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Fifteenth Annual Battery Conference on Applications and Advances (Cat. No.00TH8490)最新文献

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A regenerative zinc air fuel cell for industrial and specialty vehicles 一种用于工业和特种车辆的再生锌空气燃料电池
S. Smedley
Metallic Power has demonstrated a regenerative zinc/air fuel cell for applications in industrial and specialty vehicles. The fuel cell uses zinc pellets and atmospheric oxygen to generate electric current. The reaction product is zinc oxide, which is collected in a tank. In its present stage of development, the 36 V fuel cell will deliver approximately 6 kWh, with a maximum power of 4 kW. The device is refuelled at a zinc recycling/refuelling station where zinc pellets are pumped into each cell. ZnO is pumped from the tank and replaced with KOH electrolyte. The recycling/refuelling unit uses an electrolytic process to convert zinc oxide powder into zinc pellets.
金属动力公司已经展示了一种用于工业和特种车辆的再生锌/空气燃料电池。燃料电池使用锌球和大气中的氧气来产生电流。反应产物是氧化锌,它被收集在一个罐中。在目前的开发阶段,36v燃料电池将提供约6千瓦时,最大功率为4千瓦。该装置在锌回收/加注站进行加注,锌颗粒被泵入每个电池。将氧化锌从罐中抽出,用KOH电解液代替。回收/加注装置采用电解工艺将氧化锌粉转化为锌粒。
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引用次数: 7
Development of a 50 kW, high efficiency, high power density, CO-tolerant PEM fuel cell stack system 开发50kw、高效率、高功率密度、耐co的PEM燃料电池堆系统
T. Rehg, R. Loda, N. Minh
Honeywell has been developing a 50-kW net proton exchange membrane (PEM) fuel cell stack system for transportation applications. The stack system is comprised of a PEM fuel cell stack and supporting gas, thermal and water management subsystems and is capable of integration with a number of fuel processors. The present effort focuses on system design and analysis, stack technology development, and fabrication and testing of 10-kW class stacks leading to the demonstration of a 50 kW brassboard system. This paper summarizes the status of the PEM technology being developed at Honeywell.
霍尼韦尔(Honeywell)一直在开发一种用于交通运输的50千瓦净质子交换膜(PEM)燃料电池堆系统。该堆系统由PEM燃料电池堆和支持气体、热和水管理子系统组成,能够与许多燃料处理器集成。目前的工作重点是系统设计和分析,堆栈技术开发,以及10千瓦级堆栈的制造和测试,从而演示50千瓦的铜板系统。本文综述了霍尼韦尔PEM技术的发展现状。
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引用次数: 2
Primary zinc-air for portable electronic consumer products 便携式电子消费品用初级锌空气
D. Sieminski
The primary zinc-air electrochemical couple is an attractive power source for use in portable electronic consumer products because it has excellent characteristics for several key requirements of this market. Up until now, the use of primary zinc-air in the portable product market has been problematic because abbreviated operating life caused by water transpiration between the electrolyte and the atmosphere precluded consideration for most applications. The development of a "diffusion air manager" technology has addressed this problem making primary zinc-air batteries with operating life suited to portable consumer products possible. A zinc-air battery design incorporating diffusion air manager technology applicable to portable products is examined.
初级锌-空气电化学偶因其具有满足该市场几个关键要求的优异特性而成为便携式电子消费产品中有吸引力的电源。到目前为止,在便携式产品市场上使用初级锌空气一直存在问题,因为电解液和大气之间的水分蒸腾导致使用寿命缩短,因此大多数应用都无法考虑。“扩散空气管理器”技术的发展解决了这一问题,使一次锌空气电池的工作寿命适合便携式消费产品成为可能。研究了一种适用于便携式产品的采用扩散空气管理器技术的锌空气电池设计方案。
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引用次数: 3
Stochastic battery discharge in portable communication devices 便携式通信设备中的随机电池放电
C. F. Chiasserinia, Ramesh R. Rao
The objective of this work is to explore ways in which performance of battery systems can be enhanced through the use of energy-efficient battery management techniques. The phenomenon of charge recovery that takes place under pulsed discharge conditions is identified as a mechanism that can be exploited to enhance the capacity of a cell in a portable communication device. The bursty nature of many data traffic sources suggests that data transmissions in communication devices may provide natural opportunities for charge recovery. We model the data source as a stochastic process and let the cell discharge be driven by such a process. We use a model of a dual lithium ion insertion cell to identify the improvement to cell capacity that results from the stochastic discharge. The insight from this study leads us to propose discharge shaping techniques that tradeoff energy efficiency with delay in power supply.
这项工作的目的是探索通过使用节能电池管理技术来提高电池系统性能的方法。在脉冲放电条件下发生的电荷恢复现象被确定为一种可以用来增强便携式通信设备中电池容量的机制。许多数据通信源的突发性质表明,通信设备中的数据传输可能为电荷恢复提供自然的机会。我们将数据源建模为一个随机过程,并让电池放电由这样一个过程驱动。我们使用双锂离子插入电池模型来确定随机放电对电池容量的改善。这项研究的见解使我们提出了在能源效率和供电延迟之间进行权衡的放电整形技术。
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引用次数: 12
High pulse power batteries for air deployable Navy applications 用于海军空中部署的高脉冲动力电池
T. Squires, P.B. Keller, C. Winchester, P.H. Smith
The US Navy needs a high-power battery for an advanced sonobuoy. Several chemistries and designs have been examined and reported upon. The main focus at this point is on thermal batteries and lithium/sulfur dioxide (Li/SO/sub 2/) batteries. Other chemistries have been evaluated (e.g. lithium/manganese dioxide and lithium/thionyl chloride), however only lithium/sulfur dioxide and thermals have the combination of high power, energy, and low cost (producibility) that is required.
美国海军需要为先进声纳浮标配备高功率电池。一些化学和设计已经被检查和报道。目前的主要焦点是热电池和锂/二氧化硫(Li/SO/sub 2/)电池。其他化学物质也被评估过(例如锂/二氧化锰和锂/亚硫酰氯),但是只有锂/二氧化硫和热剂具有所需的高功率、高能量和低成本(可生产性)的组合。
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引用次数: 0
Lithium-polymer electrolyte rechargeable batteries 锂聚合物电解质可充电电池
H. V. Venkatasetty
There have been increasing efforts to develop lithium/polymer rechargeable batteries with high rate capability and long cycle life. Research efforts in preparing novel lithium-polymer electrolytes with enhanced conductivity have shown some progress and there is a great need for high conductivity electrolytes. Improvements made in the preparation of electrolytes with enhanced conductivity are described. Results of our research and development efforts on lithium rechargeable batteries with superacid-based electrolytes are presented.
高倍率、长循环寿命的锂/聚合物可充电电池的开发已经得到了越来越多的关注。制备新型高导电性锂聚合物电解质的研究取得了一定进展,对高导电性电解质的需求很大。描述了在制备具有增强导电性的电解质方面所作的改进。介绍了我国超酸性电解质锂充电电池的研究与开发成果。
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引用次数: 3
The Uncharted Territory-Thin Metal Film lead acid batteries 未知的领域——金属薄膜铅酸电池
J. Mcdermott
The recent push in battery technology has been to increase the specific energy of the battery as measured in watt-hours per kilogram, while maintaining the power capability of the battery as measured in Watts per Kilogram. BOLDER Technologies Corporation has developed an innovative battery technology that goes where no battery has gone before (The Uncharted Territory) with respect to specific power. Their patented Thin Metal Film (TMF) technology provides innovative battery solutions to a power hungry battery market. Previous publications relative to TMF technology have focused on performance at the cell level. BOLDER Technologies has recently introduced an emergency engine start product called SecureStart, which is based on the most powerful commercially produced battery on earth. This paper briefly highlights TMF technology, and focuses on performance data for their SecureStart product.
电池技术的最新进展是提高电池的比能量(以每公斤瓦时为单位),同时保持电池的功率能力(以每公斤瓦数为单位)。BOLDER技术公司开发了一种创新的电池技术,在特定功率方面,它可以达到以前没有电池去过的地方(未知领域)。他们的专利金属薄膜(TMF)技术为耗电的电池市场提供了创新的电池解决方案。以前有关TMF技术的出版物主要集中在单元级的性能上。BOLDER Technologies最近推出了一款名为SecureStart的紧急发动机启动产品,该产品基于地球上最强大的商业生产电池。本文简要介绍了TMF技术,并重点介绍了他们的SecureStart产品的性能数据。
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引用次数: 0
Advances and trends in primary and small secondary batteries with zinc anodes and manganese dioxide and/or air cathodes 锌阳极、二氧化锰和/或空气阴极的一次电池和小型二次电池的进展和趋势
B. Schumm
Incremental improvements continue to be made year by year in the consumer carbon-zinc and alkaline zinc-manganese dioxide cells. In addition, primary and secondary zinc-air cells many with substantial amounts of manganese dioxide in the cathode are becoming more common in consumer use. The gain in the past fifteen years in the carbon zinc cells approaches fifteen percent and that in alkaline cells-twenty percent. None the less the progress in zinc-air cells is most impressive as more and more commercial, compact designs appear for special purposes. These cells can produce more service than lithium cells of the same size. Finally the commercial presence of small secondary alkaline zinc-manganese dioxide cells continues. These cells are able to compete on a primary basis on heavy loads and much more obviously as rechargeable cells.
碳-锌电池和碱性锌-二氧化锰电池每年都在不断改进。此外,阴极含有大量二氧化锰的一次和二次锌空气电池在消费者使用中越来越普遍。在过去的15年里,碳锌电池的增幅接近15%,碱性电池的增幅为20%。尽管如此,锌空气电池的进步是最令人印象深刻的,因为越来越多的商业,紧凑的设计出现在特殊用途上。这些电池可以产生比相同尺寸的锂电池更多的服务。最后,小型二次碱性锌-二氧化锰电池继续商业化。这些电池能够在重载的基础上竞争,更明显的是作为可充电电池。
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引用次数: 2
Improved charge algorithms for valve regulated lead acid batteries 改进阀控铅酸电池的充电算法
E. Sexton, R. Nelson, J. Olson
The cycle life obtained from valve-regulated lead-acid (VRLA) batteries is strongly influenced by the manner in which they have been charged over their lifetime. Although VRLA batteries initially behave similarly to their flooded counterparts, that behavior changes as the batteries age and the oxygen generation/recombination cycle begins to dominate at near 100% full charge. This means that an increasing portion of the applied charge is consumed in the recombination cycle and that more and more overcharge must be applied to maintain full capacity. The overall result is that the battery heats up because of increased overcharge and oxygen generation. Conventional charge approaches attempt to deal with rising temperatures by lowering the current during the overcharge phase. However, this approach does not ultimately prevent capacity loss, and a battery charged thusly typically will yield 200-300 cycles to 50% of initial capacity. The main failure mode appears to be undercharging of the negative plate, not positive-plate corrosion. Two approaches, called partial state of recharge (PSOR) and current interrupt (CI) were successful in extending battery life. PSOR uses nine limited recharge cycles followed by a tenth cycle using 120% charge return. The best PSOR cycle life to date is 1160 cycles to 50% and 800 cycles to 80%. CI uses a high current in the overcharge applied discontinuously to control battery temperature. CI effectively maintains negative-plate capacity, with an Optima group 34 deep-cycle battery yielding 415 cycles to 80% initial capacity and 760 cycles to 50%.
阀控铅酸(VRLA)电池的循环寿命受到其使用寿命中充电方式的强烈影响。虽然VRLA电池最初的表现与淹水电池相似,但随着电池老化,氧气生成/重组循环在接近100%充满电时开始占主导地位,这种行为会发生变化。这意味着越来越多的电荷在复合循环中被消耗,并且必须施加越来越多的过电荷以保持满容量。总的结果是,由于过度充电和氧气产生的增加,电池变热。传统的充电方法试图通过在过充电阶段降低电流来应对温度上升。然而,这种方法并不能最终防止容量损失,这样充电的电池通常会产生200-300次循环,达到初始容量的50%。主要的失效模式似乎是负极板充液不足,而不是正极板腐蚀。两种方法,称为部分充电状态(PSOR)和电流中断(CI),在延长电池寿命方面取得了成功。PSOR使用9个有限的充电周期,然后是第10个周期,充电回收率为120%。迄今为止,最佳PSOR循环寿命为1160次循环至50%,800次循环至80%。CI在过充电时使用大电流间断施加来控制电池温度。CI有效地保持了负极板容量,Optima group 34型深循环电池的初始容量为80%,循环415次,循环760次,初始容量为50%。
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引用次数: 8
Float life verification of a high purity VRLA battery system 高纯度VRLA电池系统浮子寿命验证
F. Fleming, Lei Gao
This paper examines float life verification of commercially available high purity VRLA batteries in light of this recent concern regarding negative electrode capacity loss and includes data from real-time room temperature float testing which has been ongoing for 10 years. The condition of the negative electrode, from both new and real-time aged product, has been carefully examined by both electrochemical measurements of the product and also by analyzing the morphology and crystallography of the plates. The condition of the positive grid has also been examined to determine the extent of corrosion. In conclusion, this paper demonstrates that by using a high purity VRLA technology, which has been commercially available for 25 years, it is possible to far exceed 2 years of reliable service. Properly designed batteries using this technology have been proven to deliver greater than 13 years in real-time float service.
鉴于最近对负极容量损失的关注,本文研究了商用高纯度VRLA电池的浮子寿命验证,并包括了持续10年的实时室温浮子测试数据。通过对产品的电化学测量和分析板的形貌和晶体学,对新产品和实时老化产品的负极状况进行了仔细的检查。还检查了正栅极的状况,以确定腐蚀的程度。总之,本文表明,通过使用高纯度的VRLA技术,该技术已经商业化了25年,有可能远远超过2年的可靠服务。使用该技术设计合理的电池已被证明可提供超过13年的实时浮子服务。
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引用次数: 0
期刊
Fifteenth Annual Battery Conference on Applications and Advances (Cat. No.00TH8490)
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