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Fifteenth Annual Battery Conference on Applications and Advances (Cat. No.00TH8490)最新文献

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Direct methanol fuel cells-status, challenges and prospects 直接甲醇燃料电池的现状、挑战和前景
S. Narayanan, T. Valdez, A. Kindler, C. Witham, S. Surampudi, H. Frank
The status of direct methanol fuel cell technology with respect to power density, efficiency and integrated system operation have been summarized. The key challenge in improving power density is combining with operation at low air flow rates in order to maintain a water balance, and achieve attractive system mass and size. Improved catalysts and membranes with low methanol permeability are key to achieving these improvements. Challenges relating to miniature DMFC for battery replacement are discussed. Possibilities of reduction in catalyst and membrane cost suggest that premium power applications (100 W-5 kW) could be an early point of entry for DMFC into commercial markets.
综述了直接甲醇燃料电池技术在功率密度、效率和综合系统运行等方面的研究现状。提高功率密度的关键挑战是与低空气流速下的运行相结合,以保持水平衡,并实现有吸引力的系统质量和尺寸。改进的催化剂和低甲醇渗透性的膜是实现这些改进的关键。讨论了用于电池更换的微型DMFC所面临的挑战。降低催化剂和膜成本的可能性表明,优质功率应用(100 W-5 kW)可能是DMFC进入商业市场的早期起点。
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引用次数: 4
Lithium-ion system advances 锂离子系统进展
W. McCracken, B. Parmley, C. Kelly, M. Crites, S. Wilson
During the past year, Eagle-Picher Technologies, LLC (EPT) has extensively studied and improved the lithium-ion chemistry to optimize it for use in aerospace applications. Notable progress has been made in the past several months under a US Government contract awarded in the fall of 1998. Studies have been ongoing on cell components, processing and cell performance. This paper focuses on recent findings of the EPT research and development team.
在过去的一年中,Eagle-Picher Technologies, LLC (EPT)广泛研究和改进了锂离子化学,以优化其在航空航天应用中的应用。根据1998年秋季授予的美国政府合同,过去几个月取得了显著进展。对细胞组成、加工和细胞性能的研究一直在进行中。本文重点介绍了EPT研发团队的最新研究成果。
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引用次数: 2
Capacity fade of Li-ion cells: comparison of DC and ENREV charging protocols 锂离子电池的容量衰减:直流和ENREV充电方案的比较
B. Popov, A. Durairajan, Y. Podrazhansky, R.C. Cope
Sony 18650S Li-ion cells have been cycled using direct current and ENREV pulse charging (CC-CV) protocols. The influence of the charging protocol on the capacity fade of these batteries has been analyzed using cyclic voltammetry, galvanostatic charge-discharge and impedance spectroscopy. Batteries with different cycle numbers charged using ENREV pulse charging protocol showed superior charge transfer performance and rate capabilities and more than 90% retention of the initial capacity after 800 cycles compared with 64% retention of capacity observed for batteries charged using DC charge protocol.
索尼18650S锂离子电池使用直流和ENREV脉冲充电(CC-CV)协议进行循环。利用循环伏安法、恒流充放电法和阻抗谱分析了充电方式对电池容量衰减的影响。使用ENREV脉冲充电协议对不同循环次数的电池进行充电后,电池的电荷传输性能和倍率能力均优于使用直流充电协议的电池,在800次循环后,电池的初始容量保留率超过90%,而使用直流充电协议的电池的容量保留率为64%。
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引用次数: 4
VRLA batteries: reflections on and realities of previous lntelec conferences VRLA电池:对以往电子会议的反思和现实
F. Vaccaro, J. Rhoades, B. Malley, K. Marion, B. Le
Previous Intelec conferences have produced papers that have addressed the unique properties of this relatively new cell design. In this work, the authors have attempted to review those previous articles critical to successful battery design, operation, testing, and performance. This paper's analysis starts with topics presented in the late eighties, i.e., the internal resistance-capacity relationship, and ends with the present day topic of noble metal catalysts. The review spans approximately ten years.
以前的电子会议已经发表了论文,讨论了这种相对较新的电池设计的独特特性。在这项工作中,作者试图回顾那些对成功的电池设计、操作、测试和性能至关重要的先前文章。本文的分析从80年代末提出的内阻-容量关系问题开始,以当今贵金属催化剂的主题结束。审查的时间跨度大约为十年。
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引用次数: 0
The status of high-power batteries for hybrid electric vehicles 混合动力汽车用大功率电池的现状
F. Kalhammer
This paper reviews the status and prospects of high-power batteries intended for application in power trains for hybrid electric vehicles. It is based on a survey of a d v a d batteries conducted by the author for the Califomia Air Resources Board in the first half of 1999. Hybrid electric vehicle (HEV) concepts and technology are still evolving, as are the associated requirements for energy storage. The most important requirements atablished or implied for several generic HEV typa are discussed to help judge the applicability of candidate batteries. On that basis, high power versions of nickel-metal hydride, lead acid, and lithium ion batteries meet the performance requirements for the power assidregeneration BEV application. Nickel-metal hydride, lithium ion and lithium polymer batteries appear suited for hybrid electric vehicles that have significant driving range on battery power alone. The status of these technologies and their prospects for availability w i t h the nexl 3-5 years are discussed. The emergence of hybrid electric vehicles promises viable markets for advanced batteries (as well as for electric power conversion, control and motor technologies) in electric transportation Hybrid electric vehicles especially those with significant battery-only driving range also might become stepping stones in the commercial introduction of electric vehicles that take advantage of the remarkable advances in battery technolog achieved over the past five years. Introduction The successful introduction of Toyota’s PRIUS hybrid vehicle in Japan and the announcements by Ronda and Toyota of plans to introduce their hybrid vehicles in the U.S. market have dramaiically increased interest in this new automotive product. Automobile mnufacturets, regulators and environmentalists see HEVs as a potentially major avenue to increasing vehicle energy efficiency and reducing the emissions of air pollutants. Enam and environmental policy leaders view HEVs especialiy those that derive a significant portion of the propulsion energy from electricity as a stratqy to replace imported oil with domestic energy resources and reduce the emissions of carbon dioxide. Final@, electric utilities consider grid-connected hybrid electric vehicles a possible business opportunity. Batteries are an essential component of the hybrid electric vehicle types currently under development. In the functionally simplest KEV concept, the battery is employed to store energy captured in regenerative braking plus make-up energy provided by the engine, to keep the battery at approximately 50% state-ofcharge (SoC). The stored energy is used as needed to start the vehicle’s combustion engine and assist the engine during acceleration. The Toyota PRIUS and Honda’s recently announced INSIGHT HEV are exampIes of this “Power AssisuRegmration” (PAIR) -hybrid electric vehicle. Most of the hybrid vehicles currently under development at the three major U.S. carmakers also fall in this cntegoty. This type of H
本文综述了大功率电池在混合动力汽车动力系统中的应用现状和前景。这是基于作者在1999年上半年为加州空气资源委员会所做的一项关于蓄电池的调查。混合动力电动汽车(HEV)的概念和技术仍在不断发展,对能量存储的相关要求也在不断发展。讨论了几种通用HEV类型确定或隐含的最重要要求,以帮助判断候选电池的适用性。在此基础上,高功率版本的镍氢电池、铅酸电池和锂离子电池满足了电力再生电动汽车应用的性能要求。镍氢电池、锂离子电池和锂聚合物电池似乎适合于混合动力汽车,因为它们仅靠电池供电就能行驶很远的距离。讨论了这些技术的现状及其在未来3-5年的应用前景。混合动力汽车的出现为先进电池(以及电力转换、控制和电机技术)在电动交通领域提供了可行的市场。混合动力汽车,尤其是那些仅靠电池续航里程的汽车,也可能成为商业引入电动汽车的垫脚石,这些汽车利用了过去5年电池技术取得的显著进步。丰田普锐斯混合动力汽车在日本的成功推出,以及朗达和丰田宣布计划在美国市场推出混合动力汽车,极大地增加了人们对这一新型汽车产品的兴趣。汽车制造商、监管机构和环保人士将混合动力汽车视为提高汽车能源效率和减少空气污染物排放的潜在主要途径。Enam和环境政策领导人认为,混合动力汽车,特别是那些从电力中获得大部分推进能源的混合动力汽车,是一种用国内能源取代进口石油并减少二氧化碳排放的战略。最后,电力公司认为并网的混合动力电动汽车是一个可能的商机。电池是目前正在开发的混合动力电动汽车的重要组成部分。在功能最简单的KEV概念中,电池用于存储再生制动捕获的能量以及发动机提供的补充能量,以使电池保持在大约50%的充电状态(SoC)。储存的能量在需要时用于启动车辆的内燃机,并在加速时辅助发动机。丰田普锐斯(PRIUS)和本田(Honda)最近发布的INSIGHT HEV就是这种“动力辅助注册”(Power AssisuRegmration,简称PAIR)混合动力汽车的代表。美国三大汽车制造商目前正在开发的大多数混合动力汽车也属于这一范畴。这种类型的混合动力汽车只需要一个相当小的电池,但是,必须有非常高的比功率能力,如下所述。混合动力电池及其控制系统不仅可以用来补充动力,还可以用来补充内燃机提供的能量。在这种情况下,电池由车载电源充电,它为车辆提供了一个有限的范围,它可以只使用电池供电,具有零本地排放和更低的石油衍生燃料消耗的相关优势。混合动力汽车的原型具有可用的电力范围被称为“并网”,“充电耗尽”或,在本文中,电范围(ER) hev已经被证明。ER混合动力车必须满足不同的要求,如下所述。然而,如果在电动汽车上添加一个非常小的内燃机,以提供紧急行驶里程,就会产生另一种类型的混合动力汽车。从电池的角度来看,这种“增程”HEV所需的电池类型与“纯”电池驱动的电动汽车所需的电池类型几乎没有区别。电源辅助/再生必须满足苛刻的要求。其中最重要的,以及对所需电池性能的影响,在第一个数据中被概括
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引用次数: 1
Increasing material utilization of lead-acid batteries using BPI technology 利用BPI技术提高铅酸电池的材料利用率
B. Mahato, D. Boughn, J. L. Arias
The lead-acid battery technology developed at Bipolar Power International (BPI) is the outcome of its 10 years of research work in developing bipolar lead-acid batteries. This work has resulted in new paste compositions for both positive and negative plates, which provide higher material utilization and better capacity-maintenance during cycling. The new positive paste is water-based using a pre-sulfated lead compound, with a conductive additive which improves the charge efficiency during formation. The negative paste is also water-based paste, using a pre-sulfated lead compound, and has a modified expander to improve formation efficiency. The material utilization efficiencies of both negative and positive active mass as obtained from the bipolar work are described. An initial experiment using this new paste on grid-type plates in a 12V/26Ah battery has demonstrated significant performance improvement over an identical commercial battery. Simplification and improvement of VRLA manufacturing processes also appear possible using the BPI paste.
国际双极电力公司(Bipolar Power International, BPI)开发的铅酸电池技术是其10年双极铅酸电池研究工作的成果。这项工作为正负极板带来了新的浆料组合物,在循环过程中提供了更高的材料利用率和更好的容量维护。新型正极浆料是水基的,使用了预硫酸盐铅化合物,并添加了导电添加剂,提高了形成过程中的电荷效率。负极膏体也是水基膏体,使用预硫酸盐铅化合物,并具有改性膨胀剂以提高地层效率。描述了从双极功中得到的负、正活性质量的物质利用效率。在12V/26Ah电池的栅格型板上使用这种新浆料的初步实验表明,与相同的商用电池相比,性能有了显著提高。使用BPI浆料,VRLA制造工艺的简化和改进也成为可能。
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引用次数: 1
Development of a 150-watt direct methanol fuel cell system 150瓦直接甲醇燃料电池系统的研制
T. Valdez, S. Narayanan, N. Rohatgi
Stack development for a Nafion(R) based 150-watt direct methanol fuel cell (DMFC) system is discussed in this paper. Single cell data for a membrane electrode assembly (MEA) that can operate at low air stoichiometry is presented. The stack operating conditions for achieving a water balance have been determined to be 55/spl deg/C 0.5 M MeOH at a maximum of 1.75 times air stoichiometry at 100 mA/cm/sup 2/. Single cells with a 25-cm/sup 2/ active area have been operated in this regime and can maintain an average cell voltage of 0.43 V at 100 mA/cm/sup 2/ for 120 minutes with a cell voltage decay of 0.2 mV/min. A five-cell stack with a 80-cm/sup 2/ active area, scaled up from the single cell, was capable of sustaining 100-mA/cm/sup 2/ load at a 1.75 air stoichiometry for over 70 hours, with a voltage decay of the order of 2 mV/hr. Voltage decay is reversible by purging excess water in the cathode.
本文讨论了一种基于Nafion(R)的150瓦直接甲醇燃料电池(DMFC)系统的电池组开发。介绍了一种能在低空气化学计量下工作的膜电极组件(MEA)的单细胞数据。达到水平衡的堆操作条件已确定为55/spl度/C, 0.5 M MeOH,最大1.75倍空气化学计量,100 mA/cm/sup / 2/。具有25 cm/sup 2/活性面积的单个电池在该状态下运行,可以在100 mA/cm/sup 2/下保持平均电池电压0.43 V 120分钟,电池电压衰减为0.2 mV/min。一个具有80 cm/sup 2/有效面积的五电池堆叠,在1.75空气化学计量下能够维持100 ma /cm/sup 2/负载超过70小时,电压衰减为2 mV/hr。通过清除阴极中多余的水,电压衰减是可逆的。
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引用次数: 3
Current status of lithium ion and lithium polymer secondary batteries 锂离子和锂聚合物二次电池的现状
G. Blomgren
Lithium ion batteries have only a short history in battery technology, but the remarkable growth in sales of these batteries has allowed them to take a leading position in the rechargeable battery field. The present status of these batteries in terms of performance, market and manufacturers is reviewed. The newly developing lithium ion polymer batteries may experience a similar growth to liquid electrolyte lithium ion batteries and take a major share in the rechargeable battery market, if they can solve some long standing problems. The companies taking a leading role and the status of their products is also reviewed. The potentiality for future growth is also discussed.
锂离子电池在电池技术上的历史并不长,但销量的显著增长使其在可充电电池领域占据了领先地位。综述了该类电池的性能、市场和生产厂家的现状。新发展的聚合物锂离子电池如果能够解决一些长期存在的问题,可能会经历与液体电解质锂离子电池类似的增长,并在可充电电池市场占据主要份额。并对处于主导地位的企业及其产品状况进行了综述。还讨论了未来增长的潜力。
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引用次数: 17
Comparative analysis of primary lithium cells 原生锂电池的对比分析
P. Krehl, E. Takeuchi
This paper presents a general overview of primary lithium battery systems. Performance data are shown for liquid cathode, solid cathode, and solid state systems. Future research and development programs are also noted.
本文介绍了一次锂电池系统的总体概况。性能数据显示为液体阴极,固体阴极和固态系统。未来的研究和发展计划也被指出。
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引用次数: 2
Development of the nickel-zinc battery for commercial applications 商用镍锌电池的开发
D. Coates, J. Rotondo, J. O'Neill
Rechargeable nickel-zinc batteries are being developed for consumer and mobile applications such as electric bicycles, scooters and hybrid and electric vehicles. Nickel-zinc cycle life performance has been improved through the development of a reduced solubility zinc electrode. Deep cycle capability has been increased to 600 cycles while maintaining a high specific energy up to 60 Wh per kilogram. Nickel-zinc provides a commercially viable alternative for lead-acid, nickel-cadmium and nickel-metal hydride batteries for many applications.
可充电镍锌电池正被开发用于消费和移动应用,如电动自行车、踏板车、混合动力和电动汽车。通过开发低溶解度锌电极,提高了镍锌循环寿命。深循环能力已增加到600次循环,同时保持高比能量高达60 Wh / kg。镍锌电池为铅酸电池、镍镉电池和镍氢电池的许多应用提供了商业上可行的替代品。
{"title":"Development of the nickel-zinc battery for commercial applications","authors":"D. Coates, J. Rotondo, J. O'Neill","doi":"10.1109/BCAA.2000.838415","DOIUrl":"https://doi.org/10.1109/BCAA.2000.838415","url":null,"abstract":"Rechargeable nickel-zinc batteries are being developed for consumer and mobile applications such as electric bicycles, scooters and hybrid and electric vehicles. Nickel-zinc cycle life performance has been improved through the development of a reduced solubility zinc electrode. Deep cycle capability has been increased to 600 cycles while maintaining a high specific energy up to 60 Wh per kilogram. Nickel-zinc provides a commercially viable alternative for lead-acid, nickel-cadmium and nickel-metal hydride batteries for many applications.","PeriodicalId":368992,"journal":{"name":"Fifteenth Annual Battery Conference on Applications and Advances (Cat. No.00TH8490)","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2000-01-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128853865","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
期刊
Fifteenth Annual Battery Conference on Applications and Advances (Cat. No.00TH8490)
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