm3。这项研究为优化聚偏氟乙烯基铁电聚合物的性能和开发高 Ue 介电体奠定了基础。
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引用次数: 0
Flexible smart surface coating for GIS/GIL epoxy insulators 用于 GIS/GIL 环氧绝缘子的柔性智能表面涂层
IF 2.7 Q1 Physics and Astronomy Pub Date : 2024-01-02 DOI: 10.1049/nde2.12074
Yu-Huai Wang, Zhuo Chen, Jin Li, Zhi-Xiang Liu, Rong Chen, Hein Htet Aung, Hu-Cheng Liang, Bo-Xue Du

A flexible smart coating with electroluminescence effect was designed and fabricated on the surface of gas insulated switch gear (GIS)/gas insulated transmission line (GIL) epoxy insulators based on two-step curing process. As the AC voltage increases, the luminous area on the insulator surface expands from the centre to the periphery, and the light intensity shows a linear relationship with the applied voltage. Besides, the flexible smart coating can effectively identify the location of metal particle defects and the degree of electric field distortion. The flexible smart coating enhances the surface flashover voltage due to its higher dielectric constant. Simultaneously, metal particle contamination can substantially reduce the insulation performance of epoxy insulators, particularly when they are located near the high-voltage side. It is hoped that this study can provide a reference for the smart detection of surface defects GIS/GIL basin insulators.

基于两步固化工艺,在气体绝缘开关设备(GIS)/气体绝缘输电线路(GIL)环氧绝缘子表面设计并制造了一种具有电致发光效果的柔性智能涂层。随着交流电压的增加,绝缘体表面的发光面积从中心向外围扩展,发光强度与所加电压呈线性关系。此外,柔性智能涂层还能有效识别金属颗粒缺陷的位置和电场畸变程度。由于柔性智能涂层的介电常数较高,它能增强表面闪络电压。同时,金属颗粒污染会大大降低环氧绝缘体的绝缘性能,尤其是当它们位于高压侧附近时。希望本研究能为 GIS/GIL 盆式绝缘子表面缺陷的智能检测提供参考。
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引用次数: 0
Enhanced electrocaloric effect over a broad temperature range in lead-free Na0.5Bi0.5TiO3-based relaxor ferroelectrics via doping with Bi(Mg0.5Zr0.5)O3 通过掺杂 Bi(Mg0.5Zr0.5)O3,在无铅 Na0.5Bi0.5TiO3 基弛豫铁电体中增强宽温度范围内的电致发光效应
IF 2.7 Q1 Physics and Astronomy Pub Date : 2023-12-06 DOI: 10.1049/nde2.12069
Xiang Niu, Yuleng Jiang, Junying Lai, Wei Liang, Huanwei Liu, Xiaodong Jian, Xiaobo Zhao, Yingbang Yao, Bo Liang, Tao Tao, Sheng-Guo Lu

With an increasing demand for environmentally friendly refrigeration, the solid-state refrigeration based on the electrocaloric effect (ECE) has been drawn extensive attention. It is a challenge to maintain a large adiabatic temperature change (∆T) over a broad temperature span. Herein, the authors designed and synthesised (0.74-x) Na0.5Bi0.5TiO3-0.06BaTiO3-0.2SrTiO3-xBi(Mg0.5Zr0.5)O3 (abbreviated as NBT-xBMZ) (x = 0, 0.02, 0.04, 0.06 and 0.08) lead-free relaxor ferroelectrics. Their microstructures, dielectric properties, ferroelectric properties, ECEs and the structure-property relationships were investigated. Via doping with BMZ, an enhanced relaxor feature and a wider temperature range where multi-phases coexist were achieved. The relaxor ferroelectric characteristics were illustrated using the Vogel-Fulcher relation. The indirectly calculated ECE results showed that the optimal ΔT of 1.11 K was obtained for the x = 0.02 sample at 90°C and 70 kV/cm over a wide Tspan of 120°C, providing a potential ECE material. The direct ECE results procured using thermocouple indicated that the maximal ∆T of 2.14 K and ∆T/∆E of 0.31 K m/MV were achieved in the same sample at 70°C and 7 MV/m and the variation trend of ECE results was consistent with the indirect results. Moreover, the multi-phases coexistent strategy can be extended to other materials system to generate a large ΔT over a wide temperature range.

随着人们对环保制冷的需求日益增加,基于电热效应(ECE)的固态制冷受到了广泛的关注。在较宽的温度范围内保持较大的绝热温度变化(∆T)是一项挑战。在此,作者设计并合成了(0.74‐x) Na0.5Bi0.5TiO3‐0.06 batio3‐0.2SrTiO3‐xBi(Mg0.5Zr0.5)O3(缩写为NBT‐xBMZ) (x = 0,0.02, 0.04, 0.06和0.08)无铅弛豫铁电体。研究了它们的显微结构、介电性能、铁电性能、电化学性能和结构-性能关系。通过掺杂BMZ,实现了增强的弛豫特性和更宽的多相共存温度范围。利用Vogel - Fulcher关系说明了弛豫铁电特性。间接计算的ECE结果表明,在90°C和70 kV/cm的120°C宽Tspan下,x = 0.02样品获得了1.11 K的最佳ΔT,提供了一种潜在的ECE材料。采用热电偶直接测得的ECE结果表明,同一样品在70℃、7 MV/m条件下,最大∆T为2.14 K,∆T/∆E为0.31 K m/MV, ECE结果的变化趋势与间接测得结果一致。此外,多相共存策略可以扩展到其他材料体系,在宽温度范围内产生大的ΔT。
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引用次数: 0
Research progress in insulating and thermal conductivity of fluorinated graphene and its polyimide composites 氟化石墨烯及其聚酰亚胺复合材料的绝缘性和导热性研究进展
IF 2.7 Q1 Physics and Astronomy Pub Date : 2023-12-04 DOI: 10.1049/nde2.12068
Xin Wang, Shuyan Liu, Haoyu Han, Xiangyang Liu, Xu Wang

The demand for innovative thermal management materials with superior thermal conductivity and electrical insulating properties has significantly increased with the development of portable and flexible electronic gadgets. Fluorinated graphene (FG) has recently attracted the attention of the scientific community because of its exceptional thermal conductivity and electrical insulating qualities. This work aims to provide a detailed analysis of the structure-property relationships inherent in FG, including both chemical and physical properties, and to explain the FG manufacturing process. Special attention should be paid to a thorough analysis of the thermodynamic conduction mechanism exhibited by FG, including the effects of corrugation size, fluorine coverage, and fluorine atom distribution on its thermal conductivity. The essay also examines in-depth the most current and cutting-edge developments addressing the utilisation of FG as a functional filler in composite-modified polyimide (PI) materials. Furthermore, it has been noted as a crucial component in answering the needs for possible applications by maximising thermal conductivity and mechanical qualities in FG/PI composites through particular FG structural engineering and increased FG-PI interaction. As a result, these elements serve as the main focus of ongoing research projects, highlighting important directions for development and investigation.

随着便携式和柔性电子产品的发展,对具有优异导热性和电绝缘性能的创新热管理材料的需求显著增加。氟化石墨烯(FG)由于其优异的导热性和电绝缘性能,最近引起了科学界的关注。这项工作的目的是提供FG固有的结构-性质关系的详细分析,包括化学和物理性质,并解释FG的制造过程。特别需要注意的是对FG所表现出的热力学传导机制进行深入的分析,包括波纹尺寸、氟覆盖范围和氟原子分布对其导热性的影响。本文还深入研究了在复合改性聚酰亚胺(PI)材料中使用FG作为功能填料的最新和最前沿的发展。此外,它被认为是通过特殊的FG结构工程和增加FG - PI相互作用来最大限度地提高FG/PI复合材料的导热性和机械质量,以满足潜在应用需求的关键组成部分。因此,这些元素成为正在进行的研究项目的主要焦点,突出了发展和研究的重要方向。
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引用次数: 0
Siloxane-containing polyimide films with high heat resistance and low dielectric constant 具有高耐热性和低介电常数的含硅氧烷聚酰亚胺薄膜
IF 2.7 Q1 Physics and Astronomy Pub Date : 2023-11-23 DOI: 10.1049/nde2.12064
Song Mo, Lei Zhai, Yi Liu, Gang Han, Yan Jia, Min-Hui He, Lin Fan

A series of siloxane-containing polyimide films (PIS) were prepared by copolymerising with rigid aromatic dianhydride, siloxane diamines and six different aromatic diamines. The effects of siloxane structures, fluorine and imide content, rigid or flexible segment on the heat resistance, moisture absorption, dielectric performance, mechanical and bonding properties were systematically studied. The results show that PIS films maintain good heat resistance with Tg between 292 and 420°C and 5% weight loss temperature higher than 500°C. The moisture absorption and dielectric constant can be significantly reduced due to the presence of siloxanes and fluorinated groups, with the absorption rate as low as 1.2% and dielectric constant of 2.85 at 1 MHz. When measured at 10 GHz, the dielectric constant ranges from 3.10 to 3.50, and dielectric loss varies from 0.0059 to 0.0098. The PIS-6 film has the best comprehensive performance due to the low imide content, introduction of trifluoromethyl and ether bonds. The peeling strength of bonding PIS-6 film with a copper foil can reach 9.2 N/cm. It is proven that siloxane-containing PIS films with high heat resistance, low dielectric and outstanding adhesion are achieved, which can be applied for flexible integrated circuit boards, high-frequency electronics and microelectronics fields.

通过与刚性芳香族二酐、硅氧烷二胺和六种不同的芳香族二胺共聚,制备了一系列含硅氧烷的聚酰亚胺薄膜(PIS)。系统研究了硅氧烷结构、氟和亚胺含量、刚性或柔性段对耐热性、吸湿性、介电性能、机械和粘接性能的影响。结果表明,PIS 薄膜能保持良好的耐热性,其 Tg 在 292 至 420°C 之间,5% 失重温度高于 500°C。由于硅氧烷和氟化基团的存在,吸湿率和介电常数可显著降低,吸湿率低至 1.2%,介电常数在 1 MHz 时为 2.85。在 10 千兆赫时,介电常数在 3.10 至 3.50 之间,介电损耗在 0.0059 至 0.0098 之间。由于亚胺含量低、引入了三氟甲基和醚键,PIS-6 薄膜的综合性能最好。PIS-6 薄膜与铜箔粘合的剥离强度可达 9.2 N/cm。实验证明,含硅氧烷的 PIS 薄膜具有高耐热性、低介电性和出色的附着力,可应用于柔性集成电路板、高频电子和微电子领域。
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引用次数: 0
AI safety of film capacitors 薄膜电容器的 AI 安全性
IF 3.8 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2023-11-16 DOI: 10.1049/nde2.12071
Yong-Xin Zhang, Fang-Yi Chen, Di-Fan Liu, Jian-Xiao Wang, Qi-Kun Feng, Hai-Yang Jiang, Xin-Jie Wang, Hong-Bo Zhao, Shao-Long Zhong, Faisal Mehmood Shah, Zhi-Min Dang

With a large number of film capacitors being deployed in critical locations in electrical and electronic systems, artificial intelligence (AI) technology is also expected to address the problems encountered in this process. According to our findings, AI applications can cover the entire lifecycle of film capacitors. However, the AI safety hazards in these applications have not received the attention they deserve. To meet this, the authors argue, with specific examples, risks that flawed, erratic, and unethical AI can introduce in the design, operation, and evaluation of film capacitors. Human-AI common impact and more multi-dimensional evaluation for AI are proposed to better cope with unknown, ambiguity, and known risks brought from AI in film capacitors now and in the future.

随着大量薄膜电容器被部署在电气和电子系统的关键位置,人工智能(AI)技术也有望解决这一过程中遇到的问题。根据我们的研究结果,人工智能应用可覆盖薄膜电容器的整个生命周期。然而,这些应用中的人工智能安全隐患并未得到应有的重视。为此,作者通过具体实例论证了有缺陷、不稳定和不道德的人工智能在薄膜电容器的设计、运行和评估中可能带来的风险。作者提出了人类与人工智能的共同影响以及对人工智能进行更多维度评估的建议,以更好地应对人工智能在薄膜电容器中带来的未知、模糊和已知风险。
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引用次数: 0
Improvement of the flashover threshold of TUK pressboard by using FeO3-based nanofluid of monoesters 使用基于 FeO3 的单酯纳米流体提高 TUK 压板的闪蒸阈值
IF 2.7 Q1 Physics and Astronomy Pub Date : 2023-11-13 DOI: 10.1049/nde2.12070
Jean Lambert Jiosseu, Ghislain Mengata Mengounou, Emeric Tchamdjio Nkouetcha, Adolphe Moukengue Imano

This article deals with the improvement of the dielectric properties of TUK cellulose paper by impregnation. The experiment was carried out using a nanofluid based on vegetable oil esters and iron nanoparticles (FeO3). The insulating liquids used are palm kernel oil methyl ester (PKOME) and castor oil methyl ester (COME). The evaluation of the improvement is based on the analysis of the flashover voltage of the creeping discharges produced on the immersed paper. The tests were carried out under a positive lightning impulse voltage and for two electrode configurations. The concentrations of nanoparticles used in the experiment are 0.10 wt.%, 0.15 wt.% and 0.20 wt.%. The experimental results show that the 0.10 wt.% concentration gives the best improvement for the two electrode configurations used. The improvements are 53% for the inclined tip and 56.90% for the vertical tip in the case of COME + FeO3. For PKOME + FeO3, the results are 59.90% and 64.60%, respectively, for the two configurations.

本文论述了通过浸渍法改善 TUK 纤维素纸的介电性能。实验使用了基于植物油酯和纳米铁粒子(FeO3)的纳米流体。使用的绝缘液体是棕榈仁油甲酯(PKOME)和蓖麻油甲酯(COME)。对改进效果的评估基于对浸入纸张中产生的蠕变放电闪络电压的分析。测试是在正雷电冲击电压下进行的,并采用了两种电极配置。实验中使用的纳米粒子浓度分别为 0.10 wt.%、0.15 wt.% 和 0.20 wt.%。实验结果表明,0.10 wt.%的浓度对所用的两种电极配置的改善效果最好。在 COME + FeO3 的情况下,倾斜电极头的改进率为 53%,垂直电极头的改进率为 56.90%。对于 PKOME + FeO3,两种配置的结果分别为 59.90% 和 64.60%。
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引用次数: 0
Improved dielectric and energy storage properties of three-dimensional BaTiO3/polyvinyl alcohol-boron nitride flexible dielectric composite via template infiltration strategy 通过模板浸润策略改善三维 BaTiO3/ 聚乙烯醇-氮化硼柔性介电复合材料的介电和储能性能
IF 2.7 Q1 Physics and Astronomy Pub Date : 2023-11-01 DOI: 10.1049/nde2.12067
Yongzhi Yang, Jinxiang Chao, Peng Jiang, Runhan Xu, Yuchao Li, Yanhu Zhan, Zhicheng Shi, Chengzhu Liao

Continuous three-dimensional BaTiO3 (3DBT) ceramic network was prepared by the sol-gel method using cleanroom wipers as the template. Subsequently, flexible 3DBT/polyvinyl alcohol-boron nitride nanosheets (PVA-BNNS) composite dielectric films were facilely fabricated by inversely introducing different BNNS concentrations of PVA-BNNS solution into the 3DBT network. The results demonstrated that PVA solution effectively embedded into the 3DBT framework through an inverse infiltration process, thereby endowing the material with excellent flexibility. The content of 3DBT in the saturated 3DBT/PVA-BNNS composite was ∼27 wt% (6.9 vol%). In addition, the 3DBT/PVA-1.0%BNNS system exhibited an excellent dielectric constant of 17.4 (at 1 kHz), a high breakdown strength of 114.5 kV·mm−1 and an energy density of 2.51 J·cm−3 (at 110 kV·mm−1), being 1.67, 1.58 and 7.17 times higher than those of traditional fabricated 27 wt% nano-BT/PVA (at 70 kV·mm−1) composite, respectively. What's more, the obtained 3DBT/PVA-BNNS dielectric film exhibited superior thermal and mechanical stability, indicating potential applications in harsh environments.

以洁净室擦拭布为模板,采用溶胶-凝胶法制备了连续的三维 BaTiO3(3DBT)陶瓷网络。随后,将不同浓度的 PVA-BNNS 溶液反向引入 3DBT 网络,轻松制备出柔性 3DBT/ 聚乙烯醇-氮化硼纳米片(PVA-BNNS)复合介质薄膜。结果表明,PVA 溶液通过反向渗透过程有效地嵌入了 3DBT 框架,从而使材料具有优异的柔韧性。饱和 3DBT/PVA-BNNS 复合材料中的 3DBT 含量为 27 wt%(6.9 vol%)。此外,3DBT/PVA-1.0%BNNS 系统显示出 17.4 的优异介电常数(1 kHz 时)、114.5 kV-mm-1 的高击穿强度和 2.51 J-cm-3 的能量密度(110 kV-mm-1 时),分别是传统制备的 27 wt%纳米-BT/PVA(70 kV-mm-1 时)复合材料的 1.67、1.58 和 7.17 倍。此外,所获得的 3DBT/PVA-BNNS 介电薄膜还具有优异的热稳定性和机械稳定性,这表明它在恶劣环境中具有潜在的应用前景。
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引用次数: 0
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IET Nanodielectrics
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